EP4452623A1 - Tube d'insertion pour le revêtement de canalisations ou de conduits - Google Patents
Tube d'insertion pour le revêtement de canalisations ou de conduitsInfo
- Publication number
- EP4452623A1 EP4452623A1 EP22818677.1A EP22818677A EP4452623A1 EP 4452623 A1 EP4452623 A1 EP 4452623A1 EP 22818677 A EP22818677 A EP 22818677A EP 4452623 A1 EP4452623 A1 EP 4452623A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- styrene
- reaction material
- vinyl toluene
- weight
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 96
- 239000000463 material Substances 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 43
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000007787 solid Substances 0.000 claims abstract description 19
- 239000011877 solvent mixture Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 230000002787 reinforcement Effects 0.000 claims description 30
- 238000003780 insertion Methods 0.000 claims description 14
- 230000037431 insertion Effects 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 7
- 229920001567 vinyl ester resin Polymers 0.000 claims description 7
- 229920001225 polyester resin Polymers 0.000 claims description 5
- 239000004645 polyester resin Substances 0.000 claims description 5
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 claims description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 230000003014 reinforcing effect Effects 0.000 abstract description 3
- 239000012779 reinforcing material Substances 0.000 abstract description 2
- 239000003365 glass fiber Substances 0.000 description 6
- 230000009257 reactivity Effects 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920006305 unsaturated polyester Polymers 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 231100000243 mutagenic effect Toxicity 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L55/00—Devices or appurtenances for use in, or in connection with, pipes or pipe systems
- F16L55/16—Devices for covering leaks in pipes or hoses, e.g. hose-menders
- F16L55/162—Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe
- F16L55/165—Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section
- F16L55/1656—Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section materials for flexible liners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/26—Lining or sheathing of internal surfaces
- B29C63/34—Lining or sheathing of internal surfaces using tubular layers or sheathings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/04—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L55/00—Devices or appurtenances for use in, or in connection with, pipes or pipe systems
- F16L55/16—Devices for covering leaks in pipes or hoses, e.g. hose-menders
- F16L55/162—Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe
- F16L55/165—Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section
- F16L55/1651—Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section the flexible liner being everted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/04—4 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/05—5 or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
- B32B2260/023—Two or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
- B32B2264/0278—Polyester particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
Definitions
- the invention relates to an insert hose for lining pipelines or ducts in need of rehabilitation, specifically the reaction resin with which one or more reinforcement layers of the insert hose are impregnated.
- Insertion hoses also known as "liners" are used to reconstruct and rehabilitate damaged pipelines and ducts.
- the insert hoses contain at least one reinforcement layer whose reinforcement material is impregnated with a reaction material.
- the reinforcement material often consists of a glass fiber scrim or a combination of a glass fiber scrim and a random fiber layer (e.g. polyester needle felt), whereby the glass fiber scrim itself can comprise several scrim layers.
- the reaction material hardens under the influence of UV radiation, steam or hot water. However, reaction materials that harden at normal temperatures are occasionally also used.
- the inlay hose is drawn into the damaged pipeline or turned inside out (so-called inversion method) and then expanded using compressed air so that the inlay hose lies against the inner surface of the pipeline.
- the reaction resin is then cured by means of UV radiation or steam, so that the hose insert forms a liquid-tight and usually also gas-tight inner surface of the renovated pipeline or sewer section.
- polyester resins and vinyl ester resins generally consist of 45 to 70 percent by weight unsaturated polyester or vinyl ester (solids) and the remaining percent by weight styrene as the solvent.
- the styrene dissolves the semi-solid to solid unsaturated polyester at room temperature or vinyl ester and thus forms a liquid resin with the ester, the viscosity of which can be adjusted within a wide range.
- a viscosity of about 600 to 1000 mPa*s is usually set for impregnating the reinforcement material.
- the styrene acts as a reaction partner for the reactive double bonds in the unsaturated polyester or in the vinyl ester during crosslinking. Without styrene, these esters cannot be cured efficiently.
- polyester resins The high market share of polyester resins is mainly due to the fact that they have a good price-performance ratio.
- the unreinforced material already provides usable mechanical properties after curing; these are further enhanced by the embedded reinforcement material.
- Crosslinking by radical polymerisation leads to very rapid curing.
- styrene may not be harmless during processing. In animal experiments with mice - but not with rats and other laboratory animals - styrene causes lung cancer. In addition, the mutagenic potential of styrene has been the subject of controversy for many years. Styrene evaporates in large quantities both during the impregnation of the reinforcement material, which is usually carried out at the factory, and during curing under heat and/or UV light, which is noticeable through a not unpleasant but clearly perceptible odor.
- vinyl toluene which is a methyl styrene that has similar properties to styrene and is also considered to be a health problem. Insofar as styrene is mentioned below, this also applies analogously to vinyl toluene.
- a methacrylate is sometimes used as an alternative to styrene; the corresponding resin systems are then referred to as styrene-free.
- methacrylates are considerably more expensive than styrene, which, in view of the large quantities that are required for insert hoses, can mean that the renovation with an insert hose becomes uneconomical.
