ES2232300A1 - Production of antibotrytis fungicide for agricultural, food production and preparation and industrial application - Google Patents
Production of antibotrytis fungicide for agricultural, food production and preparation and industrial applicationInfo
- Publication number
- ES2232300A1 ES2232300A1 ES200302592A ES200302592A ES2232300A1 ES 2232300 A1 ES2232300 A1 ES 2232300A1 ES 200302592 A ES200302592 A ES 200302592A ES 200302592 A ES200302592 A ES 200302592A ES 2232300 A1 ES2232300 A1 ES 2232300A1
- Authority
- ES
- Spain
- Prior art keywords
- carboxylic acid
- polyalcohol
- food
- agricultural
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 6
- 235000013305 food Nutrition 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000000417 fungicide Substances 0.000 title abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 9
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 claims abstract description 6
- 125000003118 aryl group Chemical group 0.000 claims abstract description 3
- 239000000725 suspension Substances 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract 3
- 239000000047 product Substances 0.000 claims description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 230000003115 biocidal effect Effects 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 4
- 239000006228 supernatant Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- -1 carboxylic acid compound Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000002538 fungal effect Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003637 basic solution Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 241000233866 Fungi Species 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000004720 fertilization Effects 0.000 description 2
- 235000012055 fruits and vegetables Nutrition 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Procedimiento para la obtención de una composición de un antibotritis fungicida para uso agrícola alimentario e industrial.Procedure for obtaining a composition of a fungal antibiotic for agricultural use Food and industrial.
El objeto de la presente invención trata sobre un sistema sobre la fertilización de las plantas cultivables aportado el propio producto obtenido, por aplicación foliar y/o fertirrigación, de forma que dicha aportación signifique una dosis de un compuesto consistente en ácido insaturado esterificado con un polialcohol, tal que dicho compuesto permita combatir enfermedades en los cultivos causadas por el hongo "Botrytis Cinerea" y diversas cepas de "Mildiu" u otros hongos cualquiera que sea la cepa de origen y del mismo modo, también se permite su uso en alimentos o superficies donde se requiera asepsia frente a hongos y levaduras y puede ser utilizado como aditivo industrial en otro tipo de productos como el cemento.The object of the present invention is about a system on the fertilization of cultivable plants provided the product itself, by foliar application and / or fertirrigation, so that said contribution means a dose of a compound consisting of unsaturated acid esterified with a polyalcohol , such that said compound allows to fight diseases in crops caused by the fungus " Botrytis Cinerea " and various strains of " Mildiu " or other fungi whatever the strain of origin and in the same way, its use in food or surfaces is also allowed where asepsis is required against fungi and yeasts and can be used as an industrial additive in other products such as cement.
La técnica actual contempla la existencia de diversos productos y composiciones previstos para obtener la fertilización de las plantas cultivables, pero todos los procedimientos existentes conocidos, no ofrecen parecido alguno con la composición y productos utilizados en el sistema objeto del presente registro, siendo de otra parte los productos utilizados en los medios conocidos, de una gran agresividad medioambiental y de difícil eliminación espontánea, mientras que la composición del sistema que nos ocupa, al ser de uso agrícola y simultáneamente de uso alimentario, su aplicación resulta inocua y de eliminación espontánea instantánea, por lo que se considera muy beneficiosa su utilización en la agricultura o en la industria.The current technique contemplates the existence of various products and compositions planned to obtain the fertilization of arable plants, but all known existing procedures, offer no resemblance to the composition and products used in the system subject to present record, being on the other hand the products used in the known means of great environmental aggressiveness and of difficult spontaneous elimination while the composition of the system that concerns us, being of agricultural use and simultaneously of food use, its application is safe and eliminating Instant spontaneous, so it is considered very beneficial use in agriculture or industry.
La descripción de la composición del sistema con sus productos químicos para la obtención de un producto para uso agrícola y/o alimentario e industrial objeto del presente registro, consiste en un éster en matriz no acuosa a pH básico de ácido carboxílico diinsaturado y polialcohol en presencia de hierro.The description of the composition of the system with its chemical products to obtain a product for use agricultural and / or food and industrial object of this register, It consists of a non-aqueous matrix ester at basic acid pH di-unsaturated carboxylic and polyalcohol in the presence of iron.
Para la obtención del producto que se preconiza, se utilizará el siguiente proceso de fabricación:To obtain the product that is recommended, The following manufacturing process will be used:
1.- Síntesis del éster.1.- Synthesis of the ester.
