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EP3613839A1 - Reinigungsmittelzusammensetzung, einheitsdosis und system für harte boden- und oberflurflächen - Google Patents

Reinigungsmittelzusammensetzung, einheitsdosis und system für harte boden- und oberflurflächen Download PDF

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Publication number
EP3613839A1
EP3613839A1 EP18190712.2A EP18190712A EP3613839A1 EP 3613839 A1 EP3613839 A1 EP 3613839A1 EP 18190712 A EP18190712 A EP 18190712A EP 3613839 A1 EP3613839 A1 EP 3613839A1
Authority
EP
European Patent Office
Prior art keywords
cleaning agent
composition
cleaning
unit dose
agent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP18190712.2A
Other languages
English (en)
French (fr)
Inventor
Józef Zietek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lakma Strefa Spz O O
Original Assignee
Lakma Strefa Spz O O
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lakma Strefa Spz O O filed Critical Lakma Strefa Spz O O
Priority to EP18190712.2A priority Critical patent/EP3613839A1/de
Publication of EP3613839A1 publication Critical patent/EP3613839A1/de
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the invention relates to a cleaning agent composition, a cleaning agent unit dose and a cleaning agent system for cleaning hard floor and above-floor surfaces.
  • a washing machine for washing textiles is loaded e.g. with one of the above mentioned water soluble packets containing concentrates of laundry detergents and so forth.
  • the washing machine is connected to a fresh water supply, through which a predetermined amount of water is introduced.
  • the water dissolves the soluble foil package, thereby setting free the laundry detergent filling.
  • Water and filling mix with each other and form a washing liquid, which cleans the fabric, and which is pumped away after use. For every use a new detergent package and a new volume of water is required. In principle the same applies to detergent packages for use in automatic dishwashers.
  • the cleaning agents have to be compatible with the water soluble package foil. All chosen agents in their chosen mixture must not dissolve the package during storage and handling. Although a certain water contents is always present in the detergent mixture, the foil of the package must remain tight when stored in the supermarket shelf or in the household cabinet, even under moist atmospheric conditions. Once dissolved in the cleaning water, the dissolved foil material must not spoil the cleaning properties of the cleaning agents.
  • a cleaning agent composition for cleaning hard floor and above-floor surfaces is proposed, wherein the cleaning agent composition comprises one of the following three composition groups:
  • composition groups have in common, that they contain polyvinyl alcohol (PVA or PVOH) as part of the composition not as a potentially disturbing packaging ballast or remainder, but as an agent contributing to the cleaning process and complementing the other ingredients in their overall cleaning effect. All three composition groups were found to provide superior cleaning results in their respective above mentioned preferred environment.
  • PVA or PVOH polyvinyl alcohol
  • compositions are interchangeably called "super concentrate".
  • inventive super concentrates allow for a significant reduction of mass and volume to be transported and to be stored. Furthermore, the otherwise related amount of plastic packagings or containers is reduced to a minimum or even entirely eliminated.
  • the invention provides a cleaning agent unit dose for cleaning hard floor and above-floor surfaces, wherein the cleaning agent unit dose comprises said inventive cleaning agent composition, and wherein a pouch is formed by the polyvinyl alcohol portion of said cleaning agent composition, and wherein a filling of the pouch consists of the remainder of said cleaning agent composition.
  • Such pouches are easily transported and stored, and they are easily used by just dropping one of them into a predetermined amount of water. Once in contact with water, the pouch dissolves. It does not only set free its content, but becomes part of the entire mixture as a cleaning agent, thereby enhancing washing and cleaning.
  • the invention provides a cleaning agent system for cleaning hard floor and above-floor surfaces, wherein the cleaning agent system comprises the aforementioned cleaning agent unit dose, and wherein the cleaning agent system further comprises a pump spray bottle.
  • a regular, manually operated pump spray bottle of preferably 500 ml to 750 ml volume may be easily filled with tap water, followed by the insertion of one of the aforementioned unit doses.
