EP2290114A1 - Composant pour conduite d'eau - Google Patents
Composant pour conduite d'eau Download PDFInfo
- Publication number
- EP2290114A1 EP2290114A1 EP09010054A EP09010054A EP2290114A1 EP 2290114 A1 EP2290114 A1 EP 2290114A1 EP 09010054 A EP09010054 A EP 09010054A EP 09010054 A EP09010054 A EP 09010054A EP 2290114 A1 EP2290114 A1 EP 2290114A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- alloy
- weight
- less
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 21
- 239000000956 alloy Substances 0.000 claims abstract description 21
- 239000012535 impurity Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000005266 casting Methods 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 239000010949 copper Substances 0.000 claims abstract description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052759 nickel Inorganic materials 0.000 abstract description 8
- 239000011701 zinc Substances 0.000 abstract description 8
- 229910052725 zinc Inorganic materials 0.000 abstract description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 229910052787 antimony Inorganic materials 0.000 abstract description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229910000881 Cu alloy Inorganic materials 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910000914 Mn alloy Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- PDYXSJSAMVACOH-UHFFFAOYSA-N [Cu].[Zn].[Sn] Chemical compound [Cu].[Zn].[Sn] PDYXSJSAMVACOH-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/02—Alloys based on copper with tin as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/04—Alloys based on copper with zinc as the next major constituent
Definitions
- the present invention relates to a water-conducting component with a basic body produced by means of casting.
- a water-conducting component according to the present invention in particular a fitting, fitting, or pump housing is considered.
- water-bearing components can also be pipes.
- a water-conducting component in the context of the present invention basically every casting is considered, which leads water and comes into contact with this.
- the present invention relates to a development of this water-conducting component, which is made as a casting of a copper alloy.
- Copper alloys have always been used as gunmetal alloys for the production of water-bearing components. Common representatives are cast bronze alloys according to DIN EN 1982.
- the gunmetal alloy CuSn5Zn5Pb5 here with between 4 to 6 wt .-% tin, zinc and lead at a level of up to 2.0 wt .-% nickel and up to 0.1% by weight of phosphorus and as admixtures up to 0.3% by weight of iron and up to 0.25% by weight of antimony.
- this material is characterized by good castability and corrosion resistance to seawater. With regard to the release of metal ions into the water, however, this material must be regarded as unsatisfactory against the background of the future expected limit values.
- the high lead levy of CuSn5Zn5Pb5 is criticized.
- the DIN 50 930 T6 in its currently valid version prescribes a proportion of up to 3.0 wt .-% lead.
- the specified CuSn5Zn5Pb2-b casting alloy should contain between 84 and 88% by weight of copper, not more than 0.6% by weight of nickel, not more than 0.04% by weight of phosphorus, not more than Containing 6.0% by weight of tin and not more than 6.0% by weight of zinc. Tin and zinc are each contained at least 4 wt .-% in the alloy.
- the machinability of castings made with the alloy one skilled in the art will envision a certain amount of lead, not significantly below the stated upper limit of 3.0% by weight, in the alloy.
- the GB-1 443 090 discloses a dezincification-enhanced copper alloy having between 80 and 90 weight percent copper, between 6.3 and 17.5 weight percent zinc and between 2.8 and 4.75 weight percent silicon as essential alloying ingredients between 0.03 and 0.05% by weight of arsenic.
- GB-1 443 090 proposed a heat treatment of the cast parts. In this heat treatment, the cast parts are annealed at temperatures between 600 ° C and 750 ° C for a period of 5 to 10 days and then quenched. This heat treatment is carried out with the aim of obtaining the ⁇ and ⁇ phases to be preferred in view of the corrosion. By quenching in particular the formation of phases is to be avoided, the corrosion resistance is low, so the p- and x-phase.
- a copper alloy which has up to 10% by weight of aluminum and up to 5% by weight of iron and which is used for the production of water-bearing components of water installations.
- this alloy shows inadequate corrosion behavior and, in particular, excessive migration of metal ions into the water.
- manganese alloy alloy As necessary alloy is known from the EP 1 817 438 known.
