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EP3518879A1 - Produits de soin capillaire à effet de conditionnement amélioré assurant une protection contre la perte de couleur - Google Patents

Produits de soin capillaire à effet de conditionnement amélioré assurant une protection contre la perte de couleur

Info

Publication number
EP3518879A1
EP3518879A1 EP17749137.0A EP17749137A EP3518879A1 EP 3518879 A1 EP3518879 A1 EP 3518879A1 EP 17749137 A EP17749137 A EP 17749137A EP 3518879 A1 EP3518879 A1 EP 3518879A1
Authority
EP
European Patent Office
Prior art keywords
weight
hair treatment
hair
composition according
treatment composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP17749137.0A
Other languages
German (de)
English (en)
Inventor
Volker Scheunemann
Erik Schulze Zur Wiesche
René KROHN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3518879A1 publication Critical patent/EP3518879A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/004—Preparations used to protect coloured hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/592—Mixtures of compounds complementing their respective functions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the invention relates to hair treatment compositions, in particular shampoos and so-called conditioners, with a combination of active ingredients for gentle and effective care of the hair.
  • hair treatment compositions in particular shampoos and so-called conditioners
  • active ingredients for gentle and effective care of the hair.
  • care products affect the natural structure and properties of the hair.
  • the wet and dry combability of the hair, the hold and the fullness of the hair can be optimized or the hair can be protected from increased splits following such care treatments.
  • the hair is treated with special active ingredients, for example quaternary ammonium salts or special polymers, usually in the form of a rinse.
  • special active ingredients for example quaternary ammonium salts or special polymers, usually in the form of a rinse.
  • this treatment improves the combability, the hold and the fullness of the hair and reduces the splitting rate.
  • multifunctional cosmetic products are known in the prior art.
  • these include the so-called “2 in 1" shampoos, which not only cleanse the hair, but also condition it.
  • These products are highly appreciated by the consumer because of their product performance, at least one process step, for example, conditioning with a classical hair conditioner; unnecessary.
  • the term "undesired change” is understood to mean the fading or bleeding and loss of color brilliance of the hue of the hair as a result of the respective dyeing.Environmental influences and / or sun effects may exacerbate these changes.There is still a need for active ingredients or active ingredient combinations for hair treatment products with good nourishing properties, which also strengthen the adhesion of dyes to the hair fibers and thus preserve the authenticity of the artificially produced hair color, and further develop hair treatment products in this regard.
  • the present application was therefore based on the object to provide good skin-friendly and nourishing hair treatment compositions which have excellent foam properties and have a good rinsability with water and also reduce or prevent the washing out of color from dyed hair.
  • the nourishing hair treatment products should have a constant conditioning performance regardless of the water quality and in particular fine hair and / or damaged hair and thereby strengthen the hair in their structure and so protect against splits and breakage and improve combability and grip. In addition, they should have a germ-reducing effect.
  • a first object of the present invention are hair treatment compositions containing by weight
  • Hair treatment compositions for the purposes of the present invention are, for example, hair shampoos, hair conditioners, conditioning shampoos, hairsprays, hair conditioners, hair conditioners, hair wraps, hair tonics, perming solutions, hair dye shampoos, hair dyes, hair fixatives, hair dressings, hairstyling preparations, hair lotions, mousses, hair gels , Hair waxes or their combinations.
  • Preferred agents are therefore shampoos, conditioners or hair tonics.
  • the hair treatment compositions contain as the first essential ingredient 0.001 to 10 wt .-% of at least one amine salt of a carboxylic acid.
  • Amine salts of carboxylic acids are formed from a (primary, secondary or tertiary) amine with a carboxylic acid from their -COOH group.
  • the acidic acid of the acid protonates the amine to an ammonium.
  • Suitable amines are, for example, methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, n-propylamine, di-n-propylamine, tri-n-propylamine, isopropylamine, diisopropylamine, triisopropylamine, phenylamine (aniline), diphenylamine, triphenylamine, monoethanolamine, Diethanolamine, triethanolamine, ethylenediamine, propylenediamine, the phenylenediamines 1, 2-diaminobenzene, 1, 3-diaminobenzene and 1, 4-diaminobenzene, piperidine, morpholine,
  • Typical representatives of aliphatic mono- and dicarboxylic acids are, for example, acetic acid, propionic acid, oxalic acid and 1,3-propanedioic acid and aromatic carboxylic acids such as benzoic acid.
  • Further organic acids are, for example, hydroxy carboxylic acids such as glycolic acid, citric acid, tartaric acid, malic acid and lactic acid.
  • unsaturated mono- or dicarboxylic acids such as fumaric acid or ⁇ -ketocarboxylic acids such as pyruvic acid (2-oxopropionic acid) are inventively used as the amine salt.