  • the unit dose dissolves and mixes with the water to a readily usable cleaning liquid.
  • Such liquid is not limited to one single application. It rather may be used over a number of days at different locations, until the content of the pump spray bottle is depleted.
  • the pump spray bottle with not yet fully used contents may be set aside for quite a long time, since the inventive agent-water-mixture is stable and of superior quality even after long storage.
  • the invention is best suitable for cleaning hard surfaces in the kitchen, bathroom, glass surfaces, plastic surfaces, varnished surfaces, ceramic surfaces and metal surfaces, depending on the formula variant.
  • the inventive super concentrate dissolves in water after being shaken a few times, and there is no need to mix it additionally. It is advantageous if the mixture for cleaning hard floor and above-floor surfaces contains a highly concentrated surfactant in an anhydrous form with high washing and foaming properties. It further may be advantageous if the mixture for cleaning hard floor and above-floor surfaces contains a non-ionic surfactant from the group of ethoxylated fatty alcohols with high surface activity and a high moistening capability. Even further it may be advantageous if the mixture for cleaning hard floor and above-floor surfaces contains low-molecular organic acid ensuring an appropriate pH of the cleaning mixture and is characterized by high activity for dissolving scale and soap residues.
  • the cleaning agent composition further comprises 0,03 - 0,15 % w/w of colorant.
  • the colorant may be used to easily distinguish the above mentioned different compositions in order to make sure, that the right composition is applied to the desired cleaning environment.
  • the cleaning agent composition may further comprise 0,3 - 1,5 % w/w of fragrances, in particular a mixture of natural and synthetic oils. This does not only make the application more appealing, but may also help to indicate correct and sufficient distribution of the composition onto the to be cleaned surface.
  • the cleaning agent unit dose preferably has a mass in the range from 5 g to 30 g, and in particular in the range from 10 g to 20 g. This fits well to the above mentioned water volume of 500 ml to 750 ml, leading to readily and easily usable solution and mixture concentration.
  • the filled pouch has a single chamber containing said remainder of said cleaning agent composition, wherein the single chamber is formed in a generally elongate shape having a width and a length, and wherein a ratio of the length to the width is > 2 and preferably > 3.
  • the single chamber is formed in a generally elongate shape having a width, and wherein the width is ⁇ 24 mm and > 16 mm, and preferably ⁇ 20 mm and > 18 mm.
  • such pouch provides sufficient volume for a single unit dose.
  • the resultant pouch geometry allows the insertion through the bottleneck of the pump spray bottle without prematurely rupturing the pouch foil.
  • the pouch is made from a polyvinyl alcohol base foil and a polyvinyl alcohol top foil, wherein a recess to form a single chamber is deep drawn into the base foil, and the top foil is sealed onto the base foil along a single circumferential seal strip, and wherein the seal strip is extending around the recess in a circumferentially closed loop.
  • Fig. 1 shows in a schematic side view an exemplary and preferred embodiment of an inventive cleaning agent system for cleaning hard floor and above-floor surfaces, namely for washing and cleaning hard surfaces in the kitchen, bathroom, glass surfaces, plastic surfaces, varnished surfaces, ceramic surfaces and metal surfaces and so forth, depending on the below explained formula variant.
  • the cleaning agent system comprises at least one cleaning agent unit dose 1 and a manually operated pump spray bottle 9. Details of the cleaning agent unit dose 1 are described further down in the context of Figs. 2 to 4 .
  • the pump spray bottle 9 comprises a bottle body 10 with an upper threaded bottle neck 11, and further comprises a spray head 12.
  • the pump spray bottle 9, namely its bottle body 10 has an internal volume of 750 ml. It may, however, have a reduced volume of down to 500 ml. Smaller or larger volumes may be possible within the scope of the invention, as long as the filled pump spray bottle can be manually carried and operated, preferably by a single hand.
  • the bottle body 10 is filled through the bottle neck 11 with tap water.
  • one single cleaning agent unit dose is filled through the bottle neck 11 into the bottle body 10, where it dissolves and mixes with the water, thereby generating a ready-to-use cleaning liquid.
