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EP3372305A1 - Low pressure mixing system and method for liquid and pasty mixed components with gaseous and solid mixed components, in continuous operation and individual mixed portions in any outlet position - Google Patents

Low pressure mixing system and method for liquid and pasty mixed components with gaseous and solid mixed components, in continuous operation and individual mixed portions in any outlet position Download PDF

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Publication number
EP3372305A1
EP3372305A1 EP17000336.2A EP17000336A EP3372305A1 EP 3372305 A1 EP3372305 A1 EP 3372305A1 EP 17000336 A EP17000336 A EP 17000336A EP 3372305 A1 EP3372305 A1 EP 3372305A1
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EP
European Patent Office
Prior art keywords
mixing
rotor
mixing chamber
pressure
components
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EP17000336.2A
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German (de)
French (fr)
Inventor
Rudolf Schuster
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BINDER, MANFRED
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/117Stirrers provided with conical-shaped elements, e.g. funnel-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/60Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
    • B01F27/61Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis about an inclined axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/95Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with stirrers having planetary motion, i.e. rotating about their own axis and about a sun axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/75Discharge mechanisms
    • B01F35/754Discharge mechanisms characterised by the means for discharging the components from the mixer
    • B01F35/7543Discharge mechanisms characterised by the means for discharging the components from the mixer using pneumatic pressure, overpressure or gas pressure in a closed receptacle or circuit system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/30Driving arrangements; Transmissions; Couplings; Brakes
    • B01F2035/35Use of other general mechanical engineering elements in mixing devices
    • B01F2035/351Sealings
    • B01F2035/3512Fluid sealings, e.g. using liquids or air under pressure which is leaking into the mixing receptacle

Definitions

  • mixing components are injected at high pressure into a mixing chamber whose jets penetrate one another and thus form a mixture. Impurities in the mixing components lead to blockage of the mixing nozzles and thus to an undefined mixing ratio.
  • the mixing components are mixed together in a mixing chamber by a rotor.
  • the rotor carries out a circulation movement in addition to its own rotation.
  • the cured foams are used for insulation, it is possible to save about 50% of the mixing components with the same insulation values in the case of low-pressure systems due to their lower foam weight and significantly better ⁇ values.
  • the useful volume to be insulated is increased or the outer dimensions of the insulation are reduced. Also impurities in the mixing components lead to no disturbance.
  • Low pressure mixing head EP2271421 is designed for vertical material cutting and designed for continuous operation. Due to the eccentric bearing and the conical shape of the rotor, the ratio of the relative velocities along the contact line of rotor and eccentric movement changes.
  • the aim of the invention is in addition to the production of high-quality foams and mixtures with liquid and pasty mixing components with solid and gaseous components, regardless of position, in continuous operation and for mixing individual portions.
  • a displacement medium e.g., air
  • interrupted mixing components supply and ongoing rotor and tumble motion
  • the storage can be kept free of the mixing components by an overpressure at a vertical outlet upwards.
  • n R d M / d R ⁇ n T so that the contact line is kept free of solid mixing components.
  • the mixing takes place by a vortex formation, which changes its position by the tumbling motion and results in a homogeneous mixture due to the adhesion to the mixing chamber and rotor surface.
  • the exit jet should have a round shape as possible. This can be achieved for example by a spherical shape in which the end of the mixing chamber and rotor is the same. ( Fig. 2 )
  • the rotor's speed and mixing chamber's diameter mean that the rotor's speed should be significantly higher.
  • the wobble point may also be behind the drive opening in front of the outlet opening.
  • the wobble point in the drive area or behind it creates a slim design with which can be immersed through small openings in a cavity and the foaming begins at the rearmost position and is moved by a displacement of the position of the mixer (eg for foaming body parts).
  • the displaced air can escape through the opening and air bubbles in the foam can be prevented.
  • FIG. 1 and Fig. 2 shows the different shape in the Austrittsqer bain conical and spherical rotor with the effect on the outlet jet cross section.
  • Fig. 3 shows mixing component connections for the different mix variants and possible execution of the shutdown mode.
  • Inlet D for higher viscosity mixed components optionally with admixture of solid and / or gaseous mixed components.
  • Inlet F for low-viscosity mixed components with gaseous mixed components is provided.
  • Fig. 4 shows with connection F a possibility to keep the drive area free of mixing components.
  • Port P1a shows a possibility with a gaseous displacement medium and a pressure accumulator volume V in port G to empty the contents of the mixing chamber at the end of a mixture.
  • Port P2b one way with a liquid displacer and a pressure accumulator volume V in port G to empty the contents of the mixing chamber at the end of a mixture.
  • Fig. 5 shows an embodiment of a mixer with a feed region, a mixing region and an outlet region with a plurality of outlet openings in which the material in the outlet region V2 consists of non-stick material.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

