EP2143998B1 - Unité de brûleur pour combustible pulvérulent - Google Patents
Unité de brûleur pour combustible pulvérulent Download PDFInfo
- Publication number
- EP2143998B1 EP2143998B1 EP09165089A EP09165089A EP2143998B1 EP 2143998 B1 EP2143998 B1 EP 2143998B1 EP 09165089 A EP09165089 A EP 09165089A EP 09165089 A EP09165089 A EP 09165089A EP 2143998 B1 EP2143998 B1 EP 2143998B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tube
- combustion
- burner
- solid fuel
- unit according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
- F23D1/02—Vortex burners, e.g. for cyclone-type combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/005—Shaft or like vertical or substantially vertical furnaces wherein no smelting of the charge occurs, e.g. calcining or sintering furnaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/10—Details, accessories or equipment specially adapted for furnaces of these types
- F27B1/16—Arrangements of tuyeres
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D99/00—Subject matter not provided for in other groups of this subclass
- F27D99/0001—Heating elements or systems
- F27D99/0033—Heating elements or systems using burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/03006—Reverse flow combustion chambers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/99004—Combustion process using petroleum coke or any other fuel with a very low content in volatile matters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
- F23D2201/20—Fuel flow guiding devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
- F23D2201/30—Wear protection
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/00016—Preventing or reducing deposit build-up on burner parts, e.g. from carbon
Definitions
- the invention relates to a burner unit for dusty solid fuel having a first tube for conveying the solid fuel in a first conveying direction, wherein a deflecting body for deflecting the emerging from the first tube solid fuel jet is arranged in extension of the first tube. Furthermore, the invention relates to a burner assembly for a furnace, in particular for a ring-shaft furnace for burning limestone.
- Burner units of the type mentioned are known from the prior art. They are preferably used in shaft furnace systems, for example in annular shaft furnaces for burning limestone.
- the particular procedural challenge is to achieve the fullest possible implementation of the dusty fuel - this can be, for example, petroleum coke dust - in hot gases in order to use the energy content of the dusty solid fuel as completely as possible.
- the deflected fuel stream then mixes with another oncoming air stream, so that an approximately complete mixing of rod-shaped solid fuel and combustion air and thus a complete combustion of the fuel is ensured.
- a deflecting body in extension of the transport tube for the fuel-air mixture is for example from the DE 10 2006 035 174 A1and the FR 2 842 584 A1 known.
- a mixture of petroleum coke dust and primary air is deflected after exiting the burner lance at a cross-sectionally C-shaped flow deflector and mixed with tangentially injected into the burner chamber secondary air, wherein the thereby adjusting mixture of tangential blowing verdrallter secondary air, petcoke dust and primary air is transported in the direction of the exit of the combustion chamber, whereby it is completely converted into hot gases.
- the present invention is therefore based on the object to provide a burner unit for dusty solid fuel of the type mentioned, the complete implementation of the dusty fuel in hot gases ensures. Furthermore, the burner unit should be able to be operated with reduced maintenance costs, for example, by constructively avoiding the known from the prior art problem of buildup of the deflected dust-like fuel.
- the task is solved with a burner unit for dust-like solid fuel according to the preamble of claim 1, characterized in that the first tube surrounding the first tube baffle body, which deflects the deflected by the deflecting solid fuel jet substantially in the first conveying direction again.
- the particular advantage of the burner unit according to the invention is that on the one hand the principle of the deflection of the fuel jet can be maintained, which has proven to be extremely effective with respect to an intensive mixing of the dust-like fuel with the combustion air. On the other hand, it is ensured by the use of the impact tube surrounding the first tube, that the fuel jet undergoes the desired renewed change of direction, but without the risk that parts of the fuel jet strikes back into the burner unit and settle there, which is associated with the known problem.
- the baffle body can assume all geometric shapes which ensure that the solid fuel jet initially deflected by the deflecting body is deflected again in the first conveying direction, without the overall aerodynamics of the construction being changed significantly overall, particularly when installed in a corresponding burner housing.
- first tube with a circular cross-section of the baffle body is preferably annular.
- the first tube is coaxially surrounded by at least one second tube to form an annular channel for conveying combustion air, wherein the free end of the second tube is set back axially relative to the free end of the first tube, wherein the impact body to is arranged opposite the free end of the second tube projecting pipe section of the first tube.
