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ES2052030T3 - Preparacion de fenol empleando cumeno. - Google Patents

Preparacion de fenol empleando cumeno.

Info

Publication number
ES2052030T3
ES2052030T3 ES89312304T ES89312304T ES2052030T3 ES 2052030 T3 ES2052030 T3 ES 2052030T3 ES 89312304 T ES89312304 T ES 89312304T ES 89312304 T ES89312304 T ES 89312304T ES 2052030 T3 ES2052030 T3 ES 2052030T3
Authority
ES
Spain
Prior art keywords
isopropanol
cumene
phenol
benzene
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89312304T
Other languages
English (en)
Inventor
Shintaro Araki
Fujihisa Matsunaga
Hiroshi Fukuhara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP63302617A external-priority patent/JP2593212B2/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of ES2052030T3 publication Critical patent/ES2052030T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Compounds Of Unknown Constitution (AREA)

Abstract

EN UNA FORMA PRIMARIA, SE SUMINISTRA UN PROCESO PARA PREPARAR FENOL CONVIERTIENDO ACETONA PRODUCIDA POR EL PROCESO "CUMENE" EN ISOPROPANOL, Y ALQUILATANDO BENZENO CON EL ISOPROPANOL Y PROPILENO OPCIONAL, MEDIANTE LO CUAL SE FORMA FENOL SIN PRODUCTOS DE ACETONA. EL "CUMENE" SE PREPARA ALQUILATANDO BENZENO EN PRESENCIA DE UN CATALIZADOR DE ZEOLITO USANDO ISOPROPANOL O UNA MEZCLA DE ISOPROPANOL Y PROPILENO COMO AGENTE ALQUILATANTE. ADEMAS SE SUMINISTRA LA ALQUILATACION CONTINUA DE BENZENO CON ISOPROPANOL MEDIANTE LO CUAL UNA MEZCLA DE REACCION SE DIVIDEN EN UNA PRIMERA Y UNA SEGUNDA PARTE, ESTANDO LA PRIMERA PARTE RECICLADA HACIA EL REACTOR Y LA SEGUNDA PARTE SALIENDO COMO PRODUCTO DE REACCION.
ES89312304T 1988-11-28 1989-11-28 Preparacion de fenol empleando cumeno. Expired - Lifetime ES2052030T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP30030088 1988-11-28
JP63302617A JP2593212B2 (ja) 1988-11-30 1988-11-30 クメンの製造方法
JP63328722A JP2603711B2 (ja) 1988-12-26 1988-12-26 クメンの製造方法

Publications (1)

Publication Number Publication Date
ES2052030T3 true ES2052030T3 (es) 1994-07-01

Family

ID=27338376

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89312304T Expired - Lifetime ES2052030T3 (es) 1988-11-28 1989-11-28 Preparacion de fenol empleando cumeno.

Country Status (10)

