EP2419679A2

EP2419679A2 - Moulded insulating collector

Info

Publication number: EP2419679A2
Application number: EP10717186A
Authority: EP
Inventors: Hideaki Nishio; Anis Gaaloul; Franck Bollaert
Original assignee: Sumika Polymer Compounds France SA
Current assignee: Sumika Polymer Compounds France SA
Priority date: 2009-04-17
Filing date: 2010-04-07
Publication date: 2012-02-22
Also published as: WO2010119185A4; WO2010119185A2; US20120313278A1; WO2010119185A3; EP2241841A1

Abstract

The invention relates to single-block molded frames made of an expandable insulating plastic material, in particular frames for molded insulating collectors. The invention also relates to said collectors, in particular to molded insulating collectors for thermal or photovoltaic solar panels.

Description

Molded monobloc frame and collector including them

The invention is placed in the field of molded collectors made of plastic materials, possibly foams, insulators, usable particularly for the realization of low weight solar equipment and such as flat-box type collectors / chest or parabolic type collectors .

Solar panels are the basic components of most solar power generation equipment. A solar panel is a device for recovering part of the energy of solar radiation to convert it into usable electrical or thermal energy. There are two types of solar panels:

- solar thermal panels, or solar thermal collectors, which convert light into heat recovered and used in the form of hot water;

- photovoltaic solar panels, or photovoltaic modules, which convert light into electricity.

In both cases, the panels are usually flat or parabolic, with a surface area ranging from plus or minus one meter-square to several square meters (for example 2 to 6 square meters). Standard dimensions are generally defined to facilitate and optimize the installation. There are two types of solar thermal panels: water sensors and air sensors.

In "water" thermal sensors, water or more often a heat transfer fluid (glycol-based for example), circulates in closed-circuit tubes. For best performance, the assembly is placed in an insulated glass collector to obtain a greenhouse effect.

In "air" heat sensors, air circulates and heats up in contact with the absorbers. The air thus heated is then ventilated in the habitats for heating or for example in agricultural sheds for the drying of the productions. The use of a collector again makes it possible to obtain a better yield. Solar thermal technology can be used for applications other than space heating such as, for example, the heating of fluids in industrial installations such as chemical production sites, the air-conditioning of premises by solar channel, or desalination. seawater.

Photovoltaic solar panels include photovoltaic cells connected together, in series or in parallel. For reasons of strength alone, these panels generally also include a collector. Some new sensor concepts can be hybrid

(thermal and photovoltaic).

Thus, solar panels generally consist of an active element (photovoltaic cells or water or air circulation circuit) positioned in a collector, said collector possibly being insulating. At present the realization of the insulating collectors used in the solar thermal panels requires the assembly of at least 6 independent elements that are a collector, generally formed of an aluminum or metal frame, an insulator, advantageously made of glass wool, a fluid circulation circuit (water or glycol), generally coupled to a heat absorber, itself generally consisting of a metal plate, said absorber being itself covered with a material improving its performance, and a plate of glass.

The frame is usually the part of the collector that takes the constraints. In this respect it is therefore the part that requires the most attention during the design and manufacturing stages.

The assembly of the different components of such a solar panel significantly increases the cost as well as the weight. Moreover, the multiplication of the number of assembled basic elements can lead to the appearance of thermal bridges and / or thermal gradients in the collector structure which can have undesirable consequences, such as the deformation of the assembly, which can lead to to leaks, the appearance of mist on the glass or heat losses, which will affect the performance of the equipment.

It is therefore interesting to be able to provide a new collector that does not have the drawbacks of collectors known from the prior art. It is an object of the invention to provide such a collector.

This object is achieved according to the invention which proposes to provide a collector of which at least a part, advantageously the frame, is molded in the form of a monoblock of insulating plastic materials, possibly foams.

One of the advantages of the invention lies in the fact that the plastic material used to manufacture the collector can simultaneously be molded and foamed. By molding it can be given any desired shape, by foaming is created in the material an area constituting an insulation, which further improves the intrinsic insulating nature of the material used. Thus one can obtain a product of desired shape in a material having between a smooth inner face and a smooth outer face, a portion resembling a solidified foam, these two faces and this foamed portion being in the same material. The thickness of the foamed portion, when the material is foamed which is not mandatory, can range from a few tenths of millimeters to several centimeters as needed. Subsequently in the text will be used the expression "molded insulating collector" or the term "collector" to designate either a collector according to the invention of which only the frame has been molded or a collector according to the invention whose frame and the background were molded.