- This arrangement creates a combustion air cone surrounding the fuel jet emerging from the first tube, which on the one hand initially permits spatial separation of the solid fuel jet from the lining surrounding the combustion chamber in which the burner unit is arranged, wherein in the further course intensive mixing takes place second tube exiting combustion air with the solid fuel jet, which is a prerequisite for a complete implementation of the dusty solid fuel in hot gases takes place.
- the combustion air can be introduced, for example, via a substantially radial feed line into the second tube.
- a combustion chamber is provided in the flow direction in front of the second tube, in which a gas-operated pilot burner is arranged.
- a gas-operated pilot burner is arranged.
- additional thermal energy which is necessary to enable ignition of the pulverulent solid fuel entering a combustion chamber, can be provided during start-up of the furnace-fired furnace.
- the combustion chamber, in which the pilot burner is arranged this can be fed through a line opening into the combustion chamber primary combustion air, wherein in the conduit a throttle valve is arranged to the combustion of the gas also supplied, for example propane, and thus indirectly the temperature of dust-like solid fuel to be able to control exactly.
- the pilot burner can be switched off since the flame itself as well as the heat radiation of the refractory furnace lining provide enough thermal energy for stable burner operation.
- the exhaust gases of the pilot burner are preferably derived from the second tube surrounding the first tube from the combustion chamber. Accordingly, the combustion chamber is connected according to a further embodiment of the invention with the second tube, so that the burner gases into the second tube can be initiated and exit from this together with the combustion air in a combustion chamber.
- Another aspect of the present invention relates to a burner assembly for an oven, in particular for a ring-shaft furnace for burning limestone, with a combustion chamber defining a burner housing and a burner unit according to one of claims 1 to 7.
- a powerful and efficiently operating burner assembly is provided which ensures trouble-free continuous operation in an oven, in particular in a ring-shaft furnace for burning limestone.
- the combustion chamber of the burner assembly can assume a wide variety of geometries. However, it is preferably substantially cylindrical, wherein the burner unit is arranged substantially coaxially in the combustion chamber.
- the burner housing comprises a screw housing into which a combustion air duct opens tangentially.
- a combustion air duct opens tangentially.
- the screw housing is arranged back in the propagation direction of the burner flame relative to the free end of the first tube of the burner unit.
- a burner arrangement known from the prior art is shown.
- the burner assembly comprises a burner housing 100 with a rotationally symmetrical combustion chamber 200, which initially widens conically in the transport direction of the fuel or in the direction of propagation of the flame and then tapers conically in the form of a nozzle up to the burner exit.
- a coaxial with the combustion chamber 200 arranged central tube 300 dust-like solid fuel is pneumatically conveyed and exits at the free end 300 a of the central tube 300 from this. Subsequently, the dust-like solid fuel strikes a flow deflector 400, through which the fuel jet is deflected substantially 180 ° from its original flow direction.
- the secondary combustion air blown into the combustion space 200 at its closed end via a feed 500 arranged tangentially to the combustion chamber 200 is twisted in the combustion chamber 200, as indicated by the spiral line S.
- the twisted secondary combustion air then mixes with the recirculated fuel jet, with a targeted mixing takes place, so that a strong air-enriched amount of dust flows through the burner chamber 200 in the direction of its output and passes into the burner flame B.
- tertiary combustion air is still stepped through several tangentially arranged nozzles introduced into the combustion chamber 200 to support the swirl flow in the combustion chamber 200.
- FIG. 2 In contrast, an improved burner arrangement X is shown, which can be used, for example, in a ring-shaft furnace for burning limestone.
- the burner assembly X in turn comprises a housing 1 which encloses a presently cylindrical combustion chamber 2.
- a first tube 3 In the cylindrical combustion chamber 2 extends substantially coaxially a first tube 3 for the promotion of a dust-like solid fuel, in this case petcoke dust.
- a deflecting 4 for deflecting the Arranged from the first tube 3 solid fuel jet, which in the present case has approximately the shape of a mirrored "E".
- Other geometrical shapes of the deflecting body are also conceivable, for example those of a mirrored "C" or the like.
- the first tube 3 is in the burner assembly of Fig. 2 Coaxially surrounded by a second tube 6 over a certain length.
- combustion air so-called secondary air, can be conducted, which is supplied to the pipe via a radial supply line 6b.
