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ES2053523T3 - Electrodo para la fabricacion de metales en sales fundidas, su metodo y celda para el mismo. - Google Patents

Electrodo para la fabricacion de metales en sales fundidas, su metodo y celda para el mismo.

Info

Publication number
ES2053523T3
ES2053523T3 ES87201569T ES87201569T ES2053523T3 ES 2053523 T3 ES2053523 T3 ES 2053523T3 ES 87201569 T ES87201569 T ES 87201569T ES 87201569 T ES87201569 T ES 87201569T ES 2053523 T3 ES2053523 T3 ES 2053523T3
Authority
ES
Spain
Prior art keywords
metals
cerium
electrode
cast
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87201569T
Other languages
English (en)
Inventor
Dominique Darracq
Jean-Jacques Duruz
Claude Durmelat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Moltech Invent SA
Original Assignee
Moltech Invent SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Moltech Invent SA filed Critical Moltech Invent SA
Application granted granted Critical
Publication of ES2053523T3 publication Critical patent/ES2053523T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
    • C25C3/12—Anodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof
    • C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

UN ELECTRODO BIPOLAR PARA EXTRACCION ELECTROLITICA DE ALUMINIO U OTROS METALES POR ELECTROLISIS DE UN ELECTROLITO DE SAL FUNDIDA QUE CONTIENE UN COMPUESTO DISUELTO DEL METAL QUE VA A EXTRAERSE, COMPRENDE UNA SUPERFICIE ANODICA (5) Y UNA CATODICA (6) QUE SE PRESERVAN DURANTE LA OPERACION MEDIANTE DISOLUCION DE PEQUEÑAS CANTIDADES DE UNA SUSTANCIA EN EL ELECTROLITO (7), QUE ES CAPAZ DE DEPOSITARSE EN CUALQUIER SUPERFICIE A UNA TASA QUE OCMPRENDE LA CORROSION DE LA MISMA DURANTE LA ELECTROLISIS. LA SUPERFICIE ANODICA (5) ES POR EJEMPLO OXIFLUORURO DE CERIO Y LA SUPERFICIE CATODICA HEXABORURO DE CERIO (6), AMBAS SUPERFICIES SE PRESERVAN MEDIANTE LA ADICION DE COMPUESTOS DE CERIO, COMO POR EJEMPLO, OXIDOS FLUORUROS, HIDRUROS, ETC, A LA MASA FUNDIDA. LA SUPERFICIE CATODICA PUEDE INCLUIR TAMBIEN DICLORURO DE TITANIO EN VEZ DE HEXABORURO DE CERIO O JUNTO CON EL.
ES87201569T 1986-08-21 1987-08-19 Electrodo para la fabricacion de metales en sales fundidas, su metodo y celda para el mismo. Expired - Lifetime ES2053523T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP86810373 1986-08-21

Publications (1)

Publication Number Publication Date
ES2053523T3 true ES2053523T3 (es) 1994-08-01

Family

ID=8196467

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87201569T Expired - Lifetime ES2053523T3 (es) 1986-08-21 1987-08-19 Electrodo para la fabricacion de metales en sales fundidas, su metodo y celda para el mismo.

Country Status (8)

