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EP3752672B1 - Procédé de fabrication d'une couche d'oxyde de graphène/graphène et support revêtu d'oxyde de graphène/graphène - Google Patents

Procédé de fabrication d'une couche d'oxyde de graphène/graphène et support revêtu d'oxyde de graphène/graphène Download PDF

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Publication number
EP3752672B1
EP3752672B1 EP19706497.5A EP19706497A EP3752672B1 EP 3752672 B1 EP3752672 B1 EP 3752672B1 EP 19706497 A EP19706497 A EP 19706497A EP 3752672 B1 EP3752672 B1 EP 3752672B1
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Prior art keywords
graphene
graphene oxide
support
suspension
oxide layer
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German (de)
English (en)
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EP3752672A1 (fr
Inventor
Göran Bolin
Erkki LAITI
Eric Rousset
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Ahlstrom Munksjo Oyj
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Ahlstrom Munksjo Oyj
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/198—Graphene oxide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/46—Non-siliceous fibres, e.g. from metal oxides
    • D21H13/50—Carbon fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/08—Flakes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures

Definitions

  • the present invention relates to a method of manufacturing a graphene and graphene oxide layer, to a method of manufacturing graphene and graphene oxide-coated support and a graphene and graphene oxide-coated support.
  • WO 2018/018655 discloses a method for surface strengthening comprising the steps of applying graphene or graphene oxide to a surface as an absorption layer, applying optical glass or silica gel as a constraining layer thereon, and treating with pulsed laser light.
  • the laser beam is irradiated onto the absorption layer through the constraining layer; the absorption layer absorbs the laser energy to rapidly creating high temperature and high pressure plasma.
  • the rapid expansion of the plasma creates a high-intensity shock wave and the shock wave presses a part of the coating onto the surface, increasing the adhesion.
  • graphene it is desirable to manufacture it in a large scale at a reasonable cost. Further a graphene/graphene oxide layer which is continuous is desired.
  • a graphene layer comprising the steps of:
  • step b1) a graphene bonding liquid is applied on the support and, in step c), at least a part of the graphene bonding liquid is evaporated.
  • the graphene/graphene oxide layer is subjected, in step c), to heat from a non-contact or contact heat source.
  • the graphene and graphene oxide layer is subjected, in step e), to an annealing step to heat the graphene and graphene oxide layer.
  • a graphene and graphene oxide coated support is manufactured according to the method described above, wherein the support is paper.
  • One advantage is that a graphene and graphene oxide coating is obtained, which has few seams. An almost continuous graphene and graphene oxide layer could be obtained in one embodiment.
  • One advantage is that the material is inexpensive to manufacture in large scale.
  • the process makes it possible to fine-tune the quality of the graphene/graphene oxide coating according to the needs and thereby to optimize the cost.
  • Fig. 1 shows a schematic representation of a preferred embodiment of the method in accordance with the present invention where graphene/graphene oxide is applied on paper.
  • the reference numeral 1 stands for a paper roll, from where the paper is, preferably, but not necessarily, taken on a support of a wire or a table (not shown).
  • the reference numeral 2 stands for the optional application of graphene bonding liquid on the paper
  • reference numeral 3 the application of graphene/ graphene oxide suspension on the paper
  • reference numeral 4 heating of the graphene/graphene oxide suspension and the paper by means of a non-contact or contact heat source to evaporate liquid to form a layer of graphene/graphene oxide on the paper
  • reference numeral 5 calendering of the graphene/graphene oxide layer and the paper, optionally with heat treatment
  • reference numeral 6 repeated and optional application of graphene bonding liquid on the paper
  • reference numeral 7 repeated application of graphene/graphene oxide suspension on the paper
  • reference numeral 8 repeated heating of the graphene/graphene oxide suspension and the paper by means of a non-contact or contact heat source to evaporate liquid to form a layer of graphene/graphene oxide on the paper
  • reference numeral 9 repeated calendering of the graphene/graphene oxide layer and the paper, optionally with heat treatment
  • the coating is dried with a combination of different contact or non-contact driers according to desired drying profile.
  • the non-contact drier is the preferred alternative.
  • the heating is performed by means of a non-contact heat source, placed above the paper so that the heat is directed onto the coated side of the paper.
  • graphene/graphene oxide is here meant a mixture of graphene and graphene oxide.
