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ES2184088T3 - PROCEDURE FOR THE PREPARATION OF GAMMA-BUTIROLACTONE, BUTANE-1,4-DIOL AND TETRAHYDROFURAN. - Google Patents

PROCEDURE FOR THE PREPARATION OF GAMMA-BUTIROLACTONE, BUTANE-1,4-DIOL AND TETRAHYDROFURAN.

Info

Publication number
ES2184088T3
ES2184088T3 ES97921941T ES97921941T ES2184088T3 ES 2184088 T3 ES2184088 T3 ES 2184088T3 ES 97921941 T ES97921941 T ES 97921941T ES 97921941 T ES97921941 T ES 97921941T ES 2184088 T3 ES2184088 T3 ES 2184088T3
Authority
ES
Spain
Prior art keywords
phase
maleic anhydride
hydrogenation
current
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97921941T
Other languages
Spanish (es)
Inventor
Michael William Marshall Tuck
Michael Anthony Wood
Andrew George Hiles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2184088T3 publication Critical patent/ES2184088T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D307/08—Preparation of tetrahydrofuran

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION DESCRIBE UN PROCEDIMIENTO DE PRODUCCION DE AL MENOS UN COMPUESTO C 4 SELECCIONADO A PARTIR DE BUTANO 1,4 - DIOL, GA - BUTIROLACTONA Y TETRAHIDROFURANO, EL CUAL IN CLUYE UNA FASE DE HIDROGENACION EN FASE GASEOSA DE ANHIDRIDO MALEICO, EN PRESENCIA DE UN CATALIZADOR DE HIDROGENACION HETEROGENEO. DICHO PROCEDIMIENTO COMPRENDE: (A) PONER EN CONTACTO UNA CORRIENTE EN FASE DE VAPOR QUE CONTIENE ANHIDRIDO MALEICO EN FASE DE VAPOR, VAPOR DE AGUA Y OXIDOS DE CARBONO, EN UNA ZONA DE ABSORCION CON UN DISOLVENTE ORGANICO DE ELEVADO PUNTO DE EBULLICION, EL CUAL, A PRESION ATMOSFERICA, ES APROX. 30 °C SUPERIOR AL DEL ANHIDRIDO MALEICO, PARA FORMAR ASI UNA SOLUCION DE ANHIDRIDO MALEICO EN DICHO DISOLVENTE ORGANICO DE ELEVADO PUNTO DE EBULLICION; (B) UNA CORRIENTE GASEOSA QUE CONTIENE HIDROGENO, EXTRAYENDO ASI ANHIDRIDO MALEICO DE LA MISMA Y FORMANDO UNA CORRIENTE GASEOSA QUE COMPRENDE HIDROGENO Y ANHIDRIDO MALEICO; (D) PONER EN CONTACTO MATERIAL DE LA CORRIENTE EN FASE DE VAPOR DE LA FASE (E),EN UNA ZONA DE HIDROGENACION, BAJO CONDICIONES DE HIDROGENACION, EN PRESENCIA DE UN CATALIZADOR DE HIDROGENACION HETEROGENEO, PARA CONVERTIR ASI ANHIDRIDO MALEICO EN AL MENOS UN COMPUESTO C 4 , SELECCIONADO A PARTIR DE BUTANO - 1,4 - DIOL, GA BUTIROLACTONA Y TETRAHIDROFURANO; Y (E) RECUPERAR A PARTIR DE LA ZONA DE HIDROGENACION UNA CORRIENTE DE PRODUCTO QUE CONTIENE DICHO COMPUESTO C 4 .THE INVENTION DESCRIBES A PRODUCTION PROCEDURE OF AT LEAST A SELECTED C 4 COMPOUND FROM BUTANE 1,4 - DIOL, GA - BUTIROLACTONE AND TETRAHYDROFURAN, WHICH INCLUDES A GASEOUS PHASE HYDROGENATION PHASE OF A MALEIC PRESIDENT, HETEROGENEO HYDROGENATION CATALYST. SUCH PROCEDURE INCLUDES: (A) TO CONTACT A CURRENT IN THE STEAM PHASE CONTAINING MALEIC ANHYDRIDE IN THE STEAM PHASE, WATER STEAM AND CARBON OXIDES, IN AN ABSORPTION AREA WITH AN ORGANIC SOLVENT OF PUNCHED THE PUNCH , AT ATMOSPHERIC PRESSURE, IT'S APPROX. 30 ° C HIGHER THAN THE MALEIC ANHYDRIDE, TO FORM A MALEIC ANHYDRIDE SOLUTION IN THE ORGANIC SOLVENT OF ELEVATED POINTS OF EBULLITION; (B) A GASEOUS CURRENT CONTAINING HYDROGEN, REMOVING AND MALEIC ANHYDRIDE OF THE SAME AND FORMING A GASEOUS CURRENT THAT INCLUDES HYDROGEN AND MALEIC ANHYDRIDE; (D) PLACING MATERIAL CONTACT OF THE CURRENT IN THE VAPOR PHASE OF THE PHASE (E), IN A HYDROGENATION AREA, UNDER HYDROGENATION CONDITIONS, IN THE PRESENCE OF A HYDROGENOUS HYDROGENATION CATALYST, TO CONVERT A MALE HYDROGEN HYDROGEN COMPOUND C 4, SELECTED FROM BUTANE - 1,4 - DIOL, GA BUTIROLACTONE AND TETRAHYDROFURAN; AND (E) RECOVER FROM THE HYDROGENATION AREA A PRODUCT CURRENT CONTAINING SUCH COMPOUND C 4.

