ES2166953T3 - Procedimiento de amoxidacion en reactor de lecho fluidificado. - Google Patents
Procedimiento de amoxidacion en reactor de lecho fluidificado.Info
- Publication number
- ES2166953T3 ES2166953T3 ES97307483T ES97307483T ES2166953T3 ES 2166953 T3 ES2166953 T3 ES 2166953T3 ES 97307483 T ES97307483 T ES 97307483T ES 97307483 T ES97307483 T ES 97307483T ES 2166953 T3 ES2166953 T3 ES 2166953T3
- Authority
- ES
- Spain
- Prior art keywords
- methanol
- milk
- fluidized
- reaction
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000008267 milk Substances 0.000 title abstract 7
- 210000004080 milk Anatomy 0.000 title abstract 7
- 235000013336 milk Nutrition 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 6
- 229910052760 oxygen Inorganic materials 0.000 abstract 6
- 239000001301 oxygen Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 4
- 229910021529 ammonia Inorganic materials 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000011343 solid material Substances 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 241000243320 Hydrozoa Species 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- WWVKQTNONPWVEL-UHFFFAOYSA-N caffeic acid phenethyl ester Natural products C1=C(O)C(O)=CC=C1C=CC(=O)OCC1=CC=CC=C1 WWVKQTNONPWVEL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- SWUARLUWKZWEBQ-UHFFFAOYSA-N phenylethyl ester of caffeic acid Natural products C1=C(O)C(O)=CC=C1C=CC(=O)OCCC1=CC=CC=C1 SWUARLUWKZWEBQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8435—Antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0241—Preparation in gaseous phase from alcohols or aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
UN METODO DE AMOXIDACION EN UN REACTOR DE LECHO FLUIDIZADO, EN EL CUAL, CUANDO UN MATERIAL DE PARTIDA QUE VA A SER AMOXIDADO SE AMOXIDA MEDIANTE UNA REACCION EN LECHO FLUIDIZADO CATALITICA EN FASE DE VAPOR, LA REACCION SE LLEVA A CABO EN UN REACTOR DE LECHO FLUIDIZADO AL CUAL SE INTRODUCE GAS QUE CONTIENE OXIGENO A TRAVES DE UNAS ABERTURAS DE ENTRADA SITUADAS EN EL FONDO DEL MISMO Y UN MATERIAL DE PARTIDA QUE VA A SER AMOXIDADO SE INTRODUCE A TRAVES DE UNAS ABERTURAS DE ENTRADA SITUADAS POR ENCIMA DE LAS ABERTURAS DE ENTRADA PARA EL GAS QUE CONTIENE OXIGENO, SIENDO LA DISTANCIA ENTRE LAS ABERTURAS DE ENTRADA PARA EL GAS QUE CONTIENE OXIGENO Y LAS DEL MATERIAL DE PARTIDA ENTRE 30 Y 250 % DE LA ALTURA DE UN MATERIAL SOLIDO FLUIDIZADO EN UN ESTADO ESTATICO, DE MANERA QUE SE FORMA UN LECHO FLUIDIZADO TAL QUE LA DENSIDAD DEL MATERIAL SOLIDO FLUIDIZADO EN LAS ABERTURAS DE ENTRADA DEL MATERIAL QUE VA A SER AMOXIDADO ESTA EN EL INTERVALO DE ENTRE 50 Y 300 KG/M SUP,3} Y LA VELOCIDAD DEL GAS ES 1 M/SO INFERIOR. MEDIANTE ESTE METODO, LA EFICACIA DEL CONTACTO ENTRE LAS PARTICULAS DE CATALIZADOR Y UN MATERIAL DE PARTIDA Y EL RESULTADO DE LA REACCION (EL RENDIMIENTO DE UN PRODUCTO DESEADO) SE VEN MEJORADOS. UN EJEMPLO ESPECIFICO DE LA PRESENTE INVENCION ES UN METODO