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ES2129924T3 - Aparato y proceso para la polimerizacion de olefinas en fase gaseosa. - Google Patents

Aparato y proceso para la polimerizacion de olefinas en fase gaseosa.

Info

Publication number
ES2129924T3
ES2129924T3 ES96300991T ES96300991T ES2129924T3 ES 2129924 T3 ES2129924 T3 ES 2129924T3 ES 96300991 T ES96300991 T ES 96300991T ES 96300991 T ES96300991 T ES 96300991T ES 2129924 T3 ES2129924 T3 ES 2129924T3
Authority
ES
Spain
Prior art keywords
polymer
reactor
degrees
gaseous phase
angle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96300991T
Other languages
English (en)
Inventor
Jean-Claude Chinh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2129924T3 publication Critical patent/ES2129924T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809Controlling processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/02Feed or outlet devices therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00761Discharging
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A UN APARATO PARA LA POLIMERIZACION EN FASE GASEOSA DE OLEFINA(S), QUE ESENCIALMENTE COMPRENDE UN REACTOR DE LECHO FLUIDIZADO Y AL MENOS UN CONDUCTO PARA EXTRAER EL POLIMERO QUE TIENE UNA VALVULA DE SEPARACION Y QUE CONECTA LA PARED LATERAL VERTICAL DEL REACTOR CON UNA TOLVA DE RETENCION, EN DONDE DICHO CONDUCTO SALE DE LA PARED LATERAL VERTICAL DEL REACTOR MIENTRAS ES DIRIGIDO HACIA ABAJO DE MODO QUE CADA PARTE DEL CONDUCTO ANTEDICHO FORME RESPECTO A UN PLANO HORIZONTAL UN ANGULO A QUE VA DE 35 (GRADOS) A 90 (GRADOS) . TAMBIEN SE REFIERE A UN PROCEDIMIENTO DE POLIMERIZACION CONTINUA EN FASE GASEOSA DE OLEFINA(S) EN UN REACTOR DE LECHO FLUIDIFICADO, QUE CONSISTE EN EXTRAER EL POLIMERO DE LA PARED LATERAL VERTICAL DEL REACTOR E INTRODUCIRLO EN UNA TOLVA DE RETENCION A TRAVES DE UN CONDUCTO DE EXTRACCION DE MODO QUE TODO EL FLUJO DEL POLIMERO POR EL CONDUCTO DE EXTRACCION TENGA LUGAR EN UNA DIRECCION DESCENDENTE QUE FORME EN RELACION A UN PLANO HORIZONTAL UNAINCLINACION CON UN ANGULO A AL MENOS IGUAL AL ANGULO DE REPOSO {BE} DEL POLIMERO Y NO SOBREPASE LOS 90 (GRADOS) . CON LA PRESENTE INVENCION SE MEJORA EL GRADO DE LLENADO DE LA TOLVA DE RETENCION Y SE REDUCE LA CANTIDAD DE GAS EXTRAIDO JUNTO CON EL POLIMERO.
ES96300991T 1995-02-24 1996-02-13 Aparato y proceso para la polimerizacion de olefinas en fase gaseosa. Expired - Lifetime ES2129924T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9502446A FR2730999B1 (fr) 1995-02-24 1995-02-24 Appareillage et procede de polymerisation d'olefine en phase gazeuse

Publications (1)

Publication Number Publication Date
ES2129924T3 true ES2129924T3 (es) 1999-06-16

Family

ID=9476671

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96300991T Expired - Lifetime ES2129924T3 (es) 1995-02-24 1996-02-13 Aparato y proceso para la polimerizacion de olefinas en fase gaseosa.

Country Status (30)

