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EP4130354B1 - Multifilament de polyamide 610 à haute résistance et procédé de production d'un tel multifilament - Google Patents

Multifilament de polyamide 610 à haute résistance et procédé de production d'un tel multifilament

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Publication number
EP4130354B1
EP4130354B1 EP21775467.0A EP21775467A EP4130354B1 EP 4130354 B1 EP4130354 B1 EP 4130354B1 EP 21775467 A EP21775467 A EP 21775467A EP 4130354 B1 EP4130354 B1 EP 4130354B1
Authority
EP
European Patent Office
Prior art keywords
multifilament
polyamide
strength
rollers
dtex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP21775467.0A
Other languages
German (de)
English (en)
Other versions
EP4130354A1 (fr
EP4130354A4 (fr
Inventor
Takashi Uruma
Hisao Shigeno
Kazushi Minai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
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Filing date
Publication date
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Publication of EP4130354A1 publication Critical patent/EP4130354A1/fr
Publication of EP4130354A4 publication Critical patent/EP4130354A4/fr
Application granted granted Critical
Publication of EP4130354B1 publication Critical patent/EP4130354B1/fr
Active legal-status Critical Current
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Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/80—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B1/00—Constructional features of ropes or cables
    • D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
    • D07B1/025—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics comprising high modulus, or high tenacity, polymer filaments or fibres, e.g. liquid-crystal polymers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/12—Stretch-spinning methods
    • D01D5/16—Stretch-spinning methods using rollers, or like mechanical devices, e.g. snubbing pins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/444—Yarns or threads for use in sports applications
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/447—Yarns or threads for specific use in general industrial applications, e.g. as filters or reinforcement
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B1/00—Constructional features of ropes or cables
    • D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00—Characteristics of used materials
    • A63B2209/02—Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
    • A63B2209/023—Long, oriented fibres, e.g. wound filaments, woven fabrics, mats
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B51/00—Stringing tennis, badminton or like rackets; Strings therefor; Maintenance of racket strings
    • A63B51/02—Strings; String substitutes; Products applied on strings, e.g. for protection against humidity or wear
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • D01D10/02—Heat treatment
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
    • D01D5/092—Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B2205/00—Rope or cable materials
    • D07B2205/20—Organic high polymers
    • D07B2205/2046—Polyamides, e.g. nylons
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/02—Moisture-responsive characteristics
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/06—Load-responsive characteristics
    • D10B2401/063—Load-responsive characteristics high strength
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/20—Physical properties optical
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2507/00—Sport; Military
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2507/00—Sport; Military
    • D10B2507/02—Nets

Definitions

  • the present invention relates to a polyamide 610 multifilament having higher strength than a conventional polyamide 610 multifilament.
  • polyamide 6 and polyamide 66 have higher strength and elongation and superior fluff quality as compared with general-purpose multifilaments of polyester, polypropylene, and the like, they are used in a wide variety of applications such as airbags, tire cords, racket strings, ropes, fishing nets, and bag belts.
  • polyamides 6 and 66 have been used for many years from the viewpoint of high strength and elongation, high abrasion resistance, flexibility, and durability.
  • polyamides 6 and 66 are generally polymers having water and moisture absorbency, in multifilaments of what are called general-purpose polyamides such as polyamide 6 and polyamide 66, strength reduction due to water absorption and dimensional change due to moisture absorption are large. Therefore, there has been the problem that the strength and abrasion resistance are deteriorated by water absorption.
  • multifilaments of polyamide 11, polyamide 610, polyamide 612, and the like are known as low water absorption polyamide multifilaments, and for example, they have been proposed as fibers for washing brushes (Patent Document 1).
  • Patent Document 2 a method of adding a trace amount of moisture to a polymer before melting has been proposed.
  • Patent Document 3 discloses a further polyamide 610 multifilament.
  • Patent Document 3 has made it possible to provide polyamide 610 multifilaments to industrial material fields, but higher multifilament twisted yarn tenacity is required in applications of tire cords, ropes, and racket strings for which strength and durability of products are particularly emphasized.
  • higher multifilament twisted yarn tenacity is required in applications of tire cords, ropes, and racket strings for which strength and durability of products are particularly emphasized.
  • it is conceivable to increase the number of doubling to secure strength but there is the concern that the product weight increases and the cost increases due to the increase in the number of used multifilaments.
  • Patent Document 3 it has been difficult to stably produce a multifilament with a strength exceeding 9 cN/dtex even if polyamide 610 multifilaments suitable for general industrial materials can be provided.