Country Link
US (1) US5015786A (es)
EP (1) EP0371738B1 (es)
AT (1) ATE102179T1 (es)
CA (1) CA2003925C (es)
DD (3) DD301736A7 (es)
DE (1) DE68913448T2 (es)
ES (1) ES2052030T3 (es)
MY (1) MY105602A (es)
RU (1) RU1839668C (es)
SG (1) SG20295G (es)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2724001B2 (ja) * 1989-01-17 1998-03-09 三井化学株式会社 イソプロパノールの製造方法
FR2656300B1 (fr) * 1989-12-21 1993-06-11 Inst Francais Du Petrole Procede de production de phenol.
US5254751A (en) 1992-09-14 1993-10-19 General Electric Company Method for the decomposition of cumene hydroperoxide by acidic catalyst to phenol and acetone
US5371305A (en) * 1992-12-31 1994-12-06 Hercules Incorporated Process for producing phenol from cumene
DE4322712A1 (de) * 1993-07-08 1995-01-12 Huels Chemische Werke Ag Verfahren zur Durchführung chemischer Reaktionen in Reaktionsdestillationskolonnen
US5457244A (en) * 1994-10-04 1995-10-10 General Electric Company Phenol tar waste reduction process
TW318174B (es) * 1994-11-04 1997-10-21 Gen Electric
CA2161995A1 (en) * 1994-11-23 1996-05-24 Arkady S. Dyckman Method of phenol tar desalting
US5510543A (en) * 1994-12-09 1996-04-23 General Electric Company Removal and neutralization of acid catalyst from products of cumene hydroperoxide cleavage
EP0748305B1 (en) * 1994-12-30 2000-08-16 Chevron Chemical Company LLC Catalyst and process for alkylation of aromatics
US5672774A (en) * 1995-10-24 1997-09-30 General Electric Company Phenol tar processing method
PL181496B1 (pl) * 1996-03-20 2001-07-31 Politechnika Slaska Im Wincent Sposób wytwarzania ß-naftolu PL
US5962751A (en) * 1996-04-26 1999-10-05 General Electric Company Phenol tar desalting method
IT1313009B1 (it) * 1999-07-13 2002-05-29 Enichem Spa Processo per la rigenerazione di catalizzatori zeolitici.
IT1313008B1 (it) * 1999-07-13 2002-05-29 Enichem Spa Processo per l'alchilazione di composti aromatici.
IT1313007B1 (it) * 1999-07-13 2002-05-29 Enichem Spa Processso per l'alchilazione di composti aromatici in fase gas.
DE10008924A1 (de) * 2000-02-25 2001-09-06 Phenolchemie Gmbh & Co Kg Verfahren zur Herstellung von Phenol
ES2325981T3 (es) * 2000-09-25 2009-09-28 Exxonmobil Chemical Patents Inc. Hidrogenacion de los efluentes de escision en la produccion de fenol.
US7371910B2 (en) * 2000-10-20 2008-05-13 Lummus Technology Inc. Process for benzene alkylation and transalkylation of polyalkylated aromatics over improved zeolite beta catalyst
US6455712B1 (en) * 2000-12-13 2002-09-24 Shell Oil Company Preparation of oxirane compounds
US20020042548A1 (en) 2001-07-11 2002-04-11 Dandekar Ajit B. Process for producing cumene
TWI266762B (en) * 2001-11-16 2006-11-21 Shell Int Research Process for the preparation of isopropanol
US6921843B2 (en) 2001-12-21 2005-07-26 Council Of Scientific And Industrial Research Process for the preparation of diemethyl cumenes
AU2002242945A1 (en) * 2002-03-21 2003-10-08 Council Of Scientific And Industrial Research Process for the preparation of dimethylcumenes
US6984761B2 (en) * 2002-12-16 2006-01-10 Exxonmobil Chemical Patents Inc. Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
US7425659B2 (en) * 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
WO2007137020A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts
RU2341510C2 (ru) * 2006-11-03 2008-12-20 Олег Станиславович Павлов Способ получения фенола и кетона из гидропероксида алкилароматического углеводорода (варианты)
KR101066703B1 (ko) * 2006-11-21 2011-09-21 미쓰이 가가쿠 가부시키가이샤 알킬화 방향족 화합물의 제조방법 및 페놀의 제조방법
US7799958B2 (en) 2007-10-04 2010-09-21 Barclays Bank Plc Process for the production of iso-propanol by liquid phase hydrogenation
