ES2002227A6 - Gallium production - Google Patents
Gallium productionInfo
- Publication number
- ES2002227A6 ES2002227A6 ES8603423A ES8603423A ES2002227A6 ES 2002227 A6 ES2002227 A6 ES 2002227A6 ES 8603423 A ES8603423 A ES 8603423A ES 8603423 A ES8603423 A ES 8603423A ES 2002227 A6 ES2002227 A6 ES 2002227A6
- Authority
- ES
- Spain
- Prior art keywords
- gallium
- dust
- organic phase
- chloride
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052733 gallium Inorganic materials 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 239000000428 dust Substances 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 abstract 2
- 239000012074 organic phase Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B58/00—Obtaining gallium or indium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A method of producing gallium from gallium-containing dust (e.g. dust which is recovered from gas collecting systems in plants for the electrolytic production of aluminium) comprises leaching the dust in an aqueous hydrochloric acid solution (e.g. at a temperature between 50 DEG and 120 DEG C) whereby gallium is leached as gallium chloride. Gallium chloride is thereafter selectively extracted from the leach solution by an organic phase consisting of substantially undiluted tri-n-butyl-phosphate, whereafter gallium is stripped from the organic phase by water or an alkaline solution e.g. of NaOH with a concentration of 0.1 to 3 M, preferably 1-2 M.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO854797A NO158028C (en) | 1985-12-16 | 1985-12-16 | GALLIUM EXTRACTION. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2002227A6 true ES2002227A6 (en) | 1988-07-16 |
Family
ID=19888611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8603423A Expired ES2002227A6 (en) | 1985-12-16 | 1986-12-15 | Gallium production |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS62156238A (en) |
| AU (1) | AU572412B2 (en) |
| BR (1) | BR8606230A (en) |
| CA (1) | CA1309869C (en) |
| DE (1) | DE3640381A1 (en) |
| ES (1) | ES2002227A6 (en) |
| FR (1) | FR2591582B1 (en) |
| GB (1) | GB2184108B (en) |
| NL (1) | NL8602997A (en) |
| NO (1) | NO158028C (en) |
| NZ (1) | NZ218419A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2624524B1 (en) * | 1987-11-24 | 1990-05-18 | Metaleurop Sa | METHOD FOR HYDROMETALLURGICAL TREATMENT OF GALLIFER MATERIAL SOLUTION |
| RU2232199C2 (en) * | 2001-11-13 | 2004-07-10 | Общество с ограниченной ответственностью "ВИКОР" | Method for extracting of gallium from sludge in aluminum production |
| RU2237740C1 (en) * | 2003-02-07 | 2004-10-10 | Открытое акционерное общество "Всероссийский алюминиево-магниевый институт" | Method of recovering gallium from solid gallium-containing materials |
| RU2319757C2 (en) * | 2005-10-28 | 2008-03-20 | Открытое акционерное общество "РУСАЛ ВСЕРОССИЙСКИЙ АЛЮМИНИЕВО-МАГНИЕВЫЙ ИНСТИТУТ "(ОАО "РУСАЛ ВАМИ") | Gallium extraction method from waste products of process for electrolytic refining of aluminum |
| CN100396804C (en) * | 2005-12-09 | 2008-06-25 | 韶关市华韦实业有限公司 | Technology for extracting Gallium metal from lead-zine tail ore slug smelting by extracting-electrolytic method |
| RU2340402C1 (en) * | 2007-04-02 | 2008-12-10 | Государственное образовательное учреждение высшего профессионального образования Читинский государственный университет (ЧитГУ) | Production line for extraction of rare and rare-earth elements from fly ash of thermal power plants |
