EP2470441B1 - Use of a biaxially oriented film roll made of polypropylene for cigarette packages, and cigarette carton - Google Patents
Use of a biaxially oriented film roll made of polypropylene for cigarette packages, and cigarette carton Download PDFInfo
- Publication number
- EP2470441B1 EP2470441B1 EP10752721.0A EP10752721A EP2470441B1 EP 2470441 B1 EP2470441 B1 EP 2470441B1 EP 10752721 A EP10752721 A EP 10752721A EP 2470441 B1 EP2470441 B1 EP 2470441B1
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- EP
- European Patent Office
- Prior art keywords
- film
- thin
- thin areas
- lines
- cigarette
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D75/5827—Tear-lines provided in a wall portion
- B65D75/5833—Tear-lines provided in a wall portion for tearing out a portion of the wall
- B65D75/5844—Tear-lines provided in a wall portion for tearing out a portion of the wall the portion of the wall being a narrow strip, e.g. between lines of weakness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/07—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles
- B65D85/08—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular
- B65D85/10—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular for cigarettes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/07—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles
- B65D85/08—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular
- B65D85/10—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular for cigarettes
- B65D85/1072—Bundle of cigarette packs
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/15—Sheet, web, or layer weakened to permit separation through thickness
Definitions
- the present invention relates to a use of a biaxially oriented film roll according to claim 1 and a cigarette rod according to claim 7.
- biaxially oriented plastic films particularly thermoplastic polymer films, and especially biaxially oriented polypropylene films
- the polyolefin film protects the packaged goods against rapid drying or loss of flavor with very low material usage.
- Uniaxially oriented films show a low tear strength in the direction of orientation and can be easily controlled in this direction and tear further.
- uniaxially oriented films are not usable in many fields, among other things due to insufficient transverse mechanical strengths.
- the biaxial orientation on the one hand, produces the desirable high strengths (moduli) in both dimensions; on the other hand, but also the preferred directions are equalized. This has the consequence that for opening a film package (eg biscuit bag) first a high force must be overcome in order to tear the film.
- a crack will be planted even when using very low tensile forces uncontrollably continued.
- This uncontrolled tear propagation behavior is particularly problematic in biaxially oriented polypropylene films, since the tear propagation resistance is particularly weak in this material. This problem is particularly troublesome for packages with general cargo, which is not loose, but packaged orderly, such as cigarette rods, Weetabix, crispbread, biscuit rolls and the like. These types of packaging are particularly designed to ensure that the consumer initially only picks individual pieces and wants to store the remainder of the package in order to remove more units at a later date. For this application, the uncontrolled tear propagation of the film packaging is particularly annoying for the consumer.
- the WO 98/2312 describes packages that are pre-cut by a laser beam. These packages have a multilayer structure. In particular, a metallic intermediate layer is provided which is intended to prevent the laser beam from cutting through the film. This packaging is lavish and expensive due to the lamination with a metal layer. About the exact configuration of the packaging is disclosed in the description nothing.
- the perforated film must have sufficient mechanical stability so that the perforated film can be used to package the piece goods.
- the perforation is integrated as a processing step in the packing process. This solution avoids any mechanical stresses on the perforated film, e.g. when winding and unwinding.
- the integration of the perforation is not possible in all packaging processes. Firstly, the spatial conditions in existing systems are often designed so that there is simply no room to grow such a device. Furthermore, the packaging processes in the cigarette industry are running at very high speeds, which may be too fast for the perforation. Therefore, it is not always possible to incorporate a device for perforating the foil into a device for bar wrapping cigarette packets. A sufficient mechanical stability of the film is contrary to the same desire for an easy-open packaging.
- the EP1764313 discloses the use of a biaxially oriented polypropylene film as a packaging material for repackaging packed articles.
- the packaging material has two thin lines which are arranged parallel and offset from one another. However, the thin spots are shorter than the distances between the thin spots.
- JP2006-276515 describes an axially oriented shrink film Polypropylene with at least two thin-line lines, which run parallel to each other.
- the shrink film is used as a sleeve for cylindrical vessels and shrunk onto the vessel for this purpose.
- the parallel thin lines form a kind of tear tape over which the sleeve can be torn open and separated from the vessel.
- WO03072455 describes a method of wrapping an article using a wrapping film having at least one tear line. It will be described in detail how the film is cut and processed to produce a sealed package with a specially designed strip. The package can then be opened simply by pulling the free end of the strip to initiate tearing along the tear line.
- DE102006013280 discloses a cigarette rod and the use of a polypropylene shrinkable film for packaging cuboid cigarette packets.
- the object of the present invention was to provide an improved package for ordered cargo available.
- the object underlying the invention is achieved by the use of a biaxially oriented film roll of polypropylene according to claim 1.
- the two parallel, staggered thin-point lines form a predetermined breaking point in the film, in which a crack propagates very controlled after tearing.
- the tear continues to run after tearing along one of the thin-line or between the two parallel thin-line lines controlled.
- the foil packaging is opened only as far as desired.
- the packaging according to the invention is particularly suitable for ordered or stacked piece goods, e.g. Cigarette packet, suitable. It is possible for the consumer to tear the film along a predetermined predetermined breaking point in such a way that individual pieces can be removed without further units falling out uncontrollably in the case of piece goods.
- the individual segments between the parallel thin-line lines are adapted according to the size of the unit to be removed. This can be used to control whether one or more units can be conveniently removed by opening.
- the thin-line lines can be applied to the film web in a suitable pattern.
- the lines are straight.
- thin locations are understood as meaning thin areas in which no continuous hole is produced in the film, but the film only becomes thinner at the corresponding points due to removal of material, for example by a laser beam which only penetrates to a predetermined depth.
- 10 to 80% of the original film thickness preferably 20 to 60% of the original film thickness in the region of the thin location remain. In this way, a closed package is obtained, which continues to meet all hygienic requirements and their barrier properties are not impaired.
- thin sections B are followed by undamaged sections of film whose length A is determined by the distance of the thin places. Distances are for the purposes of the present invention thus the areas of undamaged film, ranging from the end of a thin spot to the beginning of the subsequent thin spot in the same thin line.
- the geometric shape of the thin site may vary and depends on the thin point method.
- laser or ultrasound is preferred. Needle perforations create circular or ellipsoidal or propeller-like shapes that result from the needle and foil contacting each other at the perforation and moving relative to each other. Knives produce more rectangular or diamond-shaped thin spots. Laser and ultrasound methods allow different geometric shapes. Except for circular thin spots, all thin spots have a greater extension in one of the two fundamental directions (longitudinal direction) aligned along the thin line.
- the thinnings have in the longitudinal direction generally a length B of 0.1 to 8 mm, preferably 0.3 to 6 mm, in particular 0.5 to 3 mm.
- the extent of the thin point transversely to this longitudinal direction is correspondingly smaller and is generally 5 to 80%, preferably 10 to 50% of its extension in the longitudinal direction. This does not apply to circular thin areas.
- Circular and approximately circular thin bodies have a diameter of 0.1-6 mm, preferably 0.3 to 5 mm, in which case the diameter corresponds to the length of the thin body B.
- the length A of the sections, i. the undamaged film between the thin points is 0.05 to ⁇ 8mm, preferably 1 to 6mm.
- distances of> 4 to 10 mm are preferred.
- the dimensions of the distances A are selected in relation to the length B of the thin spot so that this length B of the thin sites are at least as large or larger than the distances A.
- the length or diameter of a thin spot is at least 10% greater than the length of the gaps.
- the length A of the gaps is 10 to 90% of the length B of the thin spots, preferably 20 to 85%.
- the dimensions of the distances between the thin spots are generally constant, or vary only slightly within the usual manufacturing accuracy.
- the size of each thin spot along a line does not or only slightly varies (up to 10%).
- the diameter of the holes or the length of a thin spot is constant.
- the thin points and distances of the two parallel thin-line lines of a predetermined breaking point have approximately the same dimensions.
- an intended breaking point is formed from two thin lines running in parallel, which are arranged at a distance C of not more than 10 mm.
- the distance C of these two lines is preferably 0.5 to 8 mm, in particular 0.8 to 5 mm
- the second essential feature of the predetermined breaking point according to the invention is the arrangement of the thin places of the two parallel thin-layer lines to each other. It has been found that staggered placement of the thin spots of the two lines improves the control of crack propagation surprisingly. In this staggered arrangement, a thin spot of the second line does not start at the same height as the opposite thin spot of the first line. As a result, the thin point of the second line at least partially covers the distance of the first thin-line line. In preferred embodiments, especially those in which the thin spots are larger than the spacings, the sections of the one thin line are completely covered by the thin spots of the opposite lines.
- the center of the sections of the first thin line is aligned with the center of the respective opposite thin points of the second thin line, so that a symmetrical Thin-point pattern arises.
- the arrangement of two parallel, staggered thin-line lines significantly improves the control of the crack profile.
- the invention also makes it possible to break off the packaging at the predetermined breaking point over the edges of the piece goods if the piece goods have a corresponding mechanical stability and the piece goods in the package is arranged so that its edge extends at the level of the double line.
- the thin-line lines are generally applied in the machine direction of the film. This can be combined simultaneously with the cutting of the film to narrower film widths and thus be carried out in one operation. Alternatively, this can also be done before or after cutting to the finished film width.
- the film can for example be guided over rollers with suitable tools, for example, these rollers are equipped with knife blades. When using laser or ultrasound to create the thin sites, corresponding tools are positioned below or above the film web. In these processes, the film is unwound from a roll, the thin spots according to the invention are applied, and the thinned film is subsequently rewound and the roll used at the general cargo packaging facilities, ie unwound and used for wrapping the goods.
- the thin areas do not impair the winding behavior of the film or only insignificantly, so that the thin film provided with the usual devices can be wound up and unwound. It has also been found, surprisingly, that the thin areas according to the invention do not impair the mechanical stability of the film in such a way that the film breaks, film tears, thick places or thinnings arise during winding and unwinding.
- the roll of thinned film is used to make the package of the present invention.
