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ES2140907T3 - Procedimiento para modificar la porosidad de aluminosilicatos y silices, y composiciones mesoporosas que se obtienen de los mismos. - Google Patents

Procedimiento para modificar la porosidad de aluminosilicatos y silices, y composiciones mesoporosas que se obtienen de los mismos.

Info

Publication number
ES2140907T3
ES2140907T3 ES96936270T ES96936270T ES2140907T3 ES 2140907 T3 ES2140907 T3 ES 2140907T3 ES 96936270 T ES96936270 T ES 96936270T ES 96936270 T ES96936270 T ES 96936270T ES 2140907 T3 ES2140907 T3 ES 2140907T3
Authority
ES
Spain
Prior art keywords
porosity
mesoporous
aluminosilicate
silices
aluminosilicates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96936270T
Other languages
English (en)
Inventor
Dean M Millar
Juan M Garces
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2140907T3 publication Critical patent/ES2140907T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • B01J20/186Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026After-treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00Chemistry of inorganic compounds
    • Y10S423/23Ferrierite, e.g. SR-D ZSM-33
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00Gas separation: processes
    • Y10S95/90Solid sorbent
    • Y10S95/902Molecular sieve

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Silicon Compounds (AREA)

Abstract

PROCESO DE MODIFICACION DE LA POROSIDAD DE UN ALUMINOSILICATO O SILICE CUYA POROSIDAD NO SE ALTERA CON UNA EXTRACCION ACIDA. EL PROCESO CONSISTE EN HACER REACCIONAR DICHO ALUMINOSILICATO O SILICE CON UN ALUMINATO ALCALINO, Y SEGUIDAMENTE UNA EXTRACCION DEL MATERIAL TRATADO CON ALUMINATO CON UN AGENTE EXTRACTIVO PARA FORMAR EL ALUMINOSILICATO O SILICE DE POROSIDAD MODIFICADA. EL PROCESO ES APLICABLE A AQUELLAS ZEOLITAS QUE NO REACCIONEN EN CONDICIONES DE EXTRACCION ACIDA, P.EJ. FERRIERITA, Y ES APLICABLE A AQUELLAS ZEOLITAS QUE SEAN ESTRUCTURALMENTE INESTABLES EN CONDICIONES DE EXTRACCION ACIDA, COMO EL MINERAL BIKITAITO. SE DESCRIBEN UNAS COMPOSICIONES MESOPOROSAS, INCLUYENDO UNA FERRIERITA MESOPOROSA Y UNA ZEOLITA MESOPOROSA DCM-3.
ES96936270T 1995-10-24 1996-10-08 Procedimiento para modificar la porosidad de aluminosilicatos y silices, y composiciones mesoporosas que se obtienen de los mismos. Expired - Lifetime ES2140907T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US605995P 1995-10-24 1995-10-24

Publications (1)

Publication Number Publication Date
ES2140907T3 true ES2140907T3 (es) 2000-03-01

Family

ID=21719093

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96936270T Expired - Lifetime ES2140907T3 (es) 1995-10-24 1996-10-08 Procedimiento para modificar la porosidad de aluminosilicatos y silices, y composiciones mesoporosas que se obtienen de los mismos.

Country Status (10)

Country Link
US (1) US6017508A (es)
EP (1) EP0857159B1 (es)
JP (1) JPH11513662A (es)
KR (1) KR19990066988A (es)
CN (1) CN1089725C (es)
AU (1) AU711249B2 (es)
BR (1) BR9611264A (es)
DE (1) DE69606058T2 (es)
ES (1) ES2140907T3 (es)
WO (1) WO1997015528A1 (es)