  • a suspension is formed of a suspension liquid and graphene/graphene oxide particles.
  • the suspension liquid is preferably water, though also water with surface additives may be used.
  • Other suitable suspension liquids include organic solvents such as N-Methyl-pyrrolidone, Dimethylformamide, just to name a few alternatives without any intention of limiting the present invention to the listed options.
  • the suspension comprises small particles of graphene/graphene oxide. In one embodiment the particles are shaped as flakes.
  • Graphene particles are generally produced by separating layers of graphene from their parent compound, graphite.
  • a common method for this separation of graphene layers is referred to as exfoliation, and during the exfoliation process of graphite, several layers of graphene are separated from the massive number of weakly bound graphene layers which constitute graphite.
  • Various production techniques determine the total number of layers in graphene particles, therefore the number of layers present in the graphene particles will be variable. Nonetheless, the graphene particles still contain a vastly reduced number of layers compared to that of graphite.
  • Each one of the graphene particles does not necessarily comprise a monolayer of graphene, but each particle may instead comprise a plurality of graphene layers.
  • the term graphene is also used to denote several layers of graphene.
  • graphene oxide is used to describe an oxidized form of graphene containing oxygen-containing groups such as epoxide, carbonyl, carboxyl, and hydroxyl groups.
  • oxygen-containing groups such as epoxide, carbonyl, carboxyl, and hydroxyl groups.
  • the ratio of carbon to oxygen varies depending on the level of oxidation, which varies according to production method and subsequent treatment processes, such as reduction of graphene oxide.
  • exfoliation of graphite oxide is a common route to obtain graphene oxide particles, and therefore - not only the degree of oxidation - but the number of layers can vary according to manufacturing method as well as other factors. Nonetheless, the graphene oxide particles still contain a vastly reduced number of layers compared to that of graphite oxide.
  • Each one of the particles does not necessarily comprise a monolayer of graphene oxide, but each particle may instead comprise a plurality of graphene oxide layers.
  • graphene oxide is used to denote several layers of graphene oxide.
  • the suspension is created by the dispersion of exfoliated graphene/graphene oxide particles in a suspension liquid.
  • Dispersion of graphene/graphene oxide molecules can be achieved by application of external energy to the mixture most commonly with high-shear mixers, for example a rotor-stator mixer, treatment with ultrasound, for example a ultrasound probes or ultrasonic homogenizers, or other techniques known to persons skilled in the art, for example milling or high pressure homogenization.
  • high-shear mixers for example a rotor-stator mixer
  • ultrasound for example a ultrasound probes or ultrasonic homogenizers
  • milling or high pressure homogenization for example milling or high pressure homogenization.
  • the graphene/graphene oxide suspension may contain graphene and graphene oxide mixtures in a suspension liquid.
  • concentration of the mixture of graphene and graphene oxide in the suspension may be prepared in concentration up to about 15% by weight. High concentrations may present challenges such as undesired agglomeration of graphene/graphene oxide (undesirable re-stacking of layers), increased viscosity, and lower suspension stability (rapid sedimentation, for example).
  • the graphene and graphene oxide suspension quality may be improved by the addition of binders, co-binders, solvents/co-solvents as well as additives such as dispersants, surfactants, stabilizers, rheology modifiers, water retention aids, lubricants and insolubilizes, plasticizers, preservatives, anti-foams, dyes etc. into the suspension liquid.
  • binders co-binders
  • solvents/co-solvents as well as additives such as dispersants, surfactants, stabilizers, rheology modifiers, water retention aids, lubricants and insolubilizes, plasticizers, preservatives, anti-foams, dyes etc.
  • Surfactants can play a role in stabilizing the suspension, maintaining separation of exfoliated graphene and graphene oxide layers, or even promoting additional exfoliation of layers under certain circumstances.
  • surfactants and stabilizers include ionic, non-ionic, and zwitterionic surfactants, for example sodium dodecyl sulfate (SDS), sodium dodecylbenzylsulfonate (SDBS), sodium cholate, sodium taurodeoxycholate, dodecyltrimethyl ammonium bromide (DTAB), pyrene, pyrene-derivatives, Triton X-100, Tween 20, polyvinylpyrrolidone (PVP), ethyl cellulose, acrylic polymer, Pluronic ® P-123, Pluronic ® F-108.