- methacrylate-based resins have the disadvantage of lower reactivity. Since less and less heat or UV light reaches the outer reinforcement layers, especially with large hose thicknesses, curing there can sometimes take a very long time.
- epoxy resins are basically styrene-free. However, some of their ingredients are allergenic and not completely odorless. In addition, due to the short pot life, epoxy resins can only be applied shortly before the insertion hose is pulled in, which is not desirable in terms of industrial hygiene or production technology.
- peroxides are labile compounds and can show explosive and oxidizing behavior, especially in higher concentrations and at elevated temperatures.
- EP 2 525 130 A1 solves the problem of insufficient curing by applying a special size (i.e. a type of adhesion promoter) to the glass fibers of the reinforcement layers, which increases the absorption coefficient of the insert tube for the UV light is reduced in such a way that a peroxide-free reaction mass can be cured with UV light even with hose thicknesses of more than 10 mm.
- a special size i.e. a type of adhesion promoter
- this approach has not been implemented for various reasons. Above all, this includes the costs incurred for the application of the special sizing and added to the already high costs for the methacrylates.
- the object of the invention is to specify an insert tube which at least partially solves the problems associated with the use of styrene.
- an insert hose for lining pipelines or ducts with an inner film, an outer film pointing to an inner wall of the pipeline or duct when installed, and with at least one reinforcement layer arranged between the inner film and the outer film, which is a reinforcement material has, which is impregnated with a curable reaction material.
- the reaction material contains a solid and a solvent mixture, the solid in the reaction material having a solids content ranging from 45 to 65% by weight.
- the solvent mixture is a mixture of styrene and/or vinyl toluene and at least one solvent other than styrene and vinyl toluene, the styrene and/or vinyl toluene in the solvent mixture being between 5 and 80% by weight, preferably between 15 and 50% by weight.
- styrene or vinyl toluene on the one hand and styrene-free solvents such as methacrylate (particularly butanediol dimethacrylate) on the other are chemically well tolerated and can be processed very well as a mixture.
- the total proportion of styrene and/or vinyl toluene in the reaction material can be reduced from 30 to 55 percent by weight to, for example, 5 to 20 percent by weight.
- the small proportion of styrene and/or vinyl toluene ensures that the reaction material cures quickly and completely after the insertion tube has been pulled in under the influence of heat and/or UV radiation.
- the low proportion of styrene and/or vinyl toluene causes increased permeability to UV radiation due to the better interaction with the size surrounding the glass fibers compared to methacrylate, which also has a favorable effect on the UV-induced curing.
- Low-styrene resins are known in the prior art. However, the low styrene content is only achieved there by reducing the solvent content to around 30%. This is not enough for use as a reaction material in hose inserts. A proportion of the solids in the reaction material of between 52 and 58 percent by weight is preferred there—and also for the present invention.
- the solid contained in the reaction material can be, in particular, unsaturated polyester resin or vinyl ester resin.
- the polyester resin can contain a combination of isophthalic acid and neopentyl glycol or a combination of orthophthalic acid and neopentyl glycol.
- the subject matter of the invention is also a lining pipe which was obtained from an insert hose according to the invention, in that the insert hose, which was initially folded together, was expanded and the reaction material was cured.
- the invention also relates to a method for producing an insert hose for lining pipelines or ducts, with the following steps: a) feeding in a tubular inner film; b) supplying at least one reinforcement layer which has a reinforcement material, c) enclosing the at least one reinforcement layer with an outer film; d) impregnating the at least one reinforcement layer with a curable reaction material, the reaction material containing a solid and a solvent mixture, and the solid in the reaction material having a proportion of between 45 and 65 percent by weight, the solvent mixture being a mixture of styrene and/or or vinyl toluene and at least one solvent which is not styrene or vinyl toluene, the styrene and/or vinyl toluene being present in the solvent mixture in an amount between 5 and 80% by weight.
- FIG. 1 shows a cross section through an insert hose according to the invention after it has been installed in a damaged pipeline
- FIG. 2 shows the insertion tube shown in FIG. 1 prior to installation, but without the outer film.
- FIG. 1 shows an example of an insert hose 10 after it has been installed in a pipeline 12.
- the insert hose 10 has a multi-layer structure, which can be seen better in the enlarged detail A.
- the insert tube 10 comprises a styrene-tight Inner foil IF and an outer foil AF pointing to an inner wall 14 of the pipeline 12 when installed.
- a reinforcement layer VS which comprises a plurality of reinforcement layers, is arranged between the inner film IF and the outer film AF.
- Each reinforcing layer contains a reinforcing material impregnated with a UV-curable reactive material.
- the composition of the reaction material is explained in Section 2.
- the insertion tube 10 includes an intermediate film ZF, which is arranged between the outer film AF and the reinforcement layer VS.
- the insert hose 10 and in particular its hardened reinforcement layer VS, forms a liquid and gas-tight new inner surface of the pipeline 12, so that liquid 15 guided therein cannot escape from cracks 16, ruptures 18 or other damage to the pipeline 12.
- FIG. 2 shows the insert hose 10 prior to installation in the pipeline and without the intermediate film ZF and the outer film AF.
