ES2200665A1 - Metodo y aparato para separar metales no deseados de materiales que contienen hierro. - Google Patents
Metodo y aparato para separar metales no deseados de materiales que contienen hierro.Info
- Publication number
- ES2200665A1 ES2200665A1 ES200150068A ES200150068A ES2200665A1 ES 2200665 A1 ES2200665 A1 ES 2200665A1 ES 200150068 A ES200150068 A ES 200150068A ES 200150068 A ES200150068 A ES 200150068A ES 2200665 A1 ES2200665 A1 ES 2200665A1
- Authority
- ES
- Spain
- Prior art keywords
- metals
- lumps
- undesired
- iron
- typically
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 8
- 229910052751 metal Inorganic materials 0.000 title abstract 8
- 239000002184 metal Substances 0.000 title abstract 8
- 150000002739 metals Chemical class 0.000 title abstract 8
- 229910052742 iron Inorganic materials 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
- 238000009834 vaporization Methods 0.000 abstract 2
- 230000008016 vaporization Effects 0.000 abstract 2
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000010791 quenching Methods 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/2406—Binding; Briquetting ; Granulating pelletizing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0046—Making spongy iron or liquid steel, by direct processes making metallised agglomerates or iron oxide
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/04—Making spongy iron or liquid steel, by direct processes in retorts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/30—Obtaining zinc or zinc oxide from metallic residues or scraps
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/12—Dry methods smelting of sulfides or formation of mattes by gases
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
La presente invención se refiere a un método y aparato para separar metales tóxicos no deseados, tales como Zn, Pb y Cd, de materiales que contienen hierro mediante: sinterización de una mezcla de dichos materiales (típicamente incluyen polvo de EAF y cascarilla de laminación) con partículas carbonosas para formar bolas sinterizadas resistentes; precalentamiento de dichas bolas en una atmósfera no reductora, si es necesario, para conseguir una temperatura elevada generalmente por encima de la temperatura de vaporización de los metales no deseados, pero por debajo de la temperatura de adherencia de dichas bolas que contienen hierro (que típicamente está por debajo de las temperaturas de vaporización de dichos metales no deseados en su forma de óxido), alimentación de las bolas a dicha temperatura elevada en un reactor de reducción; hacer fluir gas reductor caliente por dichas bolas para volatilizar dichos metales reducidos no deseados y llevar los metales volatilizados fuera de dicho reactorde reducción, dejando las bolas que contienen hierro en gran parte separadas de los metales no deseados y listas para descargar y eliminar de forma segura y/o útil o volver a usar; y finalmente enfriamiento del gas de descarga del reactor para separar los metales no deseados solidificados resultantes (típicamente en su forma de óxido que resulta de un enfriamiento con agua).
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12156199P | 1999-02-25 | 1999-02-25 | |
| US60/121561 | 1999-02-25 | ||
| US09/505,811 US6379421B1 (en) | 1999-02-25 | 2000-02-17 | Method and apparatus removing undesirable metals from iron-containing materials |
| US09/505811 | 2000-02-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2200665A1 true ES2200665A1 (es) | 2004-03-01 |
| ES2200665B1 ES2200665B1 (es) | 2005-05-01 |
Family
ID=26819602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES200150068A Expired - Fee Related ES2200665B1 (es) | 1999-02-25 | 2000-02-23 | Metodo y aparato para separar metales no deseados de materiales que contienen hierro. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6379421B1 (es) |
| EP (1) | EP1165845B1 (es) |
| AU (1) | AU3317600A (es) |
| ES (1) | ES2200665B1 (es) |
| WO (1) | WO2000050649A2 (es) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE321364T1 (de) * | 2000-09-11 | 2006-04-15 | Antec Solar Energy Ag | Recycling-verfahren für cdte/cds- dünnschichtsolarzellenmodule |