Niederdruckmischer auch für aushärtbare Gemische aus flüssig, pastösen mit gasförmigen und festen Komponenten, bei der sich eine schrägstehende Rotorachse mit Mischkammermittellinie und Mantellinien eines konischen Rotors in einem Taumelpunkte (T) schneiden. Dabei führt der Rotor neben seiner eigenen Umdrehung eine Taumelbewegung aus. Bei gleicher Relativgeschwindigkeit von Rotor- und Taumelbewegung zur Mischkammerwand können feste Komponenten mit vermischt werden. Verunreinigungen in den Mischkomponenten beinträchtigen nicht die Funktion des Mischvorganges. Das Mischverfahren ermöglicht durch den Entleervorgang eine beliebige Auslassrichtung des Gemisches.Low-pressure mixer also for hardenable mixtures of liquid, pasty with gaseous and solid components, in which a slanted rotor axis with mixing chamber centerline and generatrices of a conical rotor intersect in a Taumelpunkte (T). The rotor performs a tumbling motion in addition to its own rotation. At the same relative speed of rotor and tumbling motion to the mixing chamber wall solid components can be mixed with. Impurities in the mixing components do not affect the function of the mixing process. The mixing process allows any discharge direction of the mixture by the emptying process.

Description

Bei der Herstellung von Schäumen nach dem Hochdruckmischsystem werden mit hohem Druck Mischkomponenten in eine Mischkammer gespritzt deren Strahlen sich gegenseitig durchdringen und somit eine Mischung entsteht. Verunreinigungen in den Mischkomponenten führen zur Verstopfung der Mischdüsen und somit zu einem undefinierten Mischungsverhältnis.In the production of foams after the high-pressure mixing system, mixing components are injected at high pressure into a mixing chamber whose jets penetrate one another and thus form a mixture. Impurities in the mixing components lead to blockage of the mixing nozzles and thus to an undefined mixing ratio.

Bei aushärtbaren Gemischen werden Ablagerungen an der Mischkammerwand aufgebaut die bei einer Mischungsunterbrechung durch einen Kolbenhub von der Mischkammerwand entfernt wird.For curable mixtures deposits are built up on the mixing chamber wall which is removed at a mixing interruption by a piston stroke of the mixing chamber wall.

Bei einem Niederdruckmischsystem werden durch einen Rotor die Mischkomponenten in einer Mischkammer miteinander vermischt. Der Rotor führt neben seiner Eigendrehung eine Umlaufbewegung aus.In a low pressure mixing system, the mixing components are mixed together in a mixing chamber by a rotor. The rotor carries out a circulation movement in addition to its own rotation.

Werden die ausgehärteten Schäume zur Isolation genutzt kann bei den Niederdrucksystemen durch ein kleineres Schaumgewicht und deutlich bessere λ-Werte etwa 50% der Mischkomponenten bei gleichen Isolationswerten eingespart werden. Zusätzlich wird das zu isolierende Nutzvolumen vergrößert oder die Außenabmessungen der Isolierung verkleinert. Auch Verunreinigungen in den Mischkomponenten führen zu keiner Störung.If the cured foams are used for insulation, it is possible to save about 50% of the mixing components with the same insulation values in the case of low-pressure systems due to their lower foam weight and significantly better λ values. In addition, the useful volume to be insulated is increased or the outer dimensions of the insulation are reduced. Also impurities in the mixing components lead to no disturbance.

