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ES2004488A4 - DICARBONIC ACID DIAMIDES, PROCEDURE FOR ITS PREPARATION, SODIUM COMPLEXES AND SELECTIVE PIECES OF IONS OF SUCH DIAMINS FOR THE DETERMINATION OF THE ION CONCENTRATION NA. - Google Patents

DICARBONIC ACID DIAMIDES, PROCEDURE FOR ITS PREPARATION, SODIUM COMPLEXES AND SELECTIVE PIECES OF IONS OF SUCH DIAMINS FOR THE DETERMINATION OF THE ION CONCENTRATION NA.

Info

Publication number
ES2004488A4
ES2004488A4 ES87114112T ES87114112T ES2004488A4 ES 2004488 A4 ES2004488 A4 ES 2004488A4 ES 87114112 T ES87114112 T ES 87114112T ES 87114112 T ES87114112 T ES 87114112T ES 2004488 A4 ES2004488 A4 ES 2004488A4
Authority
ES
Spain
Prior art keywords
sodium
determination
ions
diamins
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
ES87114112T
Other languages
Spanish (es)
Inventor
Wilhelm Simon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MOELLER WILLI AG
Moller Willi Firma
Original Assignee
MOELLER WILLI AG
Moller Willi Firma
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MOELLER WILLI AG, Moller Willi Firma filed Critical MOELLER WILLI AG
Publication of ES2004488A4 publication Critical patent/ES2004488A4/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416Systems
    • G01N27/4166Systems measuring a particular property of an electrolyte
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/333Ion-selective electrodes or membranes
    • G01N27/3335Ion-selective electrodes or membranes the membrane containing at least one organic component

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Immunology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Investigating Or Analysing Biological Materials (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE DESCRIBEN NUEVAS DIAMINAS DE ACIDOS DICARBONICOS DE FORMULA (I), QUE POSEEN UNA ELEVADA SELECTIVIDAD PARA LOS IONES SODIO FRENTE A OTROS IONES METALICOS ALCALINOS Y ALCALINOTERREOS. CON SU AYUDA PUEDEN PREPARARSE PIEZAS SELECTIVAS DE IONES DE GRAN SENSIBILIDAD PARA LA DETERMINACION DE IONES SODIO EN MEDIOS LIQUIDOS, POR EJEMPLO, MEMBRANAS SELECTIVAS DE SODIO O TIRAS PARA ENSAYO PARA LA DETERMINACION DE LA CONCENTRACION DE SODIO. LAS CORRESPONDIENTES MEMBRANAS SELECTIVAS DE SODIO TIENEN UNA LARGA VIDA EN SERVICIO AUNQUE SE APLIQUEN Y ENTREN EN CONTACTO CON SOLUCION QUE CONTENGAN PROTEINAS, COMO PUEDEN SER SUERO SANGUINEO O SANGRE COMPLETA. EN LA FORMULA (I) R SIGNIFICA HIDROGENO, ALQUILO, ALQUENILO O ALQUINILO CON 20 ATOMOS DE CARBONO COMO MAXIMO Y AMBOS RADICALES R JUNTO CON EL ATOMO DE C CON EL QUE ESTAN UNIDOS SON RADICALES CICLOALIFATICOS O AROMATICOS, PREDOMINANTEMENTE UN RADICAL FENILO, SUSTITUIDO EN SU CASO.NEW DIAMINES OF DICARBONIC ACIDS OF FORMULA (I) ARE DESCRIBED, WHICH HAVE HIGH SELECTIVITY FOR SODIUM IONS COMPARED TO OTHER ALKALINE AND ALKALINE EARTH METAL IONS. WITH THEIR HELP, ION SELECTIVE PARTS OF HIGH SENSITIVITY FOR THE DETERMINATION OF SODIUM IONS IN LIQUID MEDIA CAN BE PREPARED, FOR EXAMPLE, SODIUM SELECTIVE MEMBRANES OR TEST STRIPS FOR THE DETERMINATION OF SODIUM CONCENTRATION. THE CORRESPONDING SODIUM SELECTIVE MEMBRANES HAVE A LONG SERVICE LIFE EVEN IF THEY ARE APPLIED TO AND COME IN CONTACT WITH SOLUTIONS CONTAINING PROTEINS, SUCH AS BLOOD SERUM OR WHOLE BLOOD. IN FORMULA (I) R SIGNIFIES HYDROGEN, ALKYL, ALKENYL OR ALKYNYL WITH A MAXIMUM OF 20 CARBON ATOMS AND BOTH RADICALS R TOGETHER WITH THE C ATOM TO WHICH THEY ARE BONDED ARE CYCLOALIPHATIC OR AROMATIC RADICALS, PREDOMINANTLY A PHENYL RADICAL, SUBSTITUTED BY THEIR CASE.

