ES2183536T3 - Desacidificacion de materiales basados en celulosa usando vehiculos de hidrofluoroeter. - Google Patents
Desacidificacion de materiales basados en celulosa usando vehiculos de hidrofluoroeter.Info
- Publication number
- ES2183536T3 ES2183536T3 ES99914148T ES99914148T ES2183536T3 ES 2183536 T3 ES2183536 T3 ES 2183536T3 ES 99914148 T ES99914148 T ES 99914148T ES 99914148 T ES99914148 T ES 99914148T ES 2183536 T3 ES2183536 T3 ES 2183536T3
- Authority
- ES
- Spain
- Prior art keywords
- materials
- cellulose
- hydrofluoroeter
- deacdification
- vehicles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title abstract 4
- 229910001038 basic metal oxide Inorganic materials 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/0092—Post-treated paper
- D21H5/0097—Post-treated paper with means restoring or reinforcing the paper-structure
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/18—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00 of old paper as in books, documents, e.g. restoring
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/11—Halides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/64—Alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
Landscapes
- Paper (AREA)
- Epoxy Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Un método para desacidificar materiales basados en celulosa que incluye tratar dicho material con partículas alcalinas de óxidos, hidróxidos y/o sales, metálicos básicos, dispersas en un medio inerte compuesto de un vehículo líquido y un tensioactivo en una cantidad y durante un periodo de tiempo suficiente para que las partículas entren en los intersticios de los materiales basados en celulosa y aumenten su pH, caracterizado porque el vehículo consta de un hidrofluoroéter.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/054,690 US6080448A (en) | 1998-04-03 | 1998-04-03 | Deacidification of cellulose based materials using hydrofluoroether carriers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2183536T3 true ES2183536T3 (es) | 2003-03-16 |
Family
ID=21992867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99914148T Expired - Lifetime ES2183536T3 (es) | 1998-04-03 | 1999-03-25 | Desacidificacion de materiales basados en celulosa usando vehiculos de hidrofluoroeter. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6080448A (es) |
| EP (1) | EP1068395B1 (es) |
| JP (1) | JP4537578B2 (es) |
| KR (1) | KR100640118B1 (es) |
| AT (1) | ATE223535T1 (es) |
| AU (1) | AU743868B2 (es) |
| CA (1) | CA2326998C (es) |
| DE (1) | DE69902768T2 (es) |
| ES (1) | ES2183536T3 (es) |
| PT (1) | PT1068395E (es) |
| WO (1) | WO1999051819A1 (es) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU1478599A (en) * | 1998-04-07 | 1999-10-25 | Sm Schweizerische Munitionsunternehmung Ag | Active substance and device for the deacidification of printed matter |
| EP1001084A3 (de) * | 1998-11-16 | 2002-01-16 | ZFB Zentrum für Bucherhaltung GmbH | Entsäuerungsmittel |
| KR20010070082A (ko) * | 2000-01-10 | 2001-07-25 | 이인수 | 규소계 운반체를 이용한 각종 인쇄물의 장기 보관을 위한처리제 |
| AU2002350199A1 (en) * | 2001-11-16 | 2003-06-10 | Honeywell International Inc. | Method of deacidifying cellulose-based materials |
| EP1468143A1 (en) * | 2002-01-15 | 2004-10-20 | Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase, C.S.G.I | Basic suspension, its preparation and process for paper deacidification |
| US6890455B2 (en) * | 2003-01-25 | 2005-05-10 | The Sherwin-Williams Company | Archival spray composition |
| US7691282B2 (en) * | 2005-09-08 | 2010-04-06 | 3M Innovative Properties Company | Hydrofluoroether compounds and processes for their preparation and use |
| US7790312B2 (en) * | 2005-09-08 | 2010-09-07 | 3M Innovative Properties Company | Electrolyte composition |
| US7385089B2 (en) * | 2005-12-23 | 2008-06-10 | 3M Innovative Properties Company | Fluorochemical ketone compounds and processes for their use |