- the packaging according to the invention is particularly suitable for ordered or stacked piece goods. It is possible for the consumer to tear the film along a predetermined predetermined breaking point in such a way that individual pieces can be removed without other uncontrolled fall out in the case of general cargo.
- the individual segments are adapted according to the size of the unit to be removed. This can be used to control whether one or more units can be conveniently removed after opening.
- the film used is generally a biaxially oriented film of polypropylene.
- the film can be a translucent to transparent or an opaque film.
- "opaque film” means an opaque film whose light transmittance (ASTM-D 1003-77) is at most 70%, preferably at most 50%.
- the film can basically be constructed as a single layer or as a multilayer.
- laminates which are preferably constructed from the films described herein.
- the formulation of the film and the type of laser can be coordinated so that the laser beam in the field of thinning leaves a white or colored line.
- the package later has a recognizable mark and indicates to the consumer where the crack to open the package to allow convenient handling.
- thermoplastics for the film are polyolefins of olefinic monomers having 2 to 8 carbon atoms.
- Propylene polymers, ethylene polymers, butylene polymers, cycloolefin polymers or copolymers of propylene, ethylene, butylene units or cycloolefins are particularly suitable.
- the layers of the film, or the layer for single-layer embodiments at least 50 wt .-%, preferably 70 to 99 wt .-%, in particular 90 to 98 wt .-%, of the thermoplastic polymer, each by weight the layer.
- propylene polymers are preferred. These propylene polymers contain 90 to 100 wt .-%, preferably 95 to 100 wt .-%, in particular 98 to 100 wt .-%, of propylene and has a melting point of 120 ° C or higher, preferably 130 to 170 ° C, and im in general, a melt flow index of 0.5 g / 10 min to 15 g / 10 min, preferably 2 g / 10 min to 10 g / 10 min, at 230 ° C and a force of 21.6 N (DIN 53 735).
- Isotactic propylene homopolymer having an atactic content of 15% by weight and less copolymers of ethylene and propylene having an ethylene content of 10% by weight or less, copolymers of propylene with C 4 -C 8 olefins having an olefin content of 10% by weight. % or less, terpolymers of propylene, ethylene and butylene having an ethylene content of 10% by weight or less and having a butylene content of 15% by weight or less are preferred propylene polymers for the core layer, with isotactic propylene homopolymer being particularly preferred.
- the stated percentages by weight relate to the respective polymer.
- Suitable other polyolefins in the polymer blend are polyethylenes, especially HDPE, LDPE, VLDPE and LLDPE, wherein the proportion of these polyolefins each 15 wt .-%, based on the polymer mixture, does not exceed.
- a layer, preferably the base layer or an intermediate layer, of the film for opaque embodiments may additionally contain pigments and / or vacuole-initiating particles in customary amounts.
- the film of the invention may be single-layered, preferably the film is multi-layered.
- one or both sides of the intermediate layer and / or cover layers may be applied to the base layer.
- multi-layered embodiments of the film in addition to the base layer, optionally intermediate layers and outer layers.
- These additional cover layers and / or intermediate layers are generally composed of polyolefins. They contain at least 70 wt .-%, preferably 75 to 100 wt .-%, in particular 90 to 98 wt .-%, of a polyolefins. As polyolefins for these additional layers are basically the same polymers as described above for the base layer.
- cover layers are Copolymer of Ethylene and propylene or Ethylene and butylene or Propylene and butylene or Ethylene and another olefin having 5 to 10 carbon atoms or Propylene and another olefin having 5 to 10 carbon atoms or a terpolymer of Ethylene and propylene and butylene or Ethylene and propylene and another olefin having 5 to 10 carbon atoms or a mixture or blends of two or more of said homo-, co- and terpolymers suitable.
- ethylene-propylene random copolymers with an ethylene content of 2 to 10 wt .-%, preferably 5 to 8 wt .-%, or random propylene-butylene-1 copolymers with a butylene content of 4 to 25 wt .-%, preferably 10 to 20 wt .-%, each based on the total weight of the copolymer, or ethylene-propylene-butylene-1-terpolymers with an ethylene content of 1 to 10 wt .-%, preferably 2 to 6 wt .-%, and a butylene-1 content of 3 to 20 wt .-%, preferably 8 to 10 wt .-%, each based on the total weight of the terpolymer, or a blend of an ethylene-propylene-butylene-1 terpolymer and a propylene-butylene-1 copolymer with an ethylene content of 0.1 to 7% by weight and a propylene content
- the co- or terpolymers described above generally have a melt flow index of from 1.5 to 30 g / 10 min, preferably from 3 to 15 g / 10 min.
- the melting point is in the range of 120 to 140 ° C.
- the blend of copolymers and terpolymers described above has a melt flow index of 5 to 9 g / 10 min and a melting point of 120 to 150 ° C. All above-mentioned Schmelzflußindices are measured at 230 ° C and a force of 21.6 N (DIN 53 735).
- Layers of co- and / or terpolymers preferably form the outer layers of sealable embodiments of the film.
- the total thickness of the film can vary within wide limits and depends on the intended use.
- the preferred embodiments of the film have total thicknesses of 5 to 250 microns, with 10 to 100 .mu.m, in particular 20 to 80 microns, are preferred.
- the base layer is the layer which makes up more than 50% of the total thickness of the film. Their thickness results from the difference between the total thickness and the thickness of the applied cover and intermediate layer (s) and can therefore vary within wide limits analogously to the total thickness.
- Cover layers form the outermost layer of the film and are 0.5 to 5 microns, preferably 1 to 3 microns.
- the intermediate layer is between 1 and 20 microns, preferably 1 to 10 microns.
- both the base layer and the intermediate layer (s) and the topcoat (s) may contain additives in an effective amount, preferably hydrocarbon resin and / or antistatics and / or antiblocking agents and / or lubricants and / or or stabilizers and / or neutralizing agents which are compatible with the polymers of the core layer and the top layer (s), with the exception of the generally incompatible antiblocking agents.
- the films are produced by the extrusion process known per se.
- the melts corresponding to the individual layers of the film are extruded through a flat die.
- the film thus obtained is stripped to solidify on one or more roll (s) and cooled.
- the temperature of the take-off roll or rollers is 10 to 90 ° C, preferably 20 to 60 ° C.
- the biaxial stretching can be carried out simultaneously or sequentially, with the successive biaxial stretching in which stretching is first longitudinal (in the machine direction) and then transverse (perpendicular to the machine direction) is particularly favorable.
- In the longitudinal direction is preferably 3: 1 to 7: 1 and at a temperature of less than 140 ° C, preferably in the range of 125 to 135 ° C stretched.
- In the transverse direction is preferably 5: 1 to 12: 1, at a temperature of greater than 140 ° C, preferably at 145 to 160 ° C, stretched.
- the longitudinal stretching will be carried out expediently with the help of two different speeds corresponding to the desired stretching ratio and the transverse stretching with the aid of a corresponding clip frame.
- biaxial stretching can also be carried out simultaneously in the longitudinal transverse direction. These simultaneous stretching methods are known per se in the prior art.
- the film is finally held at a temperature of 110 to 150 ° C for about 0.5 to 10 seconds.
- one or both surfaces of the film may be corona or flame treated by one of the known methods.
- the film may be laminated, coated, melt-coated, painted or laminated by further processing steps to provide the film with further advantageous properties.
- laminates composites of polypropylene films and polyethylene films are particularly preferred. Such composites can be produced by lamination of the individual films.
- Another technically advantageous variant for the production of PP / PE laminates is the extrusion coating of a suitable polyethylene onto a biaxially oriented polypropylene film. Such extrusion coatings are known per se in the prior art. It has been found that laminates of PP / PE films are advantageous in the treatment by laser beam and are less likely to be perforated by mistake.
- the packaging is characterized by a controllable tear behavior.
- the force required to initiate a tear at the foil edge can be reduced by a notch, preferably V-shaped.
- the packaging is much easier and more controlled to continue.
- conventional film packaging also have, such as high mechanical strength, water and oxygen barrier, good optical properties.
- the packaging is particularly advantageous for use with piece goods, especially for stacked units, such as e.g. Biscuits, packets of cigarettes or pressed food moldings.
- the foil with the perforation enables a novel packaging solution for cigarette rods.
- the packets of cigarettes are stacked and wrapped in the film with the perforation according to the invention. These cigarette rods can then be opened at the predetermined breaking point by breaking along the perforation line.
- a transparent three-layer ABA film with a symmetrical structure with a total thickness of 20 ⁇ m was produced by coextrusion and subsequent stepwise orientation in the longitudinal and transverse directions.
- the cover layers had a thickness of 0.6 ⁇ m in each case.
- a top layers :
- the film was then coated on a surface with a sealable acrylate coating.
- the film was then cut to 350mm width into narrow cuts and wound up. These narrow cuts (rolls) were passed in a second step on a needled rollers and provided in the longitudinal direction of the film with perforation lines, which were arranged in parallel at a distance of 6mm.
- the perforation had a propeller-like shape with a length B of 4 mm. The distances between the individual perforations was 2mm.
- the thus perforated film was wound up into a roll of perforated film.
- the perforated film was then used for a bar wrap with 12 cigarette sachets.
- the packets were arranged so that the edges of the packets were at the level of the perforation line.
- the packets could be removed by breaking along the perforation line, without causing uncontrolled crack propagation in the film.
- a single-row perforation was applied to the film described in Example 1 with a similar needle roller.
- the perforations were the same length and spacing as in Example 1.
- the film was used in the same way for the bar wrap of 12 cigarette sachets.
