ES2099844T3 - Dispersion acuosa de particulas compuestas que incluyen un latex polimerico. - Google Patents
Dispersion acuosa de particulas compuestas que incluyen un latex polimerico.Info
- Publication number
- ES2099844T3 ES2099844T3 ES92924377T ES92924377T ES2099844T3 ES 2099844 T3 ES2099844 T3 ES 2099844T3 ES 92924377 T ES92924377 T ES 92924377T ES 92924377 T ES92924377 T ES 92924377T ES 2099844 T3 ES2099844 T3 ES 2099844T3
- Authority
- ES
- Spain
- Prior art keywords
- particles
- polymeric latex
- pigment
- latex
- strong
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004816 latex Substances 0.000 title abstract 6
- 239000002245 particle Substances 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 title 1
- 239000006185 dispersion Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- 239000000049 pigment Substances 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 3
- 230000002745 absorbent Effects 0.000 abstract 2
- 239000002250 absorbent Substances 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 239000010954 inorganic particle Substances 0.000 abstract 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3676—Treatment with macro-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
- C09D17/008—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
PARTICULAS DE MATERIAL INORGANICO TAL COMO EL DIOXIDO DE TITANIO (10) Y PARTICULAS DE PIGMENTO (12) SE DISPERSAN EN UN MEDIO ACUOSO CON UN DISPERSANTE POLIELECTROLITICO DE PIGMENTO (20). SE AÑADE UN LATEX POLIMERICO (40) RELATIVAMENTE DURO SELECCIONADO, QUE ABSORBE SOBRE LA SUPERFICIE DEL MATERIAL ORGANICO PARTICULAS EN PRESENCIA DEL DISPERSANTE DE PIGMENTO, ASI COMO UN AGLUTINANTE FORMADOR DE PELICULA (64) PARA DAR UNA COMPOSICION DE REVESTIMIENTO FORMULADA. EL LATEX POLIMERICO FUERTEMENTE ABSORBENTE PUEDE INCLUIR RESIDUOS DE ACIDO ITACONICO POLIMERIZADO O GRUPOS FUNCIONALES DE FOSFATO DE DIHIDROGENO, O TIENE UN NIVEL ELEVADO DE GRUPOS FUNCIONALES ACIDO O GRUPOS FUNCIONALES ACIDOS DISTRIBUIDOS PREFERENTEMENTE EN LA SUPERFICIE DEL LATEX. LAS PARTICULAS DE LATEX ABSORBIDAS SEPARAN LAS PARTICULAS INORGANICAS DE LA PELICULA DE REVESTIMIENTO (60), MEJORANDO LAS PROPIEDADES DE RENDIMIENTO. ALTERNATIVAMENTE, SE EMPLEA UN LATEX POLIMERICO SIMPLE SELECCIONADO PARA ABSORBER FUERTEMENTE LAS PARTICULAS DE PIGMENTO Y PARA ENLAZAR, O SE EMPLEA UNA MEZCLA DE UN LATEX POLIMERICO FUERTEMENTE ABSORBENTE QUE TIENE UNA BAJA TEMPERATURA DE TRANSICION A VIDRIO Y UN LATEX DE ENLACE CONVENCIONAL.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80197591A | 1991-12-03 | 1991-12-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2099844T3 true ES2099844T3 (es) | 1997-06-01 |
Family
ID=25182503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92924377T Expired - Lifetime ES2099844T3 (es) | 1991-12-03 | 1992-11-12 | Dispersion acuosa de particulas compuestas que incluyen un latex polimerico. |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0615534B1 (es) |
| JP (1) | JPH07508541A (es) |
| CN (1) | CN1043046C (es) |
| AU (1) | AU671963B2 (es) |
| BR (1) | BR9206867A (es) |
| CA (1) | CA2124960A1 (es) |
| DE (1) | DE69219149T2 (es) |
| ES (1) | ES2099844T3 (es) |
| IL (1) | IL103859A (es) |
| MX (1) | MX9206912A (es) |
| MY (1) | MY109852A (es) |
| NZ (1) | NZ245246A (es) |
| TW (1) | TW272209B (es) |
| WO (1) | WO1993012183A1 (es) |
| ZA (1) | ZA929301B (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5385960A (en) * | 1991-12-03 | 1995-01-31 | Rohm And Haas Company | Process for controlling adsorption of polymeric latex on titanium dioxide |