Durch den geringen Energieeintrag beim Niederdruckmischen eignet sich dies auch zum Beimischen von Pentan. Dies führt nochmals zu einer Verbesserung der λ-Werte.Due to the low energy input during low-pressure mixing, this is also suitable for adding pentane. This again leads to an improvement of the λ values.

Niederdruck Mischkopf EP2271421 ist für den vertikalen Materialauschnitt konzipiert und für den Dauerbetrieb ausgelegt. Durch die exzentrische Lagerung und der konischen Form des Rotors verändert sich das Verhältnis der Relativgeschwindigkeiten entlang der Berührlinie von Rotor- und Exzenterbewegung.Low pressure mixing head EP2271421 is designed for vertical material cutting and designed for continuous operation. Due to the eccentric bearing and the conical shape of the rotor, the ratio of the relative velocities along the contact line of rotor and eccentric movement changes.

Ziel der Erfindung ist neben der Produktion von hochwertigen Schäumen auch Gemische mit flüssigen und pastösen Mischkomponenten mit festen und gasförmigen Komponenten, lageunabhängig, im Dauerbetrieb und zur Mischung von einzelnen Portionen.The aim of the invention is in addition to the production of high-quality foams and mixtures with liquid and pasty mixing components with solid and gaseous components, regardless of position, in continuous operation and for mixing individual portions.

Diese Aufgabe wird durch einen Niederdruckmischer nach Anspruch 1 bis 4 und Mischverfahren nach Anspruch 5 bis 8 erfüllt.This object is achieved by a low-pressure mixer according to claim 1 to 4 and mixing method according to claim 5 to 8.

Die Lageunabhängigkeit wird erreicht durch die Nutzung eines Verdrängermediums (z.B. Luft), bei unterbrochenen Mischkomponenten Zufuhr und laufender Rotor- und TaumelbewegungThe positional independence is achieved by the use of a displacement medium (e.g., air), with interrupted mixing components supply and ongoing rotor and tumble motion

Im Lagerbereich kann auch durch einen Überdruck bei einem vertikalen Austritt nach oben die Lagerung frei von den Mischkomponenten gehalten werden.In the storage area, the storage can be kept free of the mixing components by an overpressure at a vertical outlet upwards.

Bei der Mischung mit festen Mischkomponenten soll die Relativgeschwindigkeit entlang der Berührlinie aus der Drehbewegung des Rotors und der Taubelbewegung gleich sein. Dadurch wird durch die Keilform ein Druck aufgebaut.When mixing with solid mixing components, the relative velocity along the line of contact from the rotational movement of the rotor and the pigeon movement should be the same. As a result, a pressure is built up by the wedge shape.

Das Verhältnis von Rotordrehzahl nR zur Drehzahl der Taumelbewegung nT sollte n R = d M / d R × n T

Figure imgb0001
sein damit die Berührlinie frei von festen Mischkomponenten gehalten wird.The ratio of rotor speed n R to the speed of the tumble motion n T should n R = d M / d R × n T
Figure imgb0001
so that the contact line is kept free of solid mixing components.

Dies wird durch eine konische Form von Rotor- und Mischkammer erreicht, bei dem sich die Mittellinien von Rotorachse und Mischkammer und den Mantellinien des Rotors in einem Punkt schneidet, dem Taumelpunkt.

