EP2325355A1 - Anlage zur Herstellung elektrogesponnene Fasern - Google Patents
Anlage zur Herstellung elektrogesponnene Fasern Download PDFInfo
- Publication number
- EP2325355A1 EP2325355A1 EP10014817A EP10014817A EP2325355A1 EP 2325355 A1 EP2325355 A1 EP 2325355A1 EP 10014817 A EP10014817 A EP 10014817A EP 10014817 A EP10014817 A EP 10014817A EP 2325355 A1 EP2325355 A1 EP 2325355A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- capillaries
- head
- spinning
- linked
- fiber take
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001523 electrospinning Methods 0.000 title claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 238000009987 spinning Methods 0.000 claims abstract description 16
- 230000002572 peristaltic effect Effects 0.000 claims abstract description 8
- 239000004020 conductor Substances 0.000 claims abstract description 7
- 238000001125 extrusion Methods 0.000 claims abstract description 4
- 238000003303 reheating Methods 0.000 claims abstract description 3
- 230000007723 transport mechanism Effects 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 14
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002121 nanofiber Substances 0.000 description 6
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 230000005686 electrostatic field Effects 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 206010014405 Electrocution Diseases 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
Definitions
- the subject of the invention is the electrospinning fiber throwing system.
- Fiber throwing from polymer alloys or solutions using the electrospinning technique is based on the effects occurring in liquids and polymers under the influence of high voltage of specific polarity applied.
- the system containing a single capillary with a nozzle, being an electrode feeding a polymer alloy or solution, connected to a high-voltage generator and a grounded collector electrode placed under it was applied.
- the forces of the electrostatic field generated between the electrodes cause that a drop of polymer formed at the end of the nozzle undergoes a deformation into the so-called Taylor cone, which then, moving in the direction of the crown discharge current towards the grounded electrode, is accelerated and stretched to be finally collected on the surface of the collector electrode in the form of loosely packed fibers.
- the work aimed at improving the efficiency of the electrospinning process focused on a change in the mode of taking up formed fibers as well as in the mode of feeding a polymer alloy or solution.
- Electrostatics 2007 describes an electrospinning system where the take-up of formed fibers is done by means of rotary rollers, made from a conductive material, which are covered with subsequent fiber layers until the assumed thickness thereof is reached, while the patent description US 2009/00910655 A1 presents an electro spinning system in which formed fibers are taken up by rotating discs.
- the referenced alloy or solution was forced by compressed air or diffusion pumps.
- the foregoing techniques made it possible to isolate a polymer of high electric potential from the environment, thereby protecting system operators from electrocution, yet at the same time curbing the control of an amount of the extruded polymer and the time instability of the electro spinning process.
- the Czech company Elmarko used an electrospinning system in which a spinning feed roller, immersed in a polymer solution, rotated, being covered with polymer film, while the voltage applied thereto caused that trickles of the polymer detached from the surface of the roller and formed fibers precipitated on an unwoven cloth belt traveling over the roller.
- EP 1982735 A1 presents an electro spinning system in which a polymer is fed by several capillaries situated one by one in single file, while formed fibers are taken up by a rotating roller, located vertically.
- the invented electro spinning fiber throwing system equipped with vertically positioned spinning capillaries connected to a source of high voltage and a device taking up formed fibers, located under the extrusion nozzles of the capillaries and linked to a driving unit, is characterized by the solution according to which the spinning capillaries are fixed in a spinning head from a non-conducting material, inside which there is a separator from a conductive material, connected to each of the capillaries and kitted in high-voltage terminals.
- the head is mounted in a slidable manner, by means of a horizontal transport mechanism connected to the driving motor, on a horizontal guide whose ends are mounted slidably as well, by means of a vertical transport mechanism connected to the driving motor, on the upright arms of the system's load-bearing structure.
- the system is equipped with a multithreaded peristaltic pump, each thread of which being linked to one of the spinning capillaries placed on the horizontal arm of the load-bearing structure.
- the unit taking up formed fibers is an advantageously rotationally fixed roller or conveyor.
- the head contains minimum 32 capillaries, advantageously spaced in four rows, at an advantageous distance of 3 cm from each other in each row and 6 cm between the rows.
- the system contains an ancillary reheating element in the form of a drying tunnel, which makes it possible to evaporate dissolvent residue, collected at the outlet of the fiber take-up device, from formed fibers.
- the system is marked by a considerably higher efficiency of the fiber throwing process compared to the systems known hitherto. Furthermore, the hazard of operators' electrocution has been eliminated from the system.
- the subject of the invention is represented as a built model in a figure showing the system from a front view.
- the system is equipped with the 32 vertically situated spinning capillaries 1, fixed in the Teflon spinning head 2.
- the capillaries 1 are positioned in the four rows, at a distance of 3 cm from each other in each row and 6 cm between the rows.
- the head 2 has the built-in steel wool separator 3, linked to each of the capillaries 1 and kitted in the high-voltage terminals.
- the head 2 is mounted in a slidable manner, by means of the horizontal transport mechanism 4 connected to the driving motor, on the horizontal guide 5 whose ends are mounted slidably, by means of the vertical transport mechanism 7 connected to the driving motor, on the upright arms 6 of the system's load-bearing structure.
- the peristaltic pump 9 is filled with the polymer and the separator 3 is connected to the source of high voltage, thus starting the pumping of the polymer into the capillaries 1.