EP2298718B1 (en) * 2008-06-10 2018-03-28 Mitsui Chemicals, Inc. Methods for producing cumene and phenol
WO2009150973A1 (ja) * 2008-06-10 2009-12-17 三井化学株式会社 アルキル化芳香族化合物の製造方法およびフェノールの製造方法
IT1392325B1 (it) 2008-09-11 2012-02-28 Polimeri Europa Spa Processo per l'alchilazione di benzene con isopropanolo o miscele di isopropanolo e propilene
TWI458695B (zh) * 2008-10-06 2014-11-01 Badger Licensing Llc 異丙苯的製造方法
KR20110082156A (ko) * 2008-10-06 2011-07-18 바져 라이센싱 엘엘씨 큐멘의 제조방법
US8546633B2 (en) * 2008-10-23 2013-10-01 Mitsui Chemicals, Inc. Method for producing alkylated aromatic compound, method for producing cumene, and method for producing phenol
KR101307727B1 (ko) * 2009-03-19 2013-09-11 미쓰이 가가쿠 가부시키가이샤 알킬화 방향족 화합물의 제조 방법 및 페놀의 제조 방법
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof
IN2014DN10948A (es) 2012-07-05 2015-09-18 Badger Licensing Llc
MY170173A (en) 2012-07-13 2019-07-09 Badger Licensing Llc Process for producing phenol
US9259722B2 (en) * 2012-07-26 2016-02-16 Badger Licensing Llc Process for producing cumene
US9796644B2 (en) 2012-08-14 2017-10-24 Badger Licensing Llc Integrated process for producing cumene and purifying isopropanol
RU2654699C2 (ru) 2012-12-11 2018-05-22 Эксонмобил Кемикэл Пейтентс Инк. Способ получения кумола с рециклом продуктов алкилирования
ITMI20131704A1 (it) * 2013-10-15 2015-04-16 Versalis Spa Composizione catalitica e processo che la utilizza per l'alchilazione di idrocarburi aromatici con alcoli, o miscele di alcoli e olefine
US9193652B2 (en) 2014-03-04 2015-11-24 Kellogg Brown & Root Llc Phenol resin treatment improvement
CN112569972B (zh) * 2019-09-29 2022-04-01 中国石油化工股份有限公司 一种制备异丙苯的催化剂及其制备与应用
CN117563604A (zh) * 2023-10-07 2024-02-20 万华化学集团股份有限公司 一种催化剂、制备方法及其用于异丙苯氧化合成异丙苯过氧化氢的方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4011278A (en) * 1963-02-27 1977-03-08 Mobil Oil Corporation Conversion of polar compounds using a zsm-5 zeolite catalyst
US3436429A (en) * 1966-11-23 1969-04-01 Skelly Oil Co Hydrogenation process
US3631120A (en) * 1969-06-13 1971-12-28 Exxon Research Engineering Co Alkylation of aromatic hydrocarbons
JPS5211511B2 (es) * 1972-06-01 1977-03-31
JPS6010010B2 (ja) * 1978-11-29 1985-03-14 三井東圧化学株式会社 酸化反応溶剤及び高沸点生成物の回収方法
US4268454A (en) * 1978-12-21 1981-05-19 Allied Chemical Corporation Anionic group VIII metal hydride catalysts
US4267380A (en) * 1979-06-25 1981-05-12 Gulf Research & Development Company Decomposition of cumene hydroperoxide using a Lewis acid catalyst
US4238417A (en) * 1979-08-15 1980-12-09 Gulf Research & Development Company Decomposition of cumene hydroperoxide and recovery of boron trifluoride catalyst
US4567304A (en) * 1983-04-05 1986-01-28 General Electric Company Process for preparing acetone and phenol
US4711869A (en) * 1985-11-08 1987-12-08 Aristech Chemical Corporation Silica-titania hydrocarbon conversion catalyst
JPS62252737A (ja) * 1986-04-01 1987-11-04 Japan Tobacco Inc アルデヒドまたはケトンのアルコールへの還元方法
JPS61204143A (ja) * 1986-09-10 1986-09-10 Japan Tobacco Inc アルデヒドまたはケトンのアルコールへの還元方法
US5017729A (en) * 1988-09-30 1991-05-21 Mitsui Petrochemical Industries, Ltd. Phenol preparation process and propylene recovery therefrom

Also Published As

Publication number Publication date
DE68913448D1 (de) 1994-04-07
CA2003925C (en) 1999-11-23
DE68913448T2 (de) 1994-06-01
DD301689A9 (de) 1993-07-01
DD301735A7 (de) 1993-09-02
RU1839668C (ru) 1993-12-30
DD301689B5 (de) 1994-01-27
MY105602A (en) 1994-11-30
CA2003925A1 (en) 1990-05-28
SG20295G (en) 1995-08-18
EP0371738A3 (en) 1991-10-30
EP0371738B1 (en) 1994-03-02
ATE102179T1 (de) 1994-03-15
DD301736A7 (de) 1993-09-02
US5015786A (en) 1991-05-14
EP0371738A2 (en) 1990-06-06

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