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EP4633589A1 - Compositions de traitement capillaire qui confèrent de la brillance et de l?éclat - Google Patents

Compositions de traitement capillaire qui confèrent de la brillance et de l?éclat

Info

Publication number
EP4633589A1
EP4633589A1 EP23833977.4A EP23833977A EP4633589A1 EP 4633589 A1 EP4633589 A1 EP 4633589A1 EP 23833977 A EP23833977 A EP 23833977A EP 4633589 A1 EP4633589 A1 EP 4633589A1
Authority
EP
European Patent Office
Prior art keywords
peg
dimethicone
ppg
hair
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23833977.4A
Other languages
German (de)
English (en)
Inventor
Liliana XAVIER
Kayla STENCEL
Kazumitsu KAWAKAMI
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US18/067,076 external-priority patent/US20240216260A1/en
Priority claimed from FR2301026A external-priority patent/FR3145485A1/fr
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP4633589A1 publication Critical patent/EP4633589A1/fr
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present disclosure relates to hair treatment compositions that impart a desirable shine and luster to hair and to methods for treating hair to impart and enhance shine and luster to hair. Regardless of whether the hair treatment compositions are rinsed from the hair as a rinse-out (or rinse-off) product or allowed to remain the hair as a leave-on product, they impart a noticeable lightweight, glistening finish and to the hair.
  • Oils, waxes, and other fatty materials have also used in products to provide shine and moisturizing properties to hair. Such products attempt to replace the natural oils removed from hair due to shampooing, chemical treatments, environmental factors, etc. with supplemental materials. Although simply replacing oils removed from hair seems logical, consumers complain the hair feels greasy and can be difficult to style.
  • the hair should feel light, be free flowing, and have a natural appearance.
  • the present disclosure relates to hair treatment compositions and methods that impart a desirable shine and luster to hair. Regardless of whether the hair treatment compositions are rinsed from the hair as a rinse-out (or rinse-off) product or remain the hair as a leave-on product, they impart a noticeable lightweight, glistening finish and shine to the hair.
  • the compositions are easy to use and provide long-lasting results that withstand rinsing and subsequent cleansing. Furthermore, the compositions are unique because they do not require film-forming styling polymers that form a film or layer on the hair, nor do they require hydrocarbon-based oils.
  • the compositions impart shine and luster to hair indicative of natural, healthy hair, without causing build-up, stickiness, and heaviness.
  • the treated hair has a lightweight feel, is free flowing, and exhibits a natural and healthy appearance.
  • the hair treatment compositions are typically an oil-in-water emulsion and includes:
  • glycols selected from ethylene glycol, propylene glycol, butylene glycol, pentylene glycol, dipropylene glycol, or a combination thereof;
  • Nonlimiting examples of polyether-modified polysilxoanes includes PEGylated dimethicones, bis-PEGylated dimethicones, PEG/PPG dimethicones, or a combination thereof.
  • PEGylated dimethicones include PEG-10 dimethicone, PEG-9 dimethicone, PEG-8 dimethicone, PEG-3 dimethicone, PEG-7 dimethicone, PEG-12 dimethicone, PEG-11 methyl ether dimethicone, PEG- 32-dimethicone, PEG-14 dimethicone, PEG-17 dimethicone, or a combination thereof.
  • Nonlimiting examples of bis-PEGylated dimethicones include bis-PEG-[10-20] dimethicone, bis-PEG-10 dimethicone, bis-PEG-12 dimethicone, bis-PEG-17 dimethicone, bis-PEG-20 dimethicone, or a combination thereof.
  • PEG/PPG dimethicones include PEG/PPG-3/10 dimethicone, PEG/PPG-4/12 dimethicone, PEG/PPG-6/11 dimethicone, PEG/PPG- 8/14 dimethicone, PEG/PPG-14/4 dimethicone, PEG/PPG-15/15 dimethicone, PEG/PPG-16/2 dimethicone, PEG/PPG-17/18 dimethicone, PEG/PPG-18/18 dimethicone, PEG/PPG-19/19 dimethicone, PEG/PPG-20/6 dimethicone, PEG/PPG- 20/15 dimethicone, PEG/PPG-20/20 Dimethicone, PEG/PPG-20/23 dimethicone, PEG/PPG-20/29 dimethicone, PEG/PPG-22/23 dimethicone, PEG/PPG-22/24 dimethicone, PEG/PPG-23/6 dimethicon
  • a preferred glycol is propylene glycol.
  • Nonlimiting examples of cationic conditioning agents include cationic surfactants, cationic polymers, or a combination thereof.
  • Nonlimiting examples of cationic surfactants include quaternary ammonium compounds, fatty dialkylamines, fatty amidoamines, salts thereof, or a combination thereof.
  • Nonlimiting examples of quaternary ammonium compounds include cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, or a combination thereof.
  • Nonlimiting examples of fatty dialkylamines include oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyl-dimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethyl-amine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamido-propyidiethylamine, arachidamidoethyidiethylamine, arachidamidoethyidimethylamine, brassicamidopropyldimethylamine, lauramidopropyl dimethylamine, myristamidopropyl dimethylamine, dilinoleamidopropyl dimethylamine, palmit
  • Fatty alcohols can be saturated (alkyl) or unsaturated (alkenyl), linear or branched, optionally substituted with one or more hydroxyl groups.
  • Nonlimiting examples of fatty alcohols include decyl alcohol, undecyl alcohol, dodecyl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, isocetyl alcohol, behenyl alcohol, linalool, oleyl alcohol, myricyl alcohol, or a combination thereof.
  • the hair treatment compositions optionally include one or more nonionic thickening polymers.
  • nonionic thickening polymers include polysaccharides, polysaccharide derivatives, or a combination thereof, more specific but nonlimiting examples of nonionic thickening polymers include sclerotium gum, guar gums, guar gum derivatives, xanthan gum, hydroxyalkyl celluloses optionally modified with a hydrophobic group, inulins, carrageenans, carrageenan derivatives, or a combination thereof.
  • the hair treatment compositions optionally include one or more surfactants, which are different from the cationic conditioning agents, which can include cationic surfactants.
  • Surfactants other than cationic surfactants can be amphoteric (zwitterionic), nonionic, or anionic. It is more common for the hair treatment compositions to include one or more amphoteric surfactants and/or nonionic surfactants than anionic surfactants. Therefore, in certain embodiments, the hair treatment compositions are free or essentially free from anionic surfactants.
  • the hair treatment compositions include one or more amphoteric surfactants.
  • Nonlimiting examples of amphoteric surfactants include alkyl betaines, alkyl sultaines, alkyl amphoacetates, alkyl amphoproprionates, or a combination thereof. Alkyl betaines are particularly useful.
  • the hair treatment compositions optionally include one or more aminofunctionalized silicone oils.
  • amino-functionalized silicone oils include amodimethicone, bis-hydroxy/methoxy amodimethicones, bis-cetearyl amodimethicone, amodimethicone, bis(C13-15 alkoxy) PG amodimethicones, aminopropyl phenyl trimethicones, aminopropyl dimethicones, bis-amino PEG/PPG- 41/3 aminoethyl PG-propyl dimethicones, or a mixture thereof.
  • amodimethicone is particularly useful.
  • the compositions are particularly useful for improving the look and feel of hair.
  • the hair treatment compositions are useful for: (i) imparting shine and luster to hair; (ii) improving texture and feel of hair; (iii) preventing or reducing frizz, especially in high humidity conditions; and (iv) improving the appearance of hair; wherein the methods typically comprise applying a hair treatment composition disclosed herein to the hair.
  • the hair treatment composition can be applied to the hair as a leave-on product (i.e., allowed to remain on the hair without rinsing) or as a rinse-out product (i.e., rinsed from the hair prior to subsequently styling the hair).
  • a leave-on product i.e., allowed to remain on the hair without rinsing
  • a rinse-out product i.e., rinsed from the hair prior to subsequently styling the hair.
  • Radical R2 constitutes the group -CcH2c-O-(C2H4O-) a (C3H6O-)bR5
  • Radical R5 constitutes a hydrogen atom or a linear or branched alkyl group with 1 to 16 C-atoms
  • n is a number from about 0 to about 500
  • p is a number from about 1 to about 50
  • a is a number from about 0 to about 50
  • b is a number from about 0 to about 50
  • a+b are at least 1
  • c is a number from about 1 to about 4.
  • polyether-modified polysiloxanes of the general structural formula (I) are:
  • DOW CORNING 193 (INCI: PEG-12 Dimethicone), ABIL® B 8843 (INCI: PEG-14 Dimethicone),
  • ABIL® B 88184 (INCI: PEG/PPG-20/6 Dimethicone)
  • ABIL® B 8851 (INCI: PEG/PPG-14/4 Dimethicone).
  • the one or more polyether-modified polysiloxanes include one or more PEGylated dimethicones selected from PEG/PPG-18/18 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone, siloxane polyalkyleneoxide copolymer, PEG/PPG-22/24 dimethicone, PEG/PPG-17/18 dimethicone, PEG/PPG- 20/6 dimethicone, PEG/PPG-14/4 dimethicone, or mixtures thereof, preferably chosen from PEG-12 dimethicone, PEG-14 dimethicone, or a mixture thereof.
  • PEGylated dimethicones selected from PEG/PPG-18/18 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone, siloxane polyalkyleneoxide copolymer, PEG/PPG-22/24 dimethicone, PEG/PPG-17/18 dimethicone, PEG/
  • the one or more polyether-modified polysiloxanes include one or more PEG/PPG dimethicones selected from PEG/PPG-3/10 dimethicone, PEG/PPG-4/12 dimethicone, PEG/PPG-6/11 dimethicone, PEG/PPG- 8/14 dimethicone, PEG/PPG-14/4 dimethicone, PEG/PPG-15/15 dimethicone, PEG/PPG-16/2 dimethicone, PEG/PPG-17/18 dimethicone, PEG/PPG-18/18 dimethicone, PEG/PPG-19/19 dimethicone, PEG/PPG-20/6 dimethicone, PEG/PPG- 20/15 dimethicone, PEG/PPG-20/20 Dimethicone, PEG/PPG-20/23 dimethicone, PEG/PPG-20/29 dimethicone, PEG/PPG-22/23 dimethicone, PEG/PPG dimethico
  • the hair treatment composition includes about 1 to about 10 wt.% of the polyether-modified polysiloxanes based on the total weight of the composition.
  • hair treatment composition includes about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 1 to about 3 wt.%, about 1 .2 to about 10 wt.%, about 1 .2 to about 8 wt.%, about 1 .2 to about 6 wt.%, about 1 .2 to about 5 wt.%, about 1 .2 to about 4 wt.%, about 1 .2 to about 3 wt.% of the one or more polyether- modified polysiloxanes, based on the total weight of the composition.
  • Glycols are a class of compounds having two hydroxyl (—OH) groups are attached to different carbon atoms, wherein the number of carbon atoms is 2 to 8 and can be linear or branched, preferably 2 to 6 carbon atoms.
  • the glycols typical consist of carbon and oxygen atoms (i.e. , they do not include nor substituted with other compounds).
  • Nonlimiting examples of useful glycols include propylene glycol, butylene glycol, pentylene glycol, dipropylene glycol, or a combination thereof. The total amount of the one or more glycols in the hair treatment compositions will vary.
  • the hair treatment composition includes about 2 to about 20 wt.% of the one or more glycols, based on a total weight of the composition.
  • the hair treatment composition include about 2 to about 18 wt.%, about 2 to about 15 wt.%, about 2 to about 12 wt.%, about 2 to about 10 wt.%, about 4 to about 20 wt.%, about 4 to about 18 wt.%, about 4 to about 15 wt.%, about 4 to about 12 wt.%, about 4 to about 10 wt.%, about 5 to about 20 wt.%, about 5 to about 18 wt.%, about 5 to about 15 wt.%, about 5 to about 12 wt.%, or about 5 to about 10 wt.%, based on a total weight of the hair treatment composition.