- Three reinforcement layers VL1, VL2, VL3 are wrapped around the tubular and flattened inner film IF, which together form the reinforcement layer VS shown in Figure 1 and each have a glass fiber fabric as reinforcement material, which is impregnated with the UV-curable reaction material.
- Each reinforcement layer VL1, VL2, VL3 has an overlapping area B1, B2 or B3, in which longitudinal sides of the reinforcement layers VL1, VL2, VL3 that are opposite one another in a circumferential direction U overlap loosely (i.e. without being connected).
- the reaction material is a polyester resin which consists of 52 percent by weight of an unsaturated polyester resin as a solid and 48 percent by weight of a solvent mixture.
- the solution medium mixture is a mixture of a good 31 percent by weight of styrene and almost 69 percent by weight of butanediol dimethacrylate (BDDMA). This corresponds to a total proportion of styrene in the reaction material of 15 percent by weight and a total proportion of butanediol dimethacrylate in the reaction material of 33 percent by weight.
- BDDMA butanediol dimethacrylate
- the table below contains the results of comparative tests.
- the starting point was a solvent mixture proportion of 48 percent by weight, but the proportion of styrene in the reaction material was varied.
- the first and last line corresponds to the state of the art, i.e. a styrene-free reaction material or a reaction material that only contains styrene as a solvent.
- the reactivity can be increased to 250 kJ/kg with a comparatively small styrene content of 15%, which is sufficient for curing thicker inner tubes.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102021134231.7A DE102021134231B4 (de) | 2021-12-22 | 2021-12-22 | Einlegeschlauch zum Auskleiden von Rohrleitungen oder Kanälen |
| PCT/EP2022/082319 WO2023117228A1 (fr) | 2021-12-22 | 2022-11-17 | Tube d'insertion pour le revêtement de canalisations ou de conduits |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4452623A1 true EP4452623A1 (fr) | 2024-10-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22818677.1A Pending EP4452623A1 (fr) | 2021-12-22 | 2022-11-17 | Tube d'insertion pour le revêtement de canalisations ou de conduits |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20250052355A1 (fr) |
| EP (1) | EP4452623A1 (fr) |
| CN (1) | CN118265603A (fr) |
| DE (2) | DE102021134231B4 (fr) |
| WO (1) | WO2023117228A1 (fr) |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB627037A (en) * | 1946-01-19 | 1949-07-26 | American Cyanamid Co | Improvements in or relating to expanded resinous compositions |
| DD133953A1 (de) | 1977-09-07 | 1979-01-31 | Hans Schlegel | Verfahren zur polymerisation ungesaettigter polyesterharze |
| JP2736368B2 (ja) * | 1990-04-10 | 1998-04-02 | 芦森工業株式会社 | 管路の内張り材及び管路の内張り方法 |
| CN101790457A (zh) * | 2007-08-30 | 2010-07-28 | 亚什兰许可和知识产权有限公司 | 具有高色牢度的低白化凝胶涂层 |
| DE102011102135B3 (de) | 2011-05-20 | 2012-08-30 | Impreg Gmbh | Einlegeschlauch zum Auskleiden und Sanieren von Rohrleitungen und Kanälen, insbesondere von Abwasserkanälen |
| DE102014118689A1 (de) * | 2014-12-15 | 2016-06-16 | Sml Verwaltungs Gmbh | Auskleidungsschlauch zur Sanierung fluidführender Systeme |
| DE102016124729A1 (de) * | 2016-12-16 | 2018-06-21 | SML Verwaltungs- GmbH | Härtbare Auskleidungsschläuche zur Sanierung fluidführender Systeme |
| CN207683066U (zh) * | 2017-09-27 | 2018-08-03 | 天津科技大学 | 一种用于管道原位修复软管内封口的复合材料 |
| DE102018111361A1 (de) * | 2018-05-14 | 2019-11-14 | Sml Verwaltungs Gmbh | Auskleidungsschlauch für die Sanierung fluidführender Systeme |
| DE102018123339A1 (de) * | 2018-09-21 | 2020-03-26 | Saertex Multicom Gmbh | Sanierung von Hochtemperaturleitungen |
-
2021
- 2021-12-22 DE DE102021134231.7A patent/DE102021134231B4/de active Active
-
2022
- 2022-11-17 EP EP22818677.1A patent/EP4452623A1/fr active Pending
- 2022-11-17 DE DE202022003037.1U patent/DE202022003037U1/de active Active
- 2022-11-17 CN CN202280077017.XA patent/CN118265603A/zh active Pending
- 2022-11-17 WO PCT/EP2022/082319 patent/WO2023117228A1/fr not_active Ceased
- 2022-11-17 US US18/722,903 patent/US20250052355A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN118265603A (zh) | 2024-06-28 |
| DE102021134231A1 (de) | 2023-06-22 |
| DE102021134231B4 (de) | 2025-06-18 |
| US20250052355A1 (en) | 2025-02-13 |
| DE202022003037U1 (de) | 2024-06-24 |
| WO2023117228A1 (fr) | 2023-06-29 |
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