  • the preparation process is completed by screwing the spray head 12 back again onto the bottle neck 11 to achieve the operational configuration as shown in Fig. 1 .
  • the spray head 12 comprises a not shown internal pump mechanism as known in the art, which is actuated by a pumping lever 13.
  • a liquid content stored in the bottle body 10 namely the afore mentioned ready-to-use cleaning liquid is pumped to exit the spray head 12 through a spray nozzle 14.
  • the pump spray bottle 9 thereby serves as a storage container. Once empty, the pump spray bottle 9 may be refilled with tap water and a corresponding cleaning agent unit dose 1, as often as desired.
  • Fig. 2 shows a front view of the inventive cleaning agent unit dose 1 according to Fig. 1 .
  • the cleaning agent unit dose 1 comprises a foil pouch 2, in which a single chamber 4 is formed.
  • the single chamber 4 contains and is nearly entirely filled with a liquid filling 3.
  • the pouch 2 is made of water soluble polyvinyl alcohol (PVA or PVOH) foil, in particular of a base foil 6 and a top foil 7.
  • Base foil 6 and top foil 7 may be made of one single foil strip, from which a top foil 7 portion is folded on top of a base foil 6 portion.
  • base foil 6 and top foil 7 are made from two separate PVA or PVOH foil strips. Both base foil 6 and top foil 7 form the foil pouch 2 tightly delimiting the single chamber 4. A recess 5 is deep drawn into the base foil 6, while the top foil 7 remains generally flat. The initially open recess 5 is filled with the filling 6. In a subsequent step the flat top foil 7 is sealed on top of the base foil 6 along a sealing strip 8 which surrounds the recess 5. Thereby a continuous pouch chain is formed, from which the ready-to-use individual cleaning agent unit doses 1 are cut off and separated. Without the support of the not shown manufacturing devices, the filled pouches 2 tend to adopt a close to circular cross-section as suggested in Fig. 2 . Such cross-section allows for insertion of the cleaning agent unit dose 1 through the bottle neck 11 of the bottle body 10 according to Fig. 1 .
  • Fig. 3 shows a schematic top view of the cleaning agent unit dose 1 according to Fig. 2 .
  • the top foil 7 is sealed onto the base foil 6 along a single circumferential seal strip 8, wherein the seal strip 8 is extending around the recess 5 in a circumferentially closed loop.
  • the entire unit dose 1 and in particular its filled chamber 4 has a generally elongate shape. Despite such pronounced elongate shape, it is said single circumferential seal strip 8 contributing to the structural integrity of the cleaning agent unit dose 1 mitigating the risk of leakage and rupture.
  • the filled chamber 4 has a length 1 and a width w.
  • the cross-section of Fig 2 including the width w is approximately constant along the length 1.
  • the width w is ⁇ 21 mm and > 16 mm, and preferably ⁇ 20 mm and > 18 mm.
  • the mean diameter of the above mentioned close to circular cross-section is approximately equal to the width w, and thereby less than the bottle neck's 11 diameter d ( Fig. 1 ).
  • the width w is 19 mm.
  • a ratio of the length 1 to the width w is > 2 and preferably > 3.
  • the length 1 is 84 mm, leading to a length-to-width-ratio of approximately 4.4.
  • the cleaning agent unit dose 1 has a mass in the range from 5 g to 30 g, and in particular in the range from 10 g to 20 g. In the shown preferred embodiment, the mass of the unit dose 1 is approximately 15 g. The actual mass is dependent on the specific type of filling 3 composition. With reference to the below described different cleaning agent compositions, the average mass of one single cleaning agent unit dose 1 is 13,5 g for kitchen cleaner and for window cleaner, and is 15 g for bathroom cleaner, when using the geometric dimensions of Fig. 3 .
  • Fig. 4 shows a variant of the cleaning agent unit dose according to Fig. 3 with reduced length 1 but same chamber width w.
  • width w is again 19 mm while the length 1 is reduced to 66 mm, leading to unit dose 1 mass of approximately 12 g.
  • the resultant length-to-width-ratio is approximately 3.5. From comparing both embodiments of Figs. 3, 4 it is apparent, that the unit dose 1 mass is adjusted by varying its chamber length 1, while its cross-section shape and width w are kept constant.
  • the embodiment of Fig. 3 is adjusted to the 750 ml water volume of the pump spray bottle 9 of Fig. 1 , while the shorter unit dose 1 of Fig. 3 is adjusted to a not shown pump spray bottle with less volume. This allows for the arbitrary use together with different spray bottles having different volumes but standardized 28/410 bottle neck thread.
