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EP1928992A1 - Produits de consommation a odeurs multiples - Google Patents

Produits de consommation a odeurs multiples

Info

Publication number
EP1928992A1
EP1928992A1 EP06776776A EP06776776A EP1928992A1 EP 1928992 A1 EP1928992 A1 EP 1928992A1 EP 06776776 A EP06776776 A EP 06776776A EP 06776776 A EP06776776 A EP 06776776A EP 1928992 A1 EP1928992 A1 EP 1928992A1
Authority
EP
European Patent Office
Prior art keywords
methyl
weight
acetate
acid
agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06776776A
Other languages
German (de)
English (en)
Inventor
Georg Meine
Walter Hofstetter
Hermann Jonke
Piotr Malecki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1928992A1 publication Critical patent/EP1928992A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the present invention relates to a perfume-containing consumer product in which at least two differently fragrant perfume oils are contained, which are not uniformly distributed in relation to each other in the product
  • the consumer product may be any commercially applicable, perfumed product, but especially to products from the Range of detergents and cleaners and cosmetics
  • fragrances in typical consumer products such as detergents usually serves two different purposes.
  • the products should be scented as such, on the other hand, the objects on which the products are to be scented. or cleaning agents should give the freshly cleaned surfaces or the freshly washed laundry a "freshly cleaned" olfactory impression, which should last as long as possible, on the other hand, the sometimes very strong odor of detergents and cleaners should be covered
  • the fragrance of the consumer product eg a washing or cleaning agent
  • a washing or cleaning agent ultimately also provides a welcome opportunity for differentiation in the face of an ever more confusing supply of products, for example in the field of detergents and cleaners
  • the scent fulfills very specific consumer preferences.
  • a variety of scents are commonly used, such as almond and honey, peach and lime blossom, wild rose, orchid and lotus flower. or, for example, "white tulip and delicate mint", etc., so that the consumer can then select the product according to his individual sensitivities and preferences
  • the spontaneity and variety of features remains problematic, but the storage of his products, eg detergents and cleaners, he likes to vary his textile soft powder scent more often he has to store a multitude of textile softeners at home A changing perfume with different fragrance impressions So far, the consumer can only be reached by using different products, which he must stockpile
  • the object underlying the present invention is therefore to be seen to provide the consumer with a need for fragrance variety an improved offer
  • a perfume-containing consumer product preferably washing or cleaning agent or cosmetic agent, which contains at least two differently scented perfume oils which are not uniformly distributed in the product in relation to one another
  • a perfume-containing consumer product preferably washing or cleaning agent or cosmetic agent
  • the product comprises ingredients from the field of detergents, detergents and / or cosmetics
  • a conventional detergent or cleaning agent is characterized by a single and uniform characteristic odor. This is due to the fact that one and the same perfume oil is possible If, for example, two cups of washing powder are removed from a conventional detergent package with a beaker, the samples contain one and the same perfumeol in the context of normal production fluctuations. This is of course true even if the product is eaten, for example, on an almond Honey odor is directed There is then only exactly one single consistent odor impression over the entire medium
  • inventive consumable product preferably detergents or cleaners
  • inventive consumable product is characterized by the fact that it contains more than one perfumeol, ie at least two differently perfumed perfumes These are not evenly distributed in the product in relation to each other goods they uniformly distributed in relation to each other in the product
  • perfumes contained are not uniformly distributed in the product, there results a qualitatively and, if necessary, quantitatively uneven product scenting with respect to the entire product concerned, preferably washing - or cleaning agent
  • the product according to the invention contains at least 2, 3, 4, 5 or 6 or even more differently perfumed perfume oils which, as will be readily apparent, differ in the number of perfume oils present and differ in odor are not evenly distributed in the product in relation to each other
  • a model for powder detergents would be, for example, the "layer model".
  • Detergent according to the "layer model” follows the principle of layered construction.
  • 11 different washing powders can be prepared in a conventional manner Washing powder 1 contains only perfume 1 and washing powder 11 contains perfumeol 2 only
  • the washing powders 2-10 contain both perfumeol 1 and perfumeol 2, but containing detergent powder 2 in different amounts, based on the total perfume contained 90% by weight of perfume 1 and 10% by weight of perfume 2 perfumeol 1 and 20% by weight of perfumeol 2, washing powder 4 70% by weight of perfumeol 1 and 30% by weight of perfume 2, etc.
  • Up to washing powder 10 which contains 10% by weight of perfumeol 1 and 90% by weight of perfumeol 2
  • washing powders are now stacked one above the other in a washing powder packet in the order of their numbering, d h the bottom layer forms washing powder 1, then comes 2 3, 4, etc. up to washing powder 11 which rests on top
  • a preferred embodiment of the invention is then that the consumption product is constructed in a layered form, wherein at least the adjoining layers are scented differently with respect to each other
  • a model for liquid consumer products were liquid detergents containing solids, for example, in the form of capsules, microcapsules or speckles.
  • the solids are each perfume carriers and distributed in the liquid medium, the distribution being static, which means that the solids in the
  • the detergent contains at least two different types of solids, wherein genus 1 contains perfume 1 and genus 2 contains perfume 2
  • genus 1 contains perfume 1
  • genus 2 contains perfume 2
  • the classes of particles are now unevenly distributed in the liquid detergent, so that the perfume in proportion In the case of product removal, at least gradually different fragrance impressions must always result
  • the product according to the invention has essentially a liquid form.
  • a product according to the invention which is essentially in liquid form contains suspended solids which advantageously carry perfume oil (e) is in liquid form ", to clarify that it may also contain solids
  • a further embodiment relates to so-called multi-phase systems (preferably 2 liquid phases), for example 2-phase Re ⁇ mger or detergent, which are characterized by one (or more) horizontal separation line
  • multi-phase systems preferably 2 liquid phases
  • 2-phase Re ⁇ mger or detergent which are characterized by one (or more) horizontal separation line
  • In the upper phase z is predominantly perfumeol 1
  • in the lower phase z B contain predominantly perfumeol 2, preferably in one of the phases, in particular in both phases, are suspended solids containing which carry perfume
  • the invention provides a wide range of possibilities for scents of products, such as detergents or cleaning agents
  • the differently fragrant perfumes may be distributed, for example, completely randomly in the product, taking into account the proviso that they are not evenly distributed in relation to each other in the product
  • the perfumes may therefore be distributed unevenly in the product in an unsystematic manner
  • the differently fragrant perfume oils can, for example, also be distributed in a very systematic manner unevenly in the product, preferably washing or cleaning agents, as outlined, for example, in the layered model.
  • the perfume oils can be distributed unevenly in the product in a systematic manner
  • perfumeol preferably means self-contained perfume compositions, which are commonly used for product scenting and are fragrant in particular according to human discretion. This is illustrated by an example. If a professional, for example, makes a fragrant shower gel, he usually does not only add one to him Such a collective usually consists of a large number of individual fragrances, for example more than 10 or 15, preferably up to 100 or more. These aggregates cooperatively form a desired fragrant, harmonious substance Fragrance picture Such a collective of fragrant substances, a fragrance composition which may possibly also contain perfume-like auxiliaries, is described according to the invention by the term perfumeol.
  • a perfumol can also be obtained by mixing two or more P.sup arfumole can be formed, but after the mixture (in the product) not the individual perfumes are perceived separately from each other, ie side by side, but form a common, uniform fragrance collective
  • a shower gel unfolds a single characteristic Fragrance, eg lemon or a single mixed odor It does not unfold several odors separately. This would only be realized if two or more different shower gels were used separately
  • the uniform scent of the conventional remedies is a forced consequence of the fact that the perfume contained are evenly distributed in the product relative to each other
  • a perfume according to the invention consists of at least 2, preferably at least 3, advantageously at least 4 different fragrances, which together develop a preferably fragrant odor image
  • a perfume oil according to the invention can therefore contain individual perfume compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons.
  • Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate ( DMBCA), phenylethyl acetate, benzyl acetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsulfacylate, cyclohexylsalicylate, floramate, melusate and jasmecyclate Benzyl ethyl ether and ambroxan pay to the ethers, while the aldehydes z B are the linear
  • the perfume oils may also contain natural fragrance mixtures, such as those obtainable from vegetable sources, such as pine, citrus, jasmine, patchouli, rose or ylang-ylang oil. Also suitable are muscatel salvia, chamomile oil, clove oil, Mehssenol, mint oil, cinnamon leaf lotion, linden-blutenol, juniper berry oil, vetiverol, ohbanumol, galbanumol and labdanumol, and orange-blutenol, nerohol, orange peel sol and sandalwood oil
  • a fragrance In order to be perceptible, a fragrance must be volatile, in addition to the nature of the functional groups and the structure of the chemical compound, the molecular weight also plays an important role So most fragrances have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and more represent an exception Due to the different odor of fragrances, the smell of a fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in top note, middle note or body and base note (end note or dry out)
  • Adhesive-resistant fragrances which are advantageously usable in the perfume oils in the context of the present invention are, for example, the essential oils such as angelica root aol, anisole, arnica-distutenol, basilikumol bayol, champacablutenol, noble-tannol, noble-pine cone oil, elemiole, eucalyptus oil.
  • fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures in the perfume oils to these compounds pay the compounds listed below and mixtures of these Ambrettolid, ⁇ -Amylz ⁇ mtaldehyd, anethole, anisaldehyde, Anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, benzoic acid ethyl ester, benzophenone, benzyl alcohol, borneol, bornyl acetate, ⁇ -bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, hexyl acetate, geranyl acetate, Geranyl formate
  • fragrances which can be used advantageously in the perfume oil in the present invention, pay in particular the lower-boiling fragrances natural or synthetic origin, which can be used alone or in mixtures
  • easily volatile fragrances are alkyl isothiocyanates (Alkylsenfole), butanedione , Limonene, linalool, malate acetate and propionate, menthol, menthone, methyl-n-heptenone phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal All of the aforementioned fragrances can be used alone or as a mixture in the perfume oils according to the present invention with the advantages already mentioned
  • fragrances from the group of allyl alcohol esters, esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof may be contained in the perfume
  • allyl alcohol esters are in particular allylamyl glycolate allyl anthranilate allyl benzoate, allyl butyrate, allyl caprate, allyl caproate, allyl cinnamate, allyl cyclohexane acetate, allyl cyclohexane tyrate, allyl cyclohexane propionate, allyl heptoate, allyl nonanoate , Allylsalicylat, Amylcmnamylacetat, Amylcin- namylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate, cinnamylformiat Geranylacetoacetat, geranyl benzoate, Geranylcinnamat, Methallylbut
  • esters of Secondary Alcohols are in particular ortho-tert -Amylcyclohexylacetat, Isoamylbenzylacetat, secondary n-amyl butyrate, Amylvinylcarbinylacetat Amylvinylcarbinylpropionat, cyclohexyl salicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionat, nylsalicylat isobornyl acetate, isobornyl, Isobornylvalerat, Frutene, 2-methylbutene 2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2
  • esters of tertiary alcohols are those in which three H atoms are substituted by organic radicals R 1 , R 2 , R 3 at the ⁇ -C atom which carries the OH group (general formula R 1 R 2 R 3 C-OH)) are tertiary amyl acetate, caryophyllene acetate, cedryl acetate, cedryl acetate, dihydromyrcenyl acetate, dihydrotinyl acetate, dimethylbenzyl carbinyl acetate, dimethylbenzylcarbinyl isobutyrate, dimethylheptenyl acetate, dimethylheptenyl formate, dimethylheptenyl propionate, dimethylheptenyl-iso-butyrate, dimethylphenylethylcarbinyl acetate, dimethylphenylethylcarbinyl isobutyrate, dimethylphenylethylcarbinyl acetate, dimethylphen
  • fragrance esters may be esters of allylic and secondary or allylic and tertiary alcohols, in particular amylvinylcarbamylacetate, amylvinylcarbinylpropionate, hexylvinylcarbmylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate , Linallyl carproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Unallylfor- mat, Linallylheptoat, L ⁇ nallyl-N-methylanthran ⁇ lat, Linallylmethyltiglat, Linallylpelargonat, Llinallylphenyl- acetate, Linallylpropionat, Lmallylpyruvat, Linallylsalicylat, L ⁇ nallyl-n-valerate, L ⁇ nally
  • C Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone benzylideneacetophenone, alphaisomethylionone, 4- (2,6,6-t-methyl-1-) cyclohexen-1-yl) 3-buten-2-one, beta-damascone (1- (2,6,6-tri-methylcyclohexen-1-yl) -2-buten-1-one), damascenone (1- (2,6 , 6-tri-methyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), delta Damascone (1- (2,6,6-trimethyl-3-cyclohexene-1-yl) 2-butene-1-one), alpha-ionone (4- (2,6,6-tri-
  • Acetals are geminal diethers of the general formula R 1 CH (OR 2 ) (OR 3 )
  • Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-d ⁇ - ⁇ so-amyl acetal, acetaldehyde-dipentanedioacetal, acetaldehyde d ⁇ - n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, cinnamic aldehyde dimethyl acetal, acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde-1-yl-amyl acetal, acetal
  • Ketals are geminal diethers of the general formula R 1 R 2 C (OR 3 ) (OR 4 ) Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be present in the perfume of the invention
  • condensation products of amines and aldehydes are amandsaldehyde methylanthranilate, aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde-methyl anthranilate), vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalanyl anthranilate, hydroxycitronellaldehyde-anthranilate .
