EP4339372B1 - Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses - Google Patents
Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses Download PDFInfo
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- EP4339372B1 EP4339372B1 EP23164428.7A EP23164428A EP4339372B1 EP 4339372 B1 EP4339372 B1 EP 4339372B1 EP 23164428 A EP23164428 A EP 23164428A EP 4339372 B1 EP4339372 B1 EP 4339372B1
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- Prior art keywords
- infill
- artificial turf
- olive
- olive pit
- fragments
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
- E01C13/08—Surfaces simulating grass ; Grass-grown sports grounds
Definitions
- EP3868955A1 patent application describes using olive pit particles as infill for artificial turf which are produced by crushing naturally occurring pits in a grinder, granulator, or cracker mill.
- the general concept of using olive pit particles is rather known since at least 2010 by the publication of US2010/055461 patent application which describes an artificial turf having organic particles of a group consisting of, coconut shells, ground pecan shells, ground peanut shells, ground corn cobs, and ground olive stones.
- coconut shells coconut shells
- ground pecan shells ground peanut shells
- ground corn cobs ground olive stones
- the present invention provides an artificial turf infill, an artificial turf employing the artificial turf infill, and a method of forming the artificial turf infill in the independent claims.
- Various embodiments of the present invention are given in the dependent claims. Embodiments of the present invention provide new, improved solutions to the above problems associated with the prior art.
- an artificial turf infill comprising an olive pit material, and microporous zeolite particles.
- the olive pit material may comprise rounded and thermally treated olive pit fragments having a size of 0.5 mm or greater, in particular 0.5 mm to 4.0 mm, more in particular 0.5 mm to 2.5 mm, and most in particular 0.5 mm to 2.0 mm, in an amount of at least 80.0 wt%, in particular 90.0 wt% to 99.0 wt%, more in particular 95.0 wt% to 99.0 wt%, and most in particular 98.0 wt% to 99.0 wt% of the total weight of the total olive pit material in the infill.
- the olive pit material may further comprise olive pit particles having a size of less than 63 ⁇ m in an amount of at least 0.5 wt%, in particular 1.0 wt% to 20.0 wt%, more in particular 1.0 wt% to 10.0 wt %, and most in particular 1.0 wt% to 2.0 wt% of the total olive pit material in the infill.
- the present invention olive pit fragments may be thermally treated for removing the residual odor from the olives, increasing their surface hardness and tenacity, and making them antimicrobially resistant, and attrition resistant.
- the method of the present invention is free of a step which crushes or grinds the not-yet rounded olive pit fragments or the rounded olive-pit fragments.
- the present invention provides a bio-based infill that exhibits improved performance characteristics in varying weather conditions over an extended period of time.
- the bio-based infill includes an olive pit material and, in some embodiments, at least one other bio-based infill.
- the bio-based material includes microporous zeolite particles.
- the present invention further provides a method for making the artificial turf infill.
- the olive pit material is prepared using olive pit fragments generated in an oil extraction process which uses compression for extracting the olive oil.
- the oil extraction process may employ an olive press.
- the olive pit fragments may have sharp edges which are created when the olive pits break under the compression force in the olive press.
- the present invention uses a tumbling treatment of the olive pit fragments to smoothen their sharp edges, and provide rounded olive pit fragments which are substantially free of any sharp edges.
- the same tumbling process may also be used for any additional bio-based material.
- the additional bio-based material may be tumbled together with the olive pit fragments to enhance the effectiveness of the tumbling process in rounding the sharp edges of the olive pit fragments.
- the artificial turf infill comprises the rounded olive pit fragments prepared by the tumbling treatment process.
- Rounded as this term is used here, means that the fragments do not have sharp edges which can cause skin injury to the users of the artificial turf.
- the tumbling of the olive pit fragments generates an olive pit material having bimodal size distribution with a major mode comprising rounded olive pit fragments having a size greater than 0.5 mm, in particular 0.5 mm to 4.0 mm, more in particular 0.5 mm to 2.5 mm, and most in particular 0.5 mm to 2.0 mm.
- a minor mode of the bimodal distribution comprises olive pit particles having a size of less than 63 ⁇ m.