  • Cationic conditioning agents are compounds having a cationic charge and compounds that are cationizable compounds and include, for example, cationic or cationizable surfactants and cationic or cationizable polymers.
  • cationic surfactant includes cationic surfactants and cationizable surfactants, unless expressly specified otherwise.
  • cationic conditioning agent includes cationic conditioning agents and cationizable conditioning agents, unless expressly specified otherwise.
  • cationic surfactant as defined by the instant disclosure as a surfactant that may be positively charged when it is contained in the hair coloring compositions.
  • the cationic surfactant may bear one or more positive permanent charges or may contain one or more functional groups that are cationizable in the composition according to the disclosure.
  • Non-limiting examples of cationic surfactants include cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethyl-amine, behenamidoethyldimethylamine, arachidamidoprop
  • the cationic surfactant is cetrimonium chloride, behentrimonium chloride, or a mixture thereof.
  • the cationic surfactant is stearamidopropyl dimethylamine.
  • cationic surfactants include behenalkonium chloride, benzethonium chloride, cetylpyridinium chloride, behentrimonium chloride, lauralkonium chloride, cetalkonium chloride, cetrimonium bromide, cetrimonium chloride, cethylamine hydrofluoride, chlorallylmethenamine chloride (Quaternium- 15), distearyldimonium chloride (Quaternium-5), dodecyl dimethyl ethylbenzyl ammonium chloride(Quatemium-14), Quaternium-22, Quatemium-26, Quaternium- 18 hectorite, dimethylaminoethylchloride hydrochloride, cysteine hydrochloride, diethanolammonium POE (10) oleyl ether phosphate, diethanolammonium POE (3)oleyl ether phosphat
  • the fatty amines generally comprise at least one Cs-Cso hydrocarbon-based chain.
  • R12 and R13 in some embodiments, denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, derived for example from tallow fatty acids, R14, in some embodiments, denotes a methyl group, and R15, in some embodiments, denotes a hydrogen atom.
  • R14 in some embodiments, denotes a methyl group
  • R15 in some embodiments, denotes a hydrogen atom.
  • Such a product is sold, for example, under the name REWOQUAT W 75 by the company Rewo.
  • Useful quaternary diammonium or triammonium salts includes those of the formula: in which R denotes an alkyl radical comprising approximately from 16 to 30 carbon atoms, which is optionally hydroxylated and/or interrupted with one or more oxygen atoms, Riz is chosen from hydrogen or an alkyl radical comprising from 1 to 4 carbon atoms or a group (Ri6a)(Ri7a)(Ri8a)N-(CH2)3, Ri6a, Ri7a, R a, R , R19, R20 and R21 , which may be identical or different, being chosen from hydrogen and an alkyl radical comprising from 1 to 4 carbon atoms, and X' is an anion chosen from the group of halides, acetates, phosphates, nitrates and methyl sulfates.
  • Such compounds are, for example, Finquat CT-P, sold by the company Finetex (Quaternium 89), and Finquat CT, sold by the company Finetex (
  • Useful cationic/cationizable surfactants include those of the general structure R4-A-R5 — B wherein R4 is a saturated or unsaturated, straight or branched alkyl chain with 8 to 24 C atoms, R5 is a straight or branched alkyl chain with 1 to 4 C atoms, A is selected from: an and B is selected from wherein Re and R7 are the same or different is H or an alkyl chain with 1 to 4 C atoms, hydroxyl alkyl chain with 1 to 4 C atoms and di hydroxyl alkyl chain with 2 to 4 C atoms, and
  • R. sub.10 is an alkyl chain with 1 to 4 C atoms, hydroxyl alkyl chain with 1 to 4 C atoms or di hydroxyl alkyl chain with 2 to 4 C atoms.
  • R4 is saturated or unsaturated, straight or branched alkyl chain with 10 to 24C atoms, in some embodiments, 12 to 22 C atoms and Rs is straight or branched alkyl group with 1 to 4 C atoms, and A, B, Rs to R10 are same as above.
  • Non-limiting suitable examples are stearyloxypropyl amine, palmityloxypropyl amine, stearyloxypropyldimethyl amine, stearyloxypropyldiethyl amine, stearyloxyethylyldimethyl amine, stearyloxyethyl amine, myristyloxypropyl amine, myristyloxypropyldimethyl amine, palmitamidopropyl amine, palmitamidopropyl methylamine, palmitamidopropyl diethylamine, palmitamidopropyl dibutylamine, palmitamidopropyl buylamine, palmitamidopropyl dipropylamine, palmitamidopropyl propylamine, palmitamidopropyl dihydroxyethylamine, palmitamidopropyl hydroxyethylamine, palmitamidopropyl dihydroxypropylamine, palmitamidoprop
  • Cationizable surfactants may be chosen from fatty alkylamines and fatty dialkylamines.
  • the fatty dialkylamines may be fatty dimethylamines.
  • Non-limiting examples include dimethyl lauramine, dimethyl behenamine, dimethyl cocamine, dimethyl myristamine, dimethyl palmitamine, dimethyl stearamine, dimethyl tallowamine, dimethyl soyamine, and mixtures thereof.
  • Fatty dialkylamines include fatty amidoamine compounds, their salts, and mixtures thereof.
  • Non-limiting examples include oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethyl-amine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamido-propyidiethylamine, arachidamidoethyidiethylamine, arachidamidoethyidimethylamine, brassicamidopropyldimethylamine, lauramidopropyl dimethylamine, myristamidopropyl dimethylamine,
  • At least one of the one or more cationic surfactants is a dialkyl dimonium compound, preferably a dialkyl dimonium halide compound.
  • dialkyl dimonium compounds include di-C12-15 alkyl dimonium chloride, C12-18 dialkyldimonium chloride, di-C12-18 alkyl dimonium chloride, dicapryl/dicaprylyl dimonium chloride, didecyldimonium chloride, dicetyldimonium chloride, ditallowdimonium chloride, dicocodimonium chloride, distearyldimonium chloride, ceteardimonium chloride, hydroxyethyl oleyl dimonium chloride, panthenyl hydroxypropyl steardimonium chloride, hydroxypropyl bis- hydroxyethyldimonium chloride, hydroxypropyl bisstearyldimonium chloride, hydroxycetyl hydroxy
  • the one or more cationic surfactants are selected from quaternary ammonium compounds, fatty dialkylamines, or a combination thereof, preferably wherein: the one or more quaternary ammonium compounds are selected from cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, or a combination thereof, preferably behentrimonium chloride; and the one or more fatty dialkylamines are selected from oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazo
  • the hair treatment composition includes about 0.5 to about 10 wt.% of the one or more cationic surfactants, based on the total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 0.5 to about 4 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 1 to about 4 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, about 2 to about 6 wt.%, about 2 to about 5 wt.%, or about 2 to about 4 wt.%, based on a total weight of the hair treatment composition.
  • the hair treatment composition may optionally include one or more cationic conditioning polymers (or simply “cationic polymers”) or cationizable conditioning polymers (or simply “cationizable polymers”).
  • cationic conditioning polymers or simply “cationic polymers”
  • cationizable conditioning polymers or simply “cationizable polymers”.
  • Non-limiting examples of cationic polymers include copolymers of 1 -vinyl-2- pyrrolidine and 1-vinyl-3-methyl-imidazolium salt (e.g., chloride salt) (referred to as Polyquaternium-16); copolymers of 1 -vinyl-2-pyrrolidine and dimethylaminoethyl methacrylate (referred to as Polyquaternium-11); cationic diallyl quaternary ammonium-containing polymer including, for example, dimethyldiallyammonium chloride homopolymer and copolymers of acrylamide and dimethyldiallyammonium chloride (referred to as Polyquaternium-6 and Polyquaternium-7); polysaccharide polymers, such as cationic cellulose derivatives and cationic starch derivatives.
  • Polyquaternium-16 copolymers of 1 -vinyl-2-pyrrolidine and 1-vinyl-3-methyl-imidazolium salt (e.g., chloride salt)
  • Polyquaternium-11
  • Cationic cellulose is available as salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide (referred to as Polyquatemium-10).
  • Another type of cationic cellulose includes the polymeric quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide (referred to as Polyquaternium-24).
  • the cationic conditioning polymers may include or be chosen from cationic guar gum derivatives, such as guar hydroxypropyltrimonium chloride.
  • the one or more cationic conditioning polymers include cationic polysaccharide polymers, such as cationic cellulose, cationic starch, and cationic guar gum.
  • cationic polysaccharide polymers include cationic polysaccharides and polysaccharide derivatives (e.g., derivatized to be cationic), for example, resulting in cationic cellulose (cellulose derivatized to be cationic), cationic starch (derivatized to be cationic), cationic guar (guar derivatized to be cationic).
  • the hair treatment compositions is free or essentially free from cationic guar and cationic guar derivatives, for example, hydroxypropyl guar hydroxypropyltrimonium chloride.
  • Non-limiting examples of cationic celluloses include hydroxyethylcellulose (also known as HEC), hydroxymethylcellulose, methylhydroxyethylcellulose, hydroxypropylcellulose (also known as HPC), hydroxybutylcellulose, hydroxyethylmethylcellulose (also known as methyl hydroxyethylcellulose) and hydroxypropylmethylcellulose (also known as HPMC), cetyl hydroxyethylcellulose, polyquaternium-10, polyquaternium-24, and mixtures thereof, preferably polyquaternium-10, polyquaternium-24, and mixtures thereof.
  • HEC hydroxyethylcellulose
  • HPC hydroxypropylcellulose
  • HPMC hydroxybutylcellulose
  • hydroxyethylmethylcellulose also known as methyl hydroxyethylcellulose
  • HPMC hydroxypropylmethylcellulose
  • cetyl hydroxyethylcellulose polyquaternium-10, polyquaternium-24, and mixtures thereof, preferably polyquaternium-10, polyquaternium-24, and mixtures
  • Non-limiting examples of cationic guar include guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride,
  • Non-limiting examples of cationic starch include starch hydroxypropyltrimonium chloride, hydroxypropyl oxidized starch PG trimonium chloride, and a mixture thereof.
  • the one or more cationic conditioning polymers are chosen from polyquaterniums.
  • Nonlimiting examples include Polyquaternium-1 (ethanol, 2, 2', 2" -nitrilotris-, polymer with 1 ,4-dichloro-2-butene and N,N,N',N'- tetramethyl-2-butene-1 ,4-diamine), Polyquaternium-2, (poly[bis(2-chloroethyl) ether- alt-1 ,3-bis[3-(dimethylamino)propyl]urea]), Polyquaternium-4, (hydroxyethyl cellulose dimethyl diallylammonium chloride copolymer; Diallyldimethylammonium chloridehydroxyethyl cellulose copolymer), Polyquaternium-5 (copolymer of acrylamide and quaternized dimethylammoniumethyl methacrylate), Polyquaternium-6 (poly(diallyldimethylammonium chloride)), Polyquaternium
  • the one or more cationic conditioning polymers are chosen from cationic cellulose derivatives, quaternized hydroxyethyl cellulose (e.g., polyquaternium-10), cationic starch derivatives, cationic guar gum derivatives, copolymers of acrylamide and dimethyldiallyammonium chloride (e.g., polyquaternium-7), polyquaterniums, and a mixture thereof.
  • the cationic polymer(s) may be selected from polyquaterniums, for example, polyquaterniums selected from polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquatemium-7, polyquaternium-10, polyquaternium-22, polyquaternium-37, polyquaternium-39, polyquaternium-47, polyquaternium-53, polyquaternium-67 and a mixture thereof.
  • polyquaterniums selected from polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquatemium-7, polyquaternium-10, polyquaternium-22, polyquaternium-37, polyquaternium-39, polyquaternium-47, polyquaternium-53, polyquaternium-67 and a mixture thereof.
  • a combination of two or more polyquaterniums can be useful.
  • a particularly preferred and useful cationic polymer is polyquaternium-10.
