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EP2567991A3 - Compositions moussantes contenant des mélanges azéotropiques ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et leurs applications dans la préparation de mousses à base de polyisocyanate - Google Patents

Compositions moussantes contenant des mélanges azéotropiques ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et leurs applications dans la préparation de mousses à base de polyisocyanate Download PDF

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Publication number
EP2567991A3
EP2567991A3 EP12191122.6A EP12191122A EP2567991A3 EP 2567991 A3 EP2567991 A3 EP 2567991A3 EP 12191122 A EP12191122 A EP 12191122A EP 2567991 A3 EP2567991 A3 EP 2567991A3
Authority
EP
European Patent Office
Prior art keywords
foam
azeotrope
hexafluoro
butene
azeotropic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP12191122.6A
Other languages
German (de)
English (en)
Other versions
EP2567991B1 (fr
EP2567991A2 (fr
Inventor
Gary Loh
Joseph Anthony Creazzo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of EP2567991A2 publication Critical patent/EP2567991A2/fr
Publication of EP2567991A3 publication Critical patent/EP2567991A3/fr
Application granted granted Critical
Publication of EP2567991B1 publication Critical patent/EP2567991B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C08G18/5027—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups directly linked to carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
EP12191122.6A 2007-12-19 2008-12-17 Compositions moussantes contenant des mélanges de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et soit 1,1,1,3,3-pentaflurobutane ou 1,1,1,3,3-pentafluroropropane et leurs applications dans la préparation de mousses à base de polyisocyanate Active EP2567991B1 (fr)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US1508607P 2007-12-19 2007-12-19
US1502707P 2007-12-19 2007-12-19
US1509207P 2007-12-19 2007-12-19
US1506107P 2007-12-19 2007-12-19
US1508907P 2007-12-19 2007-12-19
US1521807P 2007-12-20 2007-12-20
US1522107P 2007-12-20 2007-12-20
US1521407P 2007-12-20 2007-12-20
EP08866190.5A EP2222746B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du methyl formate et leurs applications dans la préparation de mousses à base de polyisocyanate

Related Parent Applications (3)

Application Number Title Priority Date Filing Date
EP08866190.5 Division 2008-12-17
EP08866190.5A Division-Into EP2222746B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du methyl formate et leurs applications dans la préparation de mousses à base de polyisocyanate
EP08866190.5A Division EP2222746B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du methyl formate et leurs applications dans la préparation de mousses à base de polyisocyanate

Publications (3)

Publication Number Publication Date
EP2567991A2 EP2567991A2 (fr) 2013-03-13
EP2567991A3 true EP2567991A3 (fr) 2013-05-01
EP2567991B1 EP2567991B1 (fr) 2015-08-05

Family

ID=40565188

Family Applications (5)

Application Number Title Priority Date Filing Date
EP12191123.4A Active EP2567992B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du cis-1,1,1,4,4,4-hexafluoro-2-butène et du trans-1,2-dichloroethylène et leurs applications dans la préparation de mousses à base de polyisocyanate
EP12191130.9A Active EP2567994B8 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du diméthoxyméthane et leurs applications dans la préparation de mousses à base de polyisocyanate
EP12191127.5A Active EP2567993B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du cis-1,1,1,4,4,4-hexafluoro-2-butène et du cyclopentane et leurs applications dans la préparation de mousses à base de polyisocyanate
EP08866190.5A Active EP2222746B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du methyl formate et leurs applications dans la préparation de mousses à base de polyisocyanate
EP12191122.6A Active EP2567991B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant des mélanges de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et soit 1,1,1,3,3-pentaflurobutane ou 1,1,1,3,3-pentafluroropropane et leurs applications dans la préparation de mousses à base de polyisocyanate

Family Applications Before (4)

Application Number Title Priority Date Filing Date
EP12191123.4A Active EP2567992B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du cis-1,1,1,4,4,4-hexafluoro-2-butène et du trans-1,2-dichloroethylène et leurs applications dans la préparation de mousses à base de polyisocyanate
EP12191130.9A Active EP2567994B8 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du diméthoxyméthane et leurs applications dans la préparation de mousses à base de polyisocyanate
EP12191127.5A Active EP2567993B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du cis-1,1,1,4,4,4-hexafluoro-2-butène et du cyclopentane et leurs applications dans la préparation de mousses à base de polyisocyanate
EP08866190.5A Active EP2222746B1 (fr) 2007-12-19 2008-12-17 Compositions moussantes contenant un mélange azéotropique ou de type azéotropique contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et du methyl formate et leurs applications dans la préparation de mousses à base de polyisocyanate

Country Status (11)

Country Link
US (1) US8658708B2 (fr)
EP (5) EP2567992B1 (fr)
JP (2) JP5703027B2 (fr)
KR (3) KR101564895B1 (fr)
CN (1) CN101903435B (fr)
AR (1) AR070677A1 (fr)
AU (1) AU2008343200A1 (fr)
BR (1) BRPI0819469B1 (fr)
CA (4) CA3023927C (fr)
ES (5) ES2560008T3 (fr)
WO (1) WO2009085857A2 (fr)