| US8791254B2 (en) * | 2006-05-19 | 2014-07-29 | 3M Innovative Properties Company | Cyclic hydrofluoroether compounds and processes for their preparation and use |
| US8193397B2 (en) * | 2006-12-06 | 2012-06-05 | 3M Innovative Properties Company | Hydrofluoroether compounds and processes for their preparation and use |
| US8071816B2 (en) * | 2008-06-30 | 2011-12-06 | 3M Innovative Properties Company | Hydrofluoroacetal compounds and processes for their preparation and use |
| US7988877B2 (en) * | 2008-11-03 | 2011-08-02 | 3M Innovative Properties Company | Methods of making fluorinated ethers, fluorinated ethers, and uses thereof |
| WO2012118602A1 (en) | 2011-03-03 | 2012-09-07 | 3M Innovative Properties Company | Lubricant compositions containing fluorooxiranes |
| CN103596915B (zh) | 2011-06-10 | 2016-08-24 | 3M创新有限公司 | 部分氟化酮及其制备和使用方法 |
| US20130158250A1 (en) * | 2011-12-16 | 2013-06-20 | Honeywell International, Inc. | Method of deacidifying cellulose based materials |
| EP3024810B1 (en) | 2013-07-25 | 2018-06-20 | 3M Innovative Properties Company | Nitrogen containing hydrofluoroethers and methods of making same |
| ITUA20161894A1 (it) * | 2016-03-22 | 2017-09-22 | Univ Degli Studi Di Palermo | Composizione per la deacidificazione e la riduzione della carta e relativo metodo per il restauro della carta |
| CN107012736B (zh) * | 2017-05-03 | 2018-12-18 | 清华大学 | 一种兼具纸张增强作用的脱酸液及其制备方法 |
| KR102233825B1 (ko) * | 2020-09-02 | 2021-03-30 | (주)흥인 | 셀룰로오스 기재용 장기 보존제 |
| CN115787350B (zh) * | 2022-11-04 | 2024-05-31 | 国家图书馆 | 一种纸张含氟脱酸液 |
| CN117306309B (zh) * | 2023-09-07 | 2025-05-06 | 中山大学 | 一种用于整册古籍浸泡脱酸的脱酸液及其制备方法和应用 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA911110A (en) * | 1972-10-03 | D. Smith Richard | Treatment of cellulosic materials | |
| US2864723A (en) * | 1956-08-23 | 1958-12-16 | American Cyanamid Co | Acid resistant cellulosic material and process for producing same |
| GB1129648A (en) * | 1965-08-27 | 1968-10-09 | William Herbert Langwell | Prevention of deterioration of documents, books, maps and like records |
| US3665041A (en) * | 1967-04-04 | 1972-05-23 | Montedison Spa | Perfluorinated polyethers and process for their preparation |
| US3536578A (en) * | 1968-02-16 | 1970-10-27 | Westvaco Corp | Treatment of paper and paperboard to prevent discoloration |
| US3810874A (en) * | 1969-03-10 | 1974-05-14 | Minnesota Mining & Mfg | Polymers prepared from poly(perfluoro-alkylene oxide) compounds |
| US3676182A (en) * | 1970-08-31 | 1972-07-11 | Richard Daniel Smith | Treatment of cellulosic materials |
| US3676055A (en) * | 1970-08-31 | 1972-07-11 | Richard Daniel Smith | Preserving cellulosic materials through treatment with alkylene oxides |
| US3703353A (en) * | 1971-04-15 | 1972-11-21 | Council On Library Resources I | Gaseous diffusion paper deacidification |
| US3771958A (en) * | 1971-12-30 | 1973-11-13 | Research Corp | Gaseous diffusion paper deacidification |
| US3898356A (en) * | 1974-02-28 | 1975-08-05 | Us Army | Method of deacidifying paper |
| US4051276A (en) * | 1974-12-24 | 1977-09-27 | The United States Government As Represented By The Librarian Of Congress | Method of deacidifying paper |
| US3969549A (en) * | 1974-12-24 | 1976-07-13 | The United States Of America As Represented By The Librarian Of Congress | Method of deacidifying paper |
| US3939091A (en) * | 1975-02-14 | 1976-02-17 | The United States Of America As Represented By The Librarian Of Congress | Composition for use in deacidification of paper |
| US4318963A (en) * | 1980-01-21 | 1982-03-09 | Smith Richard D | Treatment of cellulosic materials |
| US4523039A (en) * | 1980-04-11 | 1985-06-11 | The University Of Texas | Method for forming perfluorocarbon ethers |