- a present annular baffle body 7 is arranged in relative proximity to the deflection body 4, whose function will be explained in more detail below.
- the burner assembly X of Fig. 2 further comprises a arranged in the flow direction of the fuel in front of the burner housing combustion chamber 8, in which a pilot burner 8a is arranged for gaseous fuel, such as propane gas. Accordingly, supply lines 8b are provided for the supply of gaseous fuel as well as a combustion air supply line 8c, in which the volume flow can be adjusted by means of a throttle flap 8c *.
- a pilot burner 8a is arranged for gaseous fuel, such as propane gas.
- supply lines 8b are provided for the supply of gaseous fuel as well as a combustion air supply line 8c, in which the volume flow can be adjusted by means of a throttle flap 8c *.
- the combustion chamber 8 is connected to the second tube 6 at the end such that the exhaust gases of the pilot burner 8a can flow directly into the annular channel of the second tube and so with the introduced via the feed line 6b in the second pipe combustion air flow into the combustion chamber 2.
- a screw housing 5 is arranged, via which a mixture of combustion air and recirculating exhaust gas can be introduced tangentially with a very high volume flow.
- a mixture of the dust-like solid fuel and a transport air flow is introduced via its rear end and conveyed through the first tube 3 into the combustion chamber 2.
- the dust-like solid fuel then exits at the free end of the tube 3 and bounces against the deflection body 4, whereby it is deflected by approximately 180 ° in the opposite direction.
- the thus deflected fuel jet is now on the baffle 7, which is arranged on the opposite to the second pipe 6 projecting pipe section of the first tube 3, again deflected, so that it flows substantially back in the original conveying direction, but it has a highly divergent flow profile ,
- the gas ignition burner 8a arranged in the combustion chamber 8 becomes additional operated to provide the necessary for the ignition of the solid fuel thermal energy.
- the hot gases of the pilot burner 8a then flow together with the combustion air into the combustion chamber 2.
- the pilot burner 8a can be switched off again.
- the volume flow of the combustion air emerging from the second tube is only a fraction of the injection air flowing in tangentially via the screw housing 5, which consists of a mixture of preheated blowing air and recirculating kiln exhaust gas, as in connection with FIG Fig. 3 will be explained in more detail.
- the injection air enters the combustion chamber 2 in a highly twisted manner, as indicated by the spiral line D.
- a burner assembly in a ring shaft furnace for burning limestone is in the Fig. 3 shown.
- the ring shaft furnace of Fig. 3 is constructed according to the type "Beckenbach” and shall be briefly described below for the purpose of understanding the principle.
- the oven has a cylindrical outer shell, which is divided into a top shaft 20 and a main shaft 10.
- the inner shaft wall of the main shaft 10 is formed by a lower inner cylinder 30, the upper shaft 20 by an upper inner cylinder 40.
- the combustion zone BZ are a plurality of burner assemblies X associated with Fig. 2 described type arranged in a lower burner level, one of which is visible in the present sectional drawing.
- the granular material G to be fired is introduced into the annular shaft furnace and, due to gravity, initially moves through the preheating zone VZ, where it is heated in countercurrent by exhaust gases rising from the combustion zone BZ.
- the firing material G has passed the upper inner cylinder 40, it enters the combustion zone BZ and is first burned there in countercurrent and below the lower burner plane in direct current.
- the now fired Good G * enters the cooling zone KZ, where it is again cooled in countercurrent.
- the good G * is discharged from the ring shaft furnace.
- a partial exhaust gas flow into the upper inner cylinder 40 and from there into a recuperator unit 70, where it heats a motive air flow.
- injectors 50 together with a partial exhaust gas stream, which in turn flows through the lower inner cylinder 30 and one in the injectors 50.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
Claims (11)
- Unité de brûleur pour combustible solide, pulvérulent, qui est dotée d'un premier tube (3) pour le transport du combustible solide dans une première direction de transport, sachant qu'un organe de déflexion (4) est agencé en prolongement du premier tube (3) pour faire dévier le jet de combustible solide sortant du premier tube (3), caractérisée en ce que le premier tube (3) est doté d'un corps de rebondissement (7), qui, entourant le premier tube, renvoie sensiblement dans la première direction de transport le jet de combustible solide, dévié par l'organe de déflexion (4).
