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EP2052606A1 - Herbicide combination - Google Patents

Herbicide combination Download PDF

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Publication number
EP2052606A1
EP2052606A1 EP07020810A EP07020810A EP2052606A1 EP 2052606 A1 EP2052606 A1 EP 2052606A1 EP 07020810 A EP07020810 A EP 07020810A EP 07020810 A EP07020810 A EP 07020810A EP 2052606 A1 EP2052606 A1 EP 2052606A1
Authority
EP
European Patent Office
Prior art keywords
ion
methyl
alkyl
cas
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07020810A
Other languages
German (de)
French (fr)
Inventor
Erwin Dr. Hacker
Christian Dr. Waldraff
Dominique Schreiber
Martin Hills
Dieter Dr. Feucht
Klaus-Helmut Dr. Müller
R. F. Ernst Dr. Gesing
Georg Dr. Bonfig-Picard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP07020810A priority Critical patent/EP2052606A1/en
Priority to US12/738,777 priority patent/US20100248965A1/en
Priority to CA2703581A priority patent/CA2703581A1/en
Priority to PCT/EP2008/009031 priority patent/WO2009053095A2/en
Priority to AU2008315645A priority patent/AU2008315645A1/en
Priority to JP2010530346A priority patent/JP2011500747A/en
Priority to EA201000523A priority patent/EA201000523A1/en
Priority to EP08841028A priority patent/EP2205089A2/en
Priority to BRPI0818261-2A2A priority patent/BRPI0818261A2/en
Priority to CN200880113301A priority patent/CN101835383A/en
Priority to ARP080104597A priority patent/AR068958A1/en
Priority to MX2010004532A priority patent/MX2010004532A/en
Priority to CL2008003144A priority patent/CL2008003144A1/en
Publication of EP2052606A1 publication Critical patent/EP2052606A1/en
Priority to ZA2010/02565A priority patent/ZA201002565B/en
Priority to TN2010000183A priority patent/TN2010000183A1/en
Priority to MA32790A priority patent/MA31789B1/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

Definitions

  • Herbicide combination comprising 2-iodo-N - [(4-methoxy-6-methyl-1,3,6-triazin-2-yl) carbamoyl] benzenesulfonamide and / or its salts and herbicidal active compounds from the group of (sulfone) amides.
  • the present invention is in the technical field of pesticides, against unwanted plant growth, eg in Vorsaatvon (with or without incorporation), pre-emergence or postemergence in crops such as wheat (hard and soft wheat), corn, soy, sugar beet, Sugar cane, cotton, rice, beans (such as bush bean and horse bean), flax, barley, oats, rye, triticale, oilseed rape, potato and millet (sorghum), flax, pasture grass and green / lawns are used.
  • the invention relates to a herbicidal combination containing at least two herbicides and their use for controlling undesired plant growth.
  • substituted phenylsulfonylureas have herbicidal properties. These are, for example, phenyl derivatives which are monosubstituted or polysubstituted (for example US 4,127,405 . WO 9209608 . BE 853374 . WO 9213845 . EP 84020 . WO 9406778 . WO 02072560 . US 4169719 . US4629494 . DE 4038430 ).
  • N- (1,3,5-triazin-2-yl-aminocarbonyl) arylsulphonamides have herbicidal properties (cf. DE 2715 786 ).
  • the herbicidal action of these compounds is not satisfactory in all respects, such as tolerability, spectrum of activity, control of tolerant or resistant species, behavior towards secondary crops or application flexibility.
  • the herbicidal activity of N- (1,3,5-triazin-2-yl-aminocarbonyl) -arylsulfonamide against harmful plants is already at a high level, but generally depends on the application rate, the particular preparation form, each to be controlled harmful plants or the harmful plant spectrum, the climate and soil conditions, etc. Another criterion is the duration of the action or the degradation rate of the herbicide. It may also be necessary to take account of changes in the susceptibility of harmful plants, which may occur with prolonged use of the herbicides or geographically. Losses of activity in individual plants can only be compensated to a limited extent by higher application rates of the herbicides, e.g. because it reduces the selectivity of the herbicides or does not improve the efficacy even at higher application rates.
  • the object of the present invention was to provide an improved crop protection agent.
  • hydrocarbon radicals mentioned in the radical definitions such as alkyl, alkenyl or alkynyl, also in combinations with heteroatoms, such as in alkoxy, alkylthio, haloalkyl or alkylamino, are also straight-chain or branched, even if not expressly stated.
  • Examples of compounds preferably used as the herbicide (A) are the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide (A-0) and the compounds of the formula (I) mentioned in Table A below (ie the compounds (A-1 to A-35)).
  • herbicides (A) are 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I) in which the cation (M + ) a sodium ion, a potassium ion, a lithium ion, a magnesium ion, a calcium ion, an NH 4 + ion, a (2-hydroxyeth-1-yl) ammonium ion, Bis-N, N- (2-hydroxyeth-1-yl) ammonium ion, Tris-N, N, N- (2-hydroxyeth-1-yl) ammonium ion, a methyl ammonium ion, a dimethyl ammonium ion, a trimethyl ammonium ion , a tetramethylammonium ion, an ethylammonium ion, a diethyl
  • a diisopropylethylammonium ion a pyridinium ion, a piperidinium ion, an imidazolium ion, a morpholinium ion, a 1,8-diazabicyclo [5.4.0] undec-7-enium ion.
  • herbicides (A) are 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I) in which the cation (M + ) is a sodium ion, a potassium ion, a magnesium ion, a calcium ion, or a NH 4 + ion.
  • herbicide (A) also particularly preferred are the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I), in those containing the cation (M + ), in which the cation (M + ) is a sodium ion, a potassium ion or an NH 4 ion.
  • the herbicide combinations of the invention may contain additional additional components, e.g. As agrochemical agents of other types and / or customary in plant protection additives and / or formulation auxiliaries, or used together with these.
  • the herbicidal combinations according to the invention contain the herbicides (A) and (B) in an effective content and / or have synergistic effects.
  • the synergistic effects can be observed, for example, when the herbicides (A) and (B) are applied together, for example as a co-formulation or as a tank mixture, but they can also be detected in the case of splitting.
  • the synergistic effects allow a reduction in the application rates of the individual herbicides, a higher potency at the same rate, the control of previously unrecognized species (gaps), the control of species that have tolerances or resistance to single or multiple herbicides, an extension of the period of application and / or a reduction in the number of individual applications required and - as a result for the user - economically and ecologically more advantageous weed control systems.
  • the combinations of herbicides (A) + (B) according to the invention make possible synergistic increases in activity which go far and unexpectedly beyond the effects achieved with the individual herbicides (A) and (B).
  • Said formula (I) comprises all stereoisomers and mixtures thereof, in particular racemic mixtures, and - as far as enantiomers are possible - the respective biologically active enantiomers.
  • the herbicides of group (A) inhibit the enzyme acetolactate synthase (ALS) and thus protein biosynthesis in plants.
  • pre-emergence and post-emergence a relatively broad spectrum of harmful plants is fought, for example at Boeinglen and perenning, monocotyledonous or dicotyledonous weeds as well as unwanted crops.
  • the application rates are generally lower, z. B. in the range of 0.001 g to 1000 g AS / ha, preferably 0.1 g to 500 g AS / ha, more preferably 0.5 g to 250 g AS / ha.
  • the herbicides of group (B) influence, for example, the fatty acid biosynthesis, cell division, photosystem II and acetolactate synthase and are suitable for both pre-emergence and post-emergence applications.
  • the application rates are generally lower, z. B. in the range of 0.05 g to 15000 g AS / ha, preferably 0.1 g to 10000 g AS / ha, more preferably 0.5 g to 8000 g AS / ha.
  • herbicides (A) with one or more herbicides (B) are further preferred.
  • combinations of herbicides (A) with one or more herbicides (B) according to the scheme: (A-0) + (B1-1), (A-0) + (B1-2), (A-0) + (B9-7), (A-1) + (B1-1), (A-1) + (B1-2), (A-1) + (B9-7), (A-35) + ( B1-1), (A-35) + (B1-2), (A-35) + (B9-7).
  • those combinations according to the invention which also contain one or more other herbicides (A) and (B) different agrochemical active compounds, which also have the function of a selective herbicide.
  • herbicides according to the invention various agrochemical active ingredients, for example from the group of safeners, fungicides, insecticides, structurally from the herbicides (A) and (B) different herbicides and plant growth regulators or from the group of customary in plant protection additives and formulation auxiliaries
  • herbicides (A) and (B) structurally different herbicides in question, preferably herbicidal active ingredients which are based on an inhibition of, for example, acetolactate synthase, acetyl-coenzyme A carboxylase, PS I, PS II, HPPDO, phytoene desaturase, protoporphyrinogen oxidase, glutamine synthetase, cellulose desynthesis, 5-erlolpyruvylshikimate-3-phosphate synthetase are based as in Weed Research 26, 441-445 (1986 ), or " The Pesticide Manual, 13th Edition, The British Crop Protection Council, 2003, or 14th Edition, 2006/2007 , or in the corresponding " e-Pesticide Manual ", version 4 (2006 ), each issued by the British Crop Protection Council (hereinafter also abbreviated to "PM”), and literature cited therein.
  • PM British Crop Protection Council
  • acibenzolar-S-methyl acifluorfen (-sodium); aclonifen; AD-67; AKH 7088, ie methyl [[[1- [5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrophenyl] -2-methoxyethylidene] amino] oxy] acetic acid and acetic acid; alloxydim (-sodium); ametryn; amicarbazone, amidochlor, aminopyralid; amitrol; Ammoniumpelargonate; AMS, ie ammonium sulfamate; ancimidol; anilofos, atrazine; aviglycine; azafenidin, aziprotryn; barban; BAS 516H, ie 5-fluoro-2-phenyl-4H-3,1-benzoxazin-4-one; benazolin (-ethyl
  • herbicides (A) and (B) already have very good to sufficient selectivity in many cultures, phytotoxicities on the crop plants can in principle occur in some crops and, above all, in the case of mixtures with other herbicides which are less selective.
  • combinations of herbicides (A) and (B) which contain the herbicidally combined active ingredients and one or more safeners according to the invention.
  • the safeners which are used in an antidote effective content, reduce the phytotoxic side effects of the herbicides / pesticides used, eg. B. in economically important crops such as cereals (wheat, barley, rye, corn, rice, millet), sugar beet, sugar cane, rapeseed, cotton and soybeans, preferably cereals.
  • a mixture with other known active ingredients such as fungicides, insecticides, acaricides, nematicides, bird repellents, plant nutrients and soil conditioners is also possible.
  • the weight ratios of herbicide (mixture) to safener generally depends on the application rate of herbicide and the effectiveness of each safener and may vary within wide limits, for example in the range from 200: 1 to 1: 200, preferably 100: 1 to 1: 100, in particular 20: 1 to 1:20.
  • the safeners can be formulated analogously to the compounds of the formula (I) or mixtures thereof with further herbicides / pesticides and provided and used as finished formulation or tank mixture with the herbicides.
  • the combinations according to the invention have an excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous harmful plants such as weeds, including species which are resistant to herbicidal active substances such as glyphosate, glufosinate, atrazine or imidazolinone herbicides. Even difficult to control perennial weeds, which expel from rhizomes, rhizomes or other permanent organs, are well detected by the active ingredients.
  • the substances can be applied, for example, in pre-sowing, pre-emergence or post-emergence processes, for example jointly or separately. For example, the application is postemergence, in particular on the accumulated harmful plants.
  • the spectrum of activity extends to species such as Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharitis spp. , Polygonum spp., Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. and Viola spp., Xanthium spp., on the annual side, as well as Convolvulus, Cirsium, Rumex, and Artemisia in perennial weeds.
  • the compounds according to the invention are applied to the surface of the earth before germination, then either the emergence of the weed seedlings is completely prevented or the weeds grow up to the cotyledon stage, but then cease their growth and finally die off completely after a lapse of three to four weeks.
  • the herbicidal compositions of the invention are characterized by a rapidly onset and long-lasting herbicidal activity.
  • the rainfastness of the active ingredients in the combinations according to the invention is generally favorable.
  • a particular advantage is the fact that the effective and used in combinations combinations of compounds (A) and (B) can be set so low that their soil effect is optimally low. Thus, their use is not only possible in sensitive cultures, but groundwater contamination is virtually avoided.
  • By the combinations of active ingredients according to the invention a significant reduction of the required application rate of the active ingredients is made possible.
  • the agents for combating harmful plants can be used in known plant crops or tolerant or genetically modified crops to be developed.
  • the transgenic plants are usually characterized by particular advantageous properties, in addition to the resistance to the inventive compositions, for example, by resistance to plant diseases or pathogens of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses.
  • Other special properties relate to z. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients.
  • transgenic plants with increased starch content or altered quality of the starch or those with other fatty acid composition of Emteguts are known.
  • the active compounds can also be used to control harmful plants in crops of known or yet to be developed mutant-selected plants.
  • the production of plant cells with a reduced activity of a Gene product can be obtained, for example, by the expression of at least one corresponding antisense RNA, a sense RNA to obtain a cosuppression effect or the expression of at least one appropriately engineered ribozyme which specifically cleaves transcripts of the above gene product.
  • DNA molecules may be used which comprise the entire coding sequence of a gene product, including any flanking sequences that may be present, as well as DNA molecules which comprise only parts of the coding sequence, which parts must be long enough to be present in the cells to cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but are not completely identical.
  • the synthesized protein may be located in any compartment of the plant cell. But to achieve the localization in a particular compartment, z.
  • the coding region can be linked to DNA sequences that ensure localization in a particular compartment.
  • sequences are known to the person skilled in the art (see, for example Braun et al., EMBO J. 11 (1992). 3219-3227 ; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850 ; Sonnewald et al., Plant J. 1 (1991), 95-106 ).
  • the transgenic plant cells can be regenerated to whole plants by known techniques.
  • the transgenic plants may in principle be plants of any plant species, i. both monocotyledonous and dicotyledonous plants.
  • the present invention furthermore relates to a method for controlling undesirable plants, preferably in crops, characterized in that the herbicides (A) and (B) of the herbicidal combination according to the invention on the plants (eg harmful plants such as mono- or dicotyledonous weeds or undesirable crops), the seed (eg grains Seeds or vegetative propagules such as tubers or sprout parts with buds) or the area on which the plants grow (eg the cultivated area), for example together or separately.
  • One or more herbicides (A) may be applied before, after or simultaneously with the herbicide (s) (B) to the plants, seed or area on which the plants grow (eg the area under cultivation).
  • Undesirable plants are understood to mean all plants that grow in places where they are undesirable. This can e.g. Harmful plants (e.g., mono- or dicotyledonous weeds or undesired crops), e.g. also those which are resistant to certain herbicidal active substances such as glyphosate, atrazine, glufosinate or imidazolinone herbicides.
  • Harmful plants e.g., mono- or dicotyledonous weeds or undesired crops
  • certain herbicidal active substances such as glyphosate, atrazine, glufosinate or imidazolinone herbicides.
  • the herbicidal combinations of the invention will be used selectively to control undesired plant growth, e.g. in crops such as crops, e.g. monocotyledonous crops such as cereals (e.g., wheat, barley, rye, oats), rice, corn, millet, or dicotyledonous crops such as sugar beet, oilseed rape, cotton, sunflowers, and legumes, e.g. of the genera Glycine (eg Glycine max.
  • crops e.g. monocotyledonous crops such as cereals (e.g., wheat, barley, rye, oats), rice, corn, millet, or dicotyledonous crops such as sugar beet, oilseed rape, cotton, sunflowers, and legumes, e.g. of the genera Glycine (eg Glycine max.
  • crops e.g. monocotyledonous crops such as cereals (e.g., wheat, barley,
  • the invention also provides the use of the herbicidal combinations according to the invention for controlling undesired plant growth, preferably in crops.
  • the herbicidal combinations according to the invention can be prepared by known processes, for example as mixed formulations of the individual components, if appropriate with further active ingredients, additives and / or customary formulation auxiliaries, which are then diluted with water in a customary manner, or as so-called tank mixtures by joint dilution separately formulated or partially separately formulated components with water. Also possible is the staggered application (split application) of the separately formulated or partially separately formulated individual components. It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preference is given to the common or timely use of the active ingredients of the respective combination.
  • the herbicides (A) and (B) can be converted together or separately into customary formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, active substance-impregnated nature and synthetic substances, microencapsulations in polymeric substances.
  • the formulations may contain the usual auxiliaries and additives.
  • formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, that is to say liquid solvents, liquefied gases under pressure and / or solid carriers, if appropriate using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-forming agents.
  • extenders that is to say liquid solvents, liquefied gases under pressure and / or solid carriers, if appropriate using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-forming agents.
  • organic solvents can also be used as auxiliary solvent.
  • liquid solvents are essentially in question: aromatics such as xylene, toluene, alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, eg petroleum fractions, mineral and vegetable oils, alcohols such as butanol or Glycol and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, and water.
  • Suitable solid carriers are: e.g. Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates; as solid carriers for granules are: for example, broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corncobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g.
  • nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkylsulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Ligninsulfitablaugen and methylcellulose.
  • Adhesives such as carboxymethylcellulose, natural and synthetic, powdery, granular or latex polymers may be used in the formulations, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins and synthetic phospholipids.
  • Other additives may be mineral and vegetable oils.
  • the herbicidal action of the herbicide combinations according to the invention can be improved, for example, equally by surface-active substances, preferably wetting agents from the series of fatty alcohol polyglycol ethers.
  • the fatty alcohol polyglycol ethers preferably contain 10 - 18 C atoms in the The fatty alcohol polyglycol ethers may be nonionic, or ionic, for example in the form of fatty alcohol Polyglykolethersulfaten present, for example as alkali salts (eg sodium and potassium salts) or ammonium salts, or as alkaline earth salts such as magnesium salts be used, such as C 12 / C 14 fatty alcohol diglycol ether sulfate sodium (Genapol ® LRO, Clariant GmbH); see eg EP-A-0476555 . EP-A-0048436 . EP-A-0336151 or US-A-4,400,196 such as Proc. EWRS Symp.
  • Nonionic fatty alcohol polyglycol ethers are, for example, 2 - 20, preferably 3 - 15 ethylene oxide units containing (C 10 - C 18) -, preferably (C 10 -C 14) fatty alcohol polyglycol ethers (for example isotridecyl alcohol polyglycol ether), for example from the Genapol ® X series such as Genapol® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • Genapol ® X series such as Genapol® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • the present invention further comprises the combination of components A and B with the aforementioned wetting agents from the series of fatty alcohol polyglycol ethers which preferably contain 10 to 18 C atoms in the fatty alcohol radical and 2 to 20 ethylene oxide units in the polyglycol ether part and nonionic or ionic (for example as Fatty alcohol polyglycol ether sulfates) may be present.
  • fatty alcohol polyglycol ethers which preferably contain 10 to 18 C atoms in the fatty alcohol radical and 2 to 20 ethylene oxide units in the polyglycol ether part and nonionic or ionic (for example as Fatty alcohol polyglycol ether sulfates) may be present.
  • C 12 / C 14 -Fottalkohol diglycol ether sodium (Genapol ® LRO, Clariant GmbH) and isotridecyl alcohol polyglycol ether having 3-15 ethylene oxide units, for example from the Genapol ® X series, such as Genapol ® X-030, Genapol ® X -060, Genapol ® X-080 and Genapol ® X-150 (all from Clariant GmbH).
  • fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (eg fatty alcohol polyglycol ether) are also suitable as Penetrationsangesmlttel and effect enhancers for a number of other herbicides (see, eg EP-A-0502014 ).
  • fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (eg fatty alcohol polyglycol ether sulfates), are also suitable as penetrating aids and enhancers for a number of other herbicides (see, for example, US Pat EP-A-0502014 ).
  • the herbicidal action of the herbicidal combinations according to the invention can also be enhanced by the use of vegetable oils.
  • vegetable oils refers to oils from oil-supplying plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, thistle oil or castor oil, in particular rapeseed oil, and their transesterification products, e.g. Alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
  • the vegetable oils are preferably esters of C 10 -C 22 -, preferably C 12 -C 20 fatty acids.
  • the C 10 -C 22 fatty acid esters are, for example, esters of unsaturated or saturated C 10 -C 22 fatty acids, in particular having an even number of carbon atoms, for example erucic acid, lauric acid. Palmitic acid and in particular C 18 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • C 10 -C 22 fatty acid esters are esters which are obtained by reacting glycerol or glycol with the C 10 -C 22 fatty acids, as contained for example in oils from oil-yielding plant species, or C 1 -C 20 Alkyl C 10 -C 22 -Feftklare esters, as for example by transesterification of the aforementioned glycerol or glycol C 10 -C 22 fatty acid esters with C 1 -C 20 alcohols (eg, methanol, ethanol, propanol or Butanol) can be obtained.
  • the transesterification can be carried out by known methods, as described, for example, in US Pat Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart ,
  • Preferred C 1 -C 20 alkyl C 10 -C 22 fatty acid esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethylhexyl esters and dodecyl esters.
  • Preferred glycol and glycerol C 10 -C 22 fatty acid esters are the uniform or mixed glycol esters and glycerol esters of C 10 -C 22 fatty acids, in particular those having even numbers of carbon atoms, for example erucic, lauric, palmitic and especially C 18 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • the vegetable oils can be used in the herbicidal compositions of the invention, for example in the form commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten ® (Victorian Chemical Company, Australia, hereinbelow termed Hasten, main ingredient: rapeseed oil ethyl ester), Actirob ® B (Novance, France, hereinafter ActirobB called Main Ingredient: Rapsölmethylester), Rako-Binol (called Bayer AG, Germany, referred to as Rako-binol, main ingredient: rapeseed oil) ®, Renol ® (Stefes, hereinafter referred to Germany Renol, vegetable oil ingredient: Rapsölmethylester) or Stefes Mero ® (Stefes, Germany, termed Mero called main ingredient: Rapsölmethylester) be included.
  • Hasten ® Vanictorian Chemical Company, Australia, hereinbelow termed Hasten, main ingredient:
  • the present invention comprises combinations with the abovementioned vegetable oils such as rapeseed oil, preferably in the form of commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten® (Victorian Chemical Company, Australia, hereinafter referred to as Hasten, main constituent: rapeseed oil ethyl ester), Actirob ® s (Novance, France, hereinafter referred ActirobB, main ingredient: Rapsölmethylester), Rako-binol ® (Bayer AG, Germany, termed Rako-binol, main ingredient: rapeseed oil), Renol ® (Stefes, Germany, termed Renol, vegetable oil ingredient : Rapeseed oil methyl ester) or Stefes Mero® (Stefes, Germany, hereinafter referred to as Mero, main component: rapeseed oil methyl ester).
  • Hasten® Victorian Chemical Company, Australia, herein
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • the formulations generally contain between 0.1 and 95 percent by weight of active compound, preferably between 0.5 and 90 percent by weight.
  • the herbicides (A) and (B) can be used as such or in their formulations also in admixture with other agrochemical active substances such as known herbicides Control of undesirable plant growth, for example, for weed control or to control unwanted crops use, for example, finished formulations or tank mixes are possible.
  • the herbicides (A) and (B) can be applied as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules.
  • the application is done in the usual way, e.g. by pouring, spraying, spraying, sprinkling.
  • the active substances can be applied to the plants (for example harmful plants such as monocotyledonous or dicotyledonous weeds or undesired crop plants), the seed (for example grains, seeds or vegetative propagation organs such as tubers or shoot parts with buds) or the cultivated area (for example field soil), preferably to the green plants and parts of plants and, where appropriate, on the farmland.
  • harmful plants such as monocotyledonous or dicotyledonous weeds or undesired crop plants
  • the seed for example grains, seeds or vegetative propagation organs such as tubers or shoot parts with buds
  • the cultivated area for example field soil
  • a common herbicidal formulation of the combination of herbicides (A) and (B) according to the invention has the advantage of easier applicability, wherein the amounts of the components can be adjusted already in the optimal ratio to each other.
  • the adjuvants in the formulation can be optimally matched to one another.
  • Seeds or rhizome pieces of monocotyledonous and dicotyledonous weed plants were placed in sandy soil in cardboard pots and covered with soil.
  • the formulated in the form of wettable powders or emulsion concentrates active compounds (A) and (B) were then applied as aqueous suspensions or emulsions with a water application rate of 100 to 800 l / ha in different dosages on the surface of the cover soil.
  • the pots were placed in the greenhouse and kept under good growth conditions for the weeds.
  • the optical assessment of the plant damage and / or the emergence damage occurred after emergence of the test plants after a test time of 3 to 4 weeks in comparison to untreated controls. As the results show, the tested herbicidal combinations have a good herbicidal pre-emergence activity against a broad spectrum of grass weeds and weeds.
  • the herbicide combinations of the 2-iodo-N - [(4-methoxy-6-methyl-9,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and of the compounds of the formula (I) mentioned in Table A have Compounds of group B have very good synergistic herbicidal activity against harmful plants such as Sinapis alba, Chrysanthemum segetum, Avena sativa, Stellaria media, Echinochloa crus-galli, Lolium multiflorum, Setaria viridis, Abutilon theophrasti, Amaranthus retroflexus and Panicum miliaceum pre-emergence at an application rate of 100 g and less active substance per hectare.
  • Seeds or rhizome pieces of monocotyledonous and dicotyledonous weeds were placed in sandy loam soil in plastic pots, covered with soil and grown in the greenhouse under good growth conditions. Three weeks after sowing, the test plants were treated in the 2-4 leaf stage.
  • the compounds of the invention formulated as wettable powders or as emulsion concentrates were sprayed onto the green plant parts in various dosages with an amount of water applied of from 100 to 800 l / ha. After 3 to 4 weeks of life of the test plants in the greenhouse under optimal growth conditions, the effect of the preparations was visually scored compared to untreated controls.
  • the herbicidal combinations according to the invention have a good herbicidal activity against the emergence of a broad spectrum of economically important weeds and weeds.
  • the herbicide combinations of the 2-iodo-N - [ ⁇ 4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and of the compounds of the formula (I) mentioned in Table A have Group B compounds have very good synergistic herbicidal activity against harmful plants such as Sinapis alba, Echinochloa crus-galli, Digitaria sanguinalis, Lolium multiflorum, Chrysanthemum segetum, Setaria viridis, Polygonum convolvulus, Abutilon theophrasti, Amaranthus retroflexus, Panicum miliaceum and Avena sativa postemergence at one Application rate of 100 g and less active substance per hectare.

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Abstract

Die vorliegende Erfindung betrifft eine Herbizid-Kombination, enthaltend Komponenten (A) und (B), wobei
(A) ein oder mehrere Herbizide aus der Gruppe bestehend aus dem 2-Iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der allgemeinen Formel (I)

Figure imga0001
wobei
das Kation (M+)

(a) ein Ion der Alkalimetalle, bevorzugt Lithium, Natrium, Kalium, oder
(b) ein Ion der Erdalkalimetalle, bevorzugt Calcium und Magnesium, oder
(c) ein Ion der Übergangsmetalle, bevorzugt Mangan, Kupfer, Zink und Eisen, oder
(d) ein Ammonium-Ion, bei dem gegebenenfalls ein, zwei, drei oder alle vier Wasserstoffatome, durch gleiche oder verschiedene Reste aus der Gruppe (C1-C4)-Alkyl, Hydroxy-(C1-C4)-Alkyl, (C3-C6)-Cycloalkyl, (C1-C4)-Alkoxy-(C1-C4)-alkyl, Hydroxy-(C1-C4)-alkoxy-(C1-C4)-alkyl, (C1-C6)-Mercaptoalkyl, Phenyl oder Benzyl substituiert sind, wobei die zuvor genannten Reste gegebenenfalls durch einen oder mehrere, gleiche oder verschiedene Reste aus der Gruppe Halogen, wie F, Cl, Br oder I, Nitro, Cyano, Azido, (C1-C6)-Alkyl, (C1-C6)-Haloalkyl, (C3-C6)-Cycloalkyl, (C1-C6)-Alkoxy, (C1-C6)-Haloalkoxy und Phenyl sind, und wobei jeweils zwei Substituenten am N-Atom zusammen gegebenfalls einen unsubstituierten oder substituierten Ring bilden, oder
(e) ein Phosphonium-Ion, oder
(f) ein Sulfonium-lon, bevorzugt Tri-((C1-C4)-alkyl)-sulfonium, oder
(g) ein Oxonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-oxonium, oder
(h) eine gegebenenfalls einfach oder mehrfach annellierte und/oder durch (C1-C4)-Alkyl substituierte gesättigte oder ungesättigte/aromatische N-haltige heterocyclische ionische Verbindung mit 1-10 C-Atomen im Ringsystem
ist.
bedeutet, und
(B) ein oder mehrere Herbizide aus der Gruppe der (Sulfon)Amide bestehend aus:
beflubutamide, bromobutide, dimethenamide, dimethenamide-P, diphenamide, napropamide, pethoxamid, MT-5950, naptalam, propyzamide, diflufenican, etobenzanid, flufenacet, mefenacet, mefluidide, pentanochlor, picolinafen, propanil, N-phenylphtalamic acid, acetochlor, alachlor, butachlor, dimethachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, propachlor, propisochlor, thenylchlor, asulam, carbaryl, carbetamide, chlorpropham, desmedipham, phenmedipham, propham, butylate, cycloate, dimepiperate, EPTC, esprocarb, methasulfocarb, molinate, orbencarb, pebulate, prosulfocarb, pyributicarb, thiobencarb, tri-allate, vernolate, amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron-methyl-sodium, foramsulfuron, halosulfuron-methyl, imazosulfuron, iodosulfuron-methyl-sodium, mesosulfuron-methyl, metsulfuron-methyl, monosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron-methyl, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron, HNPC-C9908 (benzoic acid, 2-[[[[[4-methoxy-6-(methylthio)-2-pyrimidinyl]amino]carbonyl]amino]-sulfonyl]methylester), NC-330, NC-620, TH-547, flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam und pyroxsulam
bedeutet.The present invention relates to a herbicide combination containing components (A) and (B), wherein
(A) one or more herbicides selected from the group consisting of the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the general formula ( I)
Figure imga0001
 in which
the cation (M + )

(a) an ion of the alkali metals, preferably lithium, sodium, potassium, or
(b) an ion of the alkaline earth metals, preferably calcium and magnesium, or
(c) an ion of the transition metals, preferably manganese, copper, zinc and iron, or
(d) an ammonium ion in which optionally one, two, three or all four hydrogen atoms are represented by identical or different radicals from the group consisting of (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkyl , (C 3 -C 6) -cycloalkyl, (C 1 -C 4 ) -alkoxy- (C 1 -C 4 ) -alkyl, hydroxy- (C 1 -C 4 ) -alkoxy- (C 1 -C 4 ) alkyl, (C 1 -C 6) -Mercaptoalkyl, phenyl or benzyl substituted, where the radicals mentioned above optionally substituted by one or more identical or different radicals from the group halogen, such as F, Cl, Br or I, nitro Cyano, azido, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -haloalkyl, (C 3 -C 6 ) -cycloalkyl, (C 1 -C 6 ) -alkoxy, (C 1 -C 6 ) Haloalkoxy and phenyl, and wherein in each case two substituents on the N atom together optionally form an unsubstituted or substituted ring, or
(e) a phosphonium ion, or
(f) a sulfonium ion, preferably tri - ((C 1 -C 4 ) alkyl) sulfonium, or
(g) an oxonium ion, preferably tri - ((C 1 -C 4 ) alkyl) oxonium, or
(h) a saturated or unsaturated / aromatic N-containing heterocyclic ionic compound having 1-10 C atoms in the ring system which is optionally singly or multiply fused and / or substituted by (C 1 -C 4 ) -alkyl
is.
means, and
(B) one or more herbicides from the group of (sulfone) amides consisting of:
beflubutamide, bromobutide, dimethenamide, dimethenamide-P, diphenamide, napropamide, pethoxamide, MT-5950, naptalam, propyzamide, diflufenican, etobenzanide, flufenacet, mefenacet, mefluidide, pentanochlor, picolinafen, propanil, N-phenylphtalamic acid, acetochlor, alachlor, butachlor , dimethachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, propachlor, propisochlor, thenylchlor, asulam, carbaryl, carbetamide, chlorpropham, desmedipham, phenmedipham, propham, butylate, cycloate, dimepiperate, EPTC, esprocarb, methasulfocarb, molinate, orbencarb, pebulate , prosulfocarb, pyributicarb, thiobencarb, tri-allates, vernolate, amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron-methyl-sodium, foramsulfuron, halosulfuron -methyl, imazosulfuron, iodosulfuron-methyl-sodium, mesosulfuron-methyl, metsulfuron-methyl, monosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron-methyl, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron, HNPC-C9908 (benzoic acid, 2-) [[[[4-methoxy-6- (methylthio) -2-pyrimidinyl] amino] carbonyl] amino] sulfonyl] methyl ester), NC-330, NC-620, TH-547, flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam and pyroxsulam
means.

Description

Herbizid-Kombination enthaltend 2-Iodo-N-[(4-methoxy-6-methyl-1,3,6-triazin-2-yl)carbamoyl]benzolsulfonamids und/oder dessen Salze und herbizide Wirkstoffe aus der Gruppe der (Sulfon)Amide.Herbicide combination comprising 2-iodo-N - [(4-methoxy-6-methyl-1,3,6-triazin-2-yl) carbamoyl] benzenesulfonamide and / or its salts and herbicidal active compounds from the group of (sulfone) amides.

Die vorliegende Erfindung liegt auf dem technischen Gebiet der Pflanzenschutzmittel, die gegen unerwünschten Pflanzenwuchs, z.B. im Vorsaatverfahren (mit oder ohne Einarbeitung), im Vorauflauf oder im Nachauflauf in Kulturpflanzen wie beispielsweise in Weizen (Hart- und Weichweizen), Mais, Soja, Zuckerrübe, Zuckerrohr, Baumwolle, Reis, Bohnen (wie beispielsweise Buschbohne und Pferdebohne), Flachs, Gerste, Hafer, Roggen, Triticale, Raps, Kartoffel und Hirse (Sorghum), Flachs, Weidegras und Grün-/Rasenflächen eingesetzt werden.
Im Besonderen betrifft die Erfindung eine Herbizid-Kombination, enthaltend mindestens zwei Herbizide und deren Anwendung zur Bekämpfung unerwünschten Pflanzenwuchses.The present invention is in the technical field of pesticides, against unwanted plant growth, eg in Vorsaatverfahren (with or without incorporation), pre-emergence or postemergence in crops such as wheat (hard and soft wheat), corn, soy, sugar beet, Sugar cane, cotton, rice, beans (such as bush bean and horse bean), flax, barley, oats, rye, triticale, oilseed rape, potato and millet (sorghum), flax, pasture grass and green / lawns are used.
In particular, the invention relates to a herbicidal combination containing at least two herbicides and their use for controlling undesired plant growth.

Es ist bekannt, dass substituierte Phenylsulfonylhamstoffe, herbizide Eigenschaften aufweisen. Dabei handelt es sich z.B. um Phenylderivate, die einfach oder mehrfach substituiert sind (z.B. US 4127405 , WO 9209608 , BE 853374 , WO 9213845 , EP 84020 , WO 9406778 , WO 02072560 , US 4169719 , US4629494 , DE 4038430 ).It is known that substituted phenylsulfonylureas have herbicidal properties. These are, for example, phenyl derivatives which are monosubstituted or polysubstituted (for example US 4,127,405 . WO 9209608 . BE 853374 . WO 9213845 . EP 84020 . WO 9406778 . WO 02072560 . US 4169719 . US4629494 . DE 4038430 ).

Es ist weiter bekannt, dass bestimmte N-(1,3,5-Triazin-2-yl-aminocarbonyl)-arylsulfonamide herbizide Eigenschaften aufweisen (vgl. DE 2715 786 ). Die Herbizidwirkung dieser Verbindungen ist jedoch nicht in allen Belangen, wie beispielsweise Verträglichkeit, Wirkungsspektrum, Bekämpfung toleranter oder resistenter Arten, Verhalten gegenüber Folgekulturen oder Anwendungsflexibilität, zufriedenstellend.It is also known that certain N- (1,3,5-triazin-2-yl-aminocarbonyl) arylsulphonamides have herbicidal properties (cf. DE 2715 786 ). However, the herbicidal action of these compounds is not satisfactory in all respects, such as tolerability, spectrum of activity, control of tolerant or resistant species, behavior towards secondary crops or application flexibility.

Die herbizide Wirksamkeit der N-(1,3,5-Triazin-2-yl-aminocarbonyl)-arylsulfonamide gegen Schadpflanzen liegt bereits auf einem hohen Niveau, hängt jedoch im allgemeinen von der Aufwandmenge, der jeweiligen Zubereitungsform, den jeweils zu bekämpfenden Schadpflanzen oder dem Schadpflanzenspektrum, den Klima-und Bodenverhältnissen, etc. ab. Ein weiteres Kriterium ist die Dauer der Wirkung bzw. die Abbaugeschwindigkeit des Herbizids. Zu berücksichtigen sind gegebenenfalls auch Veränderungen in der Empfindlichkeit von Schadpflanzen, die bei längerer Anwendung der Herbizide oder geographisch begrenzt auftreten können. Wirkungsverluste bei einzelnen Pflanzen lassen sich nur bedingt durch höhere Aufwandmengen der Herbizide ausgleichen, z.B. weil damit die Selektivität der Herbizide reduziert wird oder eine Wirkungsverbesserung auch bei höherer Aufwandmenge nicht eintritt.The herbicidal activity of N- (1,3,5-triazin-2-yl-aminocarbonyl) -arylsulfonamide against harmful plants is already at a high level, but generally depends on the application rate, the particular preparation form, each to be controlled harmful plants or the harmful plant spectrum, the climate and soil conditions, etc. Another criterion is the duration of the action or the degradation rate of the herbicide. It may also be necessary to take account of changes in the susceptibility of harmful plants, which may occur with prolonged use of the herbicides or geographically. Losses of activity in individual plants can only be compensated to a limited extent by higher application rates of the herbicides, e.g. because it reduces the selectivity of the herbicides or does not improve the efficacy even at higher application rates.

Die Aufgabe der vorliegenden Erfindung bestand darin, ein verbessertes Pflanzenschutzmittel zur Verfügung zu stellen.The object of the present invention was to provide an improved crop protection agent.

Überraschenderweise wurde nun gefunden, dass diese Aufgabe durch Verwendung des 2-Iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamids und/oder dessen Salze in Kombination mit sich von diesen strukturell unterscheidenden Herbiziden aus der Gruppe der (Sulfon)Amide gelöste werden kann, die in besonders günstiger Weise zusammenwirken, z.B. wenn sie zur Bekämpfung von unerwünschtem Pflanzenwuchs in Kulturpflanzen wie Weizen (Hart- und Weichweizen), Mais, Soja, Zuckerrübe, Zuckerrohr, Baumwolle, Reis, Bohnen (wie beispielsweise Buschbohne und Pferdebohne), Flachs, Gerste, Hafer, Roggen, Triticale, Raps, Kartoffel und Hirse (Sorghum), Flachs, Weideland und Grün-/Rasenflächen eingesetzt werden.Surprisingly, it has now been found that this object is achieved by using the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and / or its salts in combination with can be solved by these structurally different herbicides from the group of (sulfone) amides, which interact in a particularly favorable manner, eg when used to control undesirable plant growth in crops such as wheat (hard and soft wheat), corn, soybeans, sugarbeet, sugarcane, cotton, rice, beans (such as common bean and horse bean), flax, barley, oats, rye, triticale, rapeseed , Potato and millet (sorghum), flax, pasture and green / lawns are used.

Verbindungen aus der Gruppe der (Sulfon)Amide, sind bereits als herbizide Wirkstoffe für die Bekämpfung von unerwünschtem Pflanzenwachstum bekannt; siehe hierzu beispielsweise EP 239414 , US 4288244 , DE 3303388 , US 5457085 , US 3120434 , US 3480671 , EP 206251 , EP 205271 , US 2556664 , US 3534098 , EP 53011 , US 04385927 , EP 348737 , DE 2822155 , US 3894078 , GB 869169 , EP 447004 , DE 1039779 , HU 176582 , US 3442945 , DE 2305495 , DE 2648008 , DE 2328340 , DE 1014380 , HU 53483 , US 4802907 , GB 1040541 , US 2903478 , US 3177061 , US 2695225 , DE 1567151 , GB 574995 , DE 1031571 , US 3175897 , JP 1098331 , US 2913327 , WO 8300329 , JP 80127302 , DE 1300947 , DE 2135768 , US 3175887 , US 3836524 , JP 85067463 , US 3582314 , US 53330821 , EP 131258 , US 4746353 , US 4420325 , US 4394506 , US 4127405 , US 4479821 , US 5009699 , EP, 136061 , EP 324569 , EP, 184385 , WO 2002030921 , WO 09215576 , WO 09529899 , US 4668277 , EP 305939 , WO 09641537 , WO 09510507 , EP 7677 , CN 01080116 , US 4789393 , EP 971902 , US 5209771 , EP 84020 , EP 120814 , EP 87780 , WO 08804297 , EP 477808 , EP 30142 , EP 44808 , EP 202830 , WO 09741112 , EP 336587 , DE 4038430 , CN 01323789 , EP 189069 , WO 2005103044 , WO 2003061388 , EP 507171 , WO 2001005788 , US 5163995 , EP 142152 , US 5828924 , WO 2002036595 und die in den zuvor genannten Druckschriften zitierte Literatur.Compounds from the group of (sulfone) amides are already known as herbicidal active substances for controlling unwanted plant growth; see for example EP 239414 . US 4288244 . DE 3303388 . US 5457085 . US 3,120,434 . US 3,480,671 . EP 206251 . EP 205271 . US 2556664 . US 3534098 . EP 53011 . US 04385927 . EP 348737 . DE 2822155 . US 3894078 . GB 869169 . EP 447004 . DE 1039779 . HU 176582 . US 3442945 . DE 2305495 . DE 2648008 . DE 2328340 . DE 1014380 . HU 53483 . US 4802907 . GB 1040541 . US 2903478 . US 3177061 . US 2695225 . DE 1567151 . GB 574995 . DE 1031571 . US 3,175,897 . JP 1098331 . US 2,913,327 . WO 8300329 . JP 80127302 . DE 1300947 . DE 2135768 . US 3,175,887 . US 3836524 . JP 85067463 . US 3582314 . US 53330821 . EP 131258 . US 4746353 . US 4420325 . US 4394506 . US 4,127,405 . US 4479821 . US 5009699 . EP, 136061 . EP 324569 . EP, 184385 . WO 2002030921 . WO 09/215576 . WO 09529899 . US 4668277 . EP 305939 . WO 09641537 . WO 09510507 . EP 7677 . CN 01080116 . US 4789393 . EP 971902 . US 5209771 . EP 84020 . EP 120814 . EP 87780 . WO 08804297 . EP 477808 . EP 30142 . EP 44808 . EP 202830 . WO 09741112 . EP 336587 . DE 4038430 . CN 01323789 . EP 189069 . WO 2005103044 . WO 2003061388 . EP 507171 . WO 2001005788 . US 5163995 . EP 142152 . US 5828924 . WO 2002036595 and the literature cited in the aforementioned references.

Gegenstand der vorliegenden Erfindung ist somit eine Herbizid-Kombination enthaltend Herbizide aus (A) und Herbizide aus (B), wobei

  1. (A) ein oder mehrere Herbizide aus der Gruppe bestehend aus dem 2-lodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der allgemeinen Formel (I)
    Figure imgb0001
     wobei
    das Kation (M+)
    (a) ein Ion der Alkalimetalle, bevorzugt Lithium, Natrium, Kalium, oder
    • (b) ein Ion der Erdalkalimetalle, bevorzugt Calcium und Magnesium, oder
    • (c) ein Ion der Übergangsmetalle, bevorzugt Mangan, Kupfer, Zink und Eisen, oder
    • (d) ein Ammonium-Ion, bei dem gegebenenfalls ein, zwei, drei oder alle vier Wasserstoffatome, durch gleiche oder verschiedene Reste aus der Gruppe (C1-C4)-Alkyl, Hydroxy-(C1-C4)-Alkyl, (C3-C6)-Cycloalkyl, (C1-C4)-Alkoxy-(C1-C4)-alkyl, Hydroxy-(C1-C4)-alkoxy-(C1-C4)-alkyl, (C1-C6)-Mercaptoalkyl, Phenyl oder Benzyl substituiert sind, wobei die zuvor genannten Reste gegebenenfalls durch einen oder mehrere, gleiche oder verschiedene Reste aus der Gruppe Halogen, wie F, Cl, Br oder I, Nitro, Cyano, Azido, (C1-C6)-Alkyl, (C1-C6)-Haloalkyl, (C3-C6)-Cycloalkyl, (C1-C6)-Alkoxy, (C1-C6)-Haloalkoxy und Phenyl substituiert sind, und wobei jeweils zwei Substituenten am N-Atom zusammen gegebenfalls einen unsubstituierten oder substituierten Ring bilden, oder
    • (e) ein Phosphonium-Ion, oder
    • (f) ein Sulfonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-sulfonium, oder
    • (g) ein Oxonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-oxonium, oder
    • (h) eine gegebenenfalls einfach oder mehrfach annellierte und/oder durch (C1-C4)-Alkyl substituierte gesättigte oder ungesättigte/aromatische N-haitige heterocyclische ionische Verbindung mit 1-10 C-Atomen im Ringsystem ist.
    bedeutet, und
  2. (B) ein oder mehrere Herbizide aus der Gruppe der (Sulfon)Amide bestehend aus:
    • der Untergruppe der Alkylamide (Untergruppe 1), bestehend aus: beflubutamide [CAS RN 113614-08-7] (= B1-1); bromobutide [CAS RN 74712-19-9] (= B1-2); dimethenamide [CAS RN 87674-68-8] (= B1-3); dimethenamide-P [CAS RN 163515-14-8] (= B1-4); diphenamide [CAS RN 957-51-7] (= B1-5); napropamide [CAS RN 15299-99-7] (= B1-6); pethoxamid [CAS RN 106700-29-2] (= B1-7); MT-5950, d.h. N-[3-Chlor-4-(1-methylethyl)-phenyl]-2-methylpentanamid [CAS RN 106827-21-8] (= B1-8);
    • der Untergruppe der Benzamide (Untergruppe 2), bestehend aus: naptalam [CAS RN 132-66-1] (= B2-1); propyzamide [CAS RN 23950-58-5] (= B2-2);
    • der Untergruppe der Anilide (Untergruppe 3), bestehend aus: diflufenican [CAS RN 83164-33-4] (= B3-1); etobenzanid [CAS RN 79540-50-4] (= B3-2); flufenacet [CAS RN 142459-58-3] (= B3-3); mefenacet [CAS RN 73250-68-7] (= B3-4); mefluidide [CAS RN 53780-34-0] (= B3-5); pentanochlor [CAS RN 2307-68-8] (= B3-6); picolinafen [CAS RN 137641-05-5] (= B3-7); propanil [CAS RN 709-98-8] (= B3-8); N-phenylphtalamic acid [CAS RN 4727-29-1] (= B3-9);
    • der Untergruppe der Chloracetanilide (Untergruppe 4) bestehend aus: acetochlor [CAS RN 34256-82-1] (= B4-1); alachlor [CAS RN 15972-60-8] (= B4-2); butachlor [CAS RN 23184-66-9] (= B4-3); dimethachlor [CAS RN 50563-36-5] (= B4-4); metazachlor [CAS RN 67129-08-2] (= B4-5); metolachlor [CAS RN 51218-45-2] (= B4-6); S-metolachlor [CAS RN 87392-12-9, (S)-Isomer, [CAS RN 178961-20-1, (R)-Isomer (= B4-7); pretilachlor [CAS RN 51218-49-6] (= B4-8); propachlor [CAS RN 1918-16-7] (= B4-9); propisochlor [CAS RN 86763-47-5] (2-chloro-6'-ethyl-N-isopropoxymethylaceto-o-toluidide) (= B4-10); thenylchlor [CAS RN 98491-05-3] (= B4-11);
    • der Untergruppe der Carbamate (Untegruppe 5), bestehend aus: asulam [CAS RN 3337-71-1] (= B5-1); carbaryl [CAS RN 63-25-2] (= B5-2); carbetamide [CAS RN 16118-49-3] (= B5-3); chlorpropham [CAS RN 101-21-3] (= B5-4); desmedipham [CAS RN 13684-56-5] (= B5-5); phenmedipham [CAS RN 13684-63-4] (= B5-6); propham [CAS RN 122-42-9] (= B5-7);
    • der Untergruppe der Thiocarbamate (Untergruppe 6), bestehend aus: butylate [CAS RN 2008-41-5] (= B6-1); cycloate [CAS RN 1134-23-2] (= B6-2); dimepiperate [CAS RN 61432-55-1] (= B6-3); EPTC [CAS RN 759-94-4] (= B6-4); esprocarb [CAS RN 85758-20-2] (= B6-5); methasulfocarb [CAS RN 66952-49-6] (= B6-6); molinate [CAS RN 2212-67-1] (= B6-7); orbencarb [CAS RN 34622-58-7] (= B6-8); pebulate [CAS RN 1114-71-2] (= B6-9); prosulfocarb [CAS RN 52888-80-9] (= B6-10); pyributicarb [CAS RN 88678-67-5] (= B6-11); thiobencarb [CAS RN 28249-77-6] (= B6-12); tri-allate [CAS RN 2303-17-5] (= B6-13); vernolate [CAS RN 1929-77-7] (= B6-14);
    • der Untergruppe der Sulfonylharnstoffe (Untergruppe 7), bestehend aus: amidosulfuron [CAS RN 120923-37-7] (= B7-1); azimsulfuron [CAS RN 120162-55-2] (= B7-2); bensulfuron-methyl [CAS RN 83055-99-6] (= B7-3); chlorimuron-ethyl [CAS RN 90982-32-4] (= B7-4); chlorsulfuron [CAS RN 64902-72-3] (= B7-5); cinosulfuron [CAS RN 94593-91-6] (= B7-6); cyclosulfamuron [CAS RN 136849-15-5] (= B7-7); ethametsulfuron-methyl [CAS RN 97780-06-8] (= B7-8); ethoxysulfuron [CAS RN 126801-58-9] (= B7-9); flazasulfuron [CAS RN 104040-78-0] (= B7-10); flucetosulfuron [CAS RN 412928-75-7] (= B7-11); flupyrsulfuron-methyl-sodium [CAS RN 144740-54-5] [(= B7-12); foramsulfuron [CAS RN 173159-57-4] (= B7-13); halosulfuron-methyl [[CAS RN 100784-20-1 (= B7-14); imazosulfuron [CAS RN 122548-33-8] (= B7-15); iodosulfuron-methyl-sodium [CAS RN 144550-36-7] (= B7-16); mesosulfuron-methyl [CAS RN 208465-21-8] (= B7-17); metsulfuron-methyl [CAS RN 74223-64-6] (= B7-18); monosulfuron [CAS RN 155860-63-2] (= B7-19); nicosulfuron [CAS RN 111991-09-4] (= B7-20); orthosulfamuron [CAS RN 213464-77-8] (= B7-21); oxasulfuron [CAS RN 144651-06-9] (= B7-22); primisulfuron-methyl [CAS RN 86209-51-0] (= B7-23); prosulfuron [CAS RN 94125-34-5] (= B7-24); pyrazosulfuron-ethyl [CAS RN 93697-74-6] (= B7-25); rimsulfuron [CAS RN 122931-48-0] (= B7-26); sulfometuron-methyl [CAS RN 74222-97-2] (= B7-27); sulfosulfuron [CAS RN 141776-32-1] (= B7-28); thifensulfuron-methyl [CAS RN 79277-27-3] (= B7-29); triasulfuron [CAS RN 82097-50-5] (= B7-30); tribenuron-methyl [CAS RN 101200-48-0] (= B7-31); trifloxysulfuron [CAS RN 145099-21-4] (sodium) (= B7-32); triflusulfuronmethyl [CAS RN 126535-15-7] (= B7-33); tritosulfuron [CAS RN 142469-14-51 (= B7-34); HNPC-C9908 [CAS RN 441050-97-1] (benzoic acid, 2-[[[[[4-methoxy-6-(methylthio)-2-pyrimidinyl]amino]carbonyl]amino]-sulfonyl]methylester) (= B7-35); NC-330 [CAS RN 104770-29-8] (= B7-36); NC-620 [CAS RN 868680-84-6] (= B7-37); TH-547 [CAS RN 570415-88-2] (= B7-38);
    • der Untergruppe der Sulfonylaminocarbonyltriazolinone (Untergruppe 8), bestehend aus:
      • flucarbazone-sodium [CAS RN 181274-17-9] (= B8-1); propoxycarbazone-sodium [CAS RN 181274-15-7] (= B8-2); thiencarbazone-methyl [CAS RN 317815-83-1] (= B8-3);
      • der Untergruppe der Triazolopyrimidine (Untergruppe 9), bestehend aus; cloransulam-methyl [147150-35-4] (= B9-1); diclosulam [CAS RN 145701-21-9] [(= B9-2); florasulam [CAS RN 145701-23-1] (= B9-3); flumetsulam [CAS RN 98967-40-9] (= B9-4); metosulam [CAS RN 139528-85-1] (= B9-5); penoxsulam [CAS RN 219714-96-2] (= B9-6); pyroxsulam [CAS RN 422556-08-9] (= B9-7);
bedeutet.The present invention thus relates to a herbicide combination comprising herbicides of (A) and herbicides of (B), wherein
  1. (A) one or more herbicides selected from the group consisting of the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the general formula ( I)
    Figure imgb0001
     in which
    the cation (M + )
    (a) an ion of the alkali metals, preferably lithium, sodium, potassium, or
    • (b) an ion of the alkaline earth metals, preferably calcium and magnesium, or
    • (c) an ion of the transition metals, preferably manganese, copper, zinc and iron, or
    • (d) an ammonium ion in which optionally one, two, three or all four hydrogen atoms are represented by identical or different radicals from the group consisting of (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkyl , (C 3 -C 6 ) -cycloalkyl, (C 1 -C 4 ) -alkoxy (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkoxy- (C 1 -C 4 ) alkyl, (C 1 -C 6) -Mercaptoalkyl, phenyl or benzyl substituted, where the radicals mentioned above optionally substituted by one or more identical or different radicals from the group halogen, such as F, Cl, Br or I, nitro Cyano, azido, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -haloalkyl, (C 3 -C 6 ) -cycloalkyl, (C 1 -C 6 ) -alkoxy, (C 1 -C 6 ) Haloalkoxy and phenyl are substituted, and wherein in each case two substituents on the N atom together optionally form an unsubstituted or substituted ring, or
    • (e) a phosphonium ion, or
    • (f) a sulfonium ion, preferably tri - ((C 1 -C 4 ) alkyl) sulfonium, or
    • (g) an oxonium ion, preferably tri - ((C 1 -C 4 ) alkyl) oxonium, or
    • (h) is an optionally mono- or poly-fused and / or (C 1 -C 4 ) alkyl-substituted saturated or unsaturated / aromatic N-containing heterocyclic ionic compound having 1-10 C atoms in the ring system.
    means, and
  2. (B) one or more herbicides from the group of (sulfone) amides consisting of:
    • the subgroup of alkylamides (subgroup 1), consisting of: beflubutamide [CAS RN 113614-08-7] (= B1-1); bromobutide [CAS RN 74712-19-9] (= B1-2); dimethenamide [CAS RN 87674-68-8] (= B1-3); dimethenamide-P [CAS RN 163515-14-8] (= B1-4); diphenamides [CAS RN 957-51-7] (= B1-5); napropamide [CAS RN 15299-99-7] (= B1-6); pethoxamide [CAS RN 106700-29-2] (= B1-7); MT-5950, ie N- [3-chloro-4- (1-methylethyl) phenyl] -2-methylpentanamide [CAS RN 106827-21-8] (= B1-8);
    • subgroup of benzamides (subgroup 2), consisting of: naptalam [CAS RN 132-66-1] (= B2-1); propyzamide [CAS RN 23950-58-5] (= B2-2);
    • the subgroup of anilides (subgroup 3), consisting of: diflufenican [CAS RN 83164-33-4] (= B3-1); etobenzanide [CAS RN 79540-50-4] (= B3-2); flufenacet [CAS RN 142459-58-3] (= B3-3); mefenacet [CAS RN 73250-68-7] (= B3-4); mefluidide [CAS RN 53780-34-0] (= B3-5); pentanochlor [CAS RN 2307-68-8] (= B3-6); picolinafen [CAS RN 137641-05-5] (= B3-7); propanil [CAS RN 709-98-8] (= B3-8); N-phenylphtalamic acid [CAS RN 4727-29-1] (= B3-9);
    • the subgroup of chloroacetanilides (subgroup 4) consisting of: acetochlor [CAS RN 34256-82-1] (= B4-1); alachlor [CAS RN 15972-60-8] (= B4-2); butachlor [CAS RN 23184-66-9] (= B4-3); dimethachlor [CAS RN 50563-36-5] (= B4-4); metazachlor [CAS RN 67129-08-2] (= B4-5); metolachlor [CAS RN 51218-45-2] (= B4-6); S-metolachlor [CAS RN 87392-12-9, (S) isomer, [CAS RN 178961-20-1, (R) isomer (= B4-7); pretilachlor [CAS RN 51218-49-6] (= B4-8); propachlor [CAS RN 1918-16-7] (= B4-9); propisochlor [CAS RN 86763-47-5] (2-chloro-6'-ethyl-N-isopropoxymethylaceto-o-toluidides) (= B4-10); thenylchlorine [CAS RN 98491-05-3] (= B4-11);
    • the subgroup of carbamates (Untegruppe 5), consisting of: asulam [CAS RN 3337-71-1] (= B5-1); carbaryl [CAS RN 63-25-2] (= B5-2); carbetamide [CAS RN 16118-49-3] (= B5-3); chlorpropham [CAS RN 101-21-3] (= B5-4); desmedipham [CAS RN 13684-56-5] (= B5-5); phenmedipham [CAS RN 13684-63-4] (= B5-6); propham [CAS RN 122-42-9] (= B5-7);
    • the subgroup of thiocarbamates (subgroup 6), consisting of: butylate [CAS RN 2008-41-5] (= B6-1); cycloate [CAS RN 1134-23-2] (= B6-2); dimepiperate [CAS RN 61432-55-1] (= B6-3); EPTC [CAS RN 759-94-4] (= B6-4); esprocarb [CAS RN 85758-20-2] (= B6-5); methasulfocarb [CAS RN 66952-49-6] (= B6-6); molinates [CAS RN 2212-67-1] (= B6-7); orbencarb [CAS RN 34622-58-7] (= B6-8); pebulate [CAS RN 1114-71-2] (= B6-9); prosulfocarb [CAS RN 52888-80-9] (= B6-10); pyributicarb [CAS RN 88678-67-5] (= B6-11); thiobencarb [CAS RN 28249-77-6] (= B6-12); tri-allate [CAS RN 2303-17-5] (= B6-13); vernolate [CAS RN 1929-77-7] (= B6-14);
    • the subgroup of sulphonylureas (subgroup 7), consisting of: amidosulfuron [CAS RN 120923-37-7] (= B7-1); azimsulfuron [CAS RN 120162-55-2] (= B7-2); bensulfuron-methyl [CAS RN 83055-99-6] (= B7-3); chlorimuron-ethyl [CAS RN 90982-32-4] (= B7-4); chlorosulfuron [CAS RN 64902-72-3] (= B7-5); cinosulfuron [CAS RN 94593-91-6] (= B7-6); cyclosulfamuronic acid [CAS RN 136849-15-5] (= B7-7); ethametsulfuron-methyl [CAS RN 97780-06-8] (= B7-8); ethoxysulfuron [CAS RN 126801-58-9] (= B7-9); flazasulfuron [CAS RN 104040-78-0] (= B7-10); flucetosulfuron [CAS RN 412928-75-7] (= B7-11); flupyrsulfuron-methyl-sodium [CAS RN 144740-54-5] [(= B7-12); foramsulfuron [CAS RN 173159-57-4] (= B7-13); halosulfuron-methyl [[CAS RN 100784-20-1 (= B7-14); imazosulfuron [CAS RN 122548-33-8] (= B7-15); iodosulfuron-methyl-sodium [CAS RN 144550-36-7] (= B7-16); mesosulfuron-methyl [CAS RN 208465-21-8] (= B7-17); metsulfuron-methyl [CAS RN 74223-64-6] (= B7-18); monosulfuron [CAS RN 155860-63-2] (= B7-19); nicosulfuron [CAS RN 111991-09-4] (= B7-20); orthosulfamuron [CAS RN 213464-77-8] (= B7-21); oxasulfuron [CAS RN 144651-06-9] (= B7-22); primisulfuron-methyl [CAS RN 86209-51-0] (= B7-23); prosulfuron [CAS RN 94125-34-5] (= B7-24); pyrazosulfuron-ethyl [CAS RN 93697-74-6] (= B7-25); rimsulfuron [CAS RN 122931-48-0] (= B7-26); sulfometuron-methyl [CAS RN 74222-97-2] (= B7-27); sulfosulfuron [CAS RN 141776-32-1] (= B7-28); thifensulfuron-methyl [CAS RN 79277-27-3] (= B7-29); triasulfuron [CAS RN 82097-50-5] (= B7-30); tribenuron-methyl [CAS RN 101200-48-0] (= B7-31); trifloxysulfuron [CAS RN 145099-21-4] (sodium) (= B7-32); triflusulfuron methyl [CAS RN 126535-15-7] (= B7-33); tritosulfuron [CAS RN 142469-14-51 (= B7-34); HNPC-C9908 [CAS RN 441050-97-1] (benzoic acid, 2 - [[[[[4-methoxy-6- (methylthio) -2-pyrimidinyl] amino] carbonyl] amino] sulfonyl] methyl ester) (= B7-35); NC-330 [CAS RN 104770-29-8] (= B7-36); NC-620 [CAS RN 868680-84-6] (= B7-37); TH-547 [CAS RN 570415-88-2] (= B7-38);
    • the subgroup of sulfonylaminocarbonyltriazolinones (subgroup 8), consisting of:
      • flucarbazone-sodium [CAS RN 181274-17-9] (= B8-1); propoxycarbazone-sodium [CAS RN 181274-15-7] (= B8-2); thiencarbazone-methyl [CAS RN 317815-83-1] (= B8-3);
      • the subgroup of triazolopyrimidines (subgroup 9), consisting of; cloransulam-methyl [147150-35-4] (= B9-1); diclosulam [CAS RN 145701-21-9] [(= B9-2); florasulam [CAS RN 145701-23-1] (= B9-3); flumetsulam [CAS RN 98967-40-9] (= B9-4); metosulam [CAS RN 139528-85-1] (= B9-5); penoxsulam [CAS RN 219714-96-2] (= B9-6); pyroxsulam [CAS RN 422556-08-9] (= B9-7);
means.