| WO2002090604A2 (de) * | 2001-05-08 | 2002-11-14 | Voest-Alpine Industrieanlagenbau Gmbh & Co. | Verfahren und anlage zur verwertung von kohlenwasserstoff- und eisenoxidhaltigen abfallstoffen, insbesondere walzzunderschlämmen, und feinkohlen |
| PL1641948T3 (pl) * | 2003-07-04 | 2007-11-30 | Umicore Nv | Odzyskiwanie metali innych niż żelazo z pozostałości zawierających cynk |
| ES2289545T3 (es) * | 2003-09-29 | 2008-02-01 | Umicore | Proceso y aparato para recuperacion de metales no ferreos a partir de residuos de cinc. |
| RU2306348C1 (ru) * | 2005-12-21 | 2007-09-20 | Виктор Васильевич Кашин | Способ переработки цинксодержащих отходов черной металлургии |
| US7608129B2 (en) * | 2006-04-24 | 2009-10-27 | Hyl Technologies S.A. De C.V. | Method and apparatus for producing direct reduced iron |
| WO2007134725A2 (en) * | 2006-05-24 | 2007-11-29 | Saudi Basic Industries Corporation | Process for recycling of steel industry iron-bearing by-products by treating pellets in direct reduction furnaces |
| BRPI0720363A2 (pt) * | 2006-12-22 | 2013-12-24 | Umicore Nv | PROCESSO PARA PREPARAR PÓ DE LiMnPO4 CRISTALINO, PÓ DE LiMnPO4 CRISTALINO PARA USO COMO MATERIAL DE ELETRODO EM UMA BATERIA, USO DO MESMO, E MISTURA DE ELETRODO. |
| BRPI0809276A2 (pt) * | 2007-03-19 | 2014-10-14 | Umicore Nv | MATERIAL EM PÓ DE INSERÇÃO/EXTRAÇÃO DE Li; PROCESSO PARA PREPARAR O MESMO, BATERIA SECUNDÁRIA À BASE DE Li, E MISTURA DE ELETRODO PARA BATERIAS SECUNDÁRIAS À BASE DE Li. |
| US7968044B2 (en) * | 2007-04-30 | 2011-06-28 | Spraying Systems Co. | Sinter processing system |
| US8202345B2 (en) * | 2009-05-28 | 2012-06-19 | Premier Enviro Services, Inc. | Method of producing non-pyrophoric metallic iron |
| US8518146B2 (en) | 2009-06-29 | 2013-08-27 | Gb Group Holdings Limited | Metal reduction processes, metallurgical processes and products and apparatus |
| CA2775756A1 (en) * | 2009-09-29 | 2011-04-07 | Nu-Iron Technology, Llc | System and method for producing metallic iron |
| CA2775709A1 (en) | 2009-09-29 | 2011-04-07 | Nu-Iron Technology, Llc | System and method for producing metallic iron |
| DE102012011240A1 (de) * | 2012-06-06 | 2013-12-12 | Outotec Oyj | Verfahren zur Herstellung von gehärteten Granalien aus eisenhaltigen Partikeln |
| EP2677043A1 (de) * | 2012-06-21 | 2013-12-25 | Siemens VAI Metals Technologies GmbH | Verfahren und Vorrichtung zur Herstellung von flüssigem Roheisen oder flüssigem Stahlvorprodukt |
| RU2567782C2 (ru) * | 2013-09-24 | 2015-11-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Курганский государственный университет" | Способ получения металлического цинка из водной суспензии частиц, содержащих соединения этого элемента руды, и устройство для его осуществления |
| EP2905345A1 (de) * | 2014-02-10 | 2015-08-12 | Primetals Technologies Austria GmbH | Pneumatische Erzchargierung |
| RU2661323C2 (ru) * | 2016-12-23 | 2018-07-13 | Акционерное общество "Уралэлектромедь" | Способ извлечения цинка из цинкосодержащих отходов |
| US10704119B2 (en) | 2017-05-04 | 2020-07-07 | Nu-Iron Technology, Llc. | Cokeless sinter blend compositions |
| FI128915B (en) | 2019-02-28 | 2021-03-15 | Metalcirc Oy | PROCEDURE FOR ASH TREATMENT |
| DE102024111430A1 (de) * | 2024-04-23 | 2025-10-23 | Voestalpine Stahl Gmbh | Sinter für ein Direktreduktionsverfahren, Verfahren zur dessen Herstellung und Mischung zur Herstellung eines Sinters |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4473519A (en) * | 1980-02-13 | 1984-09-25 | Estel Hoogovens B.V. | Method of agglomeration of fly ash into pellets |
| US5474592A (en) * | 1993-05-27 | 1995-12-12 | Metallgesellschaft Aktiengesellschaft | Method of reprocessing metallurgical residues, which contain zinc and lead |
| US5667556A (en) * | 1995-05-05 | 1997-09-16 | Metallgesellschaft Aktiengesellschaft | Method of reprocessing zinc- and iron oxide-containing residual material |
| US5865875A (en) * | 1995-08-25 | 1999-02-02 | Maumee Research & Engineering, Inc. | Process for treating metal oxide fines |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1705128A (en) | 1925-07-20 | 1929-03-12 | Krupp Ag Grusonwerk | Process of producing zinc |
| US1800856A (en) * | 1926-04-07 | 1931-04-14 | Bradley Linn | Treating iron ore |
| US1816743A (en) | 1928-07-26 | 1931-07-28 | Queneau Augustin Leon Jean | Recovery of metals from ores |