  • Condensation products of amines and aldehydes can preferably in the inventive
  • fragrances such as Adoxal (2,6,10-T ⁇ methyl-9-undecen-1-al) amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2,2 , 3-trimethyl-3-cyclopent-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexene-1-ol cetalox (dodecahydro-3A, 6,6 , 9A-tetramethyl-naphtho [2.1 B] -furan) cis-3-hexenylacetate, cis-3-hexenyl- cecallate, citronellol, coumarin, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde),
  • Adoxal 2,6,
  • At least one of the contained perfumes may also be combined with a perfume fixative. It is believed that perfume fixatives may slow the evaporation of the high volatile levels of perfume, which may be advantageous in the present invention
  • At least one of the perfumes contained comprises a perfume fixative, preferably in the form of diethyl phthalates, musk (derivatives) and mixtures thereof, the amount of fixative preferably being from 1 to 55% by weight, advantageously from 2 to 50% by weight more preferably 10 to 45% by weight, in particular 10 to 40% by weight, of the total amount of the particular perfume concerned
  • At least one of the perfume oils contained contains a viscosity of liquids, in particular perfume-increasing agent preferably PEG (polyethylene glycol), advantageously having a molecular weight of 400 to 2000, wherein the viscosity-increasing agent preferably in amounts of 0, 1 to 20% by weight more advantageously from 0.15 to 10% by weight, in a further advantageous manner from 0.2 to 5% by weight, in particular from 0.25 to 3% by weight, based on the total amount of the particular perfume concerned
  • PEG polyethylene glycol
  • At least one perfume oil contains a viscosity-increasing agent, preferably polyethylene glycols (PEG for short), which can be described by the following general formula
  • the polymerization can n of about 5 to> 100,000, corresponding to molecular weights from 200 to 5,000,000 gmol ⁇ vary the products with molecular weights below 25,000 gmol 1 are referred to as actual polyethylene glycols, while high molecular weight products in the literature often as polyethylene oxide ( PEOX for short).
  • the polyethylene glycols preferably used may have a linear or branched structure, with linear polyethylene glycols in particular being preferred, and end-capped
  • the particularly preferred polyethylene glycols include those having relative molecular weights between 400 and 2000. Polyethylene glycols which are present in a liquid state at room temperature and a pressure of 1 bar can also be used in particular. Polyethylene glycol having a relative molecular mass of 200 is especially important here , 400 and 600 the speech
  • top note As already mentioned before, the structure of a perfume composition is classified into “top note”, “middle note or body” and “base note” (end note or dry out).
  • the top note Tete
  • the middle note (Bouqet, Corporation, Coeur, heart note, body) comprises essentially moderate volatile fragrances, preferably mostly flowery character and the base note (rear, smell) comprises substantially little volatile perfumes, essentially determine the basic character (Leitgeruch) of the perfume
  • the top note essentially determines the first phase of the perfume process of a perfume or a perfume scented agent, such as a detergent. It plays the decisive role in the first impression of the scent experience, ie when the detergent pack is opened and when the scent is released Filling the detergent into the washing machine
  • the top note is essentially intended to attract attention and interest in the perfume and thus in the scented medium excite them, which is why they essentially represents a mixture of light volatiles, although in part even notes of the heart and base already play a role in the first fragrance phase
  • Typical ingredients of the top note are, for example, the Agrumenole, fruit notes, lavender, Dihydomyrcenol or rose oxide The skilled artisan knows a variety of other components from the daily intuition or can take these from the relevant technical literature.
  • the second, middle phase of the perfume process of a perfume or perfume scented agent, such as a detergent is determined by the heart note.
  • This is preferably formed
  • a blend of rounder, more complex notes that give a perfume fullness, character, and direction can be dominated by floral components such as lily-of-the-valley, jasmine, or rose.
  • many of the spicy ingredients of a perfume, such as Eugenol can be found here (indicating The person skilled in the art is familiar with a large number of further constituents from the daily intuition or can take these from the relevant specialist literature
  • the base note of the perfume determines the character of the fragrance It adheres very long on the fragranced objects and is composed mainly of heavier warmer notes For example, you can a precious wood base with isolated odorants of other Holzer and z B also combine with musk fragrances and / or an animal complex and predestined base notes such as patchouli and vanilla
  • the perfume compositions are generally created, whereby a perfume of complex structure can even consist of several hundred individual components.
  • a perfume of complex structure can even consist of several hundred individual components.
  • the notes of one and the same perfume differ with regard to their quantitative weighting, preferably
  • the headnote is weighted higher in terms of quantity than the middle note and the base note, wherein the two lower-weighted notes may be substantially equally weighted to one another or one of the lower-weighted notes is weighted higher than the other, or
  • the middle note is weighted quantitatively higher than the top note and base note, wherein the two lower weighted notes may be substantially equally weighted to each other or one of the lower weighted notes is weighted higher than the other, or (c) the base note is weighted quantitatively higher than the top note and middle note, wherein the two lower-weighted notes may be substantially equally weighted to each other or one of the lower-weighted notes is weighted higher than the other
  • One grade, quantitatively more highly weighted than another means that the total mass of fragrances forming the high weighted note is greater than the total mass of fragrances forming the lower weighted note, advantageously at least 10% by weight, preferably at least 20% % By weight, in particular at least 30% by weight, based on the total mass of the respective perfume composition concerned
  • the notes of at least two different perfumes differ with regard to their quantitative weighting, preferably
  • the middle note of perfumeol 1 is weighted quantitatively higher than the middle note of perfumeol 2, or vice versa, and / or
  • the total mass of the fragrances of one perfume forming the high weighted note is greater than the total mass of the less weighted fragrances of the other perfume, advantageously at least 10 wt. %, preferably at least 20% by weight, in particular at least 30% by weight, based on the respective total mass of the particular perfume concerned
  • all notes of the perfume composition are weighted substantially equally
  • the present invention enables the person skilled in the art to have greater freedom in the scenting of products, enabling them to produce products with a completely novel scent profile.
  • the perfume molecules to be used comprise very specific odor notes Purpose of the inventive product according to a preferred embodiment, in particular fragrances
  • almond-like odor such as preferably benzaldehyde, pentanal, heptenal 5-methylfurfural methylbutanal furfural and / or acetophenone or
  • apple-like odor preferably (S) - (+) - ethyl 2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) - ⁇ -damascone, heptyl-2-methyl butyrate, Methyl 3-methylbutanoate, 2-hexenalpentyl-methyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
  • apple peel-like odor such as preferably ethyl hexanoate, hexyl butanoate and / or hexyl hexanoate or
  • apricot-like odor preferably ⁇ -undecalactone, or
  • banana-like odor such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
  • bitter almond-like odor such as preferably 4-acetyltoluene or
  • blackcurrant-like odor such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
  • citrus-like odor preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, ⁇ -p-dimethylstyrene, p-cymenol, nonanal, ⁇ -cube level,
  • Z -methylene oxime, cis-6-ethenyl-tetrahydro-2,2, 6-tri methylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrohnalool, 6 (10) -D ⁇ hy- dromyrcenol, dihydromyrcenol, ß-Farnesen, (Z) - ⁇ -Farnesen, (Z) -Oc ⁇ men, (E) -L ⁇ monenox ⁇ d Dihy- droterpinylacetat, (+) - Lmmonen, (Epoxymethylbutyl) -methylfuran and
  • cocoa-like odor such as preferably dimethylpyrazine, butylmethyl butyrate and / or methyl butanal or
  • coconut-like odor such as preferably ⁇ -octalactone, ⁇ -nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 ( 3H) -one, 5-butyld ⁇ hydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or ⁇ -decalactone or
  • (K) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentad ⁇ on and / or 4-heptenal or
  • (I) flower-like odor preferably benzyl alcohol, phenylacetic acid, trimellal, p-anhydyl alcohol, hexanol, (E, E) -famesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-ep ⁇ - ⁇ -eudesmol, nerol oxide, ethyldihydrocinnamate, ⁇ -dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -OClumen, cetyl alcohol, nerolidol, ethyl (E) -cnamenate, Elemicin, Pinocarveol, ⁇ -B ⁇ sabolol, (2R, 4R) tetrahydro-4-
  • Fruit odor such as ethylphenyl acetate, geranyl valerate, ⁇ -heptalactone, ethyl propionate, diethyl acetal, geranyl butyrate, ethyl heptylate, ethyloctanoate, methylhexanoate, dimethylheptenalone, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, ethylamine 2-butenalmethylnonanedione, linalyl acetate, methylaryanate, ammonium oxide, hdrocinnamiccohol, dimethylsuccinate, ethylhexanoate, ethylmethylpyrazine, nylate, ctronellylbutyrate, heylacetate, nonylacetate, butylmethylbutyrate, pentenal
  • Geranium-like odor such as preferably geraniol, (E, Z) -2,4-nonad ⁇ enal, octadienone and / or o-xylene or
  • grape-like odor such as preferably ethyl decanoate and / or hexanone or
  • grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenyl-cyclo [4 4 0] dec-1-en-3-one and / or p-menthenethol or
  • grassy odor such as preferably 2-Ethylpyr ⁇ d ⁇ n, 2,6-Dmethylnaphthalen, hexanal and / or (Z) -3-hexenol or
  • Creeping odor preferably octanone, hexyloctanoate, caryophyllene oxides, methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, ⁇ -metabolol, pipetol, ⁇ -selenoene, ⁇ -cubebenzene, p-menth-1-en-9-ol , I S.S. ⁇ .-Tetramethyl - ' ⁇ - oxabicyclododeca ⁇ dienes, T-muurolol, (-) - Cube- nol, Levomenol, Ocimene, ⁇ -Thujene, p-Menth-1-en-9 -yl acetate, dehydrocarveol, Artemisia alcohol, ⁇ -Muurolene, hydroxypentanone (Z) -Oc ⁇ mene, ß-ele
  • honey-like odor preferably ethyl cinnamate, ⁇ -phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, ⁇ -damascenone, ethyl (E) -naminate, 2-phenylethyl alcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
  • (x) jasmine-like odor preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
  • (y) lavender-like odor preferably lmalyl valerate and / or linalool or
  • (dd) melon-like odor, preferably dimethylheptenal or
  • (ff) Pain-like odor, preferably 5-methyl- (E) -2-hepten-4-one, ⁇ -heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4-heptad ⁇ enal , 3-octenone hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
  • peppermint-like odor preferably methyl salicylate and / or I-menthol or
  • Pine-like odor preferably ⁇ -p-dimethylstyrene, ⁇ -pyrene, bornyl benzoate, ⁇ -terpinene, dihydroterpinyl acetate and / or ⁇ -pinene or
  • pineapple-like odor preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
  • Rose-like odor preferably ⁇ -phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl) 1-propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethylalcohol, citronellyl valerate and / or citronellyhsobutyrate, or
  • spearmint-like odor preferably carvylacetate and / or carveol, or
  • vanilla-like odor preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
  • fragrances may preferably be contained in the perfume oil according to the invention. They are highly suitable, in particular, for the scenting of washing, cleaning or care compositions or cosmetic agents
