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ES2190695A1 - Proceso y aparato para permitir la gasificacion autotermica de combustibles solidos. - Google Patents

Proceso y aparato para permitir la gasificacion autotermica de combustibles solidos.

Info

Publication number
ES2190695A1
ES2190695A1 ES200001339A ES200001339A ES2190695A1 ES 2190695 A1 ES2190695 A1 ES 2190695A1 ES 200001339 A ES200001339 A ES 200001339A ES 200001339 A ES200001339 A ES 200001339A ES 2190695 A1 ES2190695 A1 ES 2190695A1
Authority
ES
Spain
Prior art keywords
gas
gasification
produced
flow
gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200001339A
Other languages
English (en)
Other versions
ES2190695B1 (es
Inventor
Den Oosterkamp Paul Van
Helmut Kubiak
Hans-Jurgen Muhlen
Klaus Knop
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ferrostaal AG
DMT GmbH and Co KG
TEn Netherlands BV
Original Assignee
Ferrostaal AG
DMT GmbH and Co KG
Technip Benelux BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ferrostaal AG, DMT GmbH and Co KG, Technip Benelux BV filed Critical Ferrostaal AG
Publication of ES2190695A1 publication Critical patent/ES2190695A1/es
Application granted granted Critical
Publication of ES2190695B1 publication Critical patent/ES2190695B1/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
    • C10B49/10—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/04—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of powdered coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/78—High-pressure apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/80—Other features with arrangements for preheating the blast or the water vapour
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0909—Drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1838—Autothermal gasification by injection of oxygen or steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1869—Heat exchange between at least two process streams with one stream being air, oxygen or ozone
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/12—Heat utilisation in combustion or incineration of waste
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Industrial Gases (AREA)
  • Processing Of Solid Wastes (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Proceso y aparato para permitir la gasificación autotérmica de combustibles sólidos. El invento se refiere a un procedimiento de gasificación autotérmica de combustibles sólidos. Este procedimiento se efectúa bajo exceso de presión con un gas que contiene O2, donde los combustibles se someten a un pretratamiento térmico por contacto directo con un flujo de gas de humo caliente con separación del gas y de los vapores y formación de un producto intermedio frágil y donde este flujo se produce en una combustión en presencia de los gases y vapores de pretratamiento, donde el producto intermedio se somete, finamente dividido, a la gasificación formando un gas de síntesis rico en H2 y CO. El combustible se utiliza en forma finamente dividida, el pretratamiento se efectúa como pirólisis a una temperatura final de por lo menos 450°C, la gasificación tiene lugar en presencia de vapor de agua y se suprime del flujo de gas de humo caliente, antes de su introducción en el pretratamiento térmico, del calor para producir la mezcla de vapor y gas conteniendo O2 requerido para la gasificación. El invento se aplica principalmente en el campo de los gases de síntesis.
ES200001339A 1999-05-27 2000-05-26 Proceso y aparato para permitir la gasificacion autotermica de combustibles solidos. Expired - Lifetime ES2190695B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19925316A DE19925316A1 (de) 1999-05-27 1999-05-27 Verfahren und Anlage zur autothermen Vergasung von festen Brennstoffen
DE19925316 1999-05-27

Publications (2)

Publication Number Publication Date
ES2190695A1 true ES2190695A1 (es) 2003-08-01
ES2190695B1 ES2190695B1 (es) 2004-11-16

Family

ID=7910045

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200001339A Expired - Lifetime ES2190695B1 (es) 1999-05-27 2000-05-26 Proceso y aparato para permitir la gasificacion autotermica de combustibles solidos.