Die hinter den unter der Gruppe B genannten Bezeichnungen (Common name) in eckigen Klammem aufgeführte "CAS RN" entspricht der "Chemical Abstract Service Registry Number", einer allgemein gebräuchlichen Referenznummer, die eine eindeutige Zuordnung der bezeichneten Substanzen ermöglicht, da die "CAS RN" u.a. zwischen Isomeren, einschließlich Stereoisomeren, unterscheidet.The "CAS RN" listed in square brackets after the names mentioned under group B corresponds to the "Chemical Abstract Service Registry Number", a generally used reference number which permits a clear assignment of the named substances, since the "CAS RN "ua between isomers, including stereoisomers.

Als Herbizid (A) bevorzugt sind das 2-Iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der Formel (I), in denen das Kation (M+)

  1. (a) ein Ion der Alkalimetalle, bevorzugt Lithium, Natrium, Kalium, oder
  2. (b) ein Ion der Erdalkalimetalle, bevorzugt Calcium und Magnesium, oder
  3. (c) ein Ion der Übergangsmetalle, bevorzugt Mangan, Kupfer, Zink und Eisen, oder
  4. (d) ein Ammonium-Ion, bei dem gegebenenfalls ein, zwei, drei oder alle vier Wasserstoffatome, durch gleiche oder verschiedene Reste aus der Gruppe (C1-C4)-Alkyl, Hydroxy-(C1-C4)-Alkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy-(C1-C2)-alkyl, Hydroxy-(C1-C2)-alkoxy-(C1-C2)-alkyl, (C1-C2)-Mercaptoalkyl, Phenyl oder Benzyl substituiert sind, wobei die zuvor genannten Reste gegebenenfalls durch einen oder mehrere, gleiche oder verschiedene Reste aus der Gruppe Halogen, wie F, Cl, Br oder I, Nitro, Cyano, Azido, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy, (C1-C2)-Naloalkoxy und Phenyl substituiert sind und wobei jeweils zwei Substituenten am N-Atom zusammen gegebenfalls einen unsubstituierten oder substituierten Ring bilden, oder
  5. (e) ein quartäres Phosphonium-Ion, bevorzugt Tetra-((C1-C4)-alkyl)-phosphonium und Tetraphenyl-phosponium, wobei die (C1-C4)-Alkylreste und die Phenylreste gegebenenfalls einfach oder mehrfach mit gleichen oder verschiedenen Resten aus der Gruppe Halogen, wie F, Cl, Br oder I, (C1-C-2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy und (C1-C2)-Haloalkoxy substituiert sind, oder
  6. (f) ein tertiäres Sulfonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-sulfonium oder Triphenyl-sulfonium, wobei die (C1-C4)-Alkylreste und die Phenylreste gegebenenfalls einfach oder mehrfach mit gleichen oder verschiedenen Resten aus der Gruppe Halogen, wie F, Cl, Br oder I, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy und (C1-C2)-Haloalkoy substituiert sind, oder
  7. (g) ein tertiäres Oxonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-oxonium, wobei die (C1-C4)-Alkylreste gegebenenfalls einfach oder mehrfach mit gleichen oder verschiedenen Resten aus der Gruppe Halogen, wie F, Cl, Br oder I, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoy und (C1-C2)-Haloalkoxy substituiert sind, oder
  8. (h) ein Kation aus der Reihe der folgenden heterocyclischen Verbindungen, wie beispielsweise Pyridin, Chinolin, 2-Methylpyridin, 3-Methylpyridin, 4-Methylpyridin, 2,4-Dimethylpyridin, 2,5-Dimethylpyridin, 2,6-Dimethylpyridin, 5-Ethyl-2-methylpyridin, Piperidin, Pyrrolidin, Morpholin, Thiomorpholin, Pyrrol, Imidazol, 1,5-Diazabicyclo[4.3.0]non-5-en (DBN), 1,8-Diazabicyclo[5.4.0]undec-7-en (DBU) ist.
Preferred herbicides (A) are 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I) in which the cation (M + )
  1. (a) an ion of the alkali metals, preferably lithium, sodium, potassium, or
  2. (b) an ion of the alkaline earth metals, preferably calcium and magnesium, or
  3. (c) an ion of the transition metals, preferably manganese, copper, zinc and iron, or
  4. (d) an ammonium ion in which optionally one, two, three or all four hydrogen atoms are represented by identical or different radicals from the group consisting of (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkyl , (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoxy- (C 1 -C 2 ) -alkyl, hydroxy- (C 1 -C 2 ) -alkoxy- (C 1 -C 2 ) alkyl, (C 1 -C 2) -Mercaptoalkyl, phenyl or benzyl substituted, where the radicals mentioned above optionally substituted by one or more identical or different radicals from the group halogen, such as F, Cl, Br or I, nitro Cyano, azido, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 2 ) -Haloalkoxy and phenyl are substituted and wherein in each case two substituents on the N-atom together optionally form an unsubstituted or substituted ring, or
  5. (E) a quaternary phosphonium ion, preferably tetra - ((C 1 -C 4 ) alkyl) phosphonium and tetraphenyl-phosphonium, where the (C 1 -C 4 ) -alkyl radicals and the phenyl radicals optionally mono- or polysubstituted by identical or different residues from the group halogen, such as F, Cl, Br or I, (C 1 -C- 2) alkyl, (C 1 -C 2) -haloalkyl, (C 3 -C 4) -cycloalkyl, (C 1 -C 2 ) -alkoxy and (C 1 -C 2 ) -haloalkoxy, or
  6. (F) a tertiary sulfonium ion, preferably tri - ((C 1 -C 4 ) alkyl) sulfonium or triphenyl-sulfonium, where the (C 1 -C 4 ) -alkyl radicals and the phenyl radicals are optionally mono- or polysubstituted by identical or different radicals from the group halogen, such as F, Cl, Br or I, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoxy and ( C 1 -C 2 ) -Haloalkoy are substituted, or
  7. (g) a tertiary oxonium ion, preferably tri - ((C 1 -C 4 ) alkyl) oxonium, where the (C 1 -C 4 ) -alkyl radicals are optionally mono- or polysubstituted by identical or different radicals from the group consisting of halogen such as F, Cl, Br or I, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoy and (C 1 -C 2 ) -haloalkoxy substituted, or
  8. (h) a cation from the series of the following heterocyclic compounds, such as pyridine, quinoline, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2,4-dimethylpyridine, 2,5-dimethylpyridine, 2,6-dimethylpyridine, 5 Ethyl 2-methylpyridine, piperidine, pyrrolidine, morpholine, thiomorpholine, pyrrole, imidazole, 1,5-diazabicyclo [4.3.0] non-5-ene (DBN), 1,8-diazabicyclo [5.4.0] undec- 7-en (DBU) is.

Die bei den Restedefinitionen genannten Kohlenwasserstoffreste, wie Alkyl, Alkenyl oder Alkinyl, auch in Kombinationen mit Heteroatomen, wie in Alkoxy, Alkylthio, Haloalkyl oder Alkylamino, sind auch dann, wenn dies nicht ausdrücklich angegeben ist, geradkettig oder verzweigt.The hydrocarbon radicals mentioned in the radical definitions, such as alkyl, alkenyl or alkynyl, also in combinations with heteroatoms, such as in alkoxy, alkylthio, haloalkyl or alkylamino, are also straight-chain or branched, even if not expressly stated.

Beispiele für als Herbizid (A) bevorzugt verwendete Verbindungen sind das 2-lodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid (A-0) und die in der nachfolgenden Tabelle A genannten Verbindungen der Formel (I) (d.h. der Verbindungen (A-1 bis A-35)). Tabelle A: Verbindungen der allgemeinen Formel (I), wobei durch M+ das jeweilige Salz der bezeichnet ist

Figure imgb0002
Verbindung M+ A-1 Lithium A-2 Natrium A-3 Kalium A-4 Magnesium A-5 Calcium A-6 Ammonium A-7 Methylammonium A-8 Dimethylammonium A-9 Tetramethylammonium A-11 Ethylammonium A-11 Diethylammonium A-12 Tetraethylammonium A-13 Propylammonium A-14 Tetrapropylammonium A-15 Isopropylammonium A-16 Diisopropylammonium A-17 Butylammonium A-18 Tetrabutylammonium A-19 (2-Hydroxyeth-1-yl)ammonium A-20 Bis-N,N-(2-hydroxyeth-1-yl)ammonium A-21 Tris-N,N,N-(2-hydroxyeth-1-yl)ammonium A-22 1-Phenylethylammonium A-23 2-Phenylethylammonium A-24 Trimethylsulfonium A-25 Trimethyloxonium A-26 Pyridinium A-27 2-Methylpyridinium A-28 4-Methylpyridinium A-29 2,4-Dimethylpyridinium A-30 2,6-Dimethylpyridinium A-31 Piperidinium A-32 Imidazolium A-33 Morpholinium A-34 1,5-Diazabicyclo[4.3.0]non-7-enium A-35 1,8-Diazabicyclo[5.4.0]undec-7-enium Examples of compounds preferably used as the herbicide (A) are the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide (A-0) and the compounds of the formula (I) mentioned in Table A below (ie the compounds (A-1 to A-35)). Table A: Compounds of the general formula (I), where M <sup> + </ sup> denotes the respective salt
Figure imgb0002
 connection M + A-1 lithium A-2 sodium A-3 potassium A-4 magnesium A-5 calcium A-6 ammonium A-7 methylammonium A-8 dimethyl A-9 Tetramethylammonium A-11 ethylammonium A-11 diethylammonium A-12 tetraethylammonium A-13 propylammonium A-14 tetrapropylammonium A-15 isopropylammonium A-16 diisopropylammonium A-17 butylammonium A-18 tetrabutylammonium A-19 (2-hydroxyeth-1-yl) ammonium A-20 Bis-N, N- (2-hydroxyeth-1-yl) ammonium A-21 Tris-N, N, N- (2-hydroxyeth-1-yl) ammonium A-22 1-phenylethylammonium A-23 2-phenylethylammonium A-24 trimethylsulfonium A-25 trimethyloxonium A-26 pyridinium A-27 2-methylpyridinium A-28 4-methylpyridinium A-29 2,4-dimethylpyridinium A-30 2,6-dimethylpyridinium A-31 piperidinium A-32 imidazolium A-33 morpholinium A-34 1,5-diazabicyclo [4.3.0] non-7-enium A-35 1,8-diazabicyclo [5.4.0] undec-7-enium

Als Herbizid (A) besonders bevorzugt sind das 2-Iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der Formel (I), in denen das Kation (M+)
ein Natrium-Ion, ein Kalium-Ion, ein Lithium-Ion, ein Magnesium-Ion, ein Calcium-Ion, ein NH4 +-Ion, ein (2-Hydroxyeth-1-yl)ammonium-Ion, Bis-N,N-(2-hydroxyeth-1-yl)ammonium-Ion, Tris-N,N,N-(2-hydroxyeth-1-yl)ammonium-Ion, ein Methylammonium-Ion, ein Dimethylammonium-Ion, ein Trimethylammonium-Ion, ein Tetramethylammonium-Ion ein Ethylammonium-Ion, ein Diethylammonium-Ion, ein Triethylammonium-Ion, ein Tretraethylammonium-Ion ein Isopropylammonium-Ion, ein Diisopropylammonium-Ion, ein Tetrapropylammonium-Ion, ein Tetrabutylammonium-Ion, ein 2-(2-Hydroxyeth-1-oxy)eth-1-yl-ammonium-Ion, ein Di-(2-hydroxyeth-1-yl)-ammonium-Ion, ein Trimethylbenzylammonium-Ion, ein Tri-((C1-C4)-alkyl)-sulfonium-Ion, oder ein Tri-((C1-C4)-alkyl)-oxonium-Ion, ein Benzylammonium-Ion, ein 1-Phenylethylammonium-Ion, ein 2-Phenylethylammonium-Ion. ein Diisopropylethylammonium-Ion, ein Pyridinium-Ion, ein Piperidinium-Ion, ein Imidazolium-Ion, ein Morpholinium-Ion, ein 1,8-Diazabicyclo[5.4.0]undec-7-enium-Ion ist.Particularly preferred herbicides (A) are 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I) in which the cation (M + )
a sodium ion, a potassium ion, a lithium ion, a magnesium ion, a calcium ion, an NH 4 + ion, a (2-hydroxyeth-1-yl) ammonium ion, Bis-N, N- (2-hydroxyeth-1-yl) ammonium ion, Tris-N, N, N- (2-hydroxyeth-1-yl) ammonium ion, a methyl ammonium ion, a dimethyl ammonium ion, a trimethyl ammonium ion , a tetramethylammonium ion, an ethylammonium ion, a diethylammonium ion, a triethylammonium ion, a tretraethylammonium ion, an isopropylammonium ion, a diisopropylammonium ion, a tetrapropylammonium ion, a tetrabutylammonium ion, a 2- (2- Hydroxyeth-1-oxy) eth-1-yl-ammonium ion, a di- (2-hydroxyeth-1-yl) ammonium ion, a trimethylbenzylammonium ion, a tri - ((C 1 -C 4 ) - alkyl) sulfonium ion, or a tri - ((C 1 -C 4 ) alkyl) oxonium ion, a benzylammonium ion, a 1-phenylethylammonium ion, a 2-phenylethylammonium ion. a diisopropylethylammonium ion, a pyridinium ion, a piperidinium ion, an imidazolium ion, a morpholinium ion, a 1,8-diazabicyclo [5.4.0] undec-7-enium ion.

Als Herbizid (A) besonders bevorzugt sind das 2-Iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der Formel (I), in denen das Kation (M+) ein Natrium-Ion, ein Kalium-Ion, ein Magnesium-Ion, ein Calcium-Ion, oder ein NH4 +-Ion ist.Particularly preferred herbicides (A) are 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I) in which the cation (M + ) is a sodium ion, a potassium ion, a magnesium ion, a calcium ion, or a NH 4 + ion.

Als Herbizid (A) ebenfalls besonders bevorzugt sind das 2-Iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der Formel (I), in denen das Kation (M+), in denen das Kation (M+) ein Natrium-Ion, ein Kalium-Ion oder ein NH4-Ion.As herbicide (A) also particularly preferred are the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the formula (I), in those containing the cation (M + ), in which the cation (M + ) is a sodium ion, a potassium ion or an NH 4 ion.

Als Herbizid (B) bevorzugte Verbindungen sind:
dimethenamide (= B1-3); dimethenamide-P (= B1-4); napropamide (= B1-6); pethoxamid (= B1-7); propyzamide (= B2-2); diflufenican (= B3-1); flufenacet (= B3-3); mefenacet (= B3-4); picolinafen (= B3-7); propanil (= B3-8); acetochlor (= B4-1); alachlor (= B4-2); butachlor (= B4-3); metazachlor (= B4-5); metolachlor (= B4-6); S-metolachlor (= B4-7); pretilachlor (= B4-8); thenylchlor (= B4-11); asulam (= B5-1); carbetamide (= B5-3); desmedipham (= B5-5); phenmedipham (= B5-6); esprocarb (= B6-5); molinate (= B6-7); prosulfocarb (= B6-10); thiobencarb (= B6-12); amidosulfuron (= B7-1); chlorimuron-ethyl (= B7-4); cyclosulfamuron (= B7-7); ethoxysulfuron (= B7-9); flupyrsulfuron-methyl-sodium (= B7-12); foramsulfuron (= B7-13); iodosulfuron-methyl-sodium (= B7-16); mesosulfuron-methyl (= B7-17); nicosulfuron (= B7-20); orthosulfamuron (= B7-21); prosulfuron (= B7-24); pyrazosulfuron-ethyl (= B7-25); rimsulfuron (= B7-26); trifloxysulfuron (sodium) (= B7-32); flucarbazone-sodium (= B8-1); propoxycarbazone-sodium (= B8-2); thiencarbazone-methyl (= B8-3); florasulam (= B9-3); metosulam (= B9-5); penoxsulam (=B9-6.As herbicide (B) preferred compounds are:
dimethenamide (= B1-3); dimethenamide-P (= B1-4); napropamide (= B1-6); pethoxamide (= B1-7); propyzamide (= B2-2); diflufenican (= B3-1); flufenacet (= B3-3); mefenacet (= B3-4); picolinafen (= B3-7); propanil (= B3-8); acetochlor (= B4-1); alachlor (= B4-2); butachlor (= B4-3); metazachlor (= B4-5); metolachlor (= B4-6); S-metolachlor (= B4-7); pretilachlor (= B4-8); thenylchlor (= B4-11); asulam (= B5-1); carbetamide (= B5-3); desmedipham (= B5-5); phenmedipham (= B5-6); esprocarb (= B6-5); molinates (= B6-7); prosulfocarb (= B6-10); thiobencarb (= B6-12); amidosulfuron (= B7-1); chlorimuron-ethyl (= B7-4); cyclosulfamuron (= B7-7); ethoxysulfuron (= B7-9); flupyrsulfuron-methyl-sodium (= B7-12); foramsulfuron (= B7-13); iodosulfuron-methyl-sodium (= B7-16); mesosulfuron-methyl (= B7-17); nicosulfuron (= B7-20); orthosulfamuron (= B7-21); prosulfuron (= B7-24); pyrazosulfuron-ethyl (= B7-25); rimsulfuron (= B7-26); trifloxysulfuron (sodium) (= B7-32); flucarbazone-sodium (= B8-1); propoxycarbazone-sodium (= B8-2); thiencarbazone-methyl (= B8-3); florasulam (= B9-3); metosulam (= B9-5); penoxsulam (= B9-6.

Als Herbizid (B) besonders bevorzugte Verbindungen sind: dimethenamide-P (= B1-4); napropamide (= B1-6); diflufenican (= B3-1); flufenacet (= B3-3); mefenacet (= B3-4; acetochlor (= B4-1); metazachlor (= B4-5); S-metolachlor (= B4-7); asulam (= B5-1); desmedipham (= B6-5); phenmedipham (= B5-6); molinate (= B6-7); prosulfocarb (= B6-10); amidosulfuron (= B7-1); ethoxysulfuron (= B7-9); foramsulfuron (= B7-13); iodosulfuron-methyl-sodium (= B7-16); mesosulfuron-methyl (= B7-17); flucarbazone-sodium (= B8-1); propoxycarbazone-sodium (= B8-2); thiencarbazone-methyl (= B8-3); florasulam (= B9-3); metosulam (= B9-5).As herbicide (B), particularly preferred compounds are: dimethenamide-P (= B1-4); napropamide (= B1-6); diflufenican (= B3-1); flufenacet (= B3-3); mefenacet (= B3-4; acetochlor (= B4-1); metazachlor (= B4-5); S-metolachlor (= B4-7); asulam (= B5-1); desmedipham (= B6-5); phenmedipham (= B5-6), molinate (= B6-7), prosulfocarb (= B6-10), amidosulfuron (= B7-1), ethoxysulfuron (= B7-9), foramsulfuron (= B7-13), iodosulfuron-methyl -sodium (= B7-16); mesosulfuron-methyl (= B7-17); flucarbazone-sodium (= B8-1); propoxycarbazone-sodium (= B8-2); thiencarbazone-methyl (= B8-3); florasulam (= B9-3); metosulam (= B9-5).

Die erfindungsgemäßen Herbizid-Kombinationen können zusätzliche weitere Komponenten enthalten, z. B. agrochemische Wirkstoffe anderer Art und/oder im Pflanzenschutz übliche Zusatzstoffe und/oder Formulierungshilfsmittel, oder zusammen mit diesen eingesetzt werden.The herbicide combinations of the invention may contain additional additional components, e.g. As agrochemical agents of other types and / or customary in plant protection additives and / or formulation auxiliaries, or used together with these.

Die Herstellung von Salzen 2-Iodo-N-[(4-methoxy-8-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamids, insbesondere von Verbindungen der allgemeinen Fomel (I), ist nach dem Stand der Technik bekannt, vgl. hierzu auch die zeitgleich eingereichte europäische Patentanmeldung der Bayer CropScience AG mit dem Titel "Salze des 2-Iodo-N-[(4-methox-6-methyl-1,3,5-triain-2-yl)carbamoyl]benzolsulfonamids, Verfahren zu deren Herstellung, sowie deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren".The preparation of salts of 2-iodo-N - [(4-methoxy-8-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide, in particular of compounds of the general formula (I), is known in the art known in the art, cf. See also the concurrently filed European Patent Application of Bayer CropScience AG entitled "Salts of 2-iodo-N - [(4-methox-6-methyl-1,3,5-triain-2-yl) carbamoyl] benzenesulfonamide, process for their production, and their use as herbicides and plant growth regulators ".

In bevorzugter Ausführungsform enthalten die erfindungsgemäßen Herbizid-Kombinationen die Herbizide (A) und (B) in einem wirksamen Gehalt und/oder weisen synergistische Wirkungen auf. Die synergistischen Wirkungen können z.B. bei gemeinsamer Ausbringung der Herbizide (A) und (B) beispielsweise als Co-Formulierung oder als Tank-Mischung beobachtet werden, sie können jedoch auch bei zeitlich versetzter Anwendung (Splitting) festgestellt werden. Möglich ist auch die Anwendung der Herbizide oder der Herbizid-Kombinationen in mehreren Portionen (Sequenzanwendung), z. B. nach Anwendungen im Vorauflauf, gefolgt von Nachauflauf-Applikationen oder nach frühen Nachauflaufanwendungen, gefolgt von Applikationen im mittleren oder späten Nachauflauf. Bevorzugt ist dabei die gemeinsame oder die zeitnahe Anwendung der Herbizide (A) und (B) der jeweiligen Kombination.In a preferred embodiment, the herbicidal combinations according to the invention contain the herbicides (A) and (B) in an effective content and / or have synergistic effects. The synergistic effects can be observed, for example, when the herbicides (A) and (B) are applied together, for example as a co-formulation or as a tank mixture, but they can also be detected in the case of splitting. It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preferred is the joint or timely application of the herbicides (A) and (B) of the respective combination.

Die synergistischen Effekte erlauben eine Reduktion der Aufwandmengen der Einzelherbizide, eine höhere Wirkungsstärke bei gleicher Aufwandmenge, die Kontrolle bislang nicht erfasster Arten (Lücken), die Kontrolle von Arten, die Toleranzen oder Resistenzen gegenüber einzelnen oder mehreren Herbiziden aufweisen, eine Ausdehnung des Anwendungszeitraums und/oder eine Reduzierung der Anzahl notwendiger Einzelanwendungen und - als Resultat für den Anwender - ökonomisch und ökologisch vorteilhaftere Unkrautbekämpfungssysteme.The synergistic effects allow a reduction in the application rates of the individual herbicides, a higher potency at the same rate, the control of previously unrecognized species (gaps), the control of species that have tolerances or resistance to single or multiple herbicides, an extension of the period of application and / or a reduction in the number of individual applications required and - as a result for the user - economically and ecologically more advantageous weed control systems.

Bespielsweise werden durch die erfindungsgemäßen Kombinationen aus Herbiziden (A)+(B) synergistische Wirkungssteigerungen möglich, die weit und in unerwarteter Weise über die Wirkungen hinausgehen, die mit den Einzelherbiziden (A) und (B) erreicht werden.For example, the combinations of herbicides (A) + (B) according to the invention make possible synergistic increases in activity which go far and unexpectedly beyond the effects achieved with the individual herbicides (A) and (B).

Die genannte Formel (I) umfaßt alle Stereoisomeren und deren Gemische, insbesondere auch racemische Gemische, und - soweit Enantiomere möglich sind - das jeweils biologisch wirksame Enantiomere.Said formula (I) comprises all stereoisomers and mixtures thereof, in particular racemic mixtures, and - as far as enantiomers are possible - the respective biologically active enantiomers.

Die Herbizide der Gruppe (A) hemmen das Enzym Acetolactatsynthase (ALS) und damit die Proteinbiosynthese in Pflanzen. Die Aufwandmenge der Herbizide (A) kann in einem weiten Bereich variieren, beispielsweise zwischen 0,001 g und 1500 g AS/ha (AS/ha bedeutet dabei im folgenden "Aktivsubstanz pro Hektar" = bezogen auf 100%igen Wirkstoff). Bei Anwendungen mit Aufwandmengen von 0,001 g bis 1500 g AS/ha der Herbizide (A), vorzugsweise der Verbindungen A-0 bis A-35, wird im Vor- und Nachauflaufverfahren ein relativ breites Spektrum an Schadpflanzen bekämpft, z.B. an annuellen und perennierenden, mono- oder dikotylen Unkräutern sowie an unerwünschten Kulturpflanzen. Bei den erfindungsgemäßen Kombinationen liegen die Aufwandmengen in der Regel niedriger, z. B. im Bereich von 0,001 g bis 1000 g AS/ha, vorzugsweise 0,1 g bis 500 g AS/ha, besonders bevorzugt 0,5 g bis 250 g AS/ha.The herbicides of group (A) inhibit the enzyme acetolactate synthase (ALS) and thus protein biosynthesis in plants. The application rate of the herbicides (A) can vary within a wide range, for example between 0.001 g and 1500 g AS / ha (AS / ha in the following means "active substance per hectare" = based on 100% active ingredient). In applications with application rates of 0.001 g to 1500 g AS / ha of the herbicides (A), preferably the compounds A-0 to A-35, pre-emergence and post-emergence a relatively broad spectrum of harmful plants is fought, for example at annuellen and perenning, monocotyledonous or dicotyledonous weeds as well as unwanted crops. In the combinations according to the invention, the application rates are generally lower, z. B. in the range of 0.001 g to 1000 g AS / ha, preferably 0.1 g to 500 g AS / ha, more preferably 0.5 g to 250 g AS / ha.

Die Herbizide der Gruppe (B) beeinflussen beispielsweise die Fettsäurebiosynthese, Zellteilung, das Photosystem II und Acetolactatsynthase und eignen sich sowohl für einen Einsatz im Vorauflauf wie auch im Nachauflauf. Die Aufwandmenge der Herbizide (B) kann in einem weiten Bereich variieren, beispielsweise zwischen 0,001 g und 15000 g AS/ha (AS/ha bedeutet dabei im folgenden "Aktivsubstanz pro Hektar" = bezogen auf 100%igen Wirkstoff). Bei Anwendungen mit Aufwandmengen von 0,01 g bis 10000 g AS/ha der Herbizide (B), vorzugsweise der Verbindungen B(1-1) bis B(9-7), wird im Vor- und Nachauflaufverfahren ein relativ breites Spektrum an Schadpflanzen bekämpft, z.B. an annuellen und perennierenden, mono- oder dikotylen Unkräutern sowie an unerwünschten Kulturpflanzen. Bei den erfindungsgemäßen Kombinationen liegen die Aufwandmengen in der Regel niedriger, z. B. im Bereich von 0,05 g bis 15000 g AS/ha, vorzugsweise 0,1 g bis 10000 g AS/ha, besonders bevorzugt 0.5 g bis 8000 g AS/ha.The herbicides of group (B) influence, for example, the fatty acid biosynthesis, cell division, photosystem II and acetolactate synthase and are suitable for both pre-emergence and post-emergence applications. The application rate of the herbicides (B) can vary within a wide range, for example between 0.001 g and 15000 g AS / ha (AS / ha in the following means "active substance per hectare" = based on 100% active ingredient). For applications at application rates of 0.01 g to 10000 g AS / ha of the herbicides (B), preferably the compounds B (1-1) to B (9-7), in pre- and post-emergence a relatively wide range of harmful plants fights, eg on annual and perennial, monocotyledonous or dicotyledonous weeds and on unwanted crops. In the combinations according to the invention, the application rates are generally lower, z. B. in the range of 0.05 g to 15000 g AS / ha, preferably 0.1 g to 10000 g AS / ha, more preferably 0.5 g to 8000 g AS / ha.

Bevorzugt sind Herbizid-Kombinationen aus einem oder mehreren Herbiziden (A) mit einem oder mehreren Herbiziden (B). Weiter bevorzugt sind Kombinationen von Herbiziden (A) mit einem oder mehreren Herbiziden (B) nach dem Schema: (A-0) + (B1-1), (A-0) + (B1-2), (A-0) + (B9-7), (A-1) + (B1-1), (A-1) + (B1-2), (A-1) + (B9-7), (A-35) + (B1-1), (A-35) + (B1-2), (A-35) + (B9-7). Dabei sind auch solche Kombinationen erfindungsgemäß, die noch ein oder mehrere weitere von Herbiziden (A) und (B) verschiedene agrochemische Wirkstoffe, die ebenfalls die Funktion eines selektiven Herbizids aufweisen, enthalten.Preference is given to herbicide combinations of one or more herbicides (A) with one or more herbicides (B). Further preferred are combinations of herbicides (A) with one or more herbicides (B) according to the scheme: (A-0) + (B1-1), (A-0) + (B1-2), (A-0) + (B9-7), (A-1) + (B1-1), (A-1) + (B1-2), (A-1) + (B9-7), (A-35) + ( B1-1), (A-35) + (B1-2), (A-35) + (B9-7). In this case, those combinations according to the invention which also contain one or more other herbicides (A) and (B) different agrochemical active compounds, which also have the function of a selective herbicide.

Für Kombinationen mit drei oder mehr Wirkstoffen gelten die nachstehend insbesondere für erfindungsgemäße Zweierkombinationen erläuterten bevorzugten Bedingungen in erster Linie ebenfalls, sofern darin die erfindungsgemäßen Zweierkombinationen enthalten sind.For combinations with three or more active ingredients, the preferred conditions explained below in particular for combinations of two according to the invention also apply primarily insofar as they contain the two-person combinations according to the invention.

Bereiche für geeignete Mengenverhältnisse der Verbindungen (A) und (B) ergeben sich z.B. aus den genannten Aufwandmengen für die Einzelstoffe. In den erfindungsgemäßen Kombinationen können die Aufwandmengen in der Regel reduziert werden. Bevorzugte Mischungsverhältnisse (A):(B), für die erfindungsgemäßen Kombinationen sind im folgenden aufgeführt:

  1. (A) : (B) = 50000 : 1 bis 1 : 100000, vorzugsweise 500 : 1 bis 1 : 16000, besonders bevorzugt 250 : 1 bis 1 : 8000.
Areas for suitable proportions of the compounds (A) and (B) arise, for example, from the stated application rates for the individual substances. In the Combinations of the invention, the application rates can be reduced as a rule. Preferred mixing ratios (A) :( B) for the combinations according to the invention are listed below:
  1. (A): (B) = 50,000: 1 to 1: 100,000, preferably 500: 1 to 1: 16,000, more preferably 250: 1 to 1: 8,000.

Von besonderem Interesse ist die Anwendung von herbiziden Mitteln mit einem Gehalt an folgenden Verbindungen (A) + (B):