- the guide 5 with the head 2 is positioned at an adequate distance from the take-up roller 8 by means of the vertical transport mechanism 7.
- the horizontal motion range of the head 2 along the guide 5 so it can extend over the entire work area of the roller 8 is set up by means of the horizontal transport mechanism 4 and the unit driving the roller 8 is activated.
- the roller 8 is set in rotary motion
- the head 2 is set in horizontal motion along the guide 5 by means of the horizontal transport mechanism 4.
- Formed nanofibers are taken up on the grounded roller 8 in the form of unwoven cloth.
- the obtained layer of unwoven cloth desirably thick, passes through the drying tunnel whose outlet releases the finished product.
- the system was used for nanofiber throwing in the form of unwoven fabric from:
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL10014817T PL2325355T3 (pl) | 2009-11-24 | 2010-11-22 | Układ do formowania włókien metodą elektroprzędzenia |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL389660A PL217525B1 (pl) | 2009-11-24 | 2009-11-24 | Układ do formowania włókien metodą elektroprzędzenia |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2325355A1 true EP2325355A1 (de) | 2011-05-25 |
| EP2325355B1 EP2325355B1 (de) | 2012-11-21 |
Family
ID=43585612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP10014817A Not-in-force EP2325355B1 (de) | 2009-11-24 | 2010-11-22 | Anlage zur Herstellung elektrogesponnene Fasern |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP2325355B1 (de) |
| PL (2) | PL217525B1 (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105162004A (zh) * | 2015-06-17 | 2015-12-16 | 中国南方电网有限责任公司超高压输电公司柳州局 | 一种伸缩式隔离开关上导电臂更换工具 |
| CN112301792A (zh) * | 2020-06-30 | 2021-02-02 | 聚纳达(青岛)科技有限公司 | 一种新型工业滤纸及制备方法和高效生产装置 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004016839A1 (en) * | 2002-08-16 | 2004-02-26 | Samshin Creation Co., Ltd. | Apparatus for producing nanofiber utilizing electrospinning and nozzle pack for the apparatus |
| WO2006009854A2 (en) * | 2004-06-18 | 2006-01-26 | Yale University | Increase of electrospray throughput using multiplexed microfabricated sources for the scalable generation of monodisperse droplets |
| WO2006043968A2 (en) * | 2004-04-08 | 2006-04-27 | Research Triangle Institute | Electrospray/ electrospinning apparatus and method |
| WO2008069795A1 (en) * | 2006-12-05 | 2008-06-12 | Nanostatics Corporation | Electrospraying/electrospinning array utilizing a replaceable array of individual tip flow restrictors |
| EP1967617A1 (de) * | 2007-03-09 | 2008-09-10 | Universiteit Gent | Fasergebilde sowie Verfahren und Vorrichtungen zu ihrer Herstellung |
| EP1982735A1 (de) | 2000-11-17 | 2008-10-22 | Virginia Commonwealth University Intellectual Property Foundation | Elektroprozessiertes Kollagen |
-
2009
- 2009-11-24 PL PL389660A patent/PL217525B1/pl not_active IP Right Cessation
-
2010
- 2010-11-22 PL PL10014817T patent/PL2325355T3/pl unknown
- 2010-11-22 EP EP10014817A patent/EP2325355B1/de not_active Not-in-force
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1982735A1 (de) | 2000-11-17 | 2008-10-22 | Virginia Commonwealth University Intellectual Property Foundation | Elektroprozessiertes Kollagen |
| WO2004016839A1 (en) * | 2002-08-16 | 2004-02-26 | Samshin Creation Co., Ltd. | Apparatus for producing nanofiber utilizing electrospinning and nozzle pack for the apparatus |
| WO2006043968A2 (en) * | 2004-04-08 | 2006-04-27 | Research Triangle Institute | Electrospray/ electrospinning apparatus and method |
| WO2006009854A2 (en) * | 2004-06-18 | 2006-01-26 | Yale University | Increase of electrospray throughput using multiplexed microfabricated sources for the scalable generation of monodisperse droplets |
| WO2008069795A1 (en) * | 2006-12-05 | 2008-06-12 | Nanostatics Corporation | Electrospraying/electrospinning array utilizing a replaceable array of individual tip flow restrictors |
| EP1967617A1 (de) * | 2007-03-09 | 2008-09-10 | Universiteit Gent | Fasergebilde sowie Verfahren und Vorrichtungen zu ihrer Herstellung |
Non-Patent Citations (1)
| Title |
|---|
| "The Journal of Physics: Conference Series", ELECTROSTATICS, vol. 142, 2007, pages 012027 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105162004A (zh) * | 2015-06-17 | 2015-12-16 | 中国南方电网有限责任公司超高压输电公司柳州局 | 一种伸缩式隔离开关上导电臂更换工具 |
| CN105162004B (zh) * | 2015-06-17 | 2017-05-03 | 中国南方电网有限责任公司超高压输电公司柳州局 | 一种伸缩式隔离开关上导电臂更换工具 |
| CN112301792A (zh) * | 2020-06-30 | 2021-02-02 | 聚纳达(青岛)科技有限公司 | 一种新型工业滤纸及制备方法和高效生产装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| PL2325355T3 (pl) | 2013-03-29 |
| PL217525B1 (pl) | 2014-07-31 |
| PL389660A1 (pl) | 2011-06-06 |
| EP2325355B1 (de) | 2012-11-21 |
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