(Fig.1) mit A
als Mischbereich
B
als Taumelpunkt
C
als Lagerbereich
B / A
Figure imgb0002
This is achieved by a conical shape of rotor and mixing chamber in which the center lines of rotor axis and mixing chamber and the generatrices of the rotor intersects in a point, the wobble point.
(Fig.1) with A
as a mixing area
B
as a stumbling block
C
as storage area
B / A
Figure imgb0002

Die Vermischung erfolgt durch eine Wirbelbildung, die durch die Taumelbewegung ihre Lage verändert und durch die Haftung an Mischkammer- und Rotoroberfläche eine homogene Mischung ergibt.The mixing takes place by a vortex formation, which changes its position by the tumbling motion and results in a homogeneous mixture due to the adhesion to the mixing chamber and rotor surface.

Auch andere Rotorformen sind möglich aber mit deutlich höheren Rotordrehzahlen und höherem Energieeitrag.Other types of rotor are possible but with significantly higher rotor speeds and higher energy contribution.

Soll die Mischung über einen Abstand durch eine kleine Öffnung in einen Hohlraum eingebracht werden, dann soll der Austrittsstrahl eine möglichst runde Form haben. Dies kann z.B. durch eine ballige Form erreicht werden bei dem das Ende von Mischkammer und Rotor gleich ist. (Fig 2)If the mixture is to be introduced through a small opening into a cavity over a distance, then the exit jet should have a round shape as possible. This can be achieved for example by a spherical shape in which the end of the mixing chamber and rotor is the same. ( Fig. 2 )

Durch Tangentenhilfspunkte (h1, h2 usw.) welche entlang der Rotormittellinie kontinuierlich verlaufen kann diese Form gebildet werden die guten Mischergebnisse aufweist. Für feste Mischkomponenten ist diese Form nicht geeignet.By Tangentenhilfspunkte (h1, h2, etc.) which run along the rotor center line continuously this shape can be formed which has good mixing results. For solid mixed components this form is not suitable.

Bei der balligen Form soll durch den grossen Durchmesser-Unterschied von Rotor und Mischkammer die Drehzahl des Rotors deutlich höher sein.In the case of the crowned shape, the rotor's speed and mixing chamber's diameter mean that the rotor's speed should be significantly higher.

Bei der Zumischung von gasförmigen Mischkomponenten kann z.B. bei CO2 ein Entzündbarkeit des Schaumes reduziert werden.When admixing gaseous mixed components, it is possible, for example in the case of CO 2, to reduce the ignitability of the foam.

Der Taumelpunkt kann vor der Auslassöffnung aber auch hinter dem Antriebsbereich liegen.The wobble point may also be behind the drive opening in front of the outlet opening.

Ist der Taumelpunkt vor der Auslassöffnung entsteht eine gedrungene Bauform.If the wobble point in front of the outlet opening creates a squat design.

Liegt der Taumelpunkt im Antriebsbereich oder dahinter entsteht eine schlanke Bauform mit der durch kleine Öffnungen in einen Hohlraum eingetaucht werden kann und der Aufschäumvorgang an der hintersten Position beginnt und durch eine Verlagerung der Position des Mischers bewegt wird (z.B. zum Ausschäumen von Karosserieteilen).If the wobble point in the drive area or behind it creates a slim design with which can be immersed through small openings in a cavity and the foaming begins at the rearmost position and is moved by a displacement of the position of the mixer (eg for foaming body parts).

Dadurch kann die verdrängte Luft durch die Öffnung entweichen und Lufteinschlüsse im Schaum verhindert werden.As a result, the displaced air can escape through the opening and air bubbles in the foam can be prevented.

Ansicht A von Fig. 1 und Fig. 2 zeigt die unterschiedliche Form im Austrittsqerschnitt bei konischen und balligen Rotor mit der Auswirkung auf den Austrittstrahlquerschnitt.View A from Fig. 1 and Fig. 2 shows the different shape in the Austrittsqerschnitt conical and spherical rotor with the effect on the outlet jet cross section.

Fig. 3 zeigt Mischkomponentenanschlüsse bei den verschiedenen Mischvarianten und eine mögliche Ausführung des Abschaltmodus. Fig. 3 shows mixing component connections for the different mix variants and possible execution of the shutdown mode.