  • An object of the present invention is to provide a polyamide multifilament having high strength and low water absorption, which cannot be obtained by conventional techniques.
  • the present inventors have made intensive studies in order to solve the above-mentioned problems, and the present invention includes the following configurations.
  • the high-strength polyamide 610 multifilament has a total fineness of 100 to 2,500 dtex and a single fiber fineness of 1.5 to 40 dtex.
  • the high-strength polyamide 610 multifilament has a birefringence ⁇ n of 50.0 ⁇ 10 -3 or more.
  • the high-strength polyamide 610 multifilament has a sulfuric acid relative viscosity of 3.0 to 3.3.
  • the high-strength polyamide 610 multifilament has change rates of strength, elongation, and intermediate elongation in a wet state of all 10% or less.
  • Also claimed is a rope including the high-strength polyamide 610 multifilament according to the present invention.
  • a racket string including the high-strength polyamide 610 multifilament according to the present invention.
  • a textile for a bag including the high-strength polyamide 610 multifilament of the present invention.
  • Also claimed is a fishing net including the high-strength polyamide 610 multifilament according to the present invention.
  • Also claimed is a method of producing the high-strength polyamide 610 multifilament according to the present invention.
  • Fig. 1 schematically shows a direct spinning/drawing machine preferably used in the present invention.
  • Raw material chips (hereinafter also simply referred to as chips) of a high-strength polyamide 610 multifilament of the present invention are polyamide 610 chips.
  • the chips are preferably composed only of polyamide 610, but it is sufficient that the chips are substantially composed of polyamide 610, and other polymers may be mixed or copolymerized within a range not impairing the characteristics of the present invention, specifically, within a range of 5 mass% or less.
  • polyamides such as polyamides 6, 66, 11, and 12 are preferable.
  • the sulfuric acid relative viscosity (hereinafter also simply referred to as the viscosity) of raw material chips of the high-strength polyamide 610 multifilament of the present invention is preferably 3.6 to 4.0, more preferably 3.7 to 3.9, still more preferably 3.7 to 3.8. If the viscosity of the chips is less than 3.6, when the moisture content of the chips is within the following preferable range, the viscosity of the polyamide 610 multifilament is excessively reduced, and it may be difficult to sufficiently obtain the dry strength. If the viscosity exceeds 4.0, the melt viscosity of the polymer in the spinning machine increases, and dischargeability from the spinneret, spinnability, or drawability may be impaired.
  • the sulfuric acid relative viscosity refers to a value obtained by dissolving a sample in 98% sulfuric acid and measuring the sulfuric acid relative viscosity at 25°C using an Ostwald viscometer.
  • the polyamide 610 as a raw material of the polyamide 610 multifilament of the present invention preferably has a chip moisture content of 0.15 wt% or more, more preferably 0.20 to 0.35 wt%, particularly preferably 0.25 to 0.35 wt%.
  • a chip moisture content 0.15 wt% or more, more preferably 0.20 to 0.35 wt%, particularly preferably 0.25 to 0.35 wt%.
  • the high-strength polyamide 610 multifilament can be obtained.
  • a method for adjusting the moisture content a method of adding measured water to dried chips and stirring the chips is preferable, but any method may be used as long as the above range is achieved.
  • the sulfuric acid relative viscosity (hereinafter also simply referred to as the viscosity) of the high-strength polyamide 610 multifilament of the present invention needs to be 3.0 to 3.7, more preferably 3.0 to 3.5, still more preferably 3.0 to 3.3.
  • the viscosity of the multifilament is less than 3.0, a raw yarn having sufficient strength cannot be obtained, and when the viscosity exceeds 3.7, drawability and fluff quality may be deteriorated.
  • the dry strength of the polyamide 610 multifilament of the present invention needs to be more than 9.2 cN/dtex and 11.0 cN/dtex or less.
  • the strength is more preferably within 9.5 to 11.0 cN/dtex.
  • the high-strength polyamide 610 multifilament can be obtained by adjusting the high moisture content used in the present invention and achieving the following chip viscosity and the viscosity range of the multifilament.
  • the present inventors have found that in order to obtain a high-strength polyamide 610 multifilament having a dry strength exceeding 9.2 cN/dtex, it is important to improve drawability in a drawn portion as compared with the prior art and to realize high ratio drawing. For this purpose, the present inventors have found that it is necessary to set the viscosity of the polyamide 610 multifilament to 3.0 to 3.7 by setting the viscosity of the raw material chips to 3.6 to 4.0 and the moisture content to 0.2 to 0.35 wt%.