ES87114112T 1986-10-01 1987-09-26 DICARBONIC ACID DIAMIDES, PROCEDURE FOR ITS PREPARATION, SODIUM COMPLEXES AND SELECTIVE PIECES OF IONS OF SUCH DIAMINS FOR THE DETERMINATION OF THE ION CONCENTRATION NA. Pending ES2004488A4 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH392786 1986-10-01

Publications (1)

Publication Number Publication Date
ES2004488A4 true ES2004488A4 (en) 1989-01-16

Family

ID=4266483

Family Applications (2)

Application Number Title Priority Date Filing Date
ES198787113937T Expired - Lifetime ES2004487T3 (en) 1986-10-01 1987-09-24 PROCEDURE TO DETERMINE THE RELATION BETWEEN THE CONCENTRATIONS OF LITHIUM IONS AND SODIUM IONS AND DEVICE FOR THE PERFORMANCE OF THIS PROCEDURE.
ES87114112T Pending ES2004488A4 (en) 1986-10-01 1987-09-26 DICARBONIC ACID DIAMIDES, PROCEDURE FOR ITS PREPARATION, SODIUM COMPLEXES AND SELECTIVE PIECES OF IONS OF SUCH DIAMINS FOR THE DETERMINATION OF THE ION CONCENTRATION NA.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES198787113937T Expired - Lifetime ES2004487T3 (en) 1986-10-01 1987-09-24 PROCEDURE TO DETERMINE THE RELATION BETWEEN THE CONCENTRATIONS OF LITHIUM IONS AND SODIUM IONS AND DEVICE FOR THE PERFORMANCE OF THIS PROCEDURE.

Country Status (6)

Country Link
US (1) US5167780A (en)
EP (2) EP0262582B1 (en)
JP (1) JPH07113620B2 (en)
AT (1) ATE82639T1 (en)
DE (1) DE3782715D1 (en)
ES (2) ES2004487T3 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2226411B (en) * 1988-12-21 1993-02-24 Forex Neptune Sa Monitoring drilling mud composition using ion selective electrodes
GB2226412B (en) * 1988-12-21 1993-04-28 Forex Neptune Sa Monitoring drilling mud compositions using flowing liquid junction electrodes
US5288678A (en) * 1990-10-19 1994-02-22 Beckman Instruments, Inc. Indirect potentiometric method and diluent for analysis of lithium
NL194838C (en) * 1991-05-17 2003-04-03 Priva Agro Holding Bv Metal ion-selective membrane and sensor including this membrane.
US5286365A (en) * 1992-01-15 1994-02-15 Beckman Instruments, Inc. Graphite-based solid state polymeric membrane ion-selective electrodes
FR2900064B1 (en) * 2006-04-24 2008-12-12 Electricite De France LITHIUM ION SELECTIVE MEMBRANE FOR MEASURING THE LITHIUM CONCENTRATION IN A FLUID SUCH AS THE PRIMARY COOLING SYSTEM FLUID OF A REACTOR OF A PRESSURIZED WATER NUCLEAR POWER PLANT
JP6127460B2 (en) * 2012-11-12 2017-05-17 オムロンヘルスケア株式会社 Electrochemical sensor
US20240125727A1 (en) * 2021-01-29 2024-04-18 Radiometer Medical Aps Electrochemical measurement with additional reference measurement
CN113991193B (en) * 2021-10-28 2023-10-03 华北电力大学 A secondary battery and its preparation method

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5825221B2 (en) * 1977-12-12 1983-05-26 株式会社クラレ FET reference electrode
US4214968A (en) * 1978-04-05 1980-07-29 Eastman Kodak Company Ion-selective electrode
US4452682A (en) * 1980-10-24 1984-06-05 Hitachi, Ltd. Apparatus for measuring clinical emergency check items of blood
US4409088A (en) * 1981-06-30 1983-10-11 Tokyo Shibaura Denki Kabushiki Kaisha Regeneration method of ion-selective electrode, and ion-selective electrode and ion-concentration analyzer containing means adapted to practice said method
JPS5938647A (en) * 1982-08-28 1984-03-02 Toshiba Corp Ion selective electrode apparatus and flowing type ion analytical apparatus
JPS59102154A (en) * 1982-12-06 1984-06-13 Olympus Optical Co Ltd Non-photosensitive type chemical responsive element
US4508613A (en) * 1983-12-19 1985-04-02 Gould Inc. Miniaturized potassium ion sensor
CH660481A5 (en) * 1984-09-13 1987-04-30 Moeller Willi Fa Cyclohexancarbonsaeurediamide and containing ion-selective membrane.

Also Published As

Publication number Publication date
EP0262633A3 (en) 1990-03-14
JPH07113620B2 (en) 1995-12-06
US5167780A (en) 1992-12-01
EP0262582A3 (en) 1990-01-17
EP0262582A2 (en) 1988-04-06
EP0262633A2 (en) 1988-04-06
DE3782715D1 (en) 1992-12-24
ATE82639T1 (en) 1992-12-15
EP0262582B1 (en) 1992-11-19
ES2004487A4 (en) 1989-01-16
JPS63277962A (en) 1988-11-15
ES2004487T3 (en) 1993-06-01

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