  • (A-0) + (B1-1), (A-0) + (B1-2), (A-0) + (B1-3), (A-0) + (B1-4), (A-0) + (B1-5), (A-0) + (B1-6), (A-0) + (B1-7), (A-0) + (B1-8), (A-0) + (B2-1), (A-0) + (B2-2), (A-0) + (B3-1), (A-0) + (B3-2), (A-0) + (B3-3), (A-0) + (B3-4), (A-0) + (B3-5), (A-0) + (B3-6), (A-0) + (B-3-7), (A-0) + (B3-8), (A-0) + (B3-9), (A-0) + (B4-1), (A-0) + (B4-2), (A-0) + (B4-3), (A-0) + (B4-4), (A-0) + (B4-5), (A-0) + (B4-6), (A-0) + (B4-7), (A-0) + (B4-8), (A-0) + (B4-9), (A-0) + (B4-10), (A-0) + (B4-11), (A-0) + (B5-1), (A-0) + (B5-2), (A-0) + (B5-3), (A-0) + (B5-4), (A-0) + (B5-5), (A-0) + (B5-6), (A-0) + (B5-7), (A-0) + (B6-1), (A-0) + (B6-2), (A-0) + (B6-3), (A-0) + (B6-4), (A-0) + (B6-5), (A-0) + (B6-6), (A-0) + (B6-7), (A-0) + (B6-8), (A-0) + (B6-9), (A-0) + (B6-10), (A-0) + (B6-11), (A-0) + (B6-12), (A-0) + (B6-13), (A-0) + (B6-14), (A-0) + (B7-1), (A-0) + (B7-2), (A-0) + (B7-3), (A-0) + (B7-4), (A-0) + (B7-5), (A-0) + (B7-6), (A-0) + (B7-7), (A-0) + (B7-8), (A-0) + (B7-9), (A-0) + (B7-10), (A-0) + (B7-11), (A-0) + (B7-12), (A-0) + (B7-13), (A-0) + (B7-14), (A-0) + (B7-15), (A-0) + (B7-16), (A-0) + (B7-17), (A-0) + (B7-18), (A-0) + (B7-19), (A-0) + (B7-20), (A-0) + (B7-21), (A-0) + (B7-22), (A-0) + (B7-23), (A-0) + (B7-24), (A-0) + (B7-25), (A-0) + (B7-26), (A-0) + (B7-27), (A-0) + (B7-28), (A-0) + (B7-29), (A-0) + (B7-30), (A-0) + (B-31), (A-0) + (B7-32), (A-0) + (B7-33), (A-0) + (B7-34), (A-0) + (B7-35), (A-0) + (B7-36), (A-0) + (B7-37), (A-0) + (B7-38), (A-0) + (B8-1), (A-0) + (B8-2), (A-0) + (B8-3), (A-0) + (B9-1), (A-0) + (B9-2), (A-0) + (B9-3), (A-0) + (B9-4), (A-0) + (B9-5), (A-0) + (B9-6), (A-0) + (B9-7).
  • (A-1) + (B1-1), (A-1) + (B1-2), (A-1) + (B1-3), (A-1) + (B1-4), (A-1) + (B1-5), (A-1) + (B1-6), (A-1) + (B1-7), (A-1) + (B1-8), (A-1) + (B2-1), (A-1) + (B2-2), (A-1) + (B3-1), (A-1) + (B3-2), (A-1) + (B3-3), (A-1) + (B3-4), (A-1) + (B3-5), (A-1) + (B3-6), (A-1) + (B-3-7), (A-1) + (B3-8), (A-1) + (B3-9), (A-1) + (B4-1), (A-1) + (B4-2), (A-1) + (B4-3), (A-1) + (B4-4), (A-1) + (B4-5), (A-1) + (B4-6), (A-1) + (B4-7), (A-1) + (B4-8), (A-1) + (B4-9), (A-1) + (B4-10), (A-1) + (B4-11), (A-1) + (B5-1), (A-1) + (B5-2), (A-1) + (B6-3), (A-1) + (B5-4), (A-1) + (B5-5), (A-1) + (B5-6), (A-1) + (B5-7), (A-1) + (B6-1), (A-1) + (B6-2), (A-1) + (B6-3), (A-1) + (B6-4), (A-1) + (B6-5), (A-1) + (B6-6), (A-1) + (B6-7), (A-1) + (B6-8), (A-1) + (B6-9), (A-1) + (B6-10), (A-1) + (B6-11), (A-1) + (B6-12), (A-1) + (B6-13), (A-1) + (B6-14), (A-1) + (B7-1), (A-1) + (B7-2), (A-1) + (B7-3), (A-1) + (B7-4), (A-1) + (B7-5), (A-1) + (B7-6), (A-1) + (B7-7), (A-1) + (B7-8), (A-1) + (B7-9), (A-1) + (B7-10), (A-1) + (B7-11), (A-1) + (B7-12), (A-1) + (B7-13), (A-1) + (B7-14), (A-1) + (B7-15), (A-1) + (B7-16), (A-1) + (B7-17), (A-1) + (B7-18), (A-1) + (B7-19), (A-1) + (B7-20), (A-1) + (B7-21), (A-1) + (B7-22), (A-1) + (B7-23), (A-1) + (B7-24), (A-1) + (B7-25), (A-1) + (B7-26), (A-1) + (B7-27), (A-1) + (B7-28), (A-1) + (B7-29), (A-1) + (B7-30), (A-1) + (B-31), (A-1) + (B7-32), (A-1) + (B7-33), (A-1) + (B7-34), (A-1) + (B7-35), (A-1) + (B7-36), (A-1) + (B7-37), (A-1) + (B7-38), (A-1) + (B8-1), (A-1) + (B8-2), (A-1) + (B8-3), (A-1) + (B9-1), (A-1) + (B9-2), (A-1) + (B9-3), (A-1) + (B9-4), (A-1) + (B9-5), (A-1) + (B9-6), (A-1) + (B9-7).
  • (A-2) + (B1-1), (A-2) + (B1-2), (A-2) + (B1-3), (A-2) + (B1-4), (A-2) + (B1-5), (A-2) + (B1-6), (A-2) + (B1-7), (A-2) + (B1-8), (A-2) + (B2-1), (A-2) + (B2-2), (A-2) + (B3-1), (A-2) + (B3-2), (A-2) + (B3-3), (A-2) + (B3-4), (A-2) + (B3-5), (A-2) + (B3-6), (A-2) + (B-3-7), (A-2) + (B3-8), (A-2) + (B3-9), (A-2) + (B4-1), (A-2) + (B4-2), (A-2) + (B4-3), (A-2) + (B4-4), (A-2) + (B4-5), (A-2) + (B4-6), (A-2) + (B4-7), (A-2) + (B4-8), (A-2) + (B4-9), (A-2) + (B4-10), (A-2) + (B4-11), (A-2) + (B5-1), (A-2) + (B5-2), (A-2) + (B5-3), (A-2) + (B5-4), (A-2) + (B5-5), (A-2) + (B5-6), (A-2) + (B5-7), (A-2) + (B6-1), (A-2) + (B6-2), (A-2) + (B6-3), (A-2) + (B6-4), (A-2) + (B6-5), (A-2) + (B6-6), (A-2) + (B6-7), (A-2) + (B6-8), (A-2) + (B6-9), (A-2) + (B6-10), (A-2) + (B6-11), (A-2) + (B6-12), (A-2) + (B6-13), (A-2) + (B6-14), (A-2) + (B7-1), (A-2) + (B7-2), (A-2) + (B7-3), (A-2) + (B7-4), (A-2) + (B7-5), (A-2) + (B7-6), (A-2) + (B7-7), (A-2) + (B7-8), (A-2) + (B7-9), (A-2) + (B7-10), (A-2) + (B7-11), (A-2) + (B7-12), (A-2) + (B7-13), (A-2) + (B7-14), (A-2) + (B7-15), (A-2) + (B7-16), (A-2) + (B7-17), (A-2) + (B7-18), (A-2) + (B7-19), (A-2) + (B7-20), (A-2) + (B7-21), (A-2) + (B7-22), (A-2) + (B7-23), (A-2) + (B7-24), (A-2) + (B7-25), (A-2) + (B7-26), (A-2) + (B7-27), (A-2) + (B7-28), (A-2) + (B7-29), (A-2) + (87-30), (A-2) + (B-31), (A-2) + (B7-32), (A-2) + (B7-33), (A-2) + (B7-34), (A-2) + (B7-35), (A-2) + (B7-36), (A-2) + (B7-37), (A-2) + (B7-38), (A-2) + (B8-1), (A-2) + (B8-2), (A-2) + (B8-3), (A-2) + (B9-1), (A-2) + (B9-2), (A-2) + (B9-3), (A-2) + (B9-4), (A-2) + (B9-5), (A-2) + (B9-6), (A-2) + (B9-7).
  • (A-3) + (B1-1), (A-3) + (B1-2), (A-3) + (B1-3), (A-3) + (B1-4), (A-3) + (B1-5), (A-3) + (B1-6), (A-3) + (B1-7), (A-3) + (B1-8), (A-3) + (B2-1), (A-3) + (B2-2), (A-3) + (B3-1), (A-3) + (B3-2), (A-3) + (B3-3), (A-3) + (B3-4), (A-3) + (B3-5), (A-3) + (B3-6), (A-3) + (B-3-7), (A-3) + (B3-8), (A-3) + (B3-9), (A-3) + (B4-1), (A-3) + (B4-2), (A-3) + (B4-3), (A-3) + (B4-4), (A-3) + (B4-5), (A-3) + (B4-6), (A-3) + (B4-7), (A-3) + (B4-8), (A-3) + (B4-9), (A-3) + (B4-10), (A-3) + (B4-11), (A-3) + (B5-1), (A-3) + (B5-2), (A-3) + (B5-3), (A-3) + (B5-4), (A-3) + (B5-5), (A-3) + (B5-6), (A-3) + (B5-7), (A-3) + (B6-1), (A-3) + (B6-2), (A-3) + (B6-3), (A-3) + (B6-4), (A-3) + (B6-5), (A-3) + (B6-6), (A-3) + (B6-7), (A-3) + (B6-8), (A-3) + (86-9), (A-3) + (B6-1 0), (A-3) + (B6-11), (A-3) + (B6-12), (A-3) + (B6-13), (A-3) + (B6-14), (A-3) + (B7-1), (A-3) + (B7-2), (A-3) + (B7-3), (A-3) + (B7-4), (A-3) + (B7-5), (A-3) + (B7-6), (A-3) + (B7-7), (A-3) + (B7-8), (A-3) + (B7-9), (A-3) + (B7-10), (A-3) + (B7-11), (A-3) + (B7-12), (A-3) + (B7-13), (A-3) + (B7-14), (A-3) + (B7-15), (A-3) + (B7-16), (A-3) + (B7-17), (A-3) + (B7-18), (A-3) + (B7-19), (A-3) + (B7-20), (A-3) + (B7-21), (A-3) + (B7-22), (A-3) + (B7-23), (A-3) + (B7-24), (A-3) + (B7-25), (A-3) + (B7-26), (A-3) + (B7-27), (A-3) + (B7-28), (A-3) + (B7-29), (A-3) + (B7-30), (A-3) + (B-31), (A-3) + (B7-32), (A-3) + (B7-33), (A-3) + (B7-34), (A-3) + (B7-35), (A-3) + (B7-36), (A-3) + (B7-37), (A-3) + (B7-38), (A-3) + (B8-1), (A-3) + (B8-2), (A-3) + (B8-3), (A-3) + (B9-1), (A-3) + (B9-2), (A-3) + (B9-3), (A-3) + (B9-4), (A-3) + (B9-5), (A-3) + (B9-6), (A-3) + (B9-7).
  • (A-4) + (B1-1), (A-4) + (B1-2), (A-4) + (B1-3), (A-4) + (B1-4), (A-4) + (B1-5), (A-4) + (B1-6), (A-4) + (B1-7), (A-4) + (B1-8), (A-4) + (B2-1), (A-4) + (B2-2), (A-4) + (B3-1), (A-4) + (B3-2), (A-4) + (B3-3), (A-4) + (B3-4), (A-4) + (B3-5), (A-4) + (B3-6), (A-4) + (B-3-7), (A-4) + (B3-8), (A-4) + (B3-9), (A-4) + (B4-1), (A-4) + (B4-2), (A-4) + (B4-3), (A-4) + (B4-4), (A-4) + (B4-6), (A-4) + (B4-6), (A-4) + (B4-7), (A-4) + (B4-8), (A-4) + (B4-9), (A-4) + (B4-10), (A-4) + (B4-11), (A-4) + (B5-1), (A-4) + (B5-2), (A-4) + (85-3), (A-4) + (B5-4), (A-4) + (B5-5), (A-4) + (B5-6), (A-4) + (B5-7), (A-4) + (B6-1), (A-4) + (B6-2), (A-4) + (86-3), (A-4) + (B8-4), (A-4) + (B6-5), (A-4) + (B6-6), (A-4) + (B6-7), (A-4) + (B6-8), (A-4) + (B6-9), (A-4) + (B6-10), (A-4) + (B6-11), (A-4) + (B6-12), (A-4) + (B6-13), (A-4) + (B6-14), (A-4) + (B7-1), (A-4) + (B7-2), (A-4) + (B7-3), (A-4) + (B7-4), (A-4) + (B7-6), (A-4) + (B7-6), (A-4) + (B7-7), (A-4) + (B7-8), (A-4) + (B7-9), (A-4) + (B7-10), (A-4) + (B7-11), (A-4) + (B7-12), (A-4) + (B7-13), (A-4) + (B7-14), (A-4) + (B7-15), (A-4) + (B7-16), (A-4) + (B7-17), (A-4) + (B7-18), (A-4) + (B7-19), (A-4) + (B7-20), (A-4) + (B7-21), (A-4) + (B7-22), (A-4) + (B7-23), (A-4) + (B7-24), (A-4) + (B7-25), (A-4) + (B7-26), (A-4) + (B7-27), (A-4) + (B7-28), (A-4) + (B7-29), (A-4) + (B7-30), (A-4) + (B-31), (A-4) + (B7-32), (A-4) + (B7-33), (A-4) + (B7-34), (A-4) + (B7-35), (A-4) + (B7-36), (A-4) + (B7-37), (A-4) + (B7-38), (A-4) + (B8-1), (A-4) + (B8-2), (A-4) + (B8-3), (A-4) + (B9-1), (A-4) + (B9-2), (A-4) + (B9-3), (A-4) + (B9-4), (A-4) + (B9-5), (A-4) + (B9-6), (A-4) + (B9-7).
  • (A-5) + (B1-1), (A-5) + (B1-2), (A-5) + (B1-3), (A-5) + (B1-4), (A-5) + (B1-5), (A-5) + (B1-6), (A-5) + (B9-7), (A-5) + (B1-8), (A-5) + (B2-1), (A-5) + (B2-2), (A-5) + (B3-1), (A-5) + (B3-2), (A-5) + (B3-3), (A-5) + (B3-4), (A-5) + (B3-5), (A-5) + (B3-6), (A-5) + (B-3-7), (A-5) + (B3-8), (A-5) + (B3-9), (A-5) + (B4-1), (A-5) + (B4-2), (A-5) + (B4-3), (A-5) + (B4-4), (A-5) + (B4-5), (A-5) + (B4-6), (A-5) + (B4-7), (A-5) + (B4-8), (A-5) + (B4-9), (A-5) + (B4-10), (A-5) + (B4-11), (A-5) + (B5-1), (A-5) + (B5-2), (A-5) + (B5-3), (A-5) + (B5-4), (A-5) + (B5-5), (A-5) + (B5-6), (A-5) + (B5-7), (A-5) + (B6-1), (A-5) + (B6-2), (A-5) + (B6-3), (A-5) + (B6-4), (A-5) + (B6-5), (A-5) + (B6-6), (A-5) + (B6-7), (A-5) + (B6-8), (A-5) + (B6-9), (A-5) + (B6-10), (A-5) + (B6-11), (A-5) + (B6-12), (A-5) + (B6-13), (A-5) + (B6-14), (A-5) + (B7-1), (A-5) + (B7-2), (A-5) + (B7-3), (A-5) + (B7-4), (A-5) + (B7-5), (A-5) + (B7-6), (A-5) + (B7-7), (A-5) + (B7-8), (A-5) + (B7-9), (A-5) + (B7-10), (A-5) + (B7-11), (A-5) + (B7-12), (A-5) + (B7-13), (A-5) + (B7-14), (A-5) + (B7-15), (A-5) + (B7-16), (A-5) + (B7-17), (A-5) + (B7-18), (A-5) + (B7-19), (A-5) + (B7-20), (A-5) + (B7-21), (A-5) + (B7-22), (A-5) + (B7-23), (A-5) + (B7-24), (A-5) + (B7-25), (A-5) + (B7-26), (A-5) + (B7-27), (A-5) + (B7-28), (A-5) + (B7-29), (A-5) + (B7-30), (A-5) + (B-31), (A-5) + (B7-32), (A-5) + (B7-33), (A-5) + (B7-34), (A-5) + (B7-36), (A-5) + (B7-36), (A-5) + (B7-37), (A-5) + (B7-38), (A-5) + (B8-1), (A-5) + (B8-2), (A-5) + (B8-3), (A-5) + (B9-1), (A-5) + (B9-2), (A-5) + (B9-3), (A-5) + (B9-4), (A-5) + (B9-5), (A-5) + (B9-6), (A-5) + (B9-7).
  • (A-6) + (B1-1), (A-6) + (B1-2), (A-6) + (B1-3), (A-6) + (B1-4), (A-6) + (B1-5), (A-6) + (B1-6), (A-6) + (B1-7), (A-6) + (B1-8), (A-6) + (B2-1), (A-6) + (B2-2), (A-6) + (B3-1), (A-6) + (B3-2), (A-6) + (B3-3), (A-6) + (B3-4), (A-6) + (B3-5), (A-6) + (B3-6), (A-6) + (B-3-7), (A-6) + (B3-8), (A-6) + (B3-9), (A-6) + (B4-1), (A-6) + (B4-2), (A-6) + (B4-3), (A-6) + (B4-4), (A-6) + (B4-5), (A-6) + (B4-6), (A-6) + (B4-7), (A-6) + (B4-8), (A-6) + (B4-9), (A-6) + (B4-10), (A-6) + (B4-11), (A-6) + (B5-1), (A-6) + (B5-2), (A-6) + (B5-3), (A-6) + (B5-4), (A-6) + (B5-5), (A-6) + (B5-6), (A-6) + (B5-7), (A-6) + (B6-1), (A-6) + (B6-2), (A-6) + (B6-3), (A-6) + (86-4), (A-6) + (B6-5), (A-6) + (B6-6), (A-6) + (B6-7), (A-6) + (B6-8), (A-6) + (B6-9), (A-6) + (B6-10), (A-6) + (B6-11), (A-6) + (B6-12), (A-6) + (B6-13), (A-6) + (B6-14), (A-6) + (B7-1), (A-6) + (B7-2), (A-6) + (B7-3), (A-6) + (B7-4), (A-6) + (B7-5), (A-6) + (B7-6), (A-6) + (B7-7), (A-6) + (B7-8), (A-6) + (B7-9), (A-6) + (B7-10), (A-6) + (B7-11), (A-6) + (B7-12), (A-6) + (B7-13), (A-6) + (B7-14), (A-6) + (B7-15), (A-6) + (B7-16), (A-6) + (B7-17), (A-6) + (B7-18), (A-6) + (B7-19), (A-6) + (B7-20), (A-6) + (B7-21), (A-6) + (B7-22), (A-6) + (B7-23), (A-6) + (B7-24), (A-6) + (B7-26), (A-6) + (B7-26), (A-6) + (B7-27), (A-6) + (B7-28), (A-6) + (B7-29), (A-6) + (B7-30), (A-6) + (B-31), (A-6) + (B7-32), (A-6) + (B7-33), (A-6) + (B7-34), (A-6) + (B7-35), (A-6) + (B7-36), (A-6) + (B7-37), (A-6) + (B7-38), (A-6) + (B8-1), (A-6) + (B8-2), (A-6) + (B8-3), (A-6) + (B9-1), (A-6) + (B9-2), (A-6) + (B9-3), (A-6) + (B9-4), (A-6) + (B9-5), (A-6) + (B9-6), (A-6) + (B9-7).
  • (A-7) + (B1-1), (A-7) + (B1-2), (A-7) + (B1-3), (A-7) + (B1-4), (A-7) + (B1-5), (A-7) + (B1-6), (A-7) + (B1-7), (A-7) + (B1-8), (A-7) + (B2-1), (A-7) + (B2-2), (A-7) + (B3-1), (A-7) + (B3-2), (A-7) + (B3-3), (A-7) + (B3-4), (A-7) + (B3-5), (A-7) + (B3-6), (A-7) + (B-3-7), (A-7) + (B3-8), (A-7) + (B3-9), (A-7) + (B4-1), (A-7) + (B4-2), (A-7) + (B4-3), (A-7) + (B4-4), (A-7) + (B4-5), (A-7) + (B4-6), (A-7) + (B4-7), (A-7) + (B4-8), (A-7) + (B4-9), (A-7) + (B4-10), (A-7) + (B4-11), (A-7) + (B5-1), (A-7) + (B5-2), (A-7) + (B5-3), (A-7) + (B5-4), (A-7) + (B5-5), (A-7) + (B5-6), (A-7) + (B5-7), (A-7) + (B6-1), (A-7) + (B6-2), (A-7) + (B6-3), (A-7) + (B6-4), (A-7) + (B6-5), (A-7) + (B6-6), (A-7) + (B6-7), (A-7) + (B6-8), (A-7) + (B6-9), (A-7) + (B6-10), (A-7) + (B6-11), (A-7) + (B6-12), (A-7) + (B6-13), (A-7) + (B6-14), (A-7) + (B7-1), (A-7) + (B7-2), (A-7) + (B7-3), (A-7) + (B7-4), (A-7) + (B7-5), (A-7) + (B7-6), (A-7) + (B7-7), (A-7) + (B7-8), (A-7) + (B7-9), (A-7) + (B7-10), (A-7) + (B7-11), (A-7) + (B7-12), (A-7) + (B7-13), (A-7) + (B7-14), (A-7) + (B7-15), (A-7) + (B7-16), (A-7) + (B7-17), (A-7) + (B7-18), (A-7) + (B7-19), (A-7) + (B7-20), (A-7) + (B7-21), (A-7) + (B7-22), (A-7) + (B7-23), (A-7) + (B7-24), (A-7) + (B7-25), (A-7) + (B7-26), (A-7) + (B7-27), (A-7) + (B7-28), (A-7) + (B7-29), (A-7) + (B7-30), (A-7) + (B-31), (A-7) + (B7-32), (A-7) + (B7-33), (A-7) + (B7-34), (A-7) + (B7-35), (A-7) + (B7-36), (A-7) + (B7-37), (A-7) + (B7-38), (A-7) + (B8-1), (A-7) + (B8-2), (A-7) + (B8-3), (A-7) + (B9-1), (A-7) + (B9-2), (A-7) + (B9-3), (A-7) + (B9-4), (A-7) + (B9-5), (A-7) + (B9-6), (A-7) + (B9-7).
  • (A-8) + (B1-1), (A-8) + (B1-2), (A-8) + (B1-3), (A-8) + (B1-4), (A-8) + (B1-5), (A-8) + (B1-6), (A-8) + (B-7), (A-8) + (B1-8), (A-8) + (B2-1), (A-8) + (B2-2), (A-8) + (B3-1), (A-8) + (B3-2), (A-8) + (B3-3), (A-8) + (B3-4), (A-8) + (B3-5), (A-8) + (B3-6), (A-8) + (B-3-7), (A-8) + (B3-8), (A-8) + (B3-9), (A-8) + (B4-1), (A-8) + (B4-2), (A-8) + (B4-3), (A-8) + (B4-4), (A-8) + (B4-5), (A-8) + (B4-6), (A-8) + (B4-7), (A-8) + (B4-8), (A-8) + (B4-9), (A-8) + (B4-10), (A-8) + (B4-11), (A-8) + (B5-1), (A-8) + (B5-2), (A-8) + (B5-3), (A-8) + (B5-4), (A-8) + (B5-5), (A-8) + (B5-6), (A-8) + (B5-7), (A-8) + (B6-1), (A-8) + (B6-2), (A-8) + (B6-3), (A-8) + (B6-4), (A-8) + (B6-5), (A-8) + (B6-6), (A-8) + (B6-7), (A-8) + (B6-8), (A-8) + (B6-9), (A-8) + (B6-10), (A-8) + (B6-11), (A-8) + (B6-12), (A-8) + (B8-13), (A-8) + (B6-14), (A-8) + (B7-1), (A-8) + (B7-2), (A-8) + (B7-3), (A-8) + (B7-4), (A-8) + (B7-5), (A-8) + (B7-6), (A-8) + (B7-7), (A-8) + (B7-8), (A-8) + (B7-9), (A-8) + (B7-10), (A-8) + (B7-11), (A-8) + (B7-12), (A-8) + (B7-13), (A-8) + (B7-14), (A-8) + (B7-15), (A-8) + (B7-16), (A-8) + (B7-17), (A-8) + (B7-18), (A-8) + (B7-19), (A-8) + (B7-20), (A-8) + (B7-21), (A-8) + (B7-22), (A-8) + (B7-23), (A-8) + (B7-24), (A-8) + (B7-25), (A-8) + (B7-26), (A-8) + (B7-27), (A-8) + (B7-28), (A-8) + (B7-29), (A-8) + (B7-30), (A-8) + (B-31), (A-8) + (B7-32), (A-8) + (B7-33), (A-8) + (B7-34), (A-8) + (B7-35), (A-8) + (B7-36), (A-8) + (B7-37), (A-8) + (B7-38), (A-8) + (B8-1), (A-8) + (B8-2), (A-8) + (B8-3), (A-8) + (B9-1), (A-8) + (B9-2), (A-8) + (B9-3), (A-8) + (B9-4), (A-8) + (B9-5), (A-8) + (B9-6), (A-8) + (B9-7).
  • (A-9) + (B1-1), (A-9) + (B1-2), (A-9) + (B1-3), (A-9) + (B1-4), (A-9) + (B1-5), (A-9) + (B1-6), (A-9) + (B1-7), (A-9) + (B1-8), (A-9) + (B2-1), (A-9) + (B2-2), (A-9) + (B3-1), (A-9) + (B3-2), (A-9) + (B3-3), (A-9) + (B3-4), (A-9) + (B3-5), (A-9) + (B3-6), (A-9) + (B-3-7), (A-9) + (B3-8), (A-9) + (B3-9), (A-9) + (B4-1), (A-9) + (B4-2), (A-9) + (B4-3), (A-9) + (B4-4), (A-9) + (B4-5), (A-9) + (B4-6), (A-9) + (B4-7), (A-9) + (B4-8), (A-9) + (B4-9), (A-9) + (B4-10), (A-9) + (B4-11), (A-9) + (B5-1), (A-9) + (B5-2), (A-9) + (B5-3), (A-9) + (B5-4), (A-9) + (B5-5), (A-9) + (B5-6), (A-9) + (B5-7), (A-9) + (B6-1), (A-9) + (B6-2), (A-9) + (B6-3), (A-9) + (B6-4), (A-9) + (B6-5), (A-9) + (B6-6), (A-9) + (B6-7), (A-9) + (B6-8), (A-9) + (B6-9), (A-9) + (B6-10), (A-9) + (B6-11), (A-9) + (B6-12), (A-9) + (B6-13), (A-9) + (B8-14), (A-9) + (B7-1), (A-9) + (B7-2), (A-9) + (B7-3), (A-9) + (B7-4), (A-9) + (B7-5), (A-9) + (B7-6), (A-9) + (B7-7), (A-9) + (B7-8), (A-9) + (B7-9), (A-9) + (B7-10), (A-9) + (B7-11), (A-9) + (B7-12), (A-9) + (B7-13), (A-9) + (B7-14), (A-9) + (B7-15), (A-9) + (B7-16), (A-9) + (B7-17), (A-9) + (B7-18), (A-9) + (B7-19), (A-9) + (B7-20), (A-9) + (B7-21), (A-9) + (B7-22), (A-9) + (B7-23), (A-9) + (B7-24), (A-9) + (B7-26), (A-9) + (B7-26), (A-9) + (B7-27), (A-9) + (B7-28), (A-9) + (B7-29), (A-9) + (B7-30), (A-9) + (B-31), (A-9) + (B7-32), (A-9) + (B7-33), (A-9) + (B7-34), (A-9) + (B7-35), (A-9) + (B7-36), (A-9) + (B7-37), (A-9) + (B7-38), (A-9) + (B8-1), (A-9) + (B8-2), (A-9) + (B8-3), (A-9) + (B9-1), (A-9) + (B9-2), (A-9) + (B9-3), (A-9) + (B9-4), (A-9) + (B9-5), (A-9) + (B9-6), (A-9) + (B9-7).
  • (A-10) + (B1-1), (A-10) + (B1-2), (A-10) + (B1-3), (A-10) + (B1-4), (A-10) + (B1-5), (A-10) + (B1-6), (A-10) + (B1-7), (A-10) + (B1-8), (A-10) + (B2-1), (A-10) + (B2-2), (A-10) + (B3-1), (A-10) + (B3-2), (A-10) + (B3-3), (A-10) + (B3-4), (A-10) + (B3-5), (A-10) + (B3-6), (A-10) + (B-3-7), (A-10) + (B3-8), (A-10) + (B3-9), (A-10) + (B4-1), (A-10) + (B4-2), (A-10) + (B4-3), (A-10) + (B4-4), (A-10) + (B4-5), (A-10) + (B4-6), (A-10) + (B4-7), (A-10) + (B4-8), (A-10) + (B4-9), (A-10) + (B4-10), (A-10) + (B4-11), (A-10) + (B5-1), (A-10) + (B5-2), (A-10) + (B5-3), (A-10) + (B5-4), (A-10) + (B5-5), (A-10) + (B5-6), (A-10) + (B5-7), (A-10) + (B6-1), (A-10) + (B6-2), (A-10) + (B6-3), (A-10) + (B6-4), (A-10) + (B6-5), (A-10) + (B6-6), (A-10) + (B6-7), (A-10) + (B6-8), (A-10) + (B6-9), (A-10) + (B6-10), (A-10) + (B6-11), (A-10) + (B6-12), (A-10) + (B6-13).
    (A-10) + (B6-14), (A-10) + (B7-1), (A-10) + (B7-2), (A-10) + (B7-3), (A-10) + (B7-4), (A-10) + (B7-5), (A-10) + (B7-6), (A-10) + (B7-7), (A-10) + (B7-8), (A-10) + (B7-9), (A-10) + (B7-10), (A-10) + (B7-11), (A-10) + (B7-12), (A-10) + (B7-13), (A-10) + (B7-14), (A-10) + (B7-15), (A-10) + (B7-16), (A-10) + (B7-17), (A-10) + (B7-18), (A-10) + (B7-19), (A-10) + (B7-20), (A-10) + (B7-21), (A-10) + (B7-22), (A-10) + (B7-23), (A-10) + (B7-24), (A-10) + (B7-25), (A-10) + (B7-26), (A-10) + (B7-27), (A-10) + (B7-28), (A-10) + (B7-29), (A-10) + (B7-30), (A-10) + (B-31), (A-10) + (B7-32), (A-10) + (B7-33), (A-10) + (B7-34), (A-10) + (B7-35), (A-10) + (B7-36), (A-10) + (B7-37), (A-10) + (B7-38), (A-10) + (B8-1), (A-10) + (B8-2), (A-10) + (B8-3), (A-10) + (B9-1), (A-10) + (B9-2), (A-10) + (B9-3), (A-10) + (B9-4), (A-10) + (B9-5), (A-10) + (B9-6), (A-10) + (B9-7).
  • (A-11) + (B1-1), (A-11) + (B1-2), (A-11) + (B1-3), (A-11) + (B1-4), (A-11) + (B1-5), (A-11) + (B1-6), (A-11) + (B1-7), (A-11) + (B1-8), (A-11) + (82-1), (A-11) + (B2-2), (A-11) + (B3-1), (A-11) + (B3-2), (A-11) + (B3-3), (A-11) + (B3-4), (A-11) + (B3-5), (A-11) + (B3-6), (A-11) + (B-3-7), (A-11) + (B3-8), (A-11) + (B3-9), (A-11) + (B4-1), (A-11) + (B4-2), (A-11) + (B4-3), (A-11) + (B4-4), (A-11) + (B4-5), (A-11) + (B4-6), (A-11) + (B4-7), (A-11) + (B4-8), (A-11) + (B4-9), (A-11) + (B4-10), (A-11) + (B4-11), (A-11) + (B5-1), (A-11) + (B5-2), (A-11) + (B6-3), (A-11) + (B5-4), (A-11) + (B5-5), (A-11) + (B5-6), (A-11) + (B5-7), (A-11) + (B6-1), (A-11) + (B6-2), (A-11) + (B6-3), (A-11) + (B6-4), (A-11) + (B6-5), (A-11) + (B6-6), (A-11) + (B6-7), (A-11) + (B6-8), (A-11) + (B6-9), (A-11) + (B8-10), (A-11) + (B6-11), (A-11) + (B6-12), (A-11) + (B6-13),
    (A-11) + (B6-14), (A-11) + (B7-1), (A-11) + (B7-2), (A-11) + (B7-3), (A-11) + (B7-4), (A-11) + (B7-5), (A-11) + (B7-6), (A-11) + (B7-7), (A-11) + (B7-8), (A-11) + (B7-9), (A-11) + (B7-10), (A-11) + (B7-11), (A-11) + (B7-12), (A-11) + (B7-13), (A-11) + (B7-14), (A-11) + (B7-15), (A-11) + (B7-16), (A-11) + (B7-17), (A-11) + (B7-18), (A-11) + (B7-19), (A-11) + (B7-20), (A-11) + (B7-21), (A-11) + (B7-22), (A-11) + (B7-23), (A-11) + (B7-24), (A-11) + (B7-25), (A-11) + (B7-26), (A-11) + (B7-27), (A-11) + (B7-28), (A-11) + (B7-29), (A-11) + (B7-30), (A-11) + (B-31), (A-11) + (B7-32), (A-11) + (B7-33), (A-11) + (B7-34), (A-11) + (B7-35), (A-11) + (B7-36), (A-11) + (B7-37), (A-11) + (B7-38), (A-11) + (B8-1), (A-11) + (B8-2), (A-11) + (B8-3), (A-11) + (B9-1), (A-11) + (B9-2), (A-11) + (B9-3), (A-11) + (B9-4), (A-11) + (B9-5), (A-11) + (B9-6), (A-11) + (B9-7).
  • (A-12) + (B1-1), (A-12) + (B1-2), (A-12) + (B1-3), (A-12) + (B1-4), (A-12) + (B1-5), (A-12) + (B1-6), (A-12) + (B1-7), (A-12) + (B1-8), (A-12) + (B2-1), (A-12) + (B2-2), (A-12) + (B3-1), (A-12) + (B3-2), (A-12) + (B3-3), (A-12) + (B3-4), (A-12) + (B3-5), (A-12) + (B3-6), (A-12) + (B-3-7), (A-12) + (B3-8), (A-12) + (B3-9), (A-12) + (B4-1), (A-12) + (B4-2), (A-12) + (B4-3), (A-12) + (B4-4), (A-12) + (B4-5), (A-12) + (B4-6), (A-12) + (B4-7), (A-12) + (B4-8), (A-12) + (B4-9), (A-12) + (B4-1 0), (A-12) + (B4-11), (A-12) + (B5-1), (A-12) + (B5-2), (A-12) + (B5-3), (A-12) + (B5-4), (A-12) + (B5-5), (A-12) + (B5-6), (A-12) + (B5-7), (A-12) + (B6-1), (A-12) + (B6-2), (A-12) + (B6-3), (A-12) + (B6-4), (A-12) + (B6-5), (A-12) + (B6-6), (A-12) + (B6-7), (A-12) + (B6-8), (A-12) + (B6-9), (A-12) + (B6-10), (A-12) + (B6-11), (A-12) + (BB-12), (A-12) + (B6-13),
    (A-12) + (B6-14), (A-12) + (B7-1), (A-12) + (B7-2), (A-12) + (B7-3), (A-12) + (B7-4), (A-12) + (B7-5), (A-12) + (B7-6), (A-12) + (B7-7), (A-12) + (B7-8), (A-12) + (B7-9), (A-12) + (B7-10), (A-12) + (B7-11), (A-12) + (B7-12), (A-12) + (B7-13), (A-12) + (B7-14), (A-12) + (B7-15), (A-12) + (B7-16), (A-12) + (B7-17), (A-12) + (B7-18), (A-12) + (B7-19), (A-12) + (B7-20), (A-12) + (B7-21), (A-12) + (B7-22), (A-12) + (B7-23), (A-12) + (B7-24), (A-12) + (B7-25), (A-12) + (B7-26), (A-12) + (B7-27), (A-12) + (B7-28), (A-12) + (B7-29), (A-12) + (B7-30), (A-12) + (B-31), (A-12) + (B7-32), (A-12) + (B7-33), (A-12) + (B7-34), (A-12) + (B7-35), (A-12) + (B7-36), (A-12) + (B7-37), (A-12) + (B7-38), (A-12) + (B8-1), (A-12) + (B8-2), (A-12) + (B8-3), (A-12) + (B9-1), (A-12) + (B9-2), (A-12) + (B9-3), (A-12) + (B9-4), (A-12) + (B9-5), (A-12) + (B9-6), (A-12) + (B9-7).
  • (A-13) + (B1-1), (A-13) + (B1-2), (A-13) + (B1-3), (A-13) + (B1-4), (A-13) + (B1-5), (A-13) + (B1-6), (A-13) + (B1-7), (A-13) + (B1-8), (A-13) + (B2-1), (A-13) + (B2-2), (A-13) + (B3-1), (A-13) + (B3-2), (A-13) + (B3-3), (A-13) + (B3-4), (A-13) + (B3-5), (A-13) + (B3-6), (A-13) + (B-3-7), (A-13) + (B3-8), (A-13) + (B3-9), (A-13) + (B4-1), (A-13) + (B4-2), (A-13) + (B4-3), (A-13) + (B4-4), (A-13) + (B4-5), (A-13) + (B4-6), (A-13) + (B4-7), (A-13) + (B4-8), (A-13) + (B4-9), (A-13) + (B4-10), (A-13) + (B4-11), (A-13) + (B5-1), (A-13) + (B5-2), (A-13) + (B5-3), (A-13) + (B5-4), (A-13) + (B5-5), (A-13) + (B5-6), (A-13) + (B5-7), (A-13) + (B6-1), (A-13) + (B6-2), (A-13) + (B6-3), (A-13) + (B6-4), (A-13) + (B6-5), (A-13) + (B6-6), (A-13) + (B6-7), (A-13) + (B6-8), (A-13) + (B6-9), (A-13) + (B6-10), (A-13) + (B6-11), (A-13) + (B6-12), (A-13) + (B6-13),
    (A-13) + (B6-14), (A-13) + (B7-1), (A-13) + (B7-2), (A-13) + (B7-3), (A-13) + (B7-4), (A-13) + (B7-6), (A-13) + (B7-6), (A-13) + (B7-7), (A-13) + (B7-8), (A-13) + (B7-9), (A-13) + (B7-10), (A-13) + (B7-11), (A-13) + (B7-12), (A-13) + (B7-13), (A-13) + (B7-14), (A-13) + (B7-15), (A-13) + (B7-16), (A-13) + (B7-17), (A-13) + (B7-18), (A-13) + (B7-19), (A-13) + (B7-20), (A-13) + (B7-21), (A-13) + (B7-22), (A-13) + (B7-23), (A-13) + (B7-24), (A-13) + (B7-25), (A-13) + (B7-26), (A-13) + (B7-27), (A-13) + (B7-28), (A-13) + (B7-29), (A-13) + (B7-30), (A-13) + (B-31), (A-13) + (B7-32), (A-13) + (B7-33), (A-13) + (B7-34), (A-13) + (B7-35), (A-13) + (B7-36), (A-13) + (B7-37), (A-13) + (B7-38), (A-13) + (B8-1), (A-13) + (B8-2), (A-13) + (B8-3), (A-13) + (B9-1), (A-13) + (B9-2), (A-13) + (B9-3), (A-13) + (B9-4), (A-13) + (B9-5), (A-13) + (B9-6), (A-13) + (B9-7).
  • (A-14) + (B1-1), (A-14) + (B1-2), (A-14) + (B1-3), (A-14) + (B1-4), (A-14) + (B1-5), (A-14) + (B1-6), (A-14) + (B1-7), (A-14) + (B1-8), (A-14) + (B2-1), (A-14) + (B2-2), (A-14) + (B3-1), (A-14) + (B3-2), (A-14) + (B3-3), (A-14) + (B3-4), (A-14) + (B3-5), (A-14) + (B3-6), (A-14) + (B-3-7), (A-14) + (B3-8), (A-14) + (B3-9), (A-14) + (B4-1), (A-14) + (B4-2), (A-14) + (B4-3), (A-14) + (B4-4), (A-14) + (B4-5), (A-14) + (B4-6), (A-14) + (B4-7), (A-14) + (B4-8), (A-14) + (B4-9), (A-14) + (B4-10), (A-14) + (B4-11), (A-14) + (B5-1), (A-14) + (B5-2), (A-14) + (B5-3), (A-14) + (B5-4), (A-14) + (B5-5), (A-14) + (85-6), (A-14) + (B5-7), (A-14) + (B6-1), (A-14) + (B6-2), (A-14) + (B6-3), (A-14) + (B6-4), (A-14) + (B6-5), (A-14) + (B6-6), (A-14) + (B6-7), (A-14) + (B6-8), (A-14) + (B6-9), (A-14) + (B6-10), (A-14) + (B6-11), (A-14) + (B6-12), (A-14) + (B6-13),
    (A-14) + (B6-14), (A-14) + (B7-1), (A-14) + (B7-2), (A-14) + (B7-3), (A-14) + (B7-4), (A-14) + (B7-5), (A-14) + (B7-6), (A-14) + (B7-7), (A-14) + (B7-8), (A-14) + (B7-9), (A-14) + (B7-10), (A-14) + (B7-11), (A-14) + (B7-12), (A-14) + (B7-13), (A-14) + (B7-14), (A-14) + (B7-15), (A-14) + (B7-16), (A-14) + (B7-17), (A-14) + (B7-18), (A-14) + (B7-19), (A-14) + (B7-20), (A-14) + (B7-21), (A-14) + (B7-22), (A-14) + (B7-23), (A-14) + (B7-24), (A-14) + (B7-25), (A-14) + (B7-26), (A-14) + (B7-27), (A-14) + (B7-28), (A-14) + (B7-29), (A-14) + (B7-30), (A-14) + (B-31), (A-14) + (B7-32), (A-14) + (B7-33), (A-14) + (B7-34), (A-14) + (B7-35), (A-14) + (B7-36), (A-14) + (B7-37), (A-14) + (B7-38), (A-14) + (B8-1), (A-14) + (B8-2), (A-14) + (B8-3), (A-14) + (B9-1), (A-14) + (B9-2), (A-14) + (B9-3), (A-14) + (B9-4), (A-14) + (B9-5), (A-14) + (B9-6), (A-14) + (B9-7).
  • (A-15) + (B1-1), (A-15) + (B1-2), (A-15) + (B1-3), (A-15) + (B1-4), (A-15) + (B1-5), (A-15) + (B1-6), (A-15) + (B1-7), (A-15) + (B1-8), (A-15) + (B2-1), (A-15) + (B2-2), (A-15) + (B3-1), (A-15) + (B3-2), (A-15) + (B3-3), (A-15) + (B3-4), (A-15) + (B3-5), (A-15) + (B3-6), (A-15) + (B-3-7), (A-15) + (B3-8), (A-15) + (B3-9), (A-15) + (B4-1), (A-15) + (B4-2), (A-15) + (B4-3), (A-15) + (B4-4), (A-15) + (B4-5), (A-15) + (B4-6), (A-15) + (B4-7), (A-15) + (B4-8), (A-15) + (B4-9), (A-15) + (B4-10), (A-15) + (B4-11), (A-15) + (B5-1), (A-15) + (B5-2), (A-15) + (B5-3), (A-15) + (B5-4), (A-15) + (B5-5), (A-15) + (B5-6), (A-15) + (B5-7), (A-15) + (B6-1), (A-15) + (B6-2), (A-15) + (B6-3), (A-15) + (B6-4), (A-15) + (B6-5), (A-15) + (B6-6), (A-15) + (B6-7), (A-15) + (B6-8), (A-15) + (B6-9), (A-15) + (B6-10), (A-15) + (B6-11), (A-15) + (B6-12), (A-15) + (B6-13),
    (A-15) + (B6-14), (A-15) + (B7-1), (A-15) + (B7-2), (A-15) + (B7-3), (A-15) + (B7-4), (A-15) + (B7-6), (A-15) + (B7-6), (A-15) + (B7-7), (A-15) + (B7-8), (A-15) + (B7-9), (A-15) + (B7-10), (A-15) + (B7-11), (A-15) + (B7-12), (A-15) + (B7-13), (A-15) + (B7-14), (A-15) + (B7-15), (A-15) + (B7-16), (A-15) + (B7-17), (A-15) + (B7-18), (A-15) + (B7-19), (A-15) + (B7-20), (A-15) + (B7-21), (A-15) + (B7-22), (A-15) + (B7-23), (A-15) + (B7-24), (A-15) + (B7-25), (A-15) + (B7-26), (A-15) + (B7-27), (A-15) + (B7-28), (A-15) + (B7-29), (A-15) + (B7-30), (A-15) + (B-31), (A-15) + (B7-32), (A-15) + (B7-33), (A-15) + (B7-34), (A-15) + (B7-35), (A-15) + (B7-36), (A-15) + (B7-37), (A-15) + (B7-38), (A-15) + (B8-1), (A-15) + (B8-2), (A-15) + (B8-3), (A-15) + (B9-1), (A-15) + (B9-2), (A-15) + (B9-3), (A-15) + (B9-4), (A-15) + (B9-5), (A-15) + (B9-6), (A-15) + (B9-7).
  • (A-16) + (B1-1), (A-16) + (B1-2), (A-16) + (B1-3), (A-16) + (B1-4), (A-16) + (B1-5), (A-16) + (B1-6), (A-16) + (B1-7), (A-16) + (B1-8), (A-16) + (B2-1), (A-16) + (B2-2), (A-16) + (B3-1), (A-16) + (B3-2), (A-16) + (B3-3), (A-16) + (B3-4), (A-16) + (B3-5), (A-16) + (B3-6), (A-16) + (B-3-7), (A-16) + (B3-8), (A-16) + (B3-9), (A-16) + (B4-1), (A-16) + (B4-2), (A-16) + (B4-3), (A-16) + (B4-4), (A-16) + (B4-5), (A-16) + (B4-6), (A-16) + (B4-7), (A-16) + (B4-8), (A-16) + (B4-9), (A-16) + (B4-10), (A-16) + (B4-11), (A-16) + (B5-1), (A-16) + (B5-2), (A-16) + (B5-3), (A-16) + (B5-4), (A-16) + (B5-5), (A-16) + (B5-6), (A-16) + (B5-7), (A-16) + (B6-1), (A-16) + (B6-2), (A-16) + (B6-3), (A-16) + (B6-4), (A-16) + (B6-5), (A-16) + (B6-6), (A-16) + (B6-7), (A-16) + (B6-8), (A-16) + (B6-9), (A-16) + (B6-10), (A-16) + (B6-11), (A-16) + (B6-12), (A-16) + (86-13),
    (A-16) + (B6-14), (A-16) + (B7-1), (A-16) + (B7-2), (A-16) + (B7-3), (A-16) + (B7-4), (A-16) + (B7-5), (A-16) + (B7-6), (A-16) + (B7-7), (A-16) + (B7-8), (A-16) + (B7-9), (A-16) + (B7-10), (A-16) + (B7-11), (A-1 6) + (B7-12), (A-16) + (B7-13), (A-16) + (B7-14), (A-16) + (B7-15), (A-16) + (B7-16), (A-16) + (B7-17), (A-16) + (B7-18), (A-16) + (B7-19), (A-16) + (B7-20), (A-16) + (B7-21), (A-16) + (B7-22), (A-16) + (B7-23), (A-16) + (B7-24), (A-16) + (B7-25), (A-16) + (B7-26), (A-16) + (B7-27), (A-16) + (B7-28), (A-16) + (B7-29), (A-16) + (B7-30), (A-16) + (B-31), (A-16) + (B7-32), (A-16) + (B7-33), (A-16) + (B7-34), (A-16) + (B7-35), (A-16) + (B7-36), (A-16) + (B7-37), (A-16) + (B7-38), (A-16) + (B8-1), (A-16) + (B8-2), (A-16) + (B8-3), (A-16) + (B9-1), (A-16) + (B9-2), (A-16) + (B9-3), (A-16) + (B9-4), (A-16) + (B9-5), (A-16) + (B9-6), (A-16) + (B9-7).
  • (A-17) + (B1-1), (A-17) + (B1-2), (A-17) + (B1-3), (A-17) + (B1-4), (A-17) + (B1-5), (A-17) + (B1-6), (A-17) + (B1-7), (A-17) + (B1-8), (A-17) + (B2-1), (A-17) + (B2-2), (A-17) + (B3-1), (A-17) + (B3-2), (A-17) + (B3-3), (A-17) + (B3-4), (A-17) + (B3-5), (A-17) + (B3-6), (A-17) + (B-3-7), (A-17) + (B3-8), (A-17) + (B3-9), (A-17) + (B4-1), (A-17) + (B4-2), (A-17) + (B4-3), (A-17) + (B4-4), (A-17) + (B4-5), (A-17) + (B4-6), (A-17) + (B4-7), (A-17) + (B4-8), (A-17) + (B4-9), (A-17) + (B4-10), (A-17) + (B4-11), (A-17) + (B5-1), (A-17) + (B5-2), (A-17) + (B5-3), (A-17) + (B5-4), (A-17) + (B5-5), (A-17) + (B5-6), (A-17) + (B5-7), (A-17) + (B6-1), (A-17) + (B6-2), (A-17) + (B6-3), (A-17) + (B6-4), (A-17) + (B6-5), (A-17) + (B6-6), (A-17) + (B6-7), (A-17) + (B6-8), (A-17) + (B6-9), (A-17) + (B6-10), (A-17) + (B6-11), (A-17) + (B6-12), (A-17) + (B6-13),
    (A-17) + (B6-14), (A-17) + (B7-1), (A-17) + (B7-2), (A-17) + (B7-3), (A-17) + (B7-4), (A-17) + (B7-5), (A-17) + (B7-6), (A-17) + (B7-7), (A-17) + (B7-8), (A-17) + (B7-9), (A-17) + (B7-10). (A-17) + (B7-11), (A-17) + (B7-12), (A-17) + (B7-13), (A-17) + (B7-14), (A-17) + (B7-15), (A-17) + (B7-16), (A-17) + (B7-17), (A-17) + (B7-18), (A-17) + (B7-19), (A-17) + (B7-20), (A-17) + (B7-21), (A-17) + (B7-22), (A-17) + (B7-23), (A-17) + (B7-24), (A-17) + (B7-25), (A-17) + (B7-26), (A-17) + (B7-27), (A-17) + (B7-28), (A-17) + (B7-29), (A-17) + (B7-30), (A-17) + (B-31), (A-17) + (B7-32), (A-17) + (B7-33), (A-17) + (B7-34), (A-17) + (B7-35), (A-17) + (B7-36), (A-17) + (B7-37), (A-17) + (B7-38), (A-17) + (B8-1), (A-17) + (B8-2), (A-17) + (B8-3), (A-17) + (B9-1), (A-17) + (B9-2), (A-17) + (B9-3), (A-17) + (B9-4), (A-17) + (B9-5), (A-17) + (B9-6), (A-17) + (B9-7).
  • (A-18) + (B1-1), (A-18) + (B1-2), (A-18) + (B1-3), (A-18) + (B1-4), (A-18) + (B1-5), (A-18) + (B1-6), (A-18) + (B1-7), (A-18) + (B1-8), (A-18) + (B2-1), (A-18) + (B2-2), (A-18) + (B3-1), (A-18) + (B3-2), (A-18) + (B3-3), (A-18) + (B3-4), (A-18) + (B3-5), (A-18) + (B3-6), (A-18) + (B-3-7), (A-18) + (B3-8), (A-18) + (B3-9), (A-18) + (B4-1), (A-18) + (B4-2), (A-18) + (B4-3), (A-18) + (B4-4), (A-18) + (B4-5), (A-18) + (B4-6), (A-18) + (B4-7), (A-18) + (B4-8), (A-18) + (B4-9), (A-18) + (B4-10), (A-18) + (B4-11), (A-18) + (B5-1), (A-18) + (B5-2), (A-18) + (B5-3), (A-18) + (B5-4), (A-18) + (B5-5), (A-18) + (B5-6), (A-18) + (B5-7), (A-18) + (B6-1), (A-18) + (B6-2), (A-18) + (B6-3), (A-18) + (B6-4), (A-18) + (B6-5), (A-18) + (B6-6), (A-18) + (B6-7), (A-18) + (B6-8), (A-18) + (B6-9), (A-18) + (B6-10), (A-18) + (B6-11), (A-18) + (B6-12), (A-18) + (B6-13),
    (A-18) + (B6-14), (A-18) + (B7-1), (A-18) + (B7-2), (A-18) + (B7-3), (A-18) + (B7-4), (A-18) + (B7-5), (A-18) + (B7-6), (A-18) + (B7-7), (A-18) + (B7-8), (A-18) + (B7-9), (A-18) + (B7-10), (A-18) + (B7-11), (A-18) + (B7-12), (A-18) + (B7-13), (A-18) + (B7-14), (A-18) + (B7-15), (A-18) + (B7-16), (A-18) + (B7-17), (A-18) + (B7-18), (A-18) + (B7-19), (A-18) + (B7-20), (A-18) + (B7-21), (A-18) + (B7-22), (A-18) + (B7-23), (A-18) + (B7-24), (A-18) + (B7-25), (A-18) + (B7-26), (A-18) + (B7-27), (A-18) + (B7-28), (A-18) + (B7-29), (A-18) + (B7-30), (A-18) + (B-31), (A-18) + (B7-32), (A-18) + (B7-33), (A-18) + (B7-34), (A-18) + (B7-35), (A-18) + (B7-36), (A-18) + (B7-37), (A-18) + (B7-38), (A-18) + (B8-1), (A-18) + (B8-2), (A-18) + (B8-3), (A-18) + (B9-1), (A-18) + (B9-2), (A-18) + (B9-3), (A-18) + (B9-4), (A-18) + (B9-5), (A-18) + (B9-6), (A-18) + (B9-7).
  • (A-19) + (B1-1), (A-19) + (B1-2), (A-19) + (B1-3), (A-19) + (B1-4), (A-19) + (B1-5), (A-19) + (B1-6), (A-19) + (B1-7), (A-19) + (B1-8), (A-19) + (B2-1), (A-19) + (B2-2), (A-19) + (B3-1), (A-19) + (B3-2), (A-19) + (B3-3), (A-19) + (B3-4), (A-19) + (B3-5), (A-19) + (B3-6), (A-19) + (B-3-7), (A-19) + (B3-8), (A-19) + (B3-9), (A-19) + (B4-1), (A-19) + (B4-2), (A-19) + (B4-3), (A-19) + (B4-4), (A-19) + (B4-5), (A-19) + (B4-6), (A-19) + (B4-7), (A-19) + (B4-8), (A-19) + (B4-9), (A-19) + (B4-10), (A-19) + (B4-11), (A-19) + (B5-1), (A-19) + (B5-2), (A-19) + (B5-3), (A-19) + (B5-4), (A-19) + (B5-5), (A-19) + (B5-6), (A-19) + (B5-7), (A-19) + (B6-1), (A-19) + (B6-2), (A-19) + (B6-3), (A-19) + (B6-4), (A-19) + (B6-5), (A-19) + (B6-6), (A-19) + (B6-7), (A-19) + (B6-8), (A-19) + (B6-9), (A-19) + (B6-10), (A-19) + (B6-11), (A-19) + (B6-12), (A-19) + (B6-13),
    (A-19) + (B6-14), (A-19) + (B7-1), (A-19) + (B7-2), (A-19) + (B7-3), (A-19) + (B7-4), (A-19) + (B7-5), (A-19) + (B7-6), (A-19) + (B7-7), (A-19) + (B7-8), (A-19) + (B7-9), (A-19) + (B7-10), (A-19) + (B7-11), (A-19) + (B7-12), (A-19) + (B7-13), (A-19) + (B7-14), (A-19) + (B7-15), (A-19) + (B7-16), (A-19) + (B7-17), (A-19) + (B7-18), (A-19) + (B7-19), (A-19) + (B7-20), (A-19) + (B7-21), (A-19) + (B7-22), (A-19) + (B7-23), (A-19) + (B7-24), (A-19) + (B7-25), (A-19) + (B7-26), (A-19) + (B7-27), (A-19) + (B7-28), (A-19) + (B7-29), (A-19) + (B7-30), (A-19) + (B-31), (A-19) + (B7-32), (A-19) + (B7-33), (A-19) + (B7-34), (A-19) + (B7-35), (A-19) + (B7-36), (A-19) + (B7-37), (A-19) + (B7-38), (A-19) + (B8-1), (A-19) + (B8-2), (A-19) + (B8-3), (A-19) + (B9-1), (A-19) + (B9-2), (A-19) + (B9-3), (A-19) + (B9-4), (A-19) + (B9-5), (A-19) + (B9-6), (A-19) + (B9-7).
  • (A-20) + (B1-1), (A-20) + (B1-2), (A-20) + (B1-3), (A-20) + (B1-4), (A-20) + (B1-5), (A-20) + (B1-6), (A-20) + (B1-7), (A-20) + (B1-8), (A-20) + (B2-1), (A-20) + (B2-2), (A-20) + (B3-1), (A-20) + (B3-2), (A-20) + (B3-3), (A-20) + (B3-4), (A-20) + (B3-5), (A-20) + (B3-6), (A-20) + (B-3-7), (A-20) + (B3-8), (A-20) + (B3-9), (A-20) + (B4-1), (A-20) + (B4-2), (A-20) + (B4-3), (A-20) + (B4-4), (A-20) + (B4-5), (A-20) + (B4-6), (A-20) + (B4-7), (A-20) + (B4-8), (A-20) + (B4-9), (A-20) + (B4-10), (A-20) + (B4-11), (A-20) + (B5-1), (A-20) + (B5-2), (A-20) + (B5-3), (A-20) + (B5-4), (A-20) + (B5-5), (A-20) + (B5-6), (A-20) + (B5-7), (A-20) + (B6-1), (A-20) + (B6-2), (A-20) + (B6-3), (A-20) + (B6-4), (A-20) + (B6-5), (A-20) + (B6-6), (A-20) + (B6-7), (A-20) + (B6-8), (A-20) + (B6-9), (A-20) + (B6-10), (A-20) + (B6-11), (A-20) + (B6-12), (A-20) + (B6-13),
    (A-20) + (B6-14), (A-20) + (B7-1), (A-20) + (B7-2), (A-20) + (B7-3), (A-20) + (B7-4), (A-20) + (B7-5), (A-20) + (B7-6), (A-20) + (B7-7), (A-20) + (B7-8), (A-20) + (B7-9), (A-20) + (B7-10), (A-20) + (B7-11), (A-20) + (B7-12), (A-20) + (B7-13), (A-20) + (B7-14), (A-20) + (B7-15), (A-20) + (B7-16), (A-20) + (B7-17), (A-20) + (B7-18), (A-20) + (B7-19), (A-20) + (B7-20), (A-20) + (B7-21), (A-20) + (B7-22), (A-20) + (B7-23), (A-20) + (B7-24), (A-20) + (B7-25), (A-20) + (B7-26), (A-20) + (B7-27), (A-20) + (B7-28), (A-20) + (B7-29), (A-20) + (B7-30), (A-20) + (B-31), (A-20) + (B7-32), (A-20) + (B7-33), (A-20) + (B7-34), (A-20) + (B7-35), (A-20) + (B7-36), (A-20) + (B7-37), (A-20) + (B7-38), (A-20) + (B8-1), (A-20) + (B8-2), (A-20) + (B8-3), (A-20) + (B9-1), (A-20) + (B9-2), (A-20) + (B9-3), (A-20) + (B9-4), (A-20) + (B9-5), (A-20) + (B9-6), (A-20) + (B9-7).
  • (A-21) + (B1-1), (A-21) + (B1-2), (A-21) + (B1-3), (A-21) + (B1-4), (A-21) + (B1-5), (A-21) + (B1-6), (A-21) + (B1-7), (A-21) + (B1-8), (A-21) + (B2-1), (A-21) + (B2-2), (A-21) + (B3-1), (A-21) + (B3-2), (A-21) + (B3-3), (A-21) + (B3-4), (A-21) + (B3-5), (A-21) + (B3-6), (A-21) + (B-3-7), (A-21) + (B3-8), (A-21) + (B3-9), (A-21) + (B4-1), (A-21) + (B4-2), (A-21) + (B4-3), (A-21) + (B4-4), (A-21) + (B4-5), (A-21) + (B4-6), (A-21) + (B4-7), (A-21) + (B4-8), (A-21) + (B4-9), (A-21) + (B4-10), (A-21) + (B4-11), (A-21) + (B5-1), (A-21) + (B5-2), (A-21) + (B5-3), (A-21) + (B5-4), (A-21) + (B5-5), (A-21) + (B5-6), (A-21) + (B5-7), (A-21) + (B6-1), (A-21) + (B6-2), (A-21) + (B6-3), (A-21) + (B6-4), (A-21) + (86-5), (A-21) + (B6-6), (A-21) + (B6-7), (A-21) + (B6-8), (A-21) + (B6-9), (A-21) + (B6-10), (A-21) + (B6-11), (A-21) + (B6-12), (A-21) + (B6-13),
    (A-21) + (B6-14), (A-21) + (B7-1), (A-21) + (B7-2), (A-21) + (B7-3), (A-21) + (B7-4), (A-21) + (B7-5), (A-21) + (B7-6), (A-21) + (B7-7), (A-21) + (B7-8), (A-21) + (B7-9), (A-21) + (B7-10), (A-21) + (B7-11), (A-21) + (B7-12), (A-21) + (B7-13), (A-21) + (B7-14), (A-21) + (B7-15), (A-21) + (B7-16), (A-21) + (B7-17), (A-21) + (B7-18), (A-21) + (B7-19), (A-21) + (B7-20), (A-21) + (B7-21), (A-21) + (B7-22), (A-21) + (B7-23), (A-21) + (B7-24), (A-21) + (B7-25), (A-21) + (B7-26), (A-21) + (B7-27), (A-21) + (B7-28), (A-21) + (B7-29), (A-21) + (B7-30), (A-21) + (B-31), (A-21) + (B7-32), (A-21) + (B7-33), (A-21) + (B7-34), (A-21) + (B7-35), (A-21) + (B7-36), (A-21) + (B7-37), (A-21) + (B7-38), (A-21) + (B8-1), (A-21) + (B8-2), (A-21) + (B8-3), (A-21) + (B9-1), (A-21) + (B9-2), (A-21) + (B9-3), (A-21) + (B9-4), (A-21) + (B9-5), (A-21) + (B9-6), (A-21) + (B9-7).
  • (A-22) + (B1-1), (A-22) + (B1-2), (A-22) + (B1-3), (A-22) + (B1-4), (A-22) + (B1-5), (A-22) + (B1-6), (A-22) + (B1-7), (A-22) + (B1-8), (A-22) + (B2-1), (A-22) + (B2-2), (A-22) + (B3-1), (A-22) + (B3-2), (A-22) + (B3-3), (A-22) + (B3-4), (A-22) + (B3-5), (A-22) + (B3-6), (A-22) + (B-3-7), (A-22) + (B3-8), (A-22) + (B3-9), (A-22) + (B4-1), (A-22) + (B4-2), (A-22) + (B4-3), (A-22) + (B4-4), (A-22) + (B4-5), (A-22) + (B4-6), (A-22) + (B4-7), (A-22) + (B4-8), (A-22) + (B4-9), (A-22) + (B4-10), (A-22) + (B4-11), (A-22) + (B5-1), (A-22) + (B5-2), (A-22) + (B5-3), (A-22) + (B5-4), (A-22) + (B5-5), (A-22) + (B5-6), (A-22) + (B5-7), (A-22) + (B6-1), (A-22) + (B6-2), (A-22) + (B6-3), (A-22) + (B6-4), (A-22) + (B6-5), (A-22) + (B6-6), (A-22) + (B6-7), (A-22) + (B6-8), (A-22) + (B6-9), (A-22) + (B6-10), (A-22) + (B6-11), (A-22) + (B6-12), (A-22) + (B6-13),
    (A-22) + (B6-14), (A-22) + (B7-1), (A-22) + (B7-2), (A-22) + (B7-3), (A-22) + (B7-4), (A-22) + (B7-5), (A-22) + (B7-6), (A-22) + (B7-7), (A-22) + (B7-8), (A-22) + (B7-9), (A-22) + (B7-10), (A-22) + (B7-11), (A-22) + (B7-12), (A-22) + (B7-13), (A-22) + (B7-14), (A-22) + (B7-15), (A-22) + (B7-16), (A-22) + (B7-17), (A-22) + (B7-18), (A-22) + (B7-19), (A-22) + (B7-20), (A-22) + (B7-21), (A-22) + (B7-22), (A-22) + (B7-23), (A-22) + (B7-24), (A-22) + (B7-25), (A-22) + (B7-26), (A-22) + (B7-27), (A-22) + (B7-28), (A-22) + (B7-29), (A-22) + (B7-30), (A-22) + (B-31), (A-22) + (B7-32), (A-22) + (B7-33), (A-22) + (B7-34), (A-22) + (B7-35), (A-22) + (B7-36), (A-22) + (B7-37), (A-22) + (B7-38), (A-22) + (B8-1), (A-22) + (B8-2), (A-22) + (B8-3), (A-22) + (B9-1), (A-22) + (B9-2), (A-22) + (B9-3), (A-22) + (B9-4), (A-22) + (B9-5), (A-22) + (B9-6), (A-22) + (B9-7).
  • (A-23) + (B1-1), (A-23) + (B1-2), (A-23) + (B1-3), (A-23) + (B1-4), (A-23) + (B1-5), (A-23) + (B1-6), (A-23) + (B1-7), (A-23) + (B1-8), (A-23) + (B2-1), (A-23) + (B2-2), (A-23) + (B3-1), (A-23) + (B3-2), (A-23) + (B3-3), (A-23) + (B3-4), (A-23) + (B3-5), (A-23) + (B3-6), (A-23) + (B-3-7), (A-23) + (B3-8), (A-23) + (B3-9), (A-23) + (B4-1), (A-23) + (B4-2), (A-23) + (B4-3), (A-23) + (B4-4), (A-23) + (B4-5), (A-23) + (B4-6), (A-23) + (B4-7), (A-23) + (B4-8), (A-23) + (B4-9), (A-23) + (B4-10), (A-23) + (B4-11), (A-23) + (B5-1), (A-23) + (B5-2), (A-23) + (B5-3), (A-23) + (B5-4), (A-23) + (B5-5), (A-23) + (B5-6), (A-23) + (B5-7), (A-23) + (B6-1), (A-23) + (B6-2), (A-23) + (B6-3), (A-23) + (B6-4), (A-23) + (B6-5), (A-23) + (B6-6), (A-23) + (B6-7), (A-23) + (B6-8), (A-23) + (B6-9), (A-23) + (B6-10), (A-23) + (B6-11), (A-23) + (B6-12), (A-23) + (B6-13),
    (A-23) + (B6-14), (A-23) + (B7-1), (A-23) + (B7-2), (A-23) + (B7-3), (A-23) + (B7-4), (A-23) + (B7-5), (A-23) + (B7-6), (A-23) + (B7-7), (A-23) + (B7-8), (A-23) + (B7-9), (A-23) + (B7-10), (A-23) + (B7-11), (A-23) + (B7-12), (A-23) + (B7-13), (A-23) + (B7-14), (A-23) + (B7-15), (A-23) + (B7-16), (A-23) + (B7-17), (A-23) + (B7-18), (A-23) + (B7-19), (A-23) + (B7-20), (A-23) + (B7-21), (A-23) + (B7-22), (A-23) + (B7-23), (A-23) + (B7-24), (A-23) + (B7-25), (A-23) + (B7-26), (A-23) + (B7-27), (A-23) + (B7-28), (A-23) + (B7-29), (A-23) + (B7-30), (A-23) + (B-31), (A-23) + (B7-32), (A-23) + (B7-33), (A-23) + (B7-34), (A-23) + (B7-35), (A-23) + (B7-36), (A-23) + (B7-37), (A-23) + (B7-38), (A-23) + (B8-1), (A-23) + (B8-2), (A-23) + (B8-3), (A-23) + (B9-1), (A-23) + (B9-2), (A-23) + (B9-3), (A-23) + (B9-4), (A-23) + (B9-5), (A-23) + (B9-6), (A-23) + (B9-7).
  • (A-24) + (B1-1), (A-24) + (B1-2), (A-24) + (B1-3), (A-24) + (B1-4), (A-24) + (B1-5), (A-24) + (B1-6), (A-24) + (B1-7), (A-24) + (B1-8), (A-24) + (B2-1), (A-24) + (B2-2), (A-24) + (B3-1), (A-24) + (B3-2), (A-24) + (B3-3), (A-24) + (B3-4), (A-24) + (B3-5), (A-24) + (B3-6), (A-24) + (B-3-7), (A-24) + (B3-8), (A-24) + (B3-9), (A-24) + (B4-1), (A-24) + (B4-2), (A-24) + (B4-3), (A-24) + (B4-4), (A-24) + (B4-5), (A-24) + (B4-6), (A-24) + (B4-7), (A-24) + (B4-8), (A-24) + (B4-9), (A-24) + (B4-10), (A-24) + (B4-11), (A-24) + (B5-1), (A-24) + (B5-2), (A-24) + (B5-3), (A-24) + (B5-4), (A-24) + (B5-5), (A-24) + (B5-6), (A-24) + (B5-7), (A-24) + (B6-1), (A-24) + (B6-2), (A-24) + (B6-3), (A-24) + (B6-4), (A-24) + (B6-5), (A-24) + (B6-6), (A-24) + (B6-7), (A-24) + (B6-8), (A-24) + (B6-9), (A-24) + (86-10), (A-24) + (B6-11), (A-24) + (B6-12), (A-24) + (B6-13),
    (A-24) + (B6-14), (A-24) + (B7-1), (A-24) + (B7-2), (A-24) + (B7-3), (A-24) + (B7-4), (A-24) + (B7-5), (A-24) + (B7-6), (A-24) + (B7-7), (A-24) + (B7-8), (A-24) + (B7-9), (A-24) + (B7-10), (A-24) + (B7-11), (A-24) + (B7-12), (A-24) + (B7-13), (A-24) + (B7-14), (A-24) + (B7-15), (A-24) + (B7-16), (A-24) + (B7-17), (A-24) + (B7-18), (A-24) + (B7-19), (A-24) + (B7-20), (A-24) + (B7-21), (A-24) + (B7-22), (A-24) + (B7-23), (A-24) + (B7-24), (A-24) + (B7-25), (A-24) + (B7-26), (A-24) + (B7-27), (A-24) + (B7-28), (A-24) + (B7-29), (A-24) + (B7-30), (A-24) + (B-31), (A-24) + (B7-32), (A-24) + (B7-33), (A-24) + (B7-34), (A-24) + (B7-35), (A-24) + (B7-36), (A-24) + (B7-37), (A-24) + (B7-38), (A-24) + (B8-1), (A-24) + (B8-2), (A-24) + (B8-3), (A-24) + (B9-1), (A-24) + (B9-2), (A-24) + (B9-3), (A-24) + (B9-4), (A-24) + (B9-5), (A-24) + (B9-6), (A-24) + (B9-7).
  • (A-25) + (B1-1), (A-25) + (B1-2), (A-25) + (B1-3), (A-25) + (B1-4), (A-25) + (B1-5), (A-25) + (B1-6), (A-26) + (B1-7), (A-25) + (B1-8), (A-25) + (B2-1), (A-25) + (B2-2), (A-25) + (B3-1), (A-25) + (B3-2), (A-25) + (B3-3), (A-25) + (B3-4), (A-25) + (B3-5), (A-25) + (B3-6), (A-25) + (B-3-7), (A-25) + (B3-8), (A-25) + (B3-9), (A-25) + (B4-1), (A-25) + (B4-2), (A-25) + (B4-3), (A-25) + (B4-4), (A-25) + (B4-5), (A-25) + (B4-6), (A-25) + (B4-7), (A-25) + (B4-8), (A-25) + (B4-9), (A-25) + (B4-10), (A-25) + (B4-11), (A-25) + (B5-1), (A-25) + (B5-2), (A-25) + (B5-3), (A-25) + (B5-4), (A-25) + (B5-5), (A-25) + (B5-6). (A-25) + (B5-7), (A-25) + (B6-1), (A-25) + (B6-2), (A-25) + (B6-3), (A-25) + (B6-4), (A-25) + (B6-5), (A-25) + (B6-6), (A-25) + (B6-7), (A-25) + (B6-8), (A-25) + (B6-9), (A-25) + (B6-10), (A-25) + (B6-11), (A-25) + (B6-12), (A-25) + (B6-13),
    (A-25) + (B6-14), (A-25) + (67-1), (A-25) + (B7-2), (A-25) + (B7-3), (A-25) + (B7-4), (A-25) + (B7-5), (A-25) + (B7-6), (A-25) + (B7-7), (A-25) + (B7-8), (A-25) + (B7-9), (A-25) + (B7-10), (A-25) + (B7-11), (A-25) + (B7-12), (A-25) + (B7-13), (A-25) + (B7-14), (A-25) + (B7-15), (A-25) + (B7-16), (A-25) + (B7-17), (A-25) + (B7-18), (A-25) + (B7-19), (A-25) + (B7-20), (A-25) + (B7-21), (A-25) + (B7-22), (A-25) + (B7-23), (A-25) + (B7-24), (A-25) + (B7-25), (A-25) + (B7-26), (A-25) + (B7-27), (A-25) + (B7-28), (A-25) + (B7-29), (A-25) + (B7-30), (A-25) + (B-31), (A-25) + (B7-32), (A-25) + (B7-33), (A-25) + (B7-34), (A-25) + (B7-35), (A-25) + (B7-36), (A-25) + (B7-37), (A-25) + (B7-38), (A-25) + (B8-1), (A-25) + (B8-2), (A-25) + (B8-3), (A-25) + (B9-1), (A-25) + (B9-2), (A-25) + (B9-3), (A-25) + (B9-4), (A-25) + (B9-5), (A-25) + (B9-6), (A-25) + (B9-7).
  • (A-26) + (B1-1), (A-26) + (B1-2), (A-26) + (B1-3), (A-26) + (B1-4), (A-26) + (B1-5), (A-26) + (B1-6), (A-26) + (B1-7), (A-26) + (B1-8), (A-26) + (B2-1), (A-26) + (B2-2), (A-26) + (B3-1), (A-26) + (B3-2), (A-26) + (B3-3), (A-26) + (B3-4), (A-26) + (B3-5), (A-26) + (B3-6), (A-26) + (B-3-7), (A-26) + (B3-8), (A-26) + (B3-9), (A-26) + (B4-1), (A-26) + (B4-2), (A-26) + (B4-3), (A-26) + (B4-4), (A-26) + (B4-5), (A-26) + (B4-6), (A-26) + (B4-7), (A-26) + (B4-8), (A-26) + (B4-9), (A-26) + (B4-10), (A-26) + (B4-11), (A-26) + (B5-1), (A-26) + (B5-2), (A-26) + (B5-3), (A-26) + (B5-4), (A-26) + (B5-5), (A-26) + (B5-6), (A-26) + (B5-7), (A-26) + (B6-1), (A-26) + (B6-2), (A-26) + (B6-3), (A-26) + (B6-4), (A-26) + (B6-5), (A-26) + (B6-6), (A-26) + (B6-7), (A-26) + (B6-8), (A-26) + (B6-9), (A-26) + (B6-10), (A-26) + (B6-11), (A-26) + (B6-12), (A-26) + (B6-13),
    (A-26) + (B6-14), (A-26) + (B7-1), (A-26) + (B7-2), (A-26) + (B7-3), (A-26) + (B7-4), (A-26) + (B7-5), (A-26) + (B7-6), (A-26) + (B7-7), (A-26) + (B7-8), (A-26) + (B7-9), (A-26) + (B7-10), (A-26) + (B7-11), (A-26) + (B7-12), (A-26) + (B7-13), (A-26) + (B7-14), (A-26) + (B7-15), (A-26) + (B7-16), (A-26) + (B7-17), (A-26) + (B7-18), (A-26) + (B7-19), (A-26) + (B7-20), (A-26) + (B7-21), (A-26) + (B7-22), (A-26) + (B7-23), (A-26) + (B7-24), (A-26) + (B7-25), (A-26) + (B7-26), (A-26) + (B7-27), (A-26) + (B7-28), (A-26) + (B7-29), (A-26) + (B7-30), (A-26) + (B-31), (A-26) + (B7-32), (A-26) + (B7-33), (A-26) + (B7-34), (A-26) + (B7-35), (A-26) + (B7-36), (A-26) + (B7-37), (A-26) + (B7-38), (A-26) + (B8-1), (A-26) + (B8-2), (A-26) + (B8-3), (A-26) + (B9-1), (A-26) + (B9-2), (A-26) + (B9-3), (A-26) + (B9-4), (A-26) + (B9-5), (A-26) + (B9-6), (A-26) + (B9-7).
  • (A-27) + (B1-1), (A-27) + (B1-2), (A-27) + (B1-3), (A-27) + (B1-4), (A-27) + (B1-5), (A-27) + (B1-6), (A-27) + (B1-7), (A-27) + (B1-8), (A-27) + (B2-1), (A-27) + (B2-2), (A-27) + (B3-1), (A-27) + (B3-2), (A-27) + (B3-3), (A-27) + (B3-4), (A-27) + (B3-5), (A-27) + (B3-6), (A-27) + (B-3-7), (A-27) + (B3-8), (A-27) + (B3-9), (A-27) + (B4-1), (A-27) + (B4-2), (A-27) + (B4-3), (A-27) + (B4-4), (A-27) + (B4-5), (A-27) + (B4-6), (A-27) + (B4-7), (A-27) + (B4-8), (A-27) + (B4-9), (A-27) + (B4-10), (A-27) + (B4-11), (A-27) + (B5-1), (A-27) + (B5-2), (A-27) + (B5-3), (A-27) + (B5-4), (A-27) + (B5-5), (A-27) + (B5-6), (A-27) + (B5-7), (A-27) + (B6-1), (A-27) + (B6-2), (A-27) + (B6-3), (A-27) + (B6-4), (A-27) + (B6-5), (A-27) + (B6-6), (A-27) + (B6-7), (A-27) + (B6-8), (A-27) + (B6-9), (A-27) + (B6-10), (A-27) + (B6-11), (A-27) + (B6-12), (A-27) + (B6-13),
    (A-27) + (B6-14), (A-27) + (B7-1), (A-27) + (B7-2), (A-27) + (B7-3), (A-27) + (B7-4), (A-27) + (B7-5), (A-27) + (B7-6), (A-27) + (B7-7), (A-27) + (B7-8), (A-27) + (B7-9), (A-27) + (B7-10), (A-27) + (B7-11), (A-27) + (B7-12), (A-27) + (B7-13), (A-27) + (B7-14), (A-27) + (B7-15), (A-27) + (B7-16), (A-27) + (B7-17), (A-27) + (B7-18), (A-27) + (B7-19), (A-27) + (B7-20), (A-27) + (B7-21), (A-27) + (B7-22), (A-27) + (B7-23), (A-27) + (B7-24), (A-27) + (B7-25), (A-27) + (B7-26), (A-27) + (B7-27), (A-27) + (B7-28), (A-27) + (B7-29), (A-27) + (B7-30), (A-27) + (B-31), (A-27) + (B7-32), (A-27) + (B7-33), (A-27) + (B7-34), (A-27) + (B7-35), (A-27) + (B7-36), (A-27) + (B7-37), (A-27) + (B7-38), (A-27) + (B8-1), (A-27) + (B8-2), (A-27) + (B8-3), (A-27) + (B9-1), (A-27) + (B9-2), (A-27) + (B9-3), (A-27) + (B9-4), (A-27) + (B9-5), (A-27) + (B9-6), (A-27) + (B9-7).
  • (A-28) + (B1-1), (A-28) + (B1-2), (A-28) + (B1-3), (A-28) + (B1-4), (A-28) + (B1-5), (A-28) + (B1-6), (A-28) + (B1-7), (A-28) + (B1-8), (A-28) + (B2-1), (A-28) + (B2-2), (A-28) + (B3-1), (A-28) + (B3-2), (A-28) + (B3-3), (A-28) + (B3-4), (A-28) + (B3-5), (A-28) + (B3-6), (A-28) + (B-3-7), (A-28) + (B3-8), (A-28) + (B3-9), (A-28) + (B4-1), (A-28) + (B4-2), (A-28) + (B4-3), (A-28) + (B4-4), (A-28) + (B4-5), (A-28) + (B4-6), (A-28) + (B4-7), (A-28) + (B4-8), (A-28) + (B4-9), (A-28) + (B4-10), (A-28) + (B4-11), (A-28) + (B5-1), (A-28) + (B5-2), (A-28) + (B5-3), (A-28) + (B5-4), (A-28) + (B5-5), (A-28) + (B5-6), (A-28) + (B5-7), (A-28) + (B6-1), (A-28) + (B6-2), (A-28) + (B6-3), (A-28) + (B6-4), (A-28) + (B6-5), (A-28) + (B6-6), (A-28) + (B6-7), (A-28) + (B6-8), (A-28) + (B6-9), (A-28) + (B6-10), (A-28) + (B6-11), (A-28) + (B6-12), (A-28) + (B6-13),
    (A-28) + (B6-14), (A-28) + (B7-1), (A-28) + (B7-2), (A-28) + (B7-3), (A-28) + (B7-4), (A-28) + (B7-5), (A-28) + (B7-6), (A-28) + (B7-7), (A-28) + (B7-8), (A-28) + (B7-9), (A-28) + (B7-10), (A-28) + (B7-11), (A-28) + (B7-12), (A-28) + (B7-13), (A-28) + (B7-14), (A-28) + (B7-15), (A-28) + (B7-16), (A-28) + (B7-17), (A-28) + (B7-18), (A-28) + (B7-19), (A-28) + (B7-20), (A-28) + (B7-21), (A-28) + (B7-22), (A-28) + (B7-23), (A-28) + (B7-24), (A-28) + (B7-25), (A-28) + (B7-26), (A-28) + (B7-27), (A-28) + (B7-28), (A-28) + (B7-29), (A-28) + (B7-30), (A-28) + (B-31), (A-28) + (B7-32), (A-28) + (B7-33), (A-28) + (B7-34), (A-28) + (B7-35), (A-28) + (B7-36), (A-28) + (B7-37), (A-28) + (B7-38), (A-28) + (B8-1), (A-28) + (B8-2), (A-28) + (B8-3), (A-28) + (B9-1), (A-28) + (B9-2), (A-28) + (B9-3), (A-28) + (B9-4), (A-28) + (B9-5), (A-28) + (B9-6), (A-28) + (B9-7).
  • (A-29) + (B1-1), (A-29) + (B1-2), (A-29) + (B1-3), (A-29) + (B1-4), (A-29) + (B1-5), (A-29) + (B1-6), (A-29) + (B1-7), (A-29) + (B1-8), (A-29) + (B2-1), (A-29) + (B2-2), (A-29) + (B3-1), (A-29) + (B3-2), (A-29) + (B3-3), (A-29) + (B3-4), (A-29) + (B3-5), (A-29) + (B3-6), (A-29) + (B-3-7), (A-29) + (B3-8), (A-29) + (B3-9), (A-29) + (B4-1), (A-29) + (B4-2), (A-29) + (B4-3), (A-29) + (B4-4), (A-29) + (B4-5), (A-29) + (B4-6), (A-29) + (B4-7), (A-29) + (B4-8), (A-29) + (B4-9), (A-29) + (B4-10), (A-29) + (B4-11), (A-29) + (B5-1), (A-29) + (B5-2), (A-29) + (B5-3), (A-29) + (B5-4), (A-29) + (B5-5), (A-29) + (B5-6), (A-29) + (B5-7), (A-29) + (B6-1), (A-29) + (B6-2), (A-29) + (B6-3), (A-29) + (B6-4), (A-29) + (B6-5), (A-29) + (B6-6), (A-29) + (B6-7), (A-29) + (B6-8), (A-29) + (B6-9), (A-29) + (B6-10), (A-29) + (B6-11), (A-29) + (B6-12), (A-29) + (B6-13),
    (A-29) + (B6-14), (A-29) + (B7-1), (A-29) + (B7-2), (A-29) + (B7-3), (A-29) + (B7-4), (A-29) + (B7-5), (A-29) + (B7-6), (A-29) + (B7-7), (A-29) + (B7-8), (A-29) + (B7-9), (A-29) + (B7-10), (A-29) + (B7-11), (A-29) + (B7-12), (A-29) + (B7-13), (A-29) + (B7-14), (A-29) + (B7-15), (A-29) + (B7-16), (A-29) + (B7-17), (A-29) + (B7-18), (A-29) + (B7-19), (A-29) + (B7-20), (A-29) + (B7-21), (A-29) + (B7-22), (A-29) + (B7-23), (A-29) + (B7-24), (A-29) + (B7-25), (A-29) + (B7-26), (A-29) + (B7-27), (A-29) + (B7-28), (A-29) + (B7-29), (A-29) + (B7-30), (A-29) + (B-31), (A-29) + (B7-32), (A-29) + (B7-33), (A-29) + (B7-34), (A-29) + (B7-35), (A-29) + (B7-36), (A-29) + (B7-37), (A-29) + (B7-38), (A-29) + (B8-1), (A-29) + (B8-2), (A-29) + (B8-3), (A-29) + (B9-1), (A-29) + (B9-2), (A-29) + (B9-3), (A-29) + (B9-4), (A-29) + (B9-5), (A-29) + (B9-6), (A-29) + (B9-7).
  • (A-30) + (B1-1), (A-30) + (B1-2), (A-30) + (B1-3), (A-30) + (B1-4), (A-30) + (B1-5), (A-30) + (B1-6), (A-30) + (B1-7), (A-30) + (B9-8), (A-30) + (B2-1), (A-30) + (B2-2), (A-30) + (B3-1), (A-30) + (B3-2), (A-30) + (B3-3), (A-30) + (B3-4), (A-30) + (B3-5), (A-30) + (B3-6), (A-30) + (B-3-7), (A-30) + (B3-8), (A-30) + (B3-9), (A-30) + (B4-1), (A-30) + (B4-2), (A-30) + (B4-3), (A-30) + (B4-4), (A-30) + (B4-5), (A-30) + (B4-6), (A-30) + (B4-7), (A-30) + (B4-8), (A-30) + (B4-9), (A-30) + (B4-10), (A-30) + (B4-11), (A-30) + (B5-1), (A-30) + (B5-2), (A-30) + (B5-3), (A-30) + (B5-4), (A-30) + (B5-5), (A-30) + (B5-6). (A-30) + (B5-7), (A-30) + (B6-1), (A-30) + (B6-2), (A-30) + (B6-3), (A-30) + (B6-4), (A-30) + (B6-5), (A-30) + (B6-6), (A-30) + (B6-7), (A-30) + (B6-8), (A-30) + (B6-9), (A-30) + (B6-10), (A-30) + (B6-11), (A-30) + (B6-12), (A-30) + (B6-13),
    (A-30) + (B6-14), (A-30) + (B7-1), (A-30) + (B7-2), (A-30) + (B7-3), (A-30) + (B7-4), (A-30) + (B7-5), (A-30) + (B7-6), (A-30) + (B7-7), (A-30) + (B7-8), (A-30) + (B7-9), (A-30) + (B7-10), (A-30) + (B7-11), (A-30) + (B7-12), (A-30) + (B7-13), (A-30) + (B7-14), (A-30) + (B7-15), (A-30) + (B7-16), (A-30) + (B7-17), (A-30) + (B7-18), (A-30) + (B7-19), (A-30) + (B7-20), (A-30) + (B7-21), (A-30) + (B7-22), (A-30) + (B7-23), (A-30) + (B7-24), (A-30) + (B7-25), (A-30) + (B7-26), (A-30) + (B7-27), (A-30) + (B7-28), (A-30) + (B7-29), (A-30) + (B7-30), (A-30) + (B-31), (A-30) + (B7-32), (A-30) + (B7-33), (A-30) + (B7-34), (A-30) + (B7-35), (A-30) + (B7-36), (A-30) + (B7-37), (A-30) + (B7-38), (A-30) + (B8-1), (A-30) + (B8-2), (A-30) + (B8-3), (A-30) + (B9-1), (A-30) + (B9-2), (A-30) + (B9-3), (A-30) + (B9-4), (A-30) + (B9-5), (A-30) + (B9-6), (A-30) + (B9-7).
  • (A-31) + (B1-1), (A-31) + (B1-2), (A-31) + (B1-3), (A-31) + (B1-4), (A-31) + (B1-5), (A-31) + (B1-6), (A-31) + (B1-7), (A-31) + (B1-8), (A-31) + (B2-1), (A-31) + (B2-2), (A-31) + (B3-1), (A-31) + (B3-2), (A-31) + (B3-3), (A-31) + (B3-4), (A-31) + (B3-5), (A-31) + (B3-6), (A-31) + (B-3-7), (A-31) + (B3-8), (A-31) + (B3-9), (A-31) + (B4-1), (A-31) + (B4-2), (A-31) + (B4-3), (A-31) + (B4-4), (A-31) + (B4-5), (A-31) + (B4-6), (A-31) + (B4-7), (A-31) + (B4-8), (A-31) + (B4-9), (A-31) + (B4-10), (A-31) + (B4-11), (A-31) + (B5-1), (A-31) + (B5-2), (A-31) + (B5-3), (A-31) + (B5-4), (A-31) + (B5-5), (A-31) + (B5-6), (A-31) + (B5-7), (A-31) + (B6-1), (A-31) + (B6-2), (A-31) + (B6-3), (A-31) + (B6-4), (A-31) + (B6-5), (A-31) + (B6-6), (A-31) + (B6-7), (A-31) + (B6-8), (A-31) + (B6-9), (A-31) + (B6-10), (A-31) + (B6-11), (A-31) + (B6-12), (A-31) + (B6-13),
    (A-31) + (B6-14), (A-31) + (B7-1), (A-31) + (B7-2), (A-31) + (B7-3), (A-31) + (B7-4), (A-31) + (B7-5), (A-31) + (B7-6), (A-31) + (B7-7), (A-31) + (B7-8), (A-31) + (B7-9), (A-31) + (B7-10), (A-31) + (B7-11), (A-31) + (B7-12), (A-31) + (B7-13), (A-31) + (B7-14), (A-31) + (B7-15), (A-31) + (B7-16), (A-31) + (B7-17), (A-31) + (B7-18), (A-31) + (B7-19), (A-31) + (B7-20), (A-31) + (B7-21), (A-31) + (B7-22), (A-31) + (B7-23), (A-31) + (B7-24), (A-31) + (B7-25), (A-31) + (B7-26), (A-31) + (B7-27), (A-31) + (B7-28), (A-31) + (87-29), (A-31) + (B7-30), (A-31) + (B-31), (A-31) + (B7-32), (A-31) + (B7-33), (A-31) + (B7-34), (A-31) + (B7-35), (A-31) + (B7-36), (A-31) + (B7-37), (A-31) + (B7-38), (A-31) + (B8-1), (A-31) + (B8-2), (A-31) + (B8-3), (A-31) + (B9-1), (A-31) + (B9-2), (A-31) + (B9-3), (A-31) + (B9-4), (A-31) + (B9-5), (A-31) + (B9-6), (A-31) + (B9-7).
  • (A-32) + (B1-1), (A-32) + (B1-2), (A-32) + (B1-3), (A-32) + (B1-4), (A-32) + (B1-5), (A-32) + (B1-6), (A-32) + (B1-7), (A-32) + (B1-8), (A-32) + (B2-1), (A-32) + (B2-2), (A-32) + (B3-1), (A-32) + (B3-2), (A-32) + (B3-3), (A-32) + (B3-4), (A-32) + (B3-5), (A-32) + (B3-6), (A-32) + (B-3-7), (A-32) + (B3-8), (A-32) + (B3-9), (A-32) + (B4-1), (A-32) + (B4-2), (A-32) + (B4-3), (A-32) + (B4-4), (A-32) + (B4-5), (A-32) + (B4-6), (A-32) + (B4-7), (A-32) + (B4-8), (A-32) + (B4-9), (A-32) + (B4-10), (A-32) + (B4-11 ), (A-32) + (B5-1), (A-32) + (B5-2), (A-32) + (B5-3), (A-32) + (B5-4), (A-32) + (B5-5), (A-32) + (B5-6), (A-32) + (B5-7), (A-32) + (B6-1), (A-32) + (B6-2), (A-32) + (B6-3), (A-32) + (B6-4), (A-32) + (B6-5), (A-32) + (B6-6), (A-32) + (B6-7), (A-32) + (B6-8), (A-32) + (B6-9), (A-32) + (B6-10), (A-32) + (B6-11), (A-32) + (B6-12), (A-32) + (B6-13),
    (A-32) + (B6-14), (A-32) + (B7-1), (A-32) + (B7-2), (A-32) + (B7-3), (A-32) + (B7-4), (A-32) + (B7-5), (A-32) + (B7-6), (A-32) + (B7-7), (A-32) + (B7-8), (A-32) + (B7-9), (A-32) + (B7-10), (A-32) + (B7-11), (A-32) + (B7-12), (A-32) + (B7-13), (A-32) + (B7-14), (A-32) + (B7-15), (A-32) + (B7-16), (A-32) + (B7-17), (A-32) + (B7-18), (A-32) + (B7-19), (A-32) + (B7-20), (A-32) + (B7-21), (A-32) + (B7-22), (A-32) + (B7-23), (A-32) + (B7-24), (A-32) + (B7-25), (A-32) + (B7-26), (A-32) + (B7-27), (A-32) + (B7-28), (A-32) + (B7-29), (A-32) + (B7-30), (A-32) + (B-31), (A-32) + (B7-32), (A-32) + (B7-33), (A-32) + (B7-34), (A-32) + (B7-35), (A-32) + (B7-36), (A-32) + (B7-37), (A-32) + (B7-38), (A-32) + (B8-1), (A-32) + (B8-2), (A-32) + (B8-3), (A-32) + (B9-1), (A-32) + (B9-2), (A-32) + (B9-3), (A-32) + (B9-4), (A-32) + (B9-5), (A-32) + (B9-6), (A-32) + (B9-7).
  • (A-33) + (B1-1), (A-33) + (B1-2), (A-33) + (B1-3), (A-33) + (B1-4), (A-33) + (B1-5), (A-33) + (B1-6), (A-33) + (B1-7), (A-33) + (B1-8), (A-33) + (B2-1), (A-33) + (B2-2), (A-33) + (B3-1), (A-33) + (B3-2), (A-33) + (B3-3), (A-33) + (B3-4), (A-33) + (B3-5), (A-33) + (B3-6), (A-33) + (B-3-7), (A-33) + (B3-8), (A-33) + (B3-9), (A-33) + (B4-1), (A-33) + (B4-2), (A-33) + (B4-3), (A-33) + (B4-4), (A-33) + (B4-5), (A-33) + (B4-6), (A-33) + (B4-7), (A-33) + (B4-8), (A-33) + (B4-9), (A-33) + (B4-10), (A-33) + (B4-11), (A-33) + (B5-1), (A-33) + (B5-2), (A-33) + (B5-3), (A-33) + (B5-4), (A-33) + (B5-5), (A-33) + (B6-8), (A-33) + (B5-7), (A-33) + (B6-1), (A-33) + (B6-2), (A-33) + (B6-3), (A-33) + (B6-4), (A-33) + (B6-5), (A-33) + (B6-6), (A-33) + (B6-7), (A-33) + (B6-8), (A-33) + (B6-9), (A-33) + (B6-10), (A-33) + (B6-11), (A-33) + (B6-12), (A-33) + (B6-13),
    (A-33) + (B6-14), (A-33) + (B7-1), (A-33) + (B7-2), (A-33) + (B7-3), (A-33) + (B7-4), (A-33) + (B7-5), (A-33) + (B7-6), (A-33) + (B7-7), (A-33) + (B7-8), (A-33) + (B7-9), (A-33) + (B7-10), (A-33) + (B7-11), (A-33) + (B7-12), (A-33) + (B7-13), (A-33) + (B7-14), (A-33) + (B7-15), (A-33) + (B7-16), (A-33) + (B7-17), (A-33) + (B7-18), (A-33) + (B7-19), (A-33) + (B7-20), (A-33) + (B7-21), (A-33) + (B7-22), (A-33) + (B7-23), (A-33) + (B7-24), (A-33) + (B7-25), (A-33) + (B7-26), (A-33) + (B7-27), (A-33) + (B7-28), (A-33) + (B7-29), (A-33) + (B7-30), (A-33) + (B-31), (A-33) + (B7-32), (A-33) + (B7-33), (A-33) + (B7-34), (A-33) + (B7-35), (A-33) + (B7-36), (A-33) + (B7-37), (A-33) + (B7-38), (A-33) + (B8-1), (A-33) + (B8-2), (A-33) + (B8-3), (A-33) + (B9-1), (A-33) + (B9-2), (A-33) + (B9-3), (A-33) + (B9-4), (A-33) + (B9-5), (A-33) + (B9-6), (A-33) + (B9-7).
  • (A-34) + (B1-1), (A-34) + (B1-2), (A-34) + (B1-3), (A-34) + (B1-4), (A-34) + (B1-5), (A-34) + (B1-8), (A-34) + (B1-7), (A-34) + (B1-8), (A-34) + (B2-1), (A-34) + (B2-2), (A-34) + (B3-1), (A-34) + (B3-2), (A-34) + (B3-3), (A-34) + (B3-4), (A-34) + (B3-5), (A-34) + (B3-6), (A-34) + (B-3-7), (A-34) + (B3-8). (A-34) + (B3-9), (A-34) + (B4-1), (A-34) + (B4-2), (A-34) + (B4-3), (A-34) + (B4-4), (A-34) + (B4-5), (A-34) + (B4-6), (A-34) + (B4-7), (A-34) + (B4-8), (A-34) + (B4-9), (A-34) + (B4-1 0), (A-34) + (B4-11), (A-34) + (B5-1), (A-34) + (B5-2), (A-34) + (B5-3), (A-34) + (B5-4), (A-34) + (B5-5), (A-34) + (B5-6), (A-34) + (B5-7), (A-34) + (B6-1), (A-34) + (B6-2), (A-34) + (B6-3), (A-34) + (B6-4), (A-34) + (B6-5), (A-34) + (B6-6), (A-34) + (B6-7), (A-34) + (B6-8), (A-34) + (B6-9), (A-34) + (B6-10), (A-34) + (B6-11), (A-34) + (B6-12), (A-34) + (B6-13),
    (A-34) + (B6-14), (A-34) + (B7-1), (A-34) + (B7-2), (A-34) + (B7-3), (A-34) + (B7-4), (A-34) + (B7-5), (A-34) + (B7-6), (A-34) + (B7-7), (A-34) + (B7-8), (A-34) + (B7-9), (A-34) + (B7-10), (A-34) + (B7-11), (A-34) + (B7-12), (A-34) + (B7-13), (A-34) + (B7-14), (A-34) + (B7-15), (A-34) + (B7-16), (A-34) + (B7-17), (A-34) + (B7-18), (A-34) + (B7-19), (A-34) + (B7-20), (A-34) + (B7-21), (A-34) + (B7-22), (A-34) + (B7-23), (A-34) + (B7-24), (A-34) + (B7-25), (A-34) + (B7-26), (A-34) + (B7-27), (A-34) + (B7-28), (A-34) + (B7-29), (A-34) + (B7-30), (A-34) + (B-31), (A-34) + (B7-32), (A-34) + (B7-33), (A-34) + (B7-34), (A-34) + (B7-35), (A-34) + (B7-36), (A-34) + (B7-37), (A-34) + (B7-38), (A-34) + (B8-1), (A-34) + (B8-2), (A-34) + (B8-3), (A-34) + (B9-1), (A-34) + (B9-2), (A-34) + (B9-3), (A-34) + (B9-4), (A-34) + (B9-5), (A-34) + (B9-6), (A-34) + (B9-7).
  • (A-35) + (B1-1), (A-35) + (B1-2), (A-35) + (B1-3), (A-35) + (B1-4), (A-35) + (B1-5), (A-35) + (B1-6), (A-35) + (B1-7), (A-35) + (B1-8), (A-35) + (B2-1), (A-35) + (B2-2), (A-35) + (B3-1), (A-35) + (B3-2), (A-35) + (B3-3), (A-35) + (B3-4), (A-35) + (B3-5), (A-35) + (B3-6), (A-35) + (B-3-7), (A-35) + (B3-8), (A-35) + (B3-9), (A-35) + (B4-1), (A-35) + (B4-2), (A-35) + (B4-3), (A-35) + (B4-4), (A-35) + (B4-5), (A-35) + (B4-6), (A-35) + (B4-7), (A-35) + (B4-8), (A-35) + (B4-9), (A-35) + (B4-10), (A-35) + (B4-11), (A-35) + (B5-1), (A-35) + (B5-2), (A-35) + (B5-3), (A-35) + (B5-4), (A-35) + (B5-5), (A-35) + (B5-6), (A-35) + (B5-7), (A-35) + (B6-1), (A-35) + (B6-2), (A-35) + (B6-3), (A-35) + (B6-4), (A-35) + (B6-5), (A-35) + (B6-6), (A-35) + (B6-7), (A-35) + (B6-8), (A-35) + (B6-9), (A-35) + (B6-10), (A-35) + (B6-11), (A-35) + (B6-12), (A-35) + (B6-13),
    (A-35) + (B6-14), (A-35) + (B7-1), (A-35) + (B7-2), (A-35) + (B7-3), (A-35) + (B7-4), (A-35) + (B7-5), (A-35) + (B7-6). (A-35) + (B7-7), (A-35) + (B7-8), (A-35) + (B7-9), (A-35) + (B7-10), (A-35) + (B7-11), (A-35) + (B7-12), (A-35) + (B7-13), (A-35) + (B7-14), (A-35) + (B7-15), (A-35) + (B7-16), (A-35) + (B7-17), (A-35) + (B7-18), (A-35) + (B7-19), (A-35) + (B7-20), (A-35) + (B7-21), (A-35) + (B7-22), (A-35) + (B7-23), (A-35) + (B7-24), (A-35) + (B7-25), (A-35) + (B7-26), (A-35) + (B7-27), (A-35) + (B7-28), (A-35) + (B7-29), (A-35) + (B7-30), (A-35) + (B-31 ), (A-35) + (B7-32), (A-35) + (B7-33), (A-35) + (B7-34), (A-35) + (B7-35), (A-35) + (B7-36), (A-35) + (B7-37), (A-35) + (B7-38), (A-35) + (B8-1), (A-35) + (B8-2), (A-35) + (B8-3), (A-35) + (B9-1), (A-35) + (B9-2), (A-35) + (B9-3), (A-35) + (B9-4), (A-35) + (B9-5), (A-35) + (B9-6), (A-35) + (B9-7).
Of particular interest is the use of herbicidal compositions containing the following compounds (A) + (B):