  • the PVA foil material of the pouch 2 dissolves in the water contained in the pump spray bottle 9, once a single unit dose 1 is inserted. Thereby the polyvinyl alcohol foil material supplements the filling 3 to a cleaning agent composition, which is mixed with said amount of water.
  • the cleaning agent composition comprises: Ethyl alcohol 30 - 50 % Hydrotrope wetting agent CAS: 64-17-5 Ethylene glycol butyl ether 20 - 50 % Wetting agent CAS: 111-76-2 Ethoxylated and sulphated alcohol C12-C14 of monoisopropanolamine salt 5 - 20 % Surfactant - wetting agent and emulsifier of the dirt and grease CAS: 1187742-72-8 Sodium salt of diethylenetriamine penta(methylene phosphonic acid) 0.3 - 1.0 % Complexing agent (binding of calcium ions) CAS: 22042-96-2 Mixture of natural and synthetic oils 0.3 - 1.5% Fragrance --- Colorant 0,05 - 0,15% Dye C.I Acid Blue 9 Demineralized water 0.3 - 5 % Hydrotope --- Polyvinyl alcohol 2.5 - 3.5%
  • the sodium salt of diethylenetriamine penta(methylene phosphonic acid) leads to a slightly acid result (ph 5 - 7).
  • the first composition is suitable for window cleaning.
  • the cleaning agent composition comprises: Ethyl alcohol 30 - 50 % Hydrotrope wetting agent CAS: 64-17-5 Ethylene glycol butyl ether 20 - 50 % Wetting agent CAS: 111-76-2 Ethoxylated and sulphated alcohol C12-C14 of monoisopropanolamine salt 5 - 2 0 % Surfactant - wetting agent and emulsifier of the dirt and grease CAS: 1187742-72-8 Alkanoloamine 0.3 - 1.0 % Softening agent of water, regulator of pH CAS: 141-43-5 Mixture of natural and synthetic oils 0.3 - 1.5% Fragrance --- Colorant 0,05 - 0,15% Dye C.I Acid Orange 7 Demineralized water 0.3 - 5 % Hydrotope --- Polyvinyl alcohol 2.5 - 3.5%
  • This second composition is identical to the first composition except that the above mentioned sodium salt is replaced by Alkanoloamine. This leads to a slightly alkaline result (ph 7 - 9).
  • the second composition is suitable for kitchen cleaning.
  • first and second embodiment form a first inventive composition group.
  • the cleaning agent composition comprises: 1-butoxypropan-2-ol 30 - 50 % Hydrotrope wetting agent CAS: 5131-66-8 Ethoxylated alcohols C9-C11 15 - 20 % Non-ionic surfactants CAS: 68439-46-3 Lactic acid 20 - 50 % Descaling agent (dissolution of lime deposits) CAS: 79-33-4 Mixture of natural and synthetic oils 0.3 - 1.5 % Fragrance --- Colorant 0.1 - 0,7 % Dye C.I Acid Blue 9 C.I Acid Yellow 23 Polyvinyl alcohol 2.5 - 3.5%
  • the third embodiment resembles a second inventive composition group having a pronounced acid property (ph 1 - 2).
  • the third composition is suitable for bathroom cleaning.
  • the cleaning agent composition comprises: Ethoxylated and sulphated alcohol C12-C14 of monoisopropanolamine salt 30 - 55% Surfactant - wetting agent and emulsifier of the dirt and grease CAS: 1187742-72-8 Ethoxylated alcohols C9-C11 5 - 20 % Non-ionic surfactants CAS:68439-46-3 Ethoxylated alcohols C12-C14 5 - 20 % Non-ionic surfactants CAS 68439-50-9 Sorbitan monolaurate, ethoxylated 5 - 20 % Non-ionic surfactants CAS 9005-64-5 Glycerin 5 - 10 % Hydrotrope CAS 56-81-5 Propylene glycol 1 - 5% H ydrotrope CAS 57-55-6 Isopropyl alcohol 1 - 5 % Hydrotrope CAS 67-63-0 Sodium salt of diethylenetriamine penta ⁇ methylene phosphonic acid)
  • the fourth embodiment resembles a third inventive composition group having a more or less neutral property (ph 6 - 8).
  • the fourth composition is suitable for floor cleaning.
  • compositions and composition groups are the presence of polyvinyl alcohol.
  • the polyvinyl alcohol portion of said cleaning agent compositions are formed by the polyvinyl alcohol portion of said cleaning agent compositions, while the fillings 3 of the pouches 2 consists of the remainder of said cleaning agent composition.
  • the polyvinyl alcohol pouch dissolves and mixes with the filling to the final cleaning agent composition, and further mixes with the water to a readily usable cleaning liquid.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
EP18190712.2A 2018-08-24 2018-08-24 Reinigungsmittelzusammensetzung, einheitsdosis und system für harte boden- und oberflurflächen Withdrawn EP3613839A1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP18190712.2A EP3613839A1 (de) 2018-08-24 2018-08-24 Reinigungsmittelzusammensetzung, einheitsdosis und system für harte boden- und oberflurflächen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP18190712.2A EP3613839A1 (de) 2018-08-24 2018-08-24 Reinigungsmittelzusammensetzung, einheitsdosis und system für harte boden- und oberflurflächen