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US6171370B1 (en) 1998-03-04 2001-01-09 Tosoh Corporation Adsorbent for separating gases
FR2806643B1 (fr) * 2000-03-27 2002-05-03 Ceca Sa Methode de separation de molecules en phase gaz par adsorption au moyen d'adsorbants inorganiques solides agglomeres a distribution mesoporeuse etroite et calibree
JP2001293368A (ja) * 2000-04-13 2001-10-23 Tosoh Corp 炭化水素吸着剤及び炭化水素の吸着除去方法
EP1205493A1 (en) * 2000-11-14 2002-05-15 ATOFINA Research Polymerisation catalyst systems and their preparation
US6993406B1 (en) * 2003-04-24 2006-01-31 Sandia Corporation Method for making a bio-compatible scaffold
US20050100493A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050100494A1 (en) 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) * 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US7304011B2 (en) * 2004-04-15 2007-12-04 W.R. Grace & Co. -Conn. Compositions and processes for reducing NOx emissions during fluid catalytic cracking
SG169976A1 (en) 2005-04-27 2011-04-29 Grace W R & Co Compositions and processes for reducing nox emissions during fluid catalytic cracking
CN101093735B (zh) * 2007-04-11 2010-12-15 浙江大学 一种用于分离发热元素Cs的吸附剂及其制备和应用
WO2009134543A1 (en) * 2008-04-30 2009-11-05 Exxonmobil Upstream Research Company Method and apparatus for removal of oil from utility gas stream
ES2875884T3 (es) * 2009-01-19 2021-11-11 Grace W R & Co Introducción de mesoporosidad en zeolitas con bajo contenido en Si/A1
KR101384479B1 (ko) 2012-08-24 2014-04-10 한국화학연구원 중형 세공을 갖는 제올라이트의 제조방법
CA2903938A1 (en) 2013-03-08 2014-09-12 Bp Chemicals Limited Carbonylation catalyst and process
US20160101383A1 (en) * 2013-05-16 2016-04-14 Shimane Prefectural Government Carbon dioxide concentration apparatus and carbon dioxide supply method
US9403148B2 (en) 2014-06-23 2016-08-02 Saudi Arabian Oil Company Synthesis of ultra-small pore aluminosilicates by controlled structural collapse of zeolites
US9333482B2 (en) 2014-06-23 2016-05-10 Saudi Arabian Oil Company Synthesis of ultra-small pore aluminosilicates by controlled structural collapse of zeolites
KR20220148515A (ko) * 2021-04-29 2022-11-07 현대자동차주식회사 합성가스로부터 디메틸에테르 합성용 촉매, 이의 제조 방법, 및 이를 이용한 디메틸에테르의 제조 방법

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US3669624A (en) * 1970-07-09 1972-06-13 Grace W R & Co Process for producing high average pore volume silica
JPS5738317A (en) * 1980-08-12 1982-03-03 Toyo Soda Mfg Co Ltd Zeolite powder with high fluidity and its manufacture
DE3170192D1 (en) * 1980-12-11 1985-05-30 Ici Plc Zeolites
US4605803A (en) * 1981-11-21 1986-08-12 Mobil Oil Corporation Acid-catalyzed organic compound conversion
US4559315A (en) * 1983-02-14 1985-12-17 Mobil Oil Corporation Zeolite modification
US4620054A (en) * 1981-11-21 1986-10-28 Mobil Oil Corporation Acid-catalyzed xylene isomerization
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US4401633A (en) * 1982-01-28 1983-08-30 Atlantic Richfield Company Two step process for the preparation of zeolite A by hydrothermal treatment of heulandite
EP0095846B1 (en) * 1982-05-27 1988-07-20 Imperial Chemical Industries Plc Preparation of modified zeolites
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US4837195A (en) * 1986-12-23 1989-06-06 E. I. Du Pont De Nemours And Company Process for porosity control and rehydroxylations of silica bodies
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US4784980A (en) * 1987-07-15 1988-11-15 Amoco Corporation Process for preparing zeolite A from spent cracking catalyst
DE3854266T2 (de) * 1988-02-11 1996-02-15 Euratom Verfahren zur Modifizierung eines Molekularsiebes.
ZA893132B (en) * 1989-04-27 1990-12-28 Zeofuels Res Pty Ltd Modification of natural zeolite and its use as an oligomerisation catalyst
US5238676A (en) * 1990-01-25 1993-08-24 Mobil Oil Corporation Method for modifying synthetic mesoporous crystalline materials
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DE4207815A1 (de) * 1992-03-09 1993-09-16 Wolfgang Dr Rer Nat Lutz Verfahren zur herstellung und stabilisierung hydrophober aluminosilicatischer zeolithe
US5397560A (en) * 1993-04-06 1995-03-14 The Dow Chemical Company Microporous crystalline aluminosilicate designated DCM-2
US5366720A (en) * 1993-12-23 1994-11-22 Uop Process for preparing low silica forms of zeolites having the faujasite type structure
US5849258A (en) * 1996-06-06 1998-12-15 Intevep, S.A. Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same

Also Published As

Publication number Publication date
EP0857159B1 (en) 2000-01-05
CN1200711A (zh) 1998-12-02
KR19990066988A (ko) 1999-08-16
WO1997015528A1 (en) 1997-05-01
AU711249B2 (en) 1999-10-07
BR9611264A (pt) 1999-03-30
EP0857159A1 (en) 1998-08-12
CN1089725C (zh) 2002-08-28
DE69606058T2 (de) 2000-09-28
JPH11513662A (ja) 1999-11-24
DE69606058D1 (de) 2000-02-10
US6017508A (en) 2000-01-25
AU7395996A (en) 1997-05-15

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