- the olive pit material of the invention can be used as infill for artificial turfs for professional sport fields, however, it can also be used in other applications such as, for example, artificial turfs in parks and private gardens.
- the total amount of olive pit material in the infill comprises at least 80.0 wt%, in particular 90.0 wt% to 99.0 wt%, more in particular 95.0 wt% to 99.0 wt%, and most in particular 98.0 wt% to 99.0 wt% of the rounded and thermally treated olive pit fragments.
- the olive pit particles may be in an amount of at least 0.5 wt%, in particular 1.0 wt% to 20.0 wt%, more in particular 1.0 wt% to 10.0 wt%, and most in particular about 1.0 wt% to 2.0 wt% of the total weight of the olive pit material.
- the performance infill layer may also include fragments of the at least one other bio-based material in addition to the rounded and thermally treated olive pit fragments.
- the rounded and thermally treated olive pit fragments and the fragments of the other bio-based material may be obtained from the same tumbling and thermal treatments.
- the artificial turf comprises an infill which consists entirely of bio-based materials.
- the present invention infill can be made totally free of any sand, or of any non-bio-based, synthetic infill like the rubber, elastomeric, or polymer-based materials used in infills of the state of the art.
- an infill which is made of compostable material, and is essentially free of any synthetic, non-biodegradable material. Essentially free means that less than 1 wt%, preferably less than 0.5 wt% of the infill may be synthetic, non-biodegradable material. Other natural materials such as zeolite and sand may be added in the infill.
- the method may further comprise thermally treating the olive pit fragments.
- thermal treatment involves heating to a temperature of 80 °C to 130 °C, in particular 100 °C to 130 °C, and more in particular 110 °C to 130 °C.
- heat treatment means that the olive pit fragments are heated to a sufficiently high temperature, that the heat treatment not only reduces the equilibrium moisture of the olive pit material and eliminates any residual olive odor, but also modifies their chemical structure.
- Chemical modification of the olive pit structure may be measured by X-ray photoelectron analysis (XPS) of the oxygen to carbon ratio of the material.
- thermally treated olive pit material means that the olive pit material has been sufficiently heated to show at least a 3%, preferably at least 5%, and more preferably 5% to 10 % reduction in the oxygen to carbon ratio compared to thermally untreated olive pit material as measured by XPS analysis.
- the thermal treatment heats the olive pit material to a temperature higher than 150°C, in particular 160 °C to 250 °C, and more in particular 180 °C to 250 °C.
- Thermal treatment at these higher temperatures has the benefit of increasing the resistance of the olive pit fragments against moisture-induced biodegradation, which is particularly beneficial in humid regions or when the artificial turf infill comprises a zeolite which is irrigated frequently before and during a game to cool the sports field and the players.
- heat treatment at the elevated temperature above 130 °C and in particular at a temperature of 150 °C to 250 °C not only removes any residual moisture or odors but, more importantly, also changes the chemical structure/composition of the hemicellulose, cellulose and lignin components of the olive pit fragments which results in substantially reduced hygroscopicity or effectively almost zero hygroscopicity for the thermally treated olive pit material at such temperatures. As a result, the olive pit material becomes resistant to natural biodegradation and is also much less likely to suffer from microbial infestations.
- thermally treated artificial turf infill of the present invention particularly suitable to be used with microporous zeolite particles that can be used to store water during watering of the turf and release it gradually thereafter, thus, cooling the turf and the athletes (or users) of the turf without reducing the useful lifespan of the infill (and of the turf) due to the increased moisture conditions.
- the artificial turf infill and artificial turf using the artificial turf infill of the present invention can be watered more frequently and also last longer than existing turfs.
- Heating for the thermal treatment may be performed with any suitable means.
- hot air, steam or superheated steam may be fed inside a tumbling apparatus and the heat treatment may be performed simultaneously with the tumbling treatment.
- the heat treatment may be performed separately and independently of any tumbling treatment, for example in an oven.
- the temperature and duration of the thermal treatment may be adjusted as may be needed for adjusting the effects of the heat treatment on the properties of the olive pit material.