  • SDS sodium dodecyl sulfate
  • SDBS sodium dodecylbenzylsulfonate
  • DTAB dodecyltrimethyl am
  • Rheology modifiers may, on their part, include, without going into their chemical composition, synthetic thickeners and water retention aids as well as natural thickeners and water retention aids (such as nanofibrillated cellulose), co-binders may also have a rheology modifier function.
  • the graphene/ graphene oxide suspension To be applied to the substrate, the graphene/ graphene oxide suspension must possess certain characteristics suitable to the substrate. Properties that make the graphene/graphene oxide suspension suitable for application to the substrate include stability of the suspension used in the process, rheology/viscosity and surface tension.
  • the suspension stability depends, for instance, on particle size distribution (finer particles are easier to stabilize: too large particles cannot be stabilized) and on particle-particle interactions.
  • repulsive forces are needed between the particles, such as electrostatic repulsion or steric repulsion, surfactants and polyelectrolytes being examples of how particle - particle repulsion is achieved.
  • the graphene/graphene oxide suspension should preferable be shear thinning and it should not be dilatant.
  • the shear viscosity of the graphene/graphene oxide suspension should not increase with application of shear rate as in a dilatant.
  • the viscosity should stay relatively stable during the coating process (as a function of time).
  • Each coating process requires an adapted viscosity level for good quality coating.
  • the coating suspension of graphene and graphene oxide is prepared to its highest practical solids content that still allows reaching correct rheological behavior (runnability & coating surface quality). In some cases however the coating solids content may be lowered in order to reduce the coat weight.
  • the graphene bonding liquid is used optionally, depending on the properties of the paper substrate.
  • the graphene bonding liquid is a liquid allowing adhesion (net attractive force) between the adhesive (in the graphene bonding liquid) and graphene particles.
  • An aqueous liquid is probably the most realistic alternative, at least for large scale manufacturing.
  • standard paper may be unsuitable as a substrate.
  • suitable paper substrates are commercially available and may be used, in which case the graphene bonding liquid is not required. Therefore, graphene bonding liquid is primarily an agent that, when applied, may be used to make standard paper suitable as a substrate for subsequent application of the graphene and/or graphene oxide suspension.
  • the graphene bonding liquid may be an aqueous solution or suspension containing common binders used for paper treatment, including - but not limited to - water soluble polymers such as polyvinyl alcohol (PVOH), starch, modified starch, or latexes such as latexes of polyacrylate or latexes of polyvinylidene dichloride (PVDC).
  • PVOH polyvinyl alcohol
  • PVDC polyvinylidene dichloride
  • the graphene bonding liquid may be in the form of a liquid, mixture of liquids, solution, suspension, emulsion or colloid.
  • the graphene bonding liquid may include particular agents, which have an affinity for graphene/graphene oxide, having non-covalent interactions with graphene / graphene oxide and with the substrate leading to, for example, surface adsorption or ⁇ - ⁇ stacking.
  • agents may be, for example, ionic, anionic, or zwitterionic surfactants and/or polymers, including but not limited to specialized pyrene derivatives such as 1-aminopyrene, pyrenesulfonic acid hydrate, pyrenesulfonic acid sodium salt, pyrenetetrasulfonic tetra acid tetra sodium salt hydrate, 1-pyrenebutyric acid, various (pyrenyl)alkyl sulfonates, derivatives of imidazole-linked pyrenes, and pyrene-terminated or pyrene-functionalized polymers and copolymers.
  • pyrene derivatives such as 1-aminopyrene, pyrenesulfonic acid hydrate, pyrenesulfonic acid sodium salt, pyrenetetrasulfonic tetra acid tetra sodium salt hydrate, 1-pyrenebutyric acid, various (pyrenyl)alkyl sulf
  • suitable paper substrates which do not require the use of bonding liquid, when coated with conventional paper coating methods, include:
  • Spantex TM Impregnated Balancing Foil An example of a suitable paper substrate is Spantex TM Impregnated Balancing Foil.
  • the liquid to be evaporated is the graphene bonding liquid and the liquid used to make the suspension of graphene/graphene oxide. In one embodiment essentially all liquid is evaporated by heat. In an alternative embodiment only a part of the liquid is evaporated in step c).
  • the graphene/graphene oxide particles are drawn together and to the paper so that a closer packed graphene/graphene oxide layer is formed.