- the packaging could not be opened by breaking. When attempting to tear the film along the perforation line, 3 out of 10 attempts led to an uncontrolled tear along the perforation line.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Laminated Bodies (AREA)
- Packages (AREA)
- Packaging Of Annular Or Rod-Shaped Articles, Wearing Apparel, Cassettes, Or The Like (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
Die vorliegende Erfindung betrifft eine Verwendung einer biaxial orientierten Folienrolle nach Anspruch 1 und eine Zigarettenstange nach Anspruch 7.The present invention relates to a use of a biaxially oriented film roll according to
Der Erfolg biaxial orientierter Kunststoffolien, insbesondere von Folien aus thermoplastischen Polymeren und speziell der biaxial orientierten Polypropylenfolien beruht im wesentlichen auf ihren hervorragenden mechanischen Festigkeitseigenschaften in Verbindung mit einem vergleichsweise geringen Gewicht, guten Sperreigenschaften und einer guten Verschweißbarkeit. Die Polyolefinfolie schützt das Packgut gegen schnelles Austrocknen bzw. gegen Verlust von Aromen bei sehr geringem Materialeinsatz.The success of biaxially oriented plastic films, particularly thermoplastic polymer films, and especially biaxially oriented polypropylene films, is essentially due to their excellent mechanical strength properties in conjunction with comparatively low weight, good barrier properties and good weldability. The polyolefin film protects the packaged goods against rapid drying or loss of flavor with very low material usage.
Dem Bedürfnis des Verbrauchers nach einer hygienischen, optisch ansprechenden, fest verschlossenen und widerstandsfähigen Verpackung steht der Wunsch eines leichten und kontrollierbaren Öffnens entgegen. Letzteres wird von Verbrauchern bei den Verpackungen aus Polyolefinfolien bemängelt und als Nachteil gegenüber Verpackungen aus Papier angesehen.The desire of the consumer for a hygienic, visually appealing, tightly closed and resistant packaging is opposed to the desire for an easy and controllable opening. The latter is criticized by consumers in the packaging of polyolefin films and regarded as a disadvantage compared to paper packaging.
Uniaxial orientierte Folien zeigen in Orientierungsrichtung eine niedrige Einreißfestigkeit und lassen sich in diese Richtung problemlos kontrolliert ein- und weiterreißen. Uniaxial orientierte Folien sind jedoch für viele Gebiete nicht einsetzbar, unter anderem auf Grund mangelhafter mechanischer Festigkeiten in Querrichtung. Die biaxiale Orientierung erzeugt einerseits die wünschenswerten hohe Festigkeiten (Moduli) in beiden Dimensionen; auf der anderen Seite werden dadurch aber auch die Vorzugsrichtungen egalisiert. Dies hat zur Folge, daß zum Öffnen einer Folienverpackung (z.B. Keksbeutel) zunächst eine hohe Kraft überwunden werden muß, um die Folie einzureißen. Ist die Folie jedoch einmal verletzt bzw. angerissen, so pflanzt sich ein Riß schon bei Anwendung sehr niedriger Zugkräfte unkontrollierbar fort. Diese mangelhaften Gebrauchseigenschaften durch eine zu hohe Einreißfestigkeit in Verbindung mit einer sehr niedrigen Weiterreißfestigkeit vermindern - trotz der eingangs erwähnten Vorteile - die Akzeptanz von Folienverpackungen am Endverbrauchermarkt.Uniaxially oriented films show a low tear strength in the direction of orientation and can be easily controlled in this direction and tear further. However, uniaxially oriented films are not usable in many fields, among other things due to insufficient transverse mechanical strengths. The biaxial orientation, on the one hand, produces the desirable high strengths (moduli) in both dimensions; on the other hand, but also the preferred directions are equalized. This has the consequence that for opening a film package (eg biscuit bag) first a high force must be overcome in order to tear the film. However, once the film has been injured or scratched, a crack will be planted even when using very low tensile forces uncontrollably continued. These inadequate service properties due to an excessively high tear strength in combination with a very low tear strength reduce the acceptance of film packaging in the end consumer market, despite the advantages mentioned at the outset.
Im Stand der Technik wurde vorgeschlagen die Folie mit einer Sollbruchstelle zu versehen. Beim Öffnen reißt die Folie in dieser Sollbruchstelle ein. Der Riß pflanzt sich dennoch häufig sehr unkontrolliert fort, da diese Lösungen zwar das Einreißen erleichtern aber beim kontrollierten Weiterreißen nicht wirklich helfen.In the prior art it has been proposed to provide the film with a predetermined breaking point. When opening, the film breaks in this predetermined breaking point. Nevertheless, the crack often propagates very uncontrolled, since these solutions facilitate tearing but do not really help with controlled tearing.
Eine weitere, bekannte mögliche Lösung ist der mechanische Einbau einer Sollbruchstelle in Form einer Perforation oder Einkerbungen entlang einer gedachten Öffnungslinie. Häufig stellt aber auch eine solche Perforation ein kontrolliertes Aufreißen nicht sicher. Beim Öffnen folgt der Riß nur anfänglich der Perforationslinie und setzt sich dann aber beliebig abweichend im Material fort.Another known possible solution is the mechanical installation of a predetermined breaking point in the form of a perforation or notches along an imaginary opening line. Often, however, such a perforation does not ensure a controlled tearing. When opening the crack follows only initially the perforation line and then continues but arbitrarily divergent in the material.
Dieses unkontrollierte Weiterreißverhalten ist insbesondere bei biaxial orientierten Polypropylenfolien problematisch, da die Weiterreißfestigkeit bei diesem Material besonders schwach ist. Dieses Problem stört besonders bei Verpackungen mit Stückgut, welches nicht lose, sondern geordnet verpackt ist, wie z.B. bei Zigarettenstangen, Weetabix, Knäckebrot, Keksrollen und ähnliches. Diese Verpackungsarten sind besonders darauf abgestellt, daß der Verbraucher zunächst nur einzelne Stücke entnehmen und den verbleibenden Rest in der Verpackung aufbewahren möchte, um weitere Einheiten zu einem späteren Zeitpunkt zu entnehmen. Für diesen Anwendungsfall ist das unkontrollierte Weiterreißen der Folienverpackung besonders ärgerlich für den Verbraucher.This uncontrolled tear propagation behavior is particularly problematic in biaxially oriented polypropylene films, since the tear propagation resistance is particularly weak in this material. This problem is particularly troublesome for packages with general cargo, which is not loose, but packaged orderly, such as cigarette rods, Weetabix, crispbread, biscuit rolls and the like. These types of packaging are particularly designed to ensure that the consumer initially only picks individual pieces and wants to store the remainder of the package in order to remove more units at a later date. For this application, the uncontrolled tear propagation of the film packaging is particularly annoying for the consumer.
Die
Zusätzlich muss die perforierte Folie eine hinreichende mechanische Stabilität aufweisen, damit die perforierte Folie zum Verpacken der Stückgüter verwendet werden kann. Es sind im Stand der Technik Verfahren beschrieben bei denen die Perforierung als Verarbeitungsschritt in den Packprozeß integriert ist. Diese Lösung vermeidet jegliche mechanische Belastungen der perforierten Folie, z.B. beim Aufwickeln und Abwickeln. Die Integration der Perforierung ist jedoch nicht bei allen Packprozessen möglich. Zum einen sind die räumlichen Gegebenheiten bei vorhandenen Anlagen oft so gestaltet, dass schlichtweg kein Platz ist um einen eine solche Vorrichtung anzubauen. Des weiteren laufen die Packprozesse in der Zigarettenindustrie mit sehr hohen Geschwindigkeiten, die für die Perforation möglicherweise zu schnell ist. Daher ist es nicht immer möglich in eine Anlage für den Stangeneinschlag von Zigarettenpäckchen eine Vorrichtung zum Perforieren der Folie zu integrieren. Einer hinreichenden mechanischen Stabilität der Folie steht jedoch dem gleichzeitig Wunsch nach einer leicht zu öffnenden Verpackung entgegen.In addition, the perforated film must have sufficient mechanical stability so that the perforated film can be used to package the piece goods. There are described in the prior art method in which the perforation is integrated as a processing step in the packing process. This solution avoids any mechanical stresses on the perforated film, e.g. when winding and unwinding. However, the integration of the perforation is not possible in all packaging processes. Firstly, the spatial conditions in existing systems are often designed so that there is simply no room to grow such a device. Furthermore, the packaging processes in the cigarette industry are running at very high speeds, which may be too fast for the perforation. Therefore, it is not always possible to incorporate a device for perforating the foil into a device for bar wrapping cigarette packets. A sufficient mechanical stability of the film is contrary to the same desire for an easy-open packaging.
Die
Die Aufgabe der vorliegenden Erfindung bestand nun darin, eine verbesserte Verpackung für geordnetes Stückgut zur Verfügung zu stellen.The object of the present invention was to provide an improved package for ordered cargo available.
Die der Erfindung zugrundeliegende Aufgabe wird gelöst durch die Verwendung einer biaxial orientierten Folienrolle aus Polypropylen nach Anspruch 1.The object underlying the invention is achieved by the use of a biaxially oriented film roll of polypropylene according to
Die Aufgabe wird des weiteren gelöst durch eine Zigarettenstange nach Anspruch 7.
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zeigt eine Ausführungsform der Folie (2) mit kreisförmigen Dünnstellen (1) mit einer Länge (Durchmesser) B. Die Länge der Abstände zwischen den Dünnstellen entspricht der Länge A. Beide parallel verlaufenden Dünnstellenlinien sind in einem Abstand von C zueinander angeordnet. In der Ausführungsform gemäßFigur 1Fig. 1 sind die Abstände A genauso lang wie die Länge der Dünnstellen B. Die Dünnstellenlinie sind so versetzt zueinander angeordnet, daß die Mitte der jeweiligen Dünnstelle mit der Mitte des gegenüberliegenden Abstandes fluchtet. -
zeigt eine Folie mit kreisförmigen Dünnstellen deren Länge B größer ist als die Abstände A.Figur 2 -
Figur 3 zeigt Dünnstellen mit einer rechteckigen Geometrie, wobei auch hier B>A ist. -
Fig. 4 zeigt eine nicht erfindungsgemäße Folie mit rautenförmigen Perforationen, wie sie beispielsweise durch rotierende Messer erzeugt werden. -
Fig. 5 zeigt eine Folie mit ellipsenförmigen Dünnstellen. Auch hier ist B>A. -
Fig. 6 zeigt eine mögliche Geometrie einer nicht erfindungsgemäßen Nadelperforation, bei der propellerartige Perforationen entstehen. -
Fig. 7 zeigt eine Folienbahn, die mehrere Dünnstellendoppellinien in Längsrichtung aufweist. -
Fig. 8 zeigt eine Stückgutverpackung (3), welche durch Abbrechen entlang der Dünnstellendoppellinie (4) geöffnet wird.
