EP3170578B1 - Procédé de fabrication d'une pièce moulée en fonte à graphite sphéroïdal - Google Patents
Procédé de fabrication d'une pièce moulée en fonte à graphite sphéroïdal Download PDFInfo
- Publication number
- EP3170578B1 EP3170578B1 EP15194848.6A EP15194848A EP3170578B1 EP 3170578 B1 EP3170578 B1 EP 3170578B1 EP 15194848 A EP15194848 A EP 15194848A EP 3170578 B1 EP3170578 B1 EP 3170578B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cast iron
- spheroidal graphite
- casting
- cast
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/20—Measures not previously mentioned for influencing the grain structure or texture; Selection of compositions therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/08—Features with respect to supply of molten metal, e.g. ingates, circular gates, skim gates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/08—Features with respect to supply of molten metal, e.g. ingates, circular gates, skim gates
- B22C9/086—Filters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
- B22D1/007—Treatment of the fused masses in the supply runners
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
- C21C1/025—Agents used for dephosphorising or desulfurising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
- C21C1/105—Nodularising additive agents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/08—Making cast-iron alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/04—Cast-iron alloys containing spheroidal graphite
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/10—Cast-iron alloys containing aluminium or silicon
Definitions
- the invention relates to a method of manufacturing a casting by means of a modification body.
- the modification body is used to produce cast iron with spheroidal graphite, in particular with a predominantly ferritic structure, containing a carrier material, preferably an iron-silicon alloy.
- Cast iron generally contains between 2 to 4 percent by weight of carbon.
- the carbon is intimately mixed with the iron and the shape that the carbon takes in the solidified cast iron defines the characteristics and properties of the cast iron pieces.
- the carbon takes the form of graphite, the cast iron is rather soft and machinable.
- Graphite can come in different forms. Cast iron with spheroidal graphite has a high strength, whereby the structure types must be taken into account. Cast iron with spheroidal graphite that has a purely ferritic structure and therefore does not contain any cementite is soft and easy to work with. Whereas cast iron with spheroidal graphite and a pearlitic structure has good wear properties due to its high strength. A pearlitic / ferritic structure in turn has a higher strength than a purely ferritic structure.
- the undesirably high pearlite content in the cast part is supported by accelerated cooling.
- the object of the invention is to propose a method for producing spheroidal graphite cast iron which, by reducing the pearlite structure in the cast iron or cast part, ensures lower hardness and higher elongation at break without making the cast iron or cast parts more expensive to manufacture.
- a modification body which contains 7 to 16 percent by weight boron. Furthermore, at least one modification body according to the invention is inserted into the casting system, where it is flowed around by the cast iron or the melt, or at least one modification body according to the invention is added to the melt before casting and dissolved by it. As a result, a casting made of spheroidal graphite cast iron is produced which has a boron content of 0.002-0.008 percent by weight.
- the pearlite-reducing effect of boron is known, but has so far been considered negative in the production of cast iron with spheroidal graphite, since microporosity and carbides can occur if the boron content is too high, which are serious if it exceeds 0.01 percent by weight and, if it is increased further, severe graphite degeneration occurs .
- At least one modification body according to the invention which has a boron content of 7 to 16 percent by weight is provided inserted into the casting system of a casting after casting.
- cast iron or melt flows around the modification body and continuously releases boron, which is absorbed by the cast iron.
- at least one modification body is inserted into the casting system before casting.
- several modification bodies can also be arranged in the casting system; this is to be selected according to the required boron content in the casting.
- a cast part made of spheroidal graphite cast iron has a boron content of 0.002-0.008 percent by weight, which suppresses or reduces the formation of pearlite and the desired hardness and elongation at break properties are achieved.
- At least one of the modification bodies is arranged between the sprue and filter before casting and the cast iron or melt flows around it during casting.
- At least one modification body can also be added directly to the cast iron or the melt prior to casting.
- the number and arrangement of the modification bodies is selected according to the required boron content in the casting or the desired hardness and elongation at break.
- the cast piece according to the invention with spheroidal graphite produced by the method according to the invention preferably has a predominantly ferritic structure.
- the method according to the invention and the use of the modification body according to the invention produce a cast piece made of spheroidal graphite which preferably does not exceed a Brinell hardness of 170 HB.
- a Brinell hardness of 140-170 HB has proven to be advantageous.
- the structure of the cast piece made of spheroidal graphite is preferably predominantly ferritic.
- a melt of spheroidal graphite cast iron has an Mn content of 0.35% by weight due to contaminated steel scrap as input material and is therefore too high for the desired application, since according to the present analysis instructions a maximum Mn content of 0.25% by weight. -% is permissible.
- the excessively high Mn content in the existing melt or cast iron resulted in a Brinell hardness of 190 HB instead of the maximum 170 HB, which is permissible according to the regulations.
- FIG. 1 a schematic representation of a casting system with a modification body according to the invention.
- Fig. 1 shows a schematic view of a casting system 1 wherein the modification body 6 according to the invention is arranged in front of the filter 3, which is a possible arrangement of the modification body 6 shows.
- the melt of cast iron with spheroidal graphite is introduced into the casting system 1 via the sprue 2.
- the melt flows around the modification body 6 and absorbs the desired amount of boron from it.
- the melt then flows through the filter 3 in order to filter out unwanted impurities.
- the melt in the subsequent feeder 4 is used to continuously replenish the melt in the casting 5 during cooling.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Claims (5)
- Procédé pour la préparation d'une pièce coulée (5) composée de fer coulé comportant du graphite sphéroïdal, caractérisé en ce qu'avant la coulée au moins un corps (6) de modification doté d'une structure principalement ferritique contenant un matériau de support composé d'un alliage fer-silicium et 7 à 16 pour cent en poids de bore, est introduit dans le système de coulée (1).