PARA LA AMOXIDACION DEL METANOL, EN EL CUAL, CUANDO LA AMOXIDACION CATALITICA EN FASE DE VAPOR DEL METANOL SE LLEVA A CABO EN UN REACTOR DE LECHO FLUIDIZADO PARA OBTENER ACIDO CIANHIDRICO, LA REACCION SE LLEVA A CABO UTILIZANDO, COMO CATALIZADOR, UN OXIDO METALICO QUE CONTIENE [I] AL MENOS UN ELEMENTO SELECCIONADO ENTRE EL GRUPO QUE CONSISTE EN HIERRO, ANTIMONIO, FOSFORO Y COBRE Y [II] AL MENOS UN ELEMENTO SELECCIONADO ENTRE EL GRUPO QUE CONSISTE EN VANADIO, MANGANESO, MOLIBDENO, TUNGSTENO Y BISMUTO, INTRODUCIENDO EN EL LECHO DEL CATALIZADOR UN GAS QUE CONTIENE OXIGENO A TRAVES DE LAS ABERTURAS DE ENTRADA SITUADAS EN LA PARTE INFERIOR DEL REACTOR Y METANOL Y AMONIACO COMO GAS QUE CONTIENE VAPOR DE AGUA A TRAVES DE LAS ABERTURAS SITUADAS POR ENCIMA DE LAS ABERTURAS DE ENTRADA PARA EL GAS QUE CONTIENE OXIGENO O INTRODUCIENDO TODA O PARTE DEL VAPOR DE AGUA EN EL LECHO DEL CATALIZADOR A TRAVES DE LAS ABERTURAS DE ENTRADAS SITUADAS POR DEBAJO DE LAS ABERTURAS DE ENTRADA DEL METANOL Y DEL AMONIACO, CON UNA RELACION MOLAR ENTRE VAPOR DE AGUA Y METANOL AJUSTADA ENTRE 0,1 Y 3. MEDIANTE ESTE METODO, LA REACCION SE PUEDE LLEVAR A CABO EFICAZMENTE INCLUSO EN TALES CONDICIONES DE REACCION EN QUE LA CANTIDAD DE OXIGENO O AMONIACO EN RELACION A LA DEL METANOL CONTENIDA EN UN GAS INTRODUCIDO ES PEQUEÑA Y EL PRODUCTO DESEADO, ES DECIR, EL ACIDO CIANHIDRICO, SE PUEDE OBTENER ASI CON UN ALTO RENDIMIENTO Y SIENDO TAMBIEN ESTABLE CON EL TIEMPO.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25349196 | 1996-09-25 | ||
| JP21022097A JP3999850B2 (ja) | 1997-07-22 | 1997-07-22 | 流動層反応による青酸の製造方法 |
| JP09207637A JP3091168B2 (ja) | 1996-09-25 | 1997-08-01 | 流動層反応器におけるアンモ酸化法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2166953T3 true ES2166953T3 (es) | 2002-05-01 |
Family
ID=27328783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97307483T Expired - Lifetime ES2166953T3 (es) | 1996-09-25 | 1997-09-24 | Procedimiento de amoxidacion en reactor de lecho fluidificado. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6057471A (es) |
| EP (1) | EP0832877B1 (es) |
| DE (1) | DE69708431T2 (es) |
| ES (1) | ES2166953T3 (es) |
| NL (1) | NL1007120C2 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999041012A1 (en) * | 1998-02-13 | 1999-08-19 | Korea Research Institute Of Chemical Technology | A solid catalyst with core-shell catalytic phase and a method of preparation thereof |
| JP2001029788A (ja) * | 1999-07-21 | 2001-02-06 | Mitsubishi Rayon Co Ltd | モリブデン−ビスマス−鉄含有金属酸化物流動層触媒の製法 |
| EP1113001B1 (en) * | 1999-12-27 | 2008-11-05 | Mitsubishi Gas Chemical Company, Inc. | Process for producing nitrile compounds |
| TWI322709B (en) | 2001-12-04 | 2010-04-01 | Bp Chem Int Ltd | Oxidation process in fluidised bed reactor |
| US6890877B2 (en) * | 2002-07-09 | 2005-05-10 | Conocophillips Company | Enhanced fluid/solids contacting in a fluidization reactor |