  • perfume alcohols which are preferably selected from acetovanillon, allylamyl glycolate, allyhsoamyl glycolate, ⁇ -Amylc ⁇ nammylalkohol, anisyl alcohol, benzoin, benzyl alcohol, benzyl salicylate, 1-butanol, butyl lactate, 2-t-butyl-5-methylphenol, 2- t-butyl-6-methylphenol, carvacrol, carveol, 4-carvomenthenol, cedrol, cetyl alcohol, cinnamic alcohol, citronellol, o-cresol, m-cresol, p-cresol
  • At least one preferably at least two, advantageously at least three, in particular at least four of the perfume contained in each case at least one, preferably at least two advantageously at least three, more preferably at least four, in an even more advantageous manner contain at least five, in particular at least six fragrances with carbonyl function, which are preferably selected from 4-acetoxy-3-pentyl-tetrahydropyran, Allylcinnamat AIIyI 2-ethyl butyrate, Allylcyclohexanepropionat, allylheptanoate, allylhexanoate, allyl isovalerate, allylnonanoate, allyloctanoate, allylphenoxyacetate, allylphenylacetate, allylpropionate, ⁇ -Amylc ⁇ nnamylacetat, amyloctanoate, anisylacetate, anisylphenylacetate ,
  • the product contains certain minimum values of perfume, namely at least 0.05% by weight, advantageously at least 0.1% by weight, in a considerably advantageous manner at least 0.15% by weight, more preferably at least 0, 2% by weight, in a further advantageous manner at least 0.25% by weight, more preferably at least 0.3% by weight, very preferably at least 0.35% by weight, in a particularly advantageous manner at least 0 4% by weight % in a particularly advantageous manner at least 0.45% by weight, in a significantly advantageous manner at least 0.5% by weight, in a very advantageously advantageous manner at least 0.55% by weight in extremely advantageous At least 0.6% by weight, most advantageously at least 0.65% by weight, in excessively more than preferably at least 0.7% by weight, in an exceptionally advantageous manner at least 0.75% by weight, in an exceptionally advantageous manner at least 0.8% by weight, in an extremely advantageous manner at least 0.85% by weight, in particular at least 0.9% by weight of perfume, based on the total product
  • the product contains relatively large amounts of perfume, namely at least 1% by weight, advantageously at least 2% by weight, in a considerably advantageous manner at least 5% by weight, more preferably at least 10% by weight, in a further advantageous manner at least 13 wt%, more preferably at least 14 wt%, most preferably at least 15 wt%, most preferably at least 16 wt%, most preferably at least 17 wt%, in substantial advantageously at least 18% by weight, very advantageously at least 19% by weight, in particular at least 20% by weight of perfume, based on the entire product
  • perfume namely at least 1% by weight, advantageously at least 2% by weight, in a considerably advantageous manner at least 5% by weight, more preferably at least 10% by weight, in a further advantageous manner at least 13 wt%, more preferably at least 14 wt%, most preferably at least 15 wt%, most preferably at least 16 wt%, most preferably at least 17 wt%, in substantial advantageously at least 18% by
  • the product contains certain maximum levels of perfumeol. namely not more than 15% by weight, advantageously not more than 10% by weight, in a considerably advantageous manner not more than 9% by weight, more preferably not more than 8% by weight, more preferably not more than 7% by weight %, more advantageously not more than 6% by weight, very advantageously not more than 5% by weight, in a particularly advantageous manner not more than 4.5% by weight, and in a particularly advantageous manner not more than 4% by weight, in a significantly advantageous manner not more than 3.5% by weight, in particular not more than 3% by weight of perfume, based on the total product
  • the ratio of perfume 1 to perfume 2 is more than 1/1, but less than 6/1, preferably less than 5/1, advantageously less than 4/1, more preferably less than 3/1, even more advantageously less than 2/1, especially less than 3/2
  • the perfumes contain less than 8, advantageously less than 7, more advantageously less than 6, more preferably less than 5, more preferably less than 4, even more preferably less than 3, preferably less than 2, especially no fragrances from the list Amylcinnamal, Amylcinnamylalkohol, Benzylalkohol, Benzylsalicylat, Cinnamylalkohol, Cmnamal, Citral, Cumarin, Eugenol, Geraniol, Hydroxycitronellal Hydroxymethylpentylcyclohexencarboxaldehyd, Isoeugenol, Anisylalkohol, Benzylbenzoat, Benzylcmnamat, Citronellol, Farnesol, Hexylcmnamaldehyd, Lilial, d -Lomonen, lmalool, methylheptmcarbonate, 3-methyl-4- (2,6,6-t-methyl-2-cyclohexen-1-y
  • the use concentrations hardly contain the amount of fragrance which could cause skin allergy, but it may also be desirable to include certain substances, which may come from a third party allergenic potential is attributed rather to avoid
  • Preferred products according to the invention are detergents or cleaners, cosmetics, adhesives, sealants, lacquers and air fresheners
  • Pre-soaking agents are usually strongly alkaline adjuvants (up to about pH 13) with a lower level of surfactant. They promote swelling during soiling and reduce soil adhesion
  • Preferred products within the meaning of the invention are also aftertreatment agents
  • washing stiffeners which have the effect of giving the wash a stiff and full-bodied shape
  • Form wipers which have the effect of consolidating textiles treated therewith in the fiber structure so that the wash obtains a light finish to strong thickening
  • Hygienespuler which are preferably added to the last Spulgang and contain an antimicrobial active ingredient and preferably nonionic surfactants
  • conditioning powders which provide the textile with textile treatment (eg machine washing) with active ingredients (eg oils) which can be given off to the human skin when the textile is worn and which benefit or care for the skin
  • Bugelberg which mineral water or demineralized water, preferably preservatives and fragrances include, for use in steam irons
  • any textile treatment agents such as, for example, detergents or softeners, in liquid or in solid form.
  • Preferred products in the meaning of the invention are therefore detergents
  • heavy-duty detergent preferably contains bleach, optical brighteners, enzymes, etc.
  • color detergent substantially free from bleach and optical brighteners, preferably containing discoloration inhibitors, cellulases, etc.
  • Sensitive detergent preferably containing nourishing substances, such as almond oil,
  • the most preferred cleaning agents pay in particular the Handgeschirrspulsch and the Maschmenischtirrspulstoff
  • the preferred cleaning agents include the toilet cleaners or toilet cleaners, ie products for cleaning toilet bowls and tubes which are preferably offered as powders, tablets, shaped bodies or liquids, preferably gels.
  • they mostly contain organic acids (eg citric acid and / or lactic acid) or sodium hydrogen sulfate, amidosulfuric acid or phosphoric acid for the removal of calcium deposits or so-called urine stones
  • the preferred cleaning agents include, among others, the pipe cleaners or drain cleaners. These are preferably strong alkaline preparations, which are usually the elimination of pipe blockages of organic materials - such as hair, fat, food residues soap deposits etc - serve to form H 2 -GaS with sparkling effect can serve additions of AI or Zn powder Possible ingredients are commonly alkalies, alkaline salts, oxidizing agents and neutral salts In powdered forms of preparation are preferably also sodium nitrate and Nat ⁇ umchlo ⁇ d contained pipe cleaners in liquid form may preferably contain hypochlorite addition there it also enzyme-based drain cleaner acid preparations are also possible
  • All-purpose cleaners for all hard household and commercial surfaces that can be wiped wet or damp are generally neutral or slightly alkaline or weakly acidic products. Especially Flussig. All diligentremiger or all-purpose cleaner usually contain surfactants Gerüststoffe solvent and Hydrotrope, dyes preservatives etc.
  • disinfectant All strictlyremiger These additionally contain antimicrobial agents (eg aldehydes alcohols, quaternary ammonium compounds, amphoteric surfactants Triclosan)
  • antimicrobial agents eg aldehydes alcohols, quaternary ammonium compounds, amphoteric surfactants Triclosan
  • the preferred cleaning agents include the sanitary cleaners These are products for cleaning in the bathroom and toilet
  • the alkaline sanitary cleaner are preferably used for the removal of grease, while the acidic sanitary cleaner are used primarily for the removal of lime deposits Sanitarr york have advantageously also a considerable disinfecting effect, in particular the strongly alkaline, chlorine-containing sanitary cleaner
  • oven cleaners and cleaners, which are advantageously offered in the form of gels or foam sprays. These are generally used to remove burned or charred food particles.
  • oven cleaners are adjusted to strongly alkaline with sodium hydroxide, sodium metasilicate, 2-aminoethanol As a rule, they also contain amonic and / or nonionic surfactants, water-soluble solvents and, in some cases, thickeners, such as polycarboxylates, carboxymethylcellulose
  • the preferred cleaning agents include the metal cleaning agents which are cleaners for certain types of metals such as stainless steel or silver.
  • Stainless steel cleaners preferably contain, in addition to acids (preferably up to 3% by weight, for example citric acid, lactic acid), surfactants (in particular up to 5% by weight, preferably nonionic and / or anionic surfactants), water also solvents (preferably up to 15% by weight) for the removal of greasy soiling and other substances such as thickener and preservatives
  • Very fine Polierkorper are also contained in products for preferably glossy stainless steel surfaces
  • Silberputzsch in turn are preferably acidic They contain in particular for the removal of black deposits of silver sulfide preferably complexing agent (eg thiourea, sodium thiosulfate)
  • Typical offer forms are cleaning mats, immersion baths, pastes, liquids To remove dark discolorations (oxide layers), copper and non-ferrous metal cleaners (eg B for brass and bronze) These are usually adjusted to weakly alkaline (
  • the preferred cleaning agents include, inter alia, the glass cleaners or window cleaners. These are preferably used to remove, in particular, greasy soil from glass surfaces. They preferably contain substances such as anionic and / or nonionic surfactants (in particular up to 5% by weight), ammonia and / or ethanolamine (in particular bis 1% by weight), ethanol and / or 2-propanol, glycol ethers (in particular 10-30% by weight), water, preservatives, colorants, anti-fogging agents, etc
  • the preferred cleaning agents include, among others, all special cleaning agents such as those for Cooktops made of glass ceramic, as well as carpet and upholstery cleaner and stain remover
  • Adhesives or sealants preferably also in the form of films, tapes or sticks, can advantageously also be paid for the agents according to the invention, likewise advantageously paints, as well as advantageously solvent-containing liquids (single- or multiphase)
  • cosmetic preparations for skin care in particular bath preparations, skin washing and cleaning preparations, skin care preparations, ocular cosmetics, lip care preparations, nail care products, personal care products foot care preparations,
  • (D) cosmetic preparations for hair care in particular shampoos, hair care products, hair hardening agents, hair shaping agents, hair colorants
  • Preferred ingredients of the consumer products according to the invention in particular of the cosmetic agents, can be defined by their function. Of course, some ingredients may also be multifunctional
  • Preferred ingredients of the inventive consumption products may be a) absorbent
  • Antiperspirants These are intended to prevent oxygen-triggered reactions such as oxidation and thus prolong the shelf life of the products, ie the quality of the products obtained d) antiperspirants
  • Binders are, for example, combability aids in hair care products. They generally reduce the electrostatic charge on objects, for example the hair-surface hairs can be combed so much more easily h) Binders
  • phytonutrients such as Gruner tea extract. They are intended to impart certain desired properties to a product which are related to the corresponding biological material or to further improve existing properties or to suppress undesired properties as far as possible reduce j) bleach
  • Emollients can help prevent or reduce the appearance of unpleasant body odors. They can mask such odors and reduce perspiration if necessary.