- the duration of the tumbling treatment of the olive pit fragments may range for a period of 1 minute to 8 minutes, and in particular for a period of 2 minutes to 6 minutes.
- the tumbling treatment may in some embodiments last for a period of 2.5 minutes to 3 minutes.
- these time periods are provided only as examples, and longer periods may be used without departing from the scope of the present invention.
- the tumbling and/or thermal treatment may last from a few minutes to a few hours.
- the method comprises sieving the thermo-tumbler product to remove at least some of the thermo-tumbler product olive pit particles having a size of less than 63 ⁇ m.
- the removed olive pit particles may be used for forming a stabilization layer for the infill.
- the product from the thermo-tumbler is used without separation or sieving to form an infill layer for an artificial turf.
- the method further comprises mixing together with the olive pit fragments, or the rounded olive pit fragments or the rounded and thermally treated olive pit fragments, at least one other bio-based material including cork particles, and cherry pits whole, fragments, or mixtures thereof.
- fragments of at least one other bio-based material may also be fed in a thermo-tumbler and mixed together with the olive pit fragments.
- the microporous zeolite particles are added in an amount of 1.0 to 30.0 wt%, in particular 5.0 to 25.0 wt%, and more in particular 10.0 to 20.0 wt% of the total amount of the infill.
- the zeolite is added for providing a cooling effect in the infill because the zeolite microporous material absorbs water in rainy, wet conditions and releases by evaporation in hot sunny days to cool down the infill and the turf.
- the zeolite may also improve the overall shaping of the olive pit fragments and of any additional bio-based additional stones by providing added abrasion during the tumbling process.
- a method for forming an infill for an artificial turf comprising: providing an infill mixture comprising:
- the olive pits and olive pit fragments obtain a rounded shape which is designed to protect the skin of the players from injury, improves the packing density of the infill, reduces undesired water splashing in rainy conditions, and minimizes infill migration into the environment.
- the rounded and thermally treated olive pit material has no residual olive odor, has antimicrobial resistance, enhanced surface hardness and tenacity.
- the thermo-tumbler product comprises olive pit particles (dust-like particles generated by abrasion).
- the method of preparing the infill further comprises a sieving operation of the thermo-tumbler product to reduce the amount of the olive pit particles having a size of less than 63 ⁇ m to an amount of 2.0 % or less of the thermo-tumbler product, preferably to an amount of 1.0 to 2.0 % by weight of the thermo-tumbler product. Keeping this level of olive pit particles has been found to be beneficial because the olive pit particles allow for a higher packing density of the infill. According to some embodiments, further sieving is possible to reduce the amount of olive pit particles to less than 1.0 wt %.
- a method of creating an artificial turf comprises installing an artificial turf, and applying the artificial turf infill on the artificial turf.
- the infill comprises at least a mixture of the rounded and thermally treated olive pit fragments and of the olive pit particles, whereby the application is performed in a single step.
- the method further comprises allowing the olive pit particles in the applied infill to automatically trickle down into the voids between the fragments, thereby automatically forming a stabilization layer consisting essentially of the trickled-down particles, and a performance layer containing the rounded olive pit fragments.
- the infill mixture may further include zeolite which may also settle and become art of the stabilization layer.
- the infill mixture may also comprise at least one other bio-based material which can form the performance layer.
- the infill 12 of figure 1 consists of a single layer of infill formed of only rounded and thermally treated olive pit fragments 24 and olive pit particles 26 from the thermo-tumbling process, without any rubber-based infill, or polymer-based infill and, more preferably, without any non-bio-based material including any sand.
- hot air or steam may be used for thermally treating the olive pit fragments.
- the olive pit particles are olive pit fragments of less than 63 ⁇ m.
- the thermo-tumbling treatment may be a batch or a continuous process.
- the thermo-tumbling treatment is a continuous process. Any suitable thermo-tumbling apparatus may be used.
- thermo-tumbler product 29 is sieved via a sieve 31 to remove the thermo-tumbler product olive pit particles 26.
- the rounded and thermally treated olive pit fragments 24 are used as infill for an artificial turf.
- the removed olive pit particles may be used for a stabilization layer of the infill.