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FIG. 1 shows an embodiment of the film (2) with circular thin points (1) with a length (diameter) B. The length of the distances between the thin locations corresponds to the length A. Both parallel thin lines are arranged at a distance from each other C. In the embodiment according toFig. 1 the distances A are the same length as the length of the thin spots B. The thin line are arranged offset from one another so that the center of the respective thin spot is aligned with the center of the opposite distance. -
FIG. 2 shows a film with circular thin points whose length B is greater than the distances A. -
FIG. 3 shows thin areas with a rectangular geometry, where again B> A. -
Fig. 4 shows a non-inventive film with diamond-shaped perforations, such as those produced by rotating knives. -
Fig. 5 shows a film with elliptical thin areas. Again, B> A. -
Fig. 6 shows a possible geometry of a non-inventive needle perforation in which arise propeller-like perforations. -
Fig. 7 shows a film web having a plurality of thin-point double lines in the longitudinal direction. -
Fig. 8 shows a package (3), which is opened by breaking along the thin line double line (4).
Allen diesen Ausführungsformen gemäß den
Die beiden parallel verlaufenden, versetzt angeordneten Dünnstellenlinien bilden eine Sollbruchstelle in der Folie, in welcher sich ein Riß nach dem Einreißen sehr kontrolliert fortpflanzt. Der Riß läuft nach dem Einreißen entlang einer der Dünnstellenlinie oder zwischen den beiden parallel angeordneten Dünnstellenlinien kontrolliert weiter. Die Folienverpackung wird nur soweit wie gewünscht geöffnet.The two parallel, staggered thin-point lines form a predetermined breaking point in the film, in which a crack propagates very controlled after tearing. The tear continues to run after tearing along one of the thin-line or between the two parallel thin-line lines controlled. The foil packaging is opened only as far as desired.
Die erfindungsgemäße Verpackung ist insbesondere für geordnetes oder gestapeltes Stückgut, z.B. Zigarettenpäckchen, geeignet. Es wird dem Verbraucher möglich, die Folie längs einer vorgegebenen Sollbruchstelle derart einzureißen, das einzelne Stücke entnommen werden können, ohne daß im Falle von Stückgut weitere Einheiten unkontrolliert herausfallen. Die einzelnen Segmente zwischen den parallelen Dünnstellenlinien werden entsprechend der Größe der zu entnehmenden Einheit angepaßt. Damit kann gesteuert werden, ob mit einem Öffnen eine oder mehrere Einheiten bequem zu entnehmen sind.The packaging according to the invention is particularly suitable for ordered or stacked piece goods, e.g. Cigarette packet, suitable. It is possible for the consumer to tear the film along a predetermined predetermined breaking point in such a way that individual pieces can be removed without further units falling out uncontrollably in the case of piece goods. The individual segments between the parallel thin-line lines are adapted according to the size of the unit to be removed. This can be used to control whether one or more units can be conveniently removed by opening.
Die Dünnstellenlinien können in einem geeigneten Muster auf die Folienbahn aufgebracht werden. Vorzugsweise verlaufen die Linien gerade. Es ist jedoch auch möglich die Linie mit einer beliebigen geometrischen Form aufzubringen, damit die Sollbruchstelle später der Form und den Abmessungen des verpackten Stückguts entspricht.The thin-line lines can be applied to the film web in a suitable pattern. Preferably, the lines are straight. However, it is also possible to apply the line with any geometric shape, so that the predetermined breaking point later the shape and dimensions of packaged piece goods corresponds.
Unter Dünnstellen werden im Sinne der vorliegenden Erfindung Dünnstellen verstanden, bei denen kein durchgehendes Loch in der Folie erzeugt wird, sondern die Folie an den entsprechenden Stellen durch Materialabtrag nur dünner wird, beispielsweise durch einen Laserstrahl der nur bis zu einer vorgegebenen Tiefe eindringt. Bei diesen Ausführungsformen bleiben 10 bis 80% der ursprünglichen Foliendicke, vorzugsweise 20 bis 60% der ursprünglichen Foliendicke im Bereich der Dünnstelle erhalten. Auf diese Weise bleibt eine geschlossene Verpackung erhalten, die weiterhin allen hygienischen Anforderungen entspricht und deren Barriereeigenschaften nicht beeinträchtigt sind.For the purposes of the present invention, thin locations are understood as meaning thin areas in which no continuous hole is produced in the film, but the film only becomes thinner at the corresponding points due to removal of material, for example by a laser beam which only penetrates to a predetermined depth. In these embodiments, 10 to 80% of the original film thickness, preferably 20 to 60% of the original film thickness in the region of the thin location remain. In this way, a closed package is obtained, which continues to meet all hygienic requirements and their barrier properties are not impaired.
Entlang der Dünnstellenlinie folgen auf Dünnstellen (Dünnstellen B) im Wechsel unbeschädigte Folienabschnitte, deren Länge A durch den Abstand der Dünnstellen vorgegebenen wird. Abstände sind im Sinne der vorliegenden Erfindung somit die Bereiche ungeschädigter Folie, die vom Ende einer Dünnstelle bis zum Beginn der darauffolgenden Dünnstelle in der gleichen Dünnstellenlinie reichen.Along the thin-point line thin sections (thin sections B) are followed by undamaged sections of film whose length A is determined by the distance of the thin places. Distances are for the purposes of the present invention thus the areas of undamaged film, ranging from the end of a thin spot to the beginning of the subsequent thin spot in the same thin line.
Die geometrische Form der Dünnstelle kann variieren und hängt von der Dünnstellenmethode ab. Für Dünnstellenlinien aus nicht-durchgehenden Dünnstellen sind Laser oder Ultraschall bevorzugt. Nadel-Perforationen erzeugen kreis- oder ellipsen-förmige oder propellerartige Formen, die dadurch entstehen, dass Nadel und Folie bei der Perforation in Kontakt sind und sich relativ zu einander bewegen. Messer erzeugen mehr rechteckige oder rautenförmige Dünnstellen. Laser- und Ultraschallmethoden ermöglichen verschiedene geometrische Formen. Außer bei kreisförmigen Dünnstellen haben alle Dünnstellen eine größere Ausdehnung in eine der beiden grundsätzlichen Richtungen (Längsrichtung), die entlang der Dünnstellenlinie ausgerichtet ist.The geometric shape of the thin site may vary and depends on the thin point method. For thin-site lines from non-continuous thin sites, laser or ultrasound is preferred. Needle perforations create circular or ellipsoidal or propeller-like shapes that result from the needle and foil contacting each other at the perforation and moving relative to each other. Knives produce more rectangular or diamond-shaped thin spots. Laser and ultrasound methods allow different geometric shapes. Except for circular thin spots, all thin spots have a greater extension in one of the two fundamental directions (longitudinal direction) aligned along the thin line.
Die Dünnstellen haben in besagte Längsrichtung im allgemeinen eine Länge B von 0,1 - 8mm, vorzugsweise 0,3 bis 6mm, insbesondere 0,5 bis 3mm. Die Ausdehnung der Dünnstelle quer zu dieser Längsrichtung ist entsprechend kleiner und beträgt im allgemeinen 5 bis 80%, vorzugsweise 10 bis 50% ihrer Ausdehnung in Längsrichtung. Dies gilt nicht für kreisförmige Dünnstellen. Kreisförmige und in etwa kreisförmige Dünnstellen haben einen Durchmesser von 0,1 - 6mm, vorzugsweise 0,3 bis 5mm, wobei in diesem Fall der Durchmesser der Länge der Dünnstelle B entspricht.The thinnings have in the longitudinal direction generally a length B of 0.1 to 8 mm, preferably 0.3 to 6 mm, in particular 0.5 to 3 mm. The extent of the thin point transversely to this longitudinal direction is correspondingly smaller and is generally 5 to 80%, preferably 10 to 50% of its extension in the longitudinal direction. This does not apply to circular thin areas. Circular and approximately circular thin bodies have a diameter of 0.1-6 mm, preferably 0.3 to 5 mm, in which case the diameter corresponds to the length of the thin body B.
Für eine besonders niedrige Einreißkraft sind insbesondere Dünnstellen mit einer Länge von >1 bis 6mm bevorzugt, insbesondere auch Längen von 1,5 bis 6mm oder 2 bis 4mm geeignet. Überraschenderweise sind auch bei diesen vergleichsweise großen oder langen Dünnstellen die mechanischen Festigkeiten der Folie nicht beeinträchtigt. Auch diese Ausführungsformen lassen sich hervorragend zu einer Folienrolle aufwickeln und an der Packmachine problemlos wieder abwickeln.For a particularly low tearing force, in particular thin sites with a length of> 1 to 6 mm are preferred, in particular also lengths of 1.5 to 6 mm or 2 to 4 mm are suitable. Surprisingly, the mechanical strengths of the film are not affected even in these comparatively large or long thin areas. These embodiments can be excellent to wind up a film roll and unwind easily on the packing machine again.
Die Länge A der Abschnitte, d.h. der unbeschädigten Folie zwischen den Dünnstellen beträgt 0,05 bis <8mm, vorzugsweise 1 bis 6mm. Für Ausführungsformen mit langen Dünnstellen von beispielsweise 1,5 bis 6mm sind Abstände von >4 bis 10mm bevorzugt. Die Dimensionen der Abständen A werden im Verhältnis zur Länge B der Dünnstelle so ausgewählt, daß diese Länge B der Dünnstellen mindestens genauso groß oder größer als die Abstände A sind. Im allgemeinen ist die Länge oder der Durchmesser einer Dünnstelle mindestens 10% größer als die Länge der Abstände. Im allgemeinen beträgt die Länge A der Abstände 10 bis 90% der Länge B der Dünnstellen, vorzugsweise 20 bis 85%.The length A of the sections, i. the undamaged film between the thin points is 0.05 to <8mm, preferably 1 to 6mm. For embodiments with long thinnings of, for example, 1.5 to 6 mm, distances of> 4 to 10 mm are preferred. The dimensions of the distances A are selected in relation to the length B of the thin spot so that this length B of the thin sites are at least as large or larger than the distances A. In general, the length or diameter of a thin spot is at least 10% greater than the length of the gaps. In general, the length A of the gaps is 10 to 90% of the length B of the thin spots, preferably 20 to 85%.