  • the cationic polymers may be a polyquaternium.
  • the cationic surfactants may be polyquaterniums selected from polyquaternium-1 , polyquaternium-2, polyquaternium-3, polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-8, polyquaternium-9, polyquaternium-10, polyquaternium-11 , polyquaternium-12, polyquaternium-13, polyquaternium-14, polyquaternium-15, polyquaternium-16, polyquaternium-17, polyquaternium-18, polyquaternium-19, polyquaternium-20, polyquaternium-21 , polyquaternium-22, polyquaternium-23, polyquaternium-24, polyquaternium-25, polyquaternium-26, polyquaternium-27, polyquaternium-28, polyquaternium-29, polyquaternium-30, polyquaternium-40, polyquaternium-41 , polyquaternium-42, polyquaternium-43, polyquaternium
  • the one or more cationic conditioning polymers are chosen from cationic proteins and cationic protein hydrolysates (e.g., hydroxypropyltrimonium hydrolyzed wheat protein), quaternary diammonium polymers (e.g., hexadimethrine chloride), copolymers of acrylamide and dimethyldiallyammonium chloride, and mixtures thereof.
  • cationic proteins and cationic protein hydrolysates e.g., hydroxypropyltrimonium hydrolyzed wheat protein
  • quaternary diammonium polymers e.g., hexadimethrine chloride
  • copolymers of acrylamide and dimethyldiallyammonium chloride e.g., hexadimethrine chloride
  • the cationic conditioning polymers may be homopolymers or formed from two or more types of monomers.
  • the molecular weight of the polymer may be between 5,000 and 10,000,000, typically at least 10,000, and preferably in the range 100,000 to about 2,000,000.
  • These polymers will typically have cationic nitrogen containing groups such as quaternary ammonium or protonated amino groups, or a mixture thereof.
  • the cationic charge density is suitably at least 0.1 meq/g, preferably above 0.8 or higher. In some instances, the cationic charge density does not exceed 3 meq/g, or does not exceed 2 meq/g.
  • the charge density can be measured using the Kjeldahl method and can be within the above limits at the desired pH of use, which will in general be from about 3 to 9 and preferably between 4 and 8.
  • Suitable cationic conditioning polymers include, for example, copolymers of vinyl monomers having cationic amine or quaternary ammonium functionalities with water soluble spacer monomers such as (meth)acrylamide, alkyl and dialkyl (meth)acrylamides, alkyl (meth)acrylate, vinyl caprolactone and vinyl pyrrolidine.
  • the alkyl and dialkyl substituted monomers preferably have C1-C7 alkyl groups, more preferably C1-C3 alkyl groups.
  • Other suitable spacers include vinyl esters, vinyl alcohol, maleic anhydride, propylene glycol and ethylene glycol.
  • the cationic amines can be primary, secondary or tertiary amines, depending upon the particular species and the pH of the composition.
  • Amine substituted vinyl monomers and amines can be polymerized in the amine form and then converted to ammonium by quaternization.
  • Suitable cationic amino and quaternary ammonium monomers include, for example, vinyl compounds substituted with dialkyl aminoalkyl acrylate, dialkylamino alkylmethacrylate, monoalkylaminoalkyl acrylate, monoalkylaminoalkyl methacrylate, trialkyl methacryloxyalkyl ammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salts, and vinyl quaternary ammonium monomers having cyclic cationic nitrogen-containing rings such as pyridinium, imidazolium, and quaternized pyrrolidine, e.g., alkyl vinyl imidazolium, and quaternized pyrrolidine, e.g., alkyl vinyl imidazolium, alkyl vinyl pyridinium, alkyl vinyl pyrrolidine salts.
  • the alkyl portions of these monomers are preferably lower alkyls such as the C1-C
  • Suitable amine-substituted vinyl monomers include dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, dialkylaminoalkyl acrylamide, and dialkylaminoalkyl methacrylamide, wherein the alkyl groups are preferably Ci -C7 hydrocarbyls, more preferably C1-C3, alkyls.
  • the cationic conditioning polymers can comprise mixtures of monomer units derived from amine- and/or quaternary ammonium-substituted monomer and/or compatible spacer monomers.
  • Suitable cationic conditioning polymers include, for example: copolymers of 1- vinyl-2-pyrrolidine and 1-vinyl-3-methyl-imidazolium salt (e.g., Chloride salt) (referred to as Polyquaternium-16) such as those commercially available from BASF under the LUVIQUAT tradename (e.g., LUVIQUAT FC 370); copolymers of 1 -vinyl-2- pyrrolidine and dimethylaminoethyl methacrylate (referred to as Polyquaternium-11) such as those commercially from Gar Corporation (Wayne, N.J., USA) under the GAFQUAT tradename (e.g., GAFQUAT 755N); and cationic diallyl quaternary ammonium-containing polymer including, for example, dimethyldiallyammonium chloride homopolymer and copolymers of acrylamide and dimethyldiallyammonium chloride (referred to as Polyquaternium-6 and Polyquaternium-7).
  • cationic conditioning polymers that can be used include cationic guar gum derivatives, such as guar hydroxypropyltrimonium chloride.
  • Polyquaterniums include Polyquaternium-1 (ethanol, 2, 2', 2 ' ' -nitrilotris-, polymer with 1 ,4-dichloro-2-butene and N,N,N',N'-tetramethyl-2-butene-1 ,4-diamine), Polyquaternium-2, (poly[bis(2-chloroethyl) ether-alt-1 ,3-bis[3- (dimethylamino)propyl]urea]), Polyquaternium-4, (hydroxyethyl cellulose dimethyl diallylammonium chloride copolymer; Diallyldimethylammonium chloridehydroxyethyl cellulose copolymer), Polyquaternium-5 (copolymer of acrylamide and quaternized dimethylammoniumethyl methacrylate), polyquaternium-6 (poly(diallyldimethylammonium chloride)), Polyquaternium-7 (copolymer of acrylamide and diallyldimethyl
  • the hair treatment composition includes about 0.1 to about 8 wt.% of the one or more cationic conditioning polymers, based on the total weight of the hair treatment composition.
  • the hair treatment composition includes about about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.1 to about 4 wt.%, about 0.1 to about 3 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 0.5 to about 4 wt.%, about 0.5 to about 3 wt.%, or about 0.5 to about 2 wt.%, based on the one or more cationic conditioning polymers, based on a total weight of the hair treatment composition.
  • fatty alcohol means an alcohol comprising at least one hydroxyl group (OH), and comprising at least 8 carbon atoms, and which is neither oxyalkylenated (in particular neither oxyethylenated nor oxypropylenated) nor glycerolated.
  • the fatty alcohols can be represented by: R-OH, wherein R denotes a saturated (alkyl) or unsaturated (alkenyl) group, linear or branched, optionally substituted with one or more hydroxyl groups, comprising from 8 to 40 carbon atoms, preferably 10 to 30 carbon atoms, more preferably 12 to 24 carbon atoms, and even more preferably 14 to 22 carbon atoms.
  • the fatty alcohols may be liquid or solid. In some instances, it is preferable that the hair treatment compositions include at least one solid fatty alcohol.
  • the solid fatty alcohols that may be used include those that are solid at ambient temperature and at atmospheric pressure (25°C, 780 mmHg), and are insoluble in water, that is to say they have a water solubility of less than 1% by weight, preferably less than 0.5% by weight, at 25°C, 1 atm.
  • the solid fatty alcohols may be represented by: R-OH, wherein R denotes a linear alkyl group, optionally substituted with one or more hydroxyl groups, comprising from 8 to 40 carbon atoms, preferably 10 to 30 carbon atoms, more preferably 12 to 24 carbon atoms, and even more preferably 14 to 22 carbon atoms.
  • Non-limiting examples of useful fatty alcohols include lauryl alcohol or lauryl alcohol (1 -dodecanol); myristic or myristyl alcohol (1 -tetradecanol); cetyl alcohol (1- hexadecanol); stearyl alcohol (1 -octadecanol); arachidyl alcohol (1-eicosanol); behenyl alcohol (1 -docosanol); lignoceryl alcohol (1 -tetracosanol); ceryl alcohol (1- hexacosanol); montanyl alcohol (1 -octacosanol); myricylic alcohol (1-triacontanol), and mixtures thereof.
  • the solid fatty alcohol is chosen from cetyl alcohol, stearyl alcohol, behenyl alcohol and mixtures thereof such as cetylstearyl or cetearyl alcohol.
  • the liquid fatty alcohol is a branched saturated alcohol.
  • R does not contain a hydroxyl group.
  • oleic alcohol linoleic alcohol, linolenic alcohol, isocetyl alcohol, isostearyl alcohol, 2-octyl-1-dodecanol, 2- butyloctanol, 2-hexyl- 1 -decanol, 2-decyl-1 -tetradecanol, 2-tetradecyl-1-cetanol and mixtures thereof.
  • the liquid fatty alcohol is 2-octyl-1 -dodecanol.
  • the hair treatment compositions include one or more fatty alcohols selected from decyl alcohol, undecyl alcohol, dodecyl, myristyl, cetyl alcohol, stearyl alcohol, cetearyl alcohol, isostearyl alcohol, isocetyl alcohol, behenyl alcohol, linalool, oleyl alcohol, myricyl alcohol and a mixture thereof.
  • the hair cosmetic compositions preferably include cetearyl alcohol.
  • the hair treatment composition includes about 1 to about 15 wt.% of the one or more fatty alcohols, based on the total weight of the hair treatment composition.
  • the hair treatment composition includes about 1 to about 12 wt.%, about 1 to about 10 wt.%, about 2 to about 15 wt.%, about 2 to about 12 wt.%, about 2 to about 10 wt.%, about 3 to about 15 wt.%, about 3 to about 12 wt.%, about 3 to about 10 wt.%, about 5 to 15 wt.%, about 5 to about 12 wt.%, or about 5 to about 10 wt.% of the one or more fatty alcohols, based on the total weight of the hair treatment composition.
  • the hair treatment composition includes about 55 to about 95 wt.% water.
  • the hair treatment composition includes about 55 to about 90 wt.%, about 55 to about 80 wt.%, about 55 to about 75 wt.%, about 60 to about 95 wt.%, about 60 to about 90 wt.%, about 60 to about 85 wt.%, about 60 to about 80 wt.%, about 60 to about 75 wt.%, about 65 to about 85 wt.%, about 65 to about 80 wt.%, or about 65 to about 75 wt.%, based on a total weight of the hair treatment composition.
  • the hair treatment compositions optionally include one or more nonionic thickening polymers (also referred to as “nonionic thickening agents” “rheology modifiers,” “thickening compounds,” “thickeners,” “gelling agents,” and the like.
  • nonionic thickening polymers include nonionic guar gums, sclerotium gum, biopolysaccharide gums of microbial origin, gums derived from plant exudates, celluloses, in particular hydroxypropylcelluloses or hydroxyethylcelluloses, pectins, and mixtures thereof.
  • Suitable nonionic thickening polymers include celluloses modified with groups comprising at least one fatty chain.
  • modified celluloses may include: hydroxyethylcelluloses modified with groups comprising at least one fatty chain, such as alkyl, arylalkyl or alkylaryl groups, or mixtures thereof, and in which the alkyl groups are preferably C8-C22, for instance the product NATROSOL PLUS GRADE 330 CS (016 alkyls) sold by the company Aquaion, or the product BERMOCOLL EHM 100 sold by the company Berol Nobel; and hydroxyethylcelluloses modified with alkylphenyl polyalkylene glycol ether groups, such as the product AMERCELL POLYMER HM-1500 (polyethylene glycol (15) nonylphenyl ether) sold by the company Amerchol,
  • Nonionic thickening polymers may include copolymers of vinylpyrrolidone and of fatty-chain hydrophobic monomers; copolymers of 01-06 alkyl methacrylates or acrylates and of amphiphilic monomers comprising at least one fatty chain; polyurethane polyethers comprising in their chain both hydrophilic blocks usually of polyoxyethylenated nature and hydrophobic blocks, which may be aliphatic sequences alone and/or cycloaliphatic and/or aromatic sequences; or polymers with an aminoplast ether backbone containing at least one fatty chain.