ES97921941T 1996-05-15 1997-05-12 PROCEDURE FOR THE PREPARATION OF GAMMA-BUTIROLACTONE, BUTANE-1,4-DIOL AND TETRAHYDROFURAN. Expired - Lifetime ES2184088T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96303428 1996-05-15

Publications (1)

Publication Number Publication Date
ES2184088T3 true ES2184088T3 (en) 2003-04-01

Family

ID=8224940

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97921941T Expired - Lifetime ES2184088T3 (en) 1996-05-15 1997-05-12 PROCEDURE FOR THE PREPARATION OF GAMMA-BUTIROLACTONE, BUTANE-1,4-DIOL AND TETRAHYDROFURAN.

Country Status (17)

Country Link
US (1) US6077964A (en)
EP (1) EP0922022B1 (en)
JP (1) JP4021490B2 (en)
KR (1) KR100464610B1 (en)
CN (1) CN1089743C (en)
AR (1) AR007126A1 (en)
AU (1) AU707824B2 (en)
BR (1) BR9709250A (en)
CA (1) CA2255912C (en)
DE (1) DE69715640T2 (en)
ES (1) ES2184088T3 (en)
MX (1) MX204063B (en)
NO (1) NO311932B1 (en)
SA (1) SA97180160B1 (en)
TW (1) TW413673B (en)
WO (1) WO1997043234A1 (en)
ZA (1) ZA973971B (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9724195D0 (en) * 1997-11-14 1998-01-14 Kvaerner Process Tech Ltd Process
BE1011699A6 (en) * 1998-01-08 1999-12-07 Pantochim Sa Method for producing and gamma-tetrahydrofuran butyrolactone.
DE19806038A1 (en) * 1998-02-13 1999-08-19 Basf Ag Process for the separation of maleic anhydride from mixtures containing maleic anhydride by stripping
DE69800886T2 (en) * 1998-03-23 2001-10-11 Basf Ag Process for the preparation of 1,4-butanediol, butyrolactone and tetrahydrofuran
BE1012274A7 (en) 1998-11-10 2000-08-01 Pantochim Sa High productivity process for the preparation of gamma and tetrahydrofuran butyrolactone.
US6235930B1 (en) * 1999-03-31 2001-05-22 Board Of Trustees Operating Michigan State University Process for the preparation of 3,4-dihydroxybutanoic acid and derivatives thereof from substituted pentose sugars
MY139259A (en) * 1999-10-12 2009-09-30 Kvaerner Process Tech Ltd Process
DE10021703A1 (en) 2000-05-04 2001-11-08 Basf Ag Continuous separation of mixtures containing tetrahydrofuran, gamma-butyrolactone and/or 1,4-butanediol, e.g. from maleic anhydride hydrogenation, uses partitioned or heat-coupled conventional distillation columns
GB0117090D0 (en) 2001-07-12 2001-09-05 Kvaerner Process Tech Ltd Process
DE10137534A1 (en) 2001-08-01 2003-02-13 Basf Ag Maleic anhydride production useful as an intermediate in the production of e.g. gamma-butyrolactone, comprises the heterogeneous catalyzed gas phase oxidation of n-butene
DE10219224A1 (en) * 2002-04-30 2003-11-13 Basf Ag Process for the production of gamma-butyrolactone
DE10225929A1 (en) * 2002-06-11 2003-12-24 Basf Ag Two-stage process for the production of butanediol with intermediate separation of succinic anhydride
DE10225928A1 (en) * 2002-06-11 2003-12-24 Basf Ag Two-stage process for the production of butanediol in two reactors
DE10225927A1 (en) 2002-06-11 2003-12-24 Basf Ag Process for the production of butanediol by combined gas phase and liquid phase synthesis
DE10225926A1 (en) 2002-06-11 2003-12-24 Basf Ag Process for the production of butanediol
GB0325530D0 (en) 2003-10-31 2003-12-03 Davy Process Techn Ltd Process
GB0325526D0 (en) 2003-10-31 2003-12-03 Davy Process Techn Ltd Process
DE10357715A1 (en) * 2003-12-09 2005-07-14 Basf Ag Process for the preparation of defined mixtures of THF, BDO and GBL by gas phase hydrogenation
GB0421928D0 (en) 2004-10-01 2004-11-03 Davy Process Techn Ltd Process
DE102005031314A1 (en) * 2005-07-05 2007-01-18 Basf Ag Process for the separation of maleic anhydride from mixtures containing maleic anhydride by stripping
KR100922998B1 (en) * 2008-03-06 2009-10-22 한국화학연구원 Process for preparing monohydric alcohol from monocarboxylic acid or derivatives thereof
KR200458108Y1 (en) * 2009-01-14 2012-01-20 제이씨코리아 주식회사 Nail ornaments
GB0906031D0 (en) * 2009-04-07 2009-05-20 Davy Process Techn Ltd Process
WO2016008904A1 (en) 2014-07-16 2016-01-21 Basf Se METHOD FOR PURIFYING RAW γ-BUTYROLACTONE
CN107245026A (en) * 2017-06-22 2017-10-13 江苏飞翔化工股份有限公司 The solvent-free method that glycol is prepared by lactone
CN116768700A (en) * 2023-05-15 2023-09-19 浙江环化科技有限公司 Method for preparing 1, 4-butanediol by maleic anhydride hydrogenation