  • (A-0) + (B1-1), (A-0) + (B1-2), (A-0) + (B1-3), (A-0) + (B1-4), (A -0) + (B1-5), (A-0) + (B1-6), (A-0) + (B1-7), (A-0) + (B1-8), (A-0 ) + (B2-1), (A-0) + (B2-2), (A-0) + (B3-1), (A-0) + (B3-2), (A-0) + (B3-3), (A-0) + (B3-4), (A-0) + (B3-5), (A-0) + (B3-6), (A-0) + (B -3-7), (A-0) + (B3-8), (A-0) + (B3-9), (A-0) + (B4-1), (A-0) + (B4 -2), (A-0) + (B4-3), (A-0) + (B4-4), (A-0) + (B4-5), (A-0) + (B4-6 ), (A-0) + (B4-7), (A-0) + (B4-8), (A-0) + (B4-9), (A-0) + (B4-10), (A-0) + (B4-11), (A-0) + (B5-1), (A-0) + (B5-2), (A-0) + (B5-3), (A -0) + (B5-4), (A-0) + (B5-5), (A-0) + (B5-6), (A-0) + (B5-7), (A-0 ) + (B6-1), (A-0) + (B6-2), (A-0) + (B6-3), (A-0) + (B6-4), (A-0) + (B6-5), (A-0) + (B6-6), (A-0) + (B6-7), (A-0) + (B6-8), (A-0) + (B6 -9), (A-0) + (B6-10), (A-0) + (B6-11), (A-0) + (B6-12), (A-0) + (B6-13 ), (A-0) + (B6-14), (A-0) + (B7-1), (A-0) + (B7-2), (A-0) + (B7-3), (A-0) + (B7-4), (A-0) + (B7-5), (A-0) + (B7-6), (A-0) + (B7-7), (A -0) + (B7-8), (A-0) + (B7-9), (A-0) + (B7-10), (A-0) + (B7-11) , (A-0) + (B7-12), (A-0) + (B7-13), (A-0) + (B7-14), (A-0) + (B7-15), ( A-0) + (B7-16), (A-0) + (B7-17), (A-0) + (B7-18), (A-0) + (B7-19), (A-) 0) + (B7-20), (A-0) + (B7-21), (A-0) + (B7-22), (A-0) + (B7-23), (A-0) + (B7-24), (A-0) + (B7-25), (A-0) + (B7-26), (A-0) + (B7-27), (A-0) + ( B7-28), (A-0) + (B7-29), (A-0) + (B7-30), (A-0) + (B-31), (A-0) + (B7- 32), (A-0) + (B7-33), (A-0) + (B7-34), (A-0) + (B7-35), (A-0) + (B7-36) , (A-0) + (B7-37), (A-0) + (B7-38), (A-0) + (B8-1), (A-0) + (B8-2), ( A-0) + (B8-3), (A-0) + (B9-1), (A-0) + (B9-2), (A-0) + (B9-3), (A-) 0) + (B9-4), (A-0) + (B9-5), (A-0) + (B9-6), (A-0) + (B9-7).
  • (A-1) + (B1-1), (A-1) + (B1-2), (A-1) + (B1-3), (A-1) + (B1-4), (A -1) + (B1-5), (A-1) + (B1-6), (A-1) + (B1-7), (A-1) + (B1-8), (A-1 ) + (B2-1), (A-1) + (B2-2), (A-1) + (B3-1), (A-1) + (B3-2), (A-1) + (B3-3), (A-1) + (B3-4), (A-1) + (B3-5), (A-1) + (B3-6), (A-1) + (B -3-7), (A-1) + (B3-8), (A-1) + (B3-9), (A-1) + (B4-1), (A-1) + (B4 -2), (A-1) + (B4-3), (A-1) + (B4-4), (A-1) + (B4-5), (A-1) + (B4-6 ), (A-1) + (B4-7), (A-1) + (B4-8), (A-1) + (B4-9), (A-1) + (B4-10), (A-1) + (B4-11), (A-1) + (B5-1), (A-1) + (B5-2), (A-1) + (B6-3), (A -1) + (B5-4), (A-1) + (B5-5), (A-1) + (B5-6), (A-1) + (B5-7), (A-1 ) + (B6-1), (A-1) + (B6-2), (A-1) + (B6-3), (A-1) + (B6-4), (A-1) + (B6-5), (A-1) + (B6-6), (A-1) + (B6-7), (A-1) + (B6-8), (A-1) + (B6 -9), (A-1) + (B6-10), (A-1) + (B6-11), (A-1) + (B6-12), (A-1) + (B6-13 ), (A-1) + (B6-14), (A-1) + (B7-1), (A-1) + (B7-2), (A-1) + (B7-3), (A-1) + (B7-4), (A-1) + (B7-5), (A-1) + (B7-6), (A-1) + (B7-7), (A -1) + (B7-8), (A-1) + (B7-9), (A-1) + (B7-10), (A-1) + (B7-11) , (A-1) + (B7-12), (A-1) + (B7-13), (A-1) + (B7-14), (A-1) + (B7-15), ( A-1) + (B7-16), (A-1) + (B7-17), (A-1) + (B7-18), (A-1) + (B7-19), (A-) 1) + (B7-20), (A-1) + (B7-21), (A-1) + (B7-22), (A-1) + (B7-23), (A-1) + (B7-24), (A-1) + (B7-25), (A-1) + (B7-26), (A-1) + (B7-27), (A-1) + ( B7-28), (A-1) + (B7-29), (A-1) + (B7-30), (A-1) + (B-31), (A-1) + (B7- 32), (A-1) + (B7-33), (A-1) + (B7-34), (A-1) + (B7-35), (A-1) + (B7-36) , (A-1) + (B7-37), (A-1) + (B7-38), (A-1) + (B8-1), (A-1) + (B8-2), ( A-1) + (B8-3), (A-1) + (B9-1), (A-1) + (B9-2), (A-1) + (B9-3), (A-) 1) + (B9-4), (A-1) + (B9-5), (A-1) + (B9-6), (A-1) + (B9-7).
  • (A-2) + (B1-1), (A-2) + (B1-2), (A-2) + (B1-3), (A-2) + (B1-4), (A -2) + (B1-5), (A-2) + (B1-6), (A-2) + (B1-7), (A-2) + (B1-8), (A-2 ) + (B2-1), (A-2) + (B2-2), (A-2) + (B3-1), (A-2) + (B3-2), (A-2) + (B3-3), (A-2) + (B3-4), (A-2) + (B3-5), (A-2) + (B3-6), (A-2) + (B -3-7), (A-2) + (B3-8), (A-2) + (B3-9), (A-2) + (B4-1), (A-2) + (B4 -2), (A-2) + (B4-3), (A-2) + (B4-4), (A-2) + (B4-5), (A-2) + (B4-6 ), (A-2) + (B4-7), (A-2) + (B4-8), (A-2) + (B4-9), (A-2) + (B4-10), (A-2) + (B4-11), (A-2) + (B5-1), (A-2) + (B5-2), (A-2) + (B5-3), (A -2) + (B5-4), (A-2) + (B5-5), (A-2) + (B5-6), (A-2) + (B5-7), (A-2 ) + (B6-1), (A-2) + (B6-2), (A-2) + (B6-3), (A-2) + (B6-4), (A-2) + (B6-5), (A-2) + (B6-6), (A-2) + (B6-7), (A-2) + (B6-8), (A-2) + (B6-9), (A-2) + (B6-10), (A-2) + (B6-11), (A-2) + (B6-12), (A -2) + (B6-13), (A-2) + (B6-14), (A-2) + (B7-1), (A-2) + (B7-2), (A-2 ) + (B7-3), (A-2) + (B7-4), (A-2) + (B7-5), (A-2) + (B7-6), (A-2) + (B7-7), (A-2) + (B7-8), (A-2) + (B7-9), (A-2) + (B7-10), (A-2) + (B7 -11), (A-2) + (B7-12), (A-2) + (B7-13), (A-2) + (B7-14), (A-2) + (B7-15 ), (A-2) + (B7-16), (A-2) + (B7-17), (A-2) + (B7-18), (A-2) + (B7-19), (A-2) + (B7-20), (A-2) + (B7-21), (A-2) + (B7-22), (A-2) + (B7-23), (A -2) + (B7-24), (A-2) + (B7-25), (A-2) + (B7-26), (A-2) + (B7-27), (A-2 ) + (B7-28), (A-2) + (B7-29), (A-2) + (87-30), (A-2) + (B-31), (A-2) + (B7-32), (A-2) + (B7-33), (A-2) + (B7-34), (A-2) + (B7-35), (A-2) + (B7 -36), (A-2) + (B7-37), (A-2) + (B7-38), (A-2) + (B8-1), (A-2) + (B8-2 ), (A-2) + (B8-3), (A-2) + (B9-1), (A-2) + (B9-2), (A-2) + (B9-3), (A-2) + (B9-4), (A-2) + (B9-5), (A-2) + (B9-6), (A-2) + (B9-7).
  • (A-3) + (B1-1), (A-3) + (B1-2), (A-3) + (B1-3), (A-3) + (B1-4), (A -3) + (B1-5), (A-3) + (B1-6), (A-3) + (B1-7), (A-3) + (B1-8), (A-3 ) + (B2-1), (A-3) + (B2-2), (A-3) + (B3-1), (A-3) + (B3-2), (A-3) + (B3-3), (A-3) + (B3-4), (A-3) + (B3-5), (A-3) + (B3-6), (A-3) + (B -3-7), (A-3) + (B3-8), (A-3) + (B3-9), (A-3) + (B4-1), (A-3) + (B4 -2), (A-3) + (B4-3), (A-3) + (B4-4), (A-3) + (B4-5), (A-3) + (B4-6 ), (A-3) + (B4-7), (A-3) + (B4-8), (A-3) + (B4-9), (A-3) + (B4-10), (A-3) + (B4-11), (A-3) + (B5-1), (A-3) + (B5-2), (A-3) + (B5-3), (A -3) + (B5-4), (A-3) + (B5-5), (A-3) + (B5-6), (A-3) + (B5-7), (A-3 ) + (B6-1), (A-3) + (B6-2), (A-3) + (B6-3), (A-3) + (B6-4), (A-3) + (B6-5), (A-3) + (B6-6), (A-3) + (B6-7), (A-3) + (B6-8), (A-3) + (86 -9), (A-3) + (B6-1 0), (A-3) + (B6-11), (A-3) + (B6-12), (A-3) + (B6- 13), (A-3) + (B6-14), (A-3) + (B7-1), (A-3) + (B7-2), (A-3) + (B7-3) , (A-3) + (B7-4), (A-3) + (B7-5), (A-3) + (B7-6), (A-3) + (B7-7), ( A-3) + (B7-8), (A-3) + (B7-9), (A-3) + (B7-10), (A-3) + (B7-11 ), (A-3) + (B7-12), (A-3) + (B7-13), (A-3) + (B7-14), (A-3) + (B7-15), (A-3) + (B7-16), (A-3) + (B7-17), (A-3) + (B7-18), (A-3) + (B7-19), (A -3) + (B7-20), (A-3) + (B7-21), (A-3) + (B7-22), (A-3) + (B7-23), (A-3 ) + (B7-24), (A-3) + (B7-25), (A-3) + (B7-26), (A-3) + (B7-27), (A-3) + (B7-28), (A-3) + (B7-29), (A-3) + (B7-30), (A-3) + (B-31), (A-3) + (B7 -32), (A-3) + (B7-33), (A-3) + (B7-34), (A-3) + (B7-35), (A-3) + (B7-36), (A-3) + (B7-37), (A -3) + (B7-38), (A-3) + (B8-1), (A-3) + (B8-2), (A-3) + (B8-3), (A-3 ) + (B9-1), (A-3) + (B9-2), (A-3) + (B9-3), (A-3) + (B9-4), (A-3) + (B9-5), (A-3) + (B9-6), (A-3) + (B9-7).
  • (A-4) + (B1-1), (A-4) + (B1-2), (A-4) + (B1-3), (A-4) + (B1-4), (A -4) + (B1-5), (A-4) + (B1-6), (A-4) + (B1-7), (A-4) + (B1-8), (A-4 ) + (B2-1), (A-4) + (B2-2), (A-4) + (B3-1), (A-4) + (B3-2), (A-4) + (B3-3), (A-4) + (B3-4), (A-4) + (B3-5), (A-4) + (B3-6), (A-4) + (B -3-7), (A-4) + (B3-8), (A-4) + (B3-9), (A-4) + (B4-1), (A-4) + (B4 -2), (A-4) + (B4-3), (A-4) + (B4-4), (A-4) + (B4-6), (A-4) + (B4-6 ), (A-4) + (B4-7), (A-4) + (B4-8), (A-4) + (B4-9), (A-4) + (B4-10), (A-4) + (B4-11), (A-4) + (B5-1), (A-4) + (B5-2), (A-4) + (85-3), (A -4) + (B5-4), (A-4) + (B5-5), (A-4) + (B5-6), (A-4) + (B5-7), (A-4 ) + (B6-1), (A-4) + (B6-2), (A-4) + (86-3), (A-4) + (B8-4), (A-4) + (B6-5), (A-4) + (B6-6), (A-4) + (B6-7), (A-4) + (B6-8), (A-4) + (B6 -9), (A-4) + (B6-10), (A-4) + (B6-11), (A-4) + (B6-12), (A-4) + (B6-13 ), (A-4) + (B6-14), (A-4) + (B7-1), (A-4) + (B7-2), (A-4) + (B7-3), (A-4) + (B7-4), (A-4) + (B7-6), (A-4) + (B7-6), (A-4) + (B7-7), (A -4) + (B7-8), (A-4) + (B7-9), (A-4) + (B7-10), (A-4) + (B7-11) , (A-4) + (B7-12), (A-4) + (B7-13), (A-4) + (B7-14), (A-4) + (B7-15), ( A-4) + (B7-16), (A-4) + (B7-17), (A-4) + (B7-18), (A-4) + (B7-19), (A-) 4) + (B7-20), (A-4) + (B7-21), (A-4) + (B7-22), (A-4) + (B7-23), (A-4) + (B7-24), (A-4) + (B7-25), (A-4) + (B7-26), (A-4) + (B7-27), (A-4) + ( B7-28), (A-4) + (B7-29), (A-4) + (B7-30), (A-4) + (B-31), (A-4) + (B7- 32), (A-4) + (B7-33), (A-4) + (B7-34), (A-4) + (B7-35), (A-4) + (B7-36) , (A-4) + (B7-37), (A-4) + (B7-38), (A-4) + (B8-1), (A-4) + (B8-2), ( A-4) + (B8-3), (A-4) + (B9-1), (A-4) + (B9-2), (A-4) + (B9-3), (A- 4) + (B9-4), (A-4) + (B9-5), (A-4) + (B9-6), (A-4) + (B9-7).
  • (A-5) + (B1-1), (A-5) + (B1-2), (A-5) + (B1-3), (A-5) + (B1-4), (A -5) + (B1-5), (A-5) + (B1-6), (A-5) + (B9-7), (A-5) + (B1-8), (A-5 ) + (B2-1), (A-5) + (B2-2), (A-5) + (B3-1), (A-5) + (B3-2), (A-5) + (B3-3), (A-5) + (B3-4), (A-5) + (B3-5), (A-5) + (B3-6), (A-5) + (B -3-7), (A-5) + (B3-8), (A-5) + (B3-9), (A-5) + (B4-1), (A-5) + (B4-2), (A-5) + (B4-3), (A-5) + (B4-4), (A-5) + (B4-5), (A -5) + (B4-6), (A-5) + (B4-7), (A-5) + (B4-8), (A-5) + (B4-9), (A-5 ) + (B4-10), (A-5) + (B4-11), (A-5) + (B5-1), (A-5) + (B5-2), (A-5) + (B5-3), (A-5) + (B5-4), (A-5) + (B5-5), (A-5) + (B5-6), (A-5) + (B5 -7), (A-5) + (B6-1), (A-5) + (B6-2), (A-5) + (B6-3), (A-5) + (B6-4 ), (A-5) + (B6-5), (A-5) + (B6-6), (A-5) + (B6-7), (A-5) + (B6-8), (A-5) + (B6-9), (A-5) + (B6-10), (A-5) + (B6-11), (A-5) + (B6-12), (A -5) + (B6-13), (A-5) + (B6-14), (A-5) + (B7-1), (A-5) + (B7-2), (A-5 ) + (B7-3), (A-5) + (B7-4), (A-5) + (B7-5), (A-5) + (B7-6), (A-5) + (B7-7), (A-5) + (B7-8), (A-5) + (B7-9), (A-5) + (B7-10), (A-5) + (B7 -11), (A-5) + (B7-12), (A-5) + (B7-13), (A-5) + (B7-14), (A-5) + (B7-15 ), (A-5) + (B7-16), (A-5) + (B7-17), (A-5) + (B7-18), (A-5) + (B7-19), (A-5) + (B7-20), (A-5) + (B7-21), (A-5) + (B7-22), (A-5) + (B7-23), (A -5) + (B7-24), (A-5) + (B7-25), (A-5) + (B7-26), (A-5) + (B7-27), (A-5 ) + (B7-28), (A-5) + (B7-29), (A-5) + (B7-3 0), (A-5) + (B-31), (A-5) + (B7-32), (A-5) + (B7-33), (A-5) + (B7-34) , (A-5) + (B7-36), (A-5) + (B7-36), (A-5) + (B7-37), (A-5) + (B7-38), ( A-5) + (B8-1), (A-5) + (B8-2), (A-5) + (B8-3), (A-5) + (B9-1), (A-) 5) + (B9-2), (A-5) + (B9-3), (A-5) + (B9-4), (A-5) + (B9-5), (A-5) + (B9-6), (A-5) + (B9-7).
  • (A-6) + (B1-1), (A-6) + (B1-2), (A-6) + (B1-3), (A-6) + (B1-4), (A -6) + (B1-5), (A-6) + (B1-6), (A-6) + (B1-7), (A-6) + (B1-8), (A-6 ) + (B2-1), (A-6) + (B2-2), (A-6) + (B3-1), (A-6) + (B3-2), (A-6) + (B3-3), (A-6) + (B3-4), (A-6) + (B3-5), (A-6) + (B3-6), (A-6) + (B -3-7), (A-6) + (B3-8), (A-6) + (B3-9), (A-6) + (B4-1), (A-6) + (B4 -2), (A-6) + (B4-3), (A-6) + (B4-4), (A-6) + (B4-5), (A-6) + (B4-6 ), (A-6) + (B4-7), (A-6) + (B4-8), (A-6) + (B4-9), (A-6) + (B4-10), (A-6) + (B4-11), (A-6) + (B5-1), (A-6) + (B5-2), (A-6) + (B5-3), (A -6) + (B5-4), (A-6) + (B5-5), (A-6) + (B5-6), (A-6) + (B5-7), (A-6 ) + (B6-1), (A-6) + (B6-2), (A-6) + (B6-3), (A-6) + (86-4), (A-6) + (B6-5), (A-6) + (B6-6), (A-6) + (B6-7), (A-6) + (B6-8), (A-6) + (B6 -9), (A-6) + (B6-10), (A-6) + (B6-11), (A-6) + (B6-12), (A-6) + (B6-13 ), (A-6) + (B6-14), (A-6) + (B7-1), (A-6) + (B7-2), (A-6) + (B7-3), (A-6) + (B7-4), (A-6) + (B7-5), (A-6) + (B7-6), (A-6) + (B7-7), (A -6) + (B7-8), (A-6) + (B7-9), (A-6) + (B7-10), (A-6) + (B7-11) , (A-6) + (B7-12), (A-6) + (B7-13), (A-6) + (B7-14), (A-6) + (B7-15), (A-6) + (B7-16), (A-6) + (B7-17), (A -6) + (B7-18), (A-6) + (B7-19), (A-6) + (B7-20), (A-6) + (B7-21), (A-6 ) + (B7-22), (A-6) + (B7-23), (A-6) + (B7-24), (A-6) + (B7-26), (A-6) + (B7-26), (A-6) + (B7-27), (A-6) + (B7-28), (A-6) + (B7-29), (A-6) + (B7 -30), (A-6) + (B-31), (A-6) + (B7-32), (A-6) + (B7-33), (A-6) + (B7-34 ), (A-6) + (B7-35), (A-6) + (B7-36), (A-6) + (B7-37), (A-6) + (B7-38), (A-6) + (B8-1), (A-6) + (B8-2), (A-6) + (B8-3), (A-6) + (B9-1), (A -6) + (B9-2), (A-6) + (B9-3), (A-6) + (B9-4), (A-6) + (B9-5), (A-6 ) + (B9-6), (A-6) + (B9-7).
  • (A-7) + (B1-1), (A-7) + (B1-2), (A-7) + (B1-3), (A-7) + (B1-4), (A -7) + (B1-5), (A-7) + (B1-6), (A-7) + (B1-7), (A-7) + (B1-8), (A-7 ) + (B2-1), (A-7) + (B2-2), (A-7) + (B3-1), (A-7) + (B3-2), (A-7) + (B3-3), (A-7) + (B3-4), (A-7) + (B3-5), (A-7) + (B3-6), (A-7) + (B -3-7), (A-7) + (B3-8), (A-7) + (B3-9), (A-7) + (B4-1), (A-7) + (B4 -2), (A-7) + (B4-3), (A-7) + (B4-4), (A-7) + (B4-5), (A-7) + (B4-6 ), (A-7) + (B4-7), (A-7) + (B4-8), (A-7) + (B4-9), (A-7) + (B4-10), (A-7) + (B4-11), (A-7) + (B5-1), (A-7) + (B5-2), (A-7) + (B5-3), (A -7) + (B5-4), (A-7) + (B5-5), (A-7) + (B5-6), (A-7) + (B5-7), (A-7 ) + (B6-1), (A-7) + (B6-2), (A-7) + (B6-3), (A-7) + (B6-4), (A-7) + (B6-5), (A-7) + (B6-6), (A-7) + (B6-7), (A-7) + (B6-8), (A-7) + (B6 -9), (A-7) + (B6-10), (A-7) + (B6-11), (A-7) + (B6-12), (A-7) + (B6-13 ), (A-7) + (B6-14), (A-7) + (B7-1), (A-7) + (B7-2), (A-7) + (B7-3), (A-7) + (B7-4), (A-7) + (B7-5), (A-7) + (B7-6), (A-7) + (B7-7), (A -7) + (B7-8), (A-7) + (B7-9), (A-7) + (B7-10), (A-7) + (B7-11) , (A-7) + (B7-12), (A-7) + (B7-13), (A-7) + (B7-14), (A-7) + (B7-15), ( A-7) + (B7-16), (A-7) + (B7-17), (A-7) + (B7-18), (A-7) + (B7-19), (A- 7) + (B7-20), (A-7) + (B7-21), (A-7) + (B7-22), (A-7) + (B7-23), (A-7) + (B7-24), (A-7) + (B7-25), (A-7) + (B7-26), (A-7) + (B7-27), (A-7) + ( B7-28), (A-7) + (B7-29), (A-7) + (B7-30), (A-7) + (B-31), (A-7) + (B7- 32), (A-7) + (B7-33), (A-7) + (B7-34), (A-7) + (B7-35), (A-7) + (B7-36) , (A-7) + (B7-37), (A-7) + (B7-38), (A-7) + (B8-1), (A-7) + (B8-2), ( A-7) + (B8-3), (A-7) + (B9-1), (A-7) + (B9-2), (A-7) + (B9-3), (A- 7) + (B9-4), (A-7) + (B9-5), (A-7) + (B9-6), (A-7) + (B9-7).
  • (A-8) + (B1-1), (A-8) + (B1-2), (A-8) + (B1-3), (A-8) + (B1-4), (A -8) + (B1-5), (A-8) + (B1-6), (A-8) + (B-7), (A-8) + (B1-8), (A-8 ) + (B2-1), (A-8) + (B2-2), (A-8) + (B3-1), (A-8) + (B3-2), (A-8) + (B3-3), (A-8) + (B3-4), (A-8) + (B3-5), (A-8) + (B3-6), (A-8) + (B -3-7), (A-8) + (B3-8), (A-8) + (B3-9), (A-8) + (B4-1), (A-8) + (B4 -2), (A-8) + (B4-3), (A-8) + (B4-4), (A-8) + (B4-5), (A-8) + (B4-6 ), (A-8) + (B4-7), (A-8) + (B4-8), (A-8) + (B4-9), (A-8) + (B4-10), (A-8) + (B4-11), (A-8) + (B5-1), (A-8) + (B5-2), (A-8) + (B5-3), (A -8) + (B5-4), (A-8) + (B5-5), (A-8) + (B5-6), (A-8) + (B5-7), (A-8 ) + (B6-1), (A-8) + (B6-2), (A-8) + (B6-3), (A-8) + (B6-4), (A-8) + (B6-5), (A-8) + (B6-6), (A-8) + (B6-7), (A-8) + (B6-8), (A-8) + (B6 -9), (A-8) + (B6-10), (A-8) + (B6-11), (A-8) + (B6-12), (A-8) + (B8-13 ), (A-8) + (B6-14), (A-8) + (B7-1), (A-8) + (B7-2), (A-8) + (B7-3), (A-8) + (B7-4), (A-8) + (B7-5), (A-8) + (B7-6), (A-8) + (B7-7), (A -8) + (B7-8), (A-8) + (B7-9), (A-8) + (B7-10), (A-8) + (B7-11), (A-8) + (B7-12), (A-8) + (B7-13), (A-8) + (B7-14), (A-8) + (B7-15), (A -8) + (B7-16), (A-8) + (B7-17), (A-8) + (B7-18), (A-8) + (B7-19), (A-8 ) + (B7-20), (A-8) + (B7-21), (A-8) + (B7-22), (A-8) + (B7-23), (A-8) + (B7-24), (A-8) + (B7-25), (A-8) + (B7-26), (A-8) + (B7-27), (A-8) + (B7 -28), (A-8) + (B7-29), (A-8) + (B7-30), (A-8) + (B-31), (A-8) + (B7-32 ), (A-8) + (B7-33), (A-8) + (B7-34), (A-8) + (B7-35), (A-8) + (B7-36), (A-8) + (B7-37), (A-8) + (B7-38), (A-8) + (B8-1), (A-8) + (B8-2), (A -8) + (B8-3), (A-8) + (B9-1), (A-8) + (B9-2), (A-8) + (B9-3), (A-8 ) + (B9-4), (A-8) + (B9-5), (A-8) + (B9-6), (A-8) + (B9-7).
  • (A-9) + (B1-1), (A-9) + (B1-2), (A-9) + (B1-3), (A-9) + (B1-4), (A -9) + (B1-5), (A-9) + (B1-6), (A-9) + (B1-7), (A-9) + (B1-8), (A-9 ) + (B2-1), (A-9) + (B2-2), (A-9) + (B3-1), (A-9) + (B3-2), (A-9) + (B3-3), (A-9) + (B3-4), (A-9) + (B3-5), (A-9) + (B3-6), (A-9) + (B -3-7), (A-9) + (B3-8), (A-9) + (B3-9), (A-9) + (B4-1), (A-9) + (B4 -2), (A-9) + (B4-3), (A-9) + (B4-4), (A-9) + (B4-5), (A-9) + (B4-6 ), (A-9) + (B4-7), (A-9) + (B4-8), (A-9) + (B4-9), (A-9) + (B4-10), (A-9) + (B4-11), (A-9) + (B5-1), (A-9) + (B5-2), (A-9) + (B5-3), (A -9) + (B5-4), (A-9) + (B5-5), (A-9) + (B5-6), (A-9) + (B5-7), (A-9 ) + (B6-1), (A-9) + (B6-2), (A-9) + (B6-3), (A-9) + (B6-4), (A-9) + (B6-5), (A-9) + (B6-6), (A-9) + (B6-7), (A -9) + (B6-8), (A-9) + (B6-9), (A-9) + (B6-10), (A-9) + (B6-11), (A-9 ) + (B6-12), (A-9) + (B6-13), (A-9) + (B8-14), (A-9) + (B7-1), (A-9) + (B7-2), (A-9) + (B7-3), (A-9) + (B7-4), (A-9) + (B7-5), (A-9) + (B7 -6), (A-9) + (B7-7), (A-9) + (B7-8), (A-9) + (B7-9), (A-9) + (B7-10 ), (A-9) + (B7-11), (A-9) + (B7-12), (A-9) + (B7-13), (A-9) + (B7-14), (A-9) + (B7-15), (A-9) + (B7-16), (A-9) + (B7-17), (A-9) + (B7-18), (A -9) + (B7-19), (A-9) + (B7-20), (A-9) + (B7-21), (A-9) + (B7-22), (A-9 ) + (B7-23), (A-9) + (B7-24), (A-9) + (B7-26), (A-9) + (B7-26), (A-9) + (B7-27), (A-9) + (B7-28), (A-9) + (B7-29), (A-9) + (B7-30), (A-9) + (B -31), (A-9) + (B7-32), (A-9) + (B7-33), (A-9) + (B7-34), (A-9) + (B7-35 ), (A-9) + (B7-36), (A-9) + (B7-37), (A-9) + (B7-38), (A-9) + (B8-1), (A-9) + (B8-2), (A-9) + (B8-3), (A-9) + (B9-1), (A-9) + (B9-2), (A -9) + (B9-3), (A-9) + (B9-4), (A-9) + (B9-5), (A-9) + (B9-6), (A-9 ) + (B9-7).
  • (A-10) + (B1-1), (A-10) + (B1-2), (A-10) + (B1-3), (A-10) + (B1-4), (A -10) + (B1-5), (A-10) + (B1-6), (A-10) + (B1-7), (A-10) + (B1-8), (A-10 ) + (B2-1), (A-10) + (B2-2), (A-10) + (B3-1), (A-10) + (B3-2), (A-10) + (B3-3), (A-10) + (B3-4), (A-10) + (B3-5), (A-10) + (B3-6), (A-10) + (B -3-7), (A-10) + (B3-8), (A-10) + (B3-9), (A-10) + (B4-1), (A-10) + (B4 -2), (A-10) + (B4-3), (A-10) + (B4-4), (A-10) + (B4-5), (A-10) + (B4-6 ), (A-10) + (B4-7), (A-10) + (B4-8), (A-10) + (B4-9), (A-10) + (B4-10), (A-10) + (B4-11), (A-10) + (B5-1), (A-10) + (B5-2), (A-10) + (B5-3), (A -10) + (B5-4), (A-10) + (B5-5), (A-10) + (B5-6), (A-10) + (B5-7), (A-10 ) + (B6-1), (A-10) + (B6-2), (A-10) + (B6-3), (A-10) + (B6-4), (A-10) + (B6-5), (A-10) + (B6-6), (A-10) + (B6-7), (A-10) + (B6-8), (A-10) + (B6 -9), (A-10) + (B6-10), (A-10) + (B6-11), (A-10) + (B6-12), (A-10) + (B6-13 ).
    (A-10) + (B6-14), (A-10) + (B7-1), (A-10) + (B7-2), (A-10) + (B7-3), (A -10) + (B7-4), (A-10) + (B7-5), (A-10) + (B7-6), (A-10) + (B7-7), (A-10 ) + (B7-8), (A-10) + (B7-9), (A-10) + (B7-10), (A-10) + (B7-11), (A-10) + (B7-12), (A-10) + (B7-13), (A-10) + (B7-14), (A-10) + (B7-15), (A-10) + (B7 -16), (A-10) + (B7-17), (A-10) + (B7-18), (A-10) + (B7-19), (A-10) + (B7-20 ), (A-10) + (B7-21), (A-10) + (B7-22), (A-10) + (B7-23), (A-10) + (B7-24), (A-10) + (B7-25), (A-10) + (B7-26), (A-10) + (B7-27), (A-10) + (B7-28), (A-10) + (B7-29), (A -10) + (B7-30), (A-10) + (B-31), (A-10) + (B7-32), (A-10) + (B7-33), (A-10 ) + (B7-34), (A-10) + (B7-35), (A-10) + (B7-36), (A-10) + (B7-37), (A-10) + (B7-38), (A-10) + (B8-1), (A-10) + (B8-2), (A-10) + (B8-3), (A-10) + (B9 -1), (A-10) + (B9-2), (A-10) + (B9-3), (A-10) + (B9-4), (A-10) + (B9-5 ), (A-10) + (B9-6), (A-10) + (B9-7).
  • (A-11) + (B1-1), (A-11) + (B1-2), (A-11) + (B1-3), (A-11) + (B1-4), (A -11) + (B1-5), (A-11) + (B1-6), (A-11) + (B1-7), (A-11) + (B1-8), (A-11 ) + (82-1), (A-11) + (B2-2), (A-11) + (B3-1), (A-11) + (B3-2), (A-11) + (B3-3), (A-11) + (B3-4), (A-11) + (B3-5), (A-11) + (B3-6), (A-11) + (B -3-7), (A-11) + (B3-8), (A-11) + (B3-9), (A-11) + (B4-1), (A-11) + (B4 -2), (A-11) + (B4-3), (A-11) + (B4-4), (A-11) + (B4-5), (A-11) + (B4-6 ), (A-11) + (B4-7), (A-11) + (B4-8), (A-11) + (B4-9), (A-11) + (B4-10), (A-11) + (B4-11), (A-11) + (B5-1), (A-11) + (B5-2), (A-11) + (B6-3), (A -11) + (B5-4), (A-11) + (B5-5), (A-11) + (B5-6), (A-11) + (B5-7), (A-11 ) + (B6-1), (A-11) + (B6-2), (A-11) + (B6-3), (A-11) + (B6-4), (A-11) + (B6-5), (A-11) + (B6-6), (A-11) + (B6-7), (A-11) + (B6-8), (A-11) + (B6 -9), (A-11) + (B8-10), (A-11) + (B6-11), (A-11) + (B6-12), (A-11) + (B6-13 )
    (A-11) + (B6-14), (A-11) + (B7-1), (A-11) + (B7-2), (A-11) + (B7-3), (A -11) + (B7-4), (A-11) + (B7-5), (A-11) + (B7-6), (A-11) + (B7-7), (A-11 ) + (B7-8), (A-11) + (B7-9), (A-11) + (B7-10), (A-11) + (B7-11), (A-11) + (B7-12), (A-11) + (B7-13), (A-11) + (B7-14), (A-11) + (B7-15), (A-11) + (B7 -16), (A-11) + (B7-17), (A-11) + (B7-18), (A-11) + (B7-19), (A-11) + (B7-20 ), (A-11) + (B7-21), (A-11) + (B7-22), (A-11) + (B7-23), (A-11) + (B7-24), (A-11) + (B7-25), (A-11) + (B7-26), (A-11) + (B7-27), (A-11) + (B7-28), (A -11) + (B7-29), (A-11) + (B7-30), (A-11) + (B-31), (A-11) + (B7-32), (A-11 ) + (B7-33), (A-11) + (B7-34), (A-11) + (B7-35), (A-11) + (B7-36), (A-11) + (B7-37), (A-11) + (B7-38), (A-11) + (B8-1), (A-11) + (B8-2), (A-11) + (B8 -3), (A-11) + (B9-1), (A-11) + (B9-2), (A-11) + (B9-3), (A-11) + (B9-4 ), (A-11) + (B9-5), (A-11) + (B9-6), (A-11) + (B9-7).
  • (A-12) + (B1-1), (A-12) + (B1-2), (A-12) + (B1-3), (A-12) + (B1-4), (A -12) + (B1-5), (A-12) + (B1-6), (A-12) + (B1-7), (A-12) + (B1-8), (A-12 ) + (B2-1), (A-12) + (B2-2), (A-12) + (B3-1), (A-12) + (B3-2), (A-12) + (B3-3), (A-12) + (B3-4), (A-12) + (B3-5), (A-12) + (B3-6), (A-12) + (B -3-7), (A-12) + (B3-8), (A-12) + (B3-9), (A-12) + (B4-1), (A-12) + (B4 -2), (A-12) + (B4-3), (A-12) + (B4-4), (A-12) + (B4-5), (A-12) + (B4-6 ), (A-12) + (B4-7), (A-12) + (B4-8), (A-12) + (B4-9), (A-12) + (B4-1 0) , (A-12) + (B4-11), (A-12) + (B5-1), (A-12) + (B5-2), (A-12) + (B5-3), ( A-12) + (B5-4), (A-12) + (B5-5), (A-12) + (B5-6), (A-12) + (B5-7), (A- 12) + (B6-1), (A-12) + (B6-2), (A-12) + (B6-3), (A-12) + (B6-4), (A-12) + (B6-5), (A-12) + (B6-6), (A-12) + (B6-7), (A-12) + (B6-8), (A-12) + ( B6-9), (A-12) + (B6-10), (A-12) + (B6-11), (A-12) + (BB-12), (A-12) + (B6- 13)
    (A-12) + (B6-14), (A-12) + (B7-1), (A-12) + (B7-2), (A-12) + (B7-3), (A -12) + (B7-4), (A-12) + (B7-5), (A-12) + (B7-6), (A-12) + (B7-7), (A-12 ) + (B7-8), (A-12) + (B7-9), (A-12) + (B7-10), (A-12) + (B7-11), (A-12) + (B7-12), (A-12) + (B7-13), (A-12) + (B7-14), (A-12) + (B7-15), (A-12) + (B7 -16), (A-12) + (B7-17), (A-12) + (B7-18), (A-12) + (B7-19), (A-12) + (B7-20 ), (A-12) + (B7-21), (A-12) + (B7-22), (A-12) + (B7-23), (A-12) + (B7-24), (A-12) + (B7-25), (A-12) + (B7-26), (A-12) + (B7-27), (A-12) + (B7-28), (A -12) + (B7-29), (A-12) + (B7-30), (A-12) + (B-31), (A-12) + (B7-32), (A-12 ) + (B7-33), (A-12) + (B7-34), (A-12) + (B7-35), (A-12) + (B7-36), (A-12) + (B7-37), (A-12) + (B7-38), (A-12) + (B8-1), (A-12) + (B8-2), (A-12) + (B8 -3), (A-12) + (B9-1), (A-12) + (B9-2), (A-12) + (B9-3), (A-12) + (B9-4 ), (A-12) + (B9-5), (A-12) + (B9-6), (A-12) + (B9-7).
  • (A-13) + (B1-1), (A-13) + (B1-2), (A-13) + (B1-3), (A-13) + (B1-4), (A -13) + (B1-5), (A-13) + (B1-6), (A-13) + (B1-7), (A-13) + (B1-8), (A-13 ) + (B2-1), (A-13) + (B2-2), (A-13) + (B3-1), (A-13) + (B3-2), (A-13) + (B3-3), (A-13) + (B3-4), (A-13) + (B3-5), (A-13) + (B3-6), (A-13) + (B -3-7), (A-13) + (B3-8), (A-13) + (B3-9), (A-13) + (B4-1), (A-13) + (B4 -2), (A-13) + (B4-3), (A-13) + (B4-4), (A-13) + (B4-5), (A-13) + (B4-6 ), (A-13) + (B4-7), (A-13) + (B4-8), (A-13) + (B4-9), (A-13) + (B4-10), (A-13) + (B4-11), (A-13) + (B5-1), (A-13) + (B5-2), (A-13) + (B5-3), (A -13) + (B5-4), (A-13) + (B5-5), (A-13) + (B5-6), (A-13) + (B5-7), (A-13 ) + (B6-1), (A-13) + (B6-2), (A-13) + (B6-3), (A-13) + (B6-4), (A-13) + (B6-5), (A-13) + (B6-6), (A-13) + (B6-7), (A -13) + (B6-8), (A-13) + (B6-9), (A-13) + (B6-10), (A-13) + (B6-11), (A-13 ) + (B6-12), (A-13) + (B6-13),
    (A-13) + (B6-14), (A-13) + (B7-1), (A-13) + (B7-2), (A-13) + (B7-3), (A -13) + (B7-4), (A-13) + (B7-6), (A-13) + (B7-6), (A-13) + (B7-7), (A-13 ) + (B7-8), (A-13) + (B7-9), (A-13) + (B7-10), (A-13) + (B7-11), (A-13) + (B7-12), (A-13) + (B7-13), (A-13) + (B7-14), (A-13) + (B7-15), (A-13) + (B7 -16), (A-13) + (B7-17), (A-13) + (B7-18), (A-13) + (B7-19), (A-13) + (B7-20 ), (A-13) + (B7-21), (A-13) + (B7-22), (A-13) + (B7-23), (A-13) + (B7-24), (A-13) + (B7-25), (A-13) + (B7-26), (A-13) + (B7-27), (A-13) + (B7-28), (A -13) + (B7-29), (A-13) + (B7-30), (A-13) + (B-31), (A-13) + (B7-32), (A-13 ) + (B7-33), (A-13) + (B7-34), (A-13) + (B7-35), (A-13) + (B7-36), (A-13) + (B7-37), (A-13) + (B7-38), (A-13) + (B8-1), (A-13) + (B8-2), (A-13) + (B8 -3), (A-13) + (B9-1), (A-13) + (B9-2), (A-13) + (B9-3), (A-13) + (B9-4 ), (A-13) + (B9-5), (A-13) + (B9-6), (A-13) + (B9-7).
  • (A-14) + (B1-1), (A-14) + (B1-2), (A-14) + (B1-3), (A-14) + (B1-4), (A -14) + (B1-5), (A-14) + (B1-6), (A-14) + (B1-7), (A-14) + (B1-8), (A-14 ) + (B2-1), (A-14) + (B2-2), (A-14) + (B3-1), (A-14) + (B3-2), (A-14) + (B3-3), (A-14) + (B3-4), (A-14) + (B3-5), (A-14) + (B3-6), (A-14) + (B -3-7), (A-14) + (B3-8), (A-14) + (B3-9), (A-14) + (B4-1), (A-14) + (B4 -2), (A-14) + (B4-3), (A-14) + (B4-4), (A-14) + (B4-5), (A-14) + (B4-6 ), (A-14) + (B4-7), (A-14) + (B4-8), (A-14) + (B4-9), (A-14) + (B4-10), (A-14) + (B4-11), (A-14) + (B5-1), (A-14) + (B5-2), (A-14) + (B5-3), (A -14) + (B5-4), (A-14) + (B5-5), (A-14) + (85-6), (A-14) + (B5-7), (A-14 ) + (B6-1), (A-14) + (B6-2), (A-14) + (B6-3), (A-14) + (B6-4), (A-14) + (B6-5), (A-14) + (B6-6), (A-14) + (B6-7), (A-14) + (B6-8), (A-14) + (B6 -9), (A-14) + (B6-10), (A-14) + (B6-11), (A-14) + (B6-12), (A-14) + (B6-13 )
    (A-14) + (B6-14), (A-14) + (B7-1), (A-14) + (B7-2), (A-14) + (B7-3), (A -14) + (B7-4), (A-14) + (B7-5), (A-14) + (B7-6), (A-14) + (B7-7), (A-14 ) + (B7-8), (A-14) + (B7-9), (A-14) + (B7-10), (A-14) + (B7-11), (A-14) + (B7-12), (A-14) + (B7-13), (A-14) + (B7-14), (A-14) + (B7-15), (A-14) + (B7 -16), (A-14) + (B7-17), (A-14) + (B7-18), (A-14) + (B7-19), (A-14) + (B7-20 ), (A-14) + (B7-21), (A-14) + (B7-22), (A-14) + (B7-23), (A-14) + (B7-24), (A-14) + (B7-25), (A -14) + (B7-26), (A-14) + (B7-27), (A-14) + (B7-28), (A-14) + (B7-29), (A-14 ) + (B7-30), (A-14) + (B-31), (A-14) + (B7-32), (A-14) + (B7-33), (A-14) + (B7-34), (A-14) + (B7-35), (A-14) + (B7-36), (A-14) + (B7-37), (A-14) + (B7 -38), (A-14) + (B8-1), (A-14) + (B8-2), (A-14) + (B8-3), (A-14) + (B9-1 ), (A-14) + (B9-2), (A-14) + (B9-3), (A-14) + (B9-4), (A-14) + (B9-5), (A-14) + (B9-6), (A-14) + (B9-7).
  • (A-15) + (B1-1), (A-15) + (B1-2), (A-15) + (B1-3), (A-15) + (B1-4), (A -15) + (B1-5), (A-15) + (B1-6), (A-15) + (B1-7), (A-15) + (B1-8), (A-15 ) + (B2-1), (A-15) + (B2-2), (A-15) + (B3-1), (A-15) + (B3-2), (A-15) + (B3-3), (A-15) + (B3-4), (A-15) + (B3-5), (A-15) + (B3-6), (A-15) + (B -3-7), (A-15) + (B3-8), (A-15) + (B3-9), (A-15) + (B4-1), (A-15) + (B4 -2), (A-15) + (B4-3), (A-15) + (B4-4), (A-15) + (B4-5), (A-15) + (B4-6 ), (A-15) + (B4-7), (A-15) + (B4-8), (A-15) + (B4-9), (A-15) + (B4-10), (A-15) + (B4-11), (A-15) + (B5-1), (A-15) + (B5-2), (A-15) + (B5-3), (A -15) + (B5-4), (A-15) + (B5-5), (A-15) + (B5-6), (A-15) + (B5-7), (A-15 ) + (B6-1), (A-15) + (B6-2), (A-15) + (B6-3), (A-15) + (B6-4), (A-15) + (B6-5), (A-15) + (B6-6), (A-15) + (B6-7), (A-15) + (B6-8), (A-15) + (B6 -9), (A-15) + (B6-10), (A-15) + (B6-11), (A-15) + (B6-12), (A-15) + (B6-13 )
    (A-15) + (B6-14), (A-15) + (B7-1), (A-15) + (B7-2), (A-15) + (B7-3), (A -15) + (B7-4), (A-15) + (B7-6), (A-15) + (B7-6), (A-15) + (B7-7), (A-15 ) + (B7-8), (A-15) + (B7-9), (A-15) + (B7-10), (A-15) + (B7-11), (A-15) + (B7-12), (A-15) + (B7-13), (A-15) + (B7-14), (A-15) + (B7-15), (A-15) + (B7 -16), (A-15) + (B7-17), (A-15) + (B7-18), (A-15) + (B7-19), (A-15) + (B7-20 ), (A-15) + (B7-21), (A-15) + (B7-22), (A-15) + (B7-23), (A-15) + (B7-24), (A-15) + (B7-25), (A-15) + (B7-26), (A-15) + (B7-27), (A-15) + (B7-28), (A -15) + (B7-29), (A-15) + (B7-30), (A-15) + (B-31), (A-15) + (B7-32), (A-15 ) + (B7-33), (A-15) + (B7-34), (A-15) + (B7-35), (A-15) + (B7-36), (A-15) + (B7-37), (A-15) + (B7-38), (A-15) + (B8-1), (A-15) + (B8-2), (A-15) + (B8 -3), (A-15) + (B9-1), (A-15) + (B9-2), (A-15) + (B9-3), (A-15) + (B9-4 ), (A-15) + (B9-5), (A-15) + (B9-6), (A-15) + (B9-7).
  • (A-16) + (B1-1), (A-16) + (B1-2), (A-16) + (B1-3), (A-16) + (B1-4), (A -16) + (B1-5), (A-16) + (B1-6), (A-16) + (B1-7), (A-16) + (B1-8), (A-16 ) + (B2-1), (A-16) + (B2-2), (A-16) + (B3-1), (A-16) + (B3-2), (A-16) + (B3-3), (A-16) + (B3-4), (A-16) + (B3-5), (A-16) + (B3-6), (A-16) + (B -3-7), (A-16) + (B3-8), (A-16) + (B3-9), (A-16) + (B4-1), (A-16) + (B4 -2), (A-16) + (B4-3), (A-16) + (B4-4), (A-16) + (B4-5), (A-16) + (B4-6 ), (A-16) + (B4-7), (A-16) + (B4-8), (A-16) + (B4-9), (A-16) + (B4-10), (A-16) + (B4-11), (A-16) + (B5-1), (A-16) + (B5-2), (A-16) + (B5-3), (A -16) + (B5-4), (A-16) + (B5-5), (A-16) + (B5-6), (A-16) + (B5-7), (A-16 ) + (B6-1), (A-16) + (B6-2), (A-16) + (B6-3), (A-16) + (B6-4), (A-16) + (B6-5), (A-16) + (B6-6), (A-16) + (B6-7), (A-16) + (B6-8), (A-16) + (B6 -9), (A-16) + (B6-10), (A-16) + (B6-11), (A-16) + (B6-12), (A-16) + (86-13 )
    (A-16) + (B6-14), (A-16) + (B7-1), (A-16) + (B7-2), (A-16) + (B7-3), (A -16) + (B7-4), (A-16) + (B7-5), (A-16) + (B7-6), (A-16) + (B7-7), (A-16 ) + (B7-8), (A-16) + (B7-9), (A-16) + (B7-10), (A-16) + (B7-11), (A-1 6) + (B7-12), (A-16) + (B7-13), (A-16) + (B7-14), (A-16) + (B7-15), (A-16) + ( B7-16), (A-16) + (B7-17), (A-16) + (B7-18), (A-16) + (B7-19), (A-16) + (B7- 20), (A-16) + (B7-21), (A-16) + (B7-22), (A-16) + (B7-23), (A-16) + (B7-24) , (A-16) + (B7-25), (A-16) + (B7-26), (A-16) + (B7-27), (A-16) + (B7-28), ( A-16) + (B7-29), (A-16) + (B7-30), (A-16) + (B-31), (A-16) + (B7-32), (A- 16) + (B7-33), (A-16) + (B7-34), (A-16) + (B7-35), (A-16) + (B7-36), (A-16) + (B7-37), (A-16) + (B7-38), (A-16) + (B8-1), (A-16) + (B8-2), (A-16) + ( B8-3), (A-16) + (B9-1), (A-16) + (B9-2), (A-16) + (B9-3), (A-16) + (B9- 4), (A-16) + (B9-5), (A-16) + (B9-6), (A-16) + (B9-7).
  • (A-17) + (B1-1), (A-17) + (B1-2), (A-17) + (B1-3), (A-17) + (B1-4), (A -17) + (B1-5), (A-17) + (B1-6), (A-17) + (B1-7), (A-17) + (B1-8), (A-17 ) + (B2-1), (A-17) + (B2-2), (A-17) + (B3-1), (A-17) + (B3-2), (A-17) + (B3-3), (A-17) + (B3-4), (A-17) + (B3-5), (A-17) + (B3-6), (A-17) + (B -3-7), (A-17) + (B3-8), (A-17) + (B3-9), (A-17) + (B4-1), (A-17) + (B4 -2), (A-17) + (B4-3), (A-17) + (B4-4), (A-17) + (B4-5), (A-17) + (B4-6 ), (A-17) + (B4-7), (A-17) + (B4-8), (A-17) + (B4-9), (A-17) + (B4-10), (A-17) + (B4-11), (A-17) + (B5-1), (A-17) + (B5-2), (A-17) + (B5-3), (A -17) + (B5-4), (A-17) + (B5-5), (A-17) + (B5-6), (A-17) + (B5-7), (A-17 ) + (B6-1), (A-17) + (B6-2), (A-17) + (B6-3), (A-17) + (B6-4), (A-17) + (B6-5), (A-17) + (B6-6), (A-17) + (B6-7), (A -17) + (B6-8), (A-17) + (B6-9), (A-17) + (B6-10), (A-17) + (B6-11), (A-17 ) + (B6-12), (A-17) + (B6-13),
    (A-17) + (B6-14), (A-17) + (B7-1), (A-17) + (B7-2), (A-17) + (B7-3), (A -17) + (B7-4), (A-17) + (B7-5), (A-17) + (B7-6), (A-17) + (B7-7), (A-17 ) + (B7-8), (A-17) + (B7-9), (A-17) + (B7-10). (A-17) + (B7-11), (A-17) + (B7-12), (A-17) + (B7-13), (A-17) + (B7-14), (A -17) + (B7-15), (A-17) + (B7-16), (A-17) + (B7-17), (A-17) + (B7-18), (A-17 ) + (B7-19), (A-17) + (B7-20), (A-17) + (B7-21), (A-17) + (B7-22), (A-17) + (B7-23), (A-17) + (B7-24), (A-17) + (B7-25), (A-17) + (B7-26), (A-17) + (B7 -27), (A-17) + (B7-28), (A-17) + (B7-29), (A-17) + (B7-30), (A-17) + (B-31 ), (A-17) + (B7-32), (A-17) + (B7-33), (A-17) + (B7-34), (A-17) + (B7-35), (A-17) + (B7-36), (A-17) + (B7-37), (A-17) + (B7-38), (A-17) + (B8-1), (A -17) + (B8-2), (A-17) + (B8-3), (A-17) + (B9-1), (A-17) + (B9-2), (A-17 ) + (B9-3), (A-17) + (B9-4), (A-17) + (B9-5), (A-17) + (B9-6), (A-17) + (B9-7).
  • (A-18) + (B1-1), (A-18) + (B1-2), (A-18) + (B1-3), (A-18) + (B1-4), (A -18) + (B1-5), (A-18) + (B1-6), (A-18) + (B1-7), (A-18) + (B1-8), (A-18 ) + (B2-1), (A-18) + (B2-2), (A-18) + (B3-1), (A-18) + (B3-2), (A-18) + (B3-3), (A-18) + (B3-4), (A-18) + (B3-5), (A-18) + (B3-6), (A-18) + (B -3-7), (A-18) + (B3-8), (A-18) + (B3-9), (A-18) + (B4-1), (A-18) + (B4 -2), (A-18) + (B4-3), (A-18) + (B4-4), (A-18) + (B4-5), (A-18) + (B4-6 ), (A-18) + (B4-7), (A-18) + (B4-8), (A-18) + (B4-9), (A-18) + (B4-10), (A-18) + (B4-11), (A-18) + (B5-1), (A-18) + (B5-2), (A-18) + (B5-3), (A -18) + (B5-4), (A-18) + (B5-5), (A-18) + (B5-6), (A-18) + (B5-7), (A-18 ) + (B6-1), (A-18) + (B6-2), (A-18) + (B6-3), (A-18) + (B6-4), (A-18) + (B6-5), (A-18) + (B6-6), (A-18) + (B6-7), (A-18) + (B6-8), (A-18) + (B6 -9), (A-18) + (B6-10), (A-18) + (B6-11), (A-18) + (B6-12), (A-18) + (B6-13 )
    (A-18) + (B6-14), (A-18) + (B7-1), (A-18) + (B7-2), (A-18) + (B7-3), (A -18) + (B7-4), (A-18) + (B7-5), (A-18) + (B7-6), (A-18) + (B7-7), (A-18 ) + (B7-8), (A-18) + (B7-9), (A-18) + (B7-10), (A-18) + (B7-11), (A-18) + (B7-12), (A-18) + (B7-13), (A-18) + (B7-14), (A-18) + (B7-15), (A-18) + (B7 -16), (A-18) + (B7-17), (A-18) + (B7-18), (A-18) + (B7-19), (A-18) + (B7-20 ), (A-18) + (B7-21), (A-18) + (B7-22), (A-18) + (B7-23), (A-18) + (B7-24), (A-18) + (B7-25), (A -18) + (B7-26), (A-18) + (B7-27), (A-18) + (B7-28), (A-18) + (B7-29), (A-18 ) + (B7-30), (A-18) + (B-31), (A-18) + (B7-32), (A-18) + (B7-33), (A-18) + (B7-34), (A-18) + (B7-35), (A-18) + (B7-36), (A-18) + (B7-37), (A-18) + (B7 -38), (A-18) + (B8-1), (A-18) + (B8-2), (A-18) + (B8-3), (A-18) + (B9-1 ), (A-18) + (B9-2), (A-18) + (B9-3), (A-18) + (B9-4), (A-18) + (B9-5), (A-18) + (B9-6), (A-18) + (B9-7).
  • (A-19) + (B1-1), (A-19) + (B1-2), (A-19) + (B1-3), (A-19) + (B1-4), (A -19) + (B1-5), (A-19) + (B1-6), (A-19) + (B1-7), (A-19) + (B1-8), (A-19 ) + (B2-1), (A-19) + (B2-2), (A-19) + (B3-1), (A-19) + (B3-2), (A-19) + (B3-3), (A-19) + (B3-4), (A-19) + (B3-5), (A-19) + (B3-6), (A-19) + (B -3-7), (A-19) + (B3-8), (A-19) + (B3-9), (A-19) + (B4-1), (A-19) + (B4 -2), (A-19) + (B4-3), (A-19) + (B4-4), (A-19) + (B4-5), (A-19) + (B4-6 ), (A-19) + (B4-7), (A-19) + (B4-8), (A-19) + (B4-9), (A-19) + (B4-10), (A-19) + (B4-11), (A-19) + (B5-1), (A-19) + (B5-2), (A-19) + (B5-3), (A -19) + (B5-4), (A-19) + (B5-5), (A-19) + (B5-6), (A-19) + (B5-7), (A-19 ) + (B6-1), (A-19) + (B6-2), (A-19) + (B6-3), (A-19) + (B6-4), (A-19) + (B6-5), (A-19) + (B6-6), (A-19) + (B6-7), (A-19) + (B6-8), (A-19) + (B6 -9), (A-19) + (B6-10), (A-19) + (B6-11), (A-19) + (B6-12), (A-19) + (B6-13 )
    (A-19) + (B6-14), (A-19) + (B7-1), (A-19) + (B7-2), (A-19) + (B7-3), (A -19) + (B7-4), (A-19) + (B7-5), (A-19) + (B7-6), (A-19) + (B7-7), (A-19 ) + (B7-8), (A-19) + (B7-9), (A-19) + (B7-10), (A-19) + (B7-11), (A-19) + (B7-12), (A-19) + (B7-13), (A-19) + (B7-14), (A-19) + (B7-15), (A-19) + (B7 -16), (A-19) + (B7-17), (A-19) + (B7-18), (A-19) + (B7-19), (A-19) + (B7-20 ), (A-19) + (B7-21), (A-19) + (B7-22), (A-19) + (B7-23), (A-19) + (B7-24), (A-19) + (B7-25), (A-19) + (B7-26), (A-19) + (B7-27), (A-19) + (B7-28), (A -19) + (B7-29), (A-19) + (B7-30), (A-19) + (B-31), (A-19) + (B7-32), (A-19 ) + (B7-33), (A-19) + (B7-34), (A-19) + (B7-35), (A-19) + (B7-36), (A-19) + (B7-37), (A-19) + (B7-38), (A-19) + (B8-1), (A-19) + (B8-2), (A-19) + (B8 -3), (A-19) + (B9-1), (A-19) + (B9-2), (A-19) + (B9-3), (A-19) + (B9-4 ), (A-19) + (B9-5), (A-19) + (B9-6), (A-19) + (B9-7).
  • (A-20) + (B1-1), (A-20) + (B1-2), (A-20) + (B1-3), (A-20) + (B1-4), (A -20) + (B1-5), (A-20) + (B1-6), (A-20) + (B1-7), (A-20) + (B1-8), (A-20 ) + (B2-1), (A-20) + (B2-2), (A-20) + (B3-1), (A-20) + (B3-2), (A-20) + (B3-3), (A-20) + (B3-4), (A-20) + (B3-5), (A-20) + (B3-6), (A-20) + (B -3-7), (A-20) + (B3-8), (A-20) + (B3-9), (A-20) + (B4-1), (A-20) + (B4 -2), (A-20) + (B4-3), (A-20) + (B4-4), (A-20) + (B4-5), (A-20) + (B4-6 ), (A-20) + (B4-7), (A-20) + (B4-8), (A-20) + (B4-9), (A-20) + (B4-10), (A-20) + (B4-11), (A-20) + (B5-1), (A-20) + (B5-2), (A-20) + (B5-3), (A -20) + (B5-4), (A-20) + (B5-5), (A-20) + (B5-6), (A-20) + (B5-7), (A-20 ) + (B6-1), (A-20) + (B6-2), (A-20) + (B6-3), (A-20) + (B6-4), (A-20) + (B6-5), (A-20) + (B6-6), (A-20) + (B6-7), (A-20) + (B6-8), (A-20) + (B6 -9), (A-20) + (B6-10), (A-20) + (B6-11), (A-20) + (B6-12), (A-20) + (B6-13 )
    (A-20) + (B6-14), (A-20) + (B7-1), (A-20) + (B7-2), (A-20) + (B7-3), (A -20) + (B7-4), (A-20) + (B7-5), (A-20) + (B7-6), (A-20) + (B7-7), (A-20 ) + (B7-8), (A-20) + (B7-9), (A-20) + (B7-10), (A-20) + (B7-11), (A-20) + (B7-12), (A-20) + (B7-13), (A-20) + (B7-14), (A-20) + (B7-15), (A-20) + (B7 -16), (A-20) + (B7-17), (A-20) + (B7-18), (A-20) + (B7-19), (A-20) + (B7-20 ), (A-20) + (B7-21), (A-20) + (B7-22), (A-20) + (B7-23), (A-20) + (B7-24), (A-20) + (B7-25), (A-20) + (B7-26), (A-20) + (B7-27), (A-20) + (B7-28), (A -20) + (B7-29), (A-20) + (B7-30), (A-20) + (B-31), (A-20) + (B7-32), (A-20 ) + (B7-33), (A-20) + (B7-34), (A-20) + (B7-35), (A-20) + (B7-36), (A-20) + (B7-37), (A-20) + (B7-38), (A-20) + (B8-1), (A-20) + (B8-2), (A-20) + (B8 -3), (A-20) + (B9-1), (A-20) + (B9-2), (A-20) + (B9-3), (A-20) + (B9-4 ), (A-20) + (B9-5), (A-20) + (B9-6), (A-20) + (B9-7).
  • (A-21) + (B1-1), (A-21) + (B1-2), (A-21) + (B1-3), (A-21) + (B1-4), (A -21) + (B1-5), (A-21) + (B1-6), (A-21) + (B1-7), (A-21) + (B1-8), (A-21 ) + (B2-1), (A-21) + (B2-2), (A-21) + (B3-1), (A-21) + (B3-2), (A-21) + (B3-3), (A-21) + (B3-4), (A-21) + (B3-5), (A-21) + (B3-6), (A-21) + (B -3-7), (A-21) + (B3-8), (A-21) + (B3-9), (A-21) + (B4-1), (A-21) + (B4 -2), (A-21) + (B4-3), (A-21) + (B4-4), (A-21) + (B4-5), (A-21) + (B4-6 ), (A-21) + (B4-7), (A-21) + (B4-8), (A-21) + (B4-9), (A-21) + (B4-10), (A-21) + (B4-11), (A-21) + (B5-1), (A-21) + (B5-2), (A-21) + (B5-3), (A -21) + (B5-4), (A-21) + (B5-5), (A-21) + (B5-6), (A-21) + (B5-7), (A-21 ) + (B6-1), (A-21) + (B6-2), (A-21) + (B6-3), (A-21) + (B6-4), (A-21) + (86-5), (A-21) + (B6-6), (A-21) + (B6-7), (A -21) + (B6-8), (A-21) + (B6-9), (A-21) + (B6-10), (A-21) + (B6-11), (A-21 ) + (B6-12), (A-21) + (B6-13),
    (A-21) + (B6-14), (A-21) + (B7-1), (A-21) + (B7-2), (A-21) + (B7-3), (A -21) + (B7-4), (A-21) + (B7-5), (A-21) + (B7-6), (A-21) + (B7-7), (A-21 ) + (B7-8), (A-21) + (B7-9), (A-21) + (B7-10), (A-21) + (B7-11), (A-21) + (B7-12), (A-21) + (B7-13), (A-21) + (B7-14), (A-21) + (B7-15), (A-21) + (B7 -16), (A-21) + (B7-17), (A-21) + (B7-18), (A-21) + (B7-19), (A-21) + (B7-20 ), (A-21) + (B7-21), (A-21) + (B7-22), (A-21) + (B7-23), (A-21) + (B7-24), (A-21) + (B7-25), (A-21) + (B7-26), (A-21) + (B7-27), (A-21) + (B7-28), (A -21) + (B7-29), (A-21) + (B7-30), (A-21) + (B-31), (A-21) + (B7-32), (A-21 ) + (B7-33), (A-21) + (B7-34), (A-21) + (B7-35), (A-21) + (B7-36), (A-21) + (B7-37), (A-21) + (B7-38), (A-21) + (B8-1), (A-21) + (B8-2), (A-21) + (B8 -3), (A-21) + (B9-1), (A-21) + (B9-2), (A-21) + (B9-3), (A-21) + (B9-4 ), (A-21) + (B9-5), (A-21) + (B9-6), (A-21) + (B9-7).
  • (A-22) + (B1-1), (A-22) + (B1-2), (A-22) + (B1-3), (A-22) + (B1-4), (A -22) + (B1-5), (A-22) + (B1-6), (A-22) + (B1-7), (A-22) + (B1-8), (A-22 ) + (B2-1), (A-22) + (B2-2), (A-22) + (B3-1), (A-22) + (B3-2), (A-22) + (B3-3), (A-22) + (B3-4), (A-22) + (B3-5), (A-22) + (B3-6), (A-22) + (B -3-7), (A-22) + (B3-8), (A-22) + (B3-9), (A-22) + (B4-1), (A-22) + (B4 -2), (A-22) + (B4-3), (A-22) + (B4-4), (A-22) + (B4-5), (A-22) + (B4-6 ), (A-22) + (B4-7), (A-22) + (B4-8), (A-22) + (B4-9), (A-22) + (B4-10), (A-22) + (B4-11), (A-22) + (B5-1), (A-22) + (B5-2), (A-22) + (B5-3), (A -22) + (B5-4), (A-22) + (B5-5), (A-22) + (B5-6), (A-22) + (B5-7), (A-22 ) + (B6-1), (A-22) + (B6-2), (A-22) + (B6-3), (A-22) + (B6-4), (A-22) + (B6-5), (A-22) + (B6-6), (A-22) + (B6-7), (A-22) + (B6-8), (A-22) + (B6 -9), (A-22) + (B6-10), (A-22) + (B6-11), (A-22) + (B6-12), (A-22) + (B6-13 )
    (A-22) + (B6-14), (A-22) + (B7-1), (A-22) + (B7-2), (A-22) + (B7-3), (A -22) + (B7-4), (A-22) + (B7-5), (A-22) + (B7-6), (A-22) + (B7-7), (A-22 ) + (B7-8), (A-22) + (B7-9), (A-22) + (B7-10), (A-22) + (B7-11), (A-22) + (B7-12), (A-22) + (B7-13), (A-22) + (B7-14), (A-22) + (B7-15), (A-22) + (B7 -16), (A-22) + (B7-17), (A-22) + (B7-18), (A-22) + (B7-19), (A-22) + (B7-20 ), (A-22) + (B7-21), (A-22) + (B7-22), (A-22) + (B7-23), (A-22) + (B7-24), (A-22) + (B7-25), (A -22) + (B7-26), (A-22) + (B7-27), (A-22) + (B7-28), (A-22) + (B7-29), (A-22 ) + (B7-30), (A-22) + (B-31), (A-22) + (B7-32), (A-22) + (B7-33), (A-22) + (B7-34), (A-22) + (B7-35), (A-22) + (B7-36), (A-22) + (B7-37), (A-22) + (B7 -38), (A-22) + (B8-1), (A-22) + (B8-2), (A-22) + (B8-3), (A-22) + (B9-1 ), (A-22) + (B9-2), (A-22) + (B9-3), (A-22) + (B9-4), (A-22) + (B9-5), (A-22) + (B9-6), (A-22) + (B9-7).
  • (A-23) + (B1-1), (A-23) + (B1-2), (A-23) + (B1-3), (A-23) + (B1-4), (A -23) + (B1-5), (A-23) + (B1-6), (A-23) + (B1-7), (A-23) + (B1-8), (A-23 ) + (B2-1), (A-23) + (B2-2), (A-23) + (B3-1), (A-23) + (B3-2), (A-23) + (B3-3), (A-23) + (B3-4), (A-23) + (B3-5), (A-23) + (B3-6), (A-23) + (B -3-7), (A-23) + (B3-8), (A-23) + (B3-9), (A-23) + (B4-1), (A-23) + (B4 -2), (A-23) + (B4-3), (A-23) + (B4-4), (A-23) + (B4-5), (A-23) + (B4-6 ), (A-23) + (B4-7), (A-23) + (B4-8), (A-23) + (B4-9), (A-23) + (B4-10), (A-23) + (B4-11), (A-23) + (B5-1), (A-23) + (B5-2), (A-23) + (B5-3), (A -23) + (B5-4), (A-23) + (B5-5), (A-23) + (B5-6), (A-23) + (B5-7), (A-23 ) + (B6-1), (A-23) + (B6-2), (A-23) + (B6-3), (A-23) + (B6-4), (A-23) + (B6-5), (A-23) + (B6-6), (A-23) + (B6-7), (A-23) + (B6-8), (A-23) + (B6 -9), (A-23) + (B6-10), (A-23) + (B6-11), (A-23) + (B6-12), (A-23) + (B6-13 )
    (A-23) + (B6-14), (A-23) + (B7-1), (A-23) + (B7-2), (A-23) + (B7-3), (A -23) + (B7-4), (A-23) + (B7-5), (A-23) + (B7-6), (A-23) + (B7-7), (A-23 ) + (B7-8), (A-23) + (B7-9), (A-23) + (B7-10), (A-23) + (B7-11), (A-23) + (B7-12), (A-23) + (B7-13), (A-23) + (B7-14), (A-23) + (B7-15), (A-23) + (B7 -16), (A-23) + (B7-17), (A-23) + (B7-18), (A-23) + (B7-19), (A-23) + (B7-20 ), (A-23) + (B7-21), (A-23) + (B7-22), (A-23) + (B7-23), (A-23) + (B7-24), (A-23) + (B7-25), (A-23) + (B7-26), (A-23) + (B7-27), (A-23) + (B7-28), (A -23) + (B7-29), (A-23) + (B7-30), (A-23) + (B-31), (A-23) + (B7-32), (A-23 ) + (B7-33), (A-23) + (B7-34), (A-23) + (B7-35), (A-23) + (B7-36), (A-23) + (B7-37), (A-23) + (B7-38), (A-23) + (B8-1), (A-23) + (B8-2), (A-23) + (B8 -3), (A-23) + (B9-1), (A-23) + (B9-2), (A-23) + (B9-3), (A-23) + (B9-4 ), (A-23) + (B9-5), (A-23) + (B9-6), (A-23) + (B9-7).
  • (A-24) + (B1-1), (A-24) + (B1-2), (A-24) + (B1-3), (A-24) + (B1-4), (A -24) + (B1-5), (A-24) + (B1-6), (A-24) + (B1-7), (A-24) + (B1-8), (A-24 ) + (B2-1), (A-24) + (B2-2), (A-24) + (B3-1), (A-24) + (B3-2), (A-24) + (B3-3), (A-24) + (B3-4), (A-24) + (B3-5), (A-24) + (B3-6), (A-24) + (B -3-7), (A-24) + (B3-8), (A-24) + (B3-9), (A-24) + (B4-1), (A-24) + (B4 -2), (A-24) + (B4-3), (A-24) + (B4-4), (A-24) + (B4-5), (A-24) + (B4-6 ), (A-24) + (B4-7), (A-24) + (B4-8), (A-24) + (B4-9), (A-24) + (B4-10), (A-24) + (B4-11), (A-24) + (B5-1), (A-24) + (B5-2), (A-24) + (B5-3), (A -24) + (B5-4), (A-24) + (B5-5), (A-24) + (B5-6), (A-24) + (B5-7), (A-24 ) + (B6-1), (A-24) + (B6-2), (A-24) + (B6-3), (A-24) + (B6-4), (A-24) + (B6-5), (A-24) + (B6-6), (A-24) + (B6-7), (A-24) + (B6-8), (A-24) + (B6 -9), (A-24) + (86-10), (A-24) + (B6-11), (A-24) + (B6-12), (A-24) + (B6-13 )
    (A-24) + (B6-14), (A-24) + (B7-1), (A-24) + (B7-2), (A-24) + (B7-3), (A -24) + (B7-4), (A-24) + (B7-5), (A-24) + (B7-6), (A-24) + (B7-7), (A-24 ) + (B7-8), (A-24) + (B7-9), (A-24) + (B7-10), (A-24) + (B7-11), (A-24) + (B7-12), (A-24) + (B7-13), (A-24) + (B7-14), (A-24) + (B7-15), (A-24) + (B7 -16), (A-24) + (B7-17), (A-24) + (B7-18), (A-24) + (B7-19), (A-24) + (B7-20 ), (A-24) + (B7-21), (A-24) + (B7-22), (A-24) + (B7-23), (A-24) + (B7-24), (A-24) + (B7-25), (A-24) + (B7-26), (A-24) + (B7-27), (A-24) + (B7-28), (A -24) + (B7-29), (A-24) + (B7-30), (A-24) + (B-31), (A-24) + (B7-32), (A-24 ) + (B7-33), (A-24) + (B7-34), (A-24) + (B7-35), (A-24) + (B7-36), (A-24) + (B7-37), (A-24) + (B7-38), (A-24) + (B8-1), (A-24) + (B8-2), (A-24) + (B8 -3), (A-24) + (B9-1), (A-24) + (B9-2), (A-24) + (B9-3), (A-24) + (B9-4 ), (A-24) + (B9-5), (A-24) + (B9-6), (A-24) + (B9-7).
  • (A-25) + (B1-1), (A-25) + (B1-2), (A-25) + (B1-3), (A-25) + (B1-4), (A -25) + (B1-5), (A-25) + (B1-6), (A-26) + (B1-7), (A-25) + (B1-8), (A-25 ) + (B2-1), (A-25) + (B2-2), (A-25) + (B3-1), (A-25) + (B3-2), (A-25) + (B3-3), (A-25) + (B3-4), (A-25) + (B3-5), (A-25) + (B3-6), (A-25) + (B -3-7), (A-25) + (B3-8), (A-25) + (B3-9), (A-25) + (B4-1), (A-25) + (B4 -2), (A-25) + (B4-3), (A-25) + (B4-4), (A-25) + (B4-5), (A-25) + (B4-6 ), (A-25) + (B4-7), (A-25) + (B4-8), (A-25) + (B4-9), (A-25) + (B4-10), (A-25) + (B4-11), (A-25) + (B5-1), (A-25) + (B5-2), (A-25) + (B5-3), (A -25) + (B5-4), (A-25) + (B5-5), (A-25) + (B5-6). (A-25) + (B5-7), (A-25) + (B6-1), (A-25) + (B6-2), (A-25) + (B6-3), (A-25) + (B6-4), (A-25) + (B6-5), (A-25) + (B6-6), (A-25) + (B6-7), (A -25) + (B6-8), (A-25) + (B6-9), (A-25) + (B6-10), (A-25) + (B6-11), (A-25 ) + (B6-12), (A-25) + (B6-13),
    (A-25) + (B6-14), (A-25) + (67-1), (A-25) + (B7-2), (A-25) + (B7-3), (A -25) + (B7-4), (A-25) + (B7-5), (A-25) + (B7-6), (A-25) + (B7-7), (A-25 ) + (B7-8), (A-25) + (B7-9), (A-25) + (B7-10), (A-25) + (B7-11), (A-25) + (B7-12), (A-25) + (B7-13), (A-25) + (B7-14), (A-25) + (B7-15), (A-25) + (B7 -16), (A-25) + (B7-17), (A-25) + (B7-18), (A-25) + (B7-19), (A-25) + (B7-20 ), (A-25) + (B7-21), (A-25) + (B7-22), (A-25) + (B7-23), (A-25) + (B7-24), (A-25) + (B7-25), (A-25) + (B7-26), (A-25) + (B7-27), (A-25) + (B7-28), (A -25) + (B7-29), (A-25) + (B7-30), (A-25) + (B-31), (A-25) + (B7-32), (A-25 ) + (B7-33), (A-25) + (B7-34), (A-25) + (B7-35), (A-25) + (B7-36), (A-25) + (B7-37), (A-25) + (B7-38), (A-25) + (B8-1), (A-25) + (B8-2), (A-25) + (B8 -3), (A-25) + (B9-1), (A-25) + (B9-2), (A-25) + (B9-3), (A-25) + (B9-4 ), (A-25) + (B9-5), (A-25) + (B9-6), (A-25) + (B9-7).
  • (A-26) + (B1-1), (A-26) + (B1-2), (A-26) + (B1-3), (A-26) + (B1-4), (A -26) + (B1-5), (A-26) + (B1-6), (A-26) + (B1-7), (A-26) + (B1-8), (A-26 ) + (B2-1), (A-26) + (B2-2), (A-26) + (B3-1), (A-26) + (B3-2), (A-26) + (B3-3), (A-26) + (B3-4), (A-26) + (B3-5), (A-26) + (B3-6), (A-26) + (B -3-7), (A-26) + (B3-8), (A-26) + (B3-9), (A-26) + (B4-1), (A-26) + (B4 -2), (A-26) + (B4-3), (A-26) + (B4-4), (A-26) + (B4-5), (A-26) + (B4-6 ), (A-26) + (B4-7), (A-26) + (B4-8), (A-26) + (B4-9), (A-26) + (B4-10), (A-26) + (B4-11), (A-26) + (B5-1), (A-26) + (B5-2), (A-26) + (B5-3), (A -26) + (B5-4), (A-26) + (B5-5), (A-26) + (B5-6), (A-26) + (B5-7), (A-26 ) + (B6-1), (A-26) + (B6-2), (A-26) + (B6-3), (A-26) + (B6-4), (A-26) + (B6-5), (A-26) + (B6-6), (A-26) + (B6-7), (A-26) + (B6-8), (A-26) + (B6 -9), (A-26) + (B6-10), (A-26) + (B6-11), (A-26) + (B6-12), (A-26) + (B6-13 )
    (A-26) + (B6-14), (A-26) + (B7-1), (A-26) + (B7-2), (A-26) + (B7-3), (A -26) + (B7-4), (A-26) + (B7-5), (A-26) + (B7-6), (A-26) + (B7-7), (A-26 ) + (B7-8), (A-26) + (B7-9), (A-26) + (B7-10), (A-26) + (B7-11), (A-26) + (B7-12), (A-26) + (B7-13), (A-26) + (B7-14), (A-26) + (B7-15), (A-26) + (B7 -16), (A-26) + (B7-17), (A-26) + (B7-18), (A-26) + (B7-19), (A-26) + (B7-20 ), (A-26) + (B7-21), (A-26) + (B7-22), (A-26) + (B7-23), (A-26) + (B7-24), (A-26) + (B7-25), (A -26) + (B7-26), (A-26) + (B7-27), (A-26) + (B7-28), (A-26) + (B7-29), (A-26 ) + (B7-30), (A-26) + (B-31), (A-26) + (B7-32), (A-26) + (B7-33), (A-26) + (B7-34), (A-26) + (B7-35), (A-26) + (B7-36), (A-26) + (B7-37), (A-26) + (B7 -38), (A-26) + (B8-1), (A-26) + (B8-2), (A-26) + (B8-3), (A-26) + (B9-1 ), (A-26) + (B9-2), (A-26) + (B9-3), (A-26) + (B9-4), (A-26) + (B9-5), (A-26) + (B9-6), (A-26) + (B9-7).
  • (A-27) + (B1-1), (A-27) + (B1-2), (A-27) + (B1-3), (A-27) + (B1-4), (A -27) + (B1-5), (A-27) + (B1-6), (A-27) + (B1-7), (A-27) + (B1-8), (A-27 ) + (B2-1), (A-27) + (B2-2), (A-27) + (B3-1), (A-27) + (B3-2), (A-27) + (B3-3), (A-27) + (B3-4), (A-27) + (B3-5), (A-27) + (B3-6), (A-27) + (B -3-7), (A-27) + (B3-8), (A-27) + (B3-9), (A-27) + (B4-1), (A-27) + (B4 -2), (A-27) + (B4-3), (A-27) + (B4-4), (A-27) + (B4-5), (A-27) + (B4-6 ), (A-27) + (B4-7), (A-27) + (B4-8), (A-27) + (B4-9), (A-27) + (B4-10), (A-27) + (B4-11), (A-27) + (B5-1), (A-27) + (B5-2), (A-27) + (B5-3), (A -27) + (B5-4), (A-27) + (B5-5), (A-27) + (B5-6), (A-27) + (B5-7), (A-27 ) + (B6-1), (A-27) + (B6-2), (A-27) + (B6-3), (A-27) + (B6-4), (A-27) + (B6-5), (A-27) + (B6-6), (A-27) + (B6-7), (A-27) + (B6-8), (A-27) + (B6 -9), (A-27) + (B6-10), (A-27) + (B6-11), (A-27) + (B6-12), (A-27) + (B6-13 )
    (A-27) + (B6-14), (A-27) + (B7-1), (A-27) + (B7-2), (A-27) + (B7-3), (A -27) + (B7-4), (A-27) + (B7-5), (A-27) + (B7-6), (A-27) + (B7-7), (A-27 ) + (B7-8), (A-27) + (B7-9), (A-27) + (B7-10), (A-27) + (B7-11), (A-27) + (B7-12), (A-27) + (B7-13), (A-27) + (B7-14), (A-27) + (B7-15), (A-27) + (B7 -16), (A-27) + (B7-17), (A-27) + (B7-18), (A-27) + (B7-19), (A-27) + (B7-20 ), (A-27) + (B7-21), (A-27) + (B7-22), (A-27) + (B7-23), (A-27) + (B7-24), (A-27) + (B7-25), (A-27) + (B7-26), (A-27) + (B7-27), (A-27) + (B7-28), (A -27) + (B7-29), (A-27) + (B7-30), (A-27) + (B-31), (A-27) + (B7-32), (A-27 ) + (B7-33), (A-27) + (B7-34), (A-27) + (B7-35), (A-27) + (B7-36), (A-27) + (B7-37), (A-27) + (B7-38), (A-27) + (B8-1), (A-27) + (B8-2), (A-27) + (B8 -3), (A-27) + (B9-1), (A-27) + (B9-2), (A-27) + (B9-3), (A-27) + (B9-4 ), (A-27) + (B9-5), (A-27) + (B9-6), (A-27) + (B9-7).
  • (A-28) + (B1-1), (A-28) + (B1-2), (A-28) + (B1-3), (A-28) + (B1-4), (A -28) + (B1-5), (A-28) + (B1-6), (A-28) + (B1-7), (A-28) + (B1-8), (A-28 ) + (B2-1), (A-28) + (B2-2), (A-28) + (B3-1), (A-28) + (B3-2), (A-28) + (B3-3), (A-28) + (B3-4), (A-28) + (B3-5), (A-28) + (B3-6), (A-28) + (B -3-7), (A-28) + (B3-8), (A-28) + (B3-9), (A-28) + (B4-1), (A-28) + (B4 -2), (A-28) + (B4-3), (A-28) + (B4-4), (A-28) + (B4-5), (A-28) + (B4-6 ), (A-28) + (B4-7), (A-28) + (B4-8), (A-28) + (B4-9), (A-28) + (B4-10), (A-28) + (B4-11), (A-28) + (B5-1), (A-28) + (B5-2), (A-28) + (B5-3), (A -28) + (B5-4), (A-28) + (B5-5), (A-28) + (B5-6), (A-28) + (B5-7), (A-28 ) + (B6-1), (A-28) + (B6-2), (A-28) + (B6-3), (A-28) + (B6-4), (A-28) + (B6-5), (A-28) + (B6-6), (A-28) + (B6-7), (A-28) + (B6-8), (A-28) + (B6 -9), (A-28) + (B6-10), (A-28) + (B6-11), (A-28) + (B6-12), (A-28) + (B6-13 )
    (A-28) + (B6-14), (A-28) + (B7-1), (A-28) + (B7-2), (A-28) + (B7-3), (A -28) + (B7-4), (A-28) + (B7-5), (A-28) + (B7-6), (A-28) + (B7-7), (A-28 ) + (B7-8), (A-28) + (B7-9), (A-28) + (B7-10), (A-28) + (B7-11), (A-28) + (B7-12), (A-28) + (B7-13), (A-28) + (B7-14), (A-28) + (B7-15), (A-28) + (B7 -16), (A-28) + (B7-17), (A-28) + (B7-18), (A-28) + (B7-19), (A-28) + (B7-20 ), (A-28) + (B7-21), (A-28) + (B7-22), (A-28) + (B7-23), (A-28) + (B7-24), (A-28) + (B7-25), (A-28) + (B7-26), (A-28) + (B7-27), (A-28) + (B7-28), (A -28) + (B7-29), (A-28) + (B7-30), (A-28) + (B-31), (A-28) + (B7-32), (A-28 ) + (B7-33), (A-28) + (B7-34), (A-28) + (B7-35), (A-28) + (B7-36), (A-28) + (B7-37), (A-28) + (B7-38), (A-28) + (B8-1), (A-28) + (B8-2), (A-28) + (B8 -3), (A-28) + (B9-1), (A-28) + (B9-2), (A-28) + (B9-3), (A-28) + (B9-4 ), (A-28) + (B9-5), (A-28) + (B9-6), (A-28) + (B9-7).
  • (A-29) + (B1-1), (A-29) + (B1-2), (A-29) + (B1-3), (A-29) + (B1-4), (A -29) + (B1-5), (A-29) + (B1-6), (A-29) + (B1-7), (A-29) + (B1-8), (A-29 ) + (B2-1), (A-29) + (B2-2), (A-29) + (B3-1), (A-29) + (B3-2), (A-29) + (B3-3), (A-29) + (B3-4), (A-29) + (B3-5), (A-29) + (B3-6), (A-29) + (B -3-7), (A-29) + (B3-8), (A-29) + (B3-9), (A-29) + (B4-1), (A-29) + (B4 -2), (A-29) + (B4-3), (A-29) + (B4-4), (A-29) + (B4-5), (A-29) + (B4-6 ), (A-29) + (B4-7), (A-29) + (B4-8), (A-29) + (B4-9), (A-29) + (B4-10), (A-29) + (B4-11), (A-29) + (B5-1), (A-29) + (B5-2), (A-29) + (B5-3), (A -29) + (B5-4), (A-29) + (B5-5), (A-29) + (B5-6), (A-29) + (B5-7), (A-29 ) + (B6-1), (A-29) + (B6-2), (A-29) + (B6-3), (A-29) + (B6-4), (A-29) + (B6-5), (A-29) + (B6-6), (A-29) + (B6-7), (A -29) + (B6-8), (A-29) + (B6-9), (A-29) + (B6-10), (A-29) + (B6-11), (A-29 ) + (B6-12), (A-29) + (B6-13),
    (A-29) + (B6-14), (A-29) + (B7-1), (A-29) + (B7-2), (A-29) + (B7-3), (A -29) + (B7-4), (A-29) + (B7-5), (A-29) + (B7-6), (A-29) + (B7-7), (A-29 ) + (B7-8), (A-29) + (B7-9), (A-29) + (B7-10), (A-29) + (B7-11), (A-29) + (B7-12), (A-29) + (B7-13), (A-29) + (B7-14), (A-29) + (B7-15), (A-29) + (B7 -16), (A-29) + (B7-17), (A-29) + (B7-18), (A-29) + (B7-19), (A-29) + (B7-20 ), (A-29) + (B7-21), (A-29) + (B7-22), (A-29) + (B7-23), (A-29) + (B7-24), (A-29) + (B7-25), (A-29) + (B7-26), (A-29) + (B7-27), (A-29) + (B7-28), (A -29) + (B7-29), (A-29) + (B7-30), (A-29) + (B-31), (A-29) + (B7-32), (A-29 ) + (B7-33), (A-29) + (B7-34), (A-29) + (B7-35), (A-29) + (B7-36), (A-29) + (B7-37), (A-29) + (B7-38), (A-29) + (B8-1), (A-29) + (B8-2), (A-29) + (B8 -3), (A-29) + (B9-1), (A-29) + (B9-2), (A-29) + (B9-3), (A-29) + (B9-4 ), (A-29) + (B9-5), (A-29) + (B9-6), (A-29) + (B9-7).
  • (A-30) + (B1-1), (A-30) + (B1-2), (A-30) + (B1-3), (A-30) + (B1-4), (A -30) + (B1-5), (A-30) + (B1-6), (A-30) + (B1-7), (A-30) + (B9-8), (A-30 ) + (B2-1), (A-30) + (B2-2), (A-30) + (B3-1), (A-30) + (B3-2), (A-30) + (B3-3), (A-30) + (B3-4), (A-30) + (B3-5), (A-30) + (B3-6), (A-30) + (B -3-7), (A-30) + (B3-8), (A-30) + (B3-9), (A-30) + (B4-1), (A-30) + (B4 -2), (A-30) + (B4-3), (A-30) + (B4-4), (A-30) + (B4-5), (A-30) + (B4-6 ), (A-30) + (B4-7), (A-30) + (B4-8), (A-30) + (B4-9), (A-30) + (B4-10), (A-30) + (B4-11), (A-30) + (B5-1), (A-30) + (B5-2), (A-30) + (B5-3), (A -30) + (B5-4), (A-30) + (B5-5), (A-30) + (B5-6). (A-30) + (B5-7), (A-30) + (B6-1), (A-30) + (B6-2), (A-30) + (B6-3), (A -30) + (B6-4), (A-30) + (B6-5), (A-30) + (B6-6), (A-30) + (B6-7), (A-30 ) + (B6-8), (A-30) + (B6-9), (A-30) + (B6-10), (A-30) + (B6-11), (A-30) + (B6-12), (A-30) + (B6-13),
    (A-30) + (B6-14), (A-30) + (B7-1), (A-30) + (B7-2), (A-30) + (B7-3), (A -30) + (B7-4), (A-30) + (B7-5), (A-30) + (B7-6), (A-30) + (B7-7), (A-30 ) + (B7-8), (A-30) + (B7-9), (A-30) + (B7-10), (A-30) + (B7-11), (A-30) + (B7-12), (A-30) + (B7-13), (A-30) + (B7-14), (A-30) + (B7-15), (A-30) + (B7 -16), (A-30) + (B7-17), (A-30) + (B7-18), (A-30) + (B7-19), (A-30) + (B7-20 ), (A-30) + (B7-21), (A-30) + (B7-22), (A-30) + (B7-23), (A-30) + (B7-24), (A-30) + (B7-25), (A -30) + (B7-26), (A-30) + (B7-27), (A-30) + (B7-28), (A-30) + (B7-29), (A-30 ) + (B7-30), (A-30) + (B-31), (A-30) + (B7-32), (A-30) + (B7-33), (A-30) + (B7-34), (A-30) + (B7-35), (A-30) + (B7-36), (A-30) + (B7-37), (A-30) + (B7 -38), (A-30) + (B8-1), (A-30) + (B8-2), (A-30) + (B8-3), (A-30) + (B9-1 ), (A-30) + (B9-2), (A-30) + (B9-3), (A-30) + (B9-4), (A-30) + (B9-5), (A-30) + (B9-6), (A-30) + (B9-7).
  • (A-31) + (B1-1), (A-31) + (B1-2), (A-31) + (B1-3), (A-31) + (B1-4), (A -31) + (B1-5), (A-31) + (B1-6), (A-31) + (B1-7), (A-31) + (B1-8), (A-31 ) + (B2-1), (A-31) + (B2-2), (A-31) + (B3-1), (A-31) + (B3-2), (A-31) + (B3-3), (A-31) + (B3-4), (A-31) + (B3-5), (A-31) + (B3-6), (A-31) + (B -3-7), (A-31) + (B3-8), (A-31) + (B3-9), (A-31) + (B4-1), (A-31) + (B4 -2), (A-31) + (B4-3), (A-31) + (B4-4), (A-31) + (B4-5), (A-31) + (B4-6 ), (A-31) + (B4-7), (A-31) + (B4-8), (A-31) + (B4-9), (A-31) + (B4-10), (A-31) + (B4-11), (A-31) + (B5-1), (A-31) + (B5-2), (A-31) + (B5-3), (A -31) + (B5-4), (A-31) + (B5-5), (A-31) + (B5-6), (A-31) + (B5-7), (A-31 ) + (B6-1), (A-31) + (B6-2), (A-31) + (B6-3), (A-31) + (B6-4), (A-31) + (B6-5), (A-31) + (B6-6), (A-31) + (B6-7), (A-31) + (B6-8), (A-31) + (B6 -9), (A-31) + (B6-10), (A-31) + (B6-11), (A-31) + (B6-12), (A-31) + (B6-13 )
    (A-31) + (B6-14), (A-31) + (B7-1), (A-31) + (B7-2), (A-31) + (B7-3), (A -31) + (B7-4), (A-31) + (B7-5), (A-31) + (B7-6), (A-31) + (B7-7), (A-31 ) + (B7-8), (A-31) + (B7-9), (A-31) + (B7-10), (A-31) + (B7-11), (A-31) + (B7-12), (A-31) + (B7-13), (A-31) + (B7-14), (A-31) + (B7-15), (A-31) + (B7 -16), (A-31) + (B7-17), (A-31) + (B7-18), (A-31) + (B7-19), (A-31) + (B7-20 ), (A-31) + (B7-21), (A-31) + (B7-22), (A-31) + (B7-23), (A-31) + (B7-24), (A-31) + (B7-25), (A-31) + (B7-26), (A-31) + (B7-27), (A-31) + (B7-28), (A -31) + (87-29), (A-31) + (B7-30), (A-31) + (B-31), (A-31) + (B7-32), (A-31 ) + (B7-33), (A-31) + (B7-34), (A-31) + (B7-35), (A-31) + (B7-36), (A-31) + (B7-37), (A-31) + (B7-38), (A-31) + (B8-1), (A-31) + (B8-2), (A-31) + (B8 -3), (A-31) + (B9-1), (A-31) + (B9-2), (A-31) + (B9-3), (A-31) + (B9-4 ), (A-31) + (B9-5), (A-31) + (B9-6), (A-31) + (B9-7).
  • (A-32) + (B1-1), (A-32) + (B1-2), (A-32) + (B1-3), (A-32) + (B1-4), (A -32) + (B1-5), (A-32) + (B1-6), (A-32) + (B1-7), (A-32) + (B1-8), (A-32 ) + (B2-1), (A-32) + (B2-2), (A-32) + (B3-1), (A-32) + (B3-2), (A-32) + (B3-3), (A-32) + (B3-4), (A-32) + (B3-5), (A-32) + (B3-6), (A-32) + (B -3-7), (A-32) + (B3-8), (A-32) + (B3-9), (A-32) + (B4-1), (A-32) + (B4 -2), (A-32) + (B4-3), (A-32) + (B4-4), (A-32) + (B4-5), (A-32) + (B4-6 ), (A-32) + (B4-7), (A-32) + (B4-8), (A-32) + (B4-9), (A-32) + (B4-10), (A-32) + (B4-11), (A-32) + (B5-1), (A-32) + (B5-2), (A-32) + (B5-3), (A -32) + (B5-4), (A-32) + (B5-5), (A-32) + (B5-6), (A-32) + (B5-7), (A-32 ) + (B6-1), (A-32) + (B6-2), (A-32) + (B6-3), (A-32) + (B6-4), (A-32) + (B6-5), (A-32) + (B6-6), (A-32) + (B6-7), (A-32) + (B6-8), (A-32) + (B6 -9), (A-32) + (B6-10), (A-32) + (B6-11), (A-32) + (B6-12), (A-32) + (B6-13 )
    (A-32) + (B6-14), (A-32) + (B7-1), (A-32) + (B7-2), (A-32) + (B7-3), (A -32) + (B7-4), (A-32) + (B7-5), (A-32) + (B7-6), (A-32) + (B7-7), (A-32 ) + (B7-8), (A-32) + (B7-9), (A-32) + (B7-10), (A-32) + (B7-11), (A-32) + (B7-12), (A-32) + (B7-13), (A-32) + (B7-14), (A-32) + (B7-15), (A-32) + (B7 -16), (A-32) + (B7-17), (A-32) + (B7-18), (A-32) + (B7-19), (A-32) + (B7-20 ), (A-32) + (B7-21), (A-32) + (B7-22), (A-32) + (B7-23), (A-32) + (B7-24), (A-32) + (B7-25), (A-32) + (B7-26), (A-32) + (B7-27), (A-32) + (B7-28), (A -32) + (B7-29), (A-32) + (B7-30), (A-32) + (B-31), (A-32) + (B7-32), (A-32 ) + (B7-33), (A-32) + (B7-34), (A-32) + (B7-35), (A-32) + (B7-36), (A-32) + (B7-37), (A-32) + (B7-38), (A-32) + (B8-1), (A-32) + (B8-2), (A-32) + (B8 -3), (A-32) + (B9-1), (A-32) + (B9-2), (A-32) + (B9-3), (A-32) + (B9-4 ), (A-32) + (B9-5), (A-32) + (B9-6), (A-32) + (B9-7).
  • (A-33) + (B1-1), (A-33) + (B1-2), (A-33) + (B1-3), (A-33) + (B1-4), (A -33) + (B1-5), (A-33) + (B1-6), (A-33) + (B1-7), (A-33) + (B1-8), (A-33 ) + (B2-1), (A-33) + (B2-2), (A-33) + (B3-1), (A-33) + (B3-2), (A-33) + (B3-3), (A-33) + (B3-4), (A-33) + (B3-5), (A-33) + (B3-6), (A-33) + (B -3-7), (A-33) + (B3-8), (A-33) + (B3-9), (A-33) + (B4-1), (A-33) + (B4 -2), (A-33) + (B4-3), (A-33) + (B4-4), (A-33) + (B4-5), (A-33) + (B4-6 ), (A-33) + (B4-7), (A-33) + (B4-8), (A-33) + (B4-9), (A-33) + (B4-10), (A-33) + (B4-11), (A-33) + (B5-1), (A-33) + (B5-2), (A-33) + (B5-3), (A -33) + (B5-4), (A-33) + (B5-5), (A-33) + (B6-8), (A-33) + (B5-7), (A-33 ) + (B6-1), (A-33) + (B6-2), (A-33) + (B6-3), (A-33) + (B6-4), (A-33) + (B6-5), (A-33) + (B6-6), (A-33) + (B6-7), (A -33) + (B6-8), (A-33) + (B6-9), (A-33) + (B6-10), (A-33) + (B6-11), (A-33 ) + (B6-12), (A-33) + (B6-13),
    (A-33) + (B6-14), (A-33) + (B7-1), (A-33) + (B7-2), (A-33) + (B7-3), (A -33) + (B7-4), (A-33) + (B7-5), (A-33) + (B7-6), (A-33) + (B7-7), (A-33 ) + (B7-8), (A-33) + (B7-9), (A-33) + (B7-10), (A-33) + (B7-11), (A-33) + (B7-12), (A-33) + (B7-13), (A-33) + (B7-14), (A-33) + (B7-15), (A-33) + (B7 -16), (A-33) + (B7-17), (A-33) + (B7-18), (A-33) + (B7-19), (A-33) + (B7-20 ), (A-33) + (B7-21), (A-33) + (B7-22), (A-33) + (B7-23), (A-33) + (B7-24), (A-33) + (B7-25), (A-33) + (B7-26), (A-33) + (B7-27), (A-33) + (B7-28), (A -33) + (B7-29), (A-33) + (B7-30), (A-33) + (B-31), (A-33) + (B7-32), (A-33 ) + (B7-33), (A-33) + (B7-34), (A-33) + (B7-35), (A-33) + (B7-36), (A-33) + (B7-37), (A-33) + (B7-38), (A-33) + (B8-1), (A-33) + (B8-2), (A-33) + (B8 -3), (A-33) + (B9-1), (A-33) + (B9-2), (A-33) + (B9-3), (A-33) + (B9-4 ), (A-33) + (B9-5), (A-33) + (B9-6), (A-33) + (B9-7).
  • (A-34) + (B1-1), (A-34) + (B1-2), (A-34) + (B1-3), (A-34) + (B1-4), (A -34) + (B1-5), (A-34) + (B1-8), (A-34) + (B1-7), (A-34) + (B1-8), (A-34 ) + (B2-1), (A-34) + (B2-2), (A-34) + (B3-1), (A-34) + (B3-2), (A-34) + (B3-3), (A-34) + (B3-4), (A-34) + (B3-5), (A-34) + (B3-6), (A-34) + (B -3-7), (A-34) + (B3-8). (A-34) + (B3-9), (A-34) + (B4-1), (A-34) + (B4-2), (A-34) + (B4-3), (A -34) + (B4-4), (A-34) + (B4-5), (A-34) + (B4-6), (A-34) + (B4-7), (A-34 ) + (B4-8), (A-34) + (B4-9), (A-34) + (B4-1 0), (A-34) + (B4-11), (A-34) + (B5-1), (A-34) + (B5-2), (A-34) + (B5-3), (A-34) + (B5-4), (A-34) + ( B5-5), (A-34) + (B5-6), (A-34) + (B5-7), (A-34) + (B6-1), (A-34) + (B6- 2), (A-34) + (B6-3), (A-34) + (B6-4), (A-34) + (B6-5), (A-34) + (B6-6) , (A-34) + (B6-7), (A-34) + (B6-8), (A-34) + (B6-9), (A-34) + (B6-10), ( A-34) + (B6-11), (A-34) + (B6-12), (A-34) + (B6-13),
    (A-34) + (B6-14), (A-34) + (B7-1), (A-34) + (B7-2), (A-34) + (B7-3), (A -34) + (B7-4), (A-34) + (B7-5), (A-34) + (B7-6), (A-34) + (B7-7), (A-34 ) + (B7-8), (A-34) + (B7-9), (A-34) + (B7-10), (A-34) + (B7-11), (A-34) + (B7-12), (A-34) + (B7-13), (A-34) + (B7-14), (A-34) + (B7-15), (A-34) + (B7 -16), (A-34) + (B7-17), (A-34) + (B7-18), (A-34) + (B7-19), (A-34) + (B7-20 ), (A-34) + (B7-21), (A-34) + (B7-22), (A-34) + (B7-23), (A-34) + (B7-24), (A-34) + (B7-25), (A -34) + (B7-26), (A-34) + (B7-27), (A-34) + (B7-28), (A-34) + (B7-29), (A-34 ) + (B7-30), (A-34) + (B-31), (A-34) + (B7-32), (A-34) + (B7-33), (A-34) + (B7-34), (A-34) + (B7-35), (A-34) + (B7-36), (A-34) + (B7-37), (A-34) + (B7 -38), (A-34) + (B8-1), (A-34) + (B8-2), (A-34) + (B8-3), (A-34) + (B9-1 ), (A-34) + (B9-2), (A-34) + (B9-3), (A-34) + (B9-4), (A-34) + (B9-5), (A-34) + (B9-6), (A-34) + (B9-7).
  • (A-35) + (B1-1), (A-35) + (B1-2), (A-35) + (B1-3), (A-35) + (B1-4), (A -35) + (B1-5), (A-35) + (B1-6), (A-35) + (B1-7), (A-35) + (B1-8), (A-35 ) + (B2-1), (A-35) + (B2-2), (A-35) + (B3-1), (A-35) + (B3-2), (A-35) + (B3-3), (A-35) + (B3-4), (A-35) + (B3-5), (A-35) + (B3-6), (A-35) + (B -3-7), (A-35) + (B3-8), (A-35) + (B3-9), (A-35) + (B4-1), (A-35) + (B4 -2), (A-35) + (B4-3), (A-35) + (B4-4), (A-35) + (B4-5), (A-35) + (B4-6 ), (A-35) + (B4-7), (A-35) + (B4-8), (A-35) + (B4-9), (A-35) + (B4-10), (A-35) + (B4-11), (A-35) + (B5-1), (A-35) + (B5-2), (A-35) + (B5-3), (A -35) + (B5-4), (A-35) + (B5-5), (A-35) + (B5-6), (A-35) + (B5-7), (A-35 ) + (B6-1), (A-35) + (B6-2), (A-35) + (B6-3), (A-35) + (B6-4), (A-35) + (B6-5), (A-35) + (B6-6), (A-35) + (B6-7), (A-35) + (B6-8), (A-35) + (B6 -9), (A-35) + (B6-10), (A-35) + (B6-11), (A-35) + (B6-12), (A-35) + (B6-13 )
    (A-35) + (B6-14), (A-35) + (B7-1), (A-35) + (B7-2), (A-35) + (B7-3), (A -35) + (B7-4), (A-35) + (B7-5), (A-35) + (B7-6). (A-35) + (B7-7), (A-35) + (B7-8), (A-35) + (B7-9), (A-35) + (B7-10), (A -35) + (B7-11), (A-35) + (B7-12), (A-35) + (B7-13), (A-35) + (B7-14), (A-35 ) + (B7-15), (A-35) + (B7-16), (A-35) + (B7-17), (A-35) + (B7-18), (A-35) + (B7-19), (A-35) + (B7-20), (A-35) + (B7-21), (A-35) + (B7-22), (A-35) + (B7 -23), (A-35) + (B7-24), (A-35) + (B7-25), (A-35) + (B7-26), (A-35) + (B7-27 ), (A-35) + (B7-28), (A-35) + (B7-29), (A-35) + (B7-30), (A-35) + (B-31), (A-35) + (B7-32), (A-35) + (B7-33), (A-35) + (B7-34), (A-35) + (B7-35), (A -35) + (B7-36), (A-35) + (B7-37), (A-35) + (B7-38), (A-35) + (B8-1), (A-35 ) + (B8-2), (A-35) + (B8-3), (A-35) + (B9-1), (A-35) + (B9-2), (A-35) + (B9-3), (A-35) + (B9-4), (A-35) + (B9-5), (A-35) + (B9-6), (A-35) + (B9 -7).