  • the liquid evaporates the distance between the graphene/graphene oxide particles decreases so that a graphene/graphene oxide layer is formed where the particles are closer to each other compared to before the evaporation.
  • the layer of graphene/graphene oxide particles and the paper is subjected to pressure it is conceived that a pressure is applied on both sides of the paper.
  • the paper is pressed between two objects. This is typically made by feeding the paper between two rolls so that a pressure is applied on the paper.
  • one roll or both of the rolls may be heated whereby the layer of graphene/graphene oxide particles and the paper is subjected to pressure under heat.
  • the pressure is applied the layer of graphene/graphene oxide is further compressed and is more closely bonded to the paper.
  • the individual graphene/graphene oxide particles may to some extent form a more covering graphene/graphene oxide layer.
  • Annealing is a common term used when speaking of the production or post-production of graphene/graphene oxide films or graphene/graphene oxide layers.
  • Annealing is generally a thermal process, and is common in the art for treating graphene/graphene oxide layers and films, implemented most frequently as a cleaning process to remove residual contaminants from the binding liquid or graphene/graphene oxide suspension (for example from surfactants, rheology modifiers, stabilizers), which otherwise effect the performance properties of the graphene/graphene oxide layer (such as its electrical, thermal, or chemical properties) and are therefore capable of improving the properties of the formed graphene/graphene oxide layer.
  • Thermal annealing can be carried out at various temperatures, the effect of which is dependent upon atmosphere (for example air, gas, inert gas (eg N 2 ), gas mixtures, for example Ar/H 2 , inert gas, or vacuum) and can be carried out at various lengths of time and at various temperatures often at or between, for example, about 175 - 500 °C.
  • atmosphere for example air, gas, inert gas (eg N 2 ), gas mixtures, for example Ar/H 2 , inert gas, or vacuum
  • the drying step not only removes liquids such as water or solvents, more generally graphene bonding liquid and/or suspension liquid, but also constitutes a thermal annealing step and improves the graphene/graphene oxide layer properties by removing residual contaminants introduced during formation of the graphene/graphene oxide layer.
  • advanced annealing techniques may confer further improved properties to the graphene/graphene oxide layer.
  • advanced annealing techniques include, for example, photonic annealing, laser annealing, or microwave annealing.
  • Additional, specialized annealing steps at higher temperatures may provide localized instantaneous heating of the graphene/graphene oxide layer to temperatures in range of 2000°C, and may have pronounced effects on the structure of a formed graphene/graphene oxide layer - improving factors such as the continuity of the sheet, homogeneity of its composition, enhanced flatness - essentially improving the properties that arise from the unique properties that arise from the 2-dimensional (planar) physiochemical nature of graphene/graphene oxide based layers and films, therefore improving the formed graphene/graphene oxide layer.
  • the effects may be so pronounced that they may be observed macroscopically, where improvement to material properties like electrical conductivity are observed, or even at the molecular level using advanced imaging techniques (like SEM)
  • the graphene/graphene oxide layer is subjected to laser light to heat the graphene/graphene oxide
  • laser light of any suitable wavelength irradiates the graphene/graphene oxide to heat it. It is important that the heating only takes place for a very short moment so that the graphene/graphene oxide is heated, but so that the paper is not heated to any major extent. In one embodiment of the present invention the paper is not heated above 250°C in order not to cause any significant impact on the properties of the paper.
  • the quick heating to high temperature typically above 2000°C
  • the graphene/graphene oxide is bonded together to an essentially covering graphene/graphene oxide layer.
  • the graphene/graphene oxide is heated to a temperature in the interval of 1500-3000°C.
  • One way of realizing the quick heating is to use a powerful laser which sweeps rapidly over the surface so that each spot is only heated for a very short moment.
  • the quick laser irradiation has the effect that the graphene/graphene oxide is heated to a high temperature, whereas the underlying paper is not heated to any major extent, or at least not to any detrimental extent.
  • Any suitable laser source can be used as long as it can deliver a short and sufficiently powerful light to the graphene/graphene oxide particles. Examples of lasers include both continuous lasers and pulsed lasers.
  • the wavelength of the laser is preferably selected so that the heating of graphene/graphene oxide is efficient.
  • a mirror can be utilized to sweep the laser over the paper surface.