  • polyamide 610 surprisingly, the phenomenon in which a decrease in melt viscosity is observed is similar, but the elongation is maintained even when the draw ratio is set to be high, and as a result, it is possible to obtain a multifilament having high strength and high elongation. This is considered to be because water molecules act as a plasticizer in the polyamide 610 molecules.
  • the degree of orientation described later is increased, suggesting that the drawability is improved by the presence of water molecules.
  • the elongation is preferably 15% or more, more preferably 17% or more.
  • Polyamide 610 multifilaments having an elongation of less than 15% significantly deteriorate the fluff quality in the spinning process, and yarn breakage in the drawing process increases, so that productivity may be poor.
  • the polyamide 610 multifilament of the present invention preferably has change rates of strength, elongation, and intermediate elongation in a wet state of all 10% or less.
  • the change rates are more preferably all 5% or less, still more preferably all 2% or less.
  • the change in the strength/elongation curve, what is called an SS curve, in a wet state can be suppressed as compared with polyamide 6 or polyamide 66, which is a general-purpose polyamide.
  • the total fineness of the polyamide 610 multifilament of the present invention is preferably 100 to 2,500 dtex, more preferably 100 to 2,000 dtex.
  • the total fineness exceeds 2,500 dtex, the polymer output from the spinneret increases, and the cooling of the yarn immediately after spinning is insufficient, so that a multifilament having sufficient strength may not be obtained.
  • the single fiber fineness is preferably 1.5 to 40 dtex, more preferably 1.5 to 15 dtex.
  • a polyamide 610 multifilament having a single fiber fineness of less than 1.5 dtex has low abrasion resistance with drawing rolls in the spinning process, and thus the fluff quality may deteriorate when the draw ratio is increased to obtain high-strength fibers.
  • the single fiber fineness exceeds 40 dtex, it may be difficult to cool the polymer in the spinning process, and sufficient strength may not be obtained.
  • the birefringence ⁇ n of the high-strength polyamide 610 multifilament of the present invention is preferably 50.0 ⁇ 10 -3 or more, more preferably 52.0 ⁇ 10 -3 or more.
  • the birefringence of the multifilament is an index indicating the degree of orientation of molecules, and it is considered that in the high-strength polyamide 610 multifilament of the present invention, when a high ratio of moisture is added to the raw material chips, a sufficient amount of water molecules is present in the polyamide molecules, and the water molecules exhibit a plasticizer effect, thereby improving drawability.
  • the mechanical draw ratio can be increased, and the degree of molecular orientation, that is, the birefringence of the resulting multifilament is further increased.
  • the degree of molecular orientation increases, oriented crystallization also sequentially proceeds and increases, so that the strength of the multifilament tends to increase.
  • the birefringence ⁇ n is a value measured using a polarization microscope described later.
  • the polyamide 610 multifilament can be preferably produced by the following method based on normal melt spinning, but in the present invention, it is particularly effective to produce the polyamide 610 filament by a direct spinning/drawing method.
  • melt spinning it is preferable to control the viscosity of the chips to an appropriate viscosity and then impart a predetermined amount of moisture, whereby the strength and elongation can be improved, and yarn breakage and generation of fluff during drawing can be suppressed.
  • the polyamide 610 multifilament having high strength can be obtained.
  • Fig. 1 schematically shows a direct spinning/drawing machine preferably used in the present invention.
  • Polyamide 610 chips having adjusted viscosity, moisture content, and the like are melted and kneaded with an extruder type spinning machine (not illustrated in Fig. 1 ) and spun by being discharged from a spinneret 1 in a spinning section.
  • the spinning temperature is generally higher than the melting point of the target polymer by 30°C or more. When the temperature is lower than 30°C, the polymer is not uniformly melted due to insufficient heat quantity, and the melt viscosity is also increased, so that the spinnability becomes unstable.
  • Spun yarns 5 spun from the spinneret 1 pass through a heating cylinder 2 and are cooled by cooling air 4 with a crossflow cooling device 3.
  • the cooled yarns 5 pass through a duct 6 and are taken up by take-up rollers 8 while being supplied with a treatment agent by oiling devices 7.
  • the taken-up yarns 5 are subjected to pre-stretch drawing between the take-up rollers 8 and a take-up roller 9. Thereafter, the yarns are drawn in three stages by first drawing rollers 10, second drawing rollers 11, and third drawing rollers 12 and relaxed by relaxation rollers 13.