- Unité de brûleur selon la revendication 1 caractérisée en ce que le corps de rebondissement (7) est réalisé en forme d'anneau.
- Unité de brûleur selon la revendication 1 ou 2, caractérisée en ce que le premier tube (3) est entouré coaxialement par au moins un deuxième tube (6), ce dont résulte un canal annulaire (6a) pour le transport de l'air de combustion, sachant que l'extrémité libre du deuxième tube (6) est axialement en retrait par rapport à l'extrémité libre du premier tube (3), le corps de rebondissement (7) étant agencé sur la partie du premier tube (3), qui est en saillie par rapport à l'extrémité libre du deuxième tube (6).
- Unité de brûleur selon la revendication 1, caractérisée en ce que le deuxième tube (6) est doté d'une conduite d'amenée (6b), sensiblement radiale, pour l'admission de l'air de combustion dans le deuxième tube (6).
- Unité de brûleur selon la revendication 3 ou 4, caractérisée en ce que, dans la direction d'écoulement, en amont du deuxième tube (6), est prévue une chambre de combustion (8), dans laquelle est installé un brûleur d'allumage (8a) exploité au gaz.
- Unité de brûleur selon la revendication 5, caractérisée en ce que, pour l'air de combustion pour le brûleur d'allumage (8a), une conduite (8c) débouche dans la chambre de combustion, sachant qu'une vanne d'étranglement (8c*) est agencée dans ladite conduite (8c).
- Unité de brûleur selon la revendication 5 ou 6, caractérisée en ce que la chambre de combustion (8) est reliée au deuxième tube (6) pour l'admission des gaz d'échappement du brûleur dans ledit deuxième tube (6).
- Arrangement de brûleur (X) pour un four, en particulier pour un four à cuve annulaire, pour la calcination de calcaire, lequel arrangement comprend un carter de brûleur (1), qui définit une chambre de combustion (2), et une unité de brûleur selon l'une des revendications 1 à 7.
- Agencement de brûleur selon la revendication 8 caractérisé en ce que la chambre de combustion (2) est de conception sensiblement cylindrique, sachant que l'unité de brûleur est disposée sensiblement coaxialement dans la chambre de combustion (2).
- Agencement de brûleur selon la revendication 8 ou 9, caractérisé en ce que le carter de brûleur (1) comprend un carter hélicoïdal (5), dans lequel débouche une conduite d'air de combustion.
- Agencement de brûleur selon la revendication 10, caractérisé en ce que le carter hélicoïdal (5) est disposé dans la direction d'écoulement du combustible solide pulvérulent, en amont de la chambre de combustion (2).
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI200930410T SI2143998T1 (sl) | 2008-07-11 | 2009-07-09 | Enota gorilnika za trdo gorivo v obliki prahu |
| PL09165089T PL2143998T3 (pl) | 2008-07-11 | 2009-07-09 | Jednostka palnikowa dla stałego paliwa w postaci pyłu |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008032589 | 2008-07-11 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP2143998A2 EP2143998A2 (fr) | 2010-01-13 |
| EP2143998A3 EP2143998A3 (fr) | 2011-04-13 |
| EP2143998B1 true EP2143998B1 (fr) | 2012-08-29 |
Family
ID=41129217
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09780392A Ceased EP2304316A2 (fr) | 2008-07-11 | 2009-07-09 | Unité brûleur et dispositif brûleur pour combustible solide pulvérulent |
| EP09165089A Active EP2143998B1 (fr) | 2008-07-11 | 2009-07-09 | Unité de brûleur pour combustible pulvérulent |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09780392A Ceased EP2304316A2 (fr) | 2008-07-11 | 2009-07-09 | Unité brûleur et dispositif brûleur pour combustible solide pulvérulent |
Country Status (6)
| Country | Link |
|---|---|
| EP (2) | EP2304316A2 (fr) |
| ES (1) | ES2394539T3 (fr) |
| PL (1) | PL2143998T3 (fr) |
