EP3759177A1 - Dispersion-based coating - Google Patents
Dispersion-based coatingInfo
- Publication number
- EP3759177A1 EP3759177A1 EP19713680.7A EP19713680A EP3759177A1 EP 3759177 A1 EP3759177 A1 EP 3759177A1 EP 19713680 A EP19713680 A EP 19713680A EP 3759177 A1 EP3759177 A1 EP 3759177A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dispersion
- weight
- based coating
- coating according
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 34
- 239000006185 dispersion Substances 0.000 title claims abstract description 33
- 239000011248 coating agent Substances 0.000 title claims abstract description 31
- 229920000642 polymer Polymers 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 11
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 10
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Chemical class 0.000 claims description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- -1 siloxanes Chemical class 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 239000005871 repellent Substances 0.000 claims description 3
- 230000002940 repellent Effects 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 2
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims description 2
- 150000003440 styrenes Chemical class 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 150000003626 triacylglycerols Chemical class 0.000 claims description 2
- 235000013799 ultramarine blue Nutrition 0.000 claims description 2
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims 2
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 1
- 230000008719 thickening Effects 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 8
- 235000019353 potassium silicate Nutrition 0.000 description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- YRJYANBGTAMXRQ-UHFFFAOYSA-N pyrazolo[3,4-h]quinazolin-2-one Chemical compound C1=C2N=NC=C2C2=NC(=O)N=CC2=C1 YRJYANBGTAMXRQ-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 125000005625 siliconate group Chemical group 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
Definitions
- the present invention relates to a dispersion-based coating using calcium hydroxide for pH control.
- Pure silicate dyes are two-component colors that contain no organic components.
- the two main components are water glass and water glass resistant pigment and fillers.
- Dispersion silicate dyes according to DIN 18363 contain, in addition to the water glass and the pigment / filler mixture, up to 5% by weight of organic constituents, based on the total amount.
- Emulsion paints usually contain resin dispersions for setting. In order to ensure a sufficient Lagerstabili ity require emulsion paints Topfkonser multungsstoff, in which case the use of isothiazolinones is common. These can cause irritation and irritation of the skin in susceptible persons.
- the publication DE 10 2016 002 221 A1 describes a combination of 1 to 15% by weight of pigment with 30 to 60% by weight of filler, 1 to 25% by weight of polymer, 0.1 to 3.5% by weight.
- German Offenlegungsschrift DE 10 2014 013 455 A1 finally describes a preservative-free dispersion paint based on siliconate, the proportion of the silicic acid being between 0.5 and 5%, preferably between 1 and 3%, and thus no preservatives are required in the still good ones Storage stability of over 6 months, even if the silicone additive is in the lower range.
- the object of the present invention is to formulate a Beschich tion on a dispersion basis covering the entire gloss range of the dispersion coatings, this is free of preservatives and at the same time has a very good shelf life and processing properties.
- the inventive coating on Dispersionsba sis has a pH of 10.5-12 and contains based on the total recipe the following components: a) 0.1 to 30% by weight of pigment, b) 15 to 65% by weight of filler, c) 1 to 35% by weight of polymer, d) 0.01 to 1% by weight of calcium hydroxide e) 5 to 70% by weight of water.
- the coating according to the invention contains on dispersion basis 0.1 to 30 wt .-% pigment.
- a pigment here are various substances in question.
- the pigment is selected from the group consisting of titanium dioxide, iron oxide yellow, bismuth vanadate, rutile tin zinc, quinacridones, iron oxide red, phthalocyanine blue, dioxazine, cobalt blue, ultramarine blue, phthalocyanine green, chrome oxide green, cobalt green, color black, iron oxide black, pyrazolo quinazolone, monoazo pigment and mixtures thereof.
- the coating according to the invention contains 10 to 65% by weight of filler based on dispersion.
- filler consisting of dolomite, barium sulfate, feldspar, quartz, calcium carbonate, mica, kaolin, calcined kaolin, talc, diatomaceous earth and mixtures.
- the dispersion-based coating contains 1 to 35% by weight of polymer, based on the total recipe.
- the information relating to the content of polymer relate in each case to the polymer as a solids content.
- the polymer is preferably added during the preparation in the form of a dispersion.