Country Link
US (2) US5929180A (es)
EP (1) EP0728771B1 (es)
JP (1) JPH093103A (es)
KR (1) KR100388507B1 (es)
CN (1) CN1095850C (es)
AR (1) AR001028A1 (es)
AT (1) ATE178619T1 (es)
AU (1) AU699640B2 (es)
BG (1) BG62364B1 (es)
BR (1) BR9600800A (es)
CA (1) CA2170098A1 (es)
CZ (1) CZ53496A3 (es)
DE (1) DE69601964T2 (es)
DZ (1) DZ1993A1 (es)
EA (1) EA000007B1 (es)
EG (1) EG21427A (es)
ES (1) ES2129924T3 (es)
FI (1) FI119644B (es)
FR (1) FR2730999B1 (es)
GR (1) GR3029929T3 (es)
HU (1) HU218098B (es)
MY (1) MY113582A (es)
NO (1) NO309148B1 (es)
NZ (1) NZ286043A (es)
PL (1) PL183282B1 (es)
RO (1) RO115168B1 (es)
SK (1) SK281885B6 (es)
TR (1) TR199600123A2 (es)
TW (1) TW408135B (es)
ZA (1) ZA961300B (es)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2731000B1 (fr) * 1995-02-24 1997-04-18 Bp Chemicals Snc Procede de polymerisation d'olefine en phase gazeuse
FR2752533B1 (fr) * 1996-08-23 1998-09-18 Bp Chemicals Snc Appareillage et procede de polymerisation d'olefine en phase gazeuse
JP3710247B2 (ja) * 1997-04-10 2005-10-26 三井化学株式会社 気相重合装置
FR2764207B1 (fr) * 1997-06-10 1999-07-16 Bp Chemicals Snc Reacteur pour la polymerisation des olefines en phase gazeuse
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
DE19744708A1 (de) 1997-10-10 1999-04-15 Bayer Ag Verfahren und Vorrichtung zum Ausschleusen von Kautschuk aus der Gasphasenpolymerisation
EP1522553B1 (en) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
EP0976445A1 (en) * 1998-07-31 2000-02-02 Bp Chemicals S.N.C. Process for introducing a solid catalyst into a fluidised or agitated vessel
FR2791983B1 (fr) * 1999-04-12 2001-05-18 Bp Chemicals Snc Appareil et procede de polymerisation en phase gazeuse d'olefine
SG82693A1 (en) * 1999-09-03 2001-08-21 Sumitomo Chemical Co Fluidized bed reactor for gas phase olefin polymerization, process for polymerizing olefin and process for producing olefin polymer
GB0026242D0 (en) * 2000-10-26 2000-12-13 Bp Chem Int Ltd Apparatus and process
ATE485319T1 (de) 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
EP1444276A1 (en) 2001-11-06 2004-08-11 Dow Global Technologies, Inc. Isotactic propylene copolymers, their preparation and use
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
WO2003057658A1 (en) * 2002-01-08 2003-07-17 Mitsubishi Chemical Corporation Method of preventing clogging of apparatus for handling (meth)acrylic acid and ester thereof
US6914104B2 (en) * 2002-04-19 2005-07-05 Sumitomo Chemical Company, Limited Process for polymerization of α-olefin
US7459500B2 (en) 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7579407B2 (en) 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
SG119367A1 (en) * 2004-07-16 2006-02-28 Sumitomo Chemical Co Apparatus for continuous polymerization of olefin method for transferring a polymer powder and method for continuous polymerization of olefin
JP4760173B2 (ja) * 2004-07-16 2011-08-31 住友化学株式会社 オレフィン連続重合装置、ポリマー粉粒体の移送方法、およびオレフィン重合方法
US7807761B2 (en) * 2005-01-26 2010-10-05 Ineos Europe Limited Apparatus and process for the withdrawal of polymer from a gas-phase polymerization reactor
CN101238295B (zh) * 2005-08-05 2011-04-13 埃克森美孚化学专利公司 压缩机,用于制造聚乙烯物的生产装置及其方法
JP5055816B2 (ja) * 2006-04-17 2012-10-24 住友化学株式会社 ポリオレフィンパウダーの移送装置及び方法
US8129486B2 (en) * 2006-10-10 2012-03-06 Univation Technologies, Llc Discharge systems and methods of using the same
MY162143A (en) * 2006-10-10 2017-05-31 Univation Tech Llc Discharge system to remove solids from a vessel
WO2008095807A1 (en) * 2007-02-05 2008-08-14 Basell Poliolefine Italia S.R.L. Apparatus for the liquid-phase polymerization of olefins
JP5420864B2 (ja) * 2008-08-01 2014-02-19 住友化学株式会社 気相重合装置およびオレフィンの重合方法
US9376517B2 (en) 2011-12-28 2016-06-28 Ineos Europe Ag Polymerisation process
KR101462466B1 (ko) 2013-03-07 2014-11-17 대림산업 주식회사 올레핀의 중합 방법
JP6902965B2 (ja) * 2017-08-29 2021-07-14 住友化学株式会社 ポリオレフィンの製造方法
CN108283917A (zh) * 2018-04-08 2018-07-17 合润科技有限公司 一种用于生产聚α烯烃用的聚合反应釜
WO2021081039A1 (en) * 2019-10-25 2021-04-29 Exxonmobil Chemical Patents Inc. Fluidized bed reactor systems
JP2024007084A (ja) * 2022-07-05 2024-01-18 住友化学株式会社 ポリオレフィン製造装置及び製造方法
US20240173660A1 (en) * 2022-11-29 2024-05-30 Chevron Phillips Chemical Company Lp Systems and techniques for polymer product withdrawal

