ES2075655T3 - STRIPPING PROCEDURE OF A SWEET STEEL MATERIAL AND STRIPPING BATH. - Google Patents
STRIPPING PROCEDURE OF A SWEET STEEL MATERIAL AND STRIPPING BATH.Info
- Publication number
- ES2075655T3 ES2075655T3 ES92403104T ES92403104T ES2075655T3 ES 2075655 T3 ES2075655 T3 ES 2075655T3 ES 92403104 T ES92403104 T ES 92403104T ES 92403104 T ES92403104 T ES 92403104T ES 2075655 T3 ES2075655 T3 ES 2075655T3
- Authority
- ES
- Spain
- Prior art keywords
- stripping
- pickling
- bath
- temperature
- steel material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 3
- 238000005554 pickling Methods 0.000 abstract 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000001117 sulphuric acid Substances 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- -1 Fe(II) ions Chemical class 0.000 abstract 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/081—Iron or steel solutions containing H2SO4
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Process for pickling a material made of mild steel, consisting in removing the scale formed during a conversion operation with heating by immersing the said material at a specified temperature in a pickling bath comprising a sulphuric acid/hydrochloric acid mixture and Fe(II) ions, characterised in that a pair of sulphuric acid concentration A and of hydrochloric acid concentration B is determined, giving an optimum pickling time for at least one Fe(II) ion concentration and at least one temperature, which are determined, the optimum pickling time being obtained as an optimised response by the simplex method, by comparing the values obtained for the pickling time for successive values of A and B, A and B being considered as variables, while the Fe(II) ion concentration and the temperature are constant. The invention also relates to a pickling bath and to a plant for making use of the process of the invention.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR919114309A FR2683832B1 (en) | 1991-11-20 | 1991-11-20 | PROCESS FOR STRIPPING MIXED STEEL MATERIAL, ESPECIALLY SHEETS, BATH AND STRIPPING INSTALLATION. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2075655T3 true ES2075655T3 (en) | 1995-10-01 |
Family
ID=9419144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92403104T Expired - Lifetime ES2075655T3 (en) | 1991-11-20 | 1992-11-18 | STRIPPING PROCEDURE OF A SWEET STEEL MATERIAL AND STRIPPING BATH. |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0543729B1 (en) |
| JP (1) | JP3135720B2 (en) |
| KR (1) | KR930010233A (en) |
| AT (1) | ATE125578T1 (en) |
| CA (1) | CA2083337C (en) |
| DE (1) | DE69203698T2 (en) |
| ES (1) | ES2075655T3 (en) |
| FR (1) | FR2683832B1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294295C (en) * | 2004-05-17 | 2007-01-10 | 文锐君 | Hot-rolling steel plate cleaning agent |
| RU2415201C1 (en) * | 2009-10-23 | 2011-03-27 | Станислав Алексеевич Суворов | Agent for removal of corrosion products off surface of metals |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE429590A (en) * | 1937-08-21 | |||
| US2927871A (en) * | 1956-03-26 | 1960-03-08 | Bethlehem Steel Corp | Control of pickling baths |
| US3074277A (en) * | 1958-03-20 | 1963-01-22 | Inland Steel Co | Method and apparatus for automatic control of acid concentration in pickling system |
| GB1362910A (en) * | 1971-06-30 | 1974-08-07 | Ibm | Data processing system for finding optimum integer-valued solutions of linear programmes |
| WO1982000836A1 (en) * | 1980-09-09 | 1982-03-18 | Niklasson R | A method of controlling or regulating the composition of pickling bath solutions for acid pickling metallic materials |
| SU1135807A1 (en) * | 1983-07-29 | 1985-01-23 | Днепропетровский Металлургический Институт Им.Л.И.Брежнева | Solution for removing scale from metal surface |
| SU1310773A1 (en) * | 1986-02-10 | 1987-05-15 | Кузнецкий металлургический комбинат им.В.И.Ленина | System for automatic optimizing |