Weiterhin können die erfindungsgemäßen Kombinationen von Herbiziden verschiedene agrochemische Wirkstoffe beispielsweise aus der Gruppe der Safener, Fungizide, Insektizide, sich strukturell von den Herbiziden (A) und (B) unterscheidenden Herbizide und Pflanzenwachstumsregulatoren oder aus der Gruppe der im Pflanzenschutz üblichen Zusatzstoffe und Formulierungshilfsmittel enthaltenFurthermore, combinations of herbicides according to the invention, various agrochemical active ingredients, for example from the group of safeners, fungicides, insecticides, structurally from the herbicides (A) and (B) different herbicides and plant growth regulators or from the group of customary in plant protection additives and formulation auxiliaries

So kommen als weitere Herbizide beispielsweise folgende von den Herbiziden (A) und (B) sich strukturell unterscheidende Herbizide in Frage, vorzugsweise herbizide Wirkstoffe, die auf einer Inhibition von beispielsweise Acetolactat-Synthase, Acetyl-Coenzym-A-Carboxylase, PS I, PS II, HPPDO, Phytoene-Desaturase, Protoporphyrinogen-Oxidase, Glutamine-Synthetase, Celluloseblosynthese, 5-Erlolpyruvylshikimat-3-phosphat-Synthetase beruhen, wie sie z.B. in Weed Research 26, 441-445 (1986 ), oder " The Pesticide Manual", 13th edition, The British Crop Protection Council, 2003, oder 14. Auflage 2006/2007 , oder in dem entsprechenden " e-Pesticide Manual", Version 4 (2006 ), jeweils herausgegeben vom British Crop Protection Council, (im Folgenden auch kurz "PM"), und dort zitierter Literatur beschrieben sind. Listen von "Common names" sind auch in "The Compendium of Pesticide Common Names" im Internet verfügbar. Die Herbizide sind dabei entweder mit dem "common name" nach der International Organization for Standardization (ISO) oder mit dem chemischen Namen, ggf. zusammen mit einer üblichen Codenummer bezeichnet und umfassen stets sämtliche Anwendungsformen wie Säuren, Salze, Ester und Isomere wie Stereoisomere und optische Isomere. Dabei sind eine und zum Teil auch mehrere Anwendungsformen genannt:
acibenzolar-S-methyl; acifluorfen(-sodium); aclonifen; AD-67; AKH 7088, d.h. [[[1-[5-[2-Chloro-4-(trifluoromethyl)-phenoxy]-2-nitrophenyl]-2-methoxyethylidene]-amino]-oxy]-essigsäure und -essigsäuremethylester; alloxydim(-sodium); ametryn; amicarbazone, amidochlor, aminopyralid; amitrol; Ammoniumpelargonate; AMS, d.h. Ammoniumsulfamat; ancimidol; anilofos, atrazine; aviglycine; azafenidin, aziprotryn; barban; BAS 516 H, d.h. 5-Fluor-2-phenyl-4H-3,1-benzoxazin-4-on; benazolin(-ethyl); bencarbazone; benfluralin; benfuresate; bensulide; bentazone; benzfendizone; benzobicyclon, benzofenap; benzofluor, benzoylprop(-ethyl); benzthiazuron; bilanaphos; bifenox; bispyribac(-sodium) (KIH-2023); borax; bromacil; bromofenoxim; bromoxynil; bromuron; buminafos; busoxinone; butafenacil; butamifos; butenachlor (KH-218); buthidazole; butralin" butroxydim; cafenstrole (CH-900); caloxydim; carfentrazone(-ethyl); catechin; CDAA, d.h. 2-Chlor-N,N-di-2-propenylacetamid; CDEC, d.h. Diethyldithiocarbaminsäure-2-chlorallylester, chlormesulon; chlomethoxyfen; chloramben; chlorazifop-butyl; chlorbromuron; chlorbufam; chlorfenac; chlorfenprop; chlorflurecol(-methyl); chlorflurenol(-methyl); chloridazon; chlormequat(-chloride); chlomitrofen; chlorophthalim (MK-616); chlorotoluron; chloroxuron; chlorthal-dimethyl; chlorthiamid; chlortoluron; cinidon(-methyl und -ethyl); cinmethylin; clefoxydim; clethodim; clodinafop und dessen Esterderivate (z.B. clodinafop-propargyl); clofencet; clomazone; clomeprop; cloprop; cloproxydim; clopyralid; clopyrasulfuron(-methyl); cumyluron (JC 940); cyanamide; cyanazine; cycloxydim; cycluron; cyhalofop und dessen Esterderivate (z.B. Butylester, DEH-112); cyperquat; cyprazine; cyprazole; daimuron; 2,4-D; 2,4-DB; dalapon; daminozide; dazomet; n-decanol; desmetryn; di-allate; dicamba; dichlobenil; dichlormid; dichlorprop(-P)-salze; diclofop und dessen Ester wie diclofop-methyl; diclofop-P(-methyl); diethatyl(-ethyl); difenoxuron; difenzoquat(-metilsulfate); diflufenzopyr(-sodium): dimefuron; dimethametryn; dimethazone; dimethylarsinic acid; dimethipin; dimetrasulfuron; dimexyflam; dinitramine; dinoseb; dinoterb; dipropetryn; diquat-salze; dithiopyr, diuron; DNOC; eglinazine-ethyl, EL 77, d.h. 5-Cyano-1-(1,1-dimethylethyl)-N-methyl-1H-pyrazole-4-carboxamid; endothal; epoprodan; ethalfluralin; ethephon; ethidimuron; ethiozin; ethofumesate; ethoxyfen und dessen Ester (z.B. Ethylester, HN-252); F5231, d.h. N-[2-Chlor-4-fluor-5-[4-(3-fluorpropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1 -yl]-phenyl]-ethansulfonamid; fenchlorazole(-ethyl); fenclorim; fenoprop; fenoxan, fenoxaprop und fenoxaprop-P sowie deren Ester, z.B. fenoxaprop-P-ethyl und fenoxaprop-ethyl; fenoxydim; fentrazamide; fenuron; ferrous sulfate; flamprop(-methyl oder -isopropyl oder -isopropyl-L); flamprop-M(-methyl oder -isopropyl); floazulate (JV-485); fluazifop und fluazifop-P und deren Ester, z.B. fluazifop-butyl und fluazifop-P-butyl; fluazolate; fluchloralin; flufenpyr(-ethyl); flumetralin; flumeturon; flumiclorac(-pentyl); flumioxazin (S-482); flumipropyn; fluometuron; fluorochloridone; fluorodifen; fluoroglycofen(-ethyl); flupoxam (KNW-739); flupropacil (UBIC-4243); flupropanoate; flurenol(-butyl); fluridone; flurochloridone; fluroxypyr(-meptyl); flurprimidol; flurtamone; fluthiacet(-methyl) (KIH-9201); fluthiamide; fluxofenim; fomesafen; forchlorfenuron; fosamine; furyloxyfen; gibberillic acid; glufosinate(-ammonium), glyphosate(-isopropylammonium); halosafen; hatoxyfop und dessen Ester, haloxyfop-P (= R-haloxyfop) und dessen Ester; HC-252; hexazinone; imazamethabenz(-methyl); imazamox; imazapic; imazapyr; imazaquin und Salze wie das Ammoniumsalz; imazethapyr, inabenfide; indanofan; ioxynil; isocarbamid; isopropalin; isoproturon; isouron; isoxaben; isoxachlortole; isoxaflutole; isoxapyrifop; karbutilate; lactofen; lenacil; linuron; Maleinsäurehydrazid (MH); MBTA; MCPA; MCPB; mecoprop(-P); mepiquat(-chloride); mesotrione; metam; metamifop; metamitron; methabenzthiazuron; metham; methazole; methoxyphenone; methylarsonic acid; methyl-cyclopropene; methyldymron; methyllsothiocyanate; methabenzthiazuron; metobenzuron; metobromuron; metoxuron; metribuzin; monalide; monocarbamide dihydrogensulfate; monolinuron; monuron; MT 128, d.h. 6-Chlor-N-(3-chlor-2-propenyl)-6-methyl-N-phenyl-3-pyridanamin; naproanilide; NC 310, d.h. 4-(2,4-dichlorbenzoyl)-1-methyl-5-benzyloxypyrazol; neburon; nipyraclofen; nitralin; nitrofen; nitrophenolate mixture; nitrofluorfen; nonanoic acid; norflurazon; oxabetrinil; oryzalin; oxadiargyl (RP-020630); oxadiazon; oxaziclomefone; oxyfluorfen; paclobutrazol; paraquat(-dichloride); pelargonic acid; pendimethalin; pentachlorophenol; pentoxazone; perfluidone; phenisopham; picloram; pinoxaden; piperophos; piributicarb; pirifenop-butyl; probenazole; procarbazone-(sodium); procyazine; prodiamine; profluralin; profoxydim; prohexadione(-calcium); prohydrojasmon; proglinazine(-ethyl); prometon; prometryn; propaquizafop und dessen Ester; propazine; prosulfalin; prynachlor; pyraclonil; pyraflufen(-ethyl) (ET-751); pyrasulfotole; pyrazolynate; pyrazon; pyrazoxyfen; pyribambenz-isopropyl (ZJ 0702); pyrimbambenz-propyl (ZJ 0273); pyribenzoxim; pyridafol; pyridate; pyriftalid; pyriminobac(-methyl) (KIH-6127); pyrimisulfan (KIH-5996); pyrithiobac(-sodium) (KIH-2031 ); pyroxasulfone (KIH-485); pyroxofop und dessen Ester (z.B. Propargylester); quinclorac; quinmerac; quinoclamine; quinofop und dessen Esterderivate, quizalofop und quizalofop-P und deren Esterderivate z.B. quizalofop-ethyl; quizalofop-P-tefuryl und -ethyl; renriduron; S 275, d.h. 2-[4-Chlor-2-fluor-5-(2-propynyloxy)-phenyl]-4,5,6,7-tetrahydro-2H-indazol; secbumeton; sethoxydim; siduron; simazine; simetryn; sintofen; SN 106279, d.h. 2-[[7-[2-Chlor-4-(trifluor-methyl)-phenoxyl-2-naphthalenyl]-oxy]-propansäure und -methylester; sulcotrione; sulfentrazone (FMC-97285, F-6285); sulfazuron; sulfosate (ICI-A0224); TCA(-sodium); tebutam (GCP-5544); tebuthiuron; tecnacene; tefuryltrione; tembotrione; tepraloxydim; terbacil; terbucarb; terbuchlor, terbumeton; terbuthylazine; terbutryn; TFH 450, d.h, N,N-Diethyl..3-[(2-ethyl-6-methylphenyl)-sulfonyl]-1 H-1,2,4-triazol-1-carboxamid; thiafluamide, thiazafluron; thiazopyr (Mon-13200); thidiazimin (SN-24085); thidiazuron; Ti 35; tiocarbazil; topramezone; tralkoxydim; triaziflam; triazofenamide; triclopyr; tridiphane; trietazine; trifluralin; trimeturon; trinexapac; tsitodef; uniconazole; WL 110547, d.h. 5-Phenoxy-1-[3-(trifluormethyl)-phenyl]-1H-tetrazol; D-489; ET-751; KIH-218; KIH-485; KIH-509; KPP-300; LS 82-556; NC-324; DPX-N8189; SC-0774; DOWCO-535; DK-8910; V-53482; PP-600; MBH-001; SYN-523; IDH-100; SYP-249; HOK-201; IR-6396; MTB-951; NC-620.Thus, as further herbicides, for example, the following of the herbicides (A) and (B) structurally different herbicides in question, preferably herbicidal active ingredients which are based on an inhibition of, for example, acetolactate synthase, acetyl-coenzyme A carboxylase, PS I, PS II, HPPDO, phytoene desaturase, protoporphyrinogen oxidase, glutamine synthetase, cellulose desynthesis, 5-erlolpyruvylshikimate-3-phosphate synthetase are based as in Weed Research 26, 441-445 (1986 ), or " The Pesticide Manual, 13th Edition, The British Crop Protection Council, 2003, or 14th Edition, 2006/2007 , or in the corresponding " e-Pesticide Manual ", version 4 (2006 ), each issued by the British Crop Protection Council (hereinafter also abbreviated to "PM"), and literature cited therein. Lists of common names are also available on The Internet in The Compendium of Pesticide Common Names. The herbicides are either with the "common name" according to the International Organization for Standardization (ISO) or with the chemical name, possibly together with a common code number and always include all forms of application such as acids, salts, esters and isomers such as stereoisomers and optical isomers. One and in part also several application forms are mentioned:
acibenzolar-S-methyl; acifluorfen (-sodium); aclonifen; AD-67; AKH 7088, ie methyl [[[1- [5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrophenyl] -2-methoxyethylidene] amino] oxy] acetic acid and acetic acid; alloxydim (-sodium); ametryn; amicarbazone, amidochlor, aminopyralid; amitrol; Ammoniumpelargonate; AMS, ie ammonium sulfamate; ancimidol; anilofos, atrazine; aviglycine; azafenidin, aziprotryn; barban; BAS 516H, ie 5-fluoro-2-phenyl-4H-3,1-benzoxazin-4-one; benazolin (-ethyl); bencarbazone; benfluralin; benfuresate; bensulide; bentazone; benzfendizone; benzobicyclone, benzofenap; benzofluoro, benzoylprop (-ethyl); benzthiazuron; bilanaphos; bifenox; bispyribac (-sodium) (KIH-2023); borax; bromacil; bromofenoxim; bromoxynil; bromuron; buminafos; busoxinone; butafenacil; butamifos; butenachlor (KH-218); buthidazole; butralin "butroxydim; cafenstrole (CH-900); caloxydim; carfentrazone (-ethyl); catechin; CDAA, ie 2-chloro-N, N-di-2-propenylacetamide; CDEC, ie diethyldithiocarbamic acid 2-chloroallyl ester, chloromesulonloromethoxyfen chloramben; chlorazifop-butyl; chlorbromuron; chlorobufam; chlorfenac; chlorfenprop; chlorflurecol (-methyl); chlorofluorol (-methyl); chloridazon; chloroformate (-chloride); chloromitrope; chlorophthalim (MK-616); chlorotoluron; chloroxuron; dimethylchlorothiamide; chlorotoluron; cinidon (-methyl and -ethyl); cinmethylin; clefoxydim; clethodim; clodinafop and its ester derivatives (eg clodinafop-propargyl); clofencet; clomazone; clomeprop; cloprop; cloproxydim; clopyralid; clopyrasulfuron (-methyl); cumyluron (JC 940); cyanamide; cyanazine; cycloxydim; cycluron; cyhalofop and its ester derivatives (eg butyl ester, DEH-112); cyperquat; cyprazine; cyprazole; daimuron; 2,4-D; 2,4-DB; dalapon; daminozide dazomet; n-decanol; desmetryn; di-allate; dicamba; dichlobenil; dichlormi d; dichlorprop (-P) salts; diclofop and its esters such as diclofop-methyl; diclofop-P (methyl); diethatyl (-ethyl); difenoxuron; difenzoquat (-metilsulfate); diflufenzopyr (-sodium): dimefuron; dimethametryn; dimethazone; dimethylarsinic acid; dimethipin; dimetrasulfuron; dimexyflam; dinitramine; dinoseb; dinoterb; dipropetryn; diquat salts; dithiopyr, diuron; DNOC; eglinazine-ethyl, EL 77, ie 5-cyano-1- (1,1-dimethylethyl) -N-methyl-1H-pyrazole-4-carboxamide; endothal; epoprodan; ethalfluralin; ethephon; Ethidimuron; ethiozin; ethofumesate; ethoxyfen and its esters (eg ethyl ester, HN-252); F5231, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1H-tetrazol-1-yl] -phenyl] -ethanesulfonamide; fenchlorazole (-ethyl); fenclorim; fenoprop; fenoxan, fenoxaprop and fenoxaprop-P and their esters, eg fenoxaprop-P-ethyl and fenoxaprop-ethyl; fenoxydim; fentrazamide; fenuron; ferrous sulfate; flamprop (-methyl or -isopropyl or -isopropyl-L); flamprop-M (-methyl or -isopropyl); floatsulate (JV-485); fluazifop and fluazifop-P and their esters, eg fluazifop-butyl and fluazifop-P-butyl; fluazolate; fluchloralin; flufenpyr (-ethyl); flumetralin; flumeturon; flumiclorac (-pentyl); flumioxazin (S-482); flumipropyn; fluometuron; fluorochloridone; fluorodifen; fluoroglycofen (-ethyl); flupoxam (KNW-739); flupropacil (UBIC-4243); flupropanoate; flurenol (-butyl); fluridone; flurochloridone; fluroxypyr (-meptyl); flurprimidol; flurtamone; fluthiacet (-methyl) (KIH-9201); fluthiamide; fluxofenim; fomesafen; forchlorfenuron; fosamine; furyloxyfen; gibberillic acid; glufosinate (-ammonium), glyphosate (-isopropylammonium); halo safen; hatoxyfop and its esters, haloxyfop-P (= R-haloxyfop) and its esters; HC-252; hexazinone; imazamethabenz (-methyl); imazamox; imazapic; imazapyr; imazaquin and salts such as the ammonium salt; imazethapyr, inabenfide; indanofan; ioxynil; isocarbamid; isopropalin; isoproturon; isouron; isoxaben; isoxachlortole; isoxaflutole; isoxapyrifop; karbutilate; lactofen; lenacil; linuron; Maleic hydrazide (MH); MBTA; MCPA; MCPB; mecoprop (-P); mepiquat (chlorides); mesotrione; metam; metamifop; metamitron; methabenzthiazuron; metham; methazole; methoxyphenone; methylarsonic acid; methyl-cyclopropene; methyldymron; methyllsothiocyanate; methabenzthiazuron; metobenzuron; metobromuron; metoxuron; metribuzin; monalide; monocarbamide dihydrogen sulfates; monolinuron; monuron; MT 128, ie 6-chloro-N- (3-chloro-2-propenyl) -6-methyl-N-phenyl-3-pyridanamine; naproanilide; NC 310, ie 4- (2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazole; neburon; nipyraclofen; nitralin; nitrofen; nitrophenolate mixture; nitrofluorfen; nonanoic acid; norflurazon; oxabetrinil; oryzalin; oxadiargyl (RP-020630); oxadiazon; oxaziclomefone; oxyfluorfen; paclobutrazol; paraquat (dichlorides); pelargonic acid; pendimethalin; pentachlorophenol; pentoxazone; perfluidone; phenisopham; picloram; pinoxaden; piperophos; piributicarb; pirifenop-butyl; probenazole; procarbazone- (sodium); procyazine; prodi amines; profluralin; profoxydim; Prohexadione (-Calcium); prohydrojasmon; proglinazine (-ethyl); prometon; prometryne; propaquizafop and its esters; propazine; prosulfalin; prynachlor; pyraclonil; pyraflufen (-ethyl) (ET-751); pyrasulfotole; pyrazolynate; pyrazon; pyrazoxyfen; pyribambenz isopropyl (ZJ 0702); pyrimbenzopropyl (ZJ 0273); pyribenzoxim; pyridafol; pyridate; pyriftalid; pyriminobac (-methyl) (KIH-6127); pyrimisulfan (KIH-5996); pyrithiobac (-sodium) (KIH-2031); pyroxasulfones (KIH-485); pyroxofop and its esters (eg propargyl esters); quinclorac; quinmerac; quinoclamine; quinofop and its ester derivatives, quizalofop and quizalofop-P and their ester derivatives, eg quizalofop-ethyl; quizalofop-P-tefuryl and -ethyl; renriduron; S 275, ie 2- [4-chloro-2-fluoro-5- (2-propynyloxy) -phenyl] -4,5,6,7-tetrahydro-2H-indazole; secbumeton; sethoxydim; siduron; simazine; simetryn; sintofen; SN 106279, ie 2 - [[7- [2-chloro-4- (trifluoromethyl) phenoxyl-2-naphthalenyl] oxy] -propanoic acid and methyl ester; sulcotrione; sulfentrazone (FMC-97285, F-6285); sulfazuron; sulfosate (ICI-A0224); TCA (-sodium); tebutam (GCP-5544); tebuthiuron; tecnacene; tefuryltrione; tembotrione; tepraloxydim; terbacil; terbucarb; terbuchlor, terbumeton; Terbuthylazine; terbutryn; TFH 450, ie, N, N-diethyl... 3 - [(2-ethyl-6-methylphenyl) sulfonyl] -1 H-1,2,4-triazole-1-carboxamide; thiafluamide, thiazafluron; thiazopyr (Mon-13200); thidiazimin (SN-24085); thidiazuron; Ti 35; tiocarbazil; topramezone; tralkoxydim; triaziflam; triazofenamide; triclopyr; tridiphane; trietazine; trifluralin; trimeturon; trinexapac; tsitodef; Uniconazole; WL 110547, ie 5-phenoxy-1- [3- (trifluoromethyl) -phenyl] -1H-tetrazole; D-489; ET-751; KIH-218; KIH-485; KIH-509; KPP-300; LS 82-556; NC-324; DPX-N8189; SC-0774; Dowco-535; DK-8910; V-53482; PP-600; MBH-001; SYN-523; IDH-100; SYP-249; HOK-201; IR 6396; MTB-951; NC 620th