Einlass D für höherviskose Mischkomponenten wahlweise mit Beimischung von festen und / oder gasförmigen Mischkomponenten.Inlet D for higher viscosity mixed components optionally with admixture of solid and / or gaseous mixed components.

Einlass F für niederviskose Mischkomponenten mit gasförmigen Mischkomponenten.Inlet F for low-viscosity mixed components with gaseous mixed components.

Fig. 4 zeigt mit Anschluss F eine Möglichkeit den Antriebsbereich frei von Mischkomponenten zu halten. Fig. 4 shows with connection F a possibility to keep the drive area free of mixing components.

Anschluss P1a zeigt eine Möglichkeit mit einem gasförmigen Verdrängermedium und einem Druckspeichervolumen V in Anschluss G den Inhalt der Mischkammer am Ende einer Mischung zu entleeren.Port P1a shows a possibility with a gaseous displacement medium and a pressure accumulator volume V in port G to empty the contents of the mixing chamber at the end of a mixture.

Anschluss P2b eine Möglichkeit mit einem flüssigen Verdrängermedium und einem Druckspeichervolumen V in Anschluss G den Inhalt der Mischkammer am Ende einer Mischung zu entleeren.Port P2b one way with a liquid displacer and a pressure accumulator volume V in port G to empty the contents of the mixing chamber at the end of a mixture.

Fig. 5 zeigt eine Ausführung von einem Mischer mit einem Zuführbereich, einem Mischbereich und einem Austrittsbereich mit mehreren Auslassöffnungen bei dem das Material im Auslassbereich V2 aus Antihaftmaterial besteht. Fig. 5 shows an embodiment of a mixer with a feed region, a mixing region and an outlet region with a plurality of outlet openings in which the material in the outlet region V2 consists of non-stick material.

Claims (10)