  • the laser irradiation is in one embodiment carried out in a cooled compartment and/or the paper is cooled from the side where graphene/graphene oxide layer is not applied, i.e. at the face of the paper opposite to the graphene/graphene oxide layer.
  • the heat from the spot that is heated with laser dissipates to the surroundings, both adjacent graphene/graphene oxide layer and the underlying paper. Since the heating is so quick and on such a small area the heat energy is small and when the heat energy dissipates to the underlying paper the temperature of the underlying paper will not give any negative effects on the paper. Thus it is possible to heat the graphene to above 2000°C for a short while on a small area while the underlying paper is not negatively affected.
  • the laser heating is made in room temperature without additional cooling, the heat is then dissipated to the underlying paper and the surroundings so that the temperature does not reach too high a value.
  • a short heating time may be achieved by sweeping the laser over the paper and by adjusting the sweep speed so that the graphene is heated sufficiently, but so that the paper is not heated too much.
  • the inventor speculate that the laser irradiation both bonds the graphene/graphene oxide particles together and increases the bonding to the underlying paper. After the laser treatment the graphene/graphene oxide coating becomes much more uniform and more homogenous.
  • the graphene bonding liquid and the suspension liquid is the same and steps b1) and b) are carried out in one step.
  • steps b1) and b) are carried out in one step.
  • a separate graphene bonding liquid is not applied, instead the liquid in which the graphene particles are suspended act as graphene bonding liquid.
  • the graphene bonding liquid is water, optionally with surface active additives to adjust the surface tension.
  • the graphene/graphene oxide particles are suspended in water.
  • a suitable paper substrate is used, so that a graphene bonding liquid is not required, and the graphene and graphene oxide suspension may be applied directly.
  • a particularly advantageous embodiment of this invention employs a suspension containing a mixture of both graphene and graphene oxide.
  • steps b), c), and d) are repeated until a layer of desired thickness of graphene/graphene oxide is obtained. In one embodiment the steps are carried out twice.
  • steps b), c), and d) are repeated until a layer of desired thickness of graphene/graphene oxide is obtained. In one embodiment the steps are carried out at least twice.
  • steps b), and c) are repeated until a layer of desired thickness of graphene/graphene oxide is obtained. In one embodiment the steps are carried out at least twice.
  • steps b1), b), and c) are repeated until a layer of desired thickness of graphene/graphene oxide is obtained. In one embodiment the steps are carried out at least twice.
  • steps b1), b), c) and d) are repeated until a layer of desired thickness of graphene/graphene oxide is obtained. In one embodiment the steps are carried out at least twice.
  • the thickness of the layer is controlled by the concentration of graphene/graphene oxide in the suspension.
  • concentration of graphene/graphene oxide in the suspension By adjusting the concentration of graphene/graphene oxide in the suspension also the number the steps b), c), at least, need to be repeated to reach the desired thickness of graphene/graphene oxide layer may be controlled.
  • the thickness of the coating is controlled by the technique employed to apply the suspension to the substrate.
  • Various techniques are known to persons of ordinary skill in the art, for example blade coating, rod coating, curtain coating, film press coating, foam coating and spray coating.
  • the thickness of the graphene/graphene oxide may be adjusted as desired before optionally performing step e) annealing.
  • the thickness of the graphene/graphene oxide before annealing it is possible to adjust the thickness and properties of the finished coating.
  • the drying step is carried out through non-contact heating, first by radiative heating, for example heating by Infra-Red lamps, followed by convective heating, for example by an air flotation dryer.
  • the drying step is carried out through non-contact heating at temperatures of about 300°C.
  • the drying is completed entirely through non-contact heating
  • the non-contact heating is optionally followed by contact heating (i.e. conductive heating), for example using a contact drum dryer.
  • contact heating i.e. conductive heating
  • the layer of graphene/graphene oxide and the paper is subjected to pressure and heat in a calender.
  • the layer of graphene/graphene oxide and the paper is subjected to a temperature of 100 - 300°C, preferably to 200-250°C in step d).
  • the layer of graphene/graphene oxide and the paper is subjected to pressure without heat in a calender
  • the layer of graphene/graphene oxide and the paper is subjected to at least one of super calendering, soft nip calendering, hard nip calendering, thermosoft calendering, shoe calendering, metal belt calendering, and multi-nip calendering.
  • the layer of graphene/graphene oxide and the paper is subjected to pressure in multiple steps, where the pressure increases for each step. In one embodiment this is carried out in a super calender with several rolls where the pressure is increased for every roll.