  • the relaxed yarns 5 are entangled by an entangling device 14 and wound by a winder 15 to form a fiber package 16.
  • the viscosity of the polyamide 610 chips used as a raw material is preferably 3.6 to 4.0, and the moisture content is preferably 0.2 wt% or more.
  • the take-up speed at the time of take-up is 350 to 1,100 m/min, preferably 400 to 800 m/min.
  • the treatment agent in the present invention is preferably used as a nonaqueous treatment agent, but sufficient physical properties can be obtained even when a water-containing treatment agent is used.
  • the method for applying the treatment agent is preferably an oiling roll device or a guide oiling.
  • the process from drawing to winding is preferably performed by a method in which the yarn is drawn in usually two or more stages and then relaxed to be wound up.
  • pre-stretch drawing and then perform drawing it is preferable to perform pre-stretch drawing and then perform drawing. It is preferable that the pre-stretch drawing and the first stage drawing be performed by heat drawing at around the glass transition temperature, and the remaining drawing and heat setting temperature be usually performed at a high temperature of 150 to 220°C. The temperature is more preferably 170 to 210°C.
  • the draw ratio that is, the ratio between the take-up rollers 8 and the second drawing rollers 11, is usually in the range of 3 to 6 times.
  • the winding speed is usually preferably 2,000 to 5,000 m/min, more preferably 2,000 to 4,000 m/min.
  • the polyamide 610 multifilament of the present invention can be produced by the above method.
  • Tenacity/strength/elongation (in wet state) A small skein having a predetermined yarn length was produced in the manner of JIS L 1013 (2010) 8.3.1 method A, and the small skein was immersed in tap water at 20°C for 24 hours. After a lapse of 24 hours, the small skein was taken out and measured within 10 minutes under constant speed elongation conditions defined in JIS L 1013 (2010) 8.5.1, Standard Time Test. The tenacity and elongation were determined from the maximum tenacity and maximum elongation in the S-S curve, and the strength was determined by dividing the tenacity by the total fineness.
  • the difference between each of the wet strength, the wet elongation, and the wet intermediate elongation obtained in this measurement and the value in a dry state was determined, and the absolute values of the differences were respectively divided by the dry strength, the dry elongation, and the dry intermediate elongation and expressed as percentages, so that the wet strength change rate, the wet elongation change rate, and the wet intermediate elongation change rate were calculated.
  • Birefringence ⁇ n Measurement was performed using a molecular orientation measurement device (Type: DELT_N-IIH) manufactured by INTEC Co., Ltd. Paraffin was added dropwise to a slide glass, one filament single fiber was placed on the slide glass, and the slide glass was covered with a cover glass from above. The slide glass was set in a polarizing microscope, and both ends of the single yarn were focused. A waveplate was inserted into the microscope to adjust a wavelength ⁇ at which black stripes were generated at both ends of the single yarn. In this measurement, waveplates were combined to achieve 2.5 ⁇ . Thereafter, a single yarn diameter D was measured by image processing. Subsequently, a distance L between two black interference fringes existing on both sides was measured.
  • a molecular orientation measurement device Type: DELT_N-IIH manufactured by INTEC Co., Ltd. Paraffin was added dropwise to a slide glass, one filament single fiber was placed on the slide glass, and the slide glass was covered with a cover glass from above. The slide
  • a 5-wt% aqueous solution of copper acetate as an antioxidant was added to and mixed with polyamide 610 (N610) chips obtained by liquid phase polymerization, and 70 ppm of copper was added and adsorbed relative to the polymer weight.
  • a 50-wt% aqueous solution of potassium iodide and a 20-wt% aqueous solution of potassium bromide were each added and adsorbed so as to be 0.1 parts by weight as potassium with respect to 100 parts by weight of the polymer chips, solid-phase polymerization was performed using a solid-phase polymerization apparatus, and then moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.80 and a moisture content of 0.31 wt%.
  • the device of Fig. 1 was used as the spinning device.
  • the polyamide 610 chips were supplied to an extruder, and the discharge amount was adjusted by a metering pump so that the total fineness was about 470 dtex.
  • the spinning temperature was 285°C, and the product was filtered through a metal nonwoven fabric filter in a spinning pack and then spun through a spinneret having 48 holes.
  • the spun yarns were passed through a heating cylinder heated to a temperature of 250°C and then cooled and solidified by cooling air at an air speed of 40 m/min.
  • a water-containing treatment agent was applied to the cooled and solidified yarns by the oiling devices 7, and the yarns were swirled by spinning take-up rollers to take up the yarns.
