ES2141372T3 - Procedimiento para preparar un material compuesto reforzado con fibra, asi como articulos moldeados elaborados con el mismo. - Google Patents
Procedimiento para preparar un material compuesto reforzado con fibra, asi como articulos moldeados elaborados con el mismo.Info
- Publication number
- ES2141372T3 ES2141372T3 ES95928860T ES95928860T ES2141372T3 ES 2141372 T3 ES2141372 T3 ES 2141372T3 ES 95928860 T ES95928860 T ES 95928860T ES 95928860 T ES95928860 T ES 95928860T ES 2141372 T3 ES2141372 T3 ES 2141372T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- polyester
- molded items
- fiber
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/14—Mixed esters, e.g. cellulose acetate-butyrate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/06—Polyurethanes from polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31794—Of cross-linked polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Moulding By Coating Moulds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
UN PROCESO DE MOLDEO POR TRANSFERENCIA AYUDADO POR UN VACIO PARA LA PREPARACION DE UN POLIESTER TERMOENDURECIBLE REFORZADO CON FIBRAS, EN DONDE DICHO COMPUESTO CONTIENE FIBRAS DE REFUERZO EN EXCESO DE UN 30% EN PESO, EN BASE AL PESO DEL COMPUESTO, EN UNA MATRIZ DE POLIESTER TERMOENDURECIDO. LA MATRIZ DE POLIESTER TERMOENDURECIDO SE PREPARA A PARTIR DE UN PRECURSOR DE MATRICES DE UNA FASE, QUE COMPRENDE, EN PORCENTAJE EN PESO EN BASE AL PESO DEL PRECURSOR DE MATRICES, DE: (A) UN 20 A UN 60% DE UNA RESINA DE POLIESTER INSATURADO CON UN COEFICIENTE DE PESO MOLECULAR/DOBLE ENLACE ENTRE 150 Y 190; (B) UN 30 A UN 70% DE UN MONOMERO REACTIVO, (C) UN 1 A UN 25% DE UN POLIMERO TERMOPLASTICO MISCIBLE EN UNA MEZCLA DE LA RESINA DE POLIESTER Y EL MONOMERO REACTIVO Y (D) UNA CANTIDAD INICIADORA DE UN INICIADOR DE RADICAL LIBRE. APLICACION PARA LA FABRICACION DE ARTICULOS MOLDEADOS, TALES COMO CASCOS DE EMBARCACIONES O PANELES DE LA CAJA DE CAMIONES, QUE COMPRENDEN UN COMPUESTO HECHO SEGUN EL PROCESO ANTEDICHO, UN REVESTIMIENTO DE GEL Y UN MATERIAL LAMINAR DE REVESTIMIENTO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/217,119 US5900311A (en) | 1994-03-23 | 1994-03-23 | Thermosetting polyester composites prepared via vacuum-assisted technique with smooth surface appearance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2141372T3 true ES2141372T3 (es) | 2000-03-16 |
Family
ID=22809746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95928860T Expired - Lifetime ES2141372T3 (es) | 1994-03-23 | 1995-03-21 | Procedimiento para preparar un material compuesto reforzado con fibra, asi como articulos moldeados elaborados con el mismo. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5900311A (es) |
| EP (1) | EP0700419B1 (es) |
| JP (1) | JPH10511124A (es) |
| KR (1) | KR100346678B1 (es) |
| CN (1) | CN1123555A (es) |
| AT (1) | ATE186935T1 (es) |
| AU (1) | AU2110495A (es) |
| CA (1) | CA2160489A1 (es) |
| DE (1) | DE69513462T2 (es) |
| ES (1) | ES2141372T3 (es) |
| FI (1) | FI954166A7 (es) |
| NO (1) | NO953599L (es) |
| PL (1) | PL310968A1 (es) |
| WO (1) | WO1995025771A1 (es) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6632382B1 (en) | 2000-02-29 | 2003-10-14 | Owens-Corning Fiberglas Technology, Inc. | Extruded foam product with reduced surface defects |
| US6623672B2 (en) | 2000-10-03 | 2003-09-23 | Vec Technology Inc. | Method and apparatus for molding composite articles |
| US7118699B2 (en) * | 2001-03-05 | 2006-10-10 | Illinois Tool Works Inc. | Method of making a composite with a barrier layer in a closed mold process |
| US20030057594A1 (en) * | 2001-03-05 | 2003-03-27 | Anderson Robert Phillip | Method of making a sheet of building material |
| US6463871B1 (en) * | 2001-03-05 | 2002-10-15 | Illinois Tool Works Inc. | Wood replacement system and method |
| US8557884B2 (en) * | 2002-05-31 | 2013-10-15 | Owens Corning Intellectual Capital, Llc | To enhance the thermal insulation of polymeric foam by reducing cell anisotropic ratio and the method for production thereof |
