ES2177401A1 - Procedimiento de extraccion y purificacion de tocoferoles naturales y esteroles por esterificacion con trimetilol propano. - Google Patents
Procedimiento de extraccion y purificacion de tocoferoles naturales y esteroles por esterificacion con trimetilol propano.Info
- Publication number
- ES2177401A1 ES2177401A1 ES200001604A ES200001604A ES2177401A1 ES 2177401 A1 ES2177401 A1 ES 2177401A1 ES 200001604 A ES200001604 A ES 200001604A ES 200001604 A ES200001604 A ES 200001604A ES 2177401 A1 ES2177401 A1 ES 2177401A1
- Authority
- ES
- Spain
- Prior art keywords
- sterols
- tocopherols
- extracting
- distillation
- sterification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229930003799 tocopherol Natural products 0.000 title abstract 4
- 239000011732 tocopherol Substances 0.000 title abstract 4
- 235000019149 tocopherols Nutrition 0.000 title abstract 4
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 title abstract 4
- 229930182558 Sterol Natural products 0.000 title abstract 3
- 150000003432 sterols Chemical class 0.000 title abstract 3
- 235000003702 sterols Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N ethyl trimethyl methane Natural products CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 title 2
- 230000032050 esterification Effects 0.000 title 1
- 238000005886 esterification reaction Methods 0.000 title 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 3
- 229930195729 fatty acid Natural products 0.000 abstract 3
- 239000000194 fatty acid Substances 0.000 abstract 3
- 150000004665 fatty acids Chemical class 0.000 abstract 3
- 239000001294 propane Substances 0.000 abstract 3
- 238000004821 distillation Methods 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 238000000199 molecular distillation Methods 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- GQZXNSPRSGFJLY-UHFFFAOYSA-N hydroxyphosphanone Chemical compound OP=O GQZXNSPRSGFJLY-UHFFFAOYSA-N 0.000 abstract 1
- 229940046817 hypophosphorus acid Drugs 0.000 abstract 1
- 230000000717 retained effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
- C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Pyrane Compounds (AREA)
- Fats And Perfumes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
Abstract
Procedimiento de extracción y purificación de tocoferoles naturales y esteroles por esterificación con trimetilol propano, que consiste en una esterificación especialmente catalizada con el fin de conseguir convertir los ácidos grasos presentes en el destilado de desodorización en esteres de alto peso molecular de poca volatilidad y que por tanto en una destilación selectiva permanezcan en el residuo de la misma, efectuándose la esterificación de ácidos grasos utilizando como alcohol trimetil- ol-propano, y como catalizador ácido hipofosforoso, así como en la dilución se emplea metanol en la proporción de 1 a 7 y el centrifugado o filtrado a -30°C, realizándose la destilación molecular para separar ésteres de ácidos grasos y trimetil-ol- propano, de tocoferoles, esteroles e hidrocarburos, realizándose la destilación molecular para purificar los tocoferoles.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200001604A ES2177401B1 (es) | 2000-06-28 | 2000-06-28 | Procedimiento de extraccion y purificacion de tocoferoles naturales y esteroles por esterificacion con trimetilol propano. |
| EP00940429A EP1426368A1 (en) | 2000-06-28 | 2000-07-05 | Method for extracting and purifying natural tocopherols and sterols by esterification with trimethyl propane |
| PCT/ES2000/000237 WO2002000640A1 (es) | 2000-06-28 | 2000-07-05 | Procedimiento de extraccion y purificacion de tocoferoles naturales y esteroles por esterificacion con trimetilol propano |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200001604A ES2177401B1 (es) | 2000-06-28 | 2000-06-28 | Procedimiento de extraccion y purificacion de tocoferoles naturales y esteroles por esterificacion con trimetilol propano. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2177401A1 true ES2177401A1 (es) | 2002-12-01 |
| ES2177401B1 ES2177401B1 (es) | 2004-09-16 |
Family
ID=8494047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES200001604A Expired - Fee Related ES2177401B1 (es) | 2000-06-28 | 2000-06-28 | Procedimiento de extraccion y purificacion de tocoferoles naturales y esteroles por esterificacion con trimetilol propano. |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1426368A1 (es) |
| ES (1) | ES2177401B1 (es) |
| WO (1) | WO2002000640A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234228A (zh) * | 2010-05-05 | 2011-11-09 | 北京石油化工学院 | 离子液体催化合成三羟甲基丙烷脂肪酸酯的方法 |
| CN103319446B (zh) * | 2013-07-05 | 2015-07-29 | 河南懿丰油脂有限公司 | 从植物油脱臭馏出物中提取天然维生素e的方法 |
| MY193786A (en) * | 2015-01-12 | 2022-10-27 | Ho Sue San David | Recovery of tocopherols/tocotrienols, carotenoids, glycerols, sterols and fatty acid esters from crude vegetable oil and the process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0610742A1 (de) * | 1993-02-11 | 1994-08-17 | F. Hoffmann-La Roche Ag | Verfahren zur Gewinnung von Tocopherolen und Sterolen aus natürlichen Quellen |
| WO1997000309A1 (es) * | 1995-06-15 | 1997-01-03 | Domingo Saura Lopez | Procedimiento para la preparacion enzimatica de extractos oleosos enriquecidos en antioxidantes naturales |
| WO1997021697A1 (en) * | 1995-12-13 | 1997-06-19 | Henkel Corporation | Recovery of tocopherols |
-
2000
- 2000-06-28 ES ES200001604A patent/ES2177401B1/es not_active Expired - Fee Related
- 2000-07-05 EP EP00940429A patent/EP1426368A1/en not_active Withdrawn
- 2000-07-05 WO PCT/ES2000/000237 patent/WO2002000640A1/es not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0610742A1 (de) * | 1993-02-11 | 1994-08-17 | F. Hoffmann-La Roche Ag | Verfahren zur Gewinnung von Tocopherolen und Sterolen aus natürlichen Quellen |
| WO1997000309A1 (es) * | 1995-06-15 | 1997-01-03 | Domingo Saura Lopez | Procedimiento para la preparacion enzimatica de extractos oleosos enriquecidos en antioxidantes naturales |
| WO1997021697A1 (en) * | 1995-12-13 | 1997-06-19 | Henkel Corporation | Recovery of tocopherols |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1426368A1 (en) | 2004-06-09 |
| ES2177401B1 (es) | 2004-09-16 |
| WO2002000640A1 (es) | 2002-01-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 20021201 Kind code of ref document: A1 |
|
| FG2A | Definitive protection |
Ref document number: 2177401B1 Country of ref document: ES |
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| FD2A | Announcement of lapse in spain |
Effective date: 20211117 |