  • the taken-up yarns were then subjected to 5% stretching between the take-up rollers 8 and the take-up roller 9 without being wound up once, then subjected to first stage drawing between the take-up roller 9 and the first drawing rollers 10 so that the rotation speed ratio between the rollers was 2.55, and subsequently subjected to second stage drawing between the first drawing rollers 10 and the second drawing rollers 11 so that the rotation speed ratio between the rollers was 1.35. Subsequently, third stage drawing was performed between the second drawing rollers 11 and the third drawing rollers 12 such that the rotation speed ratio between the rollers was 1.65.
  • the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was set to 6.0.
  • 5% relaxation heat treatment was performed between the third drawing rollers 12 and the relaxation rollers 13, and the yarns were entangled by the entangling device 14 and then wound by the winding device 15.
  • the surface temperature of each roller was set so that the take-up rollers were at room temperature, yarn feeding rollers at 45°C, the first drawing rollers at 95°C, the second drawing rollers at 150°C, the third drawing rollers at 200°C, and the relaxation rollers at 140°C.
  • the entangling treatment was performed by injecting highpressure air from a direction perpendicular to the traveling yarns in the entangling device. A guide for regulating the traveling yarns was provided before and after the entangling device, and the pressure of the injected air was constant at 0.2 MPa. Under the above conditions, a 470-dtex polyamide 610 multifilament was obtained.
  • the obtained multifilament had very high drawability and could be drawn at a high ratio.
  • a dry strength of 10.1 cN/dtex was obtained. Since the birefringence of the multifilament was as high as 58.2, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.80 and a moisture content of 0.25 wt%.
  • the obtained multifilament had very high drawability and could be drawn at a high ratio while the moisture content was 0.25 wt%.
  • a dry strength of 10.0 cN/dtex was obtained. Since the birefringence of the multifilament was as high as 55.2, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.80 and a moisture content of 0.21 wt%.
  • Production was carried out in the same manner as in Example 1 except that the third stage drawing was carried out between the second drawing rollers 11 and the third drawing rollers 12 so that the rotation speed ratio between the rollers was 1.59 and that the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was changed to 5.75.
  • the obtained multifilament had high drawability and could be drawn at a high ratio while the moisture content was 0.21 wt%.
  • a dry strength of 9.8 cN/dtex was obtained. Since the birefringence of the multifilament was as relatively high as 52.3, it is suggested that oriented crystallization in the multifilament has been promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.80 and a moisture content of 0.25 wt%.
  • Production was carried out in the same manner as in Example 1 except that the third stage drawing was carried out between the second drawing rollers 11 and the third drawing rollers 12 so that the rotation speed ratio between the rollers was 1.59 and that the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was changed to 5.75.
  • the obtained multifilament had very high drawability and could be drawn at a high ratio while the moisture content was 0.25 wt%.
  • a dry strength of 9.6 cN/dtex was obtained. Since the birefringence of the multifilament was as high as 53.8, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.80 and a moisture content of 0.22 wt%.
  • the discharge amount was adjusted with a metering pump so that the total fineness was about 970 dtex, and spinning was performed through a spinneret having 204 holes.
  • Production was carried out in the same manner as in Example 1 except that, in the take-up and drawing, the third stage drawing was carried out between the second drawing rollers 11 and the third drawing rollers 12 so that the rotation speed ratio between the rollers was 1.50 and that the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was changed to 5.42.
  • the obtained multifilament had high drawability and could be drawn at a high ratio while the moisture content was 0.22 wt%, the total fineness was 970 dtex, and the number of filaments was 204. A dry strength of 9.4 cN/dtex was obtained. Since the birefringence of the multifilament was as relatively high as 51.6, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.79 and a moisture content of 0.15 wt%.
  • Production was carried out in the same manner as in Example 1 except that the third stage drawing was carried out between the second drawing rollers 11 and the third drawing rollers 12 so that the rotation speed ratio between the rollers was 1.55 and that the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was changed to 5.60.
  • the obtained multifilament had high drawability and could be drawn at a high ratio while the moisture content was 0.15 wt%.
  • a dry strength of 9.7 cN/dtex was obtained. Since the birefringence of the multifilament was as relatively high as 52.0, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.78 and a moisture content of 0.26 wt%.
  • the discharge amount was adjusted with a metering pump so that the total fineness was about 235 dtex, and spinning was performed through a spinneret having 136 holes.