Family Cites Families (26)

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DE264533C (en) *
US2638481A (en) * 1950-05-26 1953-05-12 Hercules Powder Co Ltd Maleic acid manufacture
GB727828A (en) * 1952-12-09 1955-04-06 Chempatents Inc Recovery of polycarboxylic acid anhydrides
GB763339A (en) * 1953-03-23 1956-12-12 Chempatents Inc Improvements in recovery of maleic and phthalic acid anhydrides
FR1089012A (en) * 1953-10-08 1955-03-14 Chempatents Process for recovering polycarboxylic acid anhydrides from dilute gas mixtures
NL98195C (en) * 1955-04-20
US2893924A (en) * 1956-04-17 1959-07-07 Saint Gobain Separation and purification of anhydrides of organic diacids
US3040059A (en) * 1959-07-02 1962-06-19 Foster Wheeler Corp Recovery of the anhydrides of polycarboxylic acids
BE792879A (en) * 1971-12-17 1973-03-30 Chevron Res MALEIC ANHYDRIDE ISOLATION PROCESS
US3891680A (en) * 1972-11-29 1975-06-24 Chevron Res Maleic anhydride recovery using nonaqueous medium
US3850758A (en) * 1973-07-02 1974-11-26 Allied Chem Purification of crude maleic anhydride by treatment with dimethylbenzophenone
DE2444824A1 (en) * 1974-09-19 1976-04-08 Basf Ag PROCESS FOR THE OBTAINMENT OF MALEIC ACID ANHYDRIDE
US4071540A (en) * 1976-07-08 1978-01-31 Chevron Research Company Anhydride separation process
DE2642533C2 (en) * 1976-09-22 1985-08-22 Basf Ag, 6700 Ludwigshafen Process for the production of gamma-butyrolactone from maleic anhydride
US4118403A (en) * 1976-11-18 1978-10-03 Monsanto Company Recovery of maleic anhydride
GB8331793D0 (en) * 1983-11-29 1984-01-04 Davy Mckee Ltd Process
EP0204730A1 (en) * 1984-11-21 1986-12-17 DAVY McKEE (LONDON) LIMITED Process for the production of butane-1,4-diol
GB8618890D0 (en) * 1986-08-01 1986-09-10 Davy Mckee Ltd Process
JPH01500753A (en) * 1986-08-01 1989-03-16 デイヴィ　マッキー　（ロンドン）　リミテッド Method for simultaneous production of butane-1,4-diol and gamma-butyrolactone
GB8717992D0 (en) * 1987-07-29 1987-09-03 Davy Mckee Ltd Process
GB8717993D0 (en) * 1987-07-29 1987-09-03 Davy Mckee Ltd Process
JP2596604B2 (en) * 1988-12-14 1997-04-02 東燃株式会社 Method for producing 1,4-butanediol and tetrahydrofuran
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
GB8917859D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
GB8917864D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
US5347021A (en) * 1990-04-16 1994-09-13 Isp Investments Inc. Process of vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone in high conversion and high selectivity using an activated catalyst

Also Published As

Publication number Publication date
CA2255912A1 (en) 1997-11-20
DE69715640D1 (en) 2002-10-24
KR100464610B1 (en) 2005-05-19
EP0922022B1 (en) 2002-09-18
JP4021490B2 (en) 2007-12-12
MX204063B (en) 2001-09-03
CN1218450A (en) 1999-06-02
TW413673B (en) 2000-12-01
AU2782097A (en) 1997-12-05
KR20000011015A (en) 2000-02-25
CN1089743C (en) 2002-08-28
WO1997043234A1 (en) 1997-11-20
DE69715640T2 (en) 2003-02-06
AU707824B2 (en) 1999-07-22
CA2255912C (en) 2006-10-10
NO985291D0 (en) 1998-11-13
NO311932B1 (en) 2002-02-18
EP0922022A1 (en) 1999-06-16
SA97180160B1 (en) 2006-09-05
JP2000510475A (en) 2000-08-15
MX9809480A (en) 1999-03-31
AR007126A1 (en) 1999-10-13
BR9709250A (en) 2000-05-09
US6077964A (en) 2000-06-20
NO985291L (en) 1998-11-13
ZA973971B (en) 1998-03-23

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