Family Cites Families (8)

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Publication number Priority date Publication date Assignee Title
US3785966A (en) * 1971-04-08 1974-01-15 Agency Ind Science Techn Method for discharging particulate solid from high pressure vessel
US3994824A (en) * 1974-01-10 1976-11-30 Aerojet-General Corporation Dynamic air flow system for removing particulate bed material from a fluidized particulate bed reactor
US4039507A (en) * 1975-09-05 1977-08-02 The Dow Chemical Company Incorporation of finely divided functional solids into olefin
MX156534A (es) * 1979-12-31 1988-09-08 Exxon Research Engineering Co Sistema continuo mejorado de descarga de catalizador
US4399055A (en) * 1981-05-01 1983-08-16 Mitsubishi Petrochemical Company Limited Carrier of catalyst and catalyst component composed of the carrier, for polymerization of olefins, as well as processes for production thereof
US4425206A (en) * 1982-12-09 1984-01-10 The Dow Chemical Company Anhydrous process for preparing amorphous chlorinated polyethylene and product thereof
FR2599991B1 (fr) * 1986-06-16 1993-04-02 Bp Chimie Sa Evacuation de produits presents dans un reacteur de polymerisation d'alpha-olefines en lit fluidise
FR2731000B1 (fr) * 1995-02-24 1997-04-18 Bp Chemicals Snc Procede de polymerisation d'olefine en phase gazeuse

Also Published As

Publication number Publication date
PL183282B1 (pl) 2002-06-28
FR2730999B1 (fr) 1997-04-18
TR199600123A2 (tr) 1996-10-21
BG100382A (bg) 1996-11-29
US5928612A (en) 1999-07-27
NZ286043A (en) 1997-07-27
CN1137534A (zh) 1996-12-11
NO309148B1 (no) 2000-12-18
BR9600800A (pt) 1997-12-23
RO115168B1 (ro) 1999-11-30
AU699640B2 (en) 1998-12-10
AR001028A1 (es) 1997-08-27
EA000007B1 (ru) 1997-12-30
PL312897A1 (en) 1996-09-02
FI960853A7 (fi) 1996-08-25
CZ53496A3 (en) 1996-09-11
SK23096A3 (en) 1997-03-05
NO960737D0 (no) 1996-02-23
DZ1993A1 (fr) 2002-10-15
CN1095850C (zh) 2002-12-11
EA199600006A3 (ru) 1996-10-01
MY113582A (en) 2002-04-30
US5929180A (en) 1999-07-27
BG62364B1 (bg) 1999-09-30
SK281885B6 (sk) 2001-08-06
FI960853A0 (fi) 1996-02-23
CA2170098A1 (en) 1996-08-25
HK1011373A1 (en) 1999-07-09
FI119644B (fi) 2009-01-30
DE69601964T2 (de) 1999-08-12
TW408135B (en) 2000-10-11
KR960031491A (ko) 1996-09-17
AU4448496A (en) 1996-09-05
FR2730999A1 (fr) 1996-08-30
HU9600436D0 (en) 1996-04-29
TR199600123A3 (es) 1996-10-21
EP0728771B1 (en) 1999-04-07
HU218098B (hu) 2000-05-28
DE69601964D1 (de) 1999-05-12
ATE178619T1 (de) 1999-04-15
NO960737L (no) 1996-08-26
GR3029929T3 (en) 1999-07-30
HUP9600436A3 (en) 1997-11-28
EG21427A (en) 2001-10-31
EP0728771A1 (en) 1996-08-28
ZA961300B (en) 1997-08-19
HUP9600436A2 (en) 1997-04-28
EA199600006A2 (ru) 1996-07-01
KR100388507B1 (ko) 2003-09-13
JPH093103A (ja) 1997-01-07

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