Country Status (6)

Country Link
AU (1) AU3645700A (es)
DE (1) DE19925316A1 (es)
ES (1) ES2190695B1 (es)
FR (1) FR2794128A1 (es)
GB (1) GB2350370A (es)
ZA (1) ZA200002647B (es)

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CN1358221A (zh) * 2000-01-14 2002-07-10 冈本良一 废物的干馏减容装置
AU2002950780A0 (en) * 2002-08-12 2002-09-12 Pacific Edge Holdings Pty. Ltd. Process for gasification of low rank carbonaceous material
CN1657149B (zh) * 2004-02-16 2011-02-16 中国石化集团上海工程有限公司 卧式急冷液冷却流化床反应器
DE102004019203B3 (de) * 2004-04-16 2005-12-22 Forschungszentrum Karlsruhe Gmbh Verfahren zur Vergasung von lagerstabiler Biomasse zu Synthesegas
DE102006049781A1 (de) * 2006-10-21 2008-04-24 Andrzej Sakowicz Verfahren und Vorrichtung zur Vergasung von organischen Stoffen mit Hilfe von Luft
DE102006052345B4 (de) * 2006-11-07 2009-04-23 Herlt, Christian, Dipl.-Ing. Verfahren und Vorrichtung zur Verminderung der Feinstaubbildung bei der thermischen Vergasung von halmartiger und stückiger Biomasse in Form von Ballen
RU2333929C1 (ru) * 2007-02-26 2008-09-20 Институт химии и химической технологии СО РАН (ИХХТ СО РАН) Способ и установка для газификации твердого топлива
DE112008003917A5 (de) * 2008-04-22 2011-03-31 Herlt, Christian, Dipl.-Ing. Verfahren und Vorrichtung zur Verminderung des Feinstaubes im Abgas bei der thermischen Vergasung von halmförmiger oder stückiger Biomasse
CN101418238B (zh) * 2008-12-01 2012-02-29 武汉凯迪工程技术研究总院有限公司 利用生物质制造合成气的高温气化工艺方法及系统
CN102585913B (zh) * 2012-03-12 2013-11-06 浙江大学 基于流化床热解技术的煤气焦油半焦蒸汽多联产方法
CN103160300B (zh) * 2013-03-07 2014-05-07 华中科技大学 一种褐煤改性提质系统
CN103194265B (zh) * 2013-04-10 2014-12-24 山西鑫立能源科技有限公司 热循环连续煤矸石热解气化综合方法
CN103409164B (zh) * 2013-08-10 2014-12-24 山西鑫立能源科技有限公司 连续外热式水煤气气化方法
CN103450943B (zh) * 2013-08-10 2015-10-21 山西鑫立能源科技有限公司 外热式水煤气气化方法
CN104017594B (zh) * 2014-06-20 2015-12-02 中煤能源黑龙江煤化工有限公司 煤低温干馏方法
CN105482839A (zh) * 2015-12-30 2016-04-13 北京神雾环境能源科技集团股份有限公司 煤热解反应器-循环流化床锅炉联用系统及其应用
CN106753579B (zh) * 2016-12-26 2019-07-23 东北大学 一种固体热载体煤气化电力蓄能系统和方法
CN108384583B (zh) * 2018-03-14 2024-04-02 深圳市水务(集团)有限公司 一种固体废物热解气净化与利用系统
CN110066692A (zh) * 2019-03-22 2019-07-30 张英华 煤炭制氢气设备及控制方法
CN110129100B (zh) * 2019-05-28 2023-12-22 彭万旺 高效燃烧系统及方法
IT201900012822A1 (it) * 2019-07-24 2019-10-24 Paolo Pejrani Dispositivo e procedimento per la valorizzazione dei materiali di scarto normalizzati contenenti frazioni organiche
CN110607181A (zh) * 2019-10-24 2019-12-24 上海齐耀热能工程有限公司 一种加压直接加热裂解制备轻质烃类的设备及方法
CN111100659A (zh) * 2019-12-23 2020-05-05 江西理工大学 耦合式粉煤气热化解反应器及使用工艺

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DE905526C (de) * 1948-12-21 1954-03-04 Heinrich Ottomar Gruber Verfahren zur stetigen schlackenfreien Vergasung von Koks
FR2465778A1 (fr) * 1979-09-18 1981-03-27 G Energet In Procede perfectionne de transformation thermique d'un combustible solide broye

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Also Published As

Publication number Publication date
DE19925316A1 (de) 2000-11-30
GB0012957D0 (en) 2000-07-19
GB2350370A (en) 2000-11-29
ES2190695B1 (es) 2004-11-16
FR2794128A1 (fr) 2000-12-01
AU3645700A (en) 2000-11-30
ZA200002647B (en) 2000-12-11

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