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ES2066834T3 - Hidrogeles a base de monomeros que contienen fluor y monomeros de sacarido. - Google Patents

Hidrogeles a base de monomeros que contienen fluor y monomeros de sacarido.

Info

Publication number
ES2066834T3
ES2066834T3 ES89123225T ES89123225T ES2066834T3 ES 2066834 T3 ES2066834 T3 ES 2066834T3 ES 89123225 T ES89123225 T ES 89123225T ES 89123225 T ES89123225 T ES 89123225T ES 2066834 T3 ES2066834 T3 ES 2066834T3
Authority
ES
Spain
Prior art keywords
monomers
moles
suction
fluorine containing
hydrogels based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89123225T
Other languages
English (en)
Inventor
Gerhard Prof Dr Kossmehl
Horst Dr Schafer
Norbert Klaus
Jurgen Volkheimer
Madjid Rezaii-Djafari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of ES2066834T3 publication Critical patent/ES2066834T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F251/00Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/26Esters containing oxygen in addition to the carboxy oxygen
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041Lenses
    • G02B1/043Contact lenses

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials For Medical Uses (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Prostheses (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Colloid Chemistry (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Eyeglasses (AREA)

Abstract

EL INVENTO SE REFIERE A UN HIDROGEL, EL CUAL ES UN COPOLIMERO DE UNA MEZCLA POLIMERIZABLE DE MONOMERO, QUE CONTIENE: A) 2-85 MOLES % DE UN MONOMERO VINILICO HIDROFOBO, CON AL MENOS TRES ATOMOS DE FLUOR, B) 2-80 MOLES % DE UN MONOMERO DE POLI-HIDROXIVINILO HIDROFOBO, CUYOS GRUPOS HIDROXI SE ENCUENTRAN PROTEGIDOS, C) 2-70 MOLES % DE UN MONOMERO VINILICO HIDROFILO Y D) 0-5 MOLES % DE UN HUMECTANTE REFERIDO A LA CANTIDAD TOTAL DE LOS MONOMEROS A) Y C), EN CUYO HIDROGEL LOS GRUPOS HIDROXI DE LOS SEGMENTOS FORMADOS POR LOS MONOMEROS B) SE ENCUENTRAN EN FORMA PROTEGIDA O EN LIBERTAD
ES89123225T 1988-12-19 1989-12-15 Hidrogeles a base de monomeros que contienen fluor y monomeros de sacarido. Expired - Lifetime ES2066834T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3842752 1988-12-19

Publications (1)

Publication Number Publication Date
ES2066834T3 true ES2066834T3 (es) 1995-03-16

Family

ID=6369551

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89123225T Expired - Lifetime ES2066834T3 (es) 1988-12-19 1989-12-15 Hidrogeles a base de monomeros que contienen fluor y monomeros de sacarido.

Country Status (11)