- Procédé pour la préparation d'une pièce coulée (5) composée de fer coulé comportant du graphite sphéroïdal selon la revendication 1, caractérisé en ce qu'au moins un corps (6) de modification est introduit avant la coulée dans le système de coulée (1) entre la masselotte (2) et le filtre (3).
- Procédé pour la préparation d'une pièce coulée (5) composée de fer coulé comportant du graphite sphéroïdal selon la revendication 1, caractérisé en ce qu'au moins un corps (6) de modification est ajouté avant la coulée dans la masse fondue.
- Procédé pour la préparation d'une pièce coulée (5) composée de fer coulé comportant du graphite sphéroïdal selon l'une quelconque des revendications précédentes, caractérisé en ce que le nombre des corps de modification (6) est choisi de telle manière qu'une teneur en bore dans la pièce coulée (5) de 0,002 à 0,008 pour cent en poids soit atteinte, la pièce coulée (5) composée de fer coulé comportant du graphite sphéroïdal présentant de préférence une structure principalement ferritique.
- Procédé pour la préparation d'une pièce coulée (5) composée de fer coulé comportant du graphite sphéroïdal selon l'une quelconque des revendications précédentes, caractérisé en ce que le nombre des corps (6) de modification est choisi de telle manière qu'une dureté Brinell maximale de 17.0 HB soit atteinte, de préférence la dureté Brinell se situant dans la plage comprise entre 140 et 170 HB.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15194848.6A EP3170578B1 (fr) | 2015-11-17 | 2015-11-17 | Procédé de fabrication d'une pièce moulée en fonte à graphite sphéroïdal |
| US15/350,126 US20170136537A1 (en) | 2015-11-17 | 2016-11-14 | Modification body |
| CN201611011585.2A CN106975740A (zh) | 2015-11-17 | 2016-11-17 | 改性本体 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15194848.6A EP3170578B1 (fr) | 2015-11-17 | 2015-11-17 | Procédé de fabrication d'une pièce moulée en fonte à graphite sphéroïdal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3170578A1 EP3170578A1 (fr) | 2017-05-24 |
| EP3170578B1 true EP3170578B1 (fr) | 2021-06-30 |
Family
ID=54979362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP15194848.6A Active EP3170578B1 (fr) | 2015-11-17 | 2015-11-17 | Procédé de fabrication d'une pièce moulée en fonte à graphite sphéroïdal |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20170136537A1 (fr) |
| EP (1) | EP3170578B1 (fr) |
| CN (1) | CN106975740A (fr) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2280284A (en) * | 1940-10-02 | 1942-04-21 | Electro Metallurg Co | Method and agent for treating iron and steel |
| JPS59137155A (ja) * | 1983-01-25 | 1984-08-07 | Toshiba Corp | 鋳型内接種剤 |
| US4867227A (en) * | 1987-08-07 | 1989-09-19 | Metallgesellschaft Aktiengesellschaft | Process and apparatus for inoculating cast iron |
| WO2006068487A1 (fr) * | 2004-12-23 | 2006-06-29 | Elkem Asa | Agents modificateurs pour fonte |
| ES2342758A1 (es) * | 2008-12-18 | 2010-07-13 | Fagor, S.Coop. | Proceso de fabricacion de una fundicion esferoidal. |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3030204A (en) * | 1960-04-07 | 1962-04-17 | Vanadium Corp Of America | Process of making ferroalloys |
| SE321095B (fr) * | 1967-06-08 | 1970-02-23 | Jaernfoeraedling Ab | |
| SE406930B (sv) * | 1973-05-28 | 1979-03-05 | Pont A Mousson | Forfarande for nodularisering av grafit i smelt gjutjern med modulariseringsmedel i form av pelleter |
| CN1015553B (zh) * | 1990-01-23 | 1992-02-19 | 清华大学 | 铸铁强墨化孕育剂 |
| DE10129382A1 (de) * | 2001-06-20 | 2003-01-02 | Fischer Georg Fahrzeugtech | Sphärogusslegierung |
| DE102004056331A1 (de) * | 2004-11-22 | 2006-05-24 | Georg Fischer Fahrzeugtechnik Ag | Sphärogusslegierung und Verfahren zur Herstellung von Gussteilen aus der Sphärogusslegierung |
| JP4974591B2 (ja) * | 2005-12-07 | 2012-07-11 | 旭テック株式会社 | 黒鉛球状化剤およびこれを用いた球状黒鉛鋳鉄の製造方法 |
-
2015
- 2015-11-17 EP EP15194848.6A patent/EP3170578B1/fr active Active
-
2016
- 2016-11-14 US US15/350,126 patent/US20170136537A1/en not_active Abandoned
- 2016-11-17 CN CN201611011585.2A patent/CN106975740A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2280284A (en) * | 1940-10-02 | 1942-04-21 | Electro Metallurg Co | Method and agent for treating iron and steel |
| JPS59137155A (ja) * | 1983-01-25 | 1984-08-07 | Toshiba Corp | 鋳型内接種剤 |
| US4867227A (en) * | 1987-08-07 | 1989-09-19 | Metallgesellschaft Aktiengesellschaft | Process and apparatus for inoculating cast iron |
| WO2006068487A1 (fr) * | 2004-12-23 | 2006-06-29 | Elkem Asa | Agents modificateurs pour fonte |
| ES2342758A1 (es) * | 2008-12-18 | 2010-07-13 | Fagor, S.Coop. | Proceso de fabricacion de una fundicion esferoidal. |
Also Published As
| Publication number | Publication date |
|---|---|
| US20170136537A1 (en) | 2017-05-18 |
| EP3170578A1 (fr) | 2017-05-24 |
| CN106975740A (zh) | 2017-07-25 |
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