Die angegebenen Dimensionen für die Dünnstellen und Abstände gelten in gleicher Weise auch für Dünnstellen die kreisförmig, ellipsenförmig oder länglich geformt sein können.The dimensions given for the thin locations and distances apply in the same way also for thin bodies which are circular, elliptical or can be elongated.
Entlang einer Linie sind die Dimensionen der Abstände zwischen den Dünnstellen im allgemeinen konstant, oder variieren nur geringfügig im Rahmen der üblichen Fertigungsgenauigkeit. In gleicher Weise variiert die Größe der einzelnen Dünnstelle entlang einer Linie nicht oder nur geringfügig (bis zu 10%) d.h. beispielsweise ist der Durchmesser der Löcher oder die Länge einer Dünnstelle konstant. Ebenso haben die Dünnstellen und Abstände der beiden parallelen Dünnstellenlinien einer Sollbruchstelle in etwa gleiche Dimensionen.Along a line, the dimensions of the distances between the thin spots are generally constant, or vary only slightly within the usual manufacturing accuracy. Likewise, the size of each thin spot along a line does not or only slightly varies (up to 10%). For example, the diameter of the holes or the length of a thin spot is constant. Likewise, the thin points and distances of the two parallel thin-line lines of a predetermined breaking point have approximately the same dimensions.
Es ist erfindungswesentlich, daß eine vorgesehene Sollbruchstelle aus zwei parallel verlaufenden Dünnstellenlinien gebildet wird, die in einer Distanz C von maximal 10mm angeordnet sind. Vorzugsweise beträgt die Distanz C dieser beiden Linien 0,5 bis 8 mm, insbesondere 0,8 bis 5mmIt is essential to the invention that an intended breaking point is formed from two thin lines running in parallel, which are arranged at a distance C of not more than 10 mm. The distance C of these two lines is preferably 0.5 to 8 mm, in particular 0.8 to 5 mm
Das zweite erfindungswesentliche Merkmal der Sollbruchstelle ist die Anordnung der Dünnstellen der beiden parallelen Dünnstellenlinien zueinander. Es wurde gefunden, daß eine versetzte Anordnung der Dünnstellen der beiden Linien die Kontrolle der Rißfortpflanzung überraschende verbessert. Bei dieser versetzten Anordnung beginnt eine Dünnstelle der zweiten Linie nicht auf derselben Höhe wie die gegenüberliegende Dünnstelle der ersten Linie. Dadurch deckt die Dünnstelle der zweiten Linie den Abstand der ersten Dünnstellenlinie mindestens teilweise ab. In bevorzugten Ausführungsformen, insbesondere solchen bei denen die Dünnstellen größer als die Abstände sind, werden die Abschnitte der einen Dünnstellenlinie vollständig von den Dünnstellen der gegenüberliegenden Linien abgedeckt.The second essential feature of the predetermined breaking point according to the invention is the arrangement of the thin places of the two parallel thin-layer lines to each other. It has been found that staggered placement of the thin spots of the two lines improves the control of crack propagation surprisingly. In this staggered arrangement, a thin spot of the second line does not start at the same height as the opposite thin spot of the first line. As a result, the thin point of the second line at least partially covers the distance of the first thin-line line. In preferred embodiments, especially those in which the thin spots are larger than the spacings, the sections of the one thin line are completely covered by the thin spots of the opposite lines.
In einer bevorzugten Ausführungsform fluchtet die Mitte der Abschnitte der ersten Dünnstellenlinie mit der Mitte der jeweils gegenüberliegenden Dünnstellen der zweiten Dünnstellenlinie, so daß ein symmetrisches Dünnstellenmuster entsteht.In a preferred embodiment, the center of the sections of the first thin line is aligned with the center of the respective opposite thin points of the second thin line, so that a symmetrical Thin-point pattern arises.
Überraschenderweise verbessert die Anordnung von zwei parallelen, zueinander versetzten Dünnstellenlinien die Kontrolle des Rißverlaufes erheblich. Die Erfindung ermöglicht auch ein Abbrechen der Verpackung an der Sollbruchstelle über die Kanten des Stückgutes, wenn das Stückgut eine entsprechende mechanische Stabilität aufweist und das Stückgut in der Verpackung so angeordnet ist, daß dessen Kante in Höhe der Doppellinie verläuft.Surprisingly, the arrangement of two parallel, staggered thin-line lines significantly improves the control of the crack profile. The invention also makes it possible to break off the packaging at the predetermined breaking point over the edges of the piece goods if the piece goods have a corresponding mechanical stability and the piece goods in the package is arranged so that its edge extends at the level of the double line.
Die Dünnstellenlinien werden im allgemeinen in Maschinenlaufrichtung der Folie aufgebracht. Dies kann gleichzeitig mit dem Zuschneiden der Folie auf schmälere Folienbreiten kombiniert und somit in einem Arbeitsgang durchgeführt werden. Alternativ kann das auch vor oder nach dem Zuschneiden auf die fertige Folienbreite erfolgen. In allen diesen Verfahrensvarianten kann die Folie beispielsweise über Walzen mit geeigneten Werkzeugen geführt, beispielsweise sind diese Walzen mit Messerklingen bestückt. Bei Anwendung von Laser- oder Ultraschall zur Erzeugung der Dünnstellensind entsprechende Werkzeuge unter oder oberhalb der Folienbahn positioniert. In diesen Verfahren wird die Folie von einer Rolle abgewickelt, die erfindungsgemäßen Dünnstellen werden angebracht und die mit Dünnstellen versehene Folie wird anschließend wieder aufgewickelt und die Rolle an den Anlagen zur Verpackung von Stückgütern verwendet, d.h. abgewickelt und zum Einschlagen der Güter verwendet. Überraschenderweise beinträchtigen die Dünnstellen das Wickelverhalten der Folie nicht oder nur unwesentlich, so dass die mit Dünnstellen versehene Folie mit den üblichen Vorrichtungen auf- und abgewickelt werden kann. Es zeigte sich auch überraschend, dass die erfindungsgemäßen Dünnstellen die mechanische Stabilität der Folie nicht derart beeinträchtigt, dass beim Auf- und Abwickeln der Folienabrisse, Folieneinrisse, Dickstellen oder Verdehnungen entstehen.The thin-line lines are generally applied in the machine direction of the film. This can be combined simultaneously with the cutting of the film to narrower film widths and thus be carried out in one operation. Alternatively, this can also be done before or after cutting to the finished film width. In all these variants of the method, the film can for example be guided over rollers with suitable tools, for example, these rollers are equipped with knife blades. When using laser or ultrasound to create the thin sites, corresponding tools are positioned below or above the film web. In these processes, the film is unwound from a roll, the thin spots according to the invention are applied, and the thinned film is subsequently rewound and the roll used at the general cargo packaging facilities, ie unwound and used for wrapping the goods. Surprisingly, the thin areas do not impair the winding behavior of the film or only insignificantly, so that the thin film provided with the usual devices can be wound up and unwound. It has also been found, surprisingly, that the thin areas according to the invention do not impair the mechanical stability of the film in such a way that the film breaks, film tears, thick places or thinnings arise during winding and unwinding.
Die Rolle aus mit Dünnstellen versehener Folie wird zur Herstellung der erfindungsgemäßen Verpackung verwendet. Die erfindungsgemäße Verpackung ist insbesondere für geordnetes oder gestapeltes Stückgut geeignet. Es wird dem Verbraucher möglich, die Folie längs einer vorgegebenen Sollbruchstelle derart einzureißen, daß einzelne Stücke entnommen werden können, ohne daß im Falle von Stückgut andere unkontrolliert herausfallen. Die einzelnen Segmente werden entsprechend der Größe der zu entnehmenden Einheit angepaßt. Damit kann gesteuert werden, ob nach dem Öffnen eine oder mehrere Einheiten bequem zu entnehmen sind.The roll of thinned film is used to make the package of the present invention. The packaging according to the invention is particularly suitable for ordered or stacked piece goods. It is possible for the consumer to tear the film along a predetermined predetermined breaking point in such a way that individual pieces can be removed without other uncontrolled fall out in the case of general cargo. The individual segments are adapted according to the size of the unit to be removed. This can be used to control whether one or more units can be conveniently removed after opening.
Als Folie wird im allgemeinen eine biaxial orientierte Folie aus Polypropylen eingesetzt. Die Folie kann je nach Art der Verpackung eine transluzente bis transparente oder eine opake Folie sein. "Opake Folie" bedeutet im Sinne der vorliegenden Erfindung eine undurchsichtige Folie, deren Lichtdurchlässigkeit (ASTM-D 1003-77) höchstens 70 %, vorzugsweise höchstens 50 %, beträgt. Die Folie kann grundsätzlich einschichtig oder mehrschichtig aufgebaut sein. Für die erfindungsgemäße Verpackung sind auch Laminate geeignet, welche vorzugsweise aus den hierin beschriebenen Folien aufgebaut sind.The film used is generally a biaxially oriented film of polypropylene. Depending on the type of packaging, the film can be a translucent to transparent or an opaque film. For the purposes of the present invention, "opaque film" means an opaque film whose light transmittance (ASTM-D 1003-77) is at most 70%, preferably at most 50%. The film can basically be constructed as a single layer or as a multilayer. Also suitable for the packaging according to the invention are laminates, which are preferably constructed from the films described herein.
Für transparente Ausführungsformen können die Rezeptur der Folie und die Art des Lasers so aufeinander abgestimmt werden, daß der Laserstrahl im Bereich der Ausdünnung eine weiße oder farbige Linie hinterläßt. Damit weist die Verpackung später eine erkennbare Markierung auf und zeigt dem Verbraucher an, wo der Riß zum Öffnen der Verpackung verlaufen soll, um ein bequemes Handling zu ermöglichen.For transparent embodiments, the formulation of the film and the type of laser can be coordinated so that the laser beam in the field of thinning leaves a white or colored line. Thus, the package later has a recognizable mark and indicates to the consumer where the crack to open the package to allow convenient handling.