| US2977216A (en) * | 1958-12-31 | 1961-03-28 | Texaco Development Corp | Ore reduction process |
| US3776533A (en) * | 1970-01-28 | 1973-12-04 | Dravo Corp | Apparatus for continuous heat processing of ore pellets |
| DE2743282A1 (de) * | 1977-09-27 | 1979-04-05 | Metallgesellschaft Ag | Waelzverfahren zur verfluechtigung von zink und blei aus eisenoxydhaltigen materialien |
| US4396423A (en) | 1981-06-22 | 1983-08-02 | Stephens Jr Frank M | Process for recovering iron and zinc from steel making dusts |
| DE3536635A1 (de) * | 1985-10-15 | 1987-04-23 | Kloeckner Humboldt Deutz Ag | Verfahren und vorrichtung zur rueckgewinnung, insbesondere von eisen sowie von zink, blei und anderen ne-metallischen bestandteilen aus hocheisenhaltigen oxydischen materialien |
| US4673431A (en) | 1986-01-08 | 1987-06-16 | Bricmont & Associates, Inc. | Furnace dust recovery process |
| US4758268A (en) * | 1986-12-23 | 1988-07-19 | Zia Technology, Inc. | Method and apparatus for reclaiming metal values from electric arc furnace flue dust and sludge and rendering residual solids recyclable or non-hazardous |
| US5013532A (en) | 1988-12-15 | 1991-05-07 | Iit Research Institute | Method for recycling electric arc furnace dust |
| US4963182A (en) | 1989-03-14 | 1990-10-16 | Zia Technology, Inc. | Continuous feed shaft retort process for recovery of non-ferrous metals from process dust |
| US5186742A (en) | 1991-11-27 | 1993-02-16 | Chemical Lime Company | Method and composition for use in recycling metal containing furnace dust |
| US5338336A (en) | 1993-06-30 | 1994-08-16 | Bechtel Group, Inc. | Method of processing electric arc furnace dust and providing fuel for an iron making process |
| US5589118A (en) | 1994-01-21 | 1996-12-31 | Covol Technologies, Inc. | Process for recovering iron from iron-containing material |
| US5538532A (en) | 1995-03-02 | 1996-07-23 | Complete Recovery Process | Methods for recycling electric arc furnace dust |
| AT406485B (de) * | 1995-10-10 | 2000-05-25 | Voest Alpine Ind Anlagen | Verfahren zur herstellung von flüssigem roheisen oder flüssigen stahlvorprodukten und anlage zur durchführung des verfahrens |
| US5685524A (en) * | 1996-01-16 | 1997-11-11 | Chaparral Steel Company | Direct ironmaking or steelmaking apparatus using self-reducing iron oxide pellets |
| US6221124B1 (en) | 1996-05-28 | 2001-04-24 | L & C Steinmuller (Africa) (Proprietary) Limited | Fluidized bed treatment of EAF dust |
| US5885328A (en) | 1996-05-31 | 1999-03-23 | Ltv Steel Company, Inc. | Method of agglomerating oil-containing steel mill waste |
| KR100276324B1 (ko) * | 1996-12-20 | 2000-12-15 | 이구택 | 용융환원 장치 및 이를 이용한 용융선철 제조방법 |
| AU1674700A (en) * | 1998-12-23 | 2000-07-31 | L & C Steinmuller (Africa) (Proprietary) Limited | Eaf dust treatment by pelletising and fluidised-bed reduction |
-
2000
- 2000-02-17 US US09/505,811 patent/US6379421B1/en not_active Expired - Lifetime
- 2000-02-23 EP EP00911185A patent/EP1165845B1/en not_active Expired - Lifetime
- 2000-02-23 AU AU33176/00A patent/AU3317600A/en not_active Abandoned
- 2000-02-23 ES ES200150068A patent/ES2200665B1/es not_active Expired - Fee Related
- 2000-02-23 WO PCT/IB2000/000379 patent/WO2000050649A2/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4473519A (en) * | 1980-02-13 | 1984-09-25 | Estel Hoogovens B.V. | Method of agglomeration of fly ash into pellets |
| US5474592A (en) * | 1993-05-27 | 1995-12-12 | Metallgesellschaft Aktiengesellschaft | Method of reprocessing metallurgical residues, which contain zinc and lead |
| US5667556A (en) * | 1995-05-05 | 1997-09-16 | Metallgesellschaft Aktiengesellschaft | Method of reprocessing zinc- and iron oxide-containing residual material |
| US5865875A (en) * | 1995-08-25 | 1999-02-02 | Maumee Research & Engineering, Inc. | Process for treating metal oxide fines |
Also Published As
| Publication number | Publication date |
|---|---|
| US6379421B1 (en) | 2002-04-30 |
| AU3317600A (en) | 2000-09-14 |
| WO2000050649A2 (en) | 2000-08-31 |
| EP1165845A4 (en) | 2002-06-12 |
| WO2000050649A3 (en) | 2001-02-08 |
| EP1165845A2 (en) | 2002-01-02 |
| ES2200665B1 (es) | 2005-05-01 |
| EP1165845B1 (en) | 2006-02-08 |
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