  • Methyl ammonium formate dimethyl ammonium formate, trimethyl ammonium formate
  • Ethylammoniumpropionat Diethylammoniumpropionat, Triethylammoniumpropionat, n- Propyylammoniumpropionat, di-n-Propylammoniumpropionat, tri-n-Propylammoniumpropionat Isopropylammoniumpropionat, Diisopropylammoniumpropionat, Triisopropylammoniumpropionat Phenylammoniumpropionat, Diphenylammoniumpropionat, Triphenylammoniumpropionat Monoethanolammoniumpropionat, Diethanolammoniumpropionat, Triethanolammoniumpropionat Ethylenammoniumpropionat, Propylenammoniumpropionat, piperidinium
  • Dimethylammoniumbutyrat Trimethylammoniumbutyrat, Ethylammoniumbutyrat Diethylammoniumbutyrat, Triethylammoniumbutyrat, n-Propyylammoniumbutyrat, di-n Propylammoniumbutyrat, tri-n-Propylammoniumbutyrat, Isopropylammoniumbutyrat Diisopropylammoniumbutyrat, Triisopropylammoniumbutyrat, Phenylammoniumbutyrat Diphenylammoniumbutyrat, Triphenylammoniumbutyrat, Monoethanolammoniumbutyrat Diethanolammoniumbutyrat, Triethanolammoniumbutyrat, Ethylenammoniumbutyrat Propylenammoniumbutyrat, Piperidiniumbutyrat, Morpholiniumbutyrat, 4.4 - Dimethyloxazolidiniumbutyrat, Methylammoniumpentanoat,
  • Propylammoniumdodecanoat Isopropylammoniumdodecanoat, Diisopropylammoniumdodecanoat Triisopropylammoniumdodecanoat, Phenylammoniumdodecanoat, Diphenylammoniumdodecanoat Triphenylammoniumdodecanoat, Monoethanolammoniumdodecanoat Diethanolammoniumdodecanoat, Triethanolammoniumdodecanoat, Ethylenammoniumdodecanoat Propylenammoniumdodecanoat, Piperidiniumdodecanoat, Morpholiniumdodecanoat, 4,4 Dimethyloxazolidiniumdodecanoat, Methylammoniumoxalat, Dimethylammoniumoxalat Trimethylammoniumoxalat, Ethylammoniumoxalat, Diethylammoniumoxalat
  • Triphenylammoniumoxalat Monoethanolammoniumoxalat Diethanolammoniumoxalat Triethanolammoniumoxalat, Ethylenammoniumoxalat, Propylenammoniumoxalat Piperidiniumoxalat, Morpholiniumoxalat, 4,4-Dimethyloxazolidiniumoxalat Methylammoniumbenzoat, Dimethylammoniumbenzoat, Trimethylammoniumbenzoat Ethylammoniumbenzoat, Diethylammoniumbenzoat, Triethylammoniumbenzoat, n- Propyylammoniumbenzoat, di-n-Propylammoniumbenzoat, tri-n-Propylammoniumbenzoat Isopropylammoniumbenzoat, Diisopropylammoniumbenzoat, Triisopropylammoniumbenzoat Phenylammoniumbenzoat , Diphenyl
  • Trimethylammonium glycolate Ethylammoniumglykolat, Diethylammoniumglykolat
  • Methyl ammonium citrate dimethyl ammonium citrate, trimethyl ammonium citrate, ethyl ammonium citrate, diethyl ammonium citrate, triethyl ammonium citrate, n-propyl ammonium citrate, di-n-propyl ammonium citrate, tri-n-propyl ammonium citrate, isopropyl ammonium citrate
  • Ethylammonium tartrate diethylammonium tartrate, triethylammonium tartrate, n-
  • Trimethylammonium malate Trimethylammonium malate, ethylammonium malate, diethylammonium malate
  • Triethylammonium malate Triethylammonium malate, n-propylammonium malate, di-n-propylammonium malate, tri-n-propylammonium malate, isopropylammonium malate, diisopropylammonium malate
  • Triphenylammonium malate monoethanolammonium malate, diethanolammonium malate
  • Triethanolammonium malate ethylene ammonium malate, propylene ammonium malate, piperidinium malate, morpholinium malate, 4,4-dimethyloxazolidinium malate, methyl ammonium lactate
  • Particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0 to 1 to 6% by weight. and in particular from 0.15 to 5% by weight of amine salt (s) of carboxylic acid (s) of the formula (I)
  • R 1, R 2 and R 3 are independently selected from -H, -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 OH,
  • R is an optionally substituted saturated or unsaturated, linear, branched or cyclic, aliphatic or aromatic hydrocarbon radical having at least 2 C atoms.
  • Very particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0 to 1 to 6% by weight. % and in particular 0, 15 to 5 wt .-% of at least one amine salt from the group
  • the agents according to the invention contain from 0.001 to 50% by weight of at least one amino-functional silicone.
  • Preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (Si-II)
  • G is -H, a phenyl group, -OH, -O-CH 3 , -CH 3 , -O-CH 2 CH 3 , -CH 2 CH 3 , -O-
  • n and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10,
  • R - R ' is a monovalent radical selected from
  • each Q is a chemical bond, -CH 2 -, -CH 2 -CH 2 -, -CH 2 CH 2 CH 2 -, -C (CH 3 ) 2 -, -CH 2 CH 2 CH 2 CH 2 -, -CH 2 C (CH 3 ) 2 -, -CH (CH 3 ) CH 2 CH 2 -,
  • R " is identical or different radicals from the group -H, -phenyl, -benzyl, -CH 2 - CH (CH 3 ) Ph, the C 20 -alkyl radicals, preferably -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 CH 3 , - CH (CH 3 ) 2 , -CH 2 CH 2 CH 2 H 3 , -CH 2 CH (CH 3 ) 2 , -CH (CH 3 ) CH 2 CH 3 , -C (CH 3 ) 3 , and A represents an anion, which is preferably selected from chloride, bromide, iodide or methosulfate.