Country Link
US (1) US5019225A (es)
EP (1) EP0257710B1 (es)
AU (1) AU604746B2 (es)
BR (1) BR8707792A (es)
CA (1) CA1326469C (es)
DE (1) DE3783408T2 (es)
ES (1) ES2053523T3 (es)
WO (1) WO1988001313A1 (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4999097A (en) * 1987-01-06 1991-03-12 Massachusetts Institute Of Technology Apparatus and method for the electrolytic production of metals
US5651874A (en) 1993-05-28 1997-07-29 Moltech Invent S.A. Method for production of aluminum utilizing protected carbon-containing components
US5310476A (en) 1992-04-01 1994-05-10 Moltech Invent S.A. Application of refractory protective coatings, particularly on the surface of electrolytic cell components
US6001236A (en) 1992-04-01 1999-12-14 Moltech Invent S.A. Application of refractory borides to protect carbon-containing components of aluminium production cells
US5486278A (en) * 1993-06-02 1996-01-23 Moltech Invent S.A. Treating prebaked carbon components for aluminum production, the treated components thereof, and the components use in an electrolytic cell
DE69526264T2 (de) 1994-09-08 2002-10-24 Moltech Invent S.A., Luxemburg/Luxembourg Aluminium Elektrolysezelle mit drainierfähige Kathode
US5492604A (en) * 1994-12-28 1996-02-20 Aluminum Company Of America Coating composition for carbon electrodes
US5753163A (en) 1995-08-28 1998-05-19 Moltech. Invent S.A. Production of bodies of refractory borides
US5753382A (en) * 1996-01-10 1998-05-19 Moltech Invent S.A. Carbon bodies resistant to deterioration by oxidizing gases
US5989396A (en) * 1997-04-02 1999-11-23 Eltech Systems Corporation Electrode and electrolytic cell containing same
US6217739B1 (en) 1997-06-26 2001-04-17 Alcoa Inc. Electrolytic production of high purity aluminum using inert anodes
US6372119B1 (en) 1997-06-26 2002-04-16 Alcoa Inc. Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals
US5865980A (en) * 1997-06-26 1999-02-02 Aluminum Company Of America Electrolysis with a inert electrode containing a ferrite, copper and silver
US6423195B1 (en) 1997-06-26 2002-07-23 Alcoa Inc. Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals
US6030518A (en) * 1997-06-26 2000-02-29 Aluminum Company Of America Reduced temperature aluminum production in an electrolytic cell having an inert anode
US6821312B2 (en) * 1997-06-26 2004-11-23 Alcoa Inc. Cermet inert anode materials and method of making same
US6423204B1 (en) 1997-06-26 2002-07-23 Alcoa Inc. For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals
US6416649B1 (en) 1997-06-26 2002-07-09 Alcoa Inc. Electrolytic production of high purity aluminum using ceramic inert anodes
US6162334A (en) * 1997-06-26 2000-12-19 Alcoa Inc. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum
KR100415265B1 (ko) * 2001-03-26 2004-01-16 한국전력공사 원자력발전소 증기발생기 전열관의 2차측 응력부식균열억제 방법
US6758991B2 (en) 2002-11-08 2004-07-06 Alcoa Inc. Stable inert anodes including a single-phase oxide of nickel and iron
US7033469B2 (en) * 2002-11-08 2006-04-25 Alcoa Inc. Stable inert anodes including an oxide of nickel, iron and aluminum
US7235161B2 (en) * 2003-11-19 2007-06-26 Alcoa Inc. Stable anodes including iron oxide and use of such anodes in metal production cells
US20080023321A1 (en) * 2006-07-31 2008-01-31 Donald Sadoway Apparatus for electrolysis of molten oxides
SA110310372B1 (ar) 2009-05-12 2014-08-11 Metalysis Ltd جهاز وطريقة اختزال مخزون التغذية الصلب
BR112012002034B1 (pt) 2009-07-28 2019-11-05 Alcoa Inc eletrodo para uso em uma célula de eletrólise de alumínio, célula de eletrólise de alumínio, processo para produção de eletrodo, composição e uso de um eletrodo
MY180279A (en) 2010-11-18 2020-11-26 Metalysis Ltd Electrolysis apparatus
CN103243355B (zh) * 2013-05-02 2015-07-29 西安建筑科技大学 一种全封闭液态阴极稀土熔盐电解槽
CN103540960B (zh) * 2013-09-30 2016-08-17 赣南师范学院 一种稀土镁镍基储氢合金的制备方法
WO2021195247A1 (en) * 2020-03-25 2021-09-30 Alcoa Usa Corp. Copper-coated titanium diboride articles
US20230235470A1 (en) * 2020-04-16 2023-07-27 The Governing Council Of The University Of Toronto Apparatus for electrorefining a ferrous molten metal and method associated therewith
CN112719266A (zh) * 2020-11-27 2021-04-30 昆明理工大学 一种金属粉末电化学脱氧烧结方法
CN114906878B (zh) * 2022-04-07 2023-06-27 浙江格派钴业新材料有限公司 一种电池级氢氧化钴纳米片的制备方法
CN116162968B (zh) * 2023-03-17 2023-09-22 赣州晨光稀土新材料有限公司 一种稀土熔盐电解用钨电极及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH587929A5 (es) * 1973-08-13 1977-05-13 Alusuisse
US4111765A (en) * 1976-12-23 1978-09-05 Diamond Shamrock Technologies S.A. Silicon carbide-valve metal borides-carbon electrodes
IL53092A (en) * 1976-12-23 1980-10-26 Diamond Shamrock Techn Sintered electrodes consisting of silicon carbide "valve" metal boride and carbon
US4309467A (en) * 1980-08-22 1982-01-05 The United States Of America As Represented By Department Of Energy Composition for use in high-temperature hydrogen-fluorine environments and method for making the composition
ATE32107T1 (de) * 1982-05-10 1988-02-15 Eltech Systems Corp Aluminium benetzbare materialien.
CA1211474A (en) * 1982-12-30 1986-09-16 Corning Glass Works Reaction sintered oxide-boride
GB8301001D0 (en) * 1983-01-14 1983-02-16 Eltech Syst Ltd Molten salt electrowinning method
ATE53863T1 (de) * 1983-02-16 1990-06-15 Moltech Invent Sa Gesinterte metall-keramikverbundwerkstoffe und ihre herstellung.
US4529494A (en) * 1984-05-17 1985-07-16 Great Lakes Carbon Corporation Bipolar electrode for Hall-Heroult electrolysis
DE3685760T2 (de) * 1985-02-18 1993-05-19 Moltech Invent Sa Verfahren zur herstellung von aluminium, zelle zur herstellung von aluminium und anode fuer die elektrolyse von aluminium.
DE3774964D1 (de) * 1986-08-21 1992-01-16 Moltech Invent Sa Metall-keramikverbundwerkstoff, formkoerper und verfahren zu dessen herstellung.

Also Published As

Publication number Publication date
EP0257710A1 (en) 1988-03-02
US5019225A (en) 1991-05-28
DE3783408D1 (de) 1993-02-18
CA1326469C (en) 1994-01-25
AU7809787A (en) 1988-03-08
DE3783408T2 (de) 1993-06-09
WO1988001313A1 (en) 1988-02-25
BR8707792A (pt) 1989-08-15
AU604746B2 (en) 1991-01-03
EP0257710B1 (en) 1993-01-07

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