  • Emulsifiers are surface-active substances which are preferably capable of stably distributing immiscible liquids such as oil and water into one another o) emulsion stabilizers
  • Microorganisms (bacteria, fungi, yeasts) to preserve and thus prevent their spoilage u) corrosion inhibitors
  • Component of solid products are used w) oral care
  • UV absorbers / light filter substances may preferably be added to transparent or translucent products to make them more impenetrable to visible light or near-infrared radiation ee) UV absorbers / light filter substances
  • UV rays They are able to filter certain UV rays and can thus protect the skin, for example, from premature light-induced aging and from sunburn
  • Viscosity regulators These are able to increase or decrease the viscosity of a product
  • ingredients may be contained according to a preferred embodiments in the inventive products, preferably cosmetic agents
  • fragrances are contained in the products preferably in certain products
  • the inventive products at least one fragrance, preferably 2, 3 or more fragrances from the list galaxolide, dihydromyrcenol, 4-tert-butylcyclohexylacetate gamma-iso-methylionone tetrahydro-nalool, hexylcinnamaldehyde, Lilial linalool, amylcinnamaldehyde, 6- Methyl-gamma-ionone Methyloleate, Nerylacetate 15-Pentadecalactone Phenoxyethylisobutyrate Phenylethylmethanoate, ⁇ -Phenyl, B-Phenyl, Rose Oxide, Sabinene Anethole Benzoic acid 2-hydroxypentylester Diphenylether Benzophenone, Cyclamenaldehyde, ⁇ -Damascone Decanal, dicyclopentadiene, alcohol,
  • odoriferous substances methyl oleate, methyl palmitate, methyl laurate, eucalyptol, dihydromethyl jasmonate, dimethylbenzyl carbinylacetate, diphenyl ether, hexylcinnamaldehyde lilial, linalool, methyl oleate, methylmyrate, d-ammonium, dihydromyrcenol, 4-tert-butylcyclohexylacetate, a-da- mascon, Terp ⁇ neol, Tonahd, galaxolide, dodecanol, isopropyl, gamma-iso-methyhonone, isobornyl, Bornylacetet, 6-methyl- ⁇ - ⁇ -ionone and / or tetrahydro-alool Especially in solid, preferably powdery products of the fragrance dihydromyrcenol is extremely preferred, especially in Detergents and
  • the products according to the invention at least one fragrance, preferably 2, 3 or more fragrances from the list Bergamotteol, Dihydromyrcenol, Tange ⁇ neoel, Dimethylanthramlat, aldehyde c 11 (s), Allylamylglycolat, Cyclovertal, Calone, Styrolylacetat, Ethylnalool, isobornyl acetate, eucalyptus oil (globulus), aldehyde C 12, dynascone 10, limonene, orange oil, cyclovertal, ethyl 2-methyl butyrate, tetrahydro-naphthalene, undecavertol, aldehyde c 10, styrenyl acetate, otbca, waterfruit base, citronite, such fragrances are particularly advantageous to support the fragrance impression "freshness"
  • the inventive products at least one fragrance, preferably 2, 3 or more fragrances, from the list aldehyde C 14, decalactone gamma, cyclamen aldehyde, Lilial, Troenan, Canthoxal, citronellol, geraniol, phenylethyl alcohol, Dihy- droflonffone, Dmbca, Phenirat, phenylethyhsobutyrate, rose oxide, jasmeha, hexylcinnamaldehyde (alpha), ionone beta, ylang, cyclohexylsahcylate, hexenylsahcylate (c ⁇ s-3), sandelice, santobar, bacdanol, guaiacolite, iso E super, timberol (forte), norhmbanol, ambroxan, Cinnamyl alcohol, cyclopen
  • fragrances which comprise such fragrances with care impression are preferably applied to bentonite-containing carrier material. It may be particularly advantageous if fragrances which, as just stated, have the scent impression To support “freshness”, to be combined with those that, as just stated, support the fragrance impression of "care"
  • Air fresheners for living spaces contain volatiles and usually pleasant smelling substances, which can advantageously cover even in very small amounts of bad smells
  • Air fresheners for living spaces contain in particular natural and synthetic essential oils such as coniferous acicular, citrusol, eucalyptus oil, lavenderol etc, For example, in amounts of up to 50% by weight.
  • aerosols they contain rather lower amounts of such essential oils, for example less than 5% by weight or less than 2% by weight, but preferably also substances such as acetaldehyde (in particular ⁇ 0.5% by weight).
  • Isopropyl alcohol in particular ⁇ 5% by weight
  • mineral oil in particular ⁇ 5% by weight
  • propellants Other dosage forms are sticks and blocks
  • a gel concentrate of essential oils is preferably used.
  • formaldehyde for preservation
  • chlorophyll preferably ⁇ Gew - 5%
  • air fresheners are not restricted to living spaces, but can also be provided for cars, barriers, winders, refrigerators, shoes and even use in vacuum cleaners.
  • disinfectants are used in addition to the odor improvers which preferably contain substances such as calcium phosphate, talc, stearin and essential oils, for example in the form of sacs
  • composition according to the invention can be used for scenting an article, a surface or a room, preferably textile fabrics, household surfaces, shoes, garbage containers, fish containers, air, larger domestic appliances, cat litter, pets, pet sleeping facilities, in particular garments, carpets, carpeting, curtains , Curtains, upholstered furniture, bed linen, tents, sleeping bags, car seats, car mats, textile car interior linings, bar surfaces, walls, floor, bathroom surfaces, cake surfaces, refrigerator, freezers, washing machines, dishwashers, washer dryer, oven and microwave ovens are used directly or indirectly applied in any form, be sprayed for example by means of a Spruhapplikators
  • the perfumes may be selected from the group Essences from fruits, fruit parts and / or other plant parts, preferably herbs, drugs, essential oils derived therefrom, preferably terpene-free oils, and / or artificial essences, preferably from synthetic odorants and / or flavoring agents, more preferably vanillin, menthol, diacetyl and / or eucalyptol, and / or flavorings, preferably essential oils, anisole, star anisole, bitter almond oil, eucalyptusol, fencholol, peppermintol, citronol, wintergrunol, clove oil, menthol and / or kummelol, and / or ester-type synthetic perfume compounds, preferably benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phen
  • fragrances ie the perfume ingredients
  • Suitable carriers for the perfumes or perfumes may preferably be selected from the group comprising polymers, siloxanes, organo-modified Sihzium-containing compounds, betaines, paraffins, surfactants, in particular ethoxylated fatty alcohols, fatty acids, silicone oils and / or fatty alcohol, preferably lipophilic substances, hpophilic substances having a melting point above 25 ° C are particularly preferred
  • meltable or softenable substances from the group of waxes, paraffins, polyalkylene glycols and the like.
  • the meltable or softenable substances preferably have a melting range of between about 45 ° C and about 75 ° In the present case, that is, the melting range occurs within the specified temperature interval and does not indicate the width of the melting range
  • waxing is meant a number of natural or artificially derived substances which generally melt above 40 ° C without decomposition and are already slightly above the melting point of relatively low viscosity and non-stringy. They have a strong temperature-dependent consistency and dissociation depending on their origin the waxes into three groups, the natural waxes, chemically modified waxes and the synthetic waxes
  • Natural waxes include, for example, vegetable waxes such as Candehilla wax, carnauba wax, Japan wax, Espartogras wax, cork wax, guaruma wax, rice germ wax, sugarcane wax, Ou ⁇ curywachs, or montan wax animal waxes such as beeswax, shellac wax, spermaceti, lanolin (wool wax), or Burzelfett, mineral waxes such as Ceresin or Ozoke ⁇ t (Erdwachs), or petrochemical waxes such as Petrolatum paraffin waxes or micro waxes
  • hard waxes such as montan ester waxes pay Sassol waxes or hydrogenated jojoba waxes to the chemically modified waxes
  • Synthetic waxes are generally understood as meaning polyalkylene waxes or polyalkylene glycol waxes. As meltable or softenable substances for the composition which cures by cooling.
  • Other suitable compounds include, for example, higher esters of phthalic acid, in particular dicyclohexyl phthalate, which is commercially available under the name Unimoll.RTM.
  • Wax alcohols are high molecular weight, water-insoluble fatty alcohols with generally about 22 to 40 carbon atoms.
  • the wax alcohols are used, for example, in the form of wax esters of high molecular weight fatty acids (wax acids) as the main constituent of many natural ones Waxes before examples of wax alcohols are lignoceryl alcohol (1-tetracosanol), cetyl alcohol, my ⁇ stylalkohol or melissyl alcohol
  • Other usable melt and softenable substances are wool wax alcohols, which include terpenoid and steroid alcohols, such as lanolin, for example, under the trade name Argowax® (Pamentier & Co
  • fatty acid glyceryl esters or fatty acid alkanolamides but optionally also water may also be used as part of the meltable or softenable substances insoluble or only slightly water-soluble polyalkylene glycol compounds
  • meltable or softenable carriers are those from the group of polyethylene glycols (PEG) and / or polypropylene glycols (PPG) containing, with polyethylene glycols having molecular weights between 1500 and 36 000 are preferred, those having molecular weights of 2000 to 6000, more preferably and Those with molecular weights of from 3,000 to 5,000 are particularly preferred.
  • PEG polyethylene glycols
  • PPG polypropylene glycols
  • PPG propylene glycols
  • PEG polyethylene glycols
  • Polyethylene glycols which can preferably be used as polymeric carriers in accordance with the invention are polymers of ethylene glycol which satisfy the general formula H- (O-CH 2 -CH 2 ) n -OH, where n can assume values between 20 and approx. 1000 Preferred molecular weight ranges correspond to preferred ranges of the value n in formula IV of from 30 to 820, in particular from 34 to 818, particularly preferably from 40 to 150, in particular from 45 to 136 and more preferably from 70 to 120, in particular from 68 to 113
  • the product according to the invention thus comprises perfume or perfume which has been stored, the carrier substances preferably being selected from the group comprising polymers, siloxanes, silicon-containing compounds modified with organic radicals, betaines, paraffins, surfactants, in particular ethoxylated Fatty alcohols, fatty acid silicone oils and / or fatty alcohol, preferably lipophilic substances, with lipophilic substances having a melting point above 25 0 C are particularly preferred
  • the carrier substances preferably being selected from the group comprising polymers, siloxanes, silicon-containing compounds modified with organic radicals, betaines, paraffins, surfactants, in particular ethoxylated Fatty alcohols, fatty acid silicone oils and / or fatty alcohol, preferably lipophilic substances, with lipophilic substances having a melting point above 25 0 C are particularly preferred
  • the ratio of perfumeol to carrier substance / e in the case of a stored perfume oil is in the range from 20 l to 110, preferably from 5 l to 10 l and preferably 31 l
  • the meltable and softenable carrier substances which can be used according to the invention contain predominantly paraffin wax. This means that at least 50% by weight of the total meltable or softenable substances contained, preferably more of paraffin wax. Paraffin wax contents (based on the total amount meltable or softenable substances) of about 60% by weight, about 70% by weight or about 80% by weight, with still higher proportions of, for example, more than 90% by weight being particularly preferred. In a particular embodiment of the invention, the total amount of used meltable or softenable substances of at least one mass exclusively of paraffin wax
  • paraffin waxes have the advantage over the other natural waxes mentioned that no hydrolysis of the waxes takes place in an alkaline cleaning agent environment (as is to be expected, for example, with wax esters), since paraffin wax contains no hydrolyzable groups Paraffin waxes consist mainly of alkanes and small amounts of iso- and cyclo alkanes
  • the inventively usable paraffin preferably has substantially no constituents with a melting point greater than 70 ° C, particularly preferably of more than 60 0 C, high-melting alkanes in the paraffin If the temperature drops below this melting temperature in the detergent liquor, unwanted wax residue levels can be left on the surfaces to be cleaned or the goods to be cleaned.
  • melt or softenable carriers or carrier mixtures to be processed contain at least one paraffin wax having a melting range of 50 0 C to 60 ° C, wherein preferred methods are characterized in that the deformable mass (s) a paraffin wax having a melting range of 50 0 C to 55 ° C contains / contain n
  • Preferred carriers suitable for use with the perfume oils may also be selected from the group of water-soluble polymers, of which only the most important are water-soluble nonionic polymers (polyvinylpyrrolidones, vinylpyrrolidone / vinylester copolymers, cellulose ethers), water-soluble amphoteric polymers (alkylacrylamide / acrylic acid copolymers, alkyl acrylamide / methacrylic acid copolymers, alkylacrylamide / methyl methacrylic acid copolymers, alkylacrylamide / acrylic acid / alkylaminoalkyl (meth) acrylic acid copolymers, alkylacrylamide / methacrylic acid / alkylaminoalkyl (meth) acrylic acid copolymer , Alkylacrylamid / methyl-methacrylic acid / alkylamino-alkyl (meth) acrylic acid copolymers, alkylacrylamide / alkymethacrylate / alky
  • a erfmdungsgeEntrained means thus entrained
  • the product according to the invention in particular washing, care or cleaning agent, at least one, preferably more, active components, in particular washing, care and / or cleaning active components, advantageously selected from the group comprising anionic Surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, alkalizing agents, anti-wrinkle compounds, antibacterial agents, antioxidants, anti redeposition agents, antistatic agents, builders, bleaches, bleach activators, bleach stabilizers, bleach catalysts, balling aids, cobuilders, anti-shrinkage agents, electrolytes, enzymes, Colorants, Colorants, Dyes, Color Transfer Inhibitors Fluorescers, Fungicides Germicides, Odor-Complexing Substances, Adjuvants, Hy- drootropes, Rinse-off Agents, Complexing Agents, Preservatives, Corrosion Inhibitors, Optical Brighteners, Perfume Trumps ager, pearl
  • the surfactant content of, for example, laundry detergents z B may be between 10 and 50% by weight, preferably between 12.5 and 30% by weight and in particular between 15 and 25% by weight, while dishwasher detergents may be used for example usually between 0.1 and 10% by weight, preferably between 0.5 and 7.5% by weight, and in particular between 1 and 5% by weight, of surfactants
  • anionic surfactants are preferably included in the inventive products
  • anionic surfactants for example, those of the sulfonate type and sulfates are used as surfactants of the sulfonate type are preferably C 9 13 -Alkylbenzolsulfonate, olefinsulfonates, ie mixtures of alkene and hydroxyalkane sulfonates, and the disulfonates obtained, for example 12 i ⁇ - monoolefins with terminal or internal gallops double bond obtained from C by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products suitable are alkanesulfonates, from C 12 i 8 alkanes, for example by sulfo chlo ⁇ réelle or sulfoxidation and subsequent hydrolysis or neutralization are obtained Likewise, the esters of ⁇ -Sulfo
  • sulfonated fatty acid glycyl esters are sulfonated fatty acid glycyl esters.