  • the nonionic thickening polymers may be selected from polysaccharides and associative polymers.
  • the preferred nonionic thickening agents are sclerotium gum, guar gums, hydroxyalkyl celluloses optionally modified with a hydrophobic group, such as hydroxyethylcelluloses, hydroxymethylcelluloses optionally modified with a hydrophobic group, and inulins optionally modified with a hydrophobic group.
  • sclerotium gum is particularly useful.
  • nonionic thickening polymers that may be mentioned are:
  • Celluloses modified with groups comprising at least one fatty chain examples that may be mentioned include: hydroxyethylcelluloses modified with groups comprising at least one fatty chain, such as alkyl, arylalkyl or alkylaryl groups, or mixtures thereof, and in which the alkyl groups are preferably C8-C22, for instance the product NATROSOL PLUS GRADE 330 OS (C16 alkyls) sold by the company Aquaion, or the product BERMOCOLL EHM 100 sold by the company Berol Nobel; and hydroxyethylcelluloses modified with alkylphenyl polyalkylene glycol ether groups, such as the product AMERCELL POLYMER HM-1500 (polyethylene glycol (15) nonylphenyl ether) sold by the company Amerchol, (2) Hydroxypropyl guars modified with groups comprising at least one fatty chain, such as the product ESAFLOR HM 22 (C22 alkyl chain) sold by the company Lamberti, and the products RE
  • Copolymers of vinylpyrrolidone and of fatty-chain hydrophobic monomers examples that may be mentioned include: the products ANTARON V216 or GAN EX V216 (vinylpyrrolidone/hexadecene copolymer) sold by the company I.S.P. the products ANTARON V220 or GANEX V220 (vinylpyrrolidone/eicosene copolymer) sold by the company I.S.P.,
  • Copolymers of hydrophilic methacrylates or acrylates and of hydrophobic monomers comprising at least one fatty chain for instance the polyethylene glycol methacrylate/lauryl methacrylate copolymer
  • Polyurethane polyethers comprising in their chain both hydrophilic blocks usually of polyoxyethylenated nature and hydrophobic blocks, which may be aliphatic sequences alone and/or cycloaliphatic and/or aromatic sequences.
  • At least one of the one or more thickening polymers in the cosmetic composition is a taurate copolymer.
  • Nonlimiting examples taurate copolymers include acrylamide/sodium acryloyl dimethyl taurate copolymer, hydroxyethyl acrylate/sodium acryloyl dimethyl taurate copolymer, ammonium acryloyldimethyl taurate/VP copolymer, sodium acrylate/sodium acryloyl dimethyl taurate copolymer, hydroxyethyl acrylate/ sodium acryloyldimethyl taurate copolymer, and a mixture thereof
  • the amount of the one or more nonionic thickening polymers will vary depending on the type of thickening polymers used; and depending on the desired viscosity of the hair treatment composition. Therefore, the total amount of the one or more thickening agents is sufficient to achieve the viscosities set forth throughout the instant disclosure. Nonetheless, in various embodiments, the hair treatment compositions include about 0.01 to about 8 wt.%, based on the total weight of the cosmetic composition.
  • the total amount of the one or more thickening agents is from about 0.01 to about 6 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 4 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.1 to about 4 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, or about 0.5 to about 4 wt.%, based on a total weight of the hair treatment composition.
  • the hair treatment compositions optionally include one or more surfactants, other than the cationic or cationizable surfactants mentioned above, which are characterized as cationic conditioning agents.
  • Surfactants include amphoteric (zwitterionic) surfactants, nonionic surfactants, and anionic surfactants.
  • the hair treatment compositions include one or more amphoteric surfactants, nonionic surfactants, or a combination thereof.
  • the hair treatment compositions include one or more amphoteric surfactants.
  • the hair treatment compositions include one or more nonionic surfactants.
  • the hair treatment compositions may optionally include one or more anionic surfactants but in various embodiments, the hair treatment compositions are free or essentially free from anionic surfactants.
  • the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more surfactants (other than the cationic and/or cationizable surfactants), based on a total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, about 2 to about 6 wt.%, or about 2 to about 5 wt.% of the one or more surfactants (other than the cationic and/or cationizable surfactants), based on a total weight of the hair treatment composition.
  • the one or more surfactants other than the cationic and/or cationizable surfactants
  • amphoteric Surfactants include alkyl betaines, alkyl sultaines, alkyl amphoacetates, alkyl amphoproprionates, and mixtures thereof.
  • the hair treatment compositions include one or more betaines and/or alkyl betaines.
  • useful amphoteric surfactants are provided below.
  • Useful betaines include those of the following formulae (Xla-XId):
  • R10 is an alkyl group having 8-18 carbon atoms; and n is an integer from 1 to 3.
  • Nonlimiting examples of useful betains include cocobetaine, cocam idopropyl betaine, lauryl betaine, laurylhydroxy sulfobetaine, lauryldimethyl betaine, cocamidopropyl hydroxysultaine, behenyl betaine, capryl/capram idopropyl betaine, lauryl hydroxysultaine, stearyl betaine, and mixtures thereof.
  • at least one betaine compound is selected from coco betaine, cocamidopropyl betaine, behenyl betaine, capryl/capram idopropyl betaine, and lauryl betaine, and mixtures thereof.
  • Particularly preferred betaines include coco betaine and cocamidopropyl betaine.
  • the total amount of alkyl betaines in the hair treatment compositions composition will vary. Nonetheless, in various embodiments the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more alkyl betaines, based on a total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, about 2 to about 6 wt.%, or about 2 to about 5 wt.% of the one or more alkyl betaines, based on a total weight of the hair treatment composition.
  • alkyl sultaines include hydroxyl sultaines of formula (XII) wherein R is an alkyl group having 8-18 carbon atoms. More specific examples include, but are not limited to cocamidopropyl hydroxysultaine, lauryl hydroxysultaine, and a mixture thereof.
  • the total amount of alkyl sultaines in the hair treatment compositions composition will vary. Nonetheless, in various embodiments the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more alkyl sulitaines, based on a total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, about 2 to about 6 wt.%, or about 2 to about 5 wt.% of the one or more alkyl sulitaines, based on a total weight of the hair treatment composition.
  • Nonlimiting examples of useful alkyl amphoacetates and alkyl amphodiacetates include those of Formula (XIII) and (XIV):
  • R is an alkyl group having 8-18 carbon atoms.
  • Sodium is shown as the cation in the above formulae above but the cation may be an alkali metal ion such as sodium or potassium, ammonium ions, or alkanolammonium ions such as monoethanolammonium or triethanolammonium ions.
  • alkali metal ion such as sodium or potassium, ammonium ions, or alkanolammonium ions such as monoethanolammonium or triethanolammonium ions.
  • a more specific, but nonlimiting example, is sodium lauroamphoacetate.
  • the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more alkyl amphoacetates and alkyl amphodiacetates, based on a total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, about 2 to about 6 wt.%, or about 2 to about 5 wt.% of the one or more alkyl amphoacetates and alkyl amphodiacetates, based on a total weight of the hair treatment composition.
  • Nonlimiting examples of useful alkyl amphopropionates include cocoampho- propionate, cornamphopropionatecaprylamphopropionate, cornampho-propionate, caproamphopropionate, oleoamphopropionate, isostearoamphopropionate, stearoamphopropionate, lauroamphopropionate, salts thereof, and a mixture thereof.
  • the total amount of alkyl amphopropionates in the hair treatment compositions composition will vary. Nonetheless, in various embodiments the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more alkyl amphopropionates, based on a total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, about 1 to about 5 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, about 2 to about 6 wt.%, or about 2 to about 5 wt.% of the one or more alkyl amphopropionates, based on a total weight of the hair treatment composition.
  • the hair treatment composition may optionally include or exclude (or be essentially free from) one or more nonionic surfactants.
  • nonionic surfactants include the following: (1) polyethylene oxide condensates of alkyl phenols, e.g., the condensation products of alkyl phenols having an alkyl group containing from about 6 to about 20 carbon atoms in either a straight chain or branched chain configuration, with ethylene oxide, the said ethylene oxide being present in amounts equal to from about 10 to about 60 moles of ethylene oxide per mole of alkyl phenol; (2) those derived from the condensation of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine products;
  • R 1 contains an alkyl, alkenyl or monohydroxy alkyl radical of from about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxide moieties, and from 0 to about 1 glyceryl moiety
  • R 2 and R 3 contain from about 1 to about 3 carbon atoms and from 0 to about 1 hydroxy group, e.g., methyl, ethyl, propyl, hydroxyethyl, or hydroxypropyl radicals;
  • R contains an alkyl, alkenyl or monohydroxyalkyl radical ranging from about 8 to about 18 carbon atoms in chain length, from 0 to about 10 ethylene oxide moieties and from 0 to 1 glyceryl moieties and R' and R" are each alkyl or monohydroxyalkyl groups containing from about 1 to about 3 carbon atoms;
  • long chain dialkyl sulfoxides containing one short chain alkyl or hydroxy alkyl radical of from 1 to about 3 carbon atoms (usually methyl) and one long hydrophobic chain which include alkyl, alkenyl, hydroxy alkyl, or keto alkyl radicals containing from about 8 to about 20 carbon atoms, from 0 to about 10 ethylene oxide moieties and from 0 to 1 glyceryl moieties;
  • alkyl polysaccharide (APS) surfactants e.g. alkyl polyglycosides
  • APS surfactants having a hydrophobic group with about 6 to about 30 carbon atoms and a polysaccharide (e.g., polyglycoside) as the hydrophilic group; optionally, there can be a polyalkylene-oxide group joining the hydrophobic and hydrophilic moieties; and the alkyl group (i.e.
  • the hydrophobic moiety can be saturated or unsaturated, branched or unbranched, and unsubstituted or substituted (e.g., with hydroxy or cyclic rings); a preferred material is alkyl polyglucoside, which is commercially available from Henkel, ICI Americas, and Seppic; and
  • polyoxyethylene alkyl ethers such as those of the formula RO(CH2CH2O) n H and polyethylene glycol (PEG) glyceryl fatty esters, such as those of the formula R(O)OCH2CH(OH)CH2(OCH 2CH2)nOH, wherein n is from 1 to about 200, preferably from about 20 to about 100, and R is an alkyl having from about 8 to about 22 carbon atoms.
  • polyethylene glycol derivatives of glycerides as described in the above (8) useful herein include derivatives of mono-, di- and tri-glycerides and mixtures thereof.
  • polyethylene glycol derivatives of glycerides suitable herein is those which conform to the general formula (I): wherein n, the degree of ethoxylation, is from about 4 to about 200, preferably from about 5 to about 150, more preferably from about 20 to about 120, and wherein R comprises an aliphatic radical having from about 5 to about 25 carbon atoms, preferably from about 7 to about 20 carbon atoms.
  • Suitable polyethylene glycol derivatives of glycerides can be polyethylene glycol derivatives of hydrogenated castor oil.
  • Such polyethylene glycol derivatives of hydrogenated castor oil include, for example, PEG-20 hydrogenated castor oil, PEG-30 hydrogenated castor oil, PEG-40 hydrogenated castor oil, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG- 60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, and PEG-100 hydrogenated castor oil.
  • polyethylene glycol derivatives of glycerides can be polyethylene glycol derivatives of stearic acid.
  • Such polyethylene glycol derivatives of stearic acid include, for example, PEG-30 stearate, PEG-40 stearate, PEG-50 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, and PEG-150 stearate.
  • Ethylene glycol ethers of fatty alcohols as described in the above (3) or (8), useful herein include any ethylene glycol ethers of fatty alcohols which are suitable for use in a hair conditioning composition.