- copper alloys are from the CH 148 195 , of the US 2004/0234412 , of the DE 585 002 , of the DE 43 24 008 as well as the WO 94/24325 known.
- the present invention is based on the problem to provide a water-bearing component, which has a low migration tendency of lead and nickel in the water to be led.
- the invention wants to specify a water-conducting component made of a corresponding alloy, which has a sufficient tightness with regard to the water to be led.
- the present invention provides a water-conducting component having the features of claim 1.
- the component according to the invention consists of an alloy with a lead content and a nickel content of less than 0.1 wt .-%.
- the only essential alloy constituents besides copper are tin and zinc in the alloy. These three components constitute at least 99.75% by weight of the total alloy.
- the present invention proposes a high purity copper-tin-zinc alloy which is optimized in its migration properties due to the absence of lead and nickel.
- the proportions of these two elements are each below a proportion of 0.1 wt .-%.
- the remaining elements P, Fe, S and Sb are limited by the upper limits specified in claim 1.
- the iron content can be relatively high at 0.3% by weight. All other ingredients are below a limit that can be considered as an impurity limit.
- the upper limit for the lead and the nickel content is set to 0.05 wt .-%.
- lead and nickel are containing not more than 0.02 wt .-% in the alloy.
- the unavoidable impurities within the alloy are preferably limited to a total of 0.25% by weight.
- each element contained as an unavoidable impurity in the alloy is contained less than 0.02 wt% therein.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Sliding-Contact Bearings (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09010054A EP2290114A1 (fr) | 2009-08-04 | 2009-08-04 | Composant pour conduite d'eau |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09010054A EP2290114A1 (fr) | 2009-08-04 | 2009-08-04 | Composant pour conduite d'eau |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2290114A1 true EP2290114A1 (fr) | 2011-03-02 |
Family
ID=41259481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09010054A Withdrawn EP2290114A1 (fr) | 2009-08-04 | 2009-08-04 | Composant pour conduite d'eau |
Country Status (1)
| Country | Link |
|---|---|
| EP (1) | EP2290114A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014008969A1 (fr) * | 2012-07-12 | 2014-01-16 | Wieland-Werke Ag | Pièces moulées en alliages de cuivre résistant à la corrosion |
| DE102018004702A1 (de) | 2018-06-12 | 2019-12-12 | Gebr. Kemper Gmbh + Co. Kg Metallwerke | Formteile aus einer korrosionsbeständigen und zerspanbaren Kupferlegierung |
| CN115679149A (zh) * | 2022-11-10 | 2023-02-03 | 广州番禺职业技术学院 | 一种高亮泽高耐蚀抗菌装饰锡青铜合金及其制备方法 |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH148195A (de) | 1930-05-27 | 1931-07-15 | Hirsch Kupfer & Messingwerke | Kupfer-Silizium-Zinklegierung. |
| DE585002C (de) | 1930-05-28 | 1933-09-27 | Hirsch Kupfer Und Messingwerke | Kupfer-Silicium-Zink-Legierung |
| GB1385411A (en) | 1971-08-11 | 1975-02-26 | Toyo Valve Co Ltd | Aluminium-containing copper alloys |
| GB1443090A (en) | 1974-03-25 | 1976-07-21 | Anaconda Co | Silicon brass resistant to partin corrosion- |
| WO1994024325A1 (fr) | 1993-04-16 | 1994-10-27 | Ideal-Standard Gmbh | Alliage de laiton |
| DE4324008A1 (de) | 1993-07-17 | 1995-01-19 | Kabelmetal Ag | Verwendung einer korrosionsbeständigen Legierung auf Kupferbasis |