  • Fatty acid glycyl esters are the mono-, di- and tri-esters and mixtures thereof, as in the preparation by esterification of a monoglycerine with 1 to 3 mol fatty acid or in the transesterification of triglycerides with 0.3 to 2
  • Preferred sulfated fatty acid glycine esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caprylic acid capric acid, maleic acid, palmitic acid stearic acid or behenic acid
  • Alk (en) ylsulfates are the alkali metal salts and, in particular, the sodium salts of sulfuric acid esters of C 12 -C 18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, my ⁇ styl cetyl or stearyl alcohol or C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are furthermore preferred.
  • Alk (en) ylsulfates of said chain length which comprise a synthetic petrochemical-based straight-chain alkyl radical which has an analogous decomposition behavior to the adequate compounds based on oleochemical raw materials
  • C 12 -C 16 alkyl sulfates and C 12 -C 15 - alkyl sulfates and C 14 -C 15 alkyl sulfates preferably 2,3-alkyl sulfates can be obtained as commercial products from Shell Oil Company under the name DAN ®, are suitable anionic surfactants
  • the Schwefelsauremonoester with 1 to 6 moles of ethylene ethoxylated linear or branched C 7 21 alcohols such as 2-methyl-9 verzwe ⁇ gte C 11 alcohols containing on average 3.5 mol ethylene oxide (EO) or C 18 fatty alcohols with 2 1 up to 4 EO, are particularly suitable in detergents because of their high foaming behavior, preferably only in relatively small amounts, for example in amounts of from 1 to 5% by weight
  • Suitable anionic surfactants are, for example, the partial esters of di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the ene adducts of maleic anhydride and at least monounsaturated carboxylic acids having a chain length of from 10 to 25 carbon atoms with an acid number of from 10 to 140
  • Preferred anionic surfactants have in addition to an unbranched or branched, saturated or unsaturated, aliphatic or aromatic acyclic or cyano, optionally alkoxyher- th alkyl radical having 4 to 28, preferably 6 to 20, especially 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms two or more anionic, in particular two acid groups, preferably carboxylate sulfonate and / or sulfate groups, in particular a carboxylate and a sulfate group, examples of these compounds are the -Sulfofettsauresalze the acylglutamates, the monoglyceride disulfates and the alkyl ethers of glycerol disulfate, and in particular the monoester sulfosuccinates described below
  • Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccmamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccmamates, most preferably sulfosuccinates.
  • the sulfosuccinates are the salts of the mono- and di-esters of sulfosuccinic acid HOOCCH (SO 3 H) CH 2 COOH, while sulphosuccinamates are understood to mean the salts of the monoamides of sulphosuccinic acid and sulphosuccinamides the salts of the diamides of sulphosuccinic acids
  • the salts are preferably alkali metal salts, ammonium salts and mono-, di- or trialkanolammonium salts, for example monodi or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts, extremely preferred sodium salts
  • one or both carboxyl groups of the sulfosuccinic acid is preferably particularly preferred with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cycloalcohols having from 4 to 22, preferably 6 to 20, in particular 8 to 18, optionally alkoxylated alcohols
  • Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene oxide and / or propylene oxide , preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4
  • the monoesters are preferred over the diesters particularly preferred sulfosuc cinate is Sulfobernsteins
  • one or both carboxyl groups of the sulfosuccinic acid preferably forms with a primary or secondary amine containing one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyan, optionally alkoxylated alkyl radicals having 4 to 22, preferably 6 to 20, in particular 8 to 18, particularly preferably 10 to 16, very preferably 12 to 14 carbon atoms, a carboxylic acid amide Particular preference is given to unbranched and / or saturated and / or acyclic alkyl P2006 / 007957
  • radicals in particular unbranched, saturated fatty alkyl radicals
  • an agent according to the invention can contain very large amounts of anionic surfactant, preferably up to an order of 40 , 50 or 60% by weight or more Likewise, an agent according to the invention can contain only very small amounts of anionic surfactant, for example less than 15 or 10% by weight or less than 5% or even less
  • anionic surfactants in amounts of 2 are present in the compositions according to the invention up to 35% by weight and especially 5 to 30% by weight, with concentrations above 10% by weight and even above 15% by weight finding particular preference.
  • the product according to the invention contains anionic surfactants, preferably in quantities of at least 0 1% by weight, based on the total product
  • soaps may be present in the inventive compositions are particularly saturated fatty acids such as the salts of lauric acid, my ⁇ stinsaure, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid and in particular from natural fatty acids coconut, palm kernel or TaIg- fatty acids, derived soap mixtures
  • the content of the composition of soaps is, independently of other anionic surfactants, preferably not more than 3% by weight and in particular 0.5 to 2.5% by weight, based on the entire remedy
  • anionic surfactants and soaps may be present in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine, preferably in the form of their sodium or potassium salts, in particular in the form of Sodium salts before anionic surfactants and soaps can also be prepared in situ by introducing into the composition to be spray-dried the anionic surfactant acids and optionally fatty acids, which are then neutralized by the alkali carriers in the composition to be spray-dried
  • nonionic surfactants may also be included in the compositions of the invention, both in solid and in liquid compositions.
  • their content may be up to 2 or 3 or 5% by weight.
  • Larger amounts of nonionic surfactant, for example up to 5%, may also be included -% or 10% by weight or 15% by weight or 20% by weight or 30% by weight or even beyond, if appropriate Sensible lower limits may be 1, 2, 3 or 4% by weight 006/007957
  • the nonionic surfactants are in relatively large amounts, ie up to 50% by weight, advantageously from 0.1 to 40% by weight, particularly preferably from 0.5 to 30 and in particular from 2 to 25% by weight, in each case
  • the product according to the invention contains nonionic surfactants, preferably in amounts of at least 0.1% by weight, based on the total product
  • nonionic surfactants known from the prior art may be present in the compositions according to the invention.
  • Preferred nonionic surfactants are presented below
  • compositions according to the invention may preferably also contain cationic surfactants.
  • Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular with an ammonium, sulfonium, phosphonium, iodomum or arsonium group quaternary surface-active compounds with antimicrobial activity, the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect can be improved due to other ingredients
  • Particularly preferred cationic surfactants are the quaternary antimicrobial ammonium compounds (QAV, INCI Quaternary Ammonium Compounds) according to the general formula (R ') (R ") (R'") (R IV ) N + X " in the US Pat R 'to R 1 are identical or different C 1 -C 22 -alkyl radicals C 7, 28 -aralkyl radicals or heterocyclic radicals, where two or, in the case of an aromatic incorporation as in pyndin, even three radicals together with the nitrogen atom form the heterocycle, for example a pyndinium - or imidazolinium form, and X "halide ions, sulfate ions, hydroxide ions or similar anions for optimum antimicrobial action, preferably at least one of the radicals a chain length of 8 to 18, ⁇ sensible12 to 16 C atoms
  • QACs can be prepared by reaction of tertiary amines with alkylating agents, such as methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide.
  • alkylating agents such as methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide.
  • alkylation of tertiary amines with a long alkyl radical and two methyl groups also succeeds in quaternization of tertiary amines
  • Amines with two long radicals and one methyl group can be carried out under mild conditions with the aid of methyl chloride.
  • Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are preferably quaternized with dimethyl sulfate
  • Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride). chloride, CAS No. 58390-78-6), benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) -ammonium chloride), benzalkone B (mp-dichlorobenzyl-dimethyl-C 1-4 -alkylammonium chloride, CAS No. 58390-78-6) Cetammonium bromide (N-hexadecyl-N, N-tri- methylammonium bromide, CAS No. 57-09-0), benzetonium chloride .I.
  • dialkyldimethylammonium chloride such as di- ⁇ -decyl-dimethyl-ammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No 2390 -68-3), dioctyl-dimethyl-ammonium chloride, 1-cetylpyrrolidinium chloride (CAS No. 123-03-5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof.
  • Preferred QACs are the benzalkonium chlorides with C 8 -C 18 -alkyl radicals, in particular C ⁇ -Cu-Aklyl-benzyl-dimethylammo-niumchlorid
  • a particularly preferred QAC coconut pentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate, Rewoquat CPEM ®)
  • anionic surfactant and / or optionally cationic surfactant are preferably used or, in a particular embodiment of the invention, cationic surfactants are completely dispensed with
  • compositions according to the invention may contain one or more cationic surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably from 0 to 20% by weight, preferably 0.01 to 10% by weight, in particular 0.1 to 5% by weight Suitable minimum values may also be present at 0.5, 1, 2 or 3% by weight.
  • the product according to the invention contains cationic surfactants, preferably in quantities of at least 0.1% by weight, based on the total product
  • agents according to the invention such as, preferably, cleaning agents, care agents and detergents, may also contain amphoteric surfactants. These will be described in more detail below, in particular in connection with conditioners and plasticizers
  • compositions according to the invention may contain one or more amphoteric surfactants, advantageously in amounts, based on the total composition. from 0 to 30% by weight, more preferably from 0 to 20% by weight, preferably from 0.01 to 10% by weight, in particular from 0.1 to 5% by weight
  • compositions according to the invention may be inorganic and organic builders.
  • the inorganic builders include water-insoluble or non-water-soluble ingredients, such as aluminosilicates and in particular zeolites
  • the agent according to the invention contains no phosphate and / or no zeolite.
  • the agent contains zeolite. It may then be preferred that this zeolite content is less than 5% by weight, based on the total weight of the agent. preferably not more than 4% by weight, not more than 3% by weight or not more than 2% by weight
  • the agent according to the invention has a zeolite content of at least 10% by weight, for example at least 15% by weight or at least 20% by weight or at least 30% by weight or even beyond, for example at least 50% by weight -% having
  • Soluble builders may preferably contain the agent according to the invention in amounts of 10% by weight to 30% by weight, preferably 15% by weight to 25% by weight and particularly preferably 18% by weight to 20% by weight, based on the total weight of the composition. Natnumcarbonat being particularly preferred as a soluble builder. However, it can also be advantageously provided that the inventive composition contains less than 10% by weight, for example less than 5% by weight, of soluble builders
  • zeolite A and / or P zeolite P is, for example, zeolite MAP ⁇ R> (commercial product of the company Crosfield) is especially preferred suitable are
  • zeolite X and mixtures of A, X and / or P of particular interest a co-crystallized Nat ⁇ um / potassium Alumimum- is silicate of zeolite a and zeolite X, which is available as VEGOBOND AX ® (a product of Condea Augusta S p a) commercially
  • VEGOBOND AX ® a product of Condea Augusta S p a
  • the zeolite can When the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example from 1 to 3% by weight, based on the weight of the suspension used as spray-dried powder or else as undried suspension still moist from its production Zeolite, on ethoxylated C 12
  • zeolites are faujasite-type zeolites. Together with the zeolites X and Y, the mineral faujasite belongs to the faujasite types within the Zeohth structural group 4 which are characterized by the double-sixth subunit D6R. Structural group 4 pay the minerals chabazite and gmelinite as well as the synthetic zeolites R (chabazite type), S (gmelinite type), L and ZK-5, in addition to the faujasite types mentioned. The latter two synthetic zeolites have no mineral analogues
  • Faujasite-type zeolites are composed of ⁇ -cages which are tetrahedrally linked via D6R subunits, the p-cages being similar to the carbon atoms in the diamond.