| BR9206868A (pt) * | 1991-12-03 | 1995-11-21 | Rohm & Haas | Processo para formar uma suspensão de partículas compósitas discretas,suspensão,e,partícula multi-compósita discreta |
| GB9127293D0 (en) * | 1991-12-23 | 1992-02-19 | Ici Plc | Coating pigment particles with polymers |
| ATE174612T1 (de) * | 1994-09-08 | 1999-01-15 | Tioxide Group Services Ltd | Wässrige lackzusammensetzungen |
| GB9500497D0 (en) * | 1995-01-11 | 1995-03-01 | Tioxide Group Services Ltd | Gloss emulsion paints |
| GB9602221D0 (en) * | 1996-02-03 | 1996-04-03 | Tioxide Group Services Ltd | Composite pigmentary material |
| GB9502982D0 (en) * | 1995-02-16 | 1995-04-05 | Tioxide Group Services Ltd | Composite pigmentary material |
| GB9504962D0 (en) * | 1995-03-11 | 1995-04-26 | Tioxide Group Services Ltd | Composite pigmentary material |
| JPH11133539A (ja) * | 1997-10-27 | 1999-05-21 | Fuji Photo Film Co Ltd | 熱現像感光材料 |
| US6214467B1 (en) | 1998-07-24 | 2001-04-10 | Rohm And Haas Company | Polymer-pigment composites |
| US6110636A (en) * | 1998-10-29 | 2000-08-29 | Xerox Corporation | Polyelectrolyte toner processes |
| AU782594B2 (en) * | 2000-11-21 | 2005-08-11 | Rohm And Haas Company | Polymer-pigment composites |
| DE60319202T2 (de) | 2002-12-19 | 2009-02-12 | Rohm & Haas Company | Pigmentationspolymerzusammensetzung |
| JP2005054166A (ja) * | 2003-08-01 | 2005-03-03 | Rohm & Haas Co | コーティング組成物 |
| EP1582567B2 (en) * | 2004-04-01 | 2011-11-16 | Rohm And Haas Company | Aqueous coating composition |
| FR2873127B1 (fr) | 2004-07-13 | 2008-08-29 | Omya Development Ag | Procede de fabrication de particules pigmentaires autoliantes, seches ou en suspension ou dispersion aqueuses, contenant des matieres inorganiques et des liants |
| US7642309B2 (en) | 2004-08-09 | 2010-01-05 | Behr Process Corporation | Exterior paint formulation |
| US7947763B2 (en) | 2004-08-09 | 2011-05-24 | Behr Process Corporation | Exterior deep base paint formulation |
| US7482054B2 (en) | 2004-08-09 | 2009-01-27 | Behr Process Corporation | Pigment spacing |
| DE102004054048A1 (de) * | 2004-11-05 | 2006-05-11 | Basf Ag | Beschichtungsmassen |
| AU2005303977B2 (en) * | 2004-11-12 | 2010-05-13 | Omya International Ag | Aqueous paper coating slip containing pigment-polymer hybrids |
| US7858154B2 (en) | 2004-11-12 | 2010-12-28 | Basf Aktiengesellschaft | Paper coating slip based on pigment-polymer hybrids |
| US7417086B2 (en) | 2004-11-29 | 2008-08-26 | Rohm And Haas Company | Coating compositions |
| NZ553410A (en) | 2006-03-02 | 2008-06-30 | Rohm & Haas | Scrub and stain-resistant copolymer coating composition |
| TWM307805U (en) | 2006-06-23 | 2007-03-11 | Genesys Logic Inc | Multi-interface converting device |
| US9238747B2 (en) | 2008-11-17 | 2016-01-19 | Basf Se | Stain blocking compositions |
| JP5580860B2 (ja) * | 2011-10-14 | 2014-08-27 | ローム アンド ハース カンパニー | 着色塗料における隠蔽効率を向上させる方法 |
| CA2873736C (en) * | 2012-05-06 | 2021-02-16 | Ethox Chemicals, Llc | Method for improving the effectiveness of titanium dioxide-containing coatings |
| WO2014093412A1 (en) * | 2012-12-13 | 2014-06-19 | Dow Global Technologies Llc | Amphoteric polymer particles and compositions thereof |
| US10208428B2 (en) * | 2013-06-17 | 2019-02-19 | Encapsys, Llc | Coated paper |
| US9809725B2 (en) * | 2013-06-17 | 2017-11-07 | Encapsys, Llc | Paint with encapsulated solid particles |
| CN104558431B (zh) | 2013-10-28 | 2018-05-18 | 广东华润涂料有限公司 | 水性胶乳以及包含该水性胶乳的无机颜料颗粒的分散体 |