  • Particularly preferred agents according to the invention are characterized in that they contain at least one amino-functional silicone of the formula (Si-IIa)
  • n and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.
  • compositions according to the invention which are an amino-functional silicone of the formula (Si-IIb)
  • n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2,000, preferably between 50 and 150 , where the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.
  • agents according to the invention which contain an amino-functional silicone whose amine number is above 0.25 meq / g, preferably above 0.3 meq / g and in particular above 0.4 meq / g, are preferred ,
  • the amine number stands for the milliequivalents of amine per gram of the amino-functional silicone. It can be determined by titration and also expressed in mg KOH / g.
  • Hair-treatment agents preferred according to the invention are characterized in that, based on their weight, they contain from 0.01 to 20% by weight, preferably from 0.05 to 10% by weight, more preferably from 0.1 to 7.5% by weight and in particular from 0.15 to 5% by weight of amino-functional silicone (s).
  • the agents according to the invention contain amino-functional silicone (s) with terminal (r / n) hydroxy group (s).
  • pretreatment agents which contain at least one silicone of the formula (Si-V) have proven particularly effective with regard to the desired effects:
  • A represents a group -OH, -0-Si (CH 3) 3, -0-Si (CH3) 20H, -0-Si (CH 3) 20ch 3, D is a group of -H, -Si (CH 3 ) 3 , -Si (CH 3 ) 2 OH, -Si (CH 3 ) 2 OCH 3 ,
  • n and c are integers between 0 and 1000,
  • Hair treatment compositions according to the invention which - based on their weight - 0.01 to 20 wt.%, Preferably 0.01 to 20 wt .-%, preferably 0, 1 to 10 wt .-%, more preferably 0.5 to 7.5 Wt .-% and in particular 0.1 to 5 wt .-% of at least one silicone of the formula (Si-V) contain:
  • A represents a group -OH, -0-Si (CH 3) 3, -0-Si (CH3) 20H, -0-Si (CH 3) 20ch 3, D is a group of -H, -Si (CH 3 ) 3 , -Si (CH 3 ) 2 OH, -Si (CH 3 ) 2 OCH 3 ,
  • n and c are integers between 0 and 1000,
  • the individual siloxane units having the indices b, c and n are randomly distributed, i. it does not necessarily have to be block copolymers.
  • compositions according to the invention which, based on their weight, 0.001 to 20 wt.%, Preferably 0.01 to 10 wt.%, Particularly preferably 0.05 to 7.5 wt.% And in particular 0.5 to 5 wt.% Of at least one 4-morpholinomethyl-substituted silicone containing structural units of the formulas (Si-Via), (Si-Vlb) and (Si-Vlc)
  • R 1 is -CH 3 , -OH, -OCH 3 , -O-CH 2 CH 3 , -O-CH 2 CH 2 CH 3 , or -O-CH (CH 3 ) 2 ;
  • R 2 is -CH 3 , -OH, or -OCH 3 ,
  • Particularly preferred hair treatment compositions according to the invention contain, based on their weight, from 0.001 to 20% by weight, preferably from 0.01 to 10% by weight, particularly preferably from 0.05 to 7.5% by weight and in particular from 0.5 to 5% by weight. at least one 4-morpholinomethyl-substituted silicone of the formula (Si-Vl)
  • R 1 is -CH 3 , -OH, -OCH 3 , -O-CH 2 CH 3 , -O-CH 2 CH 2 CH 3 , or -O-CH (CH 3 ) 2 ;
  • R2 is -CH 3 , -OH, or -OCH 3 .
  • B is a group -OH, -O-Si (CH 3 ) 3, -O-Si (CH 3 ) 20H, -O-Si (CH 3 ) 2 OCH 3 ,
  • D is a group -H, -Si (CH 3 ) 3 , -Si (CH 3 ) 2 OH, -Si (CH 3 ) 2 OCH 3 ,
  • a, b and c independently represent integers between 0 and 1000, with the proviso that a + b + c> 0
  • the units a, b, c, m and n are distributed randomly or in blocks in the molecule.
  • Structural formula (Si-VI) is intended to illustrate that the siloxane groups n and m do not necessarily have to be bound directly to an end grouping B or D, respectively. Rather, in preferred formulas (Si-VI) a> 0 or b> 0 and in particularly preferred formulas (Si-Vl) a> 0 and c> 0, i. the terminal moiety B or D is preferably attached to a dimethylsiloxy moiety. Also in formula (Si-Vl), the siloxane units a, b, c, m and n are preferably randomly distributed.