El éster de ácido carboxílico diinsaturado y polialcohol, en presencia de hierro, pasa por las siguientes etapas:The diunsaturated carboxylic acid ester and Polyalcohol, in the presence of iron, goes through the following stages:
a) Selección y aprovisionamiento de las materias primas, consistentes en polialcohol, sulfato de hierro heptahidrato y ácido carboxílico diinsaturado.a) Selection and supply of materials raw, consisting of polyalcohol, iron sulfate heptahydrate and diunsaturated carboxylic acid.
b) En tanque agitado se introducen una cantidad de M Kg, de polialcohol y a continuación se agregan el 2% de hierro a base de sulfato de hierro, se agita constantemente durante un periodo de unas 6 horas.b) In an agitated tank an amount is introduced of M Kg, of polyalcohol and then 2% of iron are added based on iron sulfate, it is constantly stirred for a period of about 6 hours.
c) A continuación se adiciona el ácido carboxílico diinsaturado bajó la forma de sal potásica en proporción que puede oscilar entre el 1 y el 20%, junto con trazas de un antioxidante aromático e hidróxido de potasio y se mantiene constantemente la agitación 2 horas más.c) The acid is then added diunsaturated carboxylic lowered the potassium salt form in proportion that can range between 1 and 20%, along with traces of an aromatic antioxidant and potassium hydroxide and is maintained Stirring constantly 2 more hours.
d) Tras la agitación se obtiene una suspensión coloidal cuyo pH es ligeramente básico consistente en el éster que contiene la composición del sistema para obtener el producto para uso agrícola y/o alimentario e industrial.d) After stirring a suspension is obtained colloidal whose pH is slightly basic consisting of the ester that contains the composition of the system to obtain the product for agricultural and / or food and industrial use.
2.- La segunda fase consiste en la disolución del éster.2.- The second phase consists in the dissolution of the ester.
El éster que contiene el producto para uso agrícola y/o alimentario e industrial sintetizado como se explicó anteriormente, se diluye en agua a la dosis conveniente en otro tanque agitado, añadiendo el agua necesaria y manteniendo la agitación hasta su disolución completa.The ester that contains the product for use agricultural and / or food and industrial synthesized as explained previously, it is diluted in water at the convenient dose in another stirred tank, adding the necessary water and maintaining the stirring until complete dissolution.
3.- La siguiente fase comprende la adición de coadyuvantes y estabilizantes.3.- The next phase includes the addition of adjuvants and stabilizers.
A la disolución básica del producto para uso agrícola y/o alimentario e industrial objeto del presente registro, se le retoca el pH si fuera necesario adicionando hidróxido de potasio hasta conseguir un pH ligeramente básico (alrededor de 8 unidades de pH).To the basic dissolution of the product for use agricultural and / or food and industrial object of this register, pH is retouched if necessary by adding hydroxide of potassium until a slightly basic pH is achieved (about 8 pH units).
4.- Finalmente para la obtención del producto, se procede a la separación de materias inertes insolubles.4.- Finally to obtain the product, it proceeds to the separation of insoluble inert materials.
La disolución del producto obtenido para uso agrícola alimentario e industrial se mantiene en el tanque, en reposo, hasta que se separa una fase sólida y otra fase líquida sobrenadante, y una vez conseguido este propósito, la fase sólida se desprecia, mientras que la fase líquida sobrenadante ya estable se extrae constituyendo el producto finalizado utilizable para la agricultura y la industria listo para ser envasado.The dissolution of the product obtained for use Agricultural food and industrial remains in the tank, in rest, until a solid phase and another liquid phase are separated supernatant, and once this purpose is achieved, the solid phase it is neglected, while the liquid phase supernatant already stable it is extracted constituting the final product usable for the Agriculture and industry ready to be packaged.
5.- Envasado del producto obtenido.5.- Packaging of the product obtained.
El producto obtenido como antibotritis fungicida para uso agrícola alimentario e industrial fase líquida estable, se envasa en garrafas de polietileno de 1,5 y 20 litros para ser distribuido y aplicado en el sector agrícola o alternativamente en la industria agroalimentaria o en la industrial general como aditivo de otros productos.The product obtained as fungal antibiotic For agricultural food and industrial use stable liquid phase, it packaged in 1.5 and 20 liter polyethylene bottles to be distributed and applied in the agricultural sector or alternatively in the agri-food industry or in the general industry as Additive of other products.