Mögliche thermoplastische Kunststoffe für die Folie sind Polyolefine aus olefinischen Monomeren mit 2 bis 8 C-Atomen. Besonders geeignet sind Propylenpolymere, Ethylenpolymere, Butylenpolymere, Cycloolefinpolymere oder Mischpolymerisate aus Propylen-, Ethylen-, Butylen- Einheiten oder Cycloolefinen bevorzugt sind. Im allgemeinen enthalten die Schichten der Folie, bzw. die Schicht für einschichtige Ausführungsformen, mindestens 50 Gew.-%, vorzugsweise 70 bis 99 Gew.-%, insbesondere 90 bis 98 Gew.-%, des thermoplastischen Polymers, jeweils bezogen auf das Gewicht der Schicht.Possible thermoplastics for the film are polyolefins of olefinic monomers having 2 to 8 carbon atoms. Propylene polymers, ethylene polymers, butylene polymers, cycloolefin polymers or copolymers of propylene, ethylene, butylene units or cycloolefins are particularly suitable. In general, the layers of the film, or the layer for single-layer embodiments, at least 50 wt .-%, preferably 70 to 99 wt .-%, in particular 90 to 98 wt .-%, of the thermoplastic polymer, each by weight the layer.
Als Polyolefine sind Propylenpolymere bevorzugt. Diese Propylenpolymeren enthalten 90 bis 100 Gew.-%, vorzugsweise 95 bis 100 Gew.-%, insbesondere 98 bis 100 Gew.-%, Propylen und besitzt einen Schmelzpunkt von 120 °C oder höher, vorzugsweise 130 bis 170°C, und im allgemeinen einen Schmelzflußindex von 0,5 g/10 min bis 15 g/10 min, vorzugsweise 2 g/10 min bis 10 g/10 min, bei 230 °C und einer Kraft von 21,6 N (DIN 53 735). Isotaktisches Propylenhomopolymer mit einem ataktischen Anteil von 15 Gew.-% und weniger, Copolymere von Ethylen und Propylen mit einem Ethylengehalt von 10 Gew.-% oder weniger, Copolymere von Propylen mit C4-C8-Olefinen mit einem Olefingehalt von 10 Gew.-% oder weniger, Terpolymere von Propylen, Ethylen und Butylen mit einem Ethylengehalt von 10 Gew.-% oder weniger und mit einem Butylengehalt von 15 Gew.-% oder weniger stellen bevorzugte Propylenpolymere für die Kernschicht dar, wobei isotaktisches Propylenhomopolymer besonders bevorzugt ist. Die angegebenen Gewichtsprozente beziehen sich auf das jeweilige Polymere.As polyolefins, propylene polymers are preferred. These propylene polymers contain 90 to 100 wt .-%, preferably 95 to 100 wt .-%, in particular 98 to 100 wt .-%, of propylene and has a melting point of 120 ° C or higher, preferably 130 to 170 ° C, and im in general, a melt flow index of 0.5 g / 10 min to 15 g / 10 min, preferably 2 g / 10 min to 10 g / 10 min, at 230 ° C and a force of 21.6 N (DIN 53 735). Isotactic propylene homopolymer having an atactic content of 15% by weight and less, copolymers of ethylene and propylene having an ethylene content of 10% by weight or less, copolymers of propylene with C 4 -C 8 olefins having an olefin content of 10% by weight. % or less, terpolymers of propylene, ethylene and butylene having an ethylene content of 10% by weight or less and having a butylene content of 15% by weight or less are preferred propylene polymers for the core layer, with isotactic propylene homopolymer being particularly preferred. The stated percentages by weight relate to the respective polymer.
Des weiteren ist eine Mischung aus den genannten Propylenhomo- und/oder -copolymeren und/oder -terpolymeren und anderen Polyolefinen, insbesondere aus Monomeren mit 2 bis 6 C-Atomen, geeignet, wobei die Mischung mindestens 50 Gew.-%, insbesondere mindestens 75 Gew.-%, Propylenpolymerisat enthält. Geeignete andere Polyolefine in der Polymermischung sind Polyethylene, insbesondere HDPE, LDPE, VLDPE und LLDPE, wobei der Anteil dieser Polyolefine jeweils 15 Gew.-%, bezogen auf die Polymermischung, nicht übersteigt.Furthermore, a mixture of said propylene homo- and / or copolymers and / or terpolymers and other polyolefins, in particular from monomers having 2 to 6 carbon atoms, suitable, wherein the mixture at least 50 wt .-%, in particular at least 75 Wt .-%, containing propylene polymer. Suitable other polyolefins in the polymer blend are polyethylenes, especially HDPE, LDPE, VLDPE and LLDPE, wherein the proportion of these polyolefins each 15 wt .-%, based on the polymer mixture, does not exceed.
Gegebenenfalls kann eine Schicht, vorzugsweise die Basisschicht oder eine Zwischenschicht, der Folie für opake Ausführungsformen zusätzlich Pigmente und/oder vakuoleniniziierende Teilchen in jeweils üblichen Mengen enthalten.If appropriate, a layer, preferably the base layer or an intermediate layer, of the film for opaque embodiments may additionally contain pigments and / or vacuole-initiating particles in customary amounts.
Die erfindungsgemäße Folie kann einschichtig sein, vorzugsweise ist die Folie mehrschichtig. Hierfür können ein- oder beidseitig Zwischenschicht und/oder Deckschichten auf der Basisschicht aufgebracht sein. Entsprechend weisen mehrschichtige Ausführungsformen der Folie neben der Basisschicht, gegebenenfalls Zwischenschichten und Deckschichten auf.The film of the invention may be single-layered, preferably the film is multi-layered. For this purpose, one or both sides of the intermediate layer and / or cover layers may be applied to the base layer. Accordingly, multi-layered embodiments of the film in addition to the base layer, optionally intermediate layers and outer layers.
Diese zusätzlichen Deckschichten und/oder Zwischenschichten sind im allgemeinen aus Polyolefinen aufgebaut. Sie enthalten mindestens 70 Gew.-%, vorzugsweise 75 bis 100 Gew.-%, insbesondere 90 bis 98 Gew.-%, eines Polyolefinen. Als Polyolefinen für diese zusätzlichen Schichten sind grundsätzlich die gleichen Polymeren geeignet wie sie vorstehend für die Basisschicht beschrieben sind.These additional cover layers and / or intermediate layers are generally composed of polyolefins. They contain at least 70 wt .-%, preferably 75 to 100 wt .-%, in particular 90 to 98 wt .-%, of a polyolefins. As polyolefins for these additional layers are basically the same polymers as described above for the base layer.
Für die Deckschichten sind
Copolymer von
Ethylen und Propylen oder
Ethylen und Butylen oder
Propylen und Butylen oder
Ethylen und einem anderen Olefin mit 5 bis 10 Kohlenstoffatomen oder
Propylen und einem anderen Olefin mit 5 bis 10 Kohlenstoffatomen oder ein Terpolymer von
Ethylen und Propylen und Butylen oder
Ethylen und Propylen und einem anderen Olefin mit 5 bis 10 Kohlenstoffatomen oder
eine Mischungen oder Blends aus zwei oder mehreren der genannten Homo-, Co- und Terpolymeren geeignet.For the cover layers are
Copolymer of
Ethylene and propylene or
Ethylene and butylene or
Propylene and butylene or
Ethylene and another olefin having 5 to 10 carbon atoms or
Propylene and another olefin having 5 to 10 carbon atoms or a terpolymer of
Ethylene and propylene and butylene or
Ethylene and propylene and another olefin having 5 to 10 carbon atoms or
a mixture or blends of two or more of said homo-, co- and terpolymers suitable.
Hierunter sind
statistische Ethylen-Propylen-Copolymere mit
einem Ethylengehalt von 2 bis 10 Gew.-%, bevorzugt 5 bis 8 Gew.-%, oder statistische Propylen-Butylen-1-Copolymere mit
einem Butylengehalt von 4 bis 25 Gew.-%, bevorzugt 10 bis 20 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Copolymeren, oder
statistische Ethylen-Propylen-Butylen-1-Terpolymere mit
einem Ethylengehalt von 1 bis 10 Gew.-%, bevorzugt 2 bis 6 Gew.-%, und einem Butylen-1-Gehalt von 3 bis 20 Gew.-%, bevorzugt 8 bis 10 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Terpolymeren, oder
ein Blend aus einem Ethylen-Propylen-Butylen-1-Terpolymeren und einem Propylen-Butylen-1-Copolymeren
mit einem Ethylengehalt von 0,1 bis 7 Gew.-%
und einem Propylengehalt von 50 bis 90 Gew.-%
und einem Butylen-1-Gehalt von 10 bis 40 Gew.-%,
jeweils bezogen auf das Gesamtgewicht des Polymerblends,
besonders bevorzugt.Below are
ethylene-propylene random copolymers with
an ethylene content of 2 to 10 wt .-%, preferably 5 to 8 wt .-%, or random propylene-butylene-1 copolymers with
a butylene content of 4 to 25 wt .-%, preferably 10 to 20 wt .-%, each based on the total weight of the copolymer, or
ethylene-propylene-butylene-1-terpolymers with
an ethylene content of 1 to 10 wt .-%, preferably 2 to 6 wt .-%, and a butylene-1 content of 3 to 20 wt .-%, preferably 8 to 10 wt .-%, each based on the total weight of the terpolymer, or
a blend of an ethylene-propylene-butylene-1 terpolymer and a propylene-butylene-1 copolymer
with an ethylene content of 0.1 to 7% by weight
and a propylene content of 50 to 90 wt .-%
and a butylene-1 content of 10 to 40% by weight,
in each case based on the total weight of the polymer blend,
particularly preferred.
