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ES2160044A1 - Oxidacion de *-pineno. - Google Patents

Oxidacion de *-pineno.

Info

Publication number
ES2160044A1
ES2160044A1 ES009900565A ES9900565A ES2160044A1 ES 2160044 A1 ES2160044 A1 ES 2160044A1 ES 009900565 A ES009900565 A ES 009900565A ES 9900565 A ES9900565 A ES 9900565A ES 2160044 A1 ES2160044 A1 ES 2160044A1
Authority
ES
Spain
Prior art keywords
pinene
oxidation
silica
contain
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009900565A
Other languages
English (en)
Other versions
ES2160044B1 (es
Inventor
Canos Avelino Corma
Marcelo Eduardo Domine
Rogel Manuel Susarte
Garcia Fernando Rey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES9900565A priority Critical patent/ES2160044B1/es
Priority to JP2000604945A priority patent/JP2002538952A/ja
Priority to PCT/ES2000/000087 priority patent/WO2000054880A1/es
Priority to BR0010512-0A priority patent/BR0010512A/pt
Priority to CN 00807698 priority patent/CN1351519A/zh
Priority to EP00909371A priority patent/EP1172142A1/en
Publication of ES2160044A1 publication Critical patent/ES2160044A1/es
Application granted granted Critical
Publication of ES2160044B1 publication Critical patent/ES2160044B1/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)

Abstract

"Oxidación de {al}-pineno". En la presente invención se describe uso de catalizadores sólidos mesoporosos tipo MCM-41 basados en sílice que además contienen Ti en su composición y empleando hidroperóxidos orgánicos como agentes oxidantes, en la oxidación de {al}-pineno.
ES9900565A 1999-03-16 1999-03-16 Oxidacion de *-pineno. Expired - Lifetime ES2160044B1 (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES9900565A ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.
JP2000604945A JP2002538952A (ja) 1999-03-16 2000-03-13 Ｔｉ含有ＭＣＭ−４１型中間細孔性物質およびα−ピネン酸化用触媒としてのその使用
PCT/ES2000/000087 WO2000054880A1 (es) 1999-03-16 2000-03-13 MATERIALES MESOPOROSOS TIPO MCM-41 CONTENIENDO TITANIO Y SU USO COMO CATALIZADORES EN LA OXIDACIÓN DE α PINENO
BR0010512-0A BR0010512A (pt) 1999-03-16 2000-03-13 Uso de materiais mesoporosos tipo mcm-41 como catalisadores na oxidação de "alfa"-pineno e processo para a oxidação de "alfa"-pineno
CN 00807698 CN1351519A (zh) 1999-03-16 2000-03-13 α－蒎烯的氧化
EP00909371A EP1172142A1 (en) 1999-03-16 2000-03-13 Mcm-41 type microporous materials containing titanium and their utilization as catalysts in alpha-pinene oxidation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9900565A ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.

Publications (2)

Publication Number Publication Date
ES2160044A1 true ES2160044A1 (es) 2001-10-16
ES2160044B1 ES2160044B1 (es) 2002-06-16

Family

ID=8307719

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9900565A Expired - Lifetime ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.

Country Status (6)

Country Link
EP (1) EP1172142A1 (es)
JP (1) JP2002538952A (es)
CN (1) CN1351519A (es)
BR (1) BR0010512A (es)
ES (1) ES2160044B1 (es)
WO (1) WO2000054880A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100415427B1 (ko) * 2001-08-07 2004-01-16 인천정유 주식회사 금속/Ａｌ-ＭＣＭ-41 이원촉매 및 이의 제조방법과금속/Ａｌ-ＭＣＭ-41 이원촉매를 이용한 불포화탄화수소의 수소화반응
WO2004101472A2 (en) * 2003-05-08 2004-11-25 Flexitral Inc. Novel fragrance derivatives
RU2425040C1 (ru) * 2010-02-24 2011-07-27 Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) Способ получения 2,3-эпоксипинана из скипидара
CN101885671A (zh) * 2010-07-01 2010-11-17 杭州格林香料化学有限公司 一种连续合成龙脑烯醛的生产方法
CN104190392B (zh) * 2014-07-25 2017-04-12 广西梧州松脂股份有限公司 钛基催化剂的制备方法
PL237108B1 (pl) * 2018-02-27 2021-03-22 Univ West Pomeranian Szczecin Tech Sposób utleniania alfa-pinenu
CN113905987B (zh) * 2019-05-29 2024-10-18 住友化学株式会社 含钛的硅氧化物的制造方法、环氧化物的制造方法和含钛的硅氧化物
CN113181967B (zh) * 2021-04-28 2023-07-14 昆明理工大学 磺酸化钛改性的kit-6固体酸催化剂在合成龙脑中的应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994029022A1 (es) * 1993-06-15 1994-12-22 Consejo Superior Investigaciones Cientificas Material de estructura tipo zeolita de poros ultragrandes con una red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994029022A1 (es) * 1993-06-15 1994-12-22 Consejo Superior Investigaciones Cientificas Material de estructura tipo zeolita de poros ultragrandes con una red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CORMA, A. et al., One step synthesis of highly active and selective epoxidation catalysts formed by organic-inorganic Ti containing mesoporous composites. Chem. Commun. (Cambridge) 1998, (17), paginas 1899-1900, todo el documento. *
MASCHMEYER, I. et al., Developments in silica-supported organometallic catalysis. Silsesquioxanes and mesoporous MCM-41 silicates. NATO ASI Ser., Ser. C (1997), 498 (New Trends in Materials Chemistry), paginas 461-494, todo el documento. *
ON. D. TRONG et al., Catalytic epoxidation of alpha-pinene over bifunctional mesoporous molecular sieves. Catal. Lett. (1997), Vol. 44, no 3,4, paginas 171-176, ISSN 1011-372X, todo el documento. *

Also Published As

Publication number Publication date
EP1172142A1 (en) 2002-01-16
BR0010512A (pt) 2002-04-02
JP2002538952A (ja) 2002-11-19
ES2160044B1 (es) 2002-06-16
CN1351519A (zh) 2002-05-29
WO2000054880A1 (es) 2000-09-21

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