Von besonderem Interesse ist die selektive Bekämpfung von Schadpflanzen in Kulturen von Nutz- und Zierpflanzen. Obgleich die Herbizide (A) und (B), bereits in vielen Kulturen sehr gute bis ausreichende Selektivität aufweisen, können prinzipiell in einigen Kulturen und vor allem auch im Falle von Mischungen mit anderen Herbiziden, die weniger selektiv sind, Phytotoxizitäten an den Kulturpflanzen auftreten. Diesbezüglich sind Kombinationen von Herbiziden (A) und (B) von besonderem Interesse, welche die erfindungsgemäß kombinierten herbiziden Wirkstoffe und einen oder mehrere Safener enthalten. Die Safener, welche in einem antidotisch wirksamen Gehalt eingesetzt werden, reduzieren die phytotoxischen Nebenwirkungen der eingesetzten Herbizide/Pestizide, z. B. in wirtschaftlich bedeutenden Kulturen wie Getreide (Weizen, Gerste, Roggen, Mais, Reis, Hirse), Zuckerrübe, Zuckerrohr, Raps, Baumwolle und Soja, vorzugsweise Getreide.Of particular interest is the selective control of harmful plants in crops of commercial and ornamental plants. Although the herbicides (A) and (B) already have very good to sufficient selectivity in many cultures, phytotoxicities on the crop plants can in principle occur in some crops and, above all, in the case of mixtures with other herbicides which are less selective. In this regard, of particular interest are combinations of herbicides (A) and (B) which contain the herbicidally combined active ingredients and one or more safeners according to the invention. The safeners, which are used in an antidote effective content, reduce the phytotoxic side effects of the herbicides / pesticides used, eg. B. in economically important crops such as cereals (wheat, barley, rye, corn, rice, millet), sugar beet, sugar cane, rapeseed, cotton and soybeans, preferably cereals.