| US10167393B2 (en) | 2014-07-28 | 2019-01-01 | Dow Global Technologies Llc | Poly(vinyl acetate) dispersion, and a paint formulation comprising thereof |
| JP2019536840A (ja) | 2016-10-07 | 2019-12-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 二酸化チタン顔料を含有するラテックス塗料 |
| EP3523381B1 (en) * | 2016-10-07 | 2020-12-09 | Basf Se | Latex paint containing titanium dioxide pigment |
| MY198073A (en) * | 2019-11-07 | 2023-07-31 | Kossan Sdn Bhd | Polymeric/inorganic composite particle formulation and methods of producing rubber articles using said formulation |
| CN113318600A (zh) * | 2021-03-19 | 2021-08-31 | 苏州苏瑞膜纳米科技有限公司 | 一种反渗透膜组件用浓水网及其制备方法与应用 |
| CN114410131B (zh) * | 2021-12-14 | 2023-06-06 | 河南河大纳米材料工程研究中心有限公司 | 一种水相速溶二氧化钛材料及其制备方法和应用 |
| CN119371691B (zh) * | 2024-10-25 | 2025-05-23 | 安徽伟豪特种玻璃有限公司 | 一种有机/无机杂化纳米材料、防火预反应液及其制备方法与应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL161769C (nl) * | 1975-09-25 | 1980-03-17 | Synres Internationaal Nv | Werkwijze voor de bereiding van stabiele waterige emulsies van additiepolymeren en copolymeren. |
| US4025483A (en) * | 1975-10-06 | 1977-05-24 | Scm Corporation | Stabilizing aqueous titanium dioxide pigment slurries by blending therewith plastic particles |
| US4421660A (en) * | 1980-12-15 | 1983-12-20 | The Dow Chemical Company | Colloidal size hydrophobic polymers particulate having discrete particles of an inorganic material dispersed therein |
| CA1226400A (en) * | 1982-12-09 | 1987-09-01 | Philip M. Smith | Opacification of paint |
| GB8808755D0 (en) * | 1988-04-13 | 1988-05-18 | Crown Decorative Prod Ltd | Aqueous surface coatings |
| DE3932816A1 (de) * | 1989-09-30 | 1991-04-11 | Hoechst Ag | Verwendung von vernetzten polymermikroteilchen in lacken als fuellstoffersatz und/oder als vernetzender fuellstoff |
-
1992
- 1992-11-12 ES ES92924377T patent/ES2099844T3/es not_active Expired - Lifetime
- 1992-11-12 DE DE69219149T patent/DE69219149T2/de not_active Expired - Lifetime
- 1992-11-12 EP EP92924377A patent/EP0615534B1/en not_active Expired - Lifetime
- 1992-11-12 CA CA002124960A patent/CA2124960A1/en not_active Abandoned
- 1992-11-12 JP JP5510901A patent/JPH07508541A/ja active Pending
- 1992-11-12 BR BR9206867A patent/BR9206867A/pt not_active IP Right Cessation
- 1992-11-12 WO PCT/US1992/009648 patent/WO1993012183A1/en not_active Ceased
- 1992-11-12 AU AU30707/92A patent/AU671963B2/en not_active Expired
- 1992-11-24 IL IL10385992A patent/IL103859A/en not_active IP Right Cessation
- 1992-11-24 NZ NZ245246A patent/NZ245246A/en unknown
- 1992-11-25 MY MYPI92002150A patent/MY109852A/en unknown
- 1992-12-01 MX MX9206912A patent/MX9206912A/es unknown
- 1992-12-01 ZA ZA929301A patent/ZA929301B/xx unknown
- 1992-12-03 CN CN92113743A patent/CN1043046C/zh not_active Expired - Lifetime
-
1993
- 1993-02-05 TW TW082100766A patent/TW272209B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2124960A1 (en) | 1993-06-24 |
| EP0615534A1 (en) | 1994-09-21 |
| ZA929301B (en) | 1993-06-16 |
| CN1043046C (zh) | 1999-04-21 |
| TW272209B (es) | 1996-03-11 |
| AU671963B2 (en) | 1996-09-19 |
| WO1993012183A1 (en) | 1993-06-24 |
| EP0615534B1 (en) | 1997-04-16 |
| JPH07508541A (ja) | 1995-09-21 |
| NZ245246A (en) | 1995-07-26 |
| AU3070792A (en) | 1993-07-19 |
| DE69219149D1 (de) | 1997-05-22 |
| IL103859A0 (en) | 1993-04-04 |
| MY109852A (en) | 1997-09-30 |
| IL103859A (en) | 1996-10-16 |
| CN1072936A (zh) | 1993-06-09 |
| MX9206912A (es) | 1993-06-01 |
| BR9206867A (pt) | 1995-11-21 |
| DE69219149T2 (de) | 1997-10-02 |
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