  • the ethylene glycol ethers of fatty alcohols include; the ceteth series of compounds such as ceteth-1 through ceteth-45, preferably ceteth-7 through ceteth-20; the isoceteth series of compounds such as isoceteth-20; the steareth series of compounds such as steareth-1 through 100; ceteareth 1 through ceteareth-50; the laureth series of compounds, preferably laureth-7 through Laureth-12; the pareth series of compounds, preferably pareth-9 through pareth-15; propylene glycol ethers of the above ceteth, steareth, ceteareth, and laureth series of compounds, such propylene glycol ethers of ceteth series of compounds including, for example, PPG-5-Ceteth-
  • nonionic surfactants useful herein include, for example, polysorbates such as polysorbate-20 (POE(20) sorbitan monolaurate) having HLB value of 16.7, polysorbate-21 (POE(4) sorbitan monolaurate) having HLB value of 13.3, polysorbate-40 (POE(20) sorbitan monopalmitate) having HLB value of 15.6, polysorbate-60 (POE(20) sorbitan monostearate) having HLB value of 14.9, polysorbate-61 (POE(4) sorbitan monostearate) having HLB value of 9.6, polysorbate-80 (POE(20)sorbitan monooleate) having HLB value of 15.0, and polysorbate-81 (POE(4) sorbitan monooleate) having HLB value of 10.0.
  • polysorbates such as polysorbate-20 (POE(20) sorbitan monolaurate) having HLB value of 16.7, polysorbate-21 (POE(4) sorbitan monolaurate) having
  • one or more nonionic surfactants are selected from the group consisting of PEG-40 hydrogenated castor oil, steareth-2, steareth-20, polysorbate 60, polyclyceryl-3 stearate, glyceryl stearate citrate, and a mixture thereof.
  • the one or more nonionic surfactants includes PEG-40 hydrogenated castor oil.
  • the one or more nonionic surfactants include alkoxylated fatty alcohols or polyethylene glycol ethers of mixtures of C8-C30 fatty alcohols with an average of number of moles of ethylene oxide such as C11-15 Pareth-7, laureth-9, laureth-12, deceth-7, deceth-10, trideceth-6, trideceth-10, trideceth-12, or a mixture thereof.
  • the total amount of the one or more nonionic surfactants in the hair treatment composition, if present, will vary.
  • the hair treatment composition includes about 0.01 to about 10 wt.% of the one or more nonionic surfactants, based on a total weight of the hair styling composition.
  • the hair treatment composition includes about 0.01 to about 8 wt.%, about 0.01 to about 6 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.05 to about 10 wt.%, about 0.05 to about 8 wt.%, about 0.05 to about 6 wt.%, about 0.05 to about 5 wt.%, about 0.05 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.1 to about 3 wt.%, based on a total weight of the hair treatment composition.
  • amino-functionalized silicone or “amino silicones” means a silicone containing at least one primary amino, secondary amino, tertiary amino and/or quaternary ammonium group.
  • the structure of the amino-functionalized silicone may be linear or branched, cyclic or non-cyclic.
  • the amino functional group may be at any position in the silicone molecule, preferably at the end of the backbone (for example, in the case of amodimethicones) and/or in the side chain.
  • an amino-functionalized silicones is selected from compounds having the following formula: wherein each R 1 is independently selected from a C1-30 alkyl group, a C1-30 alkoxy group, a C5-30 aryl group, a C6-30 aralkyl group, a C6-30 aralkyloxy group, a Ci-3o alkaryl group, a C1-30 alkoxyaryl group, and a hydroxy group (preferably, each R 1 is independently selected from a C1-30 alkyl group, a C1-30 alkoxy group and a hydroxy group); each R 2 is independently a divalent alkylene radical having one to ten carbon atoms (preferably, R 2 is a divalent alkylene radical having three to six carbon atoms); each R 3 is independently selected from a C1-30 alkyl group, a C5-30 aryl group, a Ce-30 aralkyl group and a C1-30 alkaryl group (preferably, each R 3 is independently selected from of a C1-30 alky
  • Q is a monovalent radical selected from -NR 4 2 and -NR 4 (CH2)%NR 4 2; each R 4 is independently selected from a hydrogen and a C1-4 alkyl group; x is 2 to 6; z is 0 or 1 ; n is 25 to 3,000 (preferably, 25 to 2,000; more preferably, 25 to 1 ,000; most preferably 25 to 500); and m is 0 to 3,000 (preferably, 0 to 2,000; more preferably, 0 to 1 ,000; most preferably, 0 to 100); with the proviso that at least 50 mol% of the total number of R 1 and R 3 groups are methyl and with the proviso that when m is 0, z is 1 .
  • R 1 groups include methyl, methoxy, ethyl, ethoxy, propyl, propoxy, isopropyl, isopropoxy, butyl, butoxy, isobutyl, isobutoxy, phenyl, xenyl, benzyl, phenylethyl, tolyl and hydoxy.
  • Preferred R 2 divalent alkylene radicals include trimethylene, tetramethylene, pentamethylene, -CH 2 CH(CH 3 )CH2- and -CH2CH 2 CH(CH 3 )CH2-.
  • Preferred R 3 groups include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, phenyl, xenyl, benzyl, phenylethyl and tolyl.
  • Preferred R 4 groups include methyl, ethyl, propyl, isopropyl, butyl and isobutyl.
  • the amino-functionalized silicine has only pendant amine functional substituents in the polymer chain.
  • n + m is 50 to 1 ,000. More preferably, n + m is 50 to 750. Still more preferably, n + m is 50 to 500. Most preferably, n + m is 50 to 250.
  • the amino-functionalized silicones are alkoxylated and/or hydroxylated amino silicones.
  • Suitable alkoxylated and/or hydroxylated amino silicones may be selected from compounds of the following formula: wherein R 3 is hydroxyl or ORs, Rs is a Ci to C4 alkyl group, R4 is a group with structure according to the following formula: - CH Z CH CH 2 NH (CH 2 ) réelle NH 2
  • Re is a Ci to C4 alkyl
  • n is a 1 to 4
  • x is the same as “n” described above
  • y is the same as “m” described above.
  • the silicone may be a polysiloxane corresponding to the following formula: in which x' and y' are integers such that the weight-average molecular weight (Mw) is comprised between about 5000 and 500 000; b) amino silicones corresponding to following formula:
  • G which may be identical or different, designate a hydrogen atom, or a phenyl, OH or Ci-Ca alkyl group, for example methyl, or Ci-Cs alkoxy, for example methoxy, a, which may be identical or different, denote the number 0 or an integer from 1 to 3, in particular 0; b denotes 0 or 1 , and in particular 1 ; m and n are numbers such that the sum (n + m) ranges from 1 to 2000 and in particular from 50 to 150, it being possible for n to denote a number from 0 to 1999 and in particular from 49 to 149, and for m to denote a number from 1 to 2000 and in particular from 1 to 10;
  • R' which may be identical or different, denote a monovalent radical having formula -CqH2qL in which q is a number ranging from 2 to 8 and L is an optionally quaternized amino group chosen from the following groups:
  • R which may be identical or different, denote hydrogen, phenyl, benzyl, or a saturated monovalent hydrocarbon-based radical, for example a Ci-C 2 o alkyl radical
  • Q denotes a linear or branched CrH 2r group, r being an integer ranging from 2 to 6, preferably from 2 to 4
  • A- represents a cosmetically acceptable ion, in particular a halide such as fluoride, chloride, bromide or iodide.
  • silicones having the following formula: in which: m and n are numbers such that the sum (n + m) can range from 1 to 1000, in particular from 50 to 250 and more particularly from 100 to 200, it being possible for n to denote a number from 0 to 999 and in particular from 49 to 249, and more particularly from 125 to 175, and for m to denote a number from 1 to 1000 and in particular from 1 to 10, and more particularly from 1 to 5;
  • Ri, R2, R3, which may be identical or different, represent a hydroxy or C1-C4 alkoxy radical, where at least one of the radicals R1 to R3 denotes an alkoxy radical.
  • the alkoxy radical is preferably a methoxy radical.
  • the hydroxy/alkoxy mole ratio ranges preferably from 0.2:1 to 0.4:1 and preferably from 0.25:1 to 0.35:1 and more particularly equals 0.3:1.
  • the weight-average molecular weight (Mw) of the silicone ranges preferably from 2,000 to 1 ,000,000, more particularly from 3,500 to 200,000.
  • Another group of amino silicones corresponding to this definition is represented by the following formula: in which: p and q are numbers such that the sum (p + q) ranges from 1 to 1000, particularly from 50 to 350, and more particularly from 150 to 250; it being possible for p to denote a number from 0 to 999 and in particular from 49 to 349, and more particularly from 159 to 239 and for q to denote a number from 1 to 1000, in particular from 1 to 10, and more particularly from 1 to 5;
  • the alkoxy radical is preferably a methoxy radical.
  • the hydroxy/alkoxy mole ratio ranges generally from 1 :0.8 to 1 :1.1 and preferably from 1 :0.9 to 1 :1 and more particularly equals 1 :0.95.
  • n and n are numbers such that the sum (n + m) ranges from 1 to 2000 and in particular from 50 to 150, it being possible for n to denote a number from 0 to 1999 and in particular from 49 to 149, and for m to denote a number from 1 to 2000 and in particular from 1 to 10;
  • A denotes a linear or branched alkylene radical containing from 4 to 8 carbon atoms and preferably 4 carbon atoms. This radical is preferably linear.
  • the weight-average molecular weight (Mw) of these amino silicones ranges preferably from 2000 to 1 000 000 and even more particularly from 3500 to 200 000.
  • Another group of amino silicones is represented by the following formula: in which: m and n are numbers such that the sum (n + m) ranges from 1 to 2000 and in particular from 50 to 150, it being possible for n to denote a number from 0 to 1999 and in particular from 49 to 149, and for m to denote a number from 1 to 2000 and in particular from 1 to 10;
  • A denotes a linear or branched alkylene radical containing from 4 to 8 carbon atoms and preferably 4 carbon atoms. This radical is preferably branched.
  • the weight-average molecular weight (Mw) of these amino silicones ranges preferably from 500 to 1 000 000 and even more particularly from 1000 to 200 000.
  • Rs represents a monovalent hydrocarbon-based radical containing from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl or C2-Cis alkenyl radical, for example methyl;
  • Re represents a divalent hydrocarbon-based radical, in particular a C1-C18 alkylene radical or a divalent C1-C18, for example Ci-Cs, alkylenoxy radical linked to the Si via an SiC bond;
  • Q- is an anion such as a halide ion, in particular chloride, or an organic acid salt (for example acetate); r represents a mean statistical value from 2 to 20 and in particular from 2 to 8; s represents a mean statistical value from 20 to 200 and in particular from 20 to 50.
  • a group of quaternary ammonium silicones is represented by the following formula: in which:
  • R7 which may be identical or different, represent a monovalent hydrocarbonbased radical containing from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a ring containing 5 or 6 carbon atoms, for example methyl;
  • Re represents a divalent hydrocarbon-based radical, in particular a C1-C18 alkylene radical or a divalent C1-C18, for example Ci-Cs, alkylenoxy radical linked to the Si via an SiC bond;
  • R which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon-based radical containing from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a -Re-NHCOR? radical;
  • X- is an anion such as a halide ion, in particular chloride, or an organic acid salt (for example acetate); r represents a mean statistical value from 2 to 200 and in particular from 5 to 100.