It is therefore understood that according to the invention, the molded insulating collector can be made by molding at once in the form of a monoblock either of the frame-bottom assembly, or of the frame alone.

By monobloc means according to the invention, that the integrally molded part, preferably the frame but possibly the frame-bottom assembly, is in one piece made by molding a single expandable insulating plastic material. Thus, a first object of the invention is a monobloc frame molded from an expandable insulating plastic material, particularly a plastic material whose expansion may occur during molding, chosen from plastics that may comprise one or more polymers chosen from polypropylene ( PP), polyethylene (PE), aliphatic or aromatic polyamide (PA), polyphenylene ether blend (such as polyphenylene ether / polystyrene / butadiene alloy (PPE / PS), polyphenylene ether / polyphenylene sulfone alloy ( PPE / PPS), polyphenylene ether / polypropylene alloy (PPE / PP), polyphenylene ether / polyamide alloy (PPE / PA), polyethersulfone (PES), polyphenylene sulfone (PPS), polyester, polybutylene terephthalate (PBT).

The invention also relates to a molded insulating collector, characterized in that at least the frame of said collector is a molded monobloc frame as described above. The invention also relates to a molded insulating collector, characterized in that it comprises a frame and a single-piece bottom molded in one piece of a single expandable insulating plastic material, particularly a plastic material whose expansion may occur during molding composition, chosen from plastics that may comprise one or more polymers chosen from polypropylene (PP), polyethylene (PE), aliphatic or aromatic polyamide (PA), polyphenylene ether mixture (such as polyphenylene ether alloy polyphenylene ether / polyphenylene sulfone (PPE / PPS), polyphenylene ether / polypropylene alloy (PPE / PP), polyphenylene ether / polyamide alloy (PPE / PA), polyethersulfone (PES), polyphenylene sulfone (PPS), polyester, polybutylene terephthalate (PBT).

Preferentially according to the invention, the plastic material may be polypropylene, for reasons of low density, cost and recyclability.

Thus, by the use of the plastic materials mentioned above, it is possible to integrate the insulation function directly during the molding process by producing plastic foamed walls. When said molded insulating collector comprises at least one molded one-piece frame, it may further comprise a bottom which may be in any material compatible with the function of the collector, advantageously in the same material as said frame, said bottom being able to be added to the frame either by overmoulding said frame on said bottom, or by any means allowing said bottom to be joined to said frame, for example by post-molding bonding before the material constituting said frame is solid, by post-molding bonding when the frame has become rigid, or by any mechanical fastening means such as stapling, clipping, screwing, etc. It is also possible that the section of said frame comprises on one of these faces a slide obtained at the time of molding, advantageously open towards the inside of the frame, in which it is possible to slide a part such as a plate constituting the bottom of said collector.

Whatever the variant of the invention, said collector according to the invention can take any desired shape and particularly the shape of a parallelepiped, regular or not, comprising a bottom and four sides or the shape of a parabola, to at the very least of a bent plate according to at least one of these axes.

The collectors of the invention make it possible to obtain solar thermal panels comprising only three major elements, the insulating collector according to the invention, the water circulation circuit, and the translucent plate, preferably glass.

According to a particular embodiment of the invention, the plastic material may comprise all or part of recycled or regenerated material according to the criteria defined for example in the environmental charters of the automotive industry.

According to yet another particular embodiment of the invention, a

(or) reinforcing filler (s) of any type may (may) be added to the plastic material. In this regard, mention may be made, for example, of inorganic or organic fillers, nanoparticles, conductive fillers, long or short glass fibers, organic fibers, natural fibers. Advantageously, the use of thermoplastics based on natural and / or organic fibers makes it possible to lighten the molded parts.

It is also possible to use a mixture of charges, in order to limit the risk of deformation during molding. For example, with fiberglass it is possible to use a filler such as talc or calcium carbonate.

Thermoplastic materials incorporating fillers may be chosen for example from the Thermofil ^® range of Sumika Polymer Compounds. According to yet another embodiment of the invention, it is possible to add to the thermoplastic material at least one fire-retardant filler, with or without halogens, in order to add fire protection.