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KR20100105636A (ko) 2007-11-29 2010-09-29 이 아이 듀폰 디 네모아 앤드 캄파니 조성물 및 폴리아이소시아네이트계 폼의 제조에서 시스-1,1,1,4,4,4-헥사플루오로-2-부텐 폼-형성 조성물의 용도
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BR112012027758A2 (pt) 2010-04-28 2016-07-26 Arkema Inc método para melhorar estabilidade de misturas de poliol de poliuretano contendo agente de expansão de olefina halogenada
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EP2744981B1 (fr) * 2011-08-19 2024-09-25 The Chemours Company FC, LLC Procédé pour des cycles organiques de rankine permettant de produire une énergie mécanique à partir de chaleur
US8756890B2 (en) 2011-09-28 2014-06-24 Romeo Ilarian Ciuperca Insulated concrete form and method of using same
WO2013081809A1 (fr) * 2011-12-02 2013-06-06 E.I. Du Pont De Nemours And Company Compositions d'agent d'expansion de mousse contenant du z-1,1,1,4,4,4-hexafluoro-2-butène et leurs utilisations dans la préparation de mousses de polymère de polyuréthane et de polyisocyanurate
CN102675579A (zh) * 2012-05-07 2012-09-19 南京宝新聚氨酯有限公司 一种聚氨酯反应组合物及采用该组合物制备的硬质泡沫的方法
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US9458637B2 (en) 2012-09-25 2016-10-04 Romeo Ilarian Ciuperca Composite insulated plywood, insulated plywood concrete form and method of curing concrete using same
US8636941B1 (en) 2012-09-25 2014-01-28 Romeo Ilarian Ciuperca Methods of making concrete runways, roads, highways and slabs on grade
US10077330B2 (en) * 2013-03-06 2018-09-18 Honeywell International Inc. Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene
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US10065339B2 (en) * 2013-05-13 2018-09-04 Romeo Ilarian Ciuperca Removable composite insulated concrete form, insulated precast concrete table and method of accelerating concrete curing using same
CA2911409C (fr) 2013-05-13 2021-03-02 Romeo Ilarian Ciuperca Moule de batterie en beton isole, systeme de durcissement du beton passif isole, appareil de durcissement accelere du beton, et procede d'utilisation associe
EP3043971A4 (fr) 2013-09-09 2017-01-18 Romeo Ilarian Ciuperca Coffrage glissant pour béton isolé et procédé d'accélération de la prise du béton utilisant celui-ci
CN105683269A (zh) * 2013-09-19 2016-06-15 陶氏环球技术有限责任公司 使用混合发泡剂制备闭孔刚性聚氨酯泡沫体的真空辅助方法
US20150210818A1 (en) * 2014-01-27 2015-07-30 E I Du Pont De Nemours And Company Cryogenic insulation foam
KR20170041245A (ko) * 2014-08-12 2017-04-14 더 케무어스 컴퍼니 에프씨, 엘엘씨 Hfo-e-1,3,4,4,4-펜타플루오로-3-트라이플루오로메틸-1-부텐의 공비 및 공비-유사 조성물 및 이의 용도
CN104262935A (zh) * 2014-09-18 2015-01-07 关志强 一种聚氨酯混合发泡剂
CN113583632A (zh) * 2015-02-06 2021-11-02 科慕埃弗西有限公司 包含z-1,1,1,4,4,4-六氟-2-丁烯的组合物及其用途
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CN105985503B (zh) * 2016-06-20 2019-04-02 海信容声(广东)冰箱有限公司 一种负压发泡用聚氨酯反应组合物以及利用该组合物制备聚氨酯泡沫的方法
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US11505670B2 (en) 2016-11-17 2022-11-22 Covestro Llc Polyurethane foams co-blown with a mixture of a hydrocarbon and a halogenated olefin
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AT17135U3 (de) * 2017-07-11 2021-09-15 Brugg Rohr Ag Holding Thermisch gedämmte Mediumrohre mit HFO-haltigem Zellgas
CN108192065A (zh) * 2017-12-28 2018-06-22 青岛海尔股份有限公司 聚氨酯硬质泡沫塑料及其制备方法
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CA2941024C (fr) 2018-12-04
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JP6033273B2 (ja) 2016-11-30
CA2941021C (fr) 2019-01-08
ES2548184T3 (es) 2015-10-14
AU2008343200A1 (en) 2009-07-09
KR101564895B1 (ko) 2015-10-30
EP2222746B1 (fr) 2015-10-28
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EP2567992B1 (fr) 2015-11-04
JP2011508020A (ja) 2011-03-10
KR101590653B1 (ko) 2016-02-01
JP2015091973A (ja) 2015-05-14
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CA3023927A1 (fr) 2009-07-09
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BRPI0819469A2 (pt) 2015-05-05
CN101903435B (zh) 2014-07-23
EP2567991B1 (fr) 2015-08-05
EP2567993B1 (fr) 2015-09-02
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CA2941021A1 (fr) 2009-07-09
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