| PT (1) | PT2143998E (fr) |
| SI (1) | SI2143998T1 (fr) |
| WO (1) | WO2010004009A2 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8092520B2 (en) | 2005-11-10 | 2012-01-10 | CardiAQ Technologies, Inc. | Vascular prosthesis connecting stent |
| US8652203B2 (en) | 2010-09-23 | 2014-02-18 | Cardiaq Valve Technologies, Inc. | Replacement heart valves, delivery devices and methods |
| DE102015005416B4 (de) * | 2015-04-29 | 2023-11-30 | Khd Humboldt Wedag Gmbh | Verfahren zum Betrieb eines Calcinators mit einem Gasbrenner |
| BE1023896B1 (fr) * | 2016-06-28 | 2017-09-06 | Lhoist Rech Et Developpement Sa | Procede de combustion de combustible dans une chambre de combustion tubulaire |
| US10350062B2 (en) | 2016-07-21 | 2019-07-16 | Edwards Lifesciences Corporation | Replacement heart valve prosthesis |
| CN106247338B (zh) * | 2016-08-29 | 2018-05-25 | 煤科院节能技术有限公司 | 一种快速互换的多燃料燃烧器 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB207062A (en) * | 1922-12-28 | 1923-11-22 | Babcock & Wilcox Hampfkessel W | Improvements in and relating to furnaces |
| DE504546C (de) * | 1927-03-08 | 1930-08-05 | Steitz & Co G M B H | Staubfeuerungsflachbrenner |
| GB704901A (en) * | 1951-08-07 | 1954-03-03 | Pollopas Patents Ltd | Improvements in or relating to pulverised fuel burners, more particularly for cementkilns and similarly constructed furnaces |
| US4387654A (en) * | 1980-05-05 | 1983-06-14 | Coen Company, Inc. | Method for firing a rotary kiln with pulverized solid fuel |
| FR2569256B1 (fr) * | 1984-08-16 | 1989-04-07 | Stein Industrie | Bruleur d'allumage et de soutien de combustion pour combustible solide fossile pulverise, et chambre de combustion comportant de tels bruleurs |
| US5441546A (en) * | 1993-11-08 | 1995-08-15 | Moard; David | Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources |
| DE19527083A1 (de) * | 1995-07-25 | 1997-01-30 | Lentjes Kraftwerkstechnik | Verfahren und Brenner zur Verminderung der Bildung von NO¶x¶ bei der Verbrennung von Kohlenstaub |
| DE10232373B4 (de) * | 2002-07-17 | 2009-04-02 | Schoppe, Fritz, Dr.-Ing. | Verfahren zur Erhöhung der Flammstabilität bei Kohlenstaubfeuerungen und Vorrichtung zur Ausführung des Verfahrens |
| US6986311B2 (en) * | 2003-01-22 | 2006-01-17 | Joel Vatsky | Burner system and method for mixing a plurality of solid fuels |
| US20060169181A1 (en) * | 2003-02-24 | 2006-08-03 | Posco | Method and burner apparatus for injecting a pulverized coal into rotary kilns, method and apparatus for producing cao using them |
| FR2872887B1 (fr) * | 2004-07-07 | 2006-09-08 | Inst Francais Du Petrole | Procede de combustion homogene et generateur thermique utilisant un tel procede |
| DE102006035174A1 (de) * | 2006-07-29 | 2008-01-31 | Dako Kohlen Ex-Und Import Gmbh | Verfahren zur thermischen Nutzung von grünem Petrolkoks in Industrieanlagen und Brenneranlage |
-
2009
- 2009-07-09 SI SI200930410T patent/SI2143998T1/sl unknown
- 2009-07-09 EP EP09780392A patent/EP2304316A2/fr not_active Ceased
- 2009-07-09 ES ES09165089T patent/ES2394539T3/es active Active
- 2009-07-09 PT PT91650895T patent/PT2143998E/pt unknown
- 2009-07-09 EP EP09165089A patent/EP2143998B1/fr active Active
- 2009-07-09 PL PL09165089T patent/PL2143998T3/pl unknown
- 2009-07-09 WO PCT/EP2009/058770 patent/WO2010004009A2/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2304316A2 (fr) | 2011-04-06 |
| PL2143998T3 (pl) | 2013-03-29 |
| PT2143998E (pt) | 2012-12-10 |
| WO2010004009A3 (fr) | 2011-04-28 |
| EP2143998A2 (fr) | 2010-01-13 |
| ES2394539T3 (es) | 2013-02-01 |
| SI2143998T1 (sl) | 2013-01-31 |
| WO2010004009A2 (fr) | 2010-01-14 |
| EP2143998A3 (fr) | 2011-04-13 |
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