Another great advantage of the invention is that it allows the production of manifolds, thermoplastic material, large, possibly flat, having virtually no residual deformation after molding. To the knowledge of the applicant, the conventional plastic injection techniques known from the prior art make it difficult to obtain large flat collectors not having such residual deformations. Another advantage of the invention stems from the fact that the materials and techniques described above are used for its manufacture, which makes it possible not only to give any shape to the frame or to the collector but also to any size to said frame or collector. These will be easily adapted as needed. Optionally said collector may further comprise other integrated elements, for example plastic, and possibly integrated functions.

Thus, the invention allows the realization of collectors, flat or parabolic, easily integrating all kinds of reported elements in order to improve the performance of the solar panel. For example, it may be possible to integrate inside the collector according to the invention a solar reflector, for example example a solar reflector in the form of parabolic housing, each housing may correspond to a fluid circulation tube. This additional element makes it possible to reproduce and improve the principle of the open parabolic collector (without box). Yet another advantage of the invention is that the method which allows the manufacture of the collectors according to the invention, which is also an object of the present invention, allows the direct integration of functions essential to the proper functioning of a solar panel then that in the techniques of the prior art, these functions are generally reported on the collector after its manufacture.

It is also possible to integrate during the molding of the collector, a

(Or) means (s) for fixing the glass of a solar thermal panel, whether organic or mineral, by performing during molding a slide advantageously open towards the inside of the frame or by overmolding fastening means, for example clips.

It is still possible to integrate during the molding of the manifold, by overmolding, a (or) means (s) of sealing such as seals, for example elastomer, during the molding of the manifold (for example thermoplastic elastomer seals). as for example in olefinic thermoplastics vulcanized dynamically (TPV) or not (TPO) such as for example trademarks Espolex® (Sumitomo Chemical) or Santoprene®.

It is also possible to integrate in the collector, (or) means (s) for absorbing solar rays by producing absorbers, for example extruded plastic materials (Polyphenylene sulphide (PPS), polyphenylene ether alloy / polystyrene / butadiene (PPE / PS), aromatic polyamides, polysulfone, polyestersulfones, etc.) and / or plastic films on the surface of a metal absorber itself, for example aluminum or copper).

It is also possible to integrate during the molding of the collector, (or) means (s) for fixing the collector on a support, for example a roof, with the possibility of varying the inclination of said supports to increase the efficiency of the solar panel.

The collectors according to the invention can be colored in the mass, for example by masterbatches during the molding step or by decoration pre-applied in the mold with the aid of a decorative film.

The collectors can take all the desired forms, it is also possible to make collectors, and therefore solar panels, which can be integrated into their support such as the facade of a building.

In the case of solar collectors having a parabolic collector, the tube or tubes are not enclosed in a box, the plastic material used for its realization can be covered by a reflective film or absorbent.

According to yet another embodiment of the invention, and in order to lighten the solar thermal panel, an organic glass can be used as a replacement for the mineral glass. This organic glass may be chosen from polymethyl methacrylates (PMMA), reinforced with or without impact by other acrylates such as butyl acrylates or polycarbonates (PC).

According to yet another embodiment of the invention, additional insulation means and / or thermal protection means of the walls may be added if necessary.

According to the invention, the molding of the collector can be obtained by any known method which comprises at least one step of molding the insulating material and a step of expanding said insulating material.

In this respect, mention may be made, for example, of conventional thermoplastic injection, preferably at low pressure, such as the SPMoId process of Sumitomo Chemical. This method has the great advantage of avoiding any deformation phenomenon after molding.

thermoplastic injection with foaming of the plastic material, for example the SP Foaming process. Foaming of the material plastic can be obtained by adding a chemical expansion agent into the plastic material to be injected. Said chemical expansion agent may be chosen preferentially from Sekuisi or Clariant suppliers.

- the Dolphin process; the Mucell process of TREXEL, in which a gas in the supercritical state is injected into the molten plastic material;

the thermoforming of extruded and foamed plates by direct extrusion, for example the Sumiceller or Trocellen processes.

Advantageously according to the invention, the SP-MoId and Sumiceller® techniques developed by Sumitomo Chemical will be used.