  • a group of quaternary ammonium silicones is represented by the following formula: in which:
  • AB multiblockpolyoxyalkylenated amino silicones
  • Said silicones are preferably constituted of repeating units having the following general formulae:
  • a is an integer greater than or equal to 1 , preferably ranging from 5 to 200, more particularly ranging from 10 to 100;
  • b is an integer comprised between 0 and 200, preferably ranging from 4 to 100, more particularly between from 5 and 30;
  • x is an integer ranging from 1 to 10 000, more particularly from 10 to 5000;
  • R" is a hydrogen atom or a methyl
  • R which may be identical or different, represent a divalent linear or branched C 2 -Ci 2 hydrocarbon-based radical, optionally including one or more heteroatoms such as oxygen; preferably, R denotes an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a - CH 2 CH 2 CH 2 OCH(OH)CH 2 - radical; preferentially R denotes a - CH 2 CH 2 CH 2 OCH(OH)CH 2 - radical;
  • R' which may be identical or different, represent a divalent linear or branched C 2 -Ci 2 hydrocarbon-based radical, optionally including one or more heteroatoms such as oxygen; preferably, R' denotes an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a - CH2CH 2 CH 2 OCH(OH)CH2- radical; preferentially R' denotes -CH(CH 3 )-CH 2 -.
  • the siloxane blocks preferably represent between 50 and 95 mol% of the total weight of the silicone, more particularly from 70 to 85 mol%.
  • the amine content is preferably between 0.02 and 0.5 meq/g of copolymer in a 30% solution in dipropylene glycol, more particularly between 0.05 and 0.2.
  • the weight-average molecular weight (Mw) of the silicone oil is preferably comprised between 5000 and 1 ,000,000, more particularly between 10,000 and 200,000.
  • Non-limiting examples of amino-functionalized silicones include bis- hydroxy/methoxy amodimethicones, bis-cetearyl amodimethicone, amodimethicone, bis(C13-15 alkoxy) PG amodimethicones, aminopropyl phenyl trimethicones, aminopropyl dimethicones, bis-amino PEG/PPG-41/3 aminoethyl PG-propyl dimethicones, caprylyl methicones, and a mixture thereof.
  • a particularly useful amino-functionalized silicone is bis-hydroxy/methoxy amodimethicone, wherein X is isobutyl and one of the R is OH and the other is OCHs in the above structure, also known as “ Bis- Hydroxy/M ethoxy Amodimethicone” and “3-[(2-aminoethyl)amino]-2-methylpropyl Me, di-Me, [(hydroxydimethylsilyl)oxy]- and [(methoxydimethylsilyl)oxy]-terminated.”
  • Bis-hydroxy/methoxy amodimethicone is commercially available under the tradename DOWSIL AP-8087 FLUID from The Dow Chemical Company.
  • a particularly preferred amino-functionalized silicone is amodimethicone”
  • a product containing amino silicones having structure (E) is sold by Wacker under the name FLUID WR 1300.
  • the weight-average molecular weight (Mw) of the silicone ranges preferably from 2,000 to 200,000, even more particularly 5,000 to 100,000 and more particularly from 10,000 to 50,000.
  • the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more amino- functionalized silicone, based on the total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, or about 0.5 to about 4 wt.% of the one or more amino-functionalized silicones, based on a total weight of the hair treatment composition.
  • water soluble organic solvent is interchangeable with the terms “water soluble solvent” and “water-miscible solvent” and means a compound that is liquid at 25°C and at atmospheric pressure (760 mmHg), and it has a solubility of at least 50% in water under these conditions. In some cases, the water-soluble solvents has a solubility of at least 60%, 70%, 80%, or 90%.
  • water-soluble solvents include, for example, organic solvents selected from glycerin, alcohols (for example Ci-s, or C1-4 alcohols), polyols (polyhydric alcohols), glycols other than the glycols of (b), and a mixture thereof.
  • Non-limiting examples of water soluble organic solvents include monoalcohols and polyols such as ethyl alcohol, isopropyl alcohol, propyl alcohol, benzyl alcohol, and phenylethyl alcohol, or glycols or glycol ethers such as, for example, monomethyl, monoethyl and monobutyl ethers of ethylene glycol, ethers of propylene glycol, for example, monomethyl ether of propylene glycol, butylene glycol, hexylene glycol, dipropylene glycol as well as alkyl ethers of diethylene glycol, for example monoethyl ether or monobutyl ether of diethylene glycol.
  • Other suitable examples of organic solvents are ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, propane diol, and glycerin.
  • the organic solvents can be volatile or non-volatile compounds.
  • water soluble organic solvents include alkanediols (polyhydric alcohols) such as glycerin, 1 ,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, dipropylene glycol, 2-butene-1 ,4- diol, 2-ethyl-1 ,3-hexanediol, 2-methyl-2,4-pentanediol, (caprylyl glycol), 1 ,2- hexanediol, 1 ,2-pentanediol, and 4-methyl-1 ,2-pentanediol; alkyl alcohols having 1 to 4 carbon atoms such as ethanol, methanol, butanol, propanol, and isopropanol; glycol ethers such as ethylene glycol monomethyl ether,
  • Polyhydric alcohols are useful.
  • examples of polyhydric alcohols include glycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1 ,3-butanediol, 2,3-butanediol, 1 ,4-butanediol, 3-methyl-1 ,3-butanediol, 1 ,5-pentanediol, tetraethylene glycol, 1 ,6-hexanediol, 2- methyl-2,4-pentanediol, polyethylene glycol, 1 ,2,4-butanetriol, 1 ,2,6-hexanetriol, and a mixture thereof.
  • Polyol compounds may also be used.
  • Non-limiting examples include the aliphatic diols, such as 2-ethyl-2-methyl-1 ,3-propanediol, 3,3-dimethyl- 1 ,2-butanediol, 2, 2-diethyl-1 ,3-propanediol, 2-methyl-2-propyl-1 ,3-propanediol, 2,4- dimethyl-2,4-pentanediol, 2,5-dimethyl-2,5-hexanediol, 5-hexene-1 ,2-diol, and 2- ethyl-1 ,3-hexanediol, and a mixture thereof.
  • the hair treatment composition includes about 0.1 to about 10 wt.% of the one or more water soluble organic solvents, based on a total weight of the hair styling composition.
  • the hair styling composition includes about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 6 wt.%, about 0.5 to about 5 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 6 wt.%, or about 1 to about 5 wt.% of the one or more water soluble organic solvents, based on a total weight of the hair styling composition.
  • the hair treatment compositions optionally include or excludes (or is essentially free from) one or more miscellaneous ingredients.
  • the hair treatment composition includes one or more miscellaneous ingredients.
  • Miscellaneous ingredients are ingredients that are compatible with the hair treatment compositions and do not disrupt or materially affect the basic and novel properties of the compositions.
  • miscellaneous ingredients include preservatives, fragrances, pH adjusters, salts, chelating agents, amino acids (e.g., taurine), buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and/or isolates, fillers (e.g., organic and/or inorganic fillers such as talc, calcium carbonate, silica, particular materials, etc.) composition colorants, etc.
  • the miscellaneous ingredients are chosen from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, composition colorants, vegetal or botanic extracts, and mixtures thereof.
  • composition colorant is a compound that colors the composition but does not have an appreciable coloring effect on hair.
  • the composition colorant is included to provide a coloring to the composition for aesthetic appeal but is not intended to impart coloring properties to hair.
  • Styling gels for example, can be found in a variety of different colors (e.g., light blue, light pink, etc.) yet application of the styling gel to hair does not visibly change the color of the hair.
  • pearlescent agents are considered composition colorants. Pearlescent agents are cosmetic ingredients primarily used to give a shimmering effect or pearlescent effect to the composition. They can be used to enhance the visual appeal of the hair treatment composition.
  • miscellaneous ingredients can also be considered miscellaneous ingredients if not expressly set forth as an independent component of the hair treatment composition.
  • miscellaneous ingredient is understood as a catch-all phrase representing additional components that may optionally be present in amounts designated for the miscellaneous ingredients.
  • the hair treatment composition includes about 0.01 to about 10 wt.% of the one or more miscellaneous ingredients, based on a total weight of the hair treatment composition.
  • the hair treatment composition includes about 0.01 to about 8 wt.%, about 0.01 to about 6 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.05 to about 10 wt.%, about 0.05 to about 8 wt.%, about 0.05 to about 6 wt.%, about 0.05 to about 5 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.% of one or more miscellaneous ingredients, based on a total weight of the hair treatment composition.
  • the hair treatment composition is an oil-in-water composition that comprises or consists of:
  • composition preferably includes about 2 to about 20 wt.%, preferably about 3 to about 15 wt.%, more preferably about 5 to about 12 wt.% of one or more glycols selected from ethylene glycol, propylene glycol, butylene glycol, pentylene glycol, dipropylene glycol, or a combination thereof, wherein the composition preferably includes about 2 to about 20 wt.%, preferably about 3 to about 15 wt.%, more preferably about 5 to about 12 wt.% of propylene glycol;
  • hair treatment compositions include about 1 to about 12 wt.%, preferably about 2 to about 10 wt.%, more preferably about 2 to about 6 wt.% of one or more cationic conditioning agents, preferably wherein the hair treatment compositions include about 1 to about 12 wt.%, preferably about 2 to about 10 wt.%, more preferably about 2 to about 6 wt.% of one or more cationic surfactants; (d) about 1 to about 15 wt.%, preferably about 2 to about 12 wt.%, more preferably about 5 to about 10 wt.% of one or more fatty alcohols
  • the hair treatment optionally includes one or more of: (f) one or more nonionic thickening polymers; (g) one or more alkyl betaines; (h) one or more amino-functionalized silicone oils; (i) one or more water-soluble organic solvents; and/or (j) up to about 10 wt.% of one or more miscellaneous ingredients.
  • the hair treatment composition is an oil-in-water composition that comprises or consists of:
  • polyether-modified polysiloxanes selected from PEGylated dimethicones, bis-PEGylated dimethicones, PEG/PPG dimethicones, or a combination thereof, wherein: the PEGylated dimethicones are selected from PEG-10 dimethicone, PEG-9 dimethicone, PEG-8 dimethicone, PEG-3 dimethicone, PEG-7 dimethicone, PEG-12 dimethicone, PEG-11 methyl ether dimethicone, PEG-32-dimethicone, PEG-14 dimethicone, PEG-17 dimethicone, or a combination thereof; the bis-PEGylated dimethicones are selected from bis-PEG-[10- 20] dimethicone, bis-PEG-10 dimethicon
  • (f) optionally, about 0.01 to about 6 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.% of one or more nonionic thickening polymers, preferably wherein at least one of the one or more nonionic thickening polymers is selected from polysaccharides and associative polymers, in particular, sclerotium gum, guar gums, hydroxyalkyl celluloses optionally modified with a hydrophobic group, such as hydroxyethylcelluloses, hydroxymethylcelluloses optionally modified with a hydrophobic group, and inulins optionally modified with a hydrophobic group;
  • (g) optionally, about 0.1 to about 10 wt.%, preferably about 0.5 to about 8, more preferably about 1 to about 6 wt.% of one or more amphoteric surfactants selected from alkyl betaines, alkyl sultaines, alkyl amphoacetates, alkyl amphoproprionates, or a combination thereof, wherein preferably at least one of the one or more amphoteric surfactants is an alkyl betaine;
  • (h) optionally, about 0.1 to about 10 wt.%, preferably about 0.1 to about 8 wt.%, more preferably about 0.5 to about 6 wt.% of one or more aminofunctionalized silicone oils, preferably amodimethicone;
  • mono-alcohols for example C1-6 or Ci-4 mono-alcohols
  • polyols polyhydric alcohols
  • a mixture thereof more preferably selected from C1-6 or Ci-4 mono-alcohols
  • miscellaneous ingredients preferably one or more miscellaneous ingredients selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, amino acids (e.g., taurine), botanical extracts, UV filtering agents, proteins, protein hydrolysates, and/or isolates, fillers (e.g., organic and/or inorganic fillers such as talc, calcium carbonate, silica, particular materials, etc.) composition colorants, or a mixture thereof; wherein all weight percentages are based on a total weight of the composition.