El antibotritis fungicida obtenido con la debida composición, para uso agrícola se aplicará por fertirrigación o por pulverización a la dosis adecuadas según cultivos y periodos vegetativos, y también como tratamiento poscosecha para el mantenimiento de frutas y hortalizas en los almacenes de las centrales hortofrutícolas o en los puntos de venta al público de esos mismos productos.Fungicide antibotritis obtained with due composition, for agricultural use will be applied by fertirrigation or by spray at the appropriate dose according to cultures and periods vegetative, and also as a post-harvest treatment for fruit and vegetable maintenance in the warehouses of the fruit and vegetable plants or points of sale to the public of Those same products.
El mismo producto obtenido para uso alimentario, se aplicará a la dosis más conveniente, como fungiestático para evitar el desarrollo de hongos, levaduras y otros elementos extraños nocivos o como aditivo en la formulación de cementos u otros productos industriales.The same product obtained for food use, It will be applied at the most convenient dose, as fungistatic for prevent the development of fungi, yeasts and other elements harmful strangers or as an additive in cement formulation or Other industrial products.
Una vez descritas ampliamente las partes, composiciones y distintos productos con los que se constituye la composición de un sistema para la obtención de un producto para uso agrícola alimentario e industrial objeto del presente registro, solamente nos resta consignar la posibilidad de que los elementos que componen combinadamente el producto podrán presentar ciertas variaciones de acuerdo con estudios realizados, siempre y cuando las alteraciones incorporadas, no sean capaces de alterar los puntos esenciales de que es objeto el presente registro de Patente de Invención.Once the parts have been widely described, compositions and different products with which the composition of a system to obtain a product for use agricultural food and industrial object of this register, we only have to record the possibility that the elements which together make up the product may present certain variations according to studies, as long as the incorporated alterations, are not able to alter the points Essentials of the present Patent Registration of Invention.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200302592A ES2232300B1 (en) | 2003-11-06 | 2003-11-06 | PROCEDURE FOR OBTAINING A COMPOSITION OF AN ANTIBOTRITIS FUNGICIDE FOR FOOD AND INDUSTRIAL AGRICULTURAL USE. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200302592A ES2232300B1 (en) | 2003-11-06 | 2003-11-06 | PROCEDURE FOR OBTAINING A COMPOSITION OF AN ANTIBOTRITIS FUNGICIDE FOR FOOD AND INDUSTRIAL AGRICULTURAL USE. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2232300A1 true ES2232300A1 (en) | 2005-05-16 |
| ES2232300B1 ES2232300B1 (en) | 2007-03-01 |
Family
ID=34586121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES200302592A Expired - Fee Related ES2232300B1 (en) | 2003-11-06 | 2003-11-06 | PROCEDURE FOR OBTAINING A COMPOSITION OF AN ANTIBOTRITIS FUNGICIDE FOR FOOD AND INDUSTRIAL AGRICULTURAL USE. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2232300B1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3667964A (en) * | 1970-04-01 | 1972-06-06 | Exxon Research Engineering Co | Esters of 1,3 diols and 1,3,5 x-polyols as additives for baked goods |
| US3806615A (en) * | 1970-06-03 | 1974-04-23 | Exxon Research Engineering Co | Aliphatic diols and their esters as antimicrobial additives for cheese and meats |
| US4639541A (en) * | 1984-05-07 | 1987-01-27 | Consortium Fur Elektrochemische Industrie Gmbh | Substituted phenylacetic acid iodopropargyl esters, biocidal agents containing same and process for manufacturing same |
-
2003
- 2003-11-06 ES ES200302592A patent/ES2232300B1/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3667964A (en) * | 1970-04-01 | 1972-06-06 | Exxon Research Engineering Co | Esters of 1,3 diols and 1,3,5 x-polyols as additives for baked goods |
| US3806615A (en) * | 1970-06-03 | 1974-04-23 | Exxon Research Engineering Co | Aliphatic diols and their esters as antimicrobial additives for cheese and meats |
| US4639541A (en) * | 1984-05-07 | 1987-01-27 | Consortium Fur Elektrochemische Industrie Gmbh | Substituted phenylacetic acid iodopropargyl esters, biocidal agents containing same and process for manufacturing same |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2232300B1 (en) | 2007-03-01 |
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