  • Silicones particularly preferably used in the context of the present invention are selected from silicones in which
  • the agents of the invention preferably contain the silicone (s) in the form of an emulsion, more preferably in the form of a microemulsion ,
  • Nonionic components which are particularly suitable here are ethoxylates of decanol, undecanol, dodecanol, tridecanol, etc. Ethoxylated tridecanols have proven to be particularly suitable, which are incorporated with particular preference into the compositions according to the invention.
  • compositions which are particularly preferred according to the invention are characterized in that they contain 0.00001 to 5% by weight, preferably 0.0001 to 3.5% by weight, particularly preferably 0.001 to 2% by weight, based on their weight preferably 0.01 to 1 wt .-% and in particular 0.1 to 0.5 wt .-% branched, ethoxylated tridecanol (INCI name: Trideceth-5) or o iso-tridecyl-u hydroxypolyglycolether (INCI name: Trideceth -10) or mixtures thereof.
  • compositions of the invention may contain other silicone (s) which are not amino-functional.
  • preferred hair treatment compositions are characterized in that they - based on their weight - 0.01 to 20 wt .-%, preferably 0, 1 to 10 wt .-%, more preferably 0.5 to 7.5 wt .-% and in particular 1 to 5 wt .-% non-amino-functional silicone (s) included.
  • Preferred silicones are described below.
  • x is a number from 0 to 100, preferably from 0 to 50, more preferably from 0 to 20 and in particular 0 to 10.
  • the hair treatment compositions of the invention may contain surfactant (s).
  • surfactant in cleaning compositions (shampoos), in particular anionic surfactants have proven useful, in conditioning compositions, cationic surfactants are often used ingredients; Due to their advantageous properties, amphoteric surfactants are used with particular advantage both in shampoos and in conditioners.
  • the hair treatment compositions of the invention may contain at least one anionic surfactant.
  • Suitable anionic surfactants and emulsifiers for the compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
  • Preferred hair treatment compositions contain - based on their weight - 0.5 to 20 wt .-%, preferably 0.75 to 15 wt .-%, more preferably 1 to 12 wt .-% and in particular 2 to 10 wt .-% of anionic ( s) surfactant (s).
  • Particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.5 to 20% by weight, preferably from 0.75 to 15% by weight, more preferably from 1 to 12% by weight and in particular from 2 to 10% by weight of alkyl (ether) sulfates of the general formula R- (OCH 2 -CH 2) n -OSO 3 X, in which R is a straight-chain or branched, saturated or unsaturated alkyl group having 8 to 24 C atoms, n is the number 0 or 1 to 12, and X represents an alkali, alkaline earth, ammonium or alkanolamine ion included.
  • alkyl (ether) sulfates of the general formula R- (OCH 2 -CH 2) n -OSO 3 X, in which R is a straight-chain or branched, saturated or unsaturated alkyl group having 8 to 24 C atoms, n is the number 0 or 1 to 12, and X represents an
  • the hair treatment compositions of the invention may contain at least one amphoteric surfactant and / or at least one nonionic surfactant.
  • Particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.3 to 20% by weight, preferably from 0.5 to 8% by weight, more preferably from 0.75 to 6% by weight and in particular 1 to 5 wt .-% amphoteric surfactant (s) included.
  • amphoteric surfactants or as zwitterionic surfactants called surfactants, which have both a negative and a positively charged functional group.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammoniumglycinate, for example Kokosalkyldimethylammoniumglycinat, N-acyl aminopropyl-N, N-dimethylammoniumglycinate, for example Kokosacylaminopropyldimethyl- ammoniumglycinat, and 2-alkyl-3-carboxymethyl 3-hydroxyethylimidazolines having in each case 8 to 18 C atoms in the alkyl or acyl group, and also the cocoacylaminoethylhydroxyethylcarboxymethyl-glycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
  • ampholytic surfactants are N-alkylglycines, N-alkylaminopropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidoproylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C12-C18-acylsarcosine.
  • the hair treatment agents may contain nonionic surfactant (s). Hair treatment agents preferred according to the invention contain, based on their weight, 0.3 to 10% by weight, preferably 0.5 to 8% by weight, more preferably 0.75 to 6% by weight and in particular 1 to 5% by weight. % nonionic surfactant (s).
  • the hair treatment agents may contain cationic surfactant (s).
  • Cationic surfactants of the quaternary ammonium compound type, the esterquats and the amidoamines can be used according to the invention.
  • Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides.
  • the long alkyl chains of these surfactants preferably have 10 to 18 carbon atoms, such as.
  • cetyl trimethyl ammonium chloride stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, lauryl dimethyl ammonium chloride, lauryl dimethyl benzyl ammonium chloride and tricetylmethyl ammonium chloride.
  • Further preferred cationic surfactants are the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • Particularly preferred hair treatment compositions according to the invention are characterized in that they contain as cationic care substance - based on their weight - 0.05 to 7.5 wt .-%, preferably 0.1 to 5 wt .-%, particularly preferably 0.2 to 3, 5 wt .-% and in particular 0.25 to 2.5 wt .-% cationic (s) surfactant (s) from the group of quaternary ammonium compounds and / or esterquats and / or amidoamines.
