ES2057314T3 - Procedimiento para la preparacion de derivados del ciclohexanol. - Google Patents
Procedimiento para la preparacion de derivados del ciclohexanol.Info
- Publication number
- ES2057314T3 ES2057314T3 ES90119710T ES90119710T ES2057314T3 ES 2057314 T3 ES2057314 T3 ES 2057314T3 ES 90119710 T ES90119710 T ES 90119710T ES 90119710 T ES90119710 T ES 90119710T ES 2057314 T3 ES2057314 T3 ES 2057314T3
- Authority
- ES
- Spain
- Prior art keywords
- sub
- butil
- tert
- group
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
- C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
EL 4-TERT-BUTIL-CICLOHEXANOL SE OBTIENE POR UN PROCESO QUE CONSISTE EN LA HIDROGENACION DE 4-TERT-BUTIL-FENOL O DE 4-TERT-BUTIL-CICLOHEXANONA EN PRESENCIA DE UN SISTEMA CATALITICO CONSTITUIDO POR RADIO SOBRE UN SOPORTE DE AL SUB 2O SUB 3, SIO SUB 2, TIO SUB 2. AL SUB 2O SUB 3 O DE CARBON, EN COMBINACION CON HBF SUB 4 O BF SUB 3 [Y] SUB N, REPRESENTANDO Y EL GRUPO R SUB 2O, SIENDO R UN GRUPO ALQUILO INFERIOR DE C SUB 1 A C SUB 6, O EL GRUPO CH SUB 3CO SUB 2H, H SUB 3PO SUB 4 O H SUB 2O Y VALIENDO EL INDICE N CERO, 1 O 2. EL SISTEMA CATALITICO ARRIBA MENCIONADO PRESENTA LA VENTAJA DE SER FACILMENTE RECICLABLE Y DE POSEER UNA LARGA DURACION DE VIDA A LA VEZ QUE PERMITE ALCANZAR UN ALTO GRADO DE SELECTIVIDAD.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH407289 | 1989-11-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2057314T3 true ES2057314T3 (es) | 1994-10-16 |
Family
ID=4269297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90119710T Expired - Lifetime ES2057314T3 (es) | 1989-11-13 | 1990-10-15 | Procedimiento para la preparacion de derivados del ciclohexanol. |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5107038A (es) |
| EP (1) | EP0427965B1 (es) |
| JP (1) | JPH0764769B2 (es) |
| CA (1) | CA2028385C (es) |
| DE (1) | DE69009682T2 (es) |
| ES (1) | ES2057314T3 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG44770A1 (en) * | 1993-02-24 | 1997-12-19 | Givaudan Roure Int | Cyclic compounds |
| US5977402A (en) * | 1995-07-20 | 1999-11-02 | Sumitomo Chemical Company, Limited | Processes for preparing 4-tert.-butylcyclohexanol and 4-tert.-butylcyclohexyl acetate |
| KR970006259A (ko) * | 1995-07-20 | 1997-02-19 | 고사이 아키오 | 4-t-부틸사이클헥산올의 제조방법 |
| EP0809485B1 (fr) * | 1995-12-19 | 2001-11-07 | Firmenich Sa | Utilisation du 4-tert-butyl-1-cyclohexanol en tant qu'antioxydant |
| US6027668A (en) * | 1995-12-19 | 2000-02-22 | Firmenich S.A. | Use of 4-tert-butyl-1-cyclohexanol as an antioxidant |
| JPH09241194A (ja) * | 1996-03-07 | 1997-09-16 | Takasago Internatl Corp | シス−4−t−ブチルシクロヘキサノールの製造法 |
| DE10160009A1 (de) * | 2001-12-06 | 2003-06-18 | Haarmann & Reimer Gmbh | Verfahren zur Herstellung von 3,3,5-Trimethylcyclohexanol |
| JP4581078B2 (ja) * | 2003-04-18 | 2010-11-17 | 独立行政法人産業技術総合研究所 | フェノール類の水素化方法 |
| CN102448450B (zh) | 2009-04-09 | 2013-11-20 | 西姆莱斯有限公司 | 包含反式-叔丁基环己醇作为皮肤刺激缓解剂的组合物 |
| FR2947545B1 (fr) | 2009-07-03 | 2011-06-10 | Aet Group | Procede continu d'hydrogenation de composes aromatiques |
