ES2065837A1 - Process for manufacture of commercial-grade phosphoric acid containing a very low cadmium content - Google Patents
Process for manufacture of commercial-grade phosphoric acid containing a very low cadmium contentInfo
- Publication number
- ES2065837A1 ES2065837A1 ES09300202A ES9300202A ES2065837A1 ES 2065837 A1 ES2065837 A1 ES 2065837A1 ES 09300202 A ES09300202 A ES 09300202A ES 9300202 A ES9300202 A ES 9300202A ES 2065837 A1 ES2065837 A1 ES 2065837A1
- Authority
- ES
- Spain
- Prior art keywords
- phosphoric acid
- commercial
- manufacture
- cadmium content
- acid containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 3
- 229910052793 cadmium Inorganic materials 0.000 title abstract 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052925 anhydrite Inorganic materials 0.000 abstract 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/2343—Concentration concomitant with purification, e.g. elimination of fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Luminescent Compositions (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The invention relates to a process for the manufacture of phosphoric acid via wet route, which consists in reducing the cadmium in the phosphoric acid by its coprecipitation in the anhydrite formed in a reactor/evaporator governed by appropriate thermodynamic and kinetic conditions. The commercial-grade acid obtained after separation by settling has a low cadmium content.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MA22703 | 1992-02-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2065837A1 true ES2065837A1 (en) | 1995-02-16 |
| ES2065837B1 ES2065837B1 (en) | 1995-10-01 |
Family
ID=32322468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09300202A Expired - Fee Related ES2065837B1 (en) | 1992-02-07 | 1993-02-04 | PRODUCTION PROCEDURE FOR COMMERCIAL PHOSPHORIC ACID WITH A VERY LOW CADMIUM CONTENT. |
Country Status (6)
| Country | Link |
|---|---|
| DZ (1) | DZ1656A1 (en) |
| ES (1) | ES2065837B1 (en) |
| FR (1) | FR2687657B1 (en) |
| JO (1) | JO1739B1 (en) |
| OA (1) | OA09773A (en) |
| TN (1) | TNSN92119A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1317183C (en) * | 2005-12-23 | 2007-05-23 | 中国石化集团南京设计院 | Process for producing wet method phosphoric acid by medium low grade phosphorus mine |
| PL2132347T3 (en) * | 2007-03-06 | 2011-12-30 | Centre Detudes Et De Rech Des Phosphates Mineraux | Method for the treatment of cadmium-bearing solids |
| CN102826530A (en) * | 2012-09-25 | 2012-12-19 | 灵山县骄丰化工有限公司 | Method for co-producing calcium hydrogen phosphate and calcium superphosphate by using high calcium siliceous low-graded phosphate ore |
| FR3117476B1 (en) | 2020-12-10 | 2023-04-21 | Ocp Sa | INTEGRATED PHOSPHORIC ACID DECADMIATION PROCESS |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1983002107A1 (en) * | 1981-12-14 | 1983-06-23 | United States Gypsum Co | Phosphoanhydrite process |
| WO1991000244A1 (en) * | 1989-07-04 | 1991-01-10 | Office Togolais Des Phosphates | Process for eliminating heavy metals from phosphoric acid |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8601846A (en) * | 1986-07-15 | 1988-02-01 | Stamicarbon | METHOD FOR REMOVING HEAVY METALS FROM ACID PHOSPHATE-CONTAINING AQUEOUS MEDIA. |
| IL85751A (en) * | 1988-03-16 | 1991-12-15 | Negev Phosphates Ltd | Method for the removal of heavy metal ions from phosphoric acid |
-
1992
- 1992-12-28 TN TNTNSN92119A patent/TNSN92119A1/en unknown
- 1992-12-29 DZ DZ920170A patent/DZ1656A1/en active
-
1993
- 1993-02-03 FR FR9301150A patent/FR2687657B1/en not_active Expired - Fee Related
- 1993-02-04 ES ES09300202A patent/ES2065837B1/en not_active Expired - Fee Related
- 1993-02-05 OA OA60336A patent/OA09773A/en unknown
- 1993-02-06 JO JO19931739A patent/JO1739B1/en active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1983002107A1 (en) * | 1981-12-14 | 1983-06-23 | United States Gypsum Co | Phosphoanhydrite process |
| WO1991000244A1 (en) * | 1989-07-04 | 1991-01-10 | Office Togolais Des Phosphates | Process for eliminating heavy metals from phosphoric acid |
Also Published As
| Publication number | Publication date |
|---|---|
| JO1739B1 (en) | 1993-06-15 |
| ES2065837B1 (en) | 1995-10-01 |
| OA09773A (en) | 1993-11-30 |
| FR2687657A1 (en) | 1993-08-27 |
| DZ1656A1 (en) | 2002-02-17 |
| TNSN92119A1 (en) | 1993-06-08 |
| FR2687657B1 (en) | 1996-03-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD2A | Announcement of lapse in spain |
Effective date: 20180806 |