  • cationic care substance - based on their weight - 0.05 to 7.5 wt .-%, preferably 0.1 to 5 wt .-%, particularly preferably 0.2 to 3, 5 wt .-% and in particular 0.25 to 2.5 wt .-% cationic (s) surfactant (s) from the group of quaternary ammonium compounds and / or esterquats and / or amidoamines.
  • Particularly preferred hair treatment compositions according to the invention are characterized in that - based on the weight of the composition - sis -0.05 to 20 wt .-%, preferably 0, 1 to 10 wt .-%, more preferably 0.25 to 8 wt .-% and in particular from 0.5 to 7% by weight of cationic surfactant (s), preferably from 0.05 to 20% by weight, preferably from 0.1 to 10% by weight, more preferably from 0.25 to 8% by weight .-% and in particular 0.5 to 7 wt .-% behenyl trimethyl ammonium chloride.
  • cationic surfactant preferably from 0.05 to 20% by weight, preferably from 0.1 to 10% by weight, more preferably from 0.25 to 8% by weight .-% and in particular 0.5 to 7 wt .-% behenyl trimethyl ammonium chloride.
  • compositions of the invention may contain at least one cationic polymer.
  • Cationic polymers increase the care performance of the hair treatment compositions according to the invention (in particular the effectiveness of the hair breakage compositions according to the invention).
  • preferred hair treatment agents contain, based on the weight of the composition, 0.01 to 3% by weight, preferably 0.05 to 2% by weight, more preferably 0.1 to 1, 5 wt .-% and in particular 0.15 to 0.8 wt .-% cationic (s) polymer (s).
  • Cationic polysaccharide polymers increase the care performance of the hair treatment compositions according to the invention (in particular the effectiveness of the hair breakage compositions according to the invention).
  • Suitable cationic polysaccharide polymers may be selected from cationic cellulose compounds and / or from cationic guar derivatives.
  • Particularly preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt .-% and in particular 0.15 to 0.8 wt .-% at least one polymer from the group of cationic cellulose polymers and / or cationic guar derivatives.
  • s cationic polysaccharide polymer
  • Cationic cellulose compounds in the sense of the invention are those which carry more than one permanent cationic charge in at least one side chain.
  • Cellulose is composed of beta-1, 4-glycosidically linked D-glucopyranose units and forms unbranched, water-insoluble chains.
  • side chain of a cellulose chemical substituents are defined which bind to the cellulose skeleton and do not belong to the native cellulose since they have been subsequently introduced, for example, by chemical synthesis.
  • Such polymers are known to those skilled in the art and commercially available from various companies. Particularly preferred are the cationic cellulose derivatives known under the INCI names Polyquaternium-4, Polyquaternium-10, Polyquaternium-24, Polyquaternium-67 and / or Polyquaternium-72. Very particular preference is given to polyquaternium-10, polyquaternium-24 and / or polyquaternium-67 and particular preference to polyquaternium-10.
  • Preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt .-% and in particular 0, 15 to 0.8 wt .-% of at least one polymer from the group of Polyquaternium-4, Polyquaternium-10, Polyquaternium-24, Polyquaternium-67 and / or Polyquaternium-72.
  • s cationic polysaccharide polymer
  • Particularly preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt .-% and in particular 0.15 to 0.8 wt .-% Polyquaternium-10.
  • Suitable cationic guar derivatives in the context of the invention are cationic hydroxyalkyl guar derivatives, preferably cationic hydroxyethyltrimethylammonium guar and / or cationic hydroxypropyltrimethylammonium guar with average molecular weights between 100,000 and 2,000,000 daltons. Particularly preferred are the cationic guar polymers having a molecular weight (weight average) between 200,000 and 1,600,000 daltons known by the INCI name Guar Hydroxypropyltrimonium Chloride.
  • the cationic charge density of these guar polymers is preferably at least 0.4 meq / g, preferably at least 0.5 meq / g and especially at least 0.6 meq / g.
  • Their nitrogen content is preferably in the range of 1, 1 to 1, 8 wt .-% (based on their total weight).
  • Cationic guar derivatives which are known under the INCI designation Guar Hydroxypropyltrimonium Chloride, are known in the art and available, for example under the trade name Cosmedia Guar ®, N-Hance ® and / or Jaguar ® from different vendors.
  • Particularly preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0, 1 to 1, 5 wt .-% and in particular 0, 15 to 0.8 wt .-% guar hydroxypropyltrimonium chlorides.
  • preferred hair treatment compositions are characterized in that they - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt. % and in particular 0.15 to 0.8% by weight of cationic polymer (s), preferably 0.01 to 3% by weight, preferably 0.05 to 2% by weight, more preferably 0, 1 to 1, 5 wt .-% and in particular 0, 15 to 0.8 wt .-% of at least one polymer from the group of cationic cellulose polymers and / or cationic guar derivatives.
  • alpha-substituted aldehydes can further enhance the action of the compositions of the invention.
  • significant increases in performance are observed.
  • Hair treatment compositions which are preferred according to the invention are therefore characterized in that, based on the weight of the composition, they additionally contain from 0.001 to 20% by weight of at least one alpha-substituted aldehyde.
  • Preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0.1 to 6% by weight and in particular from 0.15 to 5% by weight of alpha-substituted aldehyde (s) of the formula (I)
  • Preferred aldehydes to be used according to the invention are described by the numbers 1 to 176 on pages 34 to 37 of the priority document.