| JPH09111376A (ja) * | 1995-10-13 | 1997-04-28 | Maezawa Kiyuusou Kogyo Kk | 無鉛快削銅合金 |
| EP0798298A1 (fr) | 1994-12-15 | 1997-10-01 | Sankyo Company Limited | Composes thiazolidinone ou medicament pour prevenir ou guerir l'angine de poitrine contenant ces composes en tant qu'ingredient actif |
| EP1045041A1 (fr) | 1998-10-12 | 2000-10-18 | Sambo Copper Alloy Co., Ltd | Alliage de cuivre de decolletage sans plomb |
| US20040234412A1 (en) | 2002-09-09 | 2004-11-25 | Keiichiro Oishi | High-strength copper alloy |
| EP1817438A1 (fr) | 2005-12-14 | 2007-08-15 | Gebr. Kemper GmbH + Co. KG Metallwerke | Alliage de cuivre peu sensible aux migrations |
-
2009
- 2009-08-04 EP EP09010054A patent/EP2290114A1/fr not_active Withdrawn
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH148195A (de) | 1930-05-27 | 1931-07-15 | Hirsch Kupfer & Messingwerke | Kupfer-Silizium-Zinklegierung. |
| DE585002C (de) | 1930-05-28 | 1933-09-27 | Hirsch Kupfer Und Messingwerke | Kupfer-Silicium-Zink-Legierung |
| GB1385411A (en) | 1971-08-11 | 1975-02-26 | Toyo Valve Co Ltd | Aluminium-containing copper alloys |
| GB1443090A (en) | 1974-03-25 | 1976-07-21 | Anaconda Co | Silicon brass resistant to partin corrosion- |
| WO1994024325A1 (fr) | 1993-04-16 | 1994-10-27 | Ideal-Standard Gmbh | Alliage de laiton |
| DE4324008A1 (de) | 1993-07-17 | 1995-01-19 | Kabelmetal Ag | Verwendung einer korrosionsbeständigen Legierung auf Kupferbasis |
| EP0798298A1 (fr) | 1994-12-15 | 1997-10-01 | Sankyo Company Limited | Composes thiazolidinone ou medicament pour prevenir ou guerir l'angine de poitrine contenant ces composes en tant qu'ingredient actif |
| JPH09111376A (ja) * | 1995-10-13 | 1997-04-28 | Maezawa Kiyuusou Kogyo Kk | 無鉛快削銅合金 |
| EP1045041A1 (fr) | 1998-10-12 | 2000-10-18 | Sambo Copper Alloy Co., Ltd | Alliage de cuivre de decolletage sans plomb |
| US20040234412A1 (en) | 2002-09-09 | 2004-11-25 | Keiichiro Oishi | High-strength copper alloy |
| EP1817438A1 (fr) | 2005-12-14 | 2007-08-15 | Gebr. Kemper GmbH + Co. KG Metallwerke | Alliage de cuivre peu sensible aux migrations |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Week 199727, Derwent World Patents Index; AN 1997-295348 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014008969A1 (fr) * | 2012-07-12 | 2014-01-16 | Wieland-Werke Ag | Pièces moulées en alliages de cuivre résistant à la corrosion |
| DE102012013817A1 (de) | 2012-07-12 | 2014-01-16 | Wieland-Werke Ag | Formteile aus korrosionsbeständigen Kupferlegierungen |
| DE102018004702A1 (de) | 2018-06-12 | 2019-12-12 | Gebr. Kemper Gmbh + Co. Kg Metallwerke | Formteile aus einer korrosionsbeständigen und zerspanbaren Kupferlegierung |
| EP3581667A2 (fr) | 2018-06-12 | 2019-12-18 | Gebr. Kemper GmbH + Co. KG Metallwerke | Pièces moulées d'un alliage de cuivre résistant à la corrosion et pouvant être usiné |
| CN115679149A (zh) * | 2022-11-10 | 2023-02-03 | 广州番禺职业技术学院 | 一种高亮泽高耐蚀抗菌装饰锡青铜合金及其制备方法 |
| CN115679149B (zh) * | 2022-11-10 | 2023-07-28 | 广州番禺职业技术学院 | 一种高亮泽高耐蚀抗菌装饰锡青铜合金及其制备方法 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| AK | Designated contracting states |
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| AX | Request for extension of the european patent |
Extension state: AL BA RS |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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| 18D | Application deemed to be withdrawn |
Effective date: 20110903 |