  • annealing in step e) is carried out with conventional thermal annealing by convection, using a drying oven in air atmosphere at 275°C for 30 minutes.
  • annealing in step e) is carried out using photonic annealing, by means of a Xenon Flashlamp as the pulsed radiation source, using a power density of 4 J/cm 2 and a flash time of 300 microseconds, allowing the coating layer to reach extremely high temperatures while the substrate is only heated to a fraction of the coating temperature during the flash, followed by cooling times on the order of milliseconds.
  • a particular advantage of photonic annealing is that it is amenable to substrates sensitive to thermal degradation. This is possible not only because the heating and cooling is completed so quickly, but also because many such substrates do not readily absorb much of the light emission from photonic annealing devices such as a Xenon Flashlamp. This allows surface coatings to be heated to extremely high temperatures upon inexpensive substrates that can be damaged by heat.
  • photonic annealing by Xenon flash can be used on substrates such as paper or polyethyleneterepthalate (PET), polyethylene (PE), polycarbonate (PC), and more.
  • annealing in step e) is carried out with a conventional 1000W microwave, and is performed using pulse time of about 2 seconds or less.
  • annealing in step e) is carried out in two steps, first with conventional thermal annealing at 375-500°C in a vacuum oven, followed by microwave annealing using a conventional 1000W microwave, performed using several pulses of about 1-2 seconds each.
  • step e) is performed by laser annealing and is carried out in oxygen free environment. If there is oxygen present during heating there is a significant risk that the graphene will oxidize. In general oxidation is not desired, so in most cases the environment in step e) should be oxygen free. The word oxygen free does not exclude that small amounts of oxygen can still be left even if care has been taken to remove as much oxygen as possible.
  • step e) is performed by laser annealing and is carried out in a vacuum.
  • step e) is performed by laser annealing and is carried out in an inert gas. Even if step e) is performed by laser annealing and is carried out in a vacuum or in an inert gas there still may be small amounts of oxygen left. Remaining amounts of oxygen should preferably be insignificant and so low that they do not affect the result adversely.
  • the graphene/graphene oxide is heated to a temperature in the interval 2000-2500°C in step e) by laser annealing. In one embodiment the graphene/graphene oxide is heated to a temperature above 2000°C in step e).
  • the paper is cooled during step e) of laser annealing.
  • graphene/graphene oxide is applied on one side of the paper during step b) and the paper is cooled during step e) from the side on which graphene/graphene oxide is not applied.
  • the paper may then be on a cooled surface.
  • step e) is performed by laser annealing and is carried out in a cooled atmosphere.
  • the finished paper is cooled after step e).
  • the paper for either step b1) or step b) is fed from a roll.
  • the finished paper is rolled up on a roll after step e). This facilitates manufacturing the graphene-coated paper in an industrial scale.
  • the method is carried out as a continuous process.
  • step a) i.e. the preparation of a suspension of graphene/graphene oxide in a suspension liquid is performed off-line, i.e. separate from the actual coating process.
  • step d) i.e. subjecting the graphene/graphene oxide layer and the support to pressure is performed off-line, in other words, the graphene/graphene oxide layer and the support are rolled on a roll and taken to another position for calendering.
  • the support is coated on both sides with the graphene/graphene oxide suspension. The coating may be performed in a single sequence of coating and drying steps or such that the support coated on one side is rolled on a roll and the unrolled for coating on the other side, i.e. off-line.
  • the above discussed method may be utilized, not only for producing a graphene-coated paper but also for producing a graphene/graphene oxide layer.
  • the manufacture of the graphene/graphene oxide layer is quite similar to the manufacture of the graphene-coated layer, except for the fact that in place of paper a specific support is used.
  • the support may be chosen from a group of alternative substrates, selected based on the desired function and properties of the final material but also their suitability to this manufacturing process.
  • the support may be chosen from a group of alternative substrates, selected based on the desired function and properties of the final material but also their suitability to this manufacturing process.
  • Examples include cellulosic or artificial fiber based substrates, coated and impregnated papers and release papers, foils, organic or inorganic films, polymer substrates such as PVDC, polymer dielectrics exhibiting spontaneous dipole moments, and substrates with piezoelectric properties.