Publications (1)

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EP3613839A1 true EP3613839A1 (de) 2020-02-26

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EP18190712.2A Withdrawn EP3613839A1 (de) 2018-08-24 2018-08-24 Reinigungsmittelzusammensetzung, einheitsdosis und system für harte boden- und oberflurflächen

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023237412A1 (en) * 2022-06-09 2023-12-14 Unilever Ip Holdings B.V. A concentrated liquid detergent composition
WO2024115106A1 (en) * 2022-11-29 2024-06-06 Unilever Ip Holdings B.V. Composition

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6037319A (en) * 1997-04-01 2000-03-14 Dickler Chemical Laboratories, Inc. Water-soluble packets containing liquid cleaning concentrates
WO2002057398A1 (en) * 2001-01-19 2002-07-25 Reckitt Benckiser N.V. Improvements in or relating to liquid detergent compositions
GB2376238A (en) * 2001-06-07 2002-12-11 Reckitt Benckiser Inc Hard surface cleaner in a container
WO2009125335A2 (en) * 2008-04-07 2009-10-15 Ecolab Inc. Ultra-concentrated liquid degreaser composition
US20120028874A1 (en) * 2010-07-20 2012-02-02 Susana Fernandez Prieto Particles
WO2016005775A1 (en) * 2014-07-11 2016-01-14 Revolymer (U.K.) Limited Encapsulated benefit agent particles
US20160201017A1 (en) 2015-01-08 2016-07-14 Domingo A. Mesa Laundry detergent, fabric softener and cleaning formulations, systems, and water-soluble pouches
US20160340625A1 (en) * 2015-05-22 2016-11-24 The Procter & Gamble Company Surfactant and detergent compositions containing ethoxylated glycerine

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6037319A (en) * 1997-04-01 2000-03-14 Dickler Chemical Laboratories, Inc. Water-soluble packets containing liquid cleaning concentrates
WO2002057398A1 (en) * 2001-01-19 2002-07-25 Reckitt Benckiser N.V. Improvements in or relating to liquid detergent compositions
GB2376238A (en) * 2001-06-07 2002-12-11 Reckitt Benckiser Inc Hard surface cleaner in a container
WO2009125335A2 (en) * 2008-04-07 2009-10-15 Ecolab Inc. Ultra-concentrated liquid degreaser composition
US20120028874A1 (en) * 2010-07-20 2012-02-02 Susana Fernandez Prieto Particles
WO2016005775A1 (en) * 2014-07-11 2016-01-14 Revolymer (U.K.) Limited Encapsulated benefit agent particles
US20160201017A1 (en) 2015-01-08 2016-07-14 Domingo A. Mesa Laundry detergent, fabric softener and cleaning formulations, systems, and water-soluble pouches
US20160340625A1 (en) * 2015-05-22 2016-11-24 The Procter & Gamble Company Surfactant and detergent compositions containing ethoxylated glycerine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023237412A1 (en) * 2022-06-09 2023-12-14 Unilever Ip Holdings B.V. A concentrated liquid detergent composition
WO2024115106A1 (en) * 2022-11-29 2024-06-06 Unilever Ip Holdings B.V. Composition

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