  • the three-dimensional network of the faujasite-type zeolites suitable for the invention has pores of 2 , 2 and 7.4 A, the unit cell also contains 8 Kavitaten with about 13 A diameter and can be described by the formula Na 8 ⁇ [(AI0 2 ) 86 (S ⁇ 2) io6] 264 H 2 O describe the network of zeolite X contains a void volume of about 50%, based on the dehydrated crystal, which represents the largest void space of all known zeolites (zeolite Y about 48% void volume, faujasite about 47% void volume)
  • zeolite-type zeolite denotes all three zeolites which form the faujasite subgroup of the Zeohth structural group 4.
  • zeolite X zeolite Y
  • faujasite and mixtures of these compounds are also suitable according to the invention pure zeolite X is preferred
  • Mixtures or cocatalysts of faujasite-type zeolites with other zeolites, which need not necessarily belong to the zeolite structure group 4, are also suitable according to the invention, with preferably at least 50% by weight of the faujasite-type zeolites being suitable
  • zeolite A-LSX which corresponds to a co-catalyst of Zeohth X and zeolite A and in its anhydrous form has the formula (M 2 / n O + M ' 2 / n O) Al 2 O 3 ZSiO 2 , where M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6.
  • This product is commercially available under the trade name VEGOBOND AX from the company CONDEA Augusta S p A
  • Y-type zeolites are also commercially available and can be prepared, for example, by the formulas Na 56 [(AIO 2 ) 56 (SiO 2 ) 13 6] x H 2 O,
  • the particle sizes of the suitable zeolites advantageously lie in the range from 0.1 .mu.m to 100 .mu.m, preferably from 0.5 .mu.m to 50 .mu.m and in particular from 1 .mu.m to 30 .mu.m, in each case measured using standard particle size determination methods
  • all of the inorganic constituents present are preferably water-soluble. In these embodiments, therefore, other builder substances than the zeolites mentioned are used
  • polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 C atoms and at least 3 hydroxyl groups.
  • Preferred polyacetals are prepared from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyolcarboxylic acids such as Gluconic acid and / or glucoheptonic acid
  • dextrins for example, oligomers or polymers of carbohydrates which can be obtained by partial hydrolysis of starches.
  • the hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes.
  • the hydrolysis products have average molecular weights in the region of 400 up to 500000 g / mol.
  • a polysaccharide with a dextrose equivalent (DE) in the range of From 0.5 to 40, especially from 2 to 30 is preferred, with DE being a common measure of the reducing effect of a polysaccharide compared to dextrose having a DE of 100.
  • DE dextrose equivalent
  • Oxydisuccinates and other derivatives of disuccinates, preferably Ethylendiammdisuccinat are further suitable cobuilders It is Ethylend ⁇ am ⁇ n-N, N '-d ⁇ -succ ⁇ nat (EDDS) is preferably in the form of its sodium or magnesium salts thereof are furthermore preferred in this context
  • Glyce ⁇ ndisuccinate and Glyce ⁇ ntrisuccinate Suitable Amounts are, for example, from 3 to 15% by weight, based on the total agent
  • organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may optionally also be present in lactone form and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups
  • phosphonates are, in particular, hydroxyalkane or aminoalkanephosphonates.
  • hydroxyalkanophosphonates 1-hydroxyethane-1,1-diphosphonate (HEDP) is of particular importance as a cobuilder. It is preferably used as the sodium salt.
  • Ammoalkanphosphonate are preferably ethylenediaminetetramethylenphosponate (EDTMP), Diethylent ⁇ aminpentamethylenphosphonat (DTPMP) and their higher homologs in question They are preferably in the form of neutrally reacting sodium salts, eg B as Hexasatriumsalz the EDTMP or as Hepta- and Octa Nat ⁇ umsalz the DTPMP, used as a builder is preferably from the class of phosphonates HEDP used the Ammoalkanphosphonate also have a pronounced Schwermetallbindevermogen Accordingly, it may, especially if the means also contain bleach, it is preferred to use Ammoalkanphosphonate, in particular DTPMP, or to use mixtures of said phosphonates
  • phosphates in particular pentasodium t-phosphate, optionally also pyrophosphates and orthophosphates Phosphates are predominantly used in automatic dishwashing agents, but sometimes also in detergents.
  • Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of the various phosphoric acids in which Metaphosphoric acids (HPO 3 ) ,, and orthophosphoric acid H 3 PO 4 in addition to high molecular weight representatives can differ
  • the phosphates combine several advantages They act as Alkahtrager prevent lime scale on machine parts or Kalkinkrustationen in tissues and also contribute to the cleaning performance
  • Nat ⁇ umdihydrogenphosphat NaH 2 PO 4 exists as a dihydrate (density 1 91 like 3 , melting point 60 °) and as monohydrate (density 2 04 like 3 ) Both salts are white, very soluble in water powders that lose the water of crystallization on heating and at 200 0 C into the weakly acidic diphosphate (Dm- t ⁇ umhydrogendiphosphat Na 2 H 2 P 2 ⁇ 7 ), at higher temperature in Natiumt ⁇ metaphosphat (Na 3 P 3 O 9 ) and Maddrell's salt (see below), pass NaH 2 PO 4 reacts acidic It is formed when phosphoric acid is adjusted to pH 4.5 with caustic soda and the mash is sprayed.
  • Dm- t ⁇ umhydrogendiphosphat Na 2 H 2 P 2 ⁇ 7 weakly acidic diphosphate
  • Natiumt ⁇ metaphosphat Na 3 P 3 O 9
  • Maddrell's salt see below
  • Potassium dihydrogen phosphate (potassium phosphate primary or embaseous, kahumbiphosphate, KDP), KH 2 PO 4 is a white salt of density 2.33 preferably 3 , has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO 3 ) J and is readily soluble in water
  • Dinat ⁇ umhydrogenphosphat (secondary sodium phosphate), Na 2 HPO 4 is a colorless very slightly water-soluble crystalline salt It exists anhydrous and with 2 mol (density 2.066 like 3 , water loss at 95 °), 7 mol (density 1, 68 like 3 , melting point 48 ° with loss of 5 H 2 O) and 12 moles of water (density 1, 52 like 3 , melting point 35 ° with loss of 5 H 2 O), becomes anhydrous at 100 ° C and goes on stronger heating in the diphosphate Na 4 P 2 O.
  • T ⁇ nat ⁇ umphosphat tertiary sodium phosphate, Na 3 PO 4 are colorless crystals which have a density of 1, 62 like 3 and a melting point of 73-76 ° C (decomposition), as decahydrate (corresponding to 19-20% P 2 O 5 ) as dodecahydrate having a melting point of 100 ° C. and in anhydrous form (corresponding to 39-40% P 2 O 5 ) has a density of 2 536, preferably 3 trisodium phosphate is readily soluble in water under alkaline reaction and is obtained by evaporating a solution from exactly 1 mole of sodium hydroxide.
  • K 3 PO 4 is a white zerlöchhches, granular powder density 2 56 like 3 has a melting point of 1340 ° and is readily soluble in water with an alkaline reaction. It is produced, for example, by heating Thomas slag with carbon and potassium sulfate. Despite the higher price, the more readily soluble, and therefore highly effective, potassium phosphates are often preferred in detergents
  • Tetranat ⁇ umdiphosphat (Nat ⁇ umpyrophosphat), Na 4 P 2 O 7 , exists in anhydrous form (density 2.534 like 3 , melting point 988 °, also 880 ° indicated) and as decahydrate (density 1.815-1, 836 like 3 , melting point 94 ° with loss of water) both substances are colorless crystals which dissolve in water through an alkaline reaction, crystals Na 4 P 2 O 7 is formed by heating Dinat ⁇ umphosphat to> 200 ° or by phosphoric acid with soda reacted in stochiomet ⁇ schem ratio and the solution by spraying dewatered the decahydrate complexes heavy metal salts and Hardner, and therefore reduces the hardness of the water.
  • Kahumdiphosphate (potassium pyrophosphate), K 4 P 2 O 7 , exists in the form of the hydrate and is a colorless, hygroscopic powder with a density of 2.33% "3 " which is soluble in water the pH of the 1% solution at 25 ° 10,4 amounts
  • Condensation of NaH 2 PO 4 or KH 2 PO 4 gives rise to high molecular weight sodium and potassium phosphates, in which one can distinguish chemical representatives, the sodium or potassium metaphosphates, and chain-like types, the sodium or potassium polyphosphates Much of the terms in use Melting or glowing phosphates, Graham's salt, Kurrolsches and Maddrell's salt All higher sodium and potassium phosphates are collectively referred to as condensed phosphates
  • 10O g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° about 32 g of c ⁇ stalligan990 salt, after two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate
  • Pentanat ⁇ umtriphosphat phosphoric acid is reacted with soda solution or sodium hydroxide in the stoichiometric ratio and the solution dehydrated by spraying similar to Graham's salt and Natnumdiphosphat lost pentanat ⁇ umt ⁇ phos-phat many insoluble metal compounds (also lime soap, etc.)
  • Nat ⁇ umt ⁇ polyphosphat can be used just like Nat ⁇ umt ⁇ polyphosphat, Kaliumtnpolyphosphat or mixtures of these two, and mixtures of Nat ⁇ umtripoly-phosphate and Natnumkalium- t ⁇ polyphosphat or mixtures of Kaliumtnpolyphosphat and Nat ⁇ umkaliumt ⁇ polyphosphat or mixtures of Natriumt ⁇ polyphosphat and Kaliumt ⁇ polyphosphat and Nat ⁇ umkaliumtripolyphos-phat invention can be used
  • carbonates and silicates are used as inorganic builder substances
  • crystalline silicates are preferably subsequently added to the direct or post-treated spray drying product.
  • Preferred crystalline layered silicates of the formula given are those in which M is sodium and x is Values 2 or 3
  • both ß- and ⁇ -Nat ⁇ umdisilicate Na 2 Si 2 O 5 yH 2 O are preferred such compounds are commercially available, for example, under the name SKS ® (Cla ⁇ ant)
  • SKS-6 ® mainly a ⁇ - Nat ⁇ umdi-silicate with the formula Na 2 Si 2 O 5 yH 2 O
  • SKS-7 ® mainly to the ß-Nat ⁇ umd ⁇ s ⁇ l ⁇ cat
  • acids eg citric acid or carbonic acid
  • SKS-9 ® and SKS-10 ® (Cla ⁇ ant)
  • the alkalinity of the layered silicates are suitably influenced With phosphate or carbonate doped layered silicates have K ⁇ stallmorphologien changed in comparison to the ⁇ -N
  • compounds from crystalline phyllosilates with other ingredients can also be used.
  • compounds with cellulose derivatives are used have the advantages in the disintegrating effect, as well as compounds with polycarboxylates, eg citric acid, or polymeric polycarboxylates, eg copolymers of acrylic acid, to call
  • the preferred builders include amorphous Nat ⁇ umsilikate with a modulus Na 2 O SiO 2 of 1 2 to 1 3.3, preferably from 1 2 to 1 2,8 and in particular from 1 2 to 1 2.6, which have Sekundarwascheigenschaften In the frame
  • amorphous Nat ⁇ umsilikate with a modulus Na 2 O SiO 2 of 1 2 to 1 3.3, preferably from 1 2 to 1 2,8 and in particular from 1 2 to 1 2.6 which have Sekundarwascheigenschaften In the frame
  • the silicates in X-ray diffraction exponents do not give sharp X-ray reflections, as are typical for crystalline substances, but at most one or more maxima of the scattered X-radiation, which has a width
  • the products have microcrystalline regions of 10 to a few hundred nm Values up to 50 nm and in particular up to 20 nm
  • Particular preference is given to densified / compacted amorphous silicates, compounded amorphous silicates and dried X-ray silicates.
  • the content of the (X-ray) amorphous silicates in particular zeolite-free compositions is preferably 1 to 10% by weight, which corresponds to a preferred embodiment of the invention
  • Particularly preferred inorganic water-soluble builders are alkali metal carbonates and alkali metal bicarbonates, with sodium and potassium carbonate and in particular sodium carbonate being preferred embodiments.