  • a graphene/graphene oxide- coated support having a coating comprising a layer of graphene/graphene oxide the layer having a basis weight of 2 - 50 g/m 2 , preferably 4 - 35 g/m 2 , more preferably 5 - 20 g/m 2 .
  • the support for the graphene/graphene oxide- coating comprises cellulosic or artificial fiber based substrates, coated and impregnated papers and release papers, foils, organic or inorganic films, polymer substrates such as PVDC, polymer dielectrics exhibiting spontaneous dipole moments, and substrates with piezoelectric properties.
  • the graphene/graphene oxide layer is formed of a coherent 2-dimensional planar structure.
  • the support for graphene/graphene oxide- coated support has a Cobb value, the Cobb value of the non-coated support being less than 20 g/m 2 , preferably less than 10 g/m 2 when using conventional coating processes like film press coating, rod coating, curtain coating and blade coating.
  • Graphene stock suspension acquired from a supplier consists of graphene, graphene oxide and likely a certain quantity of residual graphite.
  • the stock graphene suspension is in itself not suitable for use as a coating and must be further stabilized and reformulated by suitable rheology modifier additives to improve the stability sufficiently so as to make the graphene/graphene oxide suspension suitable for industrial coating operations.
  • the graphene/graphene oxide suspension used for coating is prepared to a desired solids content and rheological properties from a stock suspension by adding necessary other components.
  • the graphene/graphene oxide suspension is produced from the stock suspension and necessary other components under high shear mixing using a polyacrylic polymer as dispersant.
  • the graphene/graphene oxide suspension may be prepared up to 15% solids.
  • the graphene/graphene oxide suspension is applied to the substrate to provide a graphene/graphene oxide coating with a basis weight of about 20 g/m 2 .
  • Graphene (suspended in water) pph (parts per hundred) 100 Sterocoll DF3 (Polyacryl amide based rheology modifier) pph 3 Lumiten I-SC (Sulphosuccinate/isotridecanol ethoxylate based surfactant) pph 0,5 Rheocoat 35 (Acrylic thickener) pph 3,5 Solids content % 10,8 Viscosity (Brookfield 100 rpm) mPs 1250 pH 9,3 Temperature °C 21
  • a polyacrylate latex (Acronal 360D) is applied as the graphene bonding liquid, in the amount of about 10-15 g/m 2 in basis weight. Thereafter the paper substrate is coated with the coating formulations and applications discussed in Example 1.
  • the coated paper substrate is dried first by rapid IR-heating followed by air flotation drying at 300°C to final moisture of 3%.
  • Pressure is applied to the dried coated paper substrate using a multi-nip hard calender.

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Claims (17)

  1. Procédé de fabrication d'une couche de graphène et d'oxyde de graphène comprenant les étapes de :
    a) préparation d'une suspension d'un mélange de graphène et d'oxyde de graphène comprenant un mélange de particules de graphène et d'oxyde de graphène en forme de flocons dans une suspension liquide, dans lequel la suspension liquide est de l'eau,
    b) application de la suspension du mélange de graphène et d'oxyde de graphène sur un support,
    c) chauffage de la suspension et du support pour évaporer au moins une partie de la suspension liquide pour former une couche de graphène et d'oxyde de graphène sur le support, et
    d) soumission de la couche de graphène et d'oxyde de graphène et du support à une pression.
  2. Procédé selon la revendication 1, comprenant, avant l'étape b), l'étape b1) d'application d'un liquide de liaison au graphène sur le support, et dans l'étape c) le fait de laisser au moins une partie du liquide de liaison au graphène s'évaporer.
  3. Procédé selon la revendication 1, comprenant, dans l'étape c), la soumission de la couche de graphène et d'oxyde de graphène à une source de chaleur sans contact ou à contact pour réaliser le processus de séchage par évaporation d'au moins une partie de la suspension liquide.
  4. Procédé selon la revendication 1, dans lequel simultanément à l'étape b), l'étape b1) d'application d'un liquide de liaison au graphène sur le support est mise en œuvre, et, dans l'étape c) le fait de laisser au moins une partie du liquide de liaison au graphène s'évaporer, et le liquide de liaison au graphène et la suspension liquide ne font qu'un.
  5. Procédé selon l'une quelconque des revendications précédentes, dans lequel, dans l'étape d), la couche de graphène et d'oxyde de graphène et le support sont soumis à une température de 100 - 300 °C, généralement 200 - 250 °C.
