ES2026491T3 - Procedimiento para la hidroformilacion en continuo de compuestos olefinicamente insaturados. - Google Patents
Procedimiento para la hidroformilacion en continuo de compuestos olefinicamente insaturados.Info
- Publication number
- ES2026491T3 ES2026491T3 ES198787110130T ES87110130T ES2026491T3 ES 2026491 T3 ES2026491 T3 ES 2026491T3 ES 198787110130 T ES198787110130 T ES 198787110130T ES 87110130 T ES87110130 T ES 87110130T ES 2026491 T3 ES2026491 T3 ES 2026491T3
- Authority
- ES
- Spain
- Prior art keywords
- hydroformilation
- reactor
- procedure
- continuous
- unsaturated compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 239000012530 fluid Substances 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical class [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA HIDROFORMILACION CONTINUA DE COMPUESTOS OLEFINICAMENTE INSATURADOS QUE CONSISTE EN LA INTRODUCCION DE LA OLEFINA EN LA ZONA INFERIOR DEL REACTOR, A 1 HASTA 40 BAR Y 50 HASTA 140 GRADOS CENTIGRADOS, CON LA AYUDA DE COMLEJOS DE RODIO COMO CATALIZADORES EN UN REACTOR DE HIDROFORMILACION CON UNA ZONA FLUIDA DE REACCION QUE EQUIVALE AL 60-85% DEL VOLUMEN DEL REACTOR. SE RETIRAN DEL REACTOR DE HIDROFORMILACION LOS PRODUCTOS GASEOSOS DEL PROCESO Y LOS COMPUESTOS PARTICIPANTES EN LA REACCION, SE SEPARAN LOS PRODUCTOS DEL PROCESO Y SE RETORNA AL REACTOR LA MAYOR PARTE DEL GAS RESTANTE MEDIANTE UN METODO DE CIRCULACION DE GAS EN EL QUE SE CONDUCE AL REACTOR DE HIDROFORMILACION UN 20 A 80% EN VOLUMEN DEL GAS CIRCULANTE POR ENCIMA DE LA ZONA FLUIDA DE REACCION Y/O POR DEBAJO DE LA SUPERFICIE DEL LIQUIDO EN EL CUARTO SUPERIOR DE LA ZONA FLUIDA DE REACCION.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863625261 DE3625261A1 (de) | 1986-07-25 | 1986-07-25 | Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2026491T3 true ES2026491T3 (es) | 1992-05-01 |
Family
ID=6306011
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES198787110130T Expired - Lifetime ES2026491T3 (es) | 1986-07-25 | 1987-07-14 | Procedimiento para la hidroformilacion en continuo de compuestos olefinicamente insaturados. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4778929A (es) |
| EP (1) | EP0254180B1 (es) |
| JP (1) | JPS6335536A (es) |
| AT (1) | ATE68462T1 (es) |
| CA (1) | CA1297130C (es) |
| DE (2) | DE3625261A1 (es) |
| ES (1) | ES2026491T3 (es) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5030774A (en) * | 1986-10-03 | 1991-07-09 | Exxon Research And Engineering Co. | Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof |
| DE3924720A1 (de) * | 1989-07-26 | 1991-01-31 | Basf Ag | Hydroformylierungsverfahren |
| DE19836807A1 (de) | 1998-08-14 | 2000-02-17 | Basf Ag | Verfahren zur Herstellung von Aldehyden und/oder Alkoholen oder Aminen |
| DE10031519A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 8 Kohlenstoffatomen, I |
| DE10031517A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroformylierungspordukten von Olefinen mit 2 bis 8 Kohlenstoffatomen |
| DE10201676A1 (de) * | 2002-01-17 | 2003-07-31 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 6 Kohlenstoffatomen |
| MY141209A (en) * | 2003-03-13 | 2010-03-31 | Chiyoda Corp | Method of manufacturing acetic acid |
| ATE401292T1 (de) * | 2003-10-21 | 2008-08-15 | Basf Se | Verfahren zur kontinuierlichen herstellung von aldehyden |
| DE10357718A1 (de) | 2003-12-09 | 2005-07-21 | Basf Ag | Verfahren zur Herstellung von Tricyclodecandialdehyd |
| EP1697585A4 (en) * | 2003-12-15 | 2009-04-08 | Univ Yale | MAGNETOELECTRONIC DEVICES BASED ON THIN-LAYERED FILMS WITH CMR (LARGE MAGNETO-RESISTOR) |
| US7371894B2 (en) | 2004-09-02 | 2008-05-13 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7572932B2 (en) | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7608732B2 (en) | 2005-03-08 | 2009-10-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7507857B2 (en) | 2004-09-02 | 2009-03-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7381836B2 (en) | 2004-09-02 | 2008-06-03 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7582793B2 (en) | 2004-09-02 | 2009-09-01 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7741515B2 (en) | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7586000B2 (en) | 2004-09-02 | 2009-09-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7390921B2 (en) | 2004-09-02 | 2008-06-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7495125B2 (en) | 2004-09-02 | 2009-02-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7568361B2 (en) | 2004-09-02 | 2009-08-04 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7399882B2 (en) * | 2004-09-02 | 