  • Very particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0 to 1 to 6% by weight. % and in particular 0, 15 to 5 wt .-% of at least one alpha-substituted aldehyde from the group
  • succinimidyl esters can further enhance the effect of the agents according to the invention.
  • significant increases in performance are observed.
  • Hair treatment compositions which are preferred according to the invention are therefore characterized in that they contain, based on the weight of the composition, additionally from 0.001 to 10% by weight of at least one succinimidyl ester.
  • Succinimidyl esters are esters of carboxylic acids with (optionally substituted) / V-hydroxysuccinimide (NHS, IUPAC 1-hydroxy-2,5-pyrrolidinedione) and are also referred to as NHS esters.
  • Hair treatment compositions which are preferred according to the invention are characterized in that they additionally contain from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0.1 to 6% by weight, based on the weight of the composition. % and in particular 0.15 to 5% by weight of (one) succinimidyl ester (s) of the formula (III)
  • R1 represents -H or an ionic group.
  • R is an optionally substituted saturated or unsaturated, linear, branched or cyclic, aliphatic or aromatic hydrocarbon radical having at least 5 C atoms.
  • Suitable ionic groups R1 include both anionic groups such as phosphate, phosphonate, phosphinate, sulfate, sulfonate, sulfinate, sulfenate, oxysulfonate, carboxylate groups and cationic groups such as substituted or unsubstituted ammonium groups. Zwitterionic / betainic groups such as carboxybetaine or sulfobetaine groups are also possible.
  • R 1 is -H or -OSO 3 " or -SO 3 " or -SO 2 - or -COO " or -NH 3 + or -N (CH 3 ) H 2 + or -N (CH 3 ) 2 H + or -N (CH 3 ) 3 + or -N + (CH 3 ) 2 (CH 2 ) 2-COO- or -N + (CH 3 ) 2 (CH 2 ) 3 -SO 3 -.
  • succinimidyl esters to be used according to the invention are described in the priority document on pages 40 to 42 with the numbers 1 to 72.
  • Very particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0 to 1 to 6% by weight. % and in particular 0, 15 to 5 wt .-% of at least one Succinimidylesters from the group
  • X is H, a monovalent cation or the nth part of an n-valent cation
  • Complexing agents can increase the effect of the agents according to the invention even further, in particular complexing agents which are derived from polycarboxylic acids have proved useful.
  • Hair treatment compositions which are preferred according to the invention are therefore characterized in that they contain, based on their weight, from 0.001 to 20% by weight of complexing agents from the group consisting of tetrasodium A / A / bis (carboxylatomethyl) -L-glutamate (Tetrasodium glutamate diacetate, GLDA).
  • complexing agents from the group consisting of tetrasodium A / A / bis (carboxylatomethyl) -L-glutamate (Tetrasodium glutamate diacetate, GLDA).
  • Pentasodium Diethylenetriaminepentaacetate DTPA
  • tetrasodiumiminodisuccinate IDS
  • EDTA tetrasodium ethylenediaminetetraacetate
  • EDDS tetrasodium ethylenediamine disuccinic acid
  • HEDTA trisodium hydroxyethylethylenediaminetriacetic acid
  • Extremely preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.001 to 20% by weight, preferably from 0.005 to 15% by weight, preferably from 0.01 to 10% by weight, more preferably from 0.05 to 7.5 wt .-% and in particular 0, 1 to 5 wt .-% complexing agent from the group
  • the agents according to the invention may contain only one of the three complexing agents mentioned. But it is also possible that the means according to the invention two or all three of the above. Complexing agents, the manganese of all the complexing agents contained in the agents from the o.g. Group within the quantitative range 0.01 to 20 wt .-% is.
  • Hair treatment compositions which are preferred according to the invention are characterized in that they contain, based on their weight, from 0.005 to 15% by weight, preferably from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular from 0 , 1 to 5 wt .-% tetrasodium A /, A / -bis (carboxylatomethyl) - L-glutamate (Tetrasodium Glutamate Diacetate, GLDA) included.
  • Hair treatment compositions which are likewise preferred according to the invention are characterized in that they contain, based on their weight, from 0.005 to 15% by weight, preferably from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular 0, 1 to 5 wt .-% pentasodium Diethylenetriaminepentaacetate (DTPA) included.
  • DTPA pentasodium Diethylenetriaminepentaacetate
  • Hair treatment compositions which are likewise preferred according to the invention are characterized in that they contain, based on their weight, from 0.005 to 15% by weight, preferably from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular 0, 1 to 5 wt .-% tetrasodium imino disuccinate (IDS) included.
  • IDDS tetrasodium imino disuccinate
  • DTPA pentasodium diethylenetriaminepentaacetate
  • IDMS tetrasodium imino disuccinate
  • preferred hair treatment compositions contain - based on their weight - 0.01 to 10 wt .-%, more preferably 0.05 to 7.5 wt .-% and in particular 0, 1 to 5 wt .-% Pentasodium Diethylenetriaminepentaacetate (DTPA) and 0.01 to 10 wt%, more preferably 0.05 to 7.5 wt%, and most preferably 0.1 to 5 wt% of tetrasodium imino disuccinate (IDS).