| US4522843A (en) * | 1984-01-25 | 1985-06-11 | Kundrot Robert A | Deacidification of library materials |
| JPH07100920B2 (ja) * | 1985-02-20 | 1995-11-01 | コツパ−ス コムパニ− インコ−ポレ−テツド | 図書材料の脱酸方法 |
| JPS63500110A (ja) * | 1985-07-10 | 1988-01-14 | スミス,リチャ−ド・ダニエル | セルロ−ス材料の処理 |
| US5208072A (en) * | 1988-09-30 | 1993-05-04 | Fmc Corporation | Mass treatment of cellulosic materials |
| US5137760A (en) * | 1989-04-10 | 1992-08-11 | Document Reprocessors | Deacidification process |
| IT1252006B (it) * | 1991-11-20 | 1995-05-27 | Syremont Spa | Microemulsioni di acqua in olio e loro impiego nel trattamento di carta |
| US5605882A (en) * | 1992-05-28 | 1997-02-25 | E. I. Du Pont De Nemours And Company | Azeotrope(like) compositions of pentafluorodimethyl ether and difluoromethane |
| US5264243A (en) * | 1992-06-16 | 1993-11-23 | Fmc Corporation | Mass cellulose deacidification process |
| US5422147A (en) * | 1993-08-12 | 1995-06-06 | Preservation Technologies, Inc. | Method and apparatus for the deacidification of library materials |
| US5409736A (en) * | 1993-08-31 | 1995-04-25 | Preservation Technologies, Inc. | Deacidification of cellulose based materials using perfluorinated carriers |
| US5565497A (en) * | 1995-12-07 | 1996-10-15 | The Celotex Corporation | Dispersant for filled, rigid cellular polymers |
| US5770148A (en) * | 1996-01-16 | 1998-06-23 | Preservation Technologies, L.P. | Method and apparatus for the deacidification of library materials |
| US5733416A (en) * | 1996-02-22 | 1998-03-31 | Entropic Systems, Inc. | Process for water displacement and component recycling |
| JP3357070B2 (ja) * | 1996-03-15 | 2002-12-16 | 松本油脂製薬株式会社 | 磁性流体を内包するマイクロカプセル及びその製造方法とその利用 |
| US5750797A (en) * | 1996-04-15 | 1998-05-12 | Minnesota Mining And Manufacturing Company | Process for the production of hydrofluoroethers |
| US5851436A (en) * | 1996-06-13 | 1998-12-22 | E. I. Du Pont De Nemours And Company | Nonafluoromethoxybutane compositions |
| JPH1046497A (ja) * | 1996-07-30 | 1998-02-17 | Hiroshi Kato | 酸性紙の脱酸兼紙質補強剤の製法 |
| US6023002A (en) * | 1998-01-26 | 2000-02-08 | 3M Innovative Properties Company | Process for preparing hydrofluoroethers |
| US6162766A (en) * | 1998-05-29 | 2000-12-19 | 3M Innovative Properties Company | Encapsulated breakers, compositions and methods of use |
-
1998
- 1998-04-03 US US09/054,690 patent/US6080448A/en not_active Expired - Lifetime
-
1999
- 1999-03-25 WO PCT/US1999/006596 patent/WO1999051819A1/en not_active Ceased
- 1999-03-25 CA CA002326998A patent/CA2326998C/en not_active Expired - Fee Related
- 1999-03-25 DE DE69902768T patent/DE69902768T2/de not_active Expired - Lifetime
- 1999-03-25 AU AU32050/99A patent/AU743868B2/en not_active Ceased
- 1999-03-25 JP JP2000542527A patent/JP4537578B2/ja not_active Expired - Lifetime
- 1999-03-25 KR KR1020007010980A patent/KR100640118B1/ko not_active Expired - Lifetime
- 1999-03-25 EP EP99914148A patent/EP1068395B1/en not_active Expired - Lifetime
- 1999-03-25 PT PT99914148T patent/PT1068395E/pt unknown
- 1999-03-25 ES ES99914148T patent/ES2183536T3/es not_active Expired - Lifetime
- 1999-03-25 AT AT99914148T patent/ATE223535T1/de active
-
2000
- 2000-05-12 US US09/570,579 patent/US6342098B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69902768D1 (de) | 2002-10-10 |
| ATE223535T1 (de) | 2002-09-15 |
| CA2326998C (en) | 2004-07-13 |
| WO1999051819A1 (en) | 1999-10-14 |
| JP4537578B2 (ja) | 2010-09-01 |
| EP1068395A1 (en) | 2001-01-17 |
| AU3205099A (en) | 1999-10-25 |
| EP1068395B1 (en) | 2002-09-04 |
| KR20010034725A (ko) | 2001-04-25 |
| US6342098B1 (en) | 2002-01-29 |
| CA2326998A1 (en) | 1999-10-14 |
| US6080448A (en) | 2000-06-27 |
| AU743868B2 (en) | 2002-02-07 |
| KR100640118B1 (ko) | 2006-10-31 |
| PT1068395E (pt) | 2002-11-29 |
| DE69902768T2 (de) | 2003-01-09 |
| JP2002510758A (ja) | 2002-04-09 |
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