  • the content of alkali metal carbonates in particular zeolite-free compositions can vary within a very wide range and is preferably from 5 to 40% by weight. in particular 8 to 30% by weight, the content of alkali metal carbonates usually being higher than on (radiopaque) amorphous silicates
  • Useful organic framework substances are, for example, the polycarboxylic acids which can be used in the form of their alkali metal salts and, in particular, sodium salts such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, succinic acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such use is not objectionable for ecological reasons, and mixtures from these Preferred salts are the salts of polycarboxylic acids such as citric acid adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.
  • the acids themselves can be used in addition to their builder effect typically also the property of an acid component and thus serve, such as in the invention suitable granules, also for setting a lower and milder pH of detergents and cleaners.
  • Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any mixtures of these may be mentioned in particular
  • polymeric polycarboxylates for example the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example those having a relative molecular weight of 500 to 70,000 g / mol.
  • the molecular weights stated for polymeric polycarboxylates are weight-average molar masses for the purposes of this document M w of the respective acid form, which were determined in principle by means of gel permeation chromatography (GPC) using a UV detector.
  • compositions according to the invention can also contain polymers, in particular as carriers for the perfumeols.
  • Suitable polymers which can also be used as carriers in combination with perfume include, in particular, polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility From this group, in turn, the short-chain polyacrylates, the molecular weights of 2000 to 10,000 g / mol, and particularly preferably from 3000 to 5000 g / mol, may be preferred
  • copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid and acrylic acid or methacrylic acid with maleic acid.
  • Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven particularly suitable
  • Their relative molecular mass, based on free acids, is generally from 2000 to 70000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular from 30,000 to 40,000 g / mol
  • the content of the organic builder substances may vary within a broad range. Preference is given to contents of from 2 to 20% by weight, in particular contents of not more than 10% by weight being particularly preferred
  • the agents according to the invention may contain components from the classes of the grayness inhibitors (soil carriers), the neutral salts and / or the textile-softening auxiliaries (for example cationic surfactants), which is preferred
  • Graying inhibitors have the task to keep suspended from the fiber debris suspended in the fleet and so prevent the re-uptake of dirt
  • water-soluble colloids are mostly organic nature suitable, for example, the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose or salts of acid or acidic sulfuric esters of cellulose or starch.
  • water-soluble polyamides containing acid groups are suitable for this purpose.
  • soluble starch preparations and other than the above-mentioned starch products can be used, eg degraded starch, strong aldehydes, etc.
  • Polyvinylpyrrolidone is useful However, preference is given to cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkyl cellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof , and polyvinyl pyrrohdone, for example, in amounts of preferably 0.1 to 5% by weight, based on the means used
  • a typical example of a suitable representative of the neutral salts is sodium sulfate. It can be used in amounts of, for example, from 0 to 60% by weight, preferably from 2 to 45% by weight
  • Suitable plasticizers which are described in more detail below, are, for example, swellable layered silicates of the type of corresponding monomers, for example bentonite, as well as cationic surfactants
  • the content of water on average depends, inter alia, on whether the agent is present in liquid or solid form and therefore preferably amounts to 0 to less than 100% by weight and in particular 0 to 95% by weight, values of not more than 5% by weight in particular to find particular preference for solid or non-aqueous liquids Not included in the case of the solid compositions is the water adhering to any aluminosilicate such as zeolite
  • the composition according to the invention contains water in an amount of more than 20% by weight, advantageously more than 30% by weight, in a preferred embodiment advantageously more than 40% by weight, more preferably more than 50% by weight, in particular 60 to 95% by weight, more preferably 70 to 93% by weight and most preferably 80 to 90% by weight, based on the total agent
  • the agent according to the invention can, if it is a solid, have an excellent trickling behavior.
  • the agent according to the invention is essentially solid, preferably in powdery, compressed or granular form
  • the particles can be aftertreated, for example by rounding the particles of the agent.
  • the rounding can be carried out in a conventional rounding agent.
  • the rounding time does not exceed 4 minutes, in particular not more than 3.5 minutes Rounding times of a maximum of 1.5 minutes or less are particularly preferred.
  • the rounding achieves a further standardization of the grain spectrum since any agglomerates formed are comminuted
  • An agent according to the invention in particulate form can be obtained in particular with nonionic surfactants, perfume and / or foam inhibitors or preparation forms which contain these ingredients, preferably with amounts of up to 20% by weight of active substance, in particular with amounts of from 2 to 18% by weight of active substance on the aftertreated product, in a conventional manner preferably in a mixer or optionally a fluidized bed, post-treatment
  • an agent according to the invention can also be post-treated or powdered with solids, preferably in amounts of up to 15% by weight, in particular in amounts of from 2 to 15% by weight, based in each case on the total weight of the post-treated agent
  • Bicarbonate, carbonate, zeolite, silicic acid, citrate, urea or mixtures thereof, in particular in amounts of from 2 to 15% by weight, based on the total weight of the aftertreated product, can preferably be used as the aftertreatment agents.
  • the aftertreatment can be advantageously achieved in a mixer and / or run through Verrunder
  • an agent according to the invention is aftertreated with nonionic surfactants which may, for example, also contain optical brighteners and / or hydrotropes.
  • nonionic surfactants which may, for example, also contain optical brighteners and / or hydrotropes.
  • optical brighteners and / or hydrotropes Perfume, and / or a solution of optical brightener and / or foam inhibitors or preparation forms which may contain these ingredients
  • the aftertreatment with the substances mentioned here in a conventional mixer only for example in a 2-shaft M ⁇ scher within a maximum of 1 minute, preferably within 30 seconds and for example within 20 seconds, the time information for simultaneous addition - and mixing time is completed
  • nonionic surfactants may be applied to the particulate agents in an aftertreatment step.
  • all nonionic surfactants may advantageously be present directly in the composition of the invention, liquid or solid, foaming or gel form
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical is linear or preferably methyl-branched in the 2-position
  • EO ethylene oxide
  • preferred preferred ethoxylated alcohols include, for example C 12 -C 14 alcohols with 3 EO to 6 EO, C 9 -C 11 -AlkOhOIe with 7 EO, C l3 -C 15 -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 14 -
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples of these are (TaIg) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO
  • Preferred nonionic surfactants are one or more C 10 alkoxylated with ethylene- (EO) and / or propylene oxide (PO) alkoxylated unbranched or branched, saturated or unsaturated.
  • nonionic surfactants which can also be employed are alkylglycosides of the general formula RO (G) x , in which R is a primary straight-chain or methyl-branched, especially methyl-branched, 2-position aliphatic radical containing 8 to 22, preferably 12 to 18, carbon atoms and G is the symbol which represents a glucose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number from 1 to 10, preferably x at 1.1 to 1.4
  • nonionic surfactants used either as the sole non-magenta surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably with 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl ester, particularly preferred are C 12 -C 18 fatty acid methyl esters having an average of 3 to 15 EO, in particular having an average of 5 to 12 EO, z B can also be used
  • nonionic surfactants of the type of amine oxides for example N-cocoalkyl-N, N-d ⁇ methylam ⁇ n- oxide and N-tallow alkyl-N, N-d ⁇ hydroxyethylam ⁇ nox ⁇ d, and the Fettsaurealkanolamide may be suitable.
  • the amount of these nonionic surfactants is preferably not more than that of ethoxy - Heated fatty alcohols, especially not more than half of them
  • alkoxylated amines advantageously ethoxylated and / or propoxylated, in particular primary and secondary amines having preferably 1 to 18 carbon atoms per alkyl chain and an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per Mole of amine
  • EO ethylene oxide
  • PO propylene oxide
  • surfactants are in principle all surfactants in question.
  • the nonionic surfactants described above and especially the low foaming ones are preferred for this purpose
  • Particular preference is given to the alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols.
  • the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols preferably
  • the long-chain alcohols C 10 to C 18 preferably from C 2 to C 16 , such as C 11 , C 12 , C 13 , C 14 , C 15 , C 16 , C 17 and C 18 -alcohols usually arise from n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, a complex mixture of addition products of different Ethoxyherungsgrades
  • Another embodiment is the use of mixtures of alkylene oxides preferably the mixture of ethylene oxide and propylene oxide
  • a conclusive etherification with short-chain alkyl groups, such as preferably the butyl group to the substance class of "closed" alcohol ethoxylates, which can also be used in the context of the invention
  • Very particularly preferred for the purposes of the present invention are highly ethoxylated
  • the agents according to the invention can also contain foam inhibitors, for example foam-inhibiting paraffinol or foam-inhibiting polyolefin, for example dimethylpolysiloxane.
  • foam inhibitors for example foam-inhibiting paraffinol or foam-inhibiting polyolefin, for example dimethylpolysiloxane.
  • mixtures of these active substances as additives which are solid at room temperature, in particular for the foam-inhibiting active ingredients mentioned, paraffin waxes, silicic acids may also be hydrophobicized in a known manner, and by C 2 7 - diamines and C 12 22 carbonic acid derived bisamides in question
  • suitable foam-inhibiting paraffin oils which may also be present in admixture with paraffin waxes are generally complex mixtures without sharp melting point.
  • the melting range is usually determined by differential thermoanalysis (DTA) and / or the solidification point below Paraffins with less than 17 carbon atoms are not suitable according to the emndungsgeINE, their proportion in the paraffinol mixture should therefore be as low as possible and is preferably below that with Paraffins which solidify in the range from 20 ° C. to 70 ° C.
  • paraffin wax mixtures which appear solid at room temperature also entail different proportions of liquid paraffinols can keep at erfmdungsgeinterpreted paraffin waxes harbors the Flussiganteil at 40 0 C as high as possible without at this temperature already 100% to be
  • Preferred paraffin wax mixtures have at 40 0 C a Flussiganteil of at least 50 wt -%, especially from 55 weight -% to 80 wt -%, and at 60 ° C a Flussiganteil of at least 90 wt -% to This has the consequence that the paraffins at temperatures down to at least 7O 0 C, preferably down to at least 6O 0 C are f profahig and pumpable is also to make sure that the paraffins contain as few volatiles as possible Preferred Paraffin waxes contain less than 1% by weight, in particular less than 0.5% by weight, vaporizable at 110 ° C. and normal pressure. Paraffins which can be used according to the invention can be
  • the paraffin oils may contain at room temperature solid bisamides derived from saturated fatty acids having 12 to 22, preferably 14 to 18, carbon atoms and alkylenediamines having 2 to 7 carbon atoms.
  • Suitable fatty acids are lactic, mynstine, stearic, Arachin and behenic acid and mixtures thereof, such as those obtainable from natural fats or hardened oils, such as tallow or hydrogenated Palmol.
  • Suitable diamines are, for example, ethylenediamine 1, 3-propylenediamine, tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, p-phenylenediamine and Toluylenediamine
  • Preferred diamines are ethylenediamine and hexamethylenediamine
  • Particularly preferred bisamides are bis-my ⁇ stoyl-ethylenediamine, bis-palmitoyl-ethylenediamine, bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding derivatives of hexamethylenediamine
  • the products according to the invention can preferably be mixed with further constituents, in particular detergents, care agents and / or cleansing agents or cosmetic ingredients.
  • further constituents in particular detergents, care agents and / or cleansing agents or cosmetic ingredients.
  • ingredients of detergents or cleansers and which raw materials are usually added are, for example, substances such as bleaches, bleach activators and / or bleach catalysts, enzymes, temperature-sensitive dyes, etc., which of course may also be contained directly in the composition
  • the composition can comprise UV absorbers which advantageously deposit on the treated textiles and improve the light stability of the fibers and / or the light stability of other formulation constituents.
  • UV absorbers are to be understood as being capable of organic substances (light protection filters)
  • heat compounds having these desired properties are, for example, the non-reactive deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position
  • salicylates organic N ⁇ -complexes and natural products such as umbelliferone and the body's own Urocansaure are particularly important biphenyl and especially all m stilbene, commercially Tinosorb FD ® ® or Tinosorb FR ex Ciba UV-B absorbers are to be mentioned
  • UV-A F ⁇ lter particular derivatives of benzoylmethane come into question, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-d ⁇ on, 4-tert-butyl-4 'Methoxyd ⁇ benzoyl- methane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) propane-1,3-d ⁇ on and Enaminverbmd.
  • the UV-A and UV-B F ⁇ lter can of course be used in mixtures
  • insoluble light-shielding pigments namely finely dispersed, preferably nano-metal oxides or salts, are suitable for this purpose.
  • suitable metal oxides are, in particular, zinc oxide and titanium dioxide and, in addition, oxides of iron.