  • Example 2 Production was carried out in the same manner as in Example 1 except that the take-up and drawing were performed at a rotation speed ratio of 2.40 between the take-up roller 9 and the first drawing rollers 10 in the first stage drawing, a rotation speed ratio of 1.35 between the first drawing rollers 10 and the second drawing rollers 11 in the second stage drawing, a rotation speed ratio of 1.41 between the second drawing rollers 11 and the third drawing rollers 12 in the third stage drawing, and a rotation speed ratio of 4.80 between the take-up rollers 8 and the third drawing rollers 12.
  • the obtained multifilament had extremely high drawability and could be drawn at a high ratio while the moisture content was 0.26 wt%, the total fineness was 235 dtex, and the number of filaments was 136. A dry strength of 9.3 cN/dtex was obtained. Since the birefringence of the multifilament was as high as 54.2, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.81 and a moisture content of 0.25 wt%.
  • the discharge amount was adjusted with a metering pump so that the total fineness was about 1,400 dtex, and spinning was performed through a spinneret having 204 holes.
  • Example 2 Production was carried out in the same manner as in Example 1 except that the take-up and drawing were performed at a rotation speed ratio of 2.70 between the take-up roller 9 and the first drawing rollers 10 in the first stage drawing, a rotation speed ratio of 1.35 between the first drawing rollers 10 and the second drawing rollers 11 in the second stage drawing, a rotation speed ratio of 1.46 between the second drawing rollers 11 and the third drawing rollers 12 in the third stage drawing, and a rotation speed ratio of 5.60 between the take-up rollers 8 and the third drawing rollers 12.
  • the obtained multifilament had high drawability and could be drawn at a high ratio while the moisture content was 0.25 wt%, the total fineness was 1,400 dtex, and the number of filaments was 204. A dry strength of 9.3 cN/dtex was obtained. Since the birefringence of the multifilament was as relatively high as 51.3, it is suggested that oriented crystallization in the multifilament has been sufficiently promoted.
  • the evaluation results of the tensile test in a wet state are shown in Table 1.
  • Chips were subjected to solid phase polymerization in the same manner as in Example 1, and moisture was added to obtain polyamide 610 chips having a sulfuric acid relative viscosity of 3.82 and a moisture content of 0.05 wt%.
  • the polyamide 610 chips were supplied to an extruder, and the discharge amount was adjusted by a metering pump so that the total fineness was about 470 dtex.
  • the spinning temperature was 285°C
  • the product was filtered through a metal nonwoven fabric filter in a spinning pack and then spun through a spinneret having 48 holes.
  • the spun yarns were passed through a heating cylinder heated to a temperature of 250°C and then cooled and solidified by cooling air at an air speed of 40 m/min.
  • a water-containing treatment agent was applied to the cooled and solidified yarns by the oiling devices 7, and the yarns were swirled by spinning take-up rollers to take up the yarns.
  • the taken-up yarns were then subjected to 5% stretching between the take-up rollers 8 and the take-up roller 9 without being wound up once, then subjected to first stage drawing between the take-up roller 9 and the first drawing rollers 10 so that the rotation speed ratio between the rollers was 2.55, and subsequently subjected to second stage drawing between the first drawing rollers 10 and the second drawing rollers 11 so that the rotation speed ratio between the rollers was 1.35. Subsequently, third stage drawing was performed between the second drawing rollers 11 and the third drawing rollers 12 such that the rotation speed ratio between the rollers was 1.35.
  • the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was set to 4.9.
  • 5% relaxation heat treatment was performed between the third drawing rollers 12 and the relaxation rollers 13, and the yarns were entangled by the entangling device 14 and then wound by the winding device 15.
  • the surface temperature of each roller was set so that the take-up rollers were at room temperature, yarn feeding rollers at 45°C, the first drawing rollers at 95°C, the second drawing rollers at 150°C, the third drawing rollers at 200°C, and the relaxation rollers at 140°C.
  • the entangling treatment was performed by injecting highpressure air from a direction perpendicular to the traveling yarns in the entangling device. A guide for regulating the traveling yarns was provided before and after the entangling device, and the pressure of the injected air was constant at 0.2 MPa. Under the above conditions, a 470-dtex polyamide 610 multifilament was obtained.
  • the obtained multifilament had insufficient drawability, and the limit of the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was about 5 times.
  • the dry strength at this time was only about 8.8 cN/dtex.
  • the birefringence of the multifilament was 47.0, which was lower than that of the multifilament of the present invention.
  • the evaluation results of the tensile test in a wet state are shown in Table 2.