Die vorstehend beschriebenen Co- oder Terpolymeren weisen im allgemeinen einen Schmelzflußindex von 1,5 bis 30 g/10 min, vorzugsweise von 3 bis 15 g/10 min, auf. Der Schmelzpunkt liegt im Bereich von 120 bis 140 °C. Das vorstehend beschriebene Blend aus Co- und Terpolymeren hat einen Schmelzflußindex von 5 bis 9 g/10 min und einen Schmelzpunkt von 120 bis 150 °C. Alle vorstehend angegebenen Schmelzflußindices werden bei 230 °C und einer Kraft von 21,6 N (DIN 53 735) gemessen. Schichten aus Co- und/oder Terpolymeren bilden vorzugsweise die Deckschichten von siegelfähigen Ausführungsformen der Folie.The co- or terpolymers described above generally have a melt flow index of from 1.5 to 30 g / 10 min, preferably from 3 to 15 g / 10 min. The melting point is in the range of 120 to 140 ° C. The blend of copolymers and terpolymers described above has a melt flow index of 5 to 9 g / 10 min and a melting point of 120 to 150 ° C. All above-mentioned Schmelzflußindices are measured at 230 ° C and a force of 21.6 N (DIN 53 735). Layers of co- and / or terpolymers preferably form the outer layers of sealable embodiments of the film.
Die Gesamtdicke der Folie kann innerhalb weiter Grenzen variieren und richtet sich nach dem beabsichtigten Verwendungszweck. Die bevorzugten Ausführungsformen der Folie haben Gesamtdicken von 5 bis 250 µm, wobei 10 bis 100 µm, insbesondere 20 bis 80 µm, bevorzugt sind.The total thickness of the film can vary within wide limits and depends on the intended use. The preferred embodiments of the film have total thicknesses of 5 to 250 microns, with 10 to 100 .mu.m, in particular 20 to 80 microns, are preferred.
Die Basisschicht ist im Sinne der vorliegenden Erfindung diejenige Schicht, welche mehr als 50 % der Gesamtdicke der Folie ausmacht. Ihre Dicke ergibt sich aus der Differenz von Gesamtdicke und der Dicke der aufgebrachten Deck- und Zwischenschicht/en und kann daher analog der Gesamtdicke innerhalb weiter Grenzen variieren. Deckschichten bilden die äußerste Schicht der Folie und betragen 0,5 bis 5 µm, vorzugsweise 1 bis 3 µm. Die Zwischenschicht liegt zwischen 1 und 20 µm, vorzugsweise 1 bis 10 µm.For the purposes of the present invention, the base layer is the layer which makes up more than 50% of the total thickness of the film. Their thickness results from the difference between the total thickness and the thickness of the applied cover and intermediate layer (s) and can therefore vary within wide limits analogously to the total thickness. Cover layers form the outermost layer of the film and are 0.5 to 5 microns, preferably 1 to 3 microns. The intermediate layer is between 1 and 20 microns, preferably 1 to 10 microns.
Um bestimmte Eigenschaften der erfindungsgemäßen Polypropylenfolie noch weiter zu verbessern, können sowohl die Basisschicht als auch die Zwischenschicht/en und die Deckschicht/en Zusätze in einer jeweils wirksamen Menge enthalten, vorzugsweise Kohlenwasserstoffharz und/oder Antistatika und/oder Antiblockmittel und/oder Gleitmittel und/oder Stabilisatoren und/oder Neutralisationsmittel, die mit den Polymeren der Kernschicht und der Deckschicht/en verträglich sind, mit Ausnahme der in der Regel unverträglichen Antiblockmittel.In order to further improve certain properties of the polypropylene film according to the invention, both the base layer and the intermediate layer (s) and the topcoat (s) may contain additives in an effective amount, preferably hydrocarbon resin and / or antistatics and / or antiblocking agents and / or lubricants and / or or stabilizers and / or neutralizing agents which are compatible with the polymers of the core layer and the top layer (s), with the exception of the generally incompatible antiblocking agents.
Die Folien werden nach dem an sich bekannten Extrusionsverfahren hergestellt. Im Rahmen dieses Verfahrens werden die den einzelnen Schichten der Folie entsprechenden Schmelzen durch eine Flachdüse extrudiert. Die so erhaltene Folie wird zur Verfestigung auf einer oder mehreren Walze/n abgezogen und abgekühlt. Die Temperatur der Abzugswalze oder -walzen beträgt 10 bis 90 °C, bevorzugt 20 bis 60 °C.The films are produced by the extrusion process known per se. In the context of this process, the melts corresponding to the individual layers of the film are extruded through a flat die. The film thus obtained is stripped to solidify on one or more roll (s) and cooled. The temperature of the take-off roll or rollers is 10 to 90 ° C, preferably 20 to 60 ° C.
Anschließend wird die Folie biaxial gestreckt. Die biaxiale Streckung kann simultan oder aufeinanderfolgend durchgeführt werden, wobei die aufeinanderfolgende biaxiale Streckung, bei der zuerst längs (in Maschinenrichtung) und dann quer (senkrecht zur Maschinenrichtung) gestreckt wird, besonders günstig ist. In Längsrichtung wird vorzugsweise 3:1 bis 7:1 und bei einer Temperatur von weniger als 140 °C, vorzugsweise im Bereich von 125 bis 135 °C gestreckt. In Querrichtung wird vorzugsweise 5:1 bis 12:1, bei einer Temperatur von größer 140 °C, vorzugsweise bei 145 bis 160°C, gestreckt. Das Längsstrecken wird man zweckmäßigerweise mit Hilfe zweier entsprechend dem angestrebten Streckverhältnis verschieden schnellaufender Walzen durchführen und das Querstrecken mit Hilfe eines entsprechenden Kluppenrahmens. Grundsätzlich kann zur biaxialen Verstreckung auch simultan in Längs-Querrichtung verstreckt werden. Diese Simultanstreckverfahren sind an sich im Stand der Technik bekannt.Subsequently, the film is stretched biaxially. The biaxial stretching can be carried out simultaneously or sequentially, with the successive biaxial stretching in which stretching is first longitudinal (in the machine direction) and then transverse (perpendicular to the machine direction) is particularly favorable. In the longitudinal direction is preferably 3: 1 to 7: 1 and at a temperature of less than 140 ° C, preferably in the range of 125 to 135 ° C stretched. In the transverse direction is preferably 5: 1 to 12: 1, at a temperature of greater than 140 ° C, preferably at 145 to 160 ° C, stretched. The longitudinal stretching will be carried out expediently with the help of two different speeds corresponding to the desired stretching ratio and the transverse stretching with the aid of a corresponding clip frame. In principle, biaxial stretching can also be carried out simultaneously in the longitudinal transverse direction. These simultaneous stretching methods are known per se in the prior art.
Für die Thermofixierung (Wärmebehandlung) wird die Folie abschließend etwa 0,5 bis 10 s lang bei einer Temperatur von 110 bis 150 °C gehalten. Gegebenenfalls kann/können, wie oben erwähnt, nach der biaxialen Streckung eine oder beide Oberfläche/n der Folie nach einer der bekannten Methoden corona- oder flammbehandelt werden.For heat setting (heat treatment), the film is finally held at a temperature of 110 to 150 ° C for about 0.5 to 10 seconds. Optionally, as mentioned above, after biaxial stretching, one or both surfaces of the film may be corona or flame treated by one of the known methods.
Gegebenenfalls kann die Folie nach der Herstellung, aber vor der Perforierung, durch weitere Verarbeitungsschritte laminiert, beschichtet, schmelzebeschichtet, lackiert oder kaschiert werden, um der Folie weitere vorteilhafte Eigenschaften zu verleihen. Als Laminate sind Verbunde aus Polypropylenfolien und Polyethylenfolien besonders bevorzugt. Derartige Verbunde können durch Laminierung der einzelnen Folien hergestellt werden. Eine weitere technisch vorteilhafte Variante zur Herstellung von PP/PE Laminaten ist die Extrusionsbeschichtung eines geeigneten Polyethylens auf eine biaxial orientierte Polypropylenfolie. Derartige Extrusionsbeschichtungen sind im Stand der Technik an sich bekannt. Es wurde gefunden, daß Laminate aus PP/PE-Folien vorteilhaft bei der Behandlung mittels Laserstrahl sind und weniger leicht versehentlich perforiert werden.Optionally, after production but before perforation, the film may be laminated, coated, melt-coated, painted or laminated by further processing steps to provide the film with further advantageous properties. As laminates, composites of polypropylene films and polyethylene films are particularly preferred. Such composites can be produced by lamination of the individual films. Another technically advantageous variant for the production of PP / PE laminates is the extrusion coating of a suitable polyethylene onto a biaxially oriented polypropylene film. Such extrusion coatings are known per se in the prior art. It has been found that laminates of PP / PE films are advantageous in the treatment by laser beam and are less likely to be perforated by mistake.
Die Verpackung zeichnet sich durch ein kontrollierbares Reißverhalten aus. Gegebenenfalls kann die zur Initiierung eines Einrisses an der Folienkante benötigte Kraft durch eine Einkerbung, vorzugsweise V-förmig, herabgesetzt werden. Die Verpackung läßt sich wesentlicher leichter und kontrollierter weiterreißen. Darüber hinaus zeigt sie weiterhin alle Vorteile, die übliche Folienverpackungen auch aufweisen, wie hohe mechanische Festigkeit, Wasser- und Sauerstoffbarriere, gute optische Eigenschaften.The packaging is characterized by a controllable tear behavior. Optionally, the force required to initiate a tear at the foil edge can be reduced by a notch, preferably V-shaped. The packaging is much easier and more controlled to continue. In addition, it also shows all the advantages that conventional film packaging also have, such as high mechanical strength, water and oxygen barrier, good optical properties.
Die Verpackung ist besonders vorteilhaft für Stückgut zu verwenden, insbesondere für gestapelte Einheiten, wie z.B. Kekse, Zigarettenpäckchen oder gepreßte Nahrungsmittelformlinge.The packaging is particularly advantageous for use with piece goods, especially for stacked units, such as e.g. Biscuits, packets of cigarettes or pressed food moldings.
Die Folie mit der Perforation ermöglicht eine neuartige Verpackungslösung für Zigarettenstangen. Die Zigarettenpäckchen werden gestapelt und in die Folie mit der erfindungsgemäßen Perforation eingeschlagen. Diese Zigarettenstangen können dann an der Sollbruchstelle durch Abbrechen entlang der Perforationslinie geöffnet werden.The foil with the perforation enables a novel packaging solution for cigarette rods. The packets of cigarettes are stacked and wrapped in the film with the perforation according to the invention. These cigarette rods can then be opened at the predetermined breaking point by breaking along the perforation line.