2008-07-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7361784B2 (en) | 2004-09-02 | 2008-04-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7563926B2 (en) * | 2004-09-02 | 2009-07-21 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7482482B2 (en) | 2004-09-02 | 2009-01-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7910769B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7589231B2 (en) | 2004-09-02 | 2009-09-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7572936B2 (en) | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7683210B2 (en) | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7504535B2 (en) | 2004-09-02 | 2009-03-17 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7608733B2 (en) | 2004-09-02 | 2009-10-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US20060116531A1 (en) * | 2004-11-29 | 2006-06-01 | Wonders Alan G | Modeling of liquid-phase oxidation |
| US7884232B2 (en) | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7358389B2 (en) | 2006-01-04 | 2008-04-15 | Eastman Chemical Company | Oxidation system employing internal structure for enhanced hydrodynamics |
| US7355068B2 (en) | 2006-01-04 | 2008-04-08 | Eastman Chemical Company | Oxidation system with internal secondary reactor |
| US8889917B2 (en) | 2012-04-12 | 2014-11-18 | Basf Se | Method of supplementing the catalyst in continuous hydroformylation |
| KR102104824B1 (ko) | 2012-04-12 | 2020-04-28 | 바스프 에스이 | 연속적 히드로포르밀화에서 촉매를 보충하는 방법 |
| EP3319951B1 (de) | 2015-07-10 | 2021-09-08 | Basf Se | Verfahren zur hydroformylierung von 2-substituierten butadienen und zur herstellung von folgeprodukten davon, speziell von ambrox |
| KR20180066076A (ko) | 2015-10-12 | 2018-06-18 | 바스프 에스이 | 1,6-이치환된 헥산 유도체를 제조하기 위한 히드로포르밀화 방법 |
| EP3638655A1 (en) | 2017-06-13 | 2020-04-22 | Basf Se | Hydroformylation process for producing 1,6-hexanediol derivatives |
| CN115066429A (zh) | 2020-02-11 | 2022-09-16 | 巴斯夫欧洲公司 | 二异丁烯的低压醛化 |
| WO2025170891A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Composition of matter for gas-stripping oxo aldehydes hydroformylation process |
| WO2025170897A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Optimized gas-stripping hydroformylation process for oxo aldehydes |
| WO2025170887A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Gas distribution in gas-stripping hydroformylation reactor for oxo aldehydes |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL146830C (es) * | 1960-07-22 | |||
| US3271458A (en) * | 1962-11-23 | 1966-09-06 | Exxon Research Engineering Co | Cooling and catalyst recycle in oxo synthesis |
| US3518319A (en) * | 1965-03-30 | 1970-06-30 | Exxon Research Engineering Co | Process for improving oxo selectivity to unbranched alcohols |
| US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| US4247486A (en) * | 1977-03-11 | 1981-01-27 | Union Carbide Corporation | Cyclic hydroformylation process |
| DE3114147A1 (de) * | 1981-04-08 | 1982-10-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur gewinnung von aldehyden |
| DE3234701A1 (de) * | 1982-09-18 | 1984-04-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3301591A1 (de) * | 1983-01-19 | 1984-07-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen |
| DE3341035A1 (de) * | 1983-11-12 | 1985-05-23 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| CA1259331A (en) * | 1984-03-30 | 1989-09-12 | Gregory J. Dembowski | Process for recovery of phosphorus ligand from vaporized aldehyde |
| DE3412336C2 (de) * | 1984-04-03 | 1994-03-31 | Hoechst Ag | Verfahren zur Hydroformylierung von Propylen |
-
1986
- 1986-07-25 DE DE19863625261 patent/DE3625261A1/de not_active Withdrawn
-
1987
- 1987-07-08 US US07/070,963 patent/US4778929A/en not_active Expired - Lifetime
- 1987-07-10 JP JP62171335A patent/JPS6335536A/ja active Pending
- 1987-07-14 DE DE8787110130T patent/DE3773780D1/de not_active Expired - Lifetime
- 1987-07-14 AT AT87110130T patent/ATE68462T1/de not_active IP Right Cessation
- 1987-07-14 EP EP87110130A patent/EP0254180B1/de not_active Expired - Lifetime
- 1987-07-14 ES ES198787110130T patent/ES2026491T3/es not_active Expired - Lifetime
- 1987-07-14 CA CA000541965A patent/CA1297130C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0254180A3 (en) | 1989-05-24 |
| CA1297130C (en) | 1992-03-10 |
| JPS6335536A (ja) | 1988-02-16 |
| EP0254180B1 (de) | 1991-10-16 |
| ATE68462T1 (de) | 1991-11-15 |
| EP0254180A2 (de) | 1988-01-27 |
| DE3625261A1 (de) | 1988-02-04 |
| DE3773780D1 (de) | 1991-11-21 |
| US4778929A (en) | 1988-10-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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