| US20030225172A1 (en) * | 2002-05-31 | 2003-12-04 | Miller Larry M. | To enhance the thermal insulation of polymeric foam by reducing cell anisotropic ratio and the method for production thereof |
| JP4621499B2 (ja) * | 2002-09-15 | 2011-01-26 | アールシーシー リージョナル コンパクト カー アーゲー | ファイバ補強熱可塑性材料から構造部品を製造する方法 |
| DE50306774D1 (de) * | 2002-09-15 | 2007-04-19 | Weber Technology Ag | Strukturbauteil aus faserverstärktem thermoplastischem kunststoff |
| CN100404238C (zh) * | 2003-10-10 | 2008-07-23 | 上海杰事杰新材料股份有限公司 | 热固性-热塑性复合树脂基连续纤维增强复合材料 |
| US8327738B2 (en) * | 2003-11-07 | 2012-12-11 | Sikorsky Aircraft Corporation | Composite transmission housing with discontinuous fiber preforms |
| US7553435B2 (en) * | 2004-01-23 | 2009-06-30 | Vec Industries, L.L.C. | Method and apparatus for molding composite articles |
| US20070090554A1 (en) * | 2005-10-26 | 2007-04-26 | Rick Wykoff | Panel molding method and apparatus |
| US20080230949A1 (en) * | 2007-03-23 | 2008-09-25 | Paul Razgunas | Injection molding process for forming coated molded parts |
| US8597793B2 (en) * | 2008-06-30 | 2013-12-03 | Dai Nippon Printing Co., Ltd. | Decorative sheet, process for producing decorative resin molded product, and decorative resin molded product |
| US8230713B2 (en) | 2008-12-30 | 2012-07-31 | Usamp | Elevated temperature forming die apparatus |
| US8459084B2 (en) * | 2009-02-05 | 2013-06-11 | Usamp | Elevated temperature forming method and preheater apparatus |
| US20120202024A1 (en) * | 2011-02-08 | 2012-08-09 | Vincent Paul Self | Product Compositions, Product Walls, And Molding Processes |
| US8486321B2 (en) * | 2011-07-27 | 2013-07-16 | GM Global Technology Operations LLC | Print through reduction in long fiber reinforced composites by addition of carbon nanotubes |
| WO2013029110A1 (en) * | 2011-09-01 | 2013-03-07 | Jumpac Pty Ltd | Composite material |
| WO2014035393A1 (en) * | 2012-08-30 | 2014-03-06 | Empire Technology Development Llc | Switchable ionic adhesive coating for recyclable carbon fiber |
| EP3057756B1 (en) | 2013-10-14 | 2019-11-27 | United Technologies Corporation | Assembly and method for transfer molding |
| WO2015057647A1 (en) | 2013-10-14 | 2015-04-23 | United Technologies Corporation | Assembly and method for transfer molding |
| JP6300510B2 (ja) * | 2013-12-18 | 2018-03-28 | キヤノン株式会社 | トランスファ成形方法および成形金型 |
| CA2987622A1 (en) * | 2016-12-02 | 2018-06-02 | Stephen Gleason | Composition and method to form a composite core material |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2913036A (en) * | 1956-08-10 | 1959-11-17 | Anthony Bros Fibre Glass Pool | Process and apparatus for molding large plastic structures |
| GB944955A (en) * | 1960-04-12 | 1963-12-18 | English Electric Co Ltd | Improvements in or relating to methods of producing reinforced plastic structures |
| US3701748A (en) * | 1966-07-20 | 1972-10-31 | Rohm & Haas | Unsaturated polyester resinous compositions |
| US3753843A (en) * | 1970-06-29 | 1973-08-21 | Monostruct Corp Ltd | Molded structural panel |
| US4132755A (en) * | 1977-07-22 | 1979-01-02 | Jay Johnson | Process for manufacturing resin-impregnated, reinforced articles without the presence of resin fumes |
| US4312829A (en) * | 1979-12-10 | 1982-01-26 | Fourcher Fredric J | Molding method |
| US4525498A (en) * | 1980-10-16 | 1985-06-25 | Union Carbide Corporation | Polyester fiber reinforced molding compounds |
| US5082878A (en) * | 1988-04-15 | 1992-01-21 | W.R. Grace & Co.-Conn | Shrink controlled low-temperature-curable polyester resin compositions |
| US4902215A (en) * | 1988-06-08 | 1990-02-20 | Seemann Iii William H | Plastic transfer molding techniques for the production of fiber reinforced plastic structures |
| US5202366A (en) * | 1988-07-20 | 1993-04-13 | Union Carbide Chemicals & Plastics Technology Corporation | Crosslinkable polyester compositions with improved properties |
| US5009821A (en) * | 1989-02-23 | 1991-04-23 | Libbey-Owens-Ford Co. | Molding method for eliminating fiber readout |
| US5052906A (en) * | 1989-03-30 | 1991-10-01 | Seemann Composite Systems, Inc. | Plastic transfer molding apparatus for the production of fiber reinforced plastic structures |