Die Erfindung wird durch die nachfolgenden Beispiele näher erläutert:The invention is explained in more detail by the following examples:
Es wurde durch Coextrusion und anschließende stufenweise Orientierung in Längs- und Querrichtung eine transparente dreischichtige ABA Folie mit symmetrischem Aufbau mit einer Gesamtdicke von 20 µm hergestellt. Die Deckschichten hatten eine Dicke von jeweils 0,6 µm.A transparent three-layer ABA film with a symmetrical structure with a total thickness of 20 μm was produced by coextrusion and subsequent stepwise orientation in the longitudinal and transverse directions. The cover layers had a thickness of 0.6 μm in each case.
Die Herstellungsbedingungen in den einzelnen Verfahrensschritten waren:
Die Folie wurde anschließend auf einer Oberfläche mit einer siegelfähigen Acrylatbeschichtung beschichtet.The film was then coated on a surface with a sealable acrylate coating.
Die Folie wurde anschließend auf eine Breite von 350mm zu Schmalschnitten zugeschnitten und aufgewickelt. Diese Schmalschnitte (Rollen) wurden in einem zweiten Arbeitsschritt über eine mit Nadeln versehene Walzen geführt und dabei in Längsrichtung der Folie mit Perforationslinien versehen, die parallel in einem Abstand von 6mm angeordnet waren. Die Perforation hatten eine propellerartige Form mit einer Länge B von 4 mm. Die Abstände zwischen den einzelnen Perforationen betrug 2mm. Die so perforierte Folie wurde zu einer Rolle aus perforierter Folie aufgewickelt.The film was then cut to 350mm width into narrow cuts and wound up. These narrow cuts (rolls) were passed in a second step on a needled rollers and provided in the longitudinal direction of the film with perforation lines, which were arranged in parallel at a distance of 6mm. The perforation had a propeller-like shape with a length B of 4 mm. The distances between the individual perforations was 2mm. The thus perforated film was wound up into a roll of perforated film.
Die so perforierte Folie wurde anschließend für einen Stangeneinschlag mit 12 Zigarettenpäkchen verwendet. Die Päckchen wurden so angeordnet, daß sich die Kanten der Päckchen in Höhe der Perforationslinie befanden. Die Päckchen konnten durch Abrechen entlang der Perforationslinie entnommen werden, ohne daß es zu einer unkontrollierten Rißfortpflanzung in der Folie kam.The perforated film was then used for a bar wrap with 12 cigarette sachets. The packets were arranged so that the edges of the packets were at the level of the perforation line. The packets could be removed by breaking along the perforation line, without causing uncontrolled crack propagation in the film.
Es wurde an der in Beispiel 1 beschriebenen Folie mit einer gleichartigen Nadelwalze eine einreihige Perforation angebracht. Die Perforationen hatten die gleiche Länge und die gleichen Abstände wie in Beispiel 1. Die Folie wurde in der gleichen Weise für den Stangeneinschlag von 12 Zigarettenpäkchen verwendet. Die Verpackung konnte nicht durch Abrechen geöffnet werden. Beim Versuch die Folie entlang der Perforationslinie einzureißen kam es bei 3 von 10 Versuchen zu einem unkontrolliertem Weiterreißen neben der Perforationslinie.A single-row perforation was applied to the film described in Example 1 with a similar needle roller. The perforations were the same length and spacing as in Example 1. The film was used in the same way for the bar wrap of 12 cigarette sachets. The packaging could not be opened by breaking. When attempting to tear the film along the perforation line, 3 out of 10 attempts led to an uncontrolled tear along the perforation line.
Claims (7)
- Use of a biaxially oriented film roll of polypropylene with lines of thin areas for packaging rectangular cigarette packages, characterized in that the film has at least two lines of thin areas running parallel to one another, situated at a distance (C) of 10 mm at most, wherein the thin areas (1) of the two lines are arranged with an offset from one another, wherein there are intervals (2) of undamaged film between the thin areas (1), and the thin areas (1) are longer than or exactly as long as the intervals (2) between the thin areas (1), and the thin areas (1) comprise 10% to 80% of the remaining thickness of the film.
- Use of a polypropylene film roll according to claim 1, characterized in that the thin areas (1) are created by abrasion of material using a laser beam or ultrasound.
- Use of a polypropylene film roll according to claim 1, characterized in that the thin areas (1) are created by means of a blade and are in the form of diamonds or rectangles.
- Use of a polypropylene film roll according to claim 1, characterized in that the thin areas (1) are 0.1-8 mm long.
- Use of a polypropylene film roll according to claim 1, characterized in that the length of the intervals (A) between these thin areas (1) amounts to 10% to 95% of the length (B) of the thin areas (1) .
- Use of a polypropylene film roll according to claim 1, characterized in that the centers of the sections of the first line of a thin area are flush with the centers of the opposing thin areas in the second line of a thin area.
- Cigarette cartons, containing rectangular packs of cigarettes, comprising a biaxially oriented polypropylene film, characterized in that the film has at least two lines of thin areas running parallel to one another, situated at a maximum distance (C) of 10 mm, and wherein the thin areas (1) of the two lines are arranged with an offset from one another, wherein there are intervals (2) of undamaged film between the thin areas (1), and the thin areas (1) are longer than or exactly as long as the intervals (2) between the thin areas (1), wherein the thin areas constitute 10% to 80% of the remaining film thickness, and wherein the cigarette carton is manufactured by using any one of claims 1 to 6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL10752721T PL2470441T3 (en) | 2009-08-28 | 2010-08-26 | Use of a biaxially oriented film roll made of polypropylene for cigarette packages, and cigarette carton |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009039221 | 2009-08-28 | ||
| PCT/EP2010/005223 WO2011023385A1 (en) | 2009-08-28 | 2010-08-26 | Polypropylene film comprising an opening aid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2470441A1 EP2470441A1 (en) | 2012-07-04 |
| EP2470441B1 true EP2470441B1 (en) | 2018-10-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP10752721.0A Not-in-force EP2470441B1 (en) | 2009-08-28 | 2010-08-26 | Use of a biaxially oriented film roll made of polypropylene for cigarette packages, and cigarette carton |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20120152773A1 (en) |
| EP (1) | EP2470441B1 (en) |
| JP (1) | JP2013503080A (en) |
| KR (1) | KR20120059519A (en) |
| CN (1) | CN102498047B (en) |
| AU (1) | AU2010288875B2 (en) |
| BR (1) | BR112012004390A2 (en) |
| CA (1) | CA2771912A1 (en) |
| DE (1) | DE202010018143U1 (en) |
| EA (1) | EA023195B1 (en) |
| MX (1) | MX2012002474A (en) |
| PL (1) | PL2470441T3 (en) |
| UA (1) | UA115860C2 (en) |
| WO (1) | WO2011023385A1 (en) |
| ZA (1) | ZA201201384B (en) |
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|---|---|---|---|---|
| CN103097258B (en) | 2010-07-09 | 2015-02-18 | 洲际大品牌有限责任公司 | Packaging with breakable section structure for stacked product blocks |
| FR3014729B1 (en) | 2013-12-12 | 2016-08-26 | Francois Gosset | METHOD FOR MAKING A LINE OF LESS RESISTANCE ON A PLASTIC FILM |
| PL3186162T3 (en) | 2014-08-26 | 2019-05-31 | Jt Int Sa | Packaging film and method of manufacturing same |
| WO2016107902A1 (en) * | 2014-12-31 | 2016-07-07 | Philip Morris Products S.A. | Improved hinge lid container with lid flap |
| ES2619420B1 (en) * | 2015-11-24 | 2018-03-20 | Francisco RUIZ BERNAL | EXTENSIBLE POLYOLEFIN FILM OBTAINABLE BY THE UNION OF TWO OR MORE COEXTRUSIONED POLYOLEFIN COATS AND METHOD FOR OBTAINING |
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- 2010-08-26 JP JP2012525930A patent/JP2013503080A/en active Pending
- 2010-08-26 WO PCT/EP2010/005223 patent/WO2011023385A1/en not_active Ceased
- 2010-08-26 DE DE202010018143.7U patent/DE202010018143U1/en not_active Expired - Lifetime
- 2010-08-26 KR KR1020127005581A patent/KR20120059519A/en not_active Withdrawn
- 2010-08-26 EP EP10752721.0A patent/EP2470441B1/en not_active Not-in-force
- 2010-08-26 AU AU2010288875A patent/AU2010288875B2/en not_active Ceased
- 2010-08-26 EA EA201270329A patent/EA023195B1/en not_active IP Right Cessation
- 2010-08-26 BR BR112012004390A patent/BR112012004390A2/en not_active Application Discontinuation
- 2010-08-26 MX MX2012002474A patent/MX2012002474A/en unknown
- 2010-08-26 PL PL10752721T patent/PL2470441T3/en unknown
- 2010-08-26 CA CA2771912A patent/CA2771912A1/en not_active Abandoned
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20120059519A (en) | 2012-06-08 |
| AU2010288875A1 (en) | 2012-03-29 |
| EA023195B1 (en) | 2016-05-31 |
| WO2011023385A1 (en) | 2011-03-03 |
| DE202010018143U1 (en) | 2014-06-04 |
| CA2771912A1 (en) | 2011-03-03 |
| MX2012002474A (en) | 2012-03-26 |
| PL2470441T3 (en) | 2019-05-31 |
| AU2010288875B2 (en) | 2014-07-17 |
| CN102498047B (en) | 2015-07-29 |
| ZA201201384B (en) | 2012-10-31 |
| UA115860C2 (en) | 2018-01-10 |
| CN102498047A (en) | 2012-06-13 |
| BR112012004390A2 (en) | 2016-03-22 |
| US20120152773A1 (en) | 2012-06-21 |
| EP2470441A1 (en) | 2012-07-04 |
| EA201270329A1 (en) | 2012-08-30 |
| JP2013503080A (en) | 2013-01-31 |
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