According to a variant of the invention, it is possible to add, by overmoulding elements reported to the collector, such as a bottom in the variant where only the frame is molded monobloc, or whatever the variant of the locking clips, reinforcements, or any other element that can be obtained by overmolding. A preferred overmolding technique may be the thermoplastic injection of polypropylene-based plastics.

According to another embodiment of the invention, the inner and / or outer surfaces of the collector, independently or simultaneously, may be coated with a material intended to provide good reflection and / or thermal protection, such as for example a protective film and / or aluminized film. According to this embodiment, the film may be affixed by deposition in the mold during the injection molding process or thermoforming or coextrusion in the case of extruded parabolic collectors.

The invention also relates to solar thermal panels for heating water or air as well as photovoltaic solar panels, comprising at least one collector according to the invention.

One of the great advantages of solar thermal panels according to the invention lies in the fact that they can be made from only 3 elements (the collector according to the invention, the water or air circuit and the glass plate organic or mineral), which induces a significant reduction of the panel assembly, as well as a significant reduction in weight (from 10 to 80%) depending on the functions integrated in the manifold. Note that the use of an organic glass instead of a mineral glass can still allow a significant weight gain (-50%). These gains increase the transport and installation facilities associated with weight reduction, which leads to lower costs and a lower CO ₂ impact on the environment.

The appearance of thermal bridges is also greatly reduced in collectors and / or solar panels according to the invention.

Another advantage of the invention lies in the fact that the solar panels incorporating a collector according to the invention can be of relatively reduced thickness, the insulator being an integral part of said collector.

The ease of dismantling (related to the reduced number of components or subsets of components) collectors according to the invention, facilitates the recycling of said components, particularly with use. polypropylene-based plastics that do not release toxic substances.

The reduction of the impact on the environment related to the removal of surface treatments and paints from the collector, the decoration of the panels can be achieved by coloring in the mass or lamination of plastic or aluminized films, compared to the current solution of frames painted aluminum is also not negligible.

Finally, the freedom of form that the design of thermoplastic parts allows, allows a better integration of the solar equipment in its environment (for example, integration in facades or on the roof of a building). In this respect, a possibility exists to design the manifold as a box of various shape integrating by its shape, the support of the collector. This box can be made from a foamed plastic plate which would be folded into different points to give the desired shape. The box of various shape thus produced can also integrate other elements such as a tank-siphon in the case of solar thermal siphon panel, a fuse box in the case of a photovoltaic panel, a box air conditioner or heat pump for better integration of the set of additional equipment currently present on a roof of a house for example.

Advantageously, said solar thermal panel may further comprise independently or simultaneously, one or more support (s) of the water or air circuits, one or several reinforcing elements, one or more supports of the plate. of glass, an additional insulator (s), or a heat absorber (s), generally made of a metal plate, said absorber being itself covered with an improving material its performance, said absorber can also be coupled to the water or air circuit. The invention also relates to the use of a collector according to the invention for mounting solar thermal or photovoltaic panels.

Those skilled in the art understand that the techniques used in the present invention and the applicable dimensions are usual data in these fields and that it will have no difficulty in implementing them. Other advantages, aims and features of the present invention will emerge from the description which follows, made for an explanatory and non-limiting purpose, with reference to the appended drawings in which:

- Figure 1 shows a sectional view of a collector according to the invention;

- Figure 2 shows a sectional view of a solar panel for heating water.

- Figure 3 shows a sectional view of a solar panel for heating water, further incorporating additional insulation.

- Figure 4 shows a sectional view of a solar panel for heating water, further incorporating another solar collector. - Figure 5 shows a 3-dimensional view of a collector according to the invention in the form of a box.

FIG. 6 shows a 3 dimensional and transparent view of a solar thermal panel integrated in a collector as represented in FIG. Thus with reference to the figures, we see in Figure 1 a sectional view of a collector (11) according to the invention incorporating an insulator (12) in its bottom.

FIG. 2 shows a sectional view of a solar thermal panel for heating water comprising a collector according to the invention (21) integrating an insulator (22) in its bottom, a glass plate (23) , a water circuit

(24) a heat absorber (25), water circuit supports (26) and overmolded glass plate support means (27).