  • miscellaneous ingredients preferably one or more miscellaneous ingredients selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, amino acids (e.g., taurine), botanical extracts, UV filtering agents, proteins, protein hydrolysates, and/or isolates, fillers (e.g., organic and/or inorganic fillers such as tal
  • the hair treatment composition is an oil-in-water composition that comprises or consists of:
  • polyether-modified polysiloxanes selected from PEGylated dimethicones, bis-PEGylated dimethicones, PEG/PPG dimethicones, or a combination thereof, wherein: the PEGylated dimethicones are selected from PEG-10 dimethicone, PEG-9 dimethicone, PEG-8 dimethicone, PEG-3 dimethicone, PEG-7 dimethicone, PEG-12 dimethicone, PEG-11 methyl ether dimethicone, PEG-32-dimethicone, PEG-14 dimethicone, PEG-17 dimethicone, or a combination thereof; the bis-PEGylated dimethicones are selected from bis-PEG-[10- 20] dimethicone, bis-PEG-10 dimethicon
  • cationic surfactants selected from: more quaternary ammonium compounds selected from cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, and mixtures thereof; and/or one or more fatty dialkylamines selected from oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamido
  • nonionic thickening polymers selected from polysaccharides and associative polymers, in particular, sclerotium gum, guar gums, hydroxyalkyl celluloses optionally modified with a hydrophobic group, such as hydroxyethylcelluloses, hydroxymethylcelluloses optionally modified with a hydrophobic group, and inulins optionally modified with a hydrophobic group;
  • alkyl betaines selected from cocobetaine, cocamidopropyl betaine, lauryl betaine, laurylhydroxy sulfobetaine, lauryldimethyl betaine, cocamidopropyl hydroxysultaine, behenyl betaine, capryl/capramidopropyl betaine, lauryl hydroxysultaine, stearyl betaine, and mixtures thereof.
  • At least one betaine compound is selected from coco betaine, cocamidopropyl betaine, behenyl betaine, capryl/capramidopropyl betaine, and lauryl betaine, and mixtures thereof, more preferably cocobetaine;
  • (h) optionally, about 0.1 to about 10 wt.%, preferably about 0.1 to about 8 wt.%, more preferably about 0.5 to about 6 wt.% of one or more aminofunctionalized silicone oils, preferably amodimethicone;
  • the hair treatment compositions described throughout the instant disclosure are free or essentially free from anionic surfactants.
  • the hair treatment composition includes less than 1 wt.% of anionic surfactants.
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of anionic surfactants.
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of one or more anionic surfactants.
  • the hair treatment compositions of the instant disclosure are free or essentially free from glycerin (glycerol).
  • the hair treatment composition includes less than 1 wt.% of glycerin.
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of glycerin.
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of glycerin.
  • the hair treatment compositions of the instant disclosure are free or essentially free from silicones other than the (a) one or more polyether-modified polysiloxanes and the (h) one or more amino-functionalized silicones.
  • the compositions may be free or essentially free from dimethicone, methicone, dimethiconol, and the like.
  • the hair treatment composition includes less than 1 wt.% of silicones other than the (a) one or more polyether-modified polysiloxanes and the (h) one or more aminofunctionalized silicones.
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of silicones other than the (a) one or more polyether-modified polysiloxanes and the (h) one or more amino-functionalized silicones.
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of one or more silicones other than the (a) one or more polyether-modified polysiloxanes and the (h) one or more amino-functionalized silicones.
  • the hair treatment compositions of the instant disclosure are free or essentially free from hair styling polymers (film-forming polymers) other than cationic conditioning polymers of (c), which may optionally exhibit film forming properties.
  • hair styling polymers or film forming polymers
  • Non-limiting examples of hair styling polymers (or film forming polymers) include nonionic hair styling polymers (or nonionic film forming polymers), anionic hair styling polymers (or anionic film forming polymers), amphoteric hair styling polymers (or amphoteric film forming polymers), or a combination thereof.
  • Cationic styling polymers (cationic film forming polymers) may also be excluded or essentially excluded to the extent such cationic hair styling polymers (or cationic film forming polymers) are not included as a cationic conditioning agent of (c).
  • the one or more cationic conditioning agents of (c) encompass cationic surfactants and cationic conditioning polymers.
  • Some cationic conditioning polymers have filmforming properties and some cationic film-forming polymers have conditioning properties.
  • the hair treatment compositions of the instant disclosure can optionally include one or more cationic conditioning polymers even if the cationic conditioning polymers have film-forming qualities.
  • the hair treatment compositions of the instant disclosure can optionally include one or more cationic conditioning polymers that do not necessarily provide appreciable film-forming properties to the hair (but provide conditioning properties to the hair) and therefore it is conceivable that such hair styling compositions could be free or essentially free from cationic film-forming polymers.
  • Nonlimiting examples of nonionic hair styling polymers include PVPs (polyvinylpyrrolidones) and N-vinylpyrrolidone/vinylacetate copolymers; and polymers obtained from polymerization of at least one type of monomers selected from vinylpyrrolidone, vinylcaprolactam, vinyl esters, vinyl alcohol, vinyl acetate, (meth)acrylamide, and/or its derivatives, (meth)acrylic acid, propylene and/or ethylene glycol acid, crotonic acid, or mixtures thereof.
  • PVPs polyvinylpyrrolidones
  • N-vinylpyrrolidone/vinylacetate copolymers and polymers obtained from polymerization of at least one type of monomers selected from vinylpyrrolidone, vinylcaprolactam, vinyl esters, vinyl alcohol, vinyl acetate, (meth)acrylamide, and/or its derivatives, (meth)acrylic acid, propylene and/or ethylene glycol acid, crotonic
  • amphoteric hair styling polymers include octylacrylamide/acrylate/butylaminoethyl methacrylate copolymers, alkylacrylamide/alkylaminoalkyl methacrylate/(meth)acrylic acid copolymers, copolymers which are formed from at least one first monomer type which has quaternary amine groups, and at least one second monomer type which has acid groups, copolymers of fatty alcohol acrylates, of alkylamine oxide methacrylate and at least one monomer chosen from acrylic acid and methacrylic acid, methacryloylethylbetaine/methacrylic acid and/or esters copolymers, polymers preparable from quaternary croton betaines or quaternary croton betaine esters, or mixtures thereof, or a mixture thereof.
  • anionic hair styling polymers include copolymers of vinyl acetate and crotonic acid; terpolymers of vinyl acetate, crotonic acid and a vinyl ester of an alpha-branched saturated aliphatic monocarboxylic acid such as vinyl neo-decanoate; copolymers of methyl vinyl ether and maleic anhydride wherein such copolymers are esterified with a saturated alcohol containing from 1 to 4 carbon atoms such as ethanol or butanol; acrylic copolymers containing acrylic acid or methacrylic acid as the anionic radicalcontaining moiety with other monomers such as: esters of acrylic or methacrylic acid with one or more saturated alcohols having from 1 to 22 carbon atoms (such as methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-butyl acrylate, t-butyl acrylate, t-butyl methacryl
  • anionic hair styling polymers include carboxylated polyurethanes.
  • Carboxylated polyurethane resins are linear, hydroxyl-terminated copolymers having pendant carboxyl groups. They may be ethoxylated and/or propoxylated at least at one terminal end.
  • the carboxyl group can be a carboxylic acid group or an ester group, wherein the alkyl moiety of the ester group contains one to three carbon atoms.
  • the carboxylated polyurethane resin can also be a copolymer of polyvinylpyrrolidone and a polyurethane, having a CTFA designation PVP/polycarbamyl polyglycol ester.
  • anionic (meth)acrylate copolymers particularly copolymers of at least two monomers selected from the group consisting of acrylic acid, methacrylic acid, C.sub.1-6-alkylester of acrylic acid, C1-6-alkylester of methacrylic acid, C2-10-aminoalkylester of acrylic acid, C2-10-aminoalkylester of methacrylic acid, C1-6-alkylamides of acrylic acid and C1-6-alkylamides of methacrylic acid.
  • the hair treatment compositions of the instant disclosure are free or essentially free from hair styling polymers (film forming polymers) other than cationic conditioning polymers of (c), which may optionally exhibit film forming properties.
  • the hair treatment composition includes less than 1 wt.% of hair styling polymers (film forming polymers) other than cationic conditioning polymers of (c), which may optionally exhibit film forming properties.
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of hair styling polymers (film forming polymers).
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of hair styling polymers (film forming polymers) other than cationic conditioning polymers of (c), which may optionally exhibit film forming properties.
  • the hair treatment compositions of the instant disclosure are free or essentially free from hair anionic hair styling polymers (anionic film forming polymers).
  • the hair treatment composition includes less than 1 wt.% of anionic hair styling polymers (anionic film forming polymers).
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of anionic hair styling polymers (anionic film forming polymers).
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of anionic hair styling polymers (anionic film forming polymers).
  • the hair treatment compositions of the instant disclosure are free or essentially free from amphoteric hair styling polymers (amphoteric film forming polymers). In further embodiments, the hair treatment composition includes less than 1 wt.% of amphoteric hair styling polymers (amphoteric film forming polymers). In further embodiments, the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of amphoteric hair styling polymers (amphoteric film forming polymers). In other embodiments, the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of amphoteric hair styling polymers (amphoteric film forming polymers).
  • the hair treatment compositions of the instant disclosure are free or essentially free from non-silicone-based oils (e.g., mineral oil, alkanes (paraffins), plant oils, and the like other than the fatty alcohols of (d).
  • the hair treatment composition includes less than 1 wt.% of non-silicone-based oils other than the fatty alcohols of (d).
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of non-silicone-based oils other than the fatty acids of (d).
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of one or more non-silicone-based oils in addition to the fatty alcohols of (d).
  • the hair treatment compositions of the instant disclosure are free or essentially free from waxes (fatty compounds that are solid at room temperature) except for the fatty alcohols of (d).
  • the hair treatment composition includes less than 1 wt.% of waxes (fatty compounds that are solid at room temperature) in addition to the fatty alcohols of (d).
  • the hair treatment composition includes less than 0.8 wt.%, less than 0.5 wt.%, less than 0.1 wt.%, or less than 0.05 wt.% of waxes (fatty compounds that are solid at room temperature) other than the fatty alcohols of (d).
  • the hair treatment compositions optionally include up to about 2, 3, or 5 wt.% of one or more waxes (fatty compounds that are solid at room temperature) in addition to the fatty alcohols of (d). pH
  • the pH of the hair treatment compositions can vary. Nonetheless, in various embodiments, the pH of the hair treatment compositions is from about 4 to about 10. IN further embodiments, the pH of the hair treatment composition is from about 4 to about 9, about 4 to about 8, about 4 to about 7, about 5 to about 10, about 5 to about 9, about 5 to about 8, about 5 to about 7, about 6 to about 10, about 6 to about 9, about 6 to about 8, or about 6 to about 7. In other embodiments, the pH of the hair treatment composition is less than 9, less than 8, or less than 8, wherein the minimum pH is about 4, 5, or 6.
  • the viscosity of the hair treatment compositions will vary. Nonetheless, in various embodiments, the viscosity of the hair treatment compositions is about 100 to about 100,000 cPs, measured with a Brookfield DV-LL+ Pro Viscometer using Spindle T bar-C and rotational speed of 10% RPM at 25°C.
  • the viscosity is from about 500 to about 100,000 cPs, about 1 ,000 to about 100,000 cps, about 5,000 to about 100,000 cPs, about 100 to about 80,000 cps, about 500 to about 80,000 cps, about 1 ,000 to about 80,000 cps, about 5,000 to about 80,000 cps, about 100 to about 60,000 cPs, about 500 to about 60,000 cPs, about 1 ,000 to about 60,000 cPs, about 5,000 to about 60,000 cPs, about 100 to about 50,000 cPs, about 500 to about 50,000 cPs, about 1 ,000 to about 50,000 cPs, about 5,000 to about 50,000 cPs, about 100 to about 25,000 cPs, about 500 to about 25,000 cPs, about 1 ,000 to about 25,000 cPs, about 5,000 to about 25,000 cPs, about 100 to about 15,000 cPs, about 15,000 cPs, about 500
  • the hair treatment compositions are typically oil-in-water emulsions.