  • Solid phase polymerization of chips was performed in the same manner as in Example 1, and no moisture was added.
  • the obtained polyamide 610 chips had a sulfuric acid relative viscosity of 3.82 and a moisture content of 0.02 wt%.
  • the obtained multifilament had insufficient drawability, and the limit of the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was about 5 times.
  • the dry strength at this time was only about 8.9 cN/dtex.
  • Solid phase polymerization of chips was performed in the same manner as in Example 1, and no moisture was added.
  • the obtained polyamide 610 chips had a sulfuric acid relative viscosity of 4.00 and a moisture content of 0.02 wt%.
  • Production was carried out in the same manner as in Example 1 except that the third stage drawing was carried out between the second drawing rollers 11 and the third drawing rollers 12 so that the rotation speed ratio between the rollers was 1.24 and that the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was changed to 4.50.
  • the obtained multifilament had poor drawability, and the limit of the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was about 4.5 times.
  • the dry strength at this time was only about 8.3 cN/dtex, and the fluff quality was not good.
  • the birefringence of the multifilament was 46.3, which was lower than that of the multifilament of the present invention.
  • the evaluation results of the tensile test in a wet state are shown in Table 2.
  • Chips obtained by liquid phase polymerization was changed from polyamide 610 chips to polyamide 6 chips, a 5-wt% aqueous solution of copper acetate as an antioxidant was added and mixed, and 70 ppm of copper was added and adsorbed relative to the polymer weight.
  • a 50-wt% aqueous solution of potassium iodide and a 20-wt% aqueous solution of potassium bromide were each added and adsorbed so as to be 0.1 parts by weight as potassium with respect to 100 parts by weight of the polymer chips, solid-phase polymerization was performed using a solid-phase polymerization apparatus, and then moisture was added to obtain polyamide 6 chips having a sulfuric acid relative viscosity of 3.80 and a moisture content of 0.05 wt%.
  • the polyamide 6 chips were supplied to an extruder, and the discharge amount was adjusted by a metering pump so that the total fineness was about 2,100 dtex.
  • the spinning temperature was 285°C
  • the product was filtered through a metal nonwoven fabric filter in a spinning pack and then spun through a spinneret having 306 holes.
  • the spun yarns were passed through a heating cylinder heated to a temperature of 315°C and then cooled and solidified by cooling air at an air speed of 35 m/min.
  • a water-containing treatment agent was applied to the cooled and solidified yarns by the oiling devices 7, and the yarns were swirled by spinning take-up rollers to take up the yarns.
  • the taken-up yarns were then subjected to 7% stretching between the take-up rollers 8 and the take-up roller 9 without being wound up once, then subjected to first stage drawing between the take-up roller 9 and the first drawing rollers 10 so that the rotation speed ratio between the rollers was 2.90, and subsequently subjected to second stage drawing between the first drawing rollers 10 and the second drawing rollers 11 so that the rotation speed ratio between the rollers was 1.50. Subsequently, third stage drawing was performed between the second drawing rollers 11 and the third drawing rollers 12 such that the rotation speed ratio between the rollers was 1.15.
  • the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was set to 5.37.
  • the surface temperature of each roller was set so that the take-up rollers were at room temperature, yarn feeding rollers at 45°C, the first drawing rollers at 105°C, the second drawing rollers at 180°C, the third drawing rollers at 200°C, and the relaxation rollers at 145°C.
  • the entangling treatment was performed by injecting highpressure air from a direction perpendicular to the traveling yarns in the entangling device. A guide for regulating the traveling yarns was provided before and after the entangling device, and the pressure of the injected air was constant at 0.3 MPa. Under the above conditions, a 2,100-dtex polyamide 6 multifilament was obtained.
  • the obtained multifilament had such drawability that the limit of the rotation speed ratio between the take-up rollers 8 and the third drawing rollers 12 was about 5.6 times.
  • the dry strength at this time was only about 9.2 cN/dtex.
  • the birefringence of the multifilament was 48.2, which was lower than that of the polyamide 610 multifilament of the present invention.
  • the evaluation results of the tensile test in a wet state are shown in Table 2, and since the polyamide 6 multifilament was used, the decrease in strength in the wet state was large.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Artificial Filaments (AREA)

Claims (11)

  1. Multifilament de polyamide 610 à haute résistance présentant une viscosité relative d'acide sulfurique de 3,0 à 3,7, dans lequel la viscosité relative d'acide sulfurique fait référence à une valeur obtenue en dissolvant un échantillon dans de l'acide sulfurique à 98 % et en mesurant la viscosité relative d'acide sulfurique à 25°C en utilisant un viscosimètre d'Ostwald, et une résistance à sec de plus de 9,2 cN/dtex et 11,0 cN/dtex ou moins telle que mesurée par le procédé de la description.