FIG. 3 shows a sectional view of a solar thermal panel according to FIG. 2 for heating water, further comprising additional insulation (38).

FIG. 4 shows a sectional view of a solar thermal panel according to FIG. 2, intended to heat water, further comprising a solar reflector (49) in the form of a parabolic housing, each housing of which may correspond to a tube fluid circulation (44). FIG. 5 shows a 3-dimensional view of a collector according to the box-shaped invention (51) and a representation of the insulating plastic sheet (510) which, by folding, gave said box. The arrows indicate the direction of folding of the foamed plastic sheet.

FIG. 6 shows a 3-dimensional view of a solar panel installed in a collector according to FIG. 5, showing in transparency a solar panel (61 1) and a reservoir (612).

Claims

1.) One-piece frame molded from an expandable insulating plastic material, particularly a plastic material which may be expanded during molding, chosen from plastics that may comprise one or more polymers chosen from polypropylene (PP), polyethylene ( PE), the aliphatic or aromatic polyamide (PA), the polyphenylene ether mixture (such as the polyphenylene ether / polystyrene / butadiene (PPE / PS) alloy, the polyphenylene ether / polyphenylene sulfone (PPE / PPS) alloy, polyphenylene ether / polypropylene alloy (PPE / PP), the polyphenylene ether / polyamide alloy

(PPE / PA), polyethersulfone (PES), polyphenylene sulfone (PPS), polyester, polybutylene terephthalate (PBT), advantageously polypropylene.

2.) molded insulating collector, characterized in that it comprises at least one molded monobloc frame according to claim 1.

3.) molded insulating collector, characterized in that it comprises a frame and a one-piece bottom molded in one piece in a single expansible insulating plastic material, particularly a plastic material whose expansion may occur during molding, selected from the plastics materials may comprise one or more polymers chosen from polypropylene (PP), polyethylene (PE), aliphatic or aromatic polyamide (PA), polyphenylene ether mixture (such as polyphenylene ether / polystyrene / butadiene alloy ( PPE / PS), polyphenylene ether / polyphenylene sulfone alloy (PPE / PPS), polyphenylene ether / polypropylene alloy (PPE / PP), polyphenylene ether / polyamide alloy (PPE / PA), polyethersulfone (PES) polyphenylene sulfone (PPS), polyester, polybutylene terephthalate (PBT), advantageously polypropylene.

4.) A collector according to claim 2, characterized in that it further comprises a bottom.

5.) A collector according to claim 4, characterized in that said bottom is added to the frame either by overmolding said frame on said bottom, or by any means for assembling said bottom to said frame such as by post-molding bonding before the material constituting said frame is solid, by post-molding bonding when the frame has become rigid, either by any mechanical means of attachment such as stapling, clipping, screwing.

6.) Frame according to claim 1 or collector according to any one of claims 2 to 5, characterized in that one (or) load (s) reinforcing (s) and / or one (or loads) (s) ) flame retardant (s) is (are) added to the plastic.

7.) Frame or collector according to claim 6, characterized in that the reinforcing filler is selected from inorganic or organic fillers, nanoparticles, conductive fillers, long or short glass fibers, organic fibers, natural fibers. preferentially natural and / or organic fibers

8.) A collector according to any one of claims 2 to 7, characterized in that it further comprises, simultaneously or independently, a solar reflector, an insulation means or a means for thermal protection of the walls, one or more means for attaching a window, one or more means (s) of sealing, one (or more) means (s) for absorbing the solar rays, one (or more) means (s) for fixing the collector on a support.

9.) A collector according to any one of claims 2 to 8, characterized in that it is capable of being obtained by conventional thermoplastic injection, preferably at low pressure, (SPMoId method of

Sumitomo Chemical), thermoplastic injection with plastic foaming (SP Foaming process), the Dolphin process, the Mucell process, the thermoforming of extruded and foamed extrusion plates (Sumiceller or Trocellen processes).

10.) A collector according to claim 9, characterized in that it is obtainable by SP-MoId and Sumiceller® techniques.

11. Solar thermal or photovoltaic or mixed panel comprising at least one frame according to claim 1, 6 or 7 or at least one collector as described in any one of claims 2 to 10.

12. solar thermal panel according to claim 10, characterized in that it further comprises a water circulation circuit and a translucent plate.