Niederdruckmischsystem und Mischverfahren von flüssigen bzw. pastösen mit gasförmigen und festen Mischkomponenten mit einer Mischkammer, mit zumindest zwei Einlassöffnungen und zumindest einer Auslassöffnung in dem ein schräg stehender Rotor die zu mischenden Komponenten durch seine Umdrehungsgeschwindigkeit vermischt und neben seiner eigenen Umdrehung eine Taumelbewegung um einen Taumelpunkt ausführt und die Mischkammer von den zu mischenden Komponenten durchströmt wird dadurch gekennzeichnet, dass der Taumelpunkt sich außerhalb der Mischkammer befindet und der Schnittpunkt bzw. der kleinste Abstand von Mischkammermittellinie und Rotormittellinie ist.Low-pressure mixing system and mixing method of liquid or pasty with gaseous and solid mixing components with a mixing chamber, with at least two inlet openings and at least one outlet opening in which an inclined rotor mixes the components to be mixed by its rotational speed and performs a tumbling motion about a Taumelpunkt next to its own revolution and flows through the mixing chamber of the components to be mixed is characterized in that the tumbling point is outside the mixing chamber and the intersection or the smallest distance from the mixing chamber center line and the rotor center line. Niederdruckmischsystem nach Anspruch 1 dadurch gekennzeichnet, dass das Material von Rotor und Mischkammer zumindest von einer Mischkomponente eine gute Haftung aufweist.Low-pressure mixing system according to claim 1, characterized in that the material of the rotor and mixing chamber has at least one of a mixing component good adhesion. Niederdruckmischsystem nach Anspruch 1 dadurch gekennzeichnet, dass im Mischbetrieb die Rotorform und die Mischkammerform im Mischbereich eine durchgehende Berührlinie aufweist.Low pressure mixing system according to claim 1, characterized in that in the mixing mode, the rotor shape and the mixing chamber shape in the mixing region has a continuous contact line. Niederdruckmischsystem nach Anspruch 1 dadurch gekennzeichnet, dass der Auslass den kleinsten Durchmesser der Mischkammer aufweist.Low-pressure mixing system according to claim 1, characterized in that the outlet has the smallest diameter of the mixing chamber. Mischverfahren nach Anspruch 1 dadurch gekennzeichnet, dass der Lagerbereich einen Überdruck aufweist, dessen Größe abhängig von der Lage der Auslassöffnung und der Strömungsverluste in der Mischkammer ist.Mixing method according to claim 1, characterized in that the storage area has an overpressure whose size is dependent on the position of the outlet opening and the flow losses in the mixing chamber. Mischverfahren nach Anspruch 5 dadurch gekennzeichnet, dass am Ende des Mischvorganges bei unterbrochener Mischkomponentenzufuhr und laufender Taumel- und Rotorbewegung ein Verdrängermedium (z. B. Luft) druck- und geschwindigkeitsabhängig den Mischkammerinhalt entleert.Mixing method according to claim 5, characterized in that at the end of the mixing process with interrupted Mischkomponententufuhr and ongoing wobble and rotor movement a displacement medium (eg., Air) pressure and speed-dependent emptied the mixing chamber contents. Mischverfahren nach Anspruch 5 dadurch gekennzeichnet, dass der Verdrängermediumspeicher auf das Volumen des Mischkammervolumen abgestimmt ist.Mixing method according to claim 5, characterized in that the displacement medium storage is tuned to the volume of the mixing chamber volume. Mischverfahren nach Anspruch 5 dadurch gekennzeichnet, dass die Austrittsrichtung der Mischung durch den Druck im Verdrängermediumspeicher eingestellt werden kann.Mixing method according to claim 5, characterized in that the outlet direction of the mixture can be adjusted by the pressure in the displacement medium storage. Mischverfahren nach Anspruch 5 dadurch gekennzeichnet, dass Abhängig von der Viskosität des Gemisches und der örtlichen Umdrehungsgeschwindigkeit durch den keilförmigen Verlauf beidseitig der Berührlinie ein Druck aufgebaut wird.Mixing method according to claim 5, characterized in that Depending on the viscosity of the mixture and the local rotational speed by the wedge-shaped course on both sides of the contact line, a pressure is built up. Mischverfahren nach Anspruch 9 dadurch gekennzeichnet, dass bei einer verjüngenden Form von Rotor und Mischkammer entlang der Berührlinie zum Auslass hin sich der Druck verkleinert und dadurch eine Strömung im berührliniennahen Material zum Auslass hin unterstützt.Mixing method according to claim 9, characterized in that with a tapered shape of the rotor and the mixing chamber along the contact line to the outlet towards the pressure decreases and thereby supports a flow in the near-touch material to the outlet towards.
EP17000336.2A 2017-03-06 2017-03-06 Low pressure mixing system and method for liquid and pasty mixed components with gaseous and solid mixed components, in continuous operation and individual mixed portions in any outlet position Withdrawn EP3372305A1 (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN111773944A (en) * 2020-07-30 2020-10-16 河南向氏药坊本草医药有限公司 Disinfection gel agitating unit

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US3171721A (en) * 1959-09-21 1965-03-02 Controls Co Of America On-stream mixer
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1634563A (en) * 1925-11-05 1927-07-05 William N Shaw Drug mixer
GB345465A (en) * 1929-03-06 1931-03-26 Chauffe Et Comb Pulverizing apparatus
GB637015A (en) * 1945-09-27 1950-05-10 Macchine Per L Ind Dolciaria C Improvements in mixing and grinding machines for the final mixing of chocolate
GB640356A (en) * 1946-11-29 1950-07-19 Renwick James Sharp Improvements in mixing and grinding machines
US3171721A (en) * 1959-09-21 1965-03-02 Controls Co Of America On-stream mixer
GB1227493A (en) * 1968-06-08 1971-04-07
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111773944A (en) * 2020-07-30 2020-10-16 河南向氏药坊本草医药有限公司 Disinfection gel agitating unit
CN111773944B (en) * 2020-07-30 2022-04-08 杭州朗索医用消毒剂有限公司 Disinfection gel agitating unit

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