Die Safener sind vorzugsweise ausgewählt aus der Gruppe bestehend aus:

  • A) Verbindungen der Formel (S-I),
    Figure imgb0003
     wobei die Symbole und Indizes folgende Bedeutungen haben:
    nA
    ist eine natürliche Zahl von 0 bis 5, vorzugsweise 0 bis 3;
    RA 1
    ist Halogen, (C1-C4)-Alkyl, (C1-C4)-Alkoxy, Nitro oder (C1-C4)-Haloalkyl;
    WA
    ist ein unsubstituierter oder substituierter divalenter heterocyclischer Rest aus der Gruppe der teilungesättigten oder aromatischen Fünfring-Heterocyclen mit 1 bis 3 Heteroringatomen des Typs N oder O, wobei mindestens ein N-Atom und höchstens ein O-Atom im Ring enthalten ist, vorzugsweise ein Rest aus der Gruppe (WA 1) bis (WA 4),
    Figure imgb0004
    mA
    ist 0 oder 1;
    RA 2
    ist ORA 3, SRA 3 oder NRA 3RA 4 oder ein gesättigter oder ungesättigter 3- bis 7-gliedriger Heterocyclus mit mindestens einem N-Atom und bis zu 3 Heteroatomen, vorzugsweise aus der Gruppe O und S, der über das N-Atom mit der Carbonylgruppe in (S-I) verbunden ist und unsubstituiert oder durch Reste aus der Gruppe (C1-C4)-Alkyl, (C1-C4)-Alkoxy oder gegebenenfalls substituiertes Phenyl substituiert ist, vorzugsweise ein Rest der Formel ORA 3, NHRA 4 oder N(CH3)2, insbesondere der Formel ORA 3;
    RA 3
    ist Wasserstoff oder ein unsubstituierter oder substituierter aliphatischer Kohlenwasserstoffrest, vorzugsweise mit insgesamt 1 bis 18 C-Atomen;
    RA 4
    ist Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Alkoxy oder substituiertes oder unsubstituiertes Phenyl;
    RA 5
    ist H, (C1-C8)-Alkyl, C1-C8(Haloalkyl), (C1-C4)-Alkoxy(C1-C8)-Alkyl, Cyano oder COORA 9, worin RA 9 Wasserstoff, (C1-C8)-Alkyl, (C1-C8)-Haloalkyl, (C1-C4)-Alkoxy-(C1-C4)-alkyl, (C1-C6)-Hydroxyalkyl, (C3-C12)-Cycloalkyl oder Tri-(C1- C4)-alkyl-silyl ist;
    RA 6, RA 7, RA 8
    sind gleich oder verschieden Wasserstoff, (C1-C8)-Alklyl, (C1-C8)-Haloalkyl, (C3-C12)-Cycloalkyl oder substituiertes oder unsubstituiertes Phenyl;
    vorzugsweise:
    1. a) Verbindungen vom Typ der Dichlorphenylpyrazolin-3-carbonsäure, vorzugsweise Verbindungen wie
      1-(2,4-Dichlorphenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3-carbonsäure-ethylester (S1-1) ("Mefenpyr-diethyl", siehe Pestic. Man.), und verwandte Verbindungen, wie sie in der WO 91/07874 beschrieben sind;
    2. b) Derivate der Dichlorphenylpyrazolcarbonsäure, vorzugsweise Verbindungen wie 1-(2,4-Dichlorphenyl)-5-methyl-pyrazol-3-carbonsäureethylester (S1-2), 1-(2,4-Dichlorphenyl)-5-isopropyl-pyrazol-3-carbonsäureethylester (S1-3), 1-(2,4-Dichiorphenyl)-5-(1,1-dimethyl-ethyl)pyrazol-3-carbonsäureethyl-ester (S1-4), 1-(2,4-Dichlorphenyl)-5-phenyl-pyrazol-3-carbonsäureethylester (S1-5) und verwandte Verbindungen, wie sie in EP-A-333131 und EP-A-269 806 beschrieben sind;
    3. c) Verbindungen vom Typ der Triazolcarbonsäuren, vorzugsweise Verbindungen wie Fenchlorazol(-ethylester), d.h. 1-(2,4-Dichlorphenyl)-5-trichlormethyl-(1H)-1,2,4-triazol-3-carbonsäureethylester (S1-6), und verwandte Verbindungen wie sie in EP-A-174 562 und EP-A-346 620 beschrieben sind;
    4. d) Verbindungen vom Typ der 5-Benzyl- oder 5-Phenyl-2-isoxazolin-3- carbonsäure, oder der 5,5-Diphenyl-2-isoxazolin-3-carbonsäure vorzugsweise Verbindungen wie 5-(2,4-Dichlorbenzyl)-2-isoxazolin-3-carbonsäureethylester (S1-7) oder 5-Phenyl-2-isoxazolin-3-carbonsäureethylester (S1-8) und verwandte Verbindungen, wie sie in WO 91/08202 beschrieben sind, bzw. der 5,5-Diphenyl-2-isoxazolin-carbonsäureethylester (S1-9) ("Isoxadifen-ethyl") oder -n-propylester (S1-10) oder der 5-(4-Fluorphenyl)-5-phenyl-2-Isoxazolin-3-carbonsäureethylester (S1-11), wie sie in der Patentanmeldung WO-A-95/07897 beschrieben sind.
  • B) Chinolinderivate der Formel (S-II),
    Figure imgb0005
     wobei die Symbole und Indizes folgende Bedeutungen haben:
    RB 1
    Halogen, (C1-C4)-Alkyl, (C1-C4)-Alkoxy, Nitro oder (C1-C4)-Haloalkyl;
    nB
    ist eine natürliche Zahl von 0 bis 5, vorzugsweise 0 bis 3;
    RB 2
    ORB 3, SRB 3 oder NRB 3RB 4 oder ein gesättigter
    oder ungesättigter 3- bis 7-gliedriger Heterocyclus mit mindestens einem N-Atom und bis zu 3 Heteroatomen, vorzugsweise aus der Gruppe O und S, der über das N-Atom mit der Carbonylgruppe in (S-II) verbunden ist und unsubstituiert oder durch Reste aus der Gruppe (C1-C4)-Alkyl, (C1-C4)-Alkoxy oder gegebenenfalls substituiertes Phenyl substituiert ist, vorzugsweise ein Rest der Formel ORB 3, NHRB 4 oder N(CH3)2, insbesondere der Formel ORB 3;
    RB 3
    ist Wasserstoff oder ein unsubstituierter oder substituierter aliphatischer Kohlenwasserstoffrest, vorzugsweise mit insgesamt 1 bis 18 C-Atomen;
    RB 4
    ist Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Alkoxy oder substituiertes oder unsubstituiertes Phenyl;
    TB
    ist eine (C1 oder C2)-Alkandiylkette, die unsubstituiert oder mit einem oder zwei (C1-C4)-Alkylresten oder mit [(C1-C3)-Alkoxy]-carbonyl substituiert ist;
    vorzugsweise:
    1. a) Verbindungen vom Typ der 8-Chinolinoxyessigsäure (S2), vorzugsweise (5-Chlor-8-chinolinoxy)essigsäure-(1-methylhexyl)-ester (Common name "Cloquintocet-mexyl" (S2-1) (siehe Pestic. Man.), (5-Chlor-8-chinolinoxy)essigsäure-(1,3-dimethyl-but-1-yl)-ester (S2-2), (5-Chlor-8-chinolinoxy)essigsäure-4-allyl-oxy-butylester (S2-3), (5-Chlor-8-chinolinoxy)essigsäure-1-allyloxy-prop-2-ylester (S2-4), (5-Chlor-8-chinolinoxy)essigsäureethylester (S2-5), (5-Chlor-8-chinolinoxy)essigsäuremethylester (S2-6), (5-Chlor-8-chinolinoxy)essigsäureallylester (S2-7), (5-Chlor-8-chinolinoxy)essigsäure-2-(2-propyliden-Iminoxy)-1-ethylester (S2-8), (5-Chlor-8-chinolinoxy)essigsäure-2-oxo-prop-1-ylester (S2-9) und verwandte Verbindungen, wie sie in EP-A-86 750 , EP-A-94 349 und EP-A-191 736 oder EP-A-0 492 366 beschrieben sind, sowie deren Hydrate und Salze wie sie in der WO-A-2002/034048 beschrieben sind.
    2. b) Verbindungen vom Typ der (5-Chlor-8-chinolinoxy)malonsäure, vorzugsweise Verbindungen wie (5-Chlor-8-chinolinoxy)malonsäurediethylester, (5-Chlor-8-chinolinoxy)malonsäurediallylester, (5-Chlor-8-chinolinoxy)malonsäure-methyl-ethylester und verwandte Verbindungen, wie sie in EP-A-0 582198 beschrieben sind.
  • C) Verbindungen der Formel (S-III)
    Figure imgb0006
     wobei die Symbole und Indizes folgende Bedeutungen haben:
    • RC 1 ist (C1-C4)-Alkyl, (C1-C4)-Haloalkyl, (C2-C4)-Alkenyl, (C2-C4)-Haloalkenyl, (C3-C7)-Cycloalkyl, vorzugsweise Dichlormethyl;
    • RC 2, RC 3 ist gleich oder verschieden Wasserstoff, (C1-C4)-Alkyl, (C2-C4)-Alkenyl, (C2-C4)-Alkinyl, (C1-C4)-Haloalkyl, (C2-C4)-Haloalkenyl, (C1-C4)-Alkylcarbamoyl-(C1-C4)-alkyl, (C2-C4)-Alkenylcarbamoyl-(C1-C4)-alkyl, (C1-C4)-Alkoxy-(C1-C4)-alkyl, Dioxolanyl-(C1-C4)-alkyl, Thiazolyl, Furyl, Furylalkyl, Thienyl, Piperidyl, substituiertes oder unsubstituiertes Phenyl, oder RC 2 und RC 3 bilden zusammen einen substituierten oder unsubstituierten heterocyclischen Ring, vorzugsweise einen Oxazolidin-, Thiazolidin-, Piperidin-, Morpholin-, Hexahydropyrimidin- oder Benzoxazinring;
    vorzugsweise:
    • Wirkstoffe vom Typ der Dichloracetamide, die häufig als Vorauflaufsafener (bodenwirksame Safener) angewendet werden, wie z. B.
    • "Dichlormid" (siehe Pestic.Man.) (= N,N-Diallyl-2,2-dichloracetamid), "R-29148" (= 3-Dichloracetyl-2,2,5-trimethyl-1,3-oxazolidin von der Firma Stauffer), "R-28725" (= 3-Dichloracetyl-2,2,-dimethyl-1,3-oxazolidin von der Firma Stauffer), "Benoxacor" (siehe Pestic. Man.) (=4-Dichloracetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazin),
    • "PPG-1292" (= N-Allyl-N-[(1,3-dioxolan-2-yl)-methyl]-dichloracetamid von der Firma PPG Industries),
    • "DKA-24" (= N-Allyl-N-[(allylaminocarbonyl)-methyl]-dichloracetamid von der Firma Sagro-Chem),
    • "AD-67" oder "MON 4660" (= 3-Dichloracetyl-1-oxa-3-aza-spiro[4,5]decan von der Firma Nitrokemia bzw. Monsanto),
    • "TI-35" (= 1-Dichloracotyl-azepan von der Firma TRI-Chemical RT) "Diclonon" (Dicyclonon) oder "BAS145138" oder "LAB145138" (= 3-Dichloracetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0]nonan von der Firma BASF) und
    • "Furilazol" oder "MON 13900" (siehe Pestic. Man.) (= (RS)-3-Dichloracetyl-5-(2-furyl)-2,2-dimethyloxazolidin)
  • D) N-Acylsulfonamide der Formel (S-IV) und ihre Salze,
    Figure imgb0007
     worin
    XD
    ist CH oder N;
    RD 1
    ist CO-NRD 5RD 6 oder NHCO-RD 7;
    RD 2
    ist Halogen, (C1-C4)-Haloalkyl, (C1-C4)-Haloalkoxy, Nitro, (C1-C4)-Alkyl, (C1-C4)-Alkoxy, (C1-C4)-Alkylsulfonyl, (C1-C4)-Alkoxycarbonyl oder (C1-C4)-Alkytcarbonyl;
    RD 3
    ist Wasserstoff, (C1-C4)-Alkyl, (C2-C4)-Alkenyl oder (C2-C4)-Alkinyl;
    RD 4
    ist Halogen, Nitro, (C1-C4)-Alkyl, (C1-C4)-Haloalkyl, (C1-C4)-Haloalkoxy, (C3-C6)-Cycloalkyl, Phenyl, (C1-C4)-Alkoxy, Cyano, (C1-C4)-Alkylthlo, (C1-C4)-Alkylsulfinyl, (C1-C4)-Alkylsulfonyl, (C1-C4)-Alkoxycarbonyl oder (C1-C4)-Alkylcarbonyl; RD 5 ist Wasserstoff, (C1-C6)-Alkyl, (C3-C6)-Cycloalkyl, (C2-C6)-Alkenyl, (C2-C6)-Alkinyl, (C5-C6)-Cycloalkenyl, Phenyl oder 3- bis 6-gliedriges Heterocyclyl enthaltend vD Heteroatome aus der Gruppe Stickstoff, Sauerstoff und Schwefel, wobei die sieben letztgenannten Reste durch vD Substituenten aus der Gruppe Halogen, (C1-C6)-Alkoy, (C1-C6)-Haloalkoxy, (C1-C2)-Alkylsulfinyl, (C1-C2)-Alkylsulionyl, (C3-C6)-Cycloalkyl, (C1-C4)-Alkoxycarbonyl, (C1-C4)-Alkylcarbonyl und Phenyl und im Falle cyclischer Reste auch (C1-C4)-Alkyl und (C1-C4)-Haloalkyl substituiert sind;
    RD 6
    ist Wasserstoff, (C1-C6)-Alkyl, (C2-C6)-Alkenyl oder (C2-C6)-Alking wobei die drei letztgenannten Reste durch vD Reste aus der Gruppe Halogen, Hydroxy, (C1-C4)-Alkyl, (C1-C4)-Alkoxy und (C1-C4)-Alkylthio substituiert sind, oder
    RD 5 und RD 6
    bilden gemeinsam mit dem dem sie tragenden Stickstoffatom einen Pyrrolidinyl- oder Piperidinyl-Rest;
    RD 7
    ist Wasserstoff, (C1-C4)-Alkylamino, Di-(C1-C4)-alkylamino, (C1-C6)-Alkyl, (C3-C6)-Cycloalkyl, wobei die 2 letztgenannten Reste durch vD Substituenten aus der Gruppe Halogen, (C1-C4)-Alkoxy, Halogen-(C1-C6)-alkoxy und (C1-C4)-Alkylthlo und im Falle cyclischer Reste auch (C1-C4)-Alkyl und (C1-C4)-Haloalkyl substituiert sind;
    nD
    ist 0, 1 oder 2;
    mD
    ist 1 oder 2;
    vD
    ist 0, 1, 2 oder 3;
    davon bevorzugt sind Verbindungen von Typ der N-Acylsulfonamide, z.B. der nachfolgenden Formel (S-V), die z. B. bekannt sind aus WO 97/45016
    Figure imgb0008
     worin
    RD 7
    (C1-C6)Alkyl, (C3-C6)Cycloalkyl, wobei die 2 letztgenannten Reste durch vD Substituenten aus der Gruppe Halogen, (C1-C4)Alkoxy, Halogen-(C1-C6)alkoxy und (C1-C4)Alkytthio und im Falle cyclischer Reste auch (C1-C4)Alkyl und (C1-C4)Haloalkyl substituiert sind;
    RD 4
    Halogen, (C1-C4)-Alkyl. (C1-C4)-Alkoxy, CF3;
    mD
    1 oder 2 bedeutet;
    vD
    ist 0, 1, 2 oder 3;
    sowie
    Acylsulfamoylbenzoesäureamide, z.B. der nachfolgenden Formel (S-VI), die z.B. bekannt sind aus WO 99/16744 .
    Figure imgb0009
     z.B. solche worin
    • RD 5 = Cyclo-Propyl und (RD 4) = 2-OMe ist ("Cyprosulfamide", S3-1),
    • RD 5 = Cyclo-Propyl und (RD 4) = 5-Cl-2-OMe ist (S3-2),
    • RD5 = Ethyl und (RD 4) = 2-OMe ist (S3-3),
    • RD 5 = iso-Propyl und (RD 4) = 5-Cl-2-OMe ist (S3-4) und
    • RD 5 = iso-Propyl und (RD 4) = 2-OMe ist (S3-5);
    sowie
    Verbindungen vom Typ der N-Acylsulfamoylphenylhamstoffe der Formel (S-VII), die z.B. bekannt sind aus der EP-A-365484 ,
    Figure imgb0010
     worin
    RD 8 und RD 9
    unabhängig voneinander Wasserstoff, (C1-C8)-Alkyl, (C3-C8)-Cycloalkyl, (C3-C6)-Alkenyl, (C3-C6)-Alkinyl,
    RD 4
    Halogen, (C1-C4)-Alkyl, (C1-C4)-Alkoxy, CF3
    mD
    1 oder 2 bedeutet;
    davon insbesondere
    • 1-[4-(N-2-Methoxybenzoylsulfamoyl)phenyl]-3-meth-lharnstoff,
    • 1-[4-(N-2-Methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylhamstoff,
    • 1-[4-(N-4,5-Dimethylbenzoylsulfamoyl)phenyl]-3-methylhamstoff,
    • 1-[4-(N-Naphthoylsulfamoyl)phenyl]-3,3-dimethylhamstoff,
  • G) Wirkstoffe aus der Klasse der Hydroxyaromaten und der aromatischaliphatischen Carbonsäurederivate, z.B.
    3,4,5-Triacetoxybenzoesäureethylester, 3,5-Dimethoxy-4-hydroxybenzoesäure, 3,5-Dihydroxybenzoesäure, 4-Hydroxysalicylsäure, 4-Fluorsalicycisäure, 1,2-Dihydro-2-oxo-6-trifluoromethylpyridin-3-carboxamid, 2-Hydroxyzimtsäure, 2,4-Dichlorzimtsäure, wie sie in der WO 2004084631 , WO 2005015994 , WO 2006007981 , WO 2005016001 beschrieben sind;
  • H) Wirkstoffe aus der Klasse der 1,2-Dihydrochinoxalin-2-one, z.B.
    1-Methyl-3-(2-thienyl)-1,2-dihydrochinoxalin-2-on, 1-Methyl-3-(2-thienyl)-1,2-dihydrochinoxalin-2-thion, 1-(2-Aminoethyl)-3-(2-thienyl)-1,2-dihydro-chinoxalin-2-on-hydrochlorid, 1-(2-Methylsuffonylaminoethyl)-3-(2-thienyl)-1,2-dihydro-chinoxalin-2-on, wie sie in der WO 2005112630 beschrieben sind,
  • I) Wirkstoffe, die neben einer herbiziden Wirkung gegen Schadpflanzen auch Safenerwirkung an Kulturpflanzen wie Reis aufweisen, wie z. B.
    "Dimepiperate" oder "MY-93" (siehe Pestic. Man.) (= Piperidin-1-thiocarbonsäure-S-1-methyl-1-phenylethylester), das als Safener für Reis gegen Schäden des Herbizids Molinate bekannt ist,
    "Daimuron" oder "SK 23" (siehe Pestic. Man.) (= 1-(1-Methyl-1-phenylethyl)-3-p-tolylharnstoff), das als Safener für Reis gegen Schäden des Herbizids Imazosulfuron bekannt ist,
    "Cumyluron" = "JC-940" (= 3-(2-Chlorphenylmethyl)-(1-methyl-1-phenylethyl)hamstoff, siehe JP-A-60087254 ), das als Safener für Reis gegen Schäden einiger Herbizide bekannt ist,
    "Methoxyphenon" oder "NK 049" (= 3.3'-Dimethy)-4-methoxy-benzophenon), das als Safener für Reis gegen Schäden einiger Herbizide bekannt ist,
    "CSB" (= 1-Brom-4-(chlormethylsulfonyl)benzol) (CAS-Reg. Nr. 54091-06-4 von Kumiai), das als Safener gegen Schäden einiger Herbizide in Reis bekannt ist,
  • K) Verbindungen der Formel (S-IX),
    wie sie in der WO-A-1998/38856 beschrieben sind
    Figure imgb0011
     worin die Symbole und Indizes folgende Bedeutungen haben:
    RK 1, RK 2
    unabhängig voneinander Halogen, (C1-C4)-Alkyl, (C1-C4)-Alkoxy, (C1-C4)-Haloalkyl, (C1-C4)Alkylamino, Di-(C1-C4)-Alkylamino, Nitro;
    AK
    COORK 3 oder COORK 4
    Rk 3, FK4
    unabhängig voneinander Wasserstoff, (C1-C4)-Alkyl, (C2-C6)-Alkenyl, (C2-C4)-Alkinyl, Cyanoalkyl, (C1-C4)-Haloalkyl, Phenyl, Nitrophenyl, Benzyl, Halobenzyl, Pyridinylalkyl und Alkylammonium,
    nK
    0 oder 1
    nK 2, nK 3
    unabhängig voneinander 0, 1 oder 2
    vorzugsweise: Methyl-(diphenylmethoxy)acetat (CAS-Regno: 41858-19-9),
  • L) Verbindungen der Formel (S-X),
    wie sie in der WO A-98/27049 beschrieben sind
    Figure imgb0012
     worin die Symbole und Indizes folgende Bedeutungen haben:
    XL
    CH oder N,
    nL
    für den Fall, dass X=N ist, eine ganze Zahl von 0 bis 4 und für den Fall, dass X=CH ist, eine ganze Zahl von 0 bis 5,
    RL 1
    Halogen, (C1-C4)-Alkyl. (C1-C4)-Haloalkyl, (C1-C4)-Alkoxy, (C1-C4)-Haloalkoxy, Nitro, (C1-C4)-Alkylthio, (C1-C4)-Alkylsulfonyl, (C1-C4)-Alkoxycarbonyl, ggf. substituiertes. Phenyl, ggf. substituiertes Phenoxy,
    RL 2
    Wasserstoff oder (C1-C4)-Alkyl
    RL 3
    Wasserstoff, (C1-C8)-Alkyl, (C2-C4)-Alkenyl, (C2-C4)-Alklnyl, oder Aryl, wobei jeder der vorgenannten C-haltigen Reste unsubstituiert oder durch einen oder mehrere, vorzugsweise bis zu drei gleiche oder verschiedene Reste aus der Gruppe, bestehend aus Halogen und Alkoxy substituiert ist; oder deren Salze.
  • M) Wirkstoffe aus der Klasse der 3-(6-Tetrazolylearbonyl)-2-chinolone, z.B. 1,2-Dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarbonyl)-2-chinolon (CAS-Regno: 219479-18-2), 1,2-Dihydro-4-hydroxy-1-methyl-3-(5-tetrazolyl-carbonyl)-2-chinolon (CAS-Regno: 95855-00-8), wie sie in der WO-A-1999000020 beschrieben sind,
  • N) Verbindungen der Formeln (S-XI) oder (S-XII)
    wie sie in der WO-A-2007023719 und WO-A-2007023764 beschrieben sind
    Figure imgb0013
     worin
    RN 1
    Halogen, (C1-C4)-Alkyl. Methoxy, Nitro, Cyano, CF3, OCF3
    Y, Z
    unabhängig voneinander O oder S,
    nN
    eine ganze Zahl von 0 bis 4,
    RN 2
    (C1-C16)-Alkyl, (C2-C6)-Alkenyl, (C3-C6)-Cycloalkyl, Aryl; Benzyl, Halogenbenzyl,
    RN 3
    Wasserstoff, (C1-C6)Alkyl bedeuten;
  • O) eine oder mehreren Verbindungen aus Gruppe:
    • 1,8-Naphthalsäureanhydrid,
    • O,O-Diethyl S-2-ethylthioethyl phosphordithioat (Disulfoton),
    • 4-Chlorphenyl-methylcarbamat (Mephenate),
    • O,O-Diethyl-O-phenylphosphorotioat (Dietholate),
    • 4-Carboxy-3,4-dihydro-2H-1-benzopyran-4-essigsäure (CL-304415, CAS-Regno: 31541-57-8),
    • 2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithloate (MG-838, CAS-Regno: 133993-74-5),
    • Methyl-[(3-oxo-1H-2-benzothiopyran-4(3H)-yliden)methoxy]acetate (aus WO-A-98/13361 , CAS-Regno: 205121-04-6),
    • Cyanomethoxyimino(phenyl)acetonitril (Cyometrinil),
    • 1,3-Dioxolan-2-ylmethoxyimino(phenyl)acetonitril (Oxabetrinil),
    • 4'-Chlor-2,2,2-trifluoracetophenon-O-1,3-dioxolan-2-ylmethyloxim (Fluxofenim), 4,6-Dichlor-2-phenylpyrimidin (Fenclorim),
    • Benzyl-2-chlor-4-trifluormethyl-1,3-thiazol-5-carboxylat (Flurazole), 2-Dichlormethyl-2-methyl-1,3-dioxolan (MG-191),
    einschließlich der Stereoisomeren und der in der Landwirtschaft gebräuchlichen Salze.
The safeners are preferably selected from the group consisting of:
  • A) compounds of the formula (SI),
    Figure imgb0003
     where the symbols and indices have the following meanings:
    n A
    is a natural number of 0 to 5, preferably 0 to 3;
    R A 1
    is halogen, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, nitro or (C 1 -C 4 ) -haloalkyl;
    W A
    is an unsubstituted or substituted divalent heterocyclic radical from the group of unsaturated or unsaturated five-membered ring heterocycles having 1 to 3 hetero-ring atoms of the type N or O, wherein at least one N-atom and at most one O-atom is contained in the ring, preferably a radical the group (W A 1 ) to (W A 4 ),
    Figure imgb0004
    m A
    is 0 or 1;
    R A 2
    is OR A 3 , SR A 3 or NR A 3 R A 4 or a saturated or unsaturated 3- to 7-membered heterocycle having at least one N-atom and up to 3 heteroatoms, preferably from the group O and S, via the N atom is connected to the carbonyl group in (SI) and is unsubstituted or substituted by radicals from the group of (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy or optionally substituted phenyl, preferably a radical of Formula OR A 3 , NHR A 4 or N (CH 3 ) 2 , in particular of the formula OR A 3 ;
    R A 3
    is hydrogen or an unsubstituted or substituted aliphatic hydrocarbon radical, preferably having a total of 1 to 18 carbon atoms;
    R A 4
    is hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -alkoxy or substituted or unsubstituted phenyl;
    R A 5
    is H, (C 1 -C 8 ) -alkyl, C 1 -C 8 (haloalkyl), (C 1 -C 4 ) -alkoxy (C 1 -C 8 ) -alkyl, cyano or COOR A 9 , wherein R A 9 is hydrogen, (C 1 -C 8 ) -alkyl, (C 1 -C 8 ) -haloalkyl, (C 1 -C 4 ) -alkoxy- (C 1 -C 4 ) -alkyl, (C 1 -C 6 ) -Hydroxyalkyl, (C 3 -C 12 ) -cycloalkyl or tri- (C 1 - C 4) -alkyl-silyl;
    R A 6 , R A 7 , R A 8
    are identical or different hydrogen, (C 1 -C 8 ) -alklyl, (C 1 -C 8 ) -haloalkyl, (C 3 -C 12 ) -cycloalkyl or substituted or unsubstituted phenyl;
    preferably:
    1. a) compounds of the type dichlorophenylpyrazoline-3-carboxylic acid, preferably compounds such
      1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1) ("mefenpyr-diethyl", see Pestic. Man.), And related Compounds, as in the WO 91/07874 are described;
    2. b) derivatives of dichlorophenylpyrazolecarboxylic acid, preferably compounds such as ethyl 1- (2,4-dichlorophenyl) -5-methyl-pyrazole-3-carboxylate (S1-2), 1- (2,4-dichlorophenyl) -5-isopropyl-pyrazole Ethyl 3-carboxylate (S1-3), 1- (2,4-dichlorophenyl) -5- (1,1-dimethyl-ethyl) -pyrazole-3-carboxylate (S1-4), 1- (2,4-) Dichlorophenyl) -5-phenyl-pyrazole-3-carboxylic acid ethyl ester (S1-5) and related compounds as described in U.S. Pat EP-A-333 131 and EP-A-269806 are described;
    3. c) compounds of the triazolecarboxylic acid type, preferably compounds such as fenchlorazole (ethyl ester), ie ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2,4-triazole-3-carboxylate (S1- 6), and related compounds as in EP-A-174 562 and EP-A-346 620 are described;
    4. d) compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid type or of the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid, preferably compounds such as 5- (2,4-dichlorobenzyl) Ethyl 2-isoxazoline-3-carboxylate (S1-7) or 5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-8); and related compounds as described in U.S. Pat WO 91/08202 or 5,5-diphenyl-2-isoxazoline-carboxylic acid ethyl ester (S1-9) ("isoxadifen-ethyl") or n-propyl ester (S1-10) or 5- (4-fluorophenyl) -5 -phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-11), as described in the patent application WO-A-95/07897 are described.
  • B) quinoline derivatives of the formula (S-II),
    Figure imgb0005
     where the symbols and indices have the following meanings:
    R B 1
    Halogen, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, nitro or (C 1 -C 4 ) -haloalkyl;
    n B
    is a natural number of 0 to 5, preferably 0 to 3;
    R B 2
    OR B 3 , SR B 3 or NR B 3 R B 4 or a saturated one
    or unsaturated 3- to 7-membered heterocycle having at least one N atom and up to 3 heteroatoms, preferably from the group O and S, which is connected via the N-atom with the carbonyl group in (S-II) and unsubstituted or by Radicals from the group (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy or optionally substituted phenyl, preferably a radical of the formula OR B 3 , NHR B 4 or N (CH 3 ) 2 , in particular the formula OR B 3 ;
    R B 3
    is hydrogen or an unsubstituted or substituted aliphatic hydrocarbon radical, preferably having a total of 1 to 18 carbon atoms;
    R B 4
    is hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -alkoxy or substituted or unsubstituted phenyl;
    T B
    is a (C 1 or C 2 ) alkanediyl chain which is unsubstituted or substituted by one or two (C 1 -C 4 ) alkyl radicals or by [(C 1 -C 3 ) alkoxy] carbonyl;
    preferably:
    1. a) Compounds of the 8-quinolinoxyacetic acid (S2) type, preferably (5-chloro-8-quinolinoxy) acetic acid (1-methylhexyl) ester (common name "cloquintocet-mexyl" (S2-1) (see Pestic .), (5-chloro-8-quinolinoxy) acetic acid (1,3-dimethyl-but-1-yl) ester (S2-2), (5-chloro-8-quinolinoxy) acetic acid 4-allyl oxy-butyl ester (S2-3), (5-chloro-8-quinolinoxy) acetic acid 1-allyloxy-prop-2-yl ester (S2-4), (5-chloro-8-quinolinoxy) acetic acid ethyl ester (S2-5) . (5-chloro-8-quinolinoxy) acetic acid methyl ester (S2-6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), (5-chloro-8-quinolinoxy) acetic acid 2- (2-propylidene) Iminoxy) -1-ethyl ester (S2-8), (5-chloro-8-quinolinoxy) acetic acid 2-oxo-prop-1-yl ester (S2-9) and related compounds as described in U.S. Pat EP-A-86,750 . EP-A-94 349 and EP-A-191 736 or EP-A-0 492 366 and their hydrates and salts as described in the WO-A-2002/034048 are described.
    2. b) compounds of the (5-chloro-8-quinolinoxy) malonic acid type, preferably compounds such as diethyl (5-chloro-8-quinolinoxy) malonate, (5-chloro-8-quinolinoxy) malonic acid, (5-chloro-8-quinolinoxy ) malonic acid methyl ethyl ester and related compounds, as in EP-A-0 582198 are described.
  • C) Compounds of the formula (S-III)
    Figure imgb0006
     where the symbols and indices have the following meanings:
    • R C 1 is (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -haloalkyl, (C 2 -C 4 ) -alkenyl, (C 2 -C 4 ) -haloalkenyl, (C 3 -C 7 ) Cycloalkyl, preferably dichloromethyl;
    • R C 2 , R C 3 is identical or different hydrogen, (C 1 -C 4 ) -alkyl, (C 2 -C 4 ) -alkenyl, (C 2 -C 4 ) -alkynyl, (C 1 -C 4 ) Haloalkyl, (C 2 -C 4 ) haloalkenyl, (C 1 -C 4 ) alkylcarbamoyl (C 1 -C 4 ) alkyl, (C 2 -C 4 ) alkenylcarbamoyl (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy- (C 1 -C 4 ) -alkyl, dioxolanyl- (C 1 -C 4 ) -alkyl, thiazolyl, furyl, furylalkyl, thienyl, piperidyl, substituted or unsubstituted phenyl, or R C 2 and R C 3 together form a substituted or unsubstituted heterocyclic ring, preferably an oxazolidine, thiazolidine, piperidine, morpholine, hexahydropyrimidine or benzoxazine ring;
    preferably:
    • Active substances of the dichloroacetamide type, which are often used as pre-emergence safeners (soil-active safeners), such as. B.
    • "Dichloromid" (see Pestic.Man.) (= N, N-diallyl-2,2-dichloroacetamide), "R-29148" (= 3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine of the company Stauffer), "R-28725" (= 3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine from Stauffer), "Benoxacor" (see Pestic. Man.) (= 4-dichloroacetyl) 3,4-dihydro-3-methyl-2H-1,4-benzoxazine),
    • "PPG-1292" (= N-allyl-N - [(1,3-dioxolan-2-yl) -methyl] -dichloroacetamide from PPG Industries),
    • "DKA-24" (= N-allyl-N - [(allylamino-carbonyl) -methyl] -dichloroacetamide from Sagro-Chem),
    • "AD-67" or "MON 4660" (= 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane from Nitrokemia or Monsanto),
    • "TI-35" (= 1-dichloroacyl-azepan from TRI-Chemical RT) "diclonone" (dicyclonone) or "BAS145138" or "LAB145138" (= 3-dichloroacetyl-2,5,5-trimethyl-1, 3-diazabicyclo [4.3.0] nonane from BASF) and
    • "Furilazole" or "MON 13900" (see Pestic. Man.) (= (RS) -3-dichloroacetyl-5- (2-furyl) -2,2-dimethyloxazolidine)
  • D) N-acylsulfonamides of the formula (S-IV) and their salts,
    Figure imgb0007
     wherein
    X D
    is CH or N;
    R D 1
    is CO-NR D 5 R D 6 or NHCO-R D 7 ;
    R D 2
    is halogen, (C 1 -C 4 ) -haloalkyl, (C 1 -C 4 ) -haloalkoxy, nitro, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, (C 1 -C 4 ) -alkylsulfonyl, (C 1 -C 4 ) -alkoxycarbonyl or (C 1 -C 4 ) -alkylcarbonyl;
    R D 3
    is hydrogen, (C 1 -C 4 ) -alkyl, (C 2 -C 4 ) -alkenyl or (C 2 -C 4 ) -alkynyl;
    R D 4
    is halogen, nitro, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -haloalkyl, (C 1 -C 4 ) -haloalkoxy, (C 3 -C 6 ) -cycloalkyl, Phenyl, (C 1 -C 4 ) alkoxy, cyano, (C 1 -C 4 ) alkylthio, (C 1 -C 4 ) alkylsulfinyl, (C 1 -C 4 ) alkylsulfonyl, (C 1 -C 4 ) Alkoxycarbonyl or (C 1 -C 4 ) alkylcarbonyl; R D 5 is hydrogen, (C 1 -C 6 ) -alkyl, (C 3 -C 6 ) -cycloalkyl, (C 2 -C 6 ) -alkenyl, (C 2 -C 6 ) -alkynyl, (C 5 - C 6 ) -cycloalkenyl, phenyl or 3- to 6-membered heterocyclyl containing v D heteroatoms from the group of nitrogen, oxygen and sulfur, where the seven latter radicals are represented by v D substituents from the group halogen, (C 1 -C 6 ) - Alkoy, (C 1 -C 6 ) -haloalkoxy, (C 1 -C 2 ) -alkylsulfinyl, (C 1 -C 2 ) -alkylsulionyl, (C 3 -C 6 ) -cycloalkyl, (C 1 -C 4 ) - Alkoxycarbonyl, (C 1 -C 4 ) -alkylcarbonyl and phenyl and in the case of cyclic radicals also (C 1 -C 4 ) -alkyl and (C 1 -C 4 ) -haloalkyl;
    R D 6
    is hydrogen, (C 1 -C 6 ) -alkyl, (C 2 -C 6 ) -alkenyl or (C 2 -C 6 ) -Alking wherein the last three radicals mentioned by v D radicals from the group halogen, hydroxy, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy and (C 1 -C 4 ) -alkylthio, or
    R D 5 and R D 6
    together with the nitrogen atom carrying them form a pyrrolidinyl or piperidinyl radical;
    R D 7
    is hydrogen, (C 1 -C 4 ) -alkylamino, di (C 1 -C 4 ) -alkylamino, (C 1 -C 6 ) -alkyl, (C 3 -C 6 ) -cycloalkyl, where the 2 last-mentioned radicals by v D substituents from the group halogen, (C 1 -C 4 ) -alkoxy, halogeno (C 1 -C 6 ) -alkoxy and (C 1 -C 4 ) -alkylthlo and in the case of cyclic radicals also (C 1 - C 4 ) alkyl and (C 1 -C 4 ) haloalkyl;
    n D
    is 0, 1 or 2;
    m D
    is 1 or 2;
    v D
    is 0, 1, 2 or 3;
    preferred are compounds of the type of N-acylsulfonamides, for example of the following formula (SV), z. B. are known WO 97/45016
    Figure imgb0008
     wherein
    R D 7
    (C 1 -C 6 ) alkyl, (C 3 -C 6 ) cycloalkyl, where the 2 last-mentioned radicals are represented by v D substituents selected from the group consisting of halogen, (C 1 -C 4 ) alkoxy, and halogen (C 1 -C 6 ) alkoxy and (C 1 -C 4 ) alkylthio and in the case of cyclic radicals also (C 1 -C 4 ) alkyl and (C 1 -C 4 ) haloalkyl;
    R D 4
    Halogen, (C 1 -C 4 ) -alkyl. (C 1 -C 4 ) alkoxy, CF 3 ;
    m D
    1 or 2;
    v D
    is 0, 1, 2 or 3;
    such as
    Acylsulfamoylbenzoesäureamide, for example, the following formula (S-VI), for example, are known from WO 99/16744 ,
    Figure imgb0009
     eg those in which
    • R D 5 = cyclopropyl and (R D 4 ) = 2-OMe ("Cyprosulfamide", S3-1),
    • R D 5 = cyclopropyl and (R D 4 ) = 5-Cl-2-OMe is (S3-2),
    • R D 5 = ethyl and (R D 4 ) = 2-OMe is (S3-3),
    • R D 5 = iso-propyl and (R D 4 ) = 5-Cl-2-OMe is (S3-4) and
    • R D 5 = iso -propyl and (R D 4 ) = 2-OMe is (S3-5);
    such as
    Compounds of the type of N-Acylsulfamoylphenylhamstoffe of formula (S-VII), which are known for example from EP-A-365484 .
    Figure imgb0010
     wherein
    R D 8 and R D 9
    independently of one another are hydrogen, (C 1 -C 8 ) -alkyl, (C 3 -C 8 ) -cycloalkyl, (C 3 -C 6 ) -alkenyl, (C 3 -C 6 ) -alkynyl,
    R D 4
    Halogen, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, CF 3
    m D
    1 or 2;
    in particular
    • 1- [4- (N-2-Methoxybenzoylsulfamoyl) phenyl] -3-meth-lharnstoff,
    • 1- [4- (N-2-Methoxybenzoylsulfamoyl) phenyl] -3,3-dimethylurea,
    • 1- [4- (N-4,5-Dimethylbenzoylsulfamoyl) phenyl] -3-methylhamstoff,
    • 1- [4- (N-Naphthoylsulfamoyl) phenyl] -3,3-dimethylurea,
  • G) active compounds from the class of hydroxyaromatics and aromatic-aliphatic carboxylic acid derivatives, eg
    Ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicyclo-acid, 1,2-dihydro-2-oxo-6-trifluoromethylpyridine-3-carboxamide, 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, as described in the WO 2004084631 . WO 2005015994 . WO 2006007981 . WO 2005016001 are described;
  • H) active compounds from the class of 1,2-dihydroquinoxaline-2-ones, eg
    1-Methyl-3- (2-thienyl) -1,2-dihydroquinoxalin-2-one, 1-methyl-3- (2-thienyl) -1,2-dihydroquinoxaline-2-thione, 1- (2-aminoethyl ) -3- (2-thienyl) -1,2-dihydro-quinoxalin-2-one hydrochloride, 1- (2-methylsulfonylaminoethyl) -3- (2-thienyl) -1,2-dihydro-quinoxaline-2 on how they are in the WO 2005112630 are described
  • I) active substances which, in addition to a herbicidal activity against harmful plants, also have safener action on crop plants such as rice, such as, for example, rice. B.
    "Dimepiperate" or "MY-93" (see Pestic. Man.) (= Piperidine-1-thiocarboxylic acid S-1-methyl-1-phenylethyl ester), which is known as a safener for rice against damage by the herbicide Molinate,
    "Daimuron" or "SK 23" (see Pestic. Man.) (= 1- (1-methyl-1-phenylethyl) -3-p-tolylurea), which is known as a safener for rice against damage of the herbicide imazosulfuron,
    "Cumyluron" = "JC-940" (= 3- (2-chlorophenylmethyl) - (1-methyl-1-phenylethyl) urea, see JP-A-60087254 ), which acts as a safener for rice against damage some herbicides is known
    "Methoxyphenone" or "NK 049" (= 3,3'-dimethyl) -4-methoxybenzophenone), which is known as a safener for rice against damage of some herbicides,
    "CSB" (= 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS Reg. No. 54091-06-4 from Kumiai), which is known as a safener against damage of some herbicides in rice,
  • K) compounds of the formula (S-IX),
    as they are in the WO-A-1998/38856 are described
    Figure imgb0011
     wherein the symbols and indices have the following meanings:
    R K 1 , R K 2
    independently of one another halogen, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, (C 1 -C 4 ) -haloalkyl, (C 1 -C 4 ) -alkylamino, di- (C 1 -C 4 ) -alkylamino, nitro;
    A K
    COOR K 3 or COOR K 4
    R k 3 , F K 4
    independently of one another are hydrogen, (C 1 -C 4 ) -alkyl, (C 2 -C 6 ) -alkenyl, (C 2 -C 4 ) -alkynyl, cyanoalkyl, (C 1 -C 4 ) -haloalkyl, phenyl, nitrophenyl, Benzyl, halobenzyl, pyridinylalkyl and alkylammonium,
    n K
    0 or 1
    n K 2 , n K 3
    independently 0, 1 or 2
    preferably: methyl (diphenylmethoxy) acetate (CAS Regno: 41858-19-9),
  • L) compounds of the formula (SX),
    as they are in the WO-A-98/27049 are described
    Figure imgb0012
     wherein the symbols and indices have the following meanings:
    XL
    CH or N,
    n L
    for the case that X = N, an integer from 0 to 4 and for the case that X = CH, an integer from 0 to 5,
    R L 1
    Halogen, (C 1 -C 4 ) -alkyl. (C 1 -C 4) -haloalkyl, (C 1 -C 4) alkoxy, (C 1 -C 4) -haloalkoxy, nitro, (C 1 -C 4) alkylthio, (C 1 -C 4) -alkylsulfonyl , (C 1 -C 4 ) -alkoxycarbonyl, optionally substituted. Phenyl, optionally substituted phenoxy,
    R L 2
    Hydrogen or (C 1 -C 4 ) -alkyl
    R L 3
    Is hydrogen, (C 1 -C 8 ) -alkyl, (C 2 -C 4 ) -alkenyl, (C 2 -C 4 ) -alklnyl, or aryl, where each of the abovementioned C-containing radicals is unsubstituted or substituted by one or more preferably up to three identical or different radicals from the group consisting of halogen and alkoxy substituted; or their salts.
  • M) Active substances from the class of 3- (6-tetrazolylearbonyl) -2-quinolones, for example 1,2-dihydro-4-hydroxy-1-ethyl-3- (5-tetrazolylcarbonyl) -2-quinolone (CAS Regno: 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3- (5-tetrazolyl-carbonyl) -2-quinolone (CAS Regno. 95855-00-8), as described in the WO-A-1999000020 are described
  • N) Compounds of the formulas (S-XI) or (S-XII)
    as they are in the WO-A-2007023719 and WO-A-2007023764 are described
    Figure imgb0013
     wherein
    R N 1
    Halogen, (C 1 -C 4 ) -alkyl. Methoxy, nitro, cyano, CF 3 , OCF 3
    Y Z
    independently of one another O or S,
    n N
    an integer from 0 to 4,
    R N 2
    (C 1 -C 16 ) alkyl, (C 2 -C 6 ) alkenyl, (C 3 -C 6 ) cycloalkyl, aryl; Benzyl, halobenzyl,
    R N 3
    Hydrogen, (C 1 -C 6 ) alkyl;
  • O) one or more compounds from group:
    • 1,8-,
    • O, O-diethyl S-2-ethylthioethyl phosphorodithioate (disulfonone),
    • 4-chlorophenyl methylcarbamate (mephenate),
    • O, O-diethyl-O-phenyl phosphorotioate (dietholate),
    • 4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid (CL-304415, CAS Regno: 31541-57-8),
    • 2-propenyl 1-oxa-4-azaspiro [4.5] decane-4-carbodithloate (MG-838, CAS Regno: 133993-74-5),
    • Methyl - [(3-oxo-1H-2-benzothiopyran-4 (3H) -ylidene) methoxy] acetate (extracted WO-A-98/13361 , CAS Regno: 205121-04-6),
    • Cyanomethoxyimino (phenyl) acetonitrile (Cyometrinil),
    • 1,3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile (oxabetrinil),
    • 4'-Chloro-2,2,2-trifluoroacetophenone-O-1,3-dioxolan-2-ylmethyloxime (Fluxofenim), 4,6-dichloro-2-phenylpyrimidine (fenclorim),
    • Benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate (flurazole), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191)
    including the stereoisomers and the salts commonly used in agriculture.

Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Fungiziden, Insektiziden, Akariziden, Nematiziden, Schutzstoffen gegen Vogelfraß, Pflanzennährstoffen und Bodenstrukturverbesserungsmitteln ist möglich.A mixture with other known active ingredients, such as fungicides, insecticides, acaricides, nematicides, bird repellents, plant nutrients and soil conditioners is also possible.

Einige der Safener sind bereits als Herbizide bekannt und entfalten somit neben der Herbizidwirkung bei Schadpflanzen zugleich auch Schutzwirkung bei den Kulturpflanzen.
Die Gewichtsverhältnisse von Herbizid(mischung) zu Safener hängt im Allgemeinen von der Aufwandmenge an Herbizid und der Wirksamkeit des jeweiligen Safeners ab und kann innerhalb weiter Grenzen variieren, beispielsweise im Bereich von 200:1 bis 1:200, vorzugsweise 100:1 bis 1:100, insbesondere 20:1 bis 1:20. Die Safener können analog den Verbindungen der Formel (I) oder deren Mischungen mit weiteren Herbiziden/Pestiziden formuliert werden und als Fertigformulierung oder Tankmischung mit den Herbiziden bereitgestellt und angewendet werden.
Die erfindungsgemäßen Kombinationen (= herbiziden Mittel) weisen eine ausgezeichnete herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger mono- und dikotyler Schadpflanzen wie Unkräuter auf, einschließlich Arten die resistent sind gegen herbizide Wirkstoffe wie Glyphosate, Glufosinate, Atrazin oder Imidazolinon-Herbizide. Auch schwer bekämpfbare perennierende Unkräuter, die aus Rhizomen, Wurzelstöcken oder anderen Dauerorganen austreiben, werden durch die Wirkstoffe gut erfaßt. Dabei können die Substanzen z.B. im Vorsaat-, Vorauflauf oder Nachauflaufverfahren ausgebracht werden, z.B. gemeinsam oder getrennt. Bevorzugt ist z.B. die Anwendung im Nachauflaufverfahren, insbesondere auf die aufgelaufenen Schadpflanzen.Some of the safeners are already known as herbicides and therefore, in addition to the herbicidal effect on harmful plants, also have a protective effect on the crop plants.
The weight ratios of herbicide (mixture) to safener generally depends on the application rate of herbicide and the effectiveness of each safener and may vary within wide limits, for example in the range from 200: 1 to 1: 200, preferably 100: 1 to 1: 100, in particular 20: 1 to 1:20. The safeners can be formulated analogously to the compounds of the formula (I) or mixtures thereof with further herbicides / pesticides and provided and used as finished formulation or tank mixture with the herbicides.
The combinations according to the invention (= herbicidal agents) have an excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous harmful plants such as weeds, including species which are resistant to herbicidal active substances such as glyphosate, glufosinate, atrazine or imidazolinone herbicides. Even difficult to control perennial weeds, which expel from rhizomes, rhizomes or other permanent organs, are well detected by the active ingredients. The substances can be applied, for example, in pre-sowing, pre-emergence or post-emergence processes, for example jointly or separately. For example, the application is postemergence, in particular on the accumulated harmful plants.

Im einzelnen seien beispielhaft einige Vertreter der mono- und dikotylen Unkrautflora genannt, die durch die erfindungsgemäßen Verbindungen kontrolliert werden können, ohne dass durch die Nennung eine Beschränkung auf bestimmte Arten erfolgen soll.Specifically, by way of example, some representatives of the monocotyledonous and dicotyledonous weed flora can be mentioned, which can be controlled by the compounds according to the invention, without the intention of limiting them to certain species.

Auf der Seite der monokotylen Unkrautarten werden z.B. Avena spp., Alopecurus spp., Apera spp., Brachiaria spp., Bromus spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp. sowie Cyperusarten aus der annuellen Gruppe und auf seiten der perennierenden Spezies Agropyron, Cynodon, imperata sowie Sorghum und auch ausdauernde Cyperusarten gut erfaßt.On the side of the monocotyledonous weeds, e.g. Avena spp., Alopecurus spp., Apera spp., Brachiaria spp., Bromus spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp. and Cyperus species from the annuelle group and on the part of the perennial species Agropyron, Cynodon, imperata and Sorghum and also perennial Cyperusarten well.

Bei dikotylen Unkrautarten erstreckt sich das Wirkungsspektrum auf Arten wie z.B. Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp.,Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. und Viola spp., Xanthium spp., auf der annuellen Seite sowie Convolvulus, Cirsium, Rumex und Artemisia bei den perennierenden Unkräutern.For dicotyledonous weed species, the spectrum of activity extends to species such as Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharitis spp. , Polygonum spp., Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. and Viola spp., Xanthium spp., on the annual side, as well as Convolvulus, Cirsium, Rumex, and Artemisia in perennial weeds.

Werden die erfindungsgemäßen Verbindungen vor dem Keimen auf die Erdoberfläche appliziert, so wird entweder das Auflaufen der Unkrautkeimlinge vollständig verhindert oder die Unkräuter wachsen bis zum Keimblattstadium heran, stellen jedoch dann ihr Wachstum ein und sterben schließlich nach Ablauf von drei bis vier Wochen vollkommen ab.If the compounds according to the invention are applied to the surface of the earth before germination, then either the emergence of the weed seedlings is completely prevented or the weeds grow up to the cotyledon stage, but then cease their growth and finally die off completely after a lapse of three to four weeks.

Bei Applikation der Wirkstoffe auf die grünen Pflanzenteile im Nachauflaufverfahren tritt ebenfalls sehr rasch nach der Behandlung ein drastischer Wachstumsstop ein und die Unkrautpflanzen bleiben in dem zum Applikationszeitpunkt vorhandenen Wachstumsstadium stehen oder sterben nach einer gewissen Zeit ganz ab, so dass auf diese Weise eine für die Kulturpflanzen schädliche Unkrautkonkurrenz sehr früh und nachhaltig beseitigt wird.Upon application of the active ingredients to the green parts of the plants postemergence also occurs very quickly after treatment, a drastic halt in growth and the weed plants remain in the existing stage of application growth stage or die after a certain time completely, so that in this way one for the crops harmful weed competition is eliminated very early and sustainably.

Die erfindungsgemäßen herbiziden Mittel zeichnen sich durch eine schnell einsetzende und lang andauernde herbizide Wirkung aus. Die Regenfestigkeit der Wirkstoffe in den erfindungsgemäßen Kombinationen ist in der Regel günstig. Als besonderer Vorteil fällt ins Gewicht, dass die in den Kombinationen verwendeten und wirksamen Dosierungen von Verbindungen (A) und (B) so gering eingestellt werden können, dass ihre Bodenwirkung optimal niedrig ist. Somit wird deren Einsatz nicht nur in empfindlichen Kulturen erst möglich, sondern Grundwasser-Kontaminationen werden praktisch vermieden. Durch die erfindungsgemäßen Kombinationen von Wirkstoffen wird eine erhebliche Reduzierung der nötigen Aufwandmenge der Wirkstoffe ermöglicht.The herbicidal compositions of the invention are characterized by a rapidly onset and long-lasting herbicidal activity. The rainfastness of the active ingredients in the combinations according to the invention is generally favorable. A particular advantage is the fact that the effective and used in combinations combinations of compounds (A) and (B) can be set so low that their soil effect is optimally low. Thus, their use is not only possible in sensitive cultures, but groundwater contamination is virtually avoided. By the combinations of active ingredients according to the invention a significant reduction of the required application rate of the active ingredients is made possible.

Bei gemeinsamer Anwendung von Herbiziden der Gruppe (A) und solchen der Gruppe (B) treten bevorzugt überadditive (= synergistische) Effekte auf. Dabei ist die Wirkung in den Kombinationen stärker als die zu erwartende Summe der Wirkungen der eingesetzten Einzelherbizide. Die synergistischen Effekte erlauben eine Reduzierung der Aufwandmenge, die Bekämpfung eines breiteren Spektrums von Unkräutern und Ungräsem, einen schnelleren Einsatz der herbiziden Wirkung, eine längere Dauerwirkung, eine bessere Kontrolle der Schadpflanzen mit nur einer bzw. wenigen Applikationen sowie eine Ausweitung des möglichen Anwendungszeitraumes. Teilweise wird durch den Einsatz der Mittel auch die Menge an schädlichen Inhaltsstoffen, wie Stickstoff oder Ölsäure, und deren Eintrag in den Boden reduziert.When herbicides of group (A) and group (B) are used together, superadditive (= synergistic) effects preferably occur. The effect in the combinations is stronger than the expected sum of the effects of the individual herbicides used. The synergistic effects allow a reduction in the application rate, combating a broader spectrum of Weeds and grass weeds, a faster use of the herbicidal action, a longer lasting effect, a better control of harmful plants with only one or a few applications and an extension of the possible period of application. In part, the use of funds also reduces the amount of harmful ingredients, such as nitrogen or oleic acid, and their entry into the soil.

Die genannten Eigenschaften und Vorteile sind in der praktischen Unkrautbekämpfung gefordert, um landwirtschaftliche/forstwirtschaftliche Kulturen von unerwünschten Konkurrenzpflanzen freizuhalten und damit die Erträge qualitativ und quantitativ zu sichern und/oder zu erhöhen, Der technische Standard wird durch diese neuen Kombinationen hinsichtlich der beschriebenen Eigenschaften deutlich übertroffen.The above-mentioned properties and advantages are required in practical weed control in order to keep agricultural / forestry crops free of undesired competing plants and thus to secure and / or increase yields qualitatively and quantitatively. The technical standard is clearly exceeded by these new combinations with regard to the described properties ,

Aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften können die Mittel zur Bekämpfung von Schadpflanzen in bekannten Pflanzenkulturen oder noch zu entwickelnden toleranten oder gentechnisch veränderten Kulturpflanzen eingesetzt werden. Die transgenen Pflanzen zeichnen sich in der Regel durch besondere vorteilhafte Eigenschaften aus, neben den Resistenzen gegenüber den erfindungsgemäßen Mitteln beispielsweise durch Resistenzen gegenüber Pflanzenkrankheiten oder Erregern von Pflanzenkrankheiten wie bestimmten Insekten oder Mikroorganismen wie Pilzen, Bakterien oder Viren. Andere besondere Eigenschaften betreffen z. B. das Erntegut hinsichtlich Menge, Qualität, Lagerfähigkeit, Zusammensetzung und spezieller Inhaltsstoffe. So sind transgene Pflanzen mit erhöhtem Stärkegehalt oder veränderter Qualität der Stärke oder solche mit anderer Fettsäurezusammensetzung des Emteguts bekannt. Gleichermaßen können die Wirkstoffe aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften auch zur Bekämpfung von Schadpflanzen in Kulturen von bekannten oder noch zu entwickelnden durch Mutatantenselektion erhaltenen Pflanzen eingesetzt werden.Because of their herbicidal and plant growth regulatory properties, the agents for combating harmful plants can be used in known plant crops or tolerant or genetically modified crops to be developed. The transgenic plants are usually characterized by particular advantageous properties, in addition to the resistance to the inventive compositions, for example, by resistance to plant diseases or pathogens of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses. Other special properties relate to z. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients. Thus, transgenic plants with increased starch content or altered quality of the starch or those with other fatty acid composition of Emteguts are known. Likewise, because of their herbicidal and plant growth regulatory properties, the active compounds can also be used to control harmful plants in crops of known or yet to be developed mutant-selected plants.

Allgemein bekannte Wege zur Herstellung neuer Pflanzen, die im Vergleich zu bisher vorkommenden Pflanzen modifizierte Eigenschaften aufweisen, bestehen beispielsweise in klassischen Züchtungsverfahren und der Erzeugung von Mutanten. Alternativ können neue Pflanzen mit veränderten Eigenschaften mit Hilfe gentechnischer Verfahren erzeugt werden (siehe z. B. EP-A-0221044 , EP-A-0131624 ). Beschrieben wurden beispielsweise in mehreren Fällen

  • gentechnische Veränderungen von Kulturpflanzen zwecks Modifikation der in den Pflanzen synthetisierten Stärke (z. B. WO 92/11376 , WO 92/14827 , WO 91/19806 ),
  • transgene Kulturpflanzen, welche Resistenzen gegen Herbizide aufweisen, beispielsweise gegen Sulfonylhamstoffe ( EP-A-0257993 , US-A-6013059 ),
  • transgene Kulturpflanzen, mit der Fähigkeit Bacillus thuringiensis-Toxine (Bt-Toxine) zu produzieren, welche die Pflanzen gegen bestimmte Schädlinge resistent machen ( EP-A-0142924 , EP-A-0193259 ).
  • transgene Kulturpflanzen mit modifizierter Fettsäurezusammensetzung ( WO 91/13972 ).
Well-known ways of producing new plants compared to have previously modified plants modified properties, for example, consist in classical breeding methods and the generation of mutants. Alternatively, new plants with altered properties can be generated by means of genetic engineering methods (see, for example, US Pat. EP-A-0221044 . EP-A-0131624 ). For example, several cases have been described
  • genetic modification of crops to modify the starch synthesized in the plants (eg. WO 92/11376 . WO 92/14827 . WO 91/19806 )
  • Transgenic crop plants which have resistance to herbicides, for example to sulfonylureas ( EP-A-0257993 . US-A-6013059 )
  • transgenic crops capable of producing Bacillus thuringiensis toxins (Bt toxins) which render plants resistant to certain pests ( EP-A-0142924 . EP-A-0193259 ).
  • Transgenic crops with modified fatty acid composition ( WO 91/13972 ).

Zahlreiche molekularbiologische Techniken, mit denen neue transgene Pflanzen mit veränderten Eigenschaften hergestellt werden können, sind im Prinzip bekannt; siehe z.B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2. Aufl. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY ; oder Winnacker "Gene und Klone", VCH Weinheim 2. Auflage 1996 oder Christou, "Trends in Plant Science" 1 (1996) 423-431 ).
Für derartige gentechnische Manipulationen können Nucleinsäuremoleküle in Plasmide eingebracht werden, die eine Mutagenese oder eine Sequenzveränderung durch Rekombination von DNA-Sequenzen erlauben, Mit Hilfe der obengenannten Standardverfahren können z. B. Basenaustausche vorgenommen, Teilsequenzen entfernt oder natürliche oder synthetische Sequenzen hinzugefügt werden. Für die Verbindung der DNA-Fragmente untereinander können an die Fragmente Adaptoren oder Linker angesetzt werden.Numerous molecular biological techniques that can be used to produce new transgenic plants with altered properties are known in principle; see eg Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd Edition Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY ; or Winnacker "Genes and Clones", VCH Weinheim 2nd edition 1996 or Christou, "Trends in Plant Science" 1 (1996) 423-431 ).
For such gene engineering manipulations nucleic acid molecules can be introduced into plasmids that allow mutagenesis or a sequence change by recombination of DNA sequences, With the aid of the abovementioned standard methods, z. For example, base substitutions are made, partial sequences are removed, or natural or synthetic sequences are added. For the connection of the DNA fragments with one another adapters or linkers can be attached to the fragments.