- the rounded and thermally treated olive pit fragments 24 are used for the performance layer of the infill.
- the rounded and thermally treated olive pit fragments 24 free of the olive pit particles 26 can be used in a performance layer 38 for an artificial turf 30 either alone or together with a second bio-based material, such as, for example, cork particles and/or cherry pits 25.
- the separated olive pit particles 26 using a sieving process are used as infill for a stabilization layer 35 preferably alone or together with any particles (of less than 63 ⁇ m size) of another bio-based material, while the rounded and thermally treated olive pit fragments 24 free of the olive pit particles 26 are used to form the performance layer 38 either alone or together with a second bio-based material fragments (of a size of 0.5 mm or greater) such as, cork particles and cherry pits 25.
- microporous zeolite particles are added in the infill for providing a cooling effect for the artificial turf.
- particles of a reflective material may also be added.
- the grain size of the microporous zeolite particles is determined such that the resulting specific surface area of the particles is smaller than a maximum specific surface area.
- the maximum specific surface area of the microporous zeolite particles is the specific surface area that enables the water in the particles to release, under an ambient temperature, at a predefined minimum rate.
- a progressive release of the water by the microporous zeolite particles and avoidance of rapid evaporation of the water after the surface has been watered is desirable in order to allow a lower temperature to be maintained at the level of the field surface compared to the ambient temperature.
- the controlled release of absorbed water causes progressive cooling under evaporation for some time.
- the amount of watering usually necessary to refresh a field surface can be reduced.
- 0.6 wt% of the zeolite particles at most is not retainable on a 10-mesh screen.
- the microporous zeolite particles have a hardness between 3.5 and 5.5 on the Mohs scale.
- the moisture level in the microporous zeolite particles is smaller than 6 wt%.
- the mixture of rounded and thermally treated olive pit fragments obtained from the thermo-tumbler is not sieved at all and is applied as obtained from the thermo-tumbler once the thermo-tumbling treatment is completed, on the backing of the artificial turf. It has been found that in a relative short time, the olive pit particles and the fragments separate with the olive pit particles settling at the bottom of the infill layer forming a stabilization layer and the larger rounded and thermally treated olive pit fragments form a performance layer over the stabilization layer with the olive pit particles.
- the microporous zeolite particles 28 of the component b when used, they separate also with the main bulk of it settling primarily within the stabilization layer 45.
- the microporous zeolite particles 28 provide a cooling effect in the infill of the artificial turf 40 and can also help the artificial turf stay drier in a rainy day because of their ability to soak water (through absorption) due to their microporous structure.
- the result is an artificial turf with less variable performance characteristic between warm, sunny days and cooler rainy days.
- the proposed infill comprising components a, b and c is advantageous because:
- these layers are formed automatically by a single-step application of the above-mentioned mixture comprising only components 'a' and 'c,' or a mixture comprising 'a', 'b' and 'c' and self-separation into the stabilizing and performance layers based on object size and specific gravity will achieve at least similar mechanical properties like a conventional two-layer artificial turf system with a stabilizing and performance layer.
- the infill mixture may include at least one other bio-based material such as cork particles and/or cherry pits 25 which after an initial settling period form part of the performance layer 48.
- the infill may further include any other suitable components such as an antimicrobial agent used for preventing the growth of bacteria, fungi, mold, or other microorganisms. Any suitable antimicrobial agent may be used and, according to some embodiments, the antimicrobial agent may also be added in the turf backing and/or turf fibers.
- the artificial turf may further include other components such as a reflective agent.
- the reflective agent may be added in the infill and/or in the polymer mixture for making the artificial turf fibers 16, for further preventing overheating of the fiber in warm and sunny conditions.
- the reflective agent may reduce the heat on the artificial turf field.
- Suitable reflective agents include titanium dioxide, zinc sulfide, tin oxide, aluminum oxide, zinc oxide, calcium sulfate, barium sulfate, calcium carbonate, antimony oxide, sodium silicate, aluminum silicate, silica, mica, clay, and the like.