| CN102093168B (zh) * | 2010-12-03 | 2013-08-07 | 西安瑞联近代电子材料有限责任公司 | 4-(反-4’-正烷基环己基)环己醇异构化方法 |
| CN110743546B (zh) * | 2019-10-31 | 2022-11-18 | 西安凯立新材料股份有限公司 | 连续制备顺式对叔丁基环己醇的催化剂及制备方法和应用 |
| EP4549419A1 (en) | 2023-10-31 | 2025-05-07 | Basf Se | Preparation of cycloaliphatic or heterocycloaliphatic compounds by hydrogenation of aromatic or heteroaromatic compounds using hydrogen with low deuterium content |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2927127A (en) * | 1958-04-08 | 1960-03-01 | Ameringen Haebler Inc Van | Process for producing para tertiary butyl cyclohexanyl esters and the intermediate alcohol therefor |
| CH416606A (fr) * | 1958-06-23 | 1966-07-15 | Int Flavors & Fragrances Inc | Procédé pour préparer des esters d'acides aliphatiques inférieurs d'un mélange de cis et tran p-tert-butylcyclohexanol |
| JPS511445A (es) * | 1974-06-05 | 1976-01-08 | Toray Industries | |
| US4067915A (en) * | 1974-06-05 | 1978-01-10 | Toray Industries, Inc. | Method for producing cyclohexane derivatives directly from aromatic hydrocarbons |
| GB1503723A (en) * | 1975-10-14 | 1978-03-15 | Scm Corp | Hydrogenation of cyclic unsaturated compounds |
| JPS6034526B2 (ja) * | 1978-01-10 | 1985-08-09 | 川研フアインケミカル株式会社 | シス型‐4‐tert‐ブチルシクロヘキサノ−ルの製造方法 |
| JPS54122253A (en) * | 1978-03-13 | 1979-09-21 | Shin Etsu Chem Co Ltd | Preparation of cis-alkylcyclohexanol |
| JPS54135714A (en) * | 1978-04-14 | 1979-10-22 | Texaco Development Corp | Hydrogenation decomposition of acetal and ketal |
| DE2819159A1 (de) * | 1978-05-02 | 1979-11-15 | Texaco Development Corp | Verfahren zur hydrogenolyse von acetalen und ketalen organischer kohlenwasserstoffe |
| DE3401343A1 (de) * | 1983-10-22 | 1985-05-09 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von 2- und 4-tert.-butylcyclohexanol mit hohen anteilen an cis-isomeren durch katalytische hydrierung der entsprechenden tert.-butylphenole |
| DE3629605A1 (de) * | 1986-08-30 | 1988-03-03 | Basf Ag | Verwendung von 2-tert.-butyl-4-methyl-cyclohexanol als riechstoff sowie als bestandteil von riechstoffkompositionen |
-
1990
- 1990-10-15 EP EP90119710A patent/EP0427965B1/fr not_active Expired - Lifetime
- 1990-10-15 ES ES90119710T patent/ES2057314T3/es not_active Expired - Lifetime
- 1990-10-15 DE DE69009682T patent/DE69009682T2/de not_active Expired - Lifetime
- 1990-10-22 US US07/602,040 patent/US5107038A/en not_active Expired - Lifetime
- 1990-10-24 CA CA002028385A patent/CA2028385C/en not_active Expired - Lifetime
- 1990-11-06 JP JP2299093A patent/JPH0764769B2/ja not_active Expired - Lifetime
-
1991
- 1991-12-20 US US07/797,565 patent/US5160498A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03173842A (ja) | 1991-07-29 |
| US5107038A (en) | 1992-04-21 |
| DE69009682T2 (de) | 1994-10-06 |
| CA2028385C (en) | 1997-10-07 |
| EP0427965A3 (en) | 1991-09-18 |
| US5160498A (en) | 1992-11-03 |
| JPH0764769B2 (ja) | 1995-07-12 |
| CA2028385A1 (en) | 1991-05-14 |
| DE69009682D1 (de) | 1994-07-14 |
| EP0427965B1 (fr) | 1994-06-08 |
| EP0427965A2 (fr) | 1991-05-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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