  • the compositions can be oil dispersions.
  • the compositions typically have a translucent or opaque appearance and can be in the form of a cream, gel, lotion, rinse, and the like.
  • the hair treatment compositions are not an aerosol.
  • the hair treatment compositions are not a foam.
  • the hair treatment compositions are preferably oil- in-water emulsions that are translucent or opaque with the consistency of a cream, a gel, or a lotion.
  • compositions are unique because they are effective as leave-on products and effective as rinse-off products.
  • the compositions interact with the hair fibers with a type of “stickiness” (attraction) such that the shine enhancing properties withstand rinsing.
  • the compositions can be used like a traditional conditioner composition applied after shampooing the hair.
  • the compositions can be used even after conditioning to provide additional shine and luster to the hair, regardless of whether the compositions are used as a leave-on or rinse-off product.
  • the hair treatment compositions of the instant disclosure may be included in a kit.
  • a kit comprising one or more hair-treatment compositions according to the instant disclosure and one or more additional hair treatment compositions, wherein the hair treatment composition(s) of the instant disclosure and the additional hair treatment composition(s) are separately contained.
  • the type and purpose of the one or more additional hair treatment compositions are not limited. Nonetheless, in various embodiments, the one or more additional hair treatment compositions are selected from shampoo compositions, conditioning compositions, styling compositions, finishing compositions, or a combination thereof.
  • a hair treatment composition of the instant disclosure is included in a kit with a shampoo composition, wherein the hair treatment composition of the instant disclosure and the shampoo composition are separately contained.
  • the hair treatment compositions may be used in various methods for improving the look and feel of hair, for example, human hair, including human hair an individual’s head.
  • the hair treatment compositions are useful for: (i) imparting shine and luster to hair; (ii) improving texture and feel of hair; (iii) preventing or reducing frizz, especially in high humidity conditions; and (iv) improving the appearance of hair; wherein the methods typically comprise applying a hair treatment composition disclosed herein to the hair.
  • the hair treatment composition can be applied to the hair as a leave-on product (i.e. , allowed to remain on the hair without rinsing and the hair subsequently styled) or as a rinse-out product (i.e., rinsed from the hair prior to subsequently styling the hair).
  • the hair treatment composition When used as a rinse-out product, the hair treatment composition is typically applied to wet or dry hair, allowed to remain on the hair for a period of time, and subsequently rinsed from the hair prior to styling the hair.
  • the hairtreatment composition may be allowed to remain on the hair for about 10 seconds to about 15 minutes.
  • the hair-treatment composition can remain on the hair for about 10 seconds to about 10 minutes, about 10 seconds to about 5 minutes, about 10 seconds to about 3 minutes, about 30 seconds to about 15 minutes, about 30 seconds to about 10 minutes, about 30 seconds to about 5 minutes.
  • the hair treatment composition when used as a rinse-off product, can be used like a traditional conditioner. However, unlike a traditional conditioner, the hair treatment compositions are not necessarily used in conjunction with a shampooing step.
  • the hair is initially cleansed with a shampoo and subsequently treated with a hair treatment composition according to the instant disclosure.
  • the hair treatment composition is used as a standalone product such that it is not necessary for use in conjunction with cleansing the hair with a shampoo.
  • the hair treatment compositions of the instant disclosure can be used even after the hair has been treated with a conditioner, for example, to provide additional shine and luster to the hair.
  • the hair treatment composition When used as a leave-on product, the hair treatment composition can be applied to wet, damp, or dry hair. As the term suggests, a leave-on product remains on the hair for an extended period of time without being rinsed from the hair.
  • the hair treatment composition is applied to the hair and the hair is subsequently styled and allowed to dry without rinsing the hair treatment composition from the hair.
  • the hair after application of the hair treatment composition, the hair can be dried, for example, with a blow drying.
  • the hair can be treated with a hot iron, for example, a flat iron or a curling iron. Implementation of the present disclosure is provided by way of the following examples. The examples serve to illustrate the technology without being limiting in nature.
  • Ethanolamine sodium chloride, citric acid, fragrance pentaerythrityl tetra-di-t- butyl hydroxyhydrocinnamate, phenoxyethanol, chlorhexidine digluconate.
  • compositions set forth in Example 1 were tested to determine their ability to impart shine to hair.
  • Caucasian virgin hair swatches (3 gram, 25-inch) were cleansed with a standard shampoo and excess water removed after cleansing.
  • the hair swatches were separately treated with one of the compositions set forth in Example 1 .
  • Each of the compositions was applied to damp hair swatches, messaged into the hair swatches, and allowed to remain on the hair swatches for 3 minutes. After 3 minutes, the swatches were rinsed with water and blow dried. Two expert evaluators then independently assessed shine of the hair swatches based on the following scale:
  • Example 3 Compositions and Shine Assessment
  • Inventive Composition H and Comparative Composition I were tested to determine their ability to impart shine to hair.
  • Caucasian virgin hair swatches (3 gram, 25-inch) were cleansed with a standard shampoo and excess water removed after cleansing.
  • the hair swatches were separately treated with Inventive Composition H or Comparative Composition I.
  • Each of the compositions was applied to damp hair swatches, messaged into the hair swatches, and allowed to remain on the hair swatches for 3 minutes. After 3 minutes, the swatches were rinsed with water and blow dried.
  • the hair swatches were dried, they were evaluated using a SAMBA SHINE® Instrument (by Bossa Nova Vision), which is a device commonly used in the cosmetics industry to measure hair shine (also called hair luster or hair gloss). It provides quantitative measurement to substantiate claims and evaluate products efficacy.
  • Results from the SAMBA SHINE® instrument showed considerably better shine for the hair treated with Inventive Composition H over the hair treated with Comparative Composition I.
  • the SAMBA SHINE® Instrument showed nearly a doubling in the range of shine area (a measurement representing an extent of shine).
  • the results showed the shine of the hair treated with Inventive Compositions was visibly brighter (more reflective) than the shine provided by Comparative Composition H. In other words, the shine provided by Inventive Composition H was appreciably more pronounced and brighter (more reflective) than shine provided by Comparative Composition I.
  • a “an,” and “the” are understood to encompass the plural as well as the singular.
  • the term “a mixture thereof” also relates to “mixtures thereof.”
  • the term “a mixture thereof” is used, following a list of elements as shown in the following example where letters A-F represent the elements: “one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture thereof.”
  • the term, “a mixture thereof” does not require that the mixture include all of A, B, C, D, E, and F (although all of A, B, C, D, E, and F may be included). Rather, it indicates that a mixture of any two or more of A, B, C, D, E, and F can be included.
  • a salt thereof also relates to “salts thereof.”
  • the disclosure refers to “an element selected from the group consisting of A, B, C, D, E, F, a salt thereof, and a mixture thereof,” it indicates that that one or more of A, B, C, D, and F may be included, one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be include, or a mixture of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included.
  • the salts referred to throughout the disclosure may include salts having a counter-ion such as an alkali metal, alkaline earth metal, or ammonium counterion. This list of counterions, however, is non-limiting. Appropriate counterions for the components described herein are known in the art.
  • an overlapping compound does not represent more than one component.
  • certain compounds may be considered both an surfactant and a fatty compound. If a particular composition includes both a surfactant and a fatty compound, a single compound will serve as only the surfactant or the fatty compound (the single compound does not serve as both the surfactant and the fatty component).
  • a “rinse-off” product refers to a composition that is rinsed and/or washed from the hair with water either after or during the application of the composition onto the hair, and before drying and/or styling the hair. At least a portion of the composition is removed from the hair during the rinsing and/or washing.
  • a “leave-on” product refers to a composition that is not rinsed and/or washed from the hair after or during application of the composition onto the hair. The composition remains on the hair during drying and/or throughout styling.
  • ranges provided are meant to include every specific range within, and combination of sub ranges between, the given ranges.
  • a range from 1-5 includes specifically 1 , 2, 3, 4 and 5, as well as sub ranges such as 2-5, 3- 5, 2-3, 2-4, 1-4, etc.
  • All ranges and values disclosed herein are inclusive and combinable. For examples, any value or point described herein that falls within a range described herein can serve as a minimum or maximum value to derive a subrange, etc.
  • the hair treatment compositions of the instant disclosure may include one or more surfactants and/or emulsifiers, for example, one or more nonionic, anionic, cationic, and/or amphoteric/zwitterionic surfactants or emulsifiers.
  • surfactants and emulsifiers include salts of the surfactants and emulsifiers even if not explicitly stated.
  • salts are also encompassed to the extent such salts exist, even though the specification may not specifically refer to a salt (or may not refer to a salt in every instance throughout the disclosure), for example, by using language such as “a salt thereof” or “salts thereof.”
  • Sodium and potassium are common cations that form salts with surfactants and emulsifiers.
  • additional cations such as ammonium ions, or alkanolammonium ions such as monoethanolammonium or triethanolammonium ions, may also form salts of surfactants.
  • compositions may include less than about 1 wt.%, less than about 0.5 wt.%, less than about 0.1 wt.%, less than about 0.01 wt.% or none of the specified material.
  • a claimed composition may be “free” or “essentially free” (or “substantially free”) of one or more components that are positively set forth in the instant disclosure.
  • the hair treatment composition of the instant disclosure may optionally include one or more nonionic film-forming polymers (or film-setting or hair-styling polymers).
  • the hair treatment compositions may be free or essentially free from the one or more nonionic film-forming polymers (or film-setting or hair-styling polymers).

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Abstract

L'invention concerne des compositions de traitement capillaire particulièrement utiles pour conférer de la brillance et de l'éclat aux cheveux. Les compositions comprennent : (a) un ou plusieurs polysiloxanes modifiés par polyéther ; (b) un ou plusieurs glycols ; (c) un ou plusieurs agents de conditionnement cationiques ; (d) un ou plusieurs alcools gras ; et (e) de l'eau. Les compositions confèrent de la brillance et de l'éclat à des cheveux indiquant des cheveux naturels et sains, sans provoquer d'accumulation, d'adhésivité et d'ondulation, indépendamment du fait que les compositions sont utilisées comme produit sans rinçage ou comme produit à rincer.
EP23833977.4A 2022-12-16 2023-11-30 Compositions de traitement capillaire qui confèrent de la brillance et de l?éclat Pending EP4633589A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US18/067,076 US20240216260A1 (en) 2022-12-16 2022-12-16 Hair treatment compositions that impart shine and luster
FR2301026A FR3145485A1 (fr) 2023-02-03 2023-02-03 Compositions de traitement des cheveux qui confèrent brillance et lustre
PCT/US2023/081818 WO2024129386A1 (fr) 2022-12-16 2023-11-30 Compositions de traitement capillaire qui confèrent de la brillance et de l'éclat

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EP4633589A1 true EP4633589A1 (fr) 2025-10-22

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US4185087A (en) 1977-12-28 1980-01-22 Union Carbide Corporation Hair conditioning compositions containing dialkylamino hydroxy organosilicon compounds and their derivatives
GB9116871D0 (en) 1991-08-05 1991-09-18 Unilever Plc Hair care composition
US7615231B2 (en) * 2005-10-24 2009-11-10 Fan Tech, Ltd. Methods for enhancing the morphology, tone, texture and/or appearance of skin or hair using a meadowlactone
JP4613258B2 (ja) * 2009-02-03 2011-01-12 株式会社資生堂 ヘアコンディショナー組成物及びその低エネルギー製造方法
FR2983721B1 (fr) * 2011-12-08 2014-05-09 Seppic Sa Nouvelles emulsions huile-dans-eau riches en sels, a viscosite elevee et stables au cours du temps
KR20160116877A (ko) * 2015-03-31 2016-10-10 (주)아모레퍼시픽 라멜라 액정 구조를 가지는 다중 에멀전 제형의 화장료 조성물
BR112022017300A2 (pt) * 2020-06-30 2023-01-10 Oreal Composições cosméticas e método para tratamento dos cabelos

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