- an infrared (IR) reflective agent is a mixed metal oxide type chosen from the group of the rutile (MeO2), hematite (Me2O3), or spinel (Me3O4) type with metals comprising cobalt, iron, trivalent chrome, tin, antimony, titanium, manganese and aluminum.
- the reflective agent may be used in an amount from 0.01 wt% to 8.0 wt%, preferably from 0.3 wt% to 5.0 wt%, more preferably from 0.3 wt% to 3.0 wt% based on the total fiber weight.
- a method of fabricating an infill for an artificial turf comprising, providing olive pit fragments separated from an olive extraction process compressing olives to extract olive oil from the olives (S50), feeding the olive pit fragments in a thermo-tumbler (S52), feeding hot air or steam through the thermo-tumbler (S54), tumbling the olive pit fragments (S56), and producing rounded and thermally treated olive pit fragments including olive pit particles (S58).
- the rounded and thermally treated olive pit fragments including the olive pit particles are used to form an infill for an artificial turf.
- the infill is free of any remaining olive odor, and is less likely to cause skin or foot injuries to the users of the artificial turf compared to an artificial turf using the untreated olive pit fragments.
- the olive pit material is applied in a single step over the thermoset polyurethane backing of an artificial turf comprising turf fibers of polyethylene having a pile height of 70 mm to form an infill having a height of 30 mm.
- the artificial turf made with the infill of the thermo-tumbled olive pit material shows a substantially improved balance of traction, energy absorption, stable foot and energy restitution characteristics compared to same artificial turf made with the untreated olive pit material.
- Untreated olive pit material refers to the olive pit material prior to the thermo-tumbling process.
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Claims (15)
- Remblai pour gazon artificiel comprenant :- un matériel de noyaux d'olives (24, 26) ; caractérisé en ce que le remblai comprend en outre- des particules de zéolithe microporeuse (28), dans lequel- le matériel de noyaux d'olives comprend des fragments de noyaux d'olives (24) arrondis obtenus par polissage conjoint avec les particules de zéolithe microporeuse (28) des noyaux d'olives fracturés obtenus à partir d'un processus d'extraction d'huile d'olive.
- Remblai pour gazon artificiel selon la revendication 1,
dans lequel le matériel de noyaux d'olives (24, 26) comprend des fragments de noyaux d'olives (24) présentant une taille de 0,5 mm ou plus, en particulier de 0,5 mm à 4,0 mm, plus particulièrement de 0,5 mm à 2,5 mm, et le plus particulièrement de 0,5 mm à 2,0 mm, à une teneur d'au moins 80,0 % en masse, en particulier de 90,0 % en masse à 99,0 % en masse, plus particulièrement de 95,0 % en masse à 99,0 % en masse, et le plus particulièrement de 98,0 % en masse à 99,0 % en masse de la masse totale du matériel de noyaux d'olives total dans le remblai, - Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel le matériel de noyaux d'olives présente une distribution de taille bimodale avec un mode majeur et un mode mineur,
dans lequel le mode majeur comprend des fragments de noyaux d'olives (24) arrondis et traités thermiquement et a un pic entre 0,5 mm et 4,0 mm, plus particulièrement entre 0,5 mm et 2,5 mm, et le plus particulièrement entre 0,5 mm et 2,0 mm, et dans lequel le mode mineur comprend des particules de noyaux d'olives (26) de moins de 63 µm à une teneur d'au moins 0,5 % et a un pic à moins de 63 µm. - Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel le matériel de noyaux d'olives est traité thermiquement (S54) à une température de 80 °C à 250 °C.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel les particules de zéolithe microporeuse (28) sont ajoutées dans le remblai à une teneur de 1,0 à 30,0 % en masse, en particulier de 5,0 à 25,0 % en masse, et plus particulièrement de 10,0 à 20,0 % en masse de la quantité totale du remblai (12).