| US7718811B2 (en) | 2002-11-26 | 2010-05-18 | Ineos Europe Limited | Oxidation process in fluidised bed reactor |
| DE10317929A1 (de) * | 2003-04-17 | 2004-11-11 | Basf Ag | Verfahren zur Aufreinigung von Blausäure |
| US7062586B2 (en) * | 2003-04-21 | 2006-06-13 | Xilinx, Inc. | Method and apparatus for communication within a programmable logic device using serial transceivers |
| FR2931477B1 (fr) * | 2008-05-21 | 2012-08-17 | Arkema France | Acide cyanhydrique derive de matiere premiere renouvable |
| FR2938838B1 (fr) | 2008-11-27 | 2012-06-08 | Arkema France | Procede de fabrication d'un methacrylate de methyle derive de la biomasse |
| CN103566838B (zh) * | 2012-08-02 | 2018-04-13 | 宁波科元塑胶有限公司 | 丙烯腈流化反应系统及丙烯腈流化床生产方法 |
| CN104941535A (zh) * | 2014-03-31 | 2015-09-30 | 英尼奥斯欧洲股份公司 | 用于氧化或氨氧化反应器的改进的空气格栅设计 |
| CN104672106A (zh) * | 2015-03-06 | 2015-06-03 | 英尼奥斯欧洲股份公司 | 改进的丙烯腈制造 |
| TWI781916B (zh) | 2016-01-09 | 2022-11-01 | 美商阿散德性能材料營運公司 | 用於在丙烯腈反應器饋入流中氰化氫之直接製備的催化劑組合物及方法 |
| JP7294401B2 (ja) * | 2019-02-27 | 2023-06-20 | 三菱ケミカル株式会社 | 青酸の製造方法及び青酸の製造装置 |
| KR102800056B1 (ko) * | 2021-11-18 | 2025-04-23 | 주식회사 엘지화학 | 스파저 및 이를 포함하는 반응기 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4083804A (en) * | 1974-02-09 | 1978-04-11 | Nitto Chemical Industry Co., Ltd. | Catalyst for use in and process for preparing acrylonitrile |
| JPS5318014B2 (es) * | 1974-02-09 | 1978-06-13 | ||
| US4102914A (en) * | 1977-05-20 | 1978-07-25 | Gulf Research & Development Company | Process for preparing acrylonitrile |
| US4511548A (en) * | 1981-12-18 | 1985-04-16 | The Standard Oil Company | Ammoxidation of methanol to produce hydrogen cyanide |
| US4801731A (en) * | 1987-12-14 | 1989-01-31 | E. I. Du Pont De Nemours And Company | Preparation of acrylonitrile |
| JPH0764555B2 (ja) * | 1988-04-05 | 1995-07-12 | 日東化学工業株式会社 | 青酸製法 |
| EP0446379B1 (en) * | 1989-10-04 | 1994-04-06 | Asahi Kasei Kogyo Kabushiki Kaisha | Apparatus for producing alpha-beta-unsaturated nitrile |
| JPH03157355A (ja) * | 1989-11-15 | 1991-07-05 | Asahi Chem Ind Co Ltd | α・β―不飽和ニトリルの製造装置 |
| KR0130715B1 (ko) * | 1995-02-01 | 1998-04-08 | 유미꾸라 레이이찌 | 유동상 반응기 및 이를 사용한 반응 방법 |
| KR0169027B1 (ko) * | 1995-04-07 | 1999-03-20 | 유미꾸라 레이이찌 | 알파,베타-불포화 니트릴의 제조 방법 |
-
1997
- 1997-09-24 DE DE69708431T patent/DE69708431T2/de not_active Expired - Lifetime
- 1997-09-24 ES ES97307483T patent/ES2166953T3/es not_active Expired - Lifetime
- 1997-09-24 EP EP97307483A patent/EP0832877B1/en not_active Expired - Lifetime
- 1997-09-25 NL NL1007120A patent/NL1007120C2/nl not_active IP Right Cessation
- 1997-09-25 US US08/936,911 patent/US6057471A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0832877A3 (en) | 1999-01-27 |
| NL1007120C2 (nl) | 1999-02-23 |
| US6057471A (en) | 2000-05-02 |
| DE69708431T2 (de) | 2002-05-02 |
| EP0832877B1 (en) | 2001-11-21 |
| NL1007120A1 (nl) | 1998-03-26 |
| EP0832877A2 (en) | 1998-04-01 |
| DE69708431D1 (de) | 2002-01-03 |
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