| CN103276407B (en) * | 2013-05-13 | 2016-12-28 | 攀枝花学院 | A kind of from low-grade containing gallium, ferrum raw material reclaim gallium and the method for ferrum |
| CN113667839B (en) * | 2021-08-20 | 2022-06-28 | 安徽工业大学 | Method for recovering metal gallium from gallium nitride waste under normal pressure |
| CN115418478B (en) * | 2022-09-05 | 2023-08-01 | 山西大学 | A method for synergistically extracting aluminum-iron-lithium-gallium from high-alumina solid waste acidic system |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2848398A (en) * | 1955-05-11 | 1958-08-19 | Zh Sekitan Sogo Kenkyujo | Recovery of gallium compounds from the combustion gases of coal |
| GB991614A (en) * | 1960-08-27 | 1965-05-12 | Asahi Chemical Ind | Process for recovering gallium in the purification of crude alumina |
| GB991613A (en) * | 1960-11-28 | 1965-05-12 | Asahi Chemical Ind | Process for the recovery of gallium |
| DD127573A1 (en) * | 1976-09-06 | 1977-10-05 | ||
| FR2397464A2 (en) * | 1977-07-13 | 1979-02-09 | Rhone Poulenc Ind | PROCESS FOR RECOVERING GALLIUM FROM VERY BASIC SOLUTIONS BY LIQUID / LIQUID EXTRACTION |
| FR2411894A1 (en) * | 1977-12-15 | 1979-07-13 | Rhone Poulenc Ind | GALLIUM EXTRACTION PROCESS |
| FR2460276A1 (en) * | 1979-07-03 | 1981-01-23 | Rhone Poulenc Ind | PROCESS FOR TREATING RARE EARTH OXIDES AND GALLIUM MIXTURES |
| FI70693C (en) * | 1980-12-05 | 1986-10-06 | Rhone Poulenc Ind | FOERFARANDE FOER RENING AV EN GALLIUMLOESNING |
| JPS6058170B2 (en) * | 1982-12-17 | 1985-12-18 | 三井アルミニウム工業株式会社 | Method for recovering gallium from dust generated in an aluminum electrolytic furnace |
| JPS60166224A (en) * | 1984-02-03 | 1985-08-29 | Mitsui Alum Kogyo Kk | Method of recovery of gallium from dust of aluminum smelting |
-
1985
- 1985-12-16 NO NO854797A patent/NO158028C/en unknown
-
1986
- 1986-11-24 CA CA 523662 patent/CA1309869C/en not_active Expired - Lifetime
- 1986-11-25 NL NL8602997A patent/NL8602997A/en active Search and Examination
- 1986-11-26 DE DE19863640381 patent/DE3640381A1/en active Granted
- 1986-11-27 NZ NZ21841986A patent/NZ218419A/en unknown
- 1986-11-28 FR FR8616649A patent/FR2591582B1/en not_active Expired
- 1986-12-15 ES ES8603423A patent/ES2002227A6/en not_active Expired
- 1986-12-16 GB GB8629961A patent/GB2184108B/en not_active Expired
- 1986-12-16 JP JP61297860A patent/JPS62156238A/en active Granted
- 1986-12-16 BR BR8606230A patent/BR8606230A/en unknown
- 1986-12-16 AU AU66588/86A patent/AU572412B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JPS642654B2 (en) | 1989-01-18 |
| NO158028C (en) | 1988-06-29 |
| AU572412B2 (en) | 1988-05-05 |
| DE3640381A1 (en) | 1987-06-04 |
| CA1309869C (en) | 1992-11-10 |
| GB2184108B (en) | 1989-10-18 |
| NO158028B (en) | 1988-03-21 |
| BR8606230A (en) | 1987-09-29 |
| FR2591582A1 (en) | 1987-06-19 |
| FR2591582B1 (en) | 1988-07-01 |
| NO854797L (en) | 1987-06-01 |
| GB8629961D0 (en) | 1987-01-28 |
| NZ218419A (en) | 1989-04-26 |
| JPS62156238A (en) | 1987-07-11 |
| GB2184108A (en) | 1987-06-17 |
| AU6658886A (en) | 1987-06-25 |
| NL8602997A (en) | 1987-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SA6 | Expiration date (snapshot 920101) |
Free format text: 2006-12-15 |
|
| FD1A | Patent lapsed |
Effective date: 19931216 |