  • DTPA Pentasodium Diethylenetriaminepentaacetate
  • IDS tetrasodium imino disuccinate
  • preferred hair treatment compositions contain - based on their weight -0, 1 to 5 wt .-% tetrasodium A /, A / -bis (carboxylatomethyl) -L-glutamate (Tetrasodium glutamate diacetates, GLDA) and 0, 1 to 5 wt % Pentasodium diethylenetriaminepentaacetate (DTPA) and 0.1 to 5% by weight tetrasodiumiminodisuccinate (IDS).
  • the hair treatment compositions may contain at least one divalent or trivalent metal salt. These lead to an improved washout prevention. To achieve an optimum effect, it is advantageous if the metal salts are present in dissolved form in the compositions according to the invention.
  • the hair cleansing and care compositions according to the invention therefore contain water-soluble divalent or trivalent metal salts.
  • water-soluble is understood to mean that at 20 ° C. at least 1 g of the respective salt can be completely dissolved in 1 l of water.
  • Suitable divalent or trivalent metal salts may be selected from divalent or trivalent organic and / or inorganic salts.
  • Particularly suitable cations within these salts may preferably be selected from alkaline earth metal cations and from copper, zinc, iron (II), iron (III) and / or aluminum cations. Very particularly preferred are alkaline earth metal cations and particularly preferably calcium and magnesium cations.
  • Particularly suitable organic anions within these salts may preferably be selected from formate, acetate, lactate, succinate, citrate, tartrate, malate, maleate, oxalate and / or glycolate ions. Very particular preference is given to acetate, lactate and / or citrate salts with the abovementioned cations.
  • Particularly preferred organic salts are calcium, calcium, calcium, magnesium, magnesium and / or magnesium acetate.
  • Particularly suitable inorganic anions within these salts can be selected from halide, sulfate, phosphate and / or carbonate ions. Very particular preference is given to sulfate and / or halide ions, such as chloride and bromide ions.
  • Particularly preferred inorganic salts are calcium chloride, calcium sulfate, magnesium chloride and / or magnesium sulfate.
  • the proportion by weight of the at least one divalent or trivalent metal salt in the total weight of the hair treatment compositions according to the invention is preferably from 0.01 to 10% by weight, preferably from 0.1 to 7.5% by weight, more preferably from 0.2 to 5% by weight. % and in particular 0.3 to 3 wt .-%.
  • preferred hair treatment compositions contain - based on their weight - 0.01 to 10 wt .-%, preferably 0.1 to 7.5 wt .-%, more preferably 0.2 to 5 wt .-% and in particular 0.3 to 3 wt .-% of at least one divalent or trivalent metal salt from the group of organic or inorganic copper, zinc, iron (II), calcium, magnesium, iron (III) and / or aluminum salts.
  • the water-soluble salts are particularly preferred. Most particularly preferred within this embodiment are calcium lactate, calcium citrate, calcium acetate, magnesium lactate, magnesium citrate, magnesium acetate, calcium halides, calcium hydroxide, magnesium halides and / or magnesium hydroxide.
  • the hair treatment compositions preferably contain the active ingredients described above in a cosmetically acceptable carrier.
  • a cosmetically acceptable carrier for the purposes of the invention, this is preferably understood as meaning an aqueous or aqueous-alcoholic carrier.
  • the cosmetic carrier preferably contains at least 50% by weight, more preferably at least 60% by weight, particularly preferably at least 70% by weight and especially preferably at least 75% by weight of water.
  • the cosmetic carrier may contain 0.01 to 40 wt .-%, preferably 0.05 to 30 wt .-% and in particular 0, 1 to 20 wt .-% of at least one alcohol.
  • Suitable alcohols are, for example, ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1,2-propylene glycol, glycerol, diglycerol, triglycerol, 1-butanol, 2-butanol, 1, 2-butanediol, 1, 3-butanediol, 1-pentanol, 2-pentanol, 1, 2-pentanediol, 1, 5-pentanediol, 1, hexanol, 2-hexanol, 1, 2-hexanediol, 1, 6-hexanediol, polyethylene glycols, sorbitol, sorbitan, benzyl alcohol or mixtures thereof alcohols.
  • the hair treatment compositions according to the invention it is advantageous if they have a slightly acidic pH.
  • compositions according to the invention in a pH range from 4.2 to 5.8 have a particularly good skin tolerance and mildness.
  • the hair treatment compositions of the invention preferably have a pH in the range of from 4.2 to 5.8, more preferably from 4.3 to 5.6, most preferably from 4.4 to 5.5, most preferably from 4.5 to 5.4, and more preferably from 4.7 to 5.3.
  • the hair treatment compositions according to the invention may contain vegetable oils, vegetable butters and / or vegetable waxes. These vegetable oil components give the hair improved combability and manageability and increase hair shine.
  • Suitable vegetable oil components include natural (vegetable) oils and / or butters, which commonly contain triglycerides and mixtures of triglycerides.
  • Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, argan oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, marula oil, meadowfoam oil, thistle oil, Macadamia nut oil, grape seed oil, amaranth seed oil, bamboo oil, Olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and / or shea butter.