Country Link
US (1) US5155194A (es)
EP (1) EP0374752B1 (es)
JP (1) JPH02229814A (es)
AT (1) ATE117699T1 (es)
AU (1) AU631162B2 (es)
CA (1) CA2005659A1 (es)
DE (1) DE58908944D1 (es)
DK (1) DK642189A (es)
ES (1) ES2066834T3 (es)
IE (1) IE64998B1 (es)
PT (1) PT92608B (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470931A (en) * 1990-12-07 1995-11-28 Hawaiian Sugar Planters' Association Thermostable polymers from 1',2',3,3',4,4',6,6'-octa-O-allylsucrose
IL109221A (en) * 1993-04-12 1998-04-05 Johnson & Johnson Vision Prod Polymeric ophthalmic lens with crosslinker containing saccharide residue
US5665840A (en) * 1994-11-18 1997-09-09 Novartis Corporation Polymeric networks from water-soluble prepolymers
JP2967093B2 (ja) * 1995-02-23 1999-10-25 ホーヤ株式会社 軟性眼内レンズ
EP0892297A4 (en) * 1997-01-23 2001-08-29 Menicon Co Ltd PROCESS FOR PRODUCING CONTACT LENSES WITH HYDROPHILIC SURFACE AND CONTACT LENS THUS OBTAINED
US6018033A (en) * 1997-05-13 2000-01-25 Purdue Research Foundation Hydrophilic, hydrophobic, and thermoreversible saccharide gels and forms, and methods for producing same
WO1998058686A1 (en) * 1997-06-24 1998-12-30 SCA Mölnlycke AB Absorbent polymer material based on renewable starting materials
TW494125B (en) * 1997-07-11 2002-07-11 Rohm And Haas Compary Preparation of fluorinated polymers
AU9326598A (en) * 1997-11-24 1999-06-10 Johnson & Johnson Vision Products, Inc. Polymeric ophthalmic lens with crosslinker containing saccharide residue
US6500481B1 (en) 1998-06-11 2002-12-31 Johnson & Johnson Vision Care, Inc. Biomedical devices with amid-containing coatings
US6478423B1 (en) 1999-10-12 2002-11-12 Johnson & Johnson Vison Care, Inc. Contact lens coating selection and manufacturing process
JP2005531648A (ja) 2002-04-11 2005-10-20 カルボマー インク 生体適合性物質およびプローブ類
ES2319042B1 (es) * 2007-05-25 2010-02-12 Universidad Del Pais Vasco Microgeles biocompatibles y sus aplicaciones.
DE102008002375A1 (de) 2008-06-12 2009-12-17 Evonik Röhm Gmbh Hydrogel basierend auf silikonhaltigen Copolymeren
US8940337B2 (en) 2009-12-30 2015-01-27 Axcelon Biopolymers Corporation Transparent bacterial cellulose nanocomposite hydrogels
TWI599813B (zh) 2010-07-30 2017-09-21 諾華公司 水合隱形鏡片
SG11201400228WA (en) 2011-10-12 2014-05-29 Novartis Ag Method for making uv-absorbing ophthalmic lenses by coating
CA2862531C (en) * 2012-01-25 2020-08-11 The University Of Akron Fluorinated polymerizable hydrogels for wound dressings and methods of making same
MY172901A (en) 2012-12-17 2019-12-13 Alcon Inc Method for making improved uv-absorbing ophthalmic lenses
US9708087B2 (en) 2013-12-17 2017-07-18 Novartis Ag Silicone hydrogel lens with a crosslinked hydrophilic coating
US11002884B2 (en) 2014-08-26 2021-05-11 Alcon Inc. Method for applying stable coating on silicone hydrogel contact lenses
EP3391101B1 (en) 2015-12-15 2020-07-08 Alcon Inc. Method for applying stable coating on silicone hydrogel contact lenses
US10941311B2 (en) * 2016-04-28 2021-03-09 Nof Corporation Polyoxyethylene compound having multiple hydroxyl groups at end, and contact lens
KR102735112B1 (ko) 2017-12-13 2024-11-28 알콘 인코포레이티드 한 주 및 한 달 착용용 워터 그래디언트 콘택트 렌즈
CN114989344B (zh) * 2022-06-14 2023-09-19 万华化学集团股份有限公司 一种偏氟乙烯共聚物及其制备方法和在锂离子电池中的应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3654244A (en) * 1970-03-16 1972-04-04 Us Agriculture Polymers for soil-release textile finishes
US3808179A (en) * 1972-06-16 1974-04-30 Polycon Laboratories Oxygen-permeable contact lens composition,methods and article of manufacture
US3989656A (en) * 1972-07-06 1976-11-02 Karme Company Ltd. Dextran-alkyl methacrylate graft composition for contact lens and corneas
JPS543738B2 (es) * 1974-05-27 1979-02-26
US4130706A (en) * 1977-08-08 1978-12-19 E. I. Du Pont De Nemours And Company Hydrophilic, oxygen permeable contact lens
CA1187645A (en) * 1981-01-12 1985-05-21 Kyoichi Tanaka Contact lens and process for preparing the same
AU550604B2 (en) * 1981-05-01 1986-03-27 Menicon Co., Ltd Water absorptive contact lens
JPS5817412A (ja) * 1981-07-24 1983-02-01 Toyo Contact Lens Co Ltd 親水性の表面を有する硬質コンタクトレンズの製造方法
DE3273355D1 (en) * 1982-07-30 1986-10-23 Hoya Corp Soft contact lens
US4638040A (en) * 1983-06-03 1987-01-20 Minnesota Mining And Manufacturing Company Acrylate and methacrylate monomers and polymers
GB8422950D0 (en) * 1984-09-11 1984-10-17 Warne K J Hydrogel
JPS61126052A (ja) * 1984-11-20 1986-06-13 Green Cross Corp:The 含フツ素メタクリル酸エステル
DE3588053D1 (de) * 1984-12-18 1995-10-12 Tr Dev Ltd Hydrogelformende Polymere.
JPS62123425A (ja) * 1985-08-02 1987-06-04 Sharp Corp 液晶表示素子
US4996275A (en) * 1985-10-11 1991-02-26 Polymer Technology Corporation Fluorine containing polymeric compositions useful in contact lenses
US4686267A (en) * 1985-10-11 1987-08-11 Polymer Technology Corporation Fluorine containing polymeric compositions useful in contact lenses
JPH0629918B2 (ja) * 1986-03-03 1994-04-20 株式会社サンコンタクトレンズ 酸素透過性コンタクトレンズ材料
US4990582A (en) * 1986-07-18 1991-02-05 Salamone Joseph C Fluorine containing soft contact lens hydrogels
WO1988005060A1 (en) * 1987-01-07 1988-07-14 Chang Sing Hsiung Wettable, hydrophilic, soft and oxygen permeable copolymer compositions
AU618817B2 (en) * 1988-07-05 1992-01-09 Novartis Ag Dimethylacrylamide-copolymer hydrogels with high oxygen permeability

Also Published As

Publication number Publication date
IE894066L (en) 1990-06-19
EP0374752A2 (de) 1990-06-27
AU631162B2 (en) 1992-11-19
AU4687689A (en) 1990-06-21
US5155194A (en) 1992-10-13
CA2005659A1 (en) 1990-06-19
EP0374752B1 (de) 1995-01-25
DE58908944D1 (de) 1995-03-09
PT92608A (pt) 1990-06-29
ATE117699T1 (de) 1995-02-15
PT92608B (pt) 1995-09-12
DK642189D0 (da) 1989-12-18
JPH02229814A (ja) 1990-09-12
DK642189A (da) 1990-06-20
EP0374752A3 (de) 1991-08-28
IE64998B1 (en) 1995-10-04

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