  2. Multifilament de polyamide 610 à haute résistance selon la revendication 1, présentant une finesse totale de 100 à 2 500 dtex et une finesse de fibre unique de 1,5 à 40 dtex.
  3. Multifilament de polyamide 610 à haute résistance selon la revendication 1 ou 2, présentant une biréfringence Δn de 50,0 x 10-3 ou plus telle que mesurée par le procédé de la description en utilisant un microscope à polarisation.
  4. Multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 3, dans lequel la viscosité relative d'acide sulfurique est de 3,0 à 3,3.
  5. Multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 4, présentant des taux de changement de résistance, d'allongement et d'allongement intermédiaire à l'état humide de 10 % ou moins, tels que mesurés par les procédés respectifs de la description.
  6. Multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 5, dans lequel la résistance à sec est comprise entre 9,5 et 11,0 cN/dtex, mesurée par le procédé de la description.
  7. Corde comprenant le multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 6.
  8. Cordage de raquette comprenant le multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 6.
  9. Textile pour un sac, comprenant le multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 6.
  10. Filet de pêche comprenant le multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 6.
  11. Procédé de production du multifilament de polyamide 610 à haute résistance selon l'une quelconque des revendications 1 à 6, le procédé comprenant les étapes consistant à :
    fournir des copeaux de polyamide 610 en tant que copeaux de matière première ;
    ajuster la viscosité relative d'acide sulfurique des copeaux de matière première à une valeur de 3,6 à 4,0 ; et
    ajuster la teneur en humidité des copeaux de matière première à une valeur de 0,15 % en poids ou plus, telle que mesurée par le procédé de la description.
EP21775467.0A 2020-03-25 2021-03-10 Multifilament de polyamide 610 à haute résistance et procédé de production d'un tel multifilament Active EP4130354B1 (fr)

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JPS609910A (ja) * 1983-06-22 1985-01-19 Unitika Ltd ポリアミドモノフイラメント
JPS60119215A (ja) * 1983-12-01 1985-06-26 Unitika Ltd 高強力ポリアミドマルチフィラメント糸の製造法
JPH042814A (ja) * 1990-04-17 1992-01-07 Teijin Ltd 高収縮性ポリアミドマルチフィラメント糸、及びその製造方法
JP2011001635A (ja) 2009-06-16 2011-01-06 Toray Ind Inc ディスプレイパネル洗浄ブラシ用ポリアミド繊維およびその製造方法
JP2012251263A (ja) * 2011-06-03 2012-12-20 Toray Ind Inc ポリアミド繊維の製造方法
JP2014214405A (ja) 2013-04-30 2014-11-17 東レ株式会社 ポリカプラミドフィラメントの製造方法
US20170311651A1 (en) * 2014-11-12 2017-11-02 Toray Industries, Inc. Ultra-fine high-strength polyamide multifilament, and covering yarn, stocking, and fabric using same
TWI519687B (zh) * 2014-12-19 2016-02-01 展頌股份有限公司 消光聚醯胺５６纖維及其製造方法
CN105780179A (zh) * 2016-05-13 2016-07-20 东华大学 一种聚酰胺纤维及其制备方法
JP7013932B2 (ja) * 2018-02-26 2022-02-15 東レ株式会社 漁網用ポリアミド６１０マルチフィラメント
KR102674777B1 (ko) 2018-02-26 2024-06-13 도레이 카부시키가이샤 폴리아미드 610 멀티필라멘트
US20190382924A1 (en) * 2018-06-19 2019-12-19 Shakespeare Company, Llc Nylon based materials, filaments, and fabrics and associated methods
JP2020133061A (ja) * 2019-02-21 2020-08-31 東レ株式会社 ロープ用ポリアミド６１０マルチフィラメント。

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TWI855241B (zh) 2024-09-11
EP4130354A1 (fr) 2023-02-08
JPWO2021193056A1 (fr) 2021-09-30
WO2021193056A1 (fr) 2021-09-30
EP4130354A4 (fr) 2024-05-01
CN115053025A (zh) 2022-09-13
US20230115178A1 (en) 2023-04-13
CN115053025B (zh) 2024-03-26

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