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel les particules de zéolithe microporeuse (28) présentent une granulométrie entre 0,1 mm et 1,5 mm, en particulier entre 0,4 mm et 1,2 mm, plus particulièrement entre 0,9 mm et 1,2 mm, et une surface spécifique de surface maximale de 21 m2/g.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel les particules de zéolithe microporeuse (28) présentent une porosité entre 15 % et 20 % de parts en volume.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel les particules de zéolithe microporeuse (28) ont une distribution granulométrique dans laquelle 70 % à 90 % des grains en masse ont une taille dans la plage de 0,4 mm à 1,5 mm et 10 % à 30 % des grains en masse ont une taille inférieure à 0,4 mm.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel au moins 10 %, en particulier au moins 50 %, en particulier au moins 70 %, ou au moins 90 % en masse du remblai est constitué de matériel de noyaux d'olives.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, dans lequel les particules de zéolithe microporeuse (28) ont une dureté comprise entre 3,5 et 5,5 sur l'échelle de Mohs et un niveau d'humidité inférieur à 6 % en masse.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes,- comprenant en outre au moins un matériel d'origine biologique (25) supplémentaire incluant des fragments de noyau d'au moins un autre fruit à noyau,- dans lequel les fragments de noyau du matériel d'origine biologique (25) supplémentaire ont une élasticité différente de celle des fragments de noyaux d'olives arrondis et traités thermiquement, et- dans lequel en particulier l'au moins un matériel d'origine biologique (25) supplémentaire est choisi dans un groupe comprenant les particules de liège, les fragments de noyaux de cerises arrondis, et les combinaisons de ceux-ci.
- Remblai pour gazon artificiel selon l'une quelconque des revendications précédentes, comprenant uniquement des matériels d'origine biologique (25) et exempt de tout remblai à base de caoutchouc, d'élastomère ou de polymère, et en particulier également exempt de tout sable.
- Gazon artificiel ou kit de gazon artificiel comprenant le remblai pour gazon artificiel selon l'une quelconque des revendications précédentes.
- Gazon artificiel selon la revendication 13, comprenant en outre :- une couche de stabilisation (35, 45) comprenant ou constituée d'au moins un parmi le sable, les particules de noyaux d'olives (26) selon la revendication 2, et au moins une partie des particules de zéolithe microporeuse (28) ;- une couche de performance (38, 48) positionnée sur la couche de stabilisation,dans lequel la couche de performance (38, 48) comprend ou est constituée du remblai pour gazon artificiel selon l'une quelconque des revendications précédentes ou comprend ou est constituée des fragments de noyaux d'olives (24) arrondis et traités thermiquement et est essentiellement exempte des particules de noyaux d'olives (26).
- Procédé de création d'un gazon artificiel, comprenant :- l'installation d'un gazon artificiel comprenant une pluralité de fibres de gazon artificiel fixées sur un support ;- l'application du remblai pour gazon artificiel selon l'une quelconque des revendications 1 à 12 sur le gazon artificiel installé entre les fibres de gazon, dans lequel le remblai comprend au moins un mélange des fragments de noyaux d'olives (24) arrondis et traités thermiquement, des particules de noyaux d'olives (26) et des particules de zéolithe microporeuse (28), dans lequel l'application du remblai pour gazon artificiel sur le gazon artificiel installé est réalisée en une seule étape, et- le ruissellement automatique des particules de noyaux d'olives (26) dans le remblai appliqué dans des espaces vides entre les fragments de noyaux d'olives (24), formant ainsi automatiquement une couche de stabilisation (35, 45) essentiellement constituée des particules ayant ruisselé, et une couche de performance (38, 48) contenant les fragments de noyaux d'olives (24) arrondis,dans lequel au moins une partie des particules de zéolithe microporeuse (28) ruisselle et s'établit dans la couche de stabilisation (35, 45).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23164428.7A EP4339372B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23164428.7A EP4339372B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