  • Carnauba waxes, beeswaxes and / or candelilla waxes may be used as suitable natural or vegetable waxes.
  • Particularly preferred vegetable oil components are (sweet) almond oil, peach kernel oil, apricot kernel oil, amaranth seed oil, argan oil, olive oil, jojoba oil, cocoa butter and / or shea butter.
  • the proportion by weight of the at least one vegetable oil, the vegetable butter and / or the vegetable wax in the total weight of the hair treatment compositions according to the invention is preferably 0.02 to 2.50 wt .-%, more preferably from 0.03 to 2.00 wt .-% , Particularly preferably 0.04 to 1, 50 wt .-% and in particular 0.05 to 1, 00 wt .-%.
  • the hair treatment compositions according to the invention may contain at least one further hair-conditioning active agent, which may be selected from the group of US Pat
  • vitamins, provitamins and vitamin precursors from groups A, B, E and H Particular preference is given to nicotinamide, biotin, pantolactone and / or panthenol.
  • the proportion by weight of the vitamin (s), vitamin derivative (s), and / or the vitamin precursor (s) in the total weight of the hair treatment agent is preferably from 0.001 to 2% by weight, particularly preferably from 0.005 to 1% by weight and in particular 0, 01 to 0.5 wt .-%.
  • hair treatment compositions according to the invention are also suitable for use as antidandruff preparation.
  • the total weight of anti-dandruff agents in the total weight of the hair treatment agent may preferably 0.01 to 10 wt .-%, more preferably 0.025 to 7.5 wt .-%, particularly preferably 0.05 to 5 wt .-% and in particular 0.075 to 3 wt. -%.
  • Suitable antidandruff active ingredients may be selected from piroctone olamine, climbazole, zinc pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparations, undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts, walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts and / or arnica extracts.
  • the agents according to the invention can be formulated as so-called rinse-off products, ie they are rinsed out of the hair again after a certain exposure time.
  • This exposure time is preferably less than one hour, ie the consumer preferably does not leave the products until the next hair wash in the hair.
  • Another object of the present invention is therefore a method for hair treatment in which an agent according to the invention is applied to dry or damp hair, left there for a period of 10 to 300 seconds and then rinsed out.
  • the agents of the invention may also be formulated as so-called leave-on products, i. are not rinsed out of the hair, but left there until the next hair wash.
  • Another object of the present invention is therefore a method for hair treatment, in which an agent according to the invention is applied to dry or damp hair and left there until the next hair wash.
  • the agents according to the invention lead to a significantly increased strengthening of the inner and outer hair structure.
  • Another object of the present invention is therefore the use of agents according to the invention for strengthening the hair structure, in particular the inner hair structure.
  • Structural strengthening in the sense of the invention is to be understood as meaning a reduction in the damage of keratinic fibers which has arisen due to the most diverse influences.
  • the restoration of natural strength plays an essential role.
  • Restructured fibers are characterized for example by an improved gloss, improved grip and easier combing.
  • they have an optimized strength and elasticity.
  • a successful structure strengthening or restructuring can be physically detected as a melting point increase in comparison to the damaged fiber.
  • compositions of the invention also lead to a significantly increased stability of artificial dyeings against the washing out of paint.
  • chemically dyed hairs can be washed significantly more frequently with the compositions according to the invention, without the undesired bleeding or color fading occurring.
  • Another object of the present invention is therefore the use of agents according to the invention for reducing the washout of color from chemically colored hair.
  • Hair conditioner 13 14 15 16 17 18

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Abstract

L'invention concerne des produits de soin capillaire contenant, par rapport à leur poids, de 0,001 à 10 % en poids d'au moins un sel aminique d'un acide carboxylique et de 0,001 à 50 % en poids d'au moins une silicone aminofonctionnelle, ces produits permettant de renforcer de manière accrue la structure interne des fibres kératiniques, d'améliorer les effets de soin et de réduire ou d'empêcher la perte de couleur des cheveux colorés.
EP17749137.0A 2016-09-30 2017-07-20 Produits de soin capillaire à effet de conditionnement amélioré assurant une protection contre la perte de couleur Withdrawn EP3518879A1 (fr)

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DE102016219000.8A DE102016219000A1 (de) 2016-09-30 2016-09-30 verbessert konditionierende Haarbehandlungsmittel mit Auswaschschutz
PCT/EP2017/068353 WO2018059780A1 (fr) 2016-09-30 2017-07-20 Produits de soin capillaire à effet de conditionnement amélioré assurant une protection contre la perte de couleur

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AU2017334287B2 (en) * 2016-09-30 2023-06-08 Innospec Limited Cosmetic compositions for combatting colour loss from a dyed material
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US20050113268A1 (en) * 2003-11-26 2005-05-26 Landa Peter A. Increased moisturization efficacy using hydroxyalkylurea
CA2587659A1 (fr) * 2004-12-02 2006-06-08 The Procter & Gamble Company Compositions de teintures capillaires
US9109068B2 (en) * 2005-07-21 2015-08-18 Akzo Nobel N.V. Hybrid copolymer compositions
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