| DE3927090A1 (de) * | 1989-08-17 | 1991-02-21 | Freudenberg Carl Fa | Faerbbare polyester-bmc-masse |
| JP2727674B2 (ja) * | 1989-08-24 | 1998-03-11 | 日本油脂株式会社 | 低収縮性不飽和ポリエステル樹脂組成物 |
| US5162401A (en) * | 1989-10-30 | 1992-11-10 | Owens-Corning Fiberglas Corporation | Unsaturated polyester resin compositions containing compatible compounds |
| DE4002218A1 (de) * | 1990-01-26 | 1991-08-01 | Hoechst Ag | Faserverstaerkte polyesterformmasse und ihre verwendung im karosseriebau |
| US5290854A (en) * | 1990-07-23 | 1994-03-01 | Owens-Corning Fiberglas Technology Inc. | Thermoplastic low-profile additives and use thereof in unsaturated polyester resin compositions |
| DE69010679D1 (de) * | 1990-08-03 | 1994-08-18 | Miki Spa | Radom mit grossen Abmessungen. |
| US5232646B1 (en) * | 1990-11-07 | 1999-02-16 | Concrete Design Specialties In | Methods of forming contoured walls |
| JP2503782B2 (ja) * | 1990-12-21 | 1996-06-05 | 住友化学工業株式会社 | 多層成形品の成形方法 |
| US5256709A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having aromatic substituents |
| US5213747A (en) * | 1991-08-27 | 1993-05-25 | William Lippert | Methods of making fiber-reinforced resin molds |
| TW279871B (es) * | 1992-02-25 | 1996-07-01 | Takeda Pharm Industry Co Ltd | |
| US5305568A (en) * | 1992-03-05 | 1994-04-26 | Comcore Utilities Products | High strength, light weight shoring panel and method of preparing same |
| FR2689154A1 (fr) * | 1992-03-27 | 1993-10-01 | Habermann Pierre | Dispositif de bouche d'égout à syphon comprenant une capacité étanche. |
| DE4240744A1 (de) * | 1992-12-03 | 1994-06-09 | Wacker Chemie Gmbh | Verfahren zur Herstellung eines Pfropfcopolymerlatex von Kern-Schale-Dispersionsteilchen mit verbesserter Phasenanbindung zwischen Kern und Schale |
| US5376721A (en) * | 1993-01-29 | 1994-12-27 | Gencorp Inc. | Low-profile additives for thermosetting polyester compositions |
| GB9310378D0 (en) * | 1993-05-20 | 1993-07-07 | Ecc Int Ltd | Improved mineral low profile additive for polymeric compositions |
| AU7845594A (en) * | 1993-09-28 | 1995-04-18 | Cambridge Industries, Inc. | Additives to improve surface characteristics of unsaturated polyester molding composition |
| US5401803A (en) * | 1993-12-23 | 1995-03-28 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene-vinyl acetate copolymer additives for molding compositions |
-
1994
- 1994-03-23 US US08/217,119 patent/US5900311A/en not_active Expired - Fee Related
-
1995
- 1995-03-21 WO PCT/EP1995/001042 patent/WO1995025771A1/en not_active Ceased
- 1995-03-21 ES ES95928860T patent/ES2141372T3/es not_active Expired - Lifetime
- 1995-03-21 KR KR1019950704586A patent/KR100346678B1/ko not_active Expired - Fee Related
- 1995-03-21 PL PL95310968A patent/PL310968A1/xx unknown
- 1995-03-21 CN CN95190115A patent/CN1123555A/zh active Pending
- 1995-03-21 DE DE69513462T patent/DE69513462T2/de not_active Expired - Fee Related
- 1995-03-21 EP EP95928860A patent/EP0700419B1/en not_active Expired - Lifetime
- 1995-03-21 FI FI954166A patent/FI954166A7/fi not_active Application Discontinuation
- 1995-03-21 AU AU21104/95A patent/AU2110495A/en not_active Abandoned
- 1995-03-21 JP JP7524383A patent/JPH10511124A/ja active Pending
- 1995-03-21 AT AT95928860T patent/ATE186935T1/de not_active IP Right Cessation
- 1995-03-21 CA CA002160489A patent/CA2160489A1/en not_active Abandoned
- 1995-09-12 NO NO953599A patent/NO953599L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2160489A1 (en) | 1995-09-28 |
| EP0700419B1 (en) | 1999-11-24 |
| WO1995025771A1 (en) | 1995-09-28 |
| ATE186935T1 (de) | 1999-12-15 |
| NO953599L (no) | 1995-09-28 |
| JPH10511124A (ja) | 1998-10-27 |
| PL310968A1 (en) | 1996-01-22 |
| KR960701952A (ko) | 1996-03-28 |
| AU2110495A (en) | 1995-10-09 |
| US5900311A (en) | 1999-05-04 |
| EP0700419A1 (en) | 1996-03-13 |
| DE69513462T2 (de) | 2000-07-13 |
| FI954166L (fi) | 1995-09-24 |
| FI954166A7 (fi) | 1995-09-24 |
| NO953599D0 (no) | 1995-09-12 |
| KR100346678B1 (ko) | 2002-11-14 |
| FI954166A0 (fi) | 1995-09-06 |
| DE69513462D1 (de) | 1999-12-30 |
| CN1123555A (zh) | 1996-05-29 |
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