  6. Procédé selon l'une quelconque des revendications précédentes, dans lequel, dans l'étape d), la couche de graphène et d'oxyde de graphène et le support sont soumis à au moins un parmi le super-calandrage, le calandrage à satiner, le calandrage thermosoft, le calandrage dur, le calandrage étendu, le calandrage à bande métallique, et le calandrage à plusieurs zones de pincement.
  7. Procédé selon l'une quelconque des revendications précédentes, dans lequel, après l'étape d), dans l'étape e), la couche de graphène et d'oxyde de graphène est soumise à un recuit pour chauffer la couche de graphène/oxyde de graphène.
  8. Procédé selon la revendication 7, dans lequel, dans l'étape e), la couche de graphène et d'oxyde de graphène est chauffée à une température dans l'intervalle de 1 000 - 3 000 °C, de préférence 1 500 - 3 000 °C, et plus préférentiellement dans l'intervalle de 2 000 -2 500 °C.
  9. Procédé selon l'une quelconque des revendications 7 ou 8, dans lequel, dans l'étape e), le support est refroidi.
  10. Procédé selon l'une quelconque des revendications 7 à 9, dans lequel, dans l'étape b) le mélange de graphène et d'oxyde de graphène est appliqué des deux côtés du support.
  11. Procédé selon la revendication 10, dans lequel une étape est divisée en deux phases, en une première phase un premier côté du support revêtu est refroidi et la couche de graphène et d'oxyde de graphène sur le second côté opposé est soumise au recuit, et en une seconde phase dans laquelle le second côté du support est soumis au refroidissement et le graphène et l'oxyde de graphène sur le premier côté au recuit.
  12. Procédé de fabrication d'un support revêtu de graphène et d'oxyde de graphène selon l'une quelconque des revendications précédentes, dans lequel le support est du papier.
  13. Procédé de fabrication d'un support revêtu de graphène et d'oxyde de graphène selon l'une quelconque des revendications précédentes, dans lequel le support comprend des substrats cellulosiques ou à base de fibres synthétiques.
  14. Support revêtu de graphène et d'oxyde de graphène fabriqué selon l'une quelconque des revendications précédentes 1-13, le support présentant un revêtement comprenant une couche de graphène et d'oxyde de graphène, la couche de graphène et d'oxyde de graphène présentant un grammage de 2 - 50 g/m2, de préférence 4 - 35 g/m2, plus préférentiellement 5 - 20 g/m2.
  15. Support revêtu de graphène et d'oxyde de graphène fabriqué selon la revendication 14, dans lequel le support pour le revêtement de graphène et d'oxyde de graphène comprend des substrats cellulosiques ou à base de fibres synthétiques, des papiers couchés et imprégnés et des papiers antiadhésifs, des feuilles, des films organiques ou inorganiques, des substrats polymères tels que le PVDC, des diélectriques polymères présentant des mouvements dipolaires spontanés, et des substrats avec des propriétés piézoélectriques.
  16. Support revêtu de graphène et d'oxyde de graphène selon la revendication 14, dans lequel la couche de graphène et d'oxyde de graphène est formée d'une structure plane bidimensionnelle cohérente.
  17. Support revêtu de graphène et d'oxyde de graphène selon la revendication 14, dans lequel le support présente une valeur Cobb, et la valeur Cobb du support est inférieure à 50 g/m2, de préférence inférieure à 30 g/m2, plus préférentiellement inférieure à 10 g/m2 lors de l'utilisation de processus de revêtement classiques comme le couchage de film sur presse, le couchage à barre, le couchage par voile et le couchage à la lame.
EP19706497.5A 2018-02-16 2019-02-15 Procédé de fabrication d'une couche d'oxyde de graphène/graphène et support revêtu d'oxyde de graphène/graphène Active EP3752672B1 (fr)

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CN114922005A (zh) * 2022-06-17 2022-08-19 理光感热技术（无锡）有限公司 一种新型热敏纸及其制备方法
CN115975423B (zh) * 2023-02-08 2024-02-27 大连交通大学 还原氧化石墨烯/铝防腐蚀材料及其制备方法和应用

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SE1850174A1 (en) 2019-08-17
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EP3752672A1 (fr) 2020-12-23
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US12122677B2 (en) 2024-10-22

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