Die Herstellung von Pflanzenzellen mit einer verringerten Aktivität eines Genprodukts kann beispielsweise erzielt werden durch die Expression mindestens einer entsprechenden antisense-RNA, einer sense-RNA zur Erzielung eines Cosuppressionseffektes oder die Expression mindestens eines entsprechend konstruierten Ribozyms, das spezifisch Transkripte des obengenannten Genprodukts spaltet.The production of plant cells with a reduced activity of a Gene product can be obtained, for example, by the expression of at least one corresponding antisense RNA, a sense RNA to obtain a cosuppression effect or the expression of at least one appropriately engineered ribozyme which specifically cleaves transcripts of the above gene product.

Hierzu können zum einen DNA-Moleküle verwendet werden, die die gesamte codierende Sequenz eines Genprodukts einschließlich eventuell vorhandener flankierender Sequenzen umfassen, als auch DNA-Moleküle, die nur Teile der codierenden Sequenz umfassen, wobei diese Teile lang genug sein müssen, um in den Zellen einen antisense-Effekt zu bewirken. Möglich ist auch die Verwendung von DNA-Sequenzen, die einen hohen Grad an Homologie zu den codiereden Sequenzen eines Genprodukts aufweisen, aber nicht vollkommen identisch sind.For this purpose, DNA molecules may be used which comprise the entire coding sequence of a gene product, including any flanking sequences that may be present, as well as DNA molecules which comprise only parts of the coding sequence, which parts must be long enough to be present in the cells to cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but are not completely identical.

Bei der Expression von Nucleinsäuremolekülen in Pflanzen kann das synthetisierte Protein in jedem beliebigen Kompartiment der pflanzlichen Zelle lokalisiert sein. Um aber die Lokalisation in einem bestimmten Kompartiment zu erreichen, kann z. B. die codierende Region mit DNA-Sequenzen verknüpft werden, die die Lokalisierung in einem bestimmten Kompartiment gewährleisten. Derartige Sequenzen sind dem Fachmann bekannt (siehe beispielsweise Braun et al., EMBO J. 11 (1992). 3219-3227 ; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850 ; Sonnewald et al., Plant J. 1 (1991), 95-106 ).In the expression of nucleic acid molecules in plants, the synthesized protein may be located in any compartment of the plant cell. But to achieve the localization in a particular compartment, z. For example, the coding region can be linked to DNA sequences that ensure localization in a particular compartment. Such sequences are known to the person skilled in the art (see, for example Braun et al., EMBO J. 11 (1992). 3219-3227 ; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850 ; Sonnewald et al., Plant J. 1 (1991), 95-106 ).

Die transgenen Pflanzenzellen können nach bekannten Techniken zu ganzen Pflanzen regeneriert werden. Bei den transgenen Pflanzen kann es sich prinzipiell um Pflanzen jeder beliebigen Pflanzenspezies handeln, d.h. sowohl monokotyle als auch dikotyle Pflanzen. So sind transgene Pflanzen erhältlich, die veränderte Eigenschaften durch Überexpression, Suppression oder Inhibierung homologer (= natürlicher) Gene oder Gensequenzen oder Expression heterologer (= fremder) Gene oder Gensequenzen aufweisen.The transgenic plant cells can be regenerated to whole plants by known techniques. The transgenic plants may in principle be plants of any plant species, i. both monocotyledonous and dicotyledonous plants. Thus, transgenic plants are available which have altered properties by overexpression, suppression or inhibition of homologous (= natural) genes or gene sequences or expression of heterologous (= foreign) genes or gene sequences.

Gegenstand der vorliegenden Erfindung ist weiterhin ein Verfahren zur Bekämpfung von unerwünschten Pflanzen, vorzugsweise in Pflanzenkulturen, das dadurch gekennzeichnet ist, dass die Herbizide (A) und (B) der erfindungsgemäßen Herbizid-Kombination auf die Pflanzen (z.B. Schadpflanzen wie mono- oder dikotyle Unkräuter oder unerwünschte Kulturpflanzen), das Saatgut (z.B. Körner. Samen oder vegetative Vermehrungsorgane wie Knollen oder Sprossteile mit Knospen) oder die Fläche, auf der die Pflanzen wachsen (z.B. die Anbaufläche), ausgebracht werden, z.B. gemeinsam oder getrennt. Dabei können eines oder mehrere Herbizide (A) vor, nach oder gleichzeitig mit dem oder den Herbizid(en) (B) auf die Pflanzen, das Saatgut oder die Fläche, auf der die Pflanzen wachsen (z.B. die Anbaufläche), appliziert werden.The present invention furthermore relates to a method for controlling undesirable plants, preferably in crops, characterized in that the herbicides (A) and (B) of the herbicidal combination according to the invention on the plants (eg harmful plants such as mono- or dicotyledonous weeds or undesirable crops), the seed (eg grains Seeds or vegetative propagules such as tubers or sprout parts with buds) or the area on which the plants grow (eg the cultivated area), for example together or separately. One or more herbicides (A) may be applied before, after or simultaneously with the herbicide (s) (B) to the plants, seed or area on which the plants grow (eg the area under cultivation).

Unter unerwünschten Pflanzen sind alle Pflanzen zu verstehen, die an Orten wachsen, wo sie unerwünscht sind. Dies können z.B. Schadpflanzen (z.B. mono- oder dikotyle Unkräuter oder unerwünschte Kulturpflanzen) sein, z.B. auch solche, die gegen bestimmte herbizide Wirkstoffe wie Glyphosate, Atrazin, Glufosinate oder Imidazolinon-Herbizide resistent sind.Undesirable plants are understood to mean all plants that grow in places where they are undesirable. This can e.g. Harmful plants (e.g., mono- or dicotyledonous weeds or undesired crops), e.g. also those which are resistant to certain herbicidal active substances such as glyphosate, atrazine, glufosinate or imidazolinone herbicides.

Die erfindungsgemäßen Herbizid-Kombinationen werden selektiv zur Bekämpfung unerwünschten Pflanzenwuchses eingesetzt werden, z.B. in Pflanzenkulturen wie Ackerbaukulturen z.B. monokotylen Ackerbaukulturen wie Getreide (z.B. Weizen, Gerste, Roggen, Hafer), Reis, Mais, Hirse, oder dikotylen Ackerbaukulturen wie Zuckerrübe, Raps, Baumwolle, Sonnenblumen und Leguminosen z.B. der Gattungen Glycine (z.B. Glycine max. (Soja) wie nicht-transgene Glycine max. (z.B. konventionelle Sorten wie STS-Sorten) oder transgene Glycine max. (z.B. RR-Soja oder LL-Soja) und deren Kreuzungen), Phaseolus, Pisum, Vicia und Arachis, oder Gemüsekulturen aus verschiedenen botanischen Gruppen wie Kartoffel, Lauch, Kohl, Karotte, Tomate, Zwiebel. Dabei erfolgt die Applikation bevorzugt auf die aufgelaufenen Schadpflanzen (z.B. Unkräuter oder unerwünschte Kutturpflanzen), insbesondere vor dem Auflaufen von (erwünschten) Kulturpflanzen.The herbicidal combinations of the invention will be used selectively to control undesired plant growth, e.g. in crops such as crops, e.g. monocotyledonous crops such as cereals (e.g., wheat, barley, rye, oats), rice, corn, millet, or dicotyledonous crops such as sugar beet, oilseed rape, cotton, sunflowers, and legumes, e.g. of the genera Glycine (eg Glycine max. (soy) as non-transgenic Glycine max (eg conventional varieties such as STS varieties) or transgenic Glycine max (eg RR soy or LL soy) and their crosses), Phaseolus, Pisum , Vicia and Arachis, or vegetable crops from various botanical groups such as potato, leek, cabbage, carrot, tomato, onion. In this case, the application is preferably carried out on the accumulated harmful plants (for example weeds or unwanted Kuttur plants), in particular before emergence of (desired) crop plants.

Gegenstand der Erfindung ist auch die Verwendung der erfindungsgemäßen Herbizid-Kombinationen zur Bekämpfung von unerwünschtem Pflanzenwuchs, vorzugsweise in Pflanzenkulturen.The invention also provides the use of the herbicidal combinations according to the invention for controlling undesired plant growth, preferably in crops.

Die erfindungsgemäßen Herbizid-Kombinationen können nach bekannten Verfahren z.B. als Mischformulierungen der Einzelkomponenten, gegebenenfalls mit weiteren Wirkstoffen, Zusatzstoffen und/oder üblichen Formulierungshilfsmitteln hergestellt werden, die dann in üblicher Weise mit Wasser verdünnt zur Anwendung gebracht werden, oder als sogenannte Tankmischungen durch gemeinsame Verdünnung der getrennt formulierten oder partiell getrennt formulierten Komponenten mit Wasser hergestellt werden. Ebenfalls möglich ist die zeitlich versetzte Anwendung (Splitapplikation) der getrennt formulierten oder partiell getrennt formulierten Einzelkomponenten.
Möglich ist auch die Anwendung der Herbizide oder der Herbizid-Kombinationen in mehreren Portionen (Sequenzanwendung), z. B. nach Anwendungen im Vorauflauf, gefolgt von Nachauflauf-Applikationen oder nach frühen Nachauflaufanwendungen, gefolgt von Applikationen im mittleren oder späten Nachauflauf. Bevorzugt ist dabei die gemeinsame oder die zeitnahe Anwendung der Wirkstoffe der jeweiligen Kombination.The herbicidal combinations according to the invention can be prepared by known processes, for example as mixed formulations of the individual components, if appropriate with further active ingredients, additives and / or customary formulation auxiliaries, which are then diluted with water in a customary manner, or as so-called tank mixtures by joint dilution separately formulated or partially separately formulated components with water. Also possible is the staggered application (split application) of the separately formulated or partially separately formulated individual components.
It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preference is given to the common or timely use of the active ingredients of the respective combination.

Die Herbizide (A) und (B) können gemeinsam oder getrennt in übliche Formulierungen übergeführt werden, wie Lösungen, Emulsionen, Suspensionen, Pulver, Schäume, Pasten, Granulate, Aerosole, Wirkstoff-imprägnierte Natur und synthetische Stoffe, Feinstverkapselungen in polymeren Stoffen. Die Formulierungen können die üblichen Hilfs- und Zusatzstoffe enthalten.The herbicides (A) and (B) can be converted together or separately into customary formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, active substance-impregnated nature and synthetic substances, microencapsulations in polymeric substances. The formulations may contain the usual auxiliaries and additives.

Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Streckmitteln, also flüssigen Lösungsmitteln, unter Druck stehenden verflüssigten Gasen und/oder festen Trägerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln.These formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, that is to say liquid solvents, liquefied gases under pressure and / or solid carriers, if appropriate using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-forming agents.

Im Falle der Benutzung von Wasser als Streckmittel könne z.B. auch organische Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen infrage: Aromaten, wie Xylol, Toluol, Alkylnaphthaline, chlorierte Aromaten oder chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene, oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone, wie Aceton, Methylethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid oder Dimethylsulfoxid, sowie Wasser.In the case of the use of water as extender, for example, organic solvents can also be used as auxiliary solvent. As liquid solvents are essentially in question: aromatics such as xylene, toluene, alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, eg petroleum fractions, mineral and vegetable oils, alcohols such as butanol or Glycol and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, and water.

Als feste Trägerstoffe kommen in Frage: z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quartz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate; als feste Trägerstoffe für Granulate kommen infrage: z.B, gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnußschalen, Maiskolben und Tabakstengel; als Emulgier- und/oder schaumerzeugende Mittel kommen infrage: z.B. nicht ionogene und anionische Emulgatoren, wie Polyoxyethylen-Fettsäureester, Polyoxyethylen-Fettalkohol-Ether, z.B. Alkylarylpolyglykolether, Alkylsulfonate, Alkylsulfate, Arylsulfonate sowie Eiweißhydrolysate; als Dispergiermittel kommen infrage: z.B. Ligninsulfitablaugen und Methylcellulose.Suitable solid carriers are: e.g. Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates; as solid carriers for granules are: for example, broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corncobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkylsulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Ligninsulfitablaugen and methylcellulose.

Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische, pulverige, körnige oder latexförmige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholipide, wie Kephaline und Lecithine und synthetische Phospholipide. Weitere Additive können mineralische und vegetabile Öle sein.
Die herbizide Wirkung der erfindungsgemäßen Herbizid-Kombinationen kann z.B. gleichemaßen durch oberflächenaktive Substanzen verbessert werden, vorzugsweise durch Netzmittel aus der Reihe der Fettalkohol-Polyglykolether. Die Fettalkohol-Polyglykolether enthalten vorzugsweise 10 - 18 C-Atome im Fettalkoholrest und 2 - 20 Ethylenoxideinheiten im Polyglykoletherteil, Die Fettalkohol-Polyglykolether können nichtionisch vorliegen, oder ionisch, z.B. in Form von Fettalkohol-Polyglykolethersulfaten, vorliegen, die z.B. als Alkalisalze (z.B. Natrium- und Kaliumsalze) oder Ammoniumsalze, oder auch als Erdalkalisalze wie Magnesiumsalze verwendet werden, wie C12/C14-Fettalkohol-diglykolethersulfat-Natrium (Genapol® LRO, Clariant GmbH); siehe z.B. EP-A-0476555 , EP-A-0048436 , EP-A-0336151 oder US-A-4,400,196 sowie Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227 - 232 (1988 ). Nichtionische Fettalkohol-Polyglykolether sind beispielsweise 2 - 20, vorzugsweise 3 - 15, Ethylenoxideinheiten enthaltende (C10 - C18)-, vorzugsweise (C10-C14)-Fettalkohol-Polyglykolether (z.B. Isotridecylalkohol-Polyglykolether) z.B. aus der Genapol® X-Reihe wie Genapol® X-030, Genapol® X-060, Genapol® X-080 oder Genapol® X-150 (alle von Clariant GmbH).Adhesives such as carboxymethylcellulose, natural and synthetic, powdery, granular or latex polymers may be used in the formulations, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins and synthetic phospholipids. Other additives may be mineral and vegetable oils.
The herbicidal action of the herbicide combinations according to the invention can be improved, for example, equally by surface-active substances, preferably wetting agents from the series of fatty alcohol polyglycol ethers. The fatty alcohol polyglycol ethers preferably contain 10 - 18 C atoms in the The fatty alcohol polyglycol ethers may be nonionic, or ionic, for example in the form of fatty alcohol Polyglykolethersulfaten present, for example as alkali salts (eg sodium and potassium salts) or ammonium salts, or as alkaline earth salts such as magnesium salts be used, such as C 12 / C 14 fatty alcohol diglycol ether sulfate sodium (Genapol ® LRO, Clariant GmbH); see eg EP-A-0476555 . EP-A-0048436 . EP-A-0336151 or US-A-4,400,196 such as Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227-232 (1988 ). Nonionic fatty alcohol polyglycol ethers are, for example, 2 - 20, preferably 3 - 15 ethylene oxide units containing (C 10 - C 18) -, preferably (C 10 -C 14) fatty alcohol polyglycol ethers (for example isotridecyl alcohol polyglycol ether), for example from the Genapol ® X series such as Genapol® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).

Die vorliegende Erfindung umfaßt ferner die Kombination von Komponenten A und B mit den vorgängig genannten Netzmitteln aus der Reihe der Fettalkohol-Polyglykolether, die vorzugsweise 10 - 18 C-Atome im Fettalkoholrest und 2 - 20 Ethylenoxideinheiten im Polyglykoletherteil enthalten und nichtionisch oder ionisch (z.B. als Fettalkohol-polyglykolethersulfate) vorliegen können. Bevorzugt sind C12/C14-Fottalkohol-diglykolethersulfat-Natrium (Genapol® LRO, Clariant GmbH) und Isotridecylalkohol-Polyglykolether, mit 3 - 15 Ethylenoxideneinheiten, z.B. aus der Genapol® X-Reihe wie Genapol® X-030, Genapol® X-060, Genapol® X-080 und Genapol® X-150 (alle von Clariant GmbH). Weiterhin ist bekannt, daß Fettalkohol-Polyglykoletherwie nichtionische oder ionische Fettalkohol-polyglykolether (z.B. Fettalkohol-Polyglykolethersulfate) auch als Penetrationshilfsmlttel und Wirkungsverstärker für eine Reihe anderer Herbizide geeignet sind (siehe z.B. EP-A-0502014 ).The present invention further comprises the combination of components A and B with the aforementioned wetting agents from the series of fatty alcohol polyglycol ethers which preferably contain 10 to 18 C atoms in the fatty alcohol radical and 2 to 20 ethylene oxide units in the polyglycol ether part and nonionic or ionic (for example as Fatty alcohol polyglycol ether sulfates) may be present. Preferred are C 12 / C 14 -Fottalkohol diglycol ether sodium (Genapol ® LRO, Clariant GmbH) and isotridecyl alcohol polyglycol ether having 3-15 ethylene oxide units, for example from the Genapol ® X series, such as Genapol ® X-030, Genapol ® X -060, Genapol ® X-080 and Genapol ® X-150 (all from Clariant GmbH). Furthermore, it is known that fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (eg fatty alcohol polyglycol ether) are also suitable as Penetrationshilfsmlttel and effect enhancers for a number of other herbicides (see, eg EP-A-0502014 ).

Weiterhin ist bekannt, daß Fettalkohol-Polyglykolether wie nichtionische oder ionische Fettelkohol-Polyglykolether (z.B. Fettalkohol-Polyglykolethersulfate) auch als Penetratiorishilfsmittel und Wirkungsverstärker für eine Reihe anderer Herbizide, geeignet sind (siehe z.B. EP-A-0502014 ).It is also known that fatty alcohol polyglycol ethers, such as nonionic or ionic fatty alcohol polyglycol ethers (eg fatty alcohol polyglycol ether sulfates), are also suitable as penetrating aids and enhancers for a number of other herbicides (see, for example, US Pat EP-A-0502014 ).

Die herbizide Wirkung der erfindungsgemäßen Herbizid-Kombinationen kann auch durch die Verwendung von Pflanzenölen verstärkt werden. Unter dem Begriff Pflanzenöle werden Öle aus ölliefernden Pflanzenarten wie Sojaöl, Rapsöl, Maiskeimöl, Sonnenblumenöl, Baumwollsaatöl, Leinöl, Kokosöl, Palmöl, Distelöl oder Rhizinusöl, insbesondere Rapsöl verstanden, sowie deren Umesterungsprodukte, z.B. Alkylester wie Rapsölmethylester oder Rapsölethylester.The herbicidal action of the herbicidal combinations according to the invention can also be enhanced by the use of vegetable oils. The term vegetable oils refers to oils from oil-supplying plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, thistle oil or castor oil, in particular rapeseed oil, and their transesterification products, e.g. Alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.

Die Pflanzenöle sind bevorzugt Ester von C10-C22-, vorzugsweise C12-C20-Fettsäuren. Die C10-C22-Fettsäureester sind beispielsweise Ester ungesättigter oder gesättigter C10-C22-Fettsäuren, insbesondere mit gerader Kohlenstoffatomzahl, z.B. Erucasäure, Laurinsäure. Palmitinsäure und insbesondere C18-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.The vegetable oils are preferably esters of C 10 -C 22 -, preferably C 12 -C 20 fatty acids. The C 10 -C 22 fatty acid esters are, for example, esters of unsaturated or saturated C 10 -C 22 fatty acids, in particular having an even number of carbon atoms, for example erucic acid, lauric acid. Palmitic acid and in particular C 18 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.

Beispiele für C10-C22-Fettsäure-Ester sind Ester, die durch Umsetzung von Glycerin oder Glykol mit den C10-C22-Fettsäuren erhalten werden, wie sie z.B. in Ölen aus ölliefernden Pflanzenarten enthalten sind, oder C1-C20-Alkyl-C10-C22-Feftsäure-Ester, wie sie z.B. durch Umesterung der vorgenannten Glycerin- oder Glykol-C10-C22-Fettsäure-Ester mit C1-C20-Alkoholen (z.B. Methanol, Ethanol, Propanol oder Butanol) erhalten werden können. Die Umesterung kann nach bekannten Methoden erfolgen, wie sie z.B. beschrieben sind im Römpp Chemie Lexikon, 9. Auflage, Band 2, Seite 1343, Thieme Verlag Stuttgart .Examples of C 10 -C 22 fatty acid esters are esters which are obtained by reacting glycerol or glycol with the C 10 -C 22 fatty acids, as contained for example in oils from oil-yielding plant species, or C 1 -C 20 Alkyl C 10 -C 22 -Feftsäure esters, as for example by transesterification of the aforementioned glycerol or glycol C 10 -C 22 fatty acid esters with C 1 -C 20 alcohols (eg, methanol, ethanol, propanol or Butanol) can be obtained. The transesterification can be carried out by known methods, as described, for example, in US Pat Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart ,

Als C1-C20-Alkyl-C10-C22-Fettsäure-Ester bevorzugt sind Methylester, Ethylester, Propylester, Butylester, 2-ethyl-hexylester und Dodecylester. Als Glykol- und Glycerin-C10-C22-Fettsäure-Ester bevorzugt sind die einheitlichen oder gemischten Glykolester und Glycerinester von C10-C22-Fettsäuren, insbesondere solcher Fettsäuren mit gerader Anzahl an Kohlenstoffatomen, z.B. Erucasäute, Laurinsäure, Palmitinsäure und insbesondere C18-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.Preferred C 1 -C 20 alkyl C 10 -C 22 fatty acid esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethylhexyl esters and dodecyl esters. Preferred glycol and glycerol C 10 -C 22 fatty acid esters are the uniform or mixed glycol esters and glycerol esters of C 10 -C 22 fatty acids, in particular those having even numbers of carbon atoms, for example erucic, lauric, palmitic and especially C 18 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.

Die Pflanzenöle können in den erfindungsgemäßen herbiziden Mitteln z.B. in Form kommerziell erhältlicher ölhaltiger Formulierungszusatzstoffe, insbesondere solcher auf Basis von Rapsöl wie Hasten® (Victorian Chemical Company, Australien, nachfolgend Hasten genannt, Hauptbestandteil: Rapsölethylester), Actirob®B (Novance, Frankreich, nachfolgend ActirobB genannt, Hauptbestandteil: Rapsölmethylester), Rako-Binol® (Bayer AG, Deutschland, nachfolgend Rako-Binol genannt, Hauptbestandteil: Rapsöl), Renol® (Stefes, Deutschland, nachfolgend Renol genannt, Pflanzenölbestandteil: Rapsölmethylester) oder Stefes Mero® (Stefes, Deutschland, nachfolgend Mero genannt, Hauptbestandteil: Rapsölmethylester) enthalten sein.The vegetable oils can be used in the herbicidal compositions of the invention, for example in the form commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten ® (Victorian Chemical Company, Australia, hereinbelow termed Hasten, main ingredient: rapeseed oil ethyl ester), Actirob ® B (Novance, France, hereinafter ActirobB called Main Ingredient: Rapsölmethylester), Rako-Binol (called Bayer AG, Germany, referred to as Rako-binol, main ingredient: rapeseed oil) ®, Renol ® (Stefes, hereinafter referred to Germany Renol, vegetable oil ingredient: Rapsölmethylester) or Stefes Mero ® (Stefes, Germany, termed Mero called main ingredient: Rapsölmethylester) be included.

Die vorliegende Erfindung umfasst in einer weiteren Ausführungsform Kombinationen mit den vorgängig genannten Pflanzenölen wie Rapsöl, bevorzugt in Form kommerziell erhältlicher ölhaltiger Formulierungszusatzstoffe, insbesondere solcher auf Basis von Rapsöl wie Hasten® (Victorian Chemical Company, Australien, nachfolgend Hasten genannt, Hauptbestandteil: Rapsölethylester), Actirob®s (Novance, Frankreich, nachfolgend ActirobB genannt, Hauptbestandteil: Rapsölmethylester), Rako-Binol® (Bayer AG, Deutschland, nachfolgend Rako-Binol genannt, Hauptbestandteil: Rapsöl), Renol® (Stefes, Deutschland, nachfolgend Renol genannt, Pflanzenölbestandteil: Rapsölmethylester) oder Stefes Mero® (Stefes, Deutschland, nachfolgend Mero genannt, Hauptbestandteil: Rapsölmethylester).In a further embodiment, the present invention comprises combinations with the abovementioned vegetable oils such as rapeseed oil, preferably in the form of commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten® (Victorian Chemical Company, Australia, hereinafter referred to as Hasten, main constituent: rapeseed oil ethyl ester), Actirob ® s (Novance, France, hereinafter referred ActirobB, main ingredient: Rapsölmethylester), Rako-binol ® (Bayer AG, Germany, termed Rako-binol, main ingredient: rapeseed oil), Renol ® (Stefes, Germany, termed Renol, vegetable oil ingredient : Rapeseed oil methyl ester) or Stefes Mero® (Stefes, Germany, hereinafter referred to as Mero, main component: rapeseed oil methyl ester).

Es können Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferrocyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyaninfarbstoffe und Spurennährstoffe wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gewichtsprozent Wirkstoff, vorzugsweise zwischen 0,5 und 90 Gew.-%.The formulations generally contain between 0.1 and 95 percent by weight of active compound, preferably between 0.5 and 90 percent by weight.

Die Herbizide (A) und (B) können als solche oder in ihren Formulierungen auch in Mischung mit anderen agrochemischen Wirkstoffen wie bekannten Herbiziden zur Bekämpfung von unerwünschtem Pflanzenwuchs, z.B. zur Unkrautbekämpfung oder zur Bekämpfung von unerwünschten Kulturpflanzen Verwendung finden, wobei z.B. Fertigformulierungen oder Tankmischungen möglich sind.The herbicides (A) and (B) can be used as such or in their formulations also in admixture with other agrochemical active substances such as known herbicides Control of undesirable plant growth, for example, for weed control or to control unwanted crops use, for example, finished formulations or tank mixes are possible.

Auch Mischungen mit anderen bekannten Wirkstoffen wie Fungiziden, Insektiziden, Akariziden, Nematiziden, Safenem, Schutzstoffen gegen Vogelfraß, Pflanzennährstoffen und Bodenstrukturverbesserungsmitteln sind möglich.Mixtures with other known active substances such as fungicides, insecticides, acaricides, nematicides, safeners, bird repellents, plant nutrients and soil conditioners are also possible.

Die Herbizide (A) und (B) können als solche, in Form ihrer Formulierungen oder den daraus durch weiteres Verdünnen bereiteten Anwendungsformen, wie gebrauchsfertige Lösungen, Suspensionen, Emulsionen, Pulver, Pasten und Granulat angewandt werden. Die Anwendung geschieht in üblicher Weise, z.B. durch Gießen, Spritzen, Sprühen, Streuen.The herbicides (A) and (B) can be applied as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. The application is done in the usual way, e.g. by pouring, spraying, spraying, sprinkling.

Die Wirkstoffe können auf die Pflanzen (z.B. Schadpflanzen wie mono- oder dikotyle Unkräuter oder unerwünschte Kulturpflanzen), das Saatgut (z.B. Körner, Samen oder vegetative Vermehrungsorgane wie Knollen oder Sprossteile mit Knospen) oder die Anbaufläche (z.B. Ackerboden) ausgebracht werden, vorzugsweise auf die grünen Pflanzen und Pflanzenteile und gegebenenfalls zusätzlich auf den Ackerboden. Eine Möglichkeit der Anwendung ist die gemeinsame Ausbringung der Wirkstoffe in Form von Tankmischungen, wobei die optimal formulierten konzentrierten Formulierungen der Einzehwirkstoffe gemeinsam im Tank mit Wasser gemischt werden und die erhaltene Spritzbrühe ausgebracht wird.The active substances can be applied to the plants (for example harmful plants such as monocotyledonous or dicotyledonous weeds or undesired crop plants), the seed (for example grains, seeds or vegetative propagation organs such as tubers or shoot parts with buds) or the cultivated area (for example field soil), preferably to the green plants and parts of plants and, where appropriate, on the farmland. One possibility of the application is the joint application of the active ingredients in the form of tank mixes, wherein the optimally formulated concentrated formulations of the Einzehwirkstoffe are mixed together in the tank with water and the resulting spray mixture is discharged.

Eine gemeinsame herbizide Formulierung der erfindungsgemäßen Kombination an Herbiziden (A) und (B) hat den Vorteil der leichteren Anwendbarkeit, wobei die Mengen der Komponenten bereits im optimalen Verhältnis zueinander eingestellt werden können. Außerdem können die Hilfsmittel in der Formulierung aufeinander optimal abgestimmt werden.A common herbicidal formulation of the combination of herbicides (A) and (B) according to the invention has the advantage of easier applicability, wherein the amounts of the components can be adjusted already in the optimal ratio to each other. In addition, the adjuvants in the formulation can be optimally matched to one another.

Biologische BeispieleBiological examples 1. Unkrautwirkung im Vorauflauf1. weed effect in pre-emergence

Samen beziehungsweise Rhizomstücke von mono- und dikotylen Unkrautpflanzen wurden in Papptöpfen in sandiger Lehmerde ausgelegt und mit Erde abgedeckt. Die in Form von benetzbaren Pulvern oder Emulsionskonzentraten formulierten Wirkstoffe (A) und (B) wurden dann als wäßrige Suspensionen bzw. Emulsionen mit einer Wasseraufwandmenge von umgerechnet 100 bis 800 l/ha in unterschiedlichen Dosierungen auf die Oberfläche der Abdeckerde appliziert.Seeds or rhizome pieces of monocotyledonous and dicotyledonous weed plants were placed in sandy soil in cardboard pots and covered with soil. The formulated in the form of wettable powders or emulsion concentrates active compounds (A) and (B) were then applied as aqueous suspensions or emulsions with a water application rate of 100 to 800 l / ha in different dosages on the surface of the cover soil.

Nach der Behandlung wurden die Töpfe im Gewächshaus aufgestellt und unter guten Wachstumsbedingungen für die Unkräuter gehalten. Die optische Bonitur der Pflanzen- bzw. Auflaufschäden erfolgte nach dem Auflaufen der Versuchspflanzen nach einer Versuchszeit von 3 bis 4 Wochen im Vergleich zu unbehandelten Kontrollen. Wie die Ergebnisse zeigen, weisen die getesteten Herbizid-Kombinationen eine gute herbizide Vorauflaufwirksamkeit gegen ein breites Spektrum von Ungräsern und Unkräutern auf. Die Herbizid-Kombinationen des 2-lodo-N-[(4-methoxy-6-methyl-9,3,5-triazin-2-yl)carbamoyl]benzolsulfonamids und von in Tabelle A genannten Verbindungen der Formel (I) weisen mit Verbindungen der Gruppe B sehr gute synergistische herbizide Wirkung gegen Schadpflanzen wie Sinapis alba, Chrysanthemum segetum, Avena sativa, Stellaria media, Echinochloa crus-galli, Lolium multiflorum, Setaria viridis, Abutilon theophrasti, Amaranthus retroflexus und Panicum miliaceum im Vorauflaufverfahren bei einer Aufwandmenge von 100 g und weniger Aktivsubstanz pro Hektar.After the treatment, the pots were placed in the greenhouse and kept under good growth conditions for the weeds. The optical assessment of the plant damage and / or the emergence damage occurred after emergence of the test plants after a test time of 3 to 4 weeks in comparison to untreated controls. As the results show, the tested herbicidal combinations have a good herbicidal pre-emergence activity against a broad spectrum of grass weeds and weeds. The herbicide combinations of the 2-iodo-N - [(4-methoxy-6-methyl-9,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and of the compounds of the formula (I) mentioned in Table A have Compounds of group B have very good synergistic herbicidal activity against harmful plants such as Sinapis alba, Chrysanthemum segetum, Avena sativa, Stellaria media, Echinochloa crus-galli, Lolium multiflorum, Setaria viridis, Abutilon theophrasti, Amaranthus retroflexus and Panicum miliaceum pre-emergence at an application rate of 100 g and less active substance per hectare.

2. Unkrautwirkung im Nachauflauf2. weed effect postemergence

Samen bzw. Rhizomstücke von mono- und dikotylen Unkräutern wurden in Plastiktöpfen in sandigem Lehmboden ausgelegt, mit Erde abgedeckt und im Gewächshaus unter guten Wachstumsbedingungen angezogen. Drei Wochen nach der Aussaat wurden die Versuchspflanzen im 2-4 Blattstadium behandelt. Die als Spritzpulver bzw. als Emulsionskonzentrate formulierten erfindungsgemäßen Verbindungen wurden in verschiedenen Dosierungen mit einer Wasseraufwandmenge von umgerechnet 100 bis 800 l/ha auf die grünen Pflanzenteile gesprüht. Nach 3 bis 4 Wochen Standzeit der Versuchspflanzen im Gewächshaus unter optimalen Wachstumsbedingungen wurde die Wirkung der Präparate optisch im Vergleich zu unbehandelten Kontrollen bonitiert.Seeds or rhizome pieces of monocotyledonous and dicotyledonous weeds were placed in sandy loam soil in plastic pots, covered with soil and grown in the greenhouse under good growth conditions. Three weeks after sowing, the test plants were treated in the 2-4 leaf stage. The compounds of the invention formulated as wettable powders or as emulsion concentrates were sprayed onto the green plant parts in various dosages with an amount of water applied of from 100 to 800 l / ha. After 3 to 4 weeks of life of the test plants in the greenhouse under optimal growth conditions, the effect of the preparations was visually scored compared to untreated controls.

Allgemein weisen die erfindungsgemäßen Herbizid-Kombinationen auch im Nachauflauf eine gute herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger Ungräser und Unkräuter auf. Die Herbizid-Kombinationen des 2-lodo-N-[{4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamids und von in Tabelle A genannten Verbindungen der Formel (I) weisen mit Verbindungen der Gruppe B sehr gute synergistische herbizide Wirkung gegen Schadpflanzen wie Sinapis alba, Echinochloa crus-galli, Digitaria sanguinalis, Lolium multiflorum, Chrysanthemum segetum, Setaria viridis, Polygonum convolvulus, Abutilon theophrasti, Amaranthus retroflexus, Panicum miliaceum und Avena sativa im Nachauflaufverfahren bei einer Aufwandmenge von 100 g und weniger Aktivsubstanz pro Hektar.In general, the herbicidal combinations according to the invention have a good herbicidal activity against the emergence of a broad spectrum of economically important weeds and weeds. The herbicide combinations of the 2-iodo-N - [{4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and of the compounds of the formula (I) mentioned in Table A have Group B compounds have very good synergistic herbicidal activity against harmful plants such as Sinapis alba, Echinochloa crus-galli, Digitaria sanguinalis, Lolium multiflorum, Chrysanthemum segetum, Setaria viridis, Polygonum convolvulus, Abutilon theophrasti, Amaranthus retroflexus, Panicum miliaceum and Avena sativa postemergence at one Application rate of 100 g and less active substance per hectare.

Claims (8)

Herbizid-Kombination enthaltend Komponenten (A) und (B), wobei (A) ein oder mehrere Herbizide aus der Gruppe bestehend aus dem 2-lodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und Verbindungen der allgemeinen Formel (I)
Figure imgb0014
 wobei das Kation (M+) (a) ein Ion der Alkalimetalle, bevorzugt Lithium, Natrium, Kalium, oder (b) ein Ion der Erdalkalimetalle, bevorzugt Calcium und Magnesium, oder (c) ein Ion der Übergangsmetalle, bevorzugt Mangan, Kupfer, Zink und Eisen, oder (d) ein Ammonium-Ion, bei dem gegebenenfalls ein, zwei, drei oder alle vier Wasserstoffatome, durch gleiche oder verschiedene Reste aus der Gruppe (C1-C4)-Alkyl, Hydroxy-(C1-C4)-Alkyl, (C3-C6)-Cycloalkyl, (C1-C4)-Alkoxy-(C1-C4)-alkyl, Hydroxy-(C1-C4)-alkoxy-(C1-C4)-alkyl, (C1-C6)-Mercaptoalkyl, Phenyl oder Benzyl substituiert sind, wobei die zuvor genannten Reste gegebenenfalls durch einen oder mehrere, gleiche oder verschiedene Reste aus der Gruppe Halogen, wie F, Cl, Br oder I, Nitro. Cyano, Azido, (C1-C6)-Alkyl, (C1-C6)-Haloalkyl, (C3-C6)-Cycloalkyl, (C1-C6)-Alkoxy, (C1-C6)-Haloalkoxy und Phenyl substituiert sind und wobei jeweils zwei Substituenten am N-Atom zusammen gegebenfalls einen unsubstituierten oder substituierten Ring bilden, oder (e) ein Phosphonium-Ion, oder (f) ein Sulfonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-sulfonium, oder (g) ein Oxonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-oxonium, oder (h) eine gegebenenfalls einfach oder mehrfach annellierte und/oder durch (C1-C4)-Alkyl substituierte gesättigte oder ungesättigte/aromatische N-haltige heterocyclische ionische Verbindung mit 1-10 C-Atomen im Ringsystem ist, bedeutet, und (B) ein oder mehrere Herbizide aus der Gruppe der (Sulfon)Amide bestehend aus:
beflubutamide, bromobutide, dimethenamide, dimethenamide-P, diphenamide, napropamide, pethoxamid, MT-5950, naptalam, propyzamide, diflufenican, etobenzanid, flufenacet, mefenacet, mefluidide, pentanochlor, picolinafen, propanil, N-phenylphtalamic acid,_acetochlor, alachlor, butachlor, dimethachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, propachlor, propisochlor, thenylchlor, asulam, carbaryl, carbetamide, chlorpropham, desmedipham, phenmedipham, propham, butylate, cycloate, dimepiperate, EPTC, esprocarb, methasulfocarb, molinate, orbencarb, pebulate, prosulfocarb, pyributicarb, thiobencarb, tri-allate, vernolate, amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsufluron-methyl-sodium, foramsulfuron, halosulfuron-methyl, imazosulfuron, iodosulfuron-methyl-sodium, mesosulfuron-methyl, metsulfuron-methyl, monosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron-methyl, trifloxysulfuron, triflusulfurorl-methyl, tritosulfuron, HNPC-C9908 (benzoic acid, 2-[[[[[4-methoxy-6-(methylthio)-2-pyrimidinyl]amino]carbonyl]amino]-sulfonyl]methylester), NC-330, NC-620, TH-547, flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam und pyroxsulam bedeutet. A herbicide combination containing components (A) and (B), wherein (A) one or more herbicides selected from the group consisting of the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and compounds of the general formula ( I)
Figure imgb0014
 in which the cation (M + ) (a) an ion of the alkali metals, preferably lithium, sodium, potassium, or (b) an ion of the alkaline earth metals, preferably calcium and magnesium, or (c) an ion of the transition metals, preferably manganese, copper, zinc and iron, or (d) an ammonium ion in which optionally one, two, three or all four hydrogen atoms are represented by identical or different radicals from the group consisting of (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkyl , (C 3 -C 6 ) -cycloalkyl, (C 1 -C 4 ) -alkoxy (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkoxy- (C 1 -C 4 ) -alkyl, (C 1 -C 6 ) -mercaptoalkyl, phenyl or benzyl, where the abovementioned radicals are optionally substituted by one or more, identical or different radicals from the group halogen, such as F, Cl, Br or I, nitro. Cyano, azido, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -haloalkyl, (C 3 -C 6 ) -cycloalkyl, (C 1 -C 6 ) -alkoxy, (C 1 -C 6 ) Haloalkoxy and phenyl are substituted and wherein in each case two substituents on the N-atom together if necessary form an unsubstituted or substituted ring, or (e) a phosphonium ion, or (f) a sulfonium ion, preferably tri - ((C 1 -C 4 ) alkyl) sulfonium, or (g) an oxonium ion, preferably tri - ((C 1 -C 4 ) alkyl) oxonium, or (h) a saturated or unsaturated / aromatic N-containing heterocyclic ionic compound having 1-10 C atoms in the ring system which may be mono- or poly-fused and / or substituted by (C 1 -C 4 ) -alkyl, means, and (B) one or more herbicides from the group of (sulfone) amides consisting of:
beflubutamide, bromobutide, dimethenamide, dimethenamide-P, diphenamide, napropamide, pethoxamide, MT-5950, naptalam, propyzamide, diflufenican, etobenzanide, flufenacet, mefenacet, mefluidide, pentanochlor, picolinafen, propanil, N-phenylphtalamic acid, _acetochlor, alachlor, butachlor , dimethachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, propachlor, propisochlor, thenylchlor, asulam, carbaryl, carbetamide, chlorpropham, desmedipham, phenmedipham, propham, butylate, cycloate, dimepiperate, EPTC, esprocarb, methasulfocarb, molinate, orbencarb, pebulate , prosulfocarb, pyributicarb, thiobencarb, tri-allates, vernolate, amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsufluron-methyl-sodium, foramsulfuron, halosulfuron -methyl, imazosulfuron, iodosulfuron-methyl-sodium, mesosulfuron-methyl, metsulfuron-methyl, monosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron-methyl, trifloxysulfuron, triflusulfurorl-methyl, tritosulfuron, HNPC-C9908 (benzoic acid , 2 - [[[[[4-methoxy-6- (methylthio) -2-pyrimidinyl] amino] carbonyl] amino] sulfonyl] methyl ester), NC-330, NC-620, TH-547, flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam and pyroxsulam. Herbizid-Kombination nach Anspruch 1, dadurch gekennzeichnet, dass als Komponente (A)
2-lodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-yl)carbamoyl]benzolsulfonamid und/oder Verbindungen der Formel (I).
in denen das Kation (M+) (a) ein Ion der Alkalimetalle, bevorzugt Lithium, Natrium, Kalium, oder (b) ein Ion der Erdalkalimetalle, bevorzugt Calcium und Magnesium, oder (c) ein Ion der Übergangsmetalle, bevorzugt Mangan, Kupfer, Zink und Eisen, oder (d) ein Ammonium-Ion, bei dem gegebenenfalls ein, zwei, drei oder alle vier Wasserstoffatome, durch gleiche oder verschiedene Reste aus der Gruppe (C1-C4)-Alkyl, Hydroxy-(C1-C4)-Alkyl, (C1-C4)-Cycloalkyl, (C1-C2)-Alkoxy-(C1-C2)-alkyl, Hydroxy-(C1-C2)-alkoxy-(C1-C2)-alkyl, (C1-C2)-Mercaptoalkyl, Phenyl oder Benzyl substituiert sind, wobei die zuvor genannten Reste gegebenenfalls durch einen oder mehrere, gleiche oder verschiedene Reste aus der Gruppe Halogen, wie F, Cl, Br oder I, Nitro, Cyano, Azido, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy, (C1-C2)-Haloalkoxy und Phenyl substituiert sind, und wobei jeweils zwei Substituenten am N-Atom zusammen gegebenfalls einen unsubstituierten oder substituierten Ring bilden, oder (e) ein quartäres Phosphonium-Ion, bevorzugt Tetra-((C1-C4)-alkyl)-phosphonium und Tetraphenyl-phosponium, wobei die (C1-C4)-Alkylreste und die Phenylreste gegebenenfalls einfach oder mehrfach mit gleichen oder verschiedenen Resten aus der Gruppe Halogen, wie F, Cl, Br oder I, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy, (C1-C2)-Haloalkoxy substituiert sind, oder (f) ein tertiäres Sulfonium-Ion, bevorzugt Tri-((C1-C4)-alkyl-sulfonium oder Triphenyl-sulfonium, wobei die (C1-C4)-Alkylreste und die Phenylreste gegebenenfalls einfach oder mehrfach mit gleichen oder verschiedenen Resten aus der Gruppe Halogen, wie F, Cl, Br oder I, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy, (C1-C2)-Haloalkoxy substituiert sind, oder (g) ein tertiäres Oxonium-Ion, bevorzugt Tri-((C1-C4)-alkyl)-oxonium, wobei die (C1-C4)-Alkylreste gegebenenfalls einfach oder mehrfach mit gleichen oder verschiedenen Resten aus der Gruppe Halogen, wie F, Cl, Br oder I, (C1-C2)-Alkyl, (C1-C2)-Haloalkyl, (C3-C4)-Cycloalkyl, (C1-C2)-Alkoxy, (C1-C2)-Haloalkoxy substituiert sind,, oder (h) ein Kation aus der Reihe der folgenden heterocyclischen Verbindungen, wie beispielsweise Pyridin, Chinolin, 2-Methylpyridin, 3-Methylpyridin, 4-Methylpyridin, 2,4-Dimethylpyridin, 2,5-Dimethylpyridin, 2,6-Dimethylpyridin, 5-Ethyl-2-methylpyridin, Piperidin, Pyrrolidin, Morpholin, Thiomorpholin, Pyrrol, Imidazol, 1,5-Diazabicyclo[4.3.0]non-5-en (DBN), 1,8-Diazabicyclo[5,4,0]undec-7-en (DBU) ist, enthalten ist oder enthalten sind.Herbicide combination according to claim 1, characterized in that as component (A)
2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-yl) carbamoyl] benzenesulfonamide and / or compounds of the formula (I).
in which the cation (M + ) (a) an ion of the alkali metals, preferably lithium, sodium, potassium, or (b) an ion of the alkaline earth metals, preferably calcium and magnesium, or (c) an ion of the transition metals, preferably manganese, copper, zinc and iron, or (d) an ammonium ion in which optionally one, two, three or all four hydrogen atoms are represented by identical or different radicals from the group consisting of (C 1 -C 4 ) -alkyl, hydroxy (C 1 -C 4 ) -alkyl , (C 1 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoxy- (C 1 -C 2 ) -alkyl, hydroxy (C 1 -C 2 ) -alkoxy- (C 1 -C 2 ) alkyl, (C 1 -C 2) -Mercaptoalkyl, phenyl or benzyl substituted, where the radicals mentioned above optionally substituted by one or more identical or different radicals from the group halogen, such as F, Cl, Br or I, nitro Cyano, azido, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 2 ) -Haloalkoxy and phenyl and in each case two substituents on the N atom together if desired form an unsubstituted or substituted ring, or (E) a quaternary phosphonium ion, preferably tetra - ((C 1 -C 4 ) alkyl) phosphonium and tetraphenyl-phosphonium, where the (C 1 -C 4 ) -alkyl radicals and the phenyl radicals optionally mono- or polysubstituted by identical or various radicals from the group halogen, such as F, Cl, Br or I, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) alkoxy, (C 1 -C 2 ) -haloalkoxy, or (F) a tertiary sulfonium ion, preferably tri - ((C 1 -C 4 ) -alkyl-sulfonium or triphenyl-sulfonium, where the (C 1 -C 4 ) -alkyl radicals and the phenyl radicals optionally mono- or polysubstituted by the same or various radicals from the group halogen, such as F, Cl, Br or I, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 - C 2 ) alkoxy, (C 1 -C 2 ) haloalkoxy, or (g) a tertiary oxonium ion, preferably tri - ((C 1 -C 4 ) alkyl) oxonium, where the (C 1 -C 4 ) -alkyl radicals are optionally mono- or polysubstituted by identical or different radicals from the group consisting of halogen such as F, Cl, Br or I, (C 1 -C 2 ) -alkyl, (C 1 -C 2 ) -haloalkyl, (C 3 -C 4 ) -cycloalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 2 ) Haloalkoxy are substituted, or (h) a cation from the series of the following heterocyclic compounds, such as pyridine, quinoline, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2,4-dimethylpyridine, 2,5-dimethylpyridine, 2,6-dimethylpyridine, 5 -Ethyl-2-methylpyridine, piperidine, pyrrolidine, morpholine, thiomorpholine, pyrrole, imidazole, 1,5-diazabicyclo [4.3.0] non-5-ene (DBN), 1,8-diazabicyclo [5,4,0] undec-7-en (DBU), is included or included. Herbizid-Kombination nach Anspruch 1, dadurch gekennzeichnet, dass als Komponente (A) das 2-lodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzolsulfonamid und/oder Verbindungen der Formel (I), in denen das Kation (M+)
ein Natrium-Ion, ein Kalium-Ion, ein Lithium-Ion, ein Magnesium-Ion, ein Calcium-Ion, ein NH4 +-Ion, ein (2-Hydroxyeth-1-yl)ammonium-Ion, Bis-N,N-(2-hydroxyeth-1-yl)ammonium-lon, Tris-N,N,N-(2-hydroxyeth-1-yl)ammonium-Ion, ein Methylammonium-Ion, ein Dimethylammonium-Ion, ein Trimethylammonium-Ion, ein Tetramethylammonium-Ion ein Ethylammonium-Ion, ein Diethylammonium-Ion, ein Triethylammonium-Ion, ein Tretraethylammonium-Ion ein Isopropylammonium-Ion, ein Diisopropylammonium-Ion, ein Tetrapropylammonium-Ion, ein Tetrabutylammonium-Ion, ein 2-(2-Hydroxyeth-1-oxy)eth-1-yl-ammonium-Ion, ein Di-(2-hydroxyeth-1-yl)-ammonium-lon, ein Trimethylbenzylammonium-Ion, ein Tri-((C1-C4)-alkyl)-sulfonium-Ion, oder ein Tri-((C1-C4)-alkyl)-oxonium-Ion, ein Benzylammonium-Ion, ein 1-Phenylethylammonium-Ion, ein 2-Phenylethylammonium-Ion, ein Diisopropylethylammonium-Ion, ein Pyridinium-Ion, ein Piperidinium-Ion, ein Imidazolium-Ion, ein Morpholinium-Ion, ein 1,8-Diazabicyclo[5,4,0]undec-7-enium-Ion ist, enthalten ist oder enthalten sind.A herbicidal combination according to claim 1, characterized in that as component (A) the 2-iodo-N - [(4-methoxy-6-methyl-1,3,5-triazin-2-yl) carbamoyl] benzenesulfonamide and / or or compounds of the formula (I) in which the cation (M + )
a sodium ion, a potassium ion, a lithium ion, a magnesium ion, a calcium ion, an NH 4 + ion, a (2-hydroxyeth-1-yl) ammonium ion, Bis-N, N- (2-hydroxyeth-1-yl) ammonium ion, Tris-N, N, N- (2-hydroxyeth-1-yl) ammonium ion, a methyl ammonium ion, a dimethyl ammonium ion, a trimethyl ammonium ion , a tetramethylammonium ion, an ethylammonium ion, a diethylammonium ion, a triethylammonium ion, a tretraethylammonium ion, an isopropylammonium ion, a diisopropylammonium ion, a tetrapropylammonium ion, a tetrabutylammonium ion, a 2- (2- Hydroxyeth-1-oxy) eth-1-yl ammonium ion, a di- (2-hydroxyeth-1-yl) ammonium ion, a trimethylbenzylammonium ion, a tri - ((C 1 -C 4 ) - alkyl) sulfonium ion, or a tri - ((C 1 -C 4 ) alkyl) oxonium ion, a benzylammonium ion, a 1-phenylethylammonium ion, a 2-phenylethylammonium ion, a diisopropylethylammonium ion , a pyridinium ion, a piperidinium ion, an imidazolium ion, a morpholinium ion, a 1,8-diazabicyclo [5,4,0] undec-7-ene um-ion is, is contained or contained. Herbizid-Kombination nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass als Komponente (B) eine oder mehrere der Verbindungen aus der nachfolgend genannten Gruppe bestehend aus: Dimethenamide, dimethenamide-P, napropamide, pethoxamid, propyzamide, diflufenican, flufenacet, mefenacet, picolinafen, propanil, acetochlor, alachlor, butachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, thenylchlor, asulam, carbetamide, desmedipham, phenmedipham, esprocarb, molinate, prosulfocarb, thiobencarb, amidosulfuron, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flupyrsulfuron-methyl-sodium, foramsulfuron, iodosulfuron-methyl-sodium, mesosulfuron-methyl, nicosulfuron, orthosulfamuron, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, trifloxysulfuron (sodium), flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl, florasulam, metosulam und penoxdulam enthalten ist oder enthalten sind.A herbicidal combination according to any one of claims 1 to 3, characterized in that as component (B) one or more of the compounds from the following group consisting of: dimethenamides, dimethenamid-P, napropamide, pethoxamid, propyzamide, diflufenican, flufenacet, mefenacet , picolinafen, propanil, acetochlor, alachlor, butachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, thenylchlor, asulam, carbetamide, desmedipham, phenmedipham, esprocarb, molinate, prosulfocarb, thiobencarb, amidosulfuron, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flupyrsulfuron -methyl-sodium, foramsulfuron, iodosulfuron-methyl-sodium, mesosulfuron-methyl, nicosulfuron, orthosulfamuron, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, trifloxysulfuron (sodium), flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl, florasulam, metosulam and penoxdulam. Herbizid-Kombination nach einem der Ansprüche 1 bis 4, enthaltend einen wirksamen Gehalt an Komponenten (A) und (B) und/oder eine oder mehrere weitere Komponenten aus der Gruppe agrochemischer Wirkstoffe anderer Art, im Pflanzenschutz übliche Zusatzstoffe und Formulierungshilfsmittel.A herbicidal combination according to any one of claims 1 to 4, containing an effective content of components (A) and (B) and / or one or more further components from the group of agrochemical active ingredients of another kind, additives customary in crop protection and formulation auxiliaries. Verfahren zur selektiven Bekämpfung von unerwünschtem Pflanzenwuchs, worin die Herbizide (A) und (B) der Herbizid-Kombination, definiert gemäß einem oder mehreren der Ansprüche 1 bis 5, gemeinsam oder getrennt appliziert werden, vorzugsweise auf die Fläche auf der die Pflanzen wachsen.A method for the selective control of undesired plant growth, wherein the herbicides (A) and (B) of the herbicide combination, defined according to one or more of claims 1 to 5, are applied together or separately, preferably on the area on which the plants grow. Verfahren nach Anspruch 6 zur selektiven Bekämpfung von unerwünschtem Pflanzenwuchs im Vorauflauf oder im Nachauflauf in Weizen (Hart- und Weichweizen), Mais, Soja, Zuckerrübe, Zuckerrohr Baumwolle, Reis, Bohnen, Flachs, Gerste, Hafer, Roggen, Triticale, Raps, Kartoffel und Hirse (Sorghum). Flachs, Weideland und Grün-/RasenflächenA method according to claim 6 for the selective control of undesirable plant growth in the pre-emergence or postemergence in wheat (hard and soft wheat), corn, soybeans, sugarbeet, sugarcane, cotton, rice, beans, flax, barley, oats, rye, triticale, rapeseed, potato and millet (sorghum). Flax, pasture and green / lawn areas Verwendung der nach einem der Ansprüche 1 bis 5 definierten Herbizid-Kombination zur selektiven Bekämpfung von unerwünschtem Pflanzenwuchs.Use of the herbicide combination as defined in any one of claims 1 to 5 for the selective control of undesired plant growth.
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