| DD265029A1 (en) * | 1987-11-25 | 1989-02-15 | Dresden Forschzentr Mikroelek | METHOD FOR LASER INTERFEROMETRIC CONTROL OF THE DEPTH IN PLASMA-RELATED PROCESSES |
-
1991
- 1991-11-20 FR FR919114309A patent/FR2683832B1/en not_active Expired - Fee Related
-
1992
- 1992-11-18 EP EP92403104A patent/EP0543729B1/en not_active Expired - Lifetime
- 1992-11-18 ES ES92403104T patent/ES2075655T3/en not_active Expired - Lifetime
- 1992-11-18 DE DE69203698T patent/DE69203698T2/en not_active Expired - Fee Related
- 1992-11-18 AT AT92403104T patent/ATE125578T1/en not_active IP Right Cessation
- 1992-11-19 KR KR1019920021821A patent/KR930010233A/en not_active Withdrawn
- 1992-11-19 CA CA002083337A patent/CA2083337C/en not_active Expired - Fee Related
- 1992-11-20 JP JP04312142A patent/JP3135720B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE125578T1 (en) | 1995-08-15 |
| KR930010233A (en) | 1993-06-22 |
| CA2083337A1 (en) | 1993-05-21 |
| EP0543729A1 (en) | 1993-05-26 |
| CA2083337C (en) | 2002-12-31 |
| DE69203698T2 (en) | 1996-03-21 |
| EP0543729B1 (en) | 1995-07-26 |
| DE69203698D1 (en) | 1995-08-31 |
| FR2683832B1 (en) | 1994-03-04 |
| JPH05239675A (en) | 1993-09-17 |
| FR2683832A1 (en) | 1993-05-21 |
| JP3135720B2 (en) | 2001-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69328139D1 (en) | Process for pickling and passivating stainless steel without using nitric acid | |
| ATE129753T1 (en) | METHOD FOR PICKLING AND PASSIVING STAINLESS STEEL WITHOUT USING NITRIC ACID. | |
| DE59207657D1 (en) | Control parameter improvement process for industrial plants | |
| ES2080372T3 (en) | PROCEDURE FOR STRIPPING STEEL BASED METAL MATERIALS. | |
| ATE76664T1 (en) | PROCESSES FOR CHEMICAL REMOVAL AND PICKLING OF COPPER RODS. | |
| US4415415A (en) | Method of controlling oxide scale formation and descaling thereof from metal articles | |
| ES2075655T3 (en) | STRIPPING PROCEDURE OF A SWEET STEEL MATERIAL AND STRIPPING BATH. | |
| US4824536A (en) | Method for processing cold-rolled stainless-steel sheet and strip | |
| ATE131539T1 (en) | METHOD FOR PRODUCING HIGHLY BREAK-RESISTANT PRODUCTS FROM UNSTABLE AUSTENITIC STEEL AND PRODUCTS PRODUCED THEREFORE | |
| ATE151819T1 (en) | METHOD FOR CONTINUOUS PICKLING OF STEEL MATERIAL IN A TREATMENT LINE | |
| NO840454L (en) | METHOD AND APPARATUS FOR MANUFACTURING AMMONIUM NITRATE | |
| Mysson et al. | A Process for the Pickling of Mild Steel Material, Bath and Pickling Facility | |
| ES8304889A1 (en) | Process for the regeneration of condensate from urea production plants. | |
| JPS5779158A (en) | Heat treatment of thin strip of amorphous magnetic alloy | |
| ATE62278T1 (en) | HEAT TREATMENT PROCESS AND APPARATUS FOR PRODUCTION OF READY-TO-USE ALLOY STEEL BARS. | |
| JPS57149421A (en) | Manufacture of surface decarburized steel excellent in resistance to stress corrosion cracking by sulfide and ammonium | |
| DE59103782D1 (en) | Process for the production of bright round steel. | |
| ATE24424T1 (en) | PROCESS FOR THERMOMECHANICAL TREATMENT IN CONTINUOUS HOT ROLLING OF ROLLED STEEL. | |
| JPS64288A (en) | Method for descaling hot rolled chromium stainless steel strip | |
| ES8202065A1 (en) | Removing oxide scale from surface of stainless steel | |
| JPS56133478A (en) | Descaling method for stainless steel | |
| GB2014978A (en) | Removal of ammonia from sludge liquor | |
| Mironenko | Investigation of the Process of Aging Stainless Maraging Steel 03 Kh 11 N 10 M 2 T Using an Experiment Planning Method | |
| JPS5669323A (en) | Direct heating method and apparatus for hoop | |
| Grigorevsky et al. | A mathematical model for crystallization of carbonate systems of deposits from real aqueous solutions. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
Ref document number: 543729 Country of ref document: ES |