| EP22194961.3A EP4335969B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
Related Parent Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22194961.3A Division EP4335969B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
| EP22194961.3A Division-Into EP4335969B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP4339372A1 EP4339372A1 (fr) | 2024-03-20 |
| EP4339372C0 EP4339372C0 (fr) | 2024-07-10 |
| EP4339372B1 true EP4339372B1 (fr) | 2024-07-10 |
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Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23164428.7A Active EP4339372B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
| EP22194961.3A Active EP4335969B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
| EP23164421.2A Active EP4339371B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22194961.3A Active EP4335969B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
| EP23164421.2A Active EP4339371B1 (fr) | 2022-09-09 | 2022-09-09 | Remplissage de gazon artificiel avec des fragments de noyaux d'olive et des particules de zéolite microporeuses |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20240084523A1 (fr) |
| EP (3) | EP4339372B1 (fr) |
| ES (1) | ES2988312T3 (fr) |
| WO (1) | WO2024052418A1 (fr) |
Families Citing this family (1)
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| ES2991842T3 (es) * | 2022-09-09 | 2024-12-05 | Polytex Sportbelaege Produktions Gmbh | Método para fabricar relleno de césped artificial con fragmentos redondeados de hueso de oliva |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69930268T2 (de) | 1998-07-22 | 2006-07-27 | Hexion Specialty Chemicals, Inc., Columbus | Stützmittelverbund, verbundstoff-filtrationsmedium und verfahren zu deren herstellung und verwendung |
| US6582819B2 (en) | 1998-07-22 | 2003-06-24 | Borden Chemical, Inc. | Low density composite proppant, filtration media, gravel packing media, and sports field media, and methods for making and using same |
| US6551689B1 (en) | 1998-09-21 | 2003-04-22 | Fieldturf Holdings Inc. | Synthetic grass with resilient granular top surface layer |
| US8236392B2 (en) | 2007-01-19 | 2012-08-07 | Brock Usa, Llc | Base for turf system |
| US20100055461A1 (en) | 2008-08-26 | 2010-03-04 | Daluise Daniel A | Artificial turf infill |
| ITPI20120099A1 (it) | 2012-09-28 | 2014-03-29 | Mar Project S R L | Materiale di intasamento perfezionato per manti in erba sintetica e manti ibridi sintetico-naturale e manti cosi' ottenuti |
| US10822752B2 (en) | 2015-06-15 | 2020-11-03 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Thermoplastic cellulosic fiber granules useful as infill materials for artificial turf |
| US20180080182A1 (en) | 2016-09-20 | 2018-03-22 | Tarkett Inc. | Organic infill for artificial turf fields |
| US12116734B2 (en) * | 2017-03-29 | 2024-10-15 | Brock Usa, Llc | Infill for artificial turf system |
| US11453982B2 (en) * | 2017-06-02 | 2022-09-27 | Benoit PINTAT | Artificial turf infill material |
| ES2961884T3 (es) | 2020-02-19 | 2024-03-14 | Tarkett Sports Canada Inc | Sistemas de relleno de huesos de aceituna y céspedes artificiales que tienen los mismos |
| US20210254290A1 (en) * | 2020-02-19 | 2021-08-19 | Fieldturf, Inc. | Olive pits infill systems and artificial turfs having the same |
| EP4001506B1 (fr) * | 2020-11-13 | 2024-03-13 | Tarkett Sports Canada Inc. | Système de gazon artificiel comprenant du sable hydrophobique |
-
2022
- 2022-09-09 EP EP23164428.7A patent/EP4339372B1/fr active Active
- 2022-09-09 ES ES22194961T patent/ES2988312T3/es active Active
- 2022-09-09 EP EP22194961.3A patent/EP4335969B1/fr active Active
- 2022-09-09 EP EP23164421.2A patent/EP4339371B1/fr active Active
- 2022-12-19 US US18/068,320 patent/US20240084523A1/en active Pending
-
2023
- 2023-09-06 WO PCT/EP2023/074483 patent/WO2024052418A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| ES2988312T3 (es) | 2024-11-20 |
| EP4339372C0 (fr) | 2024-07-10 |
| EP4339371B1 (fr) | 2024-07-10 |
| EP4339371C0 (fr) | 2024-07-10 |
| EP4339372A1 (fr) | 2024-03-20 |
| EP4335969C0 (fr) | 2024-07-10 |
| US20240084523A1 (en) | 2024-03-14 |
| EP4335969B1 (fr) | 2024-07-10 |
| EP4335969A1 (fr) | 2024-03-13 |
| EP4339371A1 (fr) | 2024-03-20 |
| WO2024052418A1 (fr) | 2024-03-14 |
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