ES2134725A1 - Procedimiento de tratamiento de pilas electroquimicas secas gastadas de usos domesticos, con recuperacion de elementos componentes. - Google Patents
Procedimiento de tratamiento de pilas electroquimicas secas gastadas de usos domesticos, con recuperacion de elementos componentes.Info
- Publication number
- ES2134725A1 ES2134725A1 ES9701296A ES9701296A ES2134725A1 ES 2134725 A1 ES2134725 A1 ES 2134725A1 ES 9701296 A ES9701296 A ES 9701296A ES 9701296 A ES9701296 A ES 9701296A ES 2134725 A1 ES2134725 A1 ES 2134725A1
- Authority
- ES
- Spain
- Prior art keywords
- recovery
- domestic use
- dry batteries
- processing
- recycled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 4
- 238000011084 recovery Methods 0.000 title abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 3
- 239000011701 zinc Substances 0.000 abstract 3
- 229910052725 zinc Inorganic materials 0.000 abstract 3
- 238000002386 leaching Methods 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 abstract 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Processing Of Solid Wastes (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Procedimiento de tratamiento de pilas electroquímicas secas gastadas de usos domésticos, con recuperación de elementos componentes. La presente invención relata un método para el tratamiento de las pilas electroquímicas secas para usos domésticos, consiguiendo de forma limpia la recuperación de los elementos presentes como zinc, manganeso y otros metales y componentes, que pueden reciclarse o comercializarse de forma ventajosa, logrando con ello solventar no solo un problema medioambiental, sino aportar una buena solución técnica y económica para su resolución. Para ello utiliza dos etapas diferenciadas: un tratamiento mecánico de clasificación y trituración, y un tratamiento hidrometalúrgico de lixiviación ácida, cementación y extracción de zinc con disolventes orgánicos, produciendo una disolución de sulfato de zinc viable de ser alimentada directamente a electrólisis convencional, un líquido ácido que se recicla a lixiviación y unas sales y óxidos de manganeso reciclables al circuito comercial. Este proceso no produce efluentes sino productos y subproductos.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES9701296A ES2134725B1 (es) | 1997-06-13 | 1997-06-13 | Procedimiento de tratamiento de pilas electroquimicas secas gastadas de usos domesticos, con recuperacion de elementos componentes. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES9701296A ES2134725B1 (es) | 1997-06-13 | 1997-06-13 | Procedimiento de tratamiento de pilas electroquimicas secas gastadas de usos domesticos, con recuperacion de elementos componentes. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2134725A1 true ES2134725A1 (es) | 1999-10-01 |
| ES2134725B1 ES2134725B1 (es) | 2000-05-16 |
Family
ID=8299680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES9701296A Expired - Fee Related ES2134725B1 (es) | 1997-06-13 | 1997-06-13 | Procedimiento de tratamiento de pilas electroquimicas secas gastadas de usos domesticos, con recuperacion de elementos componentes. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2134725B1 (es) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1148571A1 (fr) * | 2000-04-17 | 2001-10-24 | Revatech S.A. | Procédé de recyclage et de valorisation de piles salines et alcalines |
| FR2827710A1 (fr) * | 2001-07-23 | 2003-01-24 | Recupyl Sa | Perfectionnement apporte au traitement des piles electriques usagees par voie hydrometallurgique |
| US7507343B2 (en) | 2002-11-28 | 2009-03-24 | Tecnicas Reunidas S.A. | Mixing and settling method and device in solvent extraction processes to recover high-purity products |
| CN105336966A (zh) * | 2015-11-03 | 2016-02-17 | 令狐越 | 废旧干电池的资源化回收利用方法 |
| WO2019150005A1 (en) * | 2018-02-05 | 2019-08-08 | Tracegrow Oy | Processes for production of micronutrients from spent alkaline batteries |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0158627A2 (de) * | 1984-04-10 | 1985-10-16 | VOEST-ALPINE Aktiengesellschaft | Verfahren zur Rückgewinnung von Zink und Mangan aus Zink und Manganoxide enthaltendem Schrott von entladenen Zink-Kohle-Manganoxidbatterien |
| WO1992003856A1 (en) * | 1990-08-23 | 1992-03-05 | Chris Hertelendy | Electrical connector |
| EP0585701A1 (de) * | 1992-09-02 | 1994-03-09 | Enviro Ec Ag | Verfahren zum Entsorgen von Nickel-Cadmium- oder Nickel-Hydrid-Zellen |
-
1997
- 1997-06-13 ES ES9701296A patent/ES2134725B1/es not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0158627A2 (de) * | 1984-04-10 | 1985-10-16 | VOEST-ALPINE Aktiengesellschaft | Verfahren zur Rückgewinnung von Zink und Mangan aus Zink und Manganoxide enthaltendem Schrott von entladenen Zink-Kohle-Manganoxidbatterien |
| WO1992003856A1 (en) * | 1990-08-23 | 1992-03-05 | Chris Hertelendy | Electrical connector |
| EP0585701A1 (de) * | 1992-09-02 | 1994-03-09 | Enviro Ec Ag | Verfahren zum Entsorgen von Nickel-Cadmium- oder Nickel-Hydrid-Zellen |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1148571A1 (fr) * | 2000-04-17 | 2001-10-24 | Revatech S.A. | Procédé de recyclage et de valorisation de piles salines et alcalines |
| BE1013311A4 (fr) * | 2000-04-17 | 2001-11-06 | Revatech S A | Procede de recyclage et de valorisation de piles salines et alcalines |
| FR2827710A1 (fr) * | 2001-07-23 | 2003-01-24 | Recupyl Sa | Perfectionnement apporte au traitement des piles electriques usagees par voie hydrometallurgique |
| WO2003021708A3 (fr) * | 2001-07-23 | 2004-06-17 | Recupyl Sa | Procede de recyclage des piles electriques usagees par traitement hydrometallurgique |
| US7507343B2 (en) | 2002-11-28 | 2009-03-24 | Tecnicas Reunidas S.A. | Mixing and settling method and device in solvent extraction processes to recover high-purity products |
| CN105336966A (zh) * | 2015-11-03 | 2016-02-17 | 令狐越 | 废旧干电池的资源化回收利用方法 |
| WO2019150005A1 (en) * | 2018-02-05 | 2019-08-08 | Tracegrow Oy | Processes for production of micronutrients from spent alkaline batteries |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2134725B1 (es) | 2000-05-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 19991001 Kind code of ref document: A1 Effective date: 19991001 |
|
| FD2A | Announcement of lapse in spain |
Effective date: 20170926 |