- the polymer of the coating according to the invention preferably comprises at least one polymer and / or copolymer based on at least one monomer selected from the group consisting of acrylic acid, acrylic acid derivatives, acrylic esters, methacrylic acid, methacrylic acid derivatives, methacrylic acid esters, styrene, styrene derivatives, N-vinylpyrrolidone, acrylonitrile , Vinyl acetate, vinyl propionate, ethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acid esters, ethylenically unsaturated carboxylic acid anhydrides, ethylenically unsaturated carboxylic acid amides and carboxylic acid vinyl esters.
- Dispersionsba sis may also contain as further additives dispersants, wetting agents, thickeners, stabilizers, defoamers and / or Hydropho b istsstoff.
- thickeners are alcohol alkoxylates, ethylene oxide-propylene oxide copolymers, maleic anhydride-diisobutylene copolymers, polyacrylic and polymethacrylic acid and salts thereof, methylcelluloses, carboxymethylcelluloses, hydroxymethylcelluloses, polyurethanes, alkali metal phosphates and salts of modified phosphoric acids , as well as their mixtures.
- defoamers are polyglycols, triglycerides, polysiloxane-polyether copolymers and silicone oils.
- water repellents are in particular oligomeric and polymeric siloxanes and silicone resins.
- the coating according to the invention on Dispersionsba sis is suitable for a variety of uses. In particular, it is suitable for use in the interior and / orjonbe rich and on different substrates.
- the dispersion-based coating thus obtained covers the entire gloss range of the dispersion coatings, is free from preservatives and also has a very good shelf life and processing properties.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102018104815.7A DE102018104815A1 (en) | 2018-03-02 | 2018-03-02 | Dispersion-based coating |
| DE202018101199.5U DE202018101199U1 (en) | 2018-03-02 | 2018-03-02 | Dispersion-based coating |
| PCT/DE2019/100183 WO2019166062A1 (en) | 2018-03-02 | 2019-02-28 | Dispersion-based coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3759177A1 true EP3759177A1 (en) | 2021-01-06 |
Family
ID=65951447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19713680.7A Withdrawn EP3759177A1 (en) | 2018-03-02 | 2019-02-28 | Dispersion-based coating |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP3759177A1 (en) |
| WO (1) | WO2019166062A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12384921B2 (en) * | 2020-06-03 | 2025-08-12 | Bona AB | Air purifying coating system and method for making same |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10066302A1 (en) | 2000-06-21 | 2002-01-17 | Murjahn Amphibolin Werke | PRESERVATIVE-FREE DISPERSION COLOR |
| DE10144187B4 (en) * | 2001-09-07 | 2007-12-13 | Schülke & Mayr GmbH | Preservative for coating compositions |
| JP2004269860A (en) * | 2003-02-18 | 2004-09-30 | Kansai Paint Co Ltd | Powder coating having water re-dispersion property and method for producing the same |
| AR060509A1 (en) * | 2006-04-13 | 2008-06-25 | Sherwin Williams Co | PIGMENTATION AND COATING COMPOSITION ABLE TO INHIBIT CORROSION OF SUBSTRATES |
| DE102009025169A1 (en) * | 2009-06-12 | 2010-12-30 | Sto Ag | coating |
| AT511015B1 (en) * | 2011-01-19 | 2017-01-15 | Kiss Johann | COMPOSITION FOR PREPARING FLAME-REDUCING SURFACES OR OBJECTS |
| DE102014013455A1 (en) | 2014-09-17 | 2016-03-31 | Diessner GmbH & Co KG Lack- und Farbenfabrik | Pot preservative-free emulsion paint based on siliconate |
| DE102016002221A1 (en) | 2016-02-26 | 2017-08-31 | Brillux Gmbh & Co. Kg | emulsion paint |
| CN106590034B (en) * | 2016-12-13 | 2019-01-01 | 广西壮族自治区化工研究院 | A kind of phosphite powder of nano-oxide inorganic coating and water paint containing the powder |
| DE202017104644U1 (en) * | 2017-08-03 | 2017-08-17 | Schulz Farben- Und Lackfabrik Gmbh | Titanium dioxide-free composite and titanium dioxide-free emulsion paint |
| DE102017008984A1 (en) * | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Storage stable coating composition |
| DE102017008986A1 (en) * | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Storage stable coating composition |
-
2019
- 2019-02-28 EP EP19713680.7A patent/EP3759177A1/en not_active Withdrawn
- 2019-02-28 WO PCT/DE2019/100183 patent/WO2019166062A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019166062A1 (en) | 2019-09-06 |
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