  • Zirconiums, Siliciums, Mangans, Aluminum and Cers as well as their mixtures As salts Sihcate (talc), Ba ⁇ umsulfat or zinc stearate can be used.
  • the oxides and salts are already used in the form of the pigments for skin-caring and skin-protecting emulsions and decorative cosmetics They may have a spherical shape, but it is also possible to use those particles which are ellipsoidal or otherwise spherical
  • the shape of the pigments may also be surface-treated, ie hydrophilized or hydrophobic.
  • Typical examples are coated titanium dioxides, such as titanium dioxide T 805 (Degussa) or Eusolex® T2000 (Merck).
  • Suitable hydrophobic coating agents are above all else Silicones and especially Tnalkoxyoctylsilane or Simethicone in question
  • micronized zinc oxide is used.
  • Further suitable UV light protection filters can be found in the relevant prior art
  • the UV absorbers may advantageously be contained in amounts of from 0.01% by weight to 5% by weight, preferably from 0.03% by weight to 1% by weight, in the composition. They may also be added subsequently to the composition, for example together with others Substances, are mixed
  • the agents according to the invention can also be in the form of tablets or moldings.
  • tablettes or “shaped articles” are dimensionally stable, solid bodies, regardless of the manner of their preparation. Such bodies can be crystallized, for example , Molding, injection molding, reactive or thermal sintering, (co) Extrus ⁇ on, Verp ⁇ lllung, pastillation, or compaction process as the Kaland ⁇ réelle or tableting manufacture
  • the preparation of the "tablets" or “Formkorper” by tabletting is particularly preferred in the present application
  • the tablet is So preferably made of compressed, teilchenformigen material
  • Preparations according to the invention in solid form may preferably contain disintegration aids Suitable swellable desmutting aids are, for example, bentonites or other swellable silicates.
  • Synthetic polymers in particular the superabsorbent or crosslinked polyvinylpyrrolidone used in the hygiene sector, can also be used
  • Polymers based on starch and / or cellulose are used with particular advantage as swellable disintegration aids. These basic substances can be processed to swellable disintegrating agents, all or in admixture with other natural and / or synthetic polymers.
  • a cellulosic material or pure cellulose be transferred by granulation, compaction or other application of pressure in secondary particles, which swell on contact with water and thus serve as a disintegrating agent
  • wood pulp has survived by thermal or chemical-chemical processes of wood or wood chips (Sagespane, Sagereiabfalle)
  • This cellulose material from the TMP process (thermo-mechanical pulp) or the CTMP process (chemothermotherm mechanical pulp) can then be compacted by application of pressure, preferably roll-compacted and converted into particle form
  • pressure preferably roll-compacted and converted into particle form
  • both microcrystalline and amorphous fine-particle cellulose and mixtures thereof can be used Another way is then to granulate the cellulosic material with the addition of granulation.
  • Granulieryakukan for example, solutions of synthetic polymers or nonionic surfactants
  • P ⁇ marmaschinelange the cellulose or cellulose used in cellulose-containing Material below 200 microns, with P ⁇ marmaschine GmbH below 100 microns, especially below 50 microns are preferred
  • the secondary particles ideally have a particle size distribution in which preferably more than 90% by weight of the particles have a size greater than 200 ⁇ m.
  • a certain proportion of dust can contribute to an improved storage stability of the tablets produced therewith 10% by weight, preferably up to 8% by weight, may be present in the compositions according to the invention with disintegrant granules
  • compositions according to the invention can be present in the form of a conditioning agent and / or conditioning substrate and contain the appropriate components.
  • conditioning is preferably understood to mean the reviving treatment of textiles, fabrics and fabrics. Conditioning gives the textiles positive properties such as improved softness, increased gloss and color brilliance, improved scent impression, reduction of felting, ease of buffing by reducing the sliding properties, reducing the creasing behavior and the static charge as well as a color transfer inhibition in dyed textiles
  • compositions according to the invention can contain, for example, polymerizable betaine esters of the general formula (I)
  • R a is an ethylenically unsaturated radical containing at least one carbonyl function, such as
  • Example is acryloyl, methacryloyl, maleoyl or itaconoyl, X is an oxygen atom, -N (CH 3 ) - or -NH-,
  • R b , R c are independently optionally branched alkyl radicals having 1 to 4 carbon atoms, these heteroatom substituents, in particular 0, S, N, P may contain, the radicals R d , R e are independently selected from hydrogen (H ), optionally branched 57
  • R f is an optionally multiple bonds containing branched and / or substituted and / or cyclic hydrocarbon radical having 1 to 10, preferably 2 or 3 carbon atoms, or a styrene radical or is composed solely of ethylene or propylene or butylene or styrene radicals, or a the block-containing random copolymer or random copolymer is
  • a (> is an anion, and / or
  • R x and R are ⁇ H
  • R w is H or CH 3 and
  • R z is a radical containing at least one carbonyl group, such as -C (O) OR, -
  • C (O) NR 1 R " is where R, R 'and R" H or optionally multiple bonds containing linear or branched and / or cyclic and / or substituted and / or halogen atoms containing and / or heteroatoms containing and / or containing carbonyl hydrocarbon radicals 1 to 18 are C atoms, or in which
  • R w and R x H are,
  • R ⁇ and R z contain a carbonyl group-containing radicals such as -C (O) OR,
  • RR 'and R" are H or optionally containing multiple bonds, linear or branched and / or cyclic aliphatic or aromatic and / or substituted and / or halogen atoms and / or heteroatoms containing hydrocarbon radicals having 1 to 18 carbon atoms, or in which
  • R w , R x and R ⁇ are H and
  • R z is an aromatic or heteroaromatic radical optionally containing halogen atom and / or heteroatom-substituted, linear and / or branched alkyl substituents, or in which
  • R w R x and R ⁇ H are and
  • R z is - (CH 2 ) a -OR ''', where R 1 ''is H or an optionally carbonyl-containing alkyl radical having 1 to 22 C atoms or a polyether exclusively composed of ethylene oxide or propylene- or butylene- or styrene oxide, which is a block-wise or random copolymer containing said radicals and a is 0 or 1
  • polymerizable betaine esters of the formula (I) and / or the polymeric betamesters which, in the case of the homopolymerates, are prepared from the monomeric polymerizable betaine esters of the general formula (I) and / or in the case of the copolymerizable polyesters of the general formula (I) According to the invention, they can preferably be used in conditioners.
  • polymerizable betaine esters of the general formula (I) and / or the polymeric betaine esters which in the case of homo -poly- mensates of the monomeric polymerizable betaine esters of the general formula (I) are prepared and / or in the case of Copolyme ⁇ sate of polymerizable betaine esters of the general formula (I) and suitable comonomers of the general formula (II) are prepared, for the X -N (CH 3 ) - or - NH-
  • the agents according to the invention may preferably comprise oligomers and polymers prepared by copolymerization of from 0.5 to 100 mol% of a polymerizable betaine ester of the general formula (I) (100 mol% are homopolymers) and 0 to 99.5 mol% of an ethylenically unsaturated comonomer of the general formula (II), preferably prepared by copolymerization of from 20 to 70 mol% of a polymerizable betaine ester of the general formula (I), and from 30 to 80 mol% % of an unsaturated co-monomer of the general formula (II), more preferably prepared by copolymerization of 40 to 60 mol% of a polymerizable betaine ester of the general formula (I), and 60 to 40 mol% of an ethylenically unsaturated comonomer of the general formula ( II) Homopolymers prepared from polymerizable betaine esters of the formula (I) in the
  • compositions according to the invention may comprise polymerizable betaine esters of the formula (I) and / or polymeric betaine esters which, in the case of the homopolymers, are prepared from the monomeric polymerizable beta-esters of the general formula (I) and / or in the case of copolymerizable polyesters of the corresponding beta-esters general formula (I) and suitable comonomers of the general formula (II) are prepared in which R 9 is an aromatic fragrance alcohol is a particularly preferred perfume alcohols are thus phenylethanol, phenoxyethanol, 2-phenylpropanol, 3-phenylpropanol, ⁇ -methylbenzyl alcohol, amyl salicylate , Benzyl alcohol, benzylsilicate, butyl salicylate, cyclohexyl salicylate, dimethylbenzylcarbinol, ethyl salicylate, ethylvaniline, eugenol, hexyl sal
  • compositions according to the invention may advantageously have a pH of less than or equal to 8, preferably less than 7, more preferably between 1 and 6 and in particular between 2 and 5
  • the conditioners according to the invention may additionally comprise surfactants.
  • surfactants brings about an enhancement of the conditioning properties and also contributes to improved storage stability and dispersibility or emulsifiability of the individual conditioning agent components
  • the agents according to the invention can comprise plasticizer components.
  • plasticizer components examples include quaternary ammonium compounds, cationic polymers and emulsifiers, as used in hair care preparations and These softening compounds, which are also described in more detail below, can be present in all inventive compositions, but especially in the conditioners or in compositions with the desired softening effect
  • Suitable examples are quaternary ammonium compounds of the formulas (III) and (IV),
  • R and R 1 is an acyclic alkyl radical having 12 to 24 carbon atoms
  • R 2 is a saturated C 1 -C 4 alkyl or hydroxyalkyl radical
  • R 3 is either R, R 1 or R 2 or is a aromatic radical
  • X ⁇ represents either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof
  • Examples of cationic compounds of the formula (III) are Didecyldimethylammoniumchlo ⁇ d, Ditalgdimethylammoniumchlo ⁇ d or Dihexadecylammonium- chlo ⁇ d
  • Esterquats are distinguished by excellent biodegradability.
  • R 4 is an aliphatic alkyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds
  • R 5 is H, OH or O.
  • R 7 , R 6 independently of R 5 is H, OH or O
  • R 8 are each independently an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with O, 1, 2 or 3 double bonds is m
  • n and p can each independently of one another have the value 1, 2 or 3.
  • X " can be either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof.
  • R 5 contains the group O (CO) R 7 and for R 4 and R 7 contains alkyl radicals having 16 to 18 carbon atoms. Particular preference is given to compounds in which R 6 additionally represents OH.
  • Examples of compounds of the formula (IV) are methyl N- (2-hydroxy-ethyl) -N, Nd (tallow acyl-oxyethyl) ammonium methosulfate, B ⁇ s- (palm ⁇ toyl) -ethyl-hydroxyethyl-methyl-mon-ammonium metho-sulfate or methyl-N, N-b ⁇ s (acyl-oxyethyl) -N- (2-hydroxyethyl ) Ammonium Methosulfate
  • the acyl groups whose corresponding fatty acids have an iodine value between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45, and which have a cis / Trans-isomer ratio (in% by weight) of greater than 30 to 70, preferably greater than 50 to 50 and in particular greater than 70 have 30.
  • Methylhydroxyalkyldi-alkoyloxyalkylammonium methosulfates sold by Stepan under the trademark Stepantex ® or those known under Dehyquart ® Cognis products or those known under Rewoquat products from Goldschmidt-Witco
  • diesterquats corresponding to formula (V) under the name of Rewoquat® W 222 LM or CR 3099 can be obtained and in addition to the softness also Provide stability and color protection
  • R 21 and R 22 are each independently an aliphatic radical having 12 to 22 carbon atoms with 0 1, 2 or 3 double bonds
  • R 10 O wherein R 9 is H or a saturated alkyl radical having 1 to 4 carbon atoms, R 10 and R 11 are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R 10 alternatively also for 0 (CO) R 20 wherein R 20 is an aliphatic saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X "is an anion q can take integer values between 1 and 4
  • R 12 is --N - (CH 2 V - C - O (CO) R 15 X (VII)
  • RR 13 and R 14 independently represent a C 1 _ 4 alkyl, alkenyl or hydroxyalkyl group, R and R are each independently selected a C 8 _ 2 represents s-alkyl group and r is a number between 0 and 5,
  • short-chain, water-soluble, quaternary ammonium compounds such as trihydroxyethylmethylammonium methosulfate or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trimethylmethylammonium chloride, for example cetyltmethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride. methylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride, and t-cetylmethylammonium chloride
  • Protonated alkylammene compounds which have softening action as well as the non-quaternized, protonated precursors of the cationic emulsifiers are also suitable
  • cationic compounds which can be used according to the invention are the quaternized protein hydrolysates
  • Suitable cationic polymers include the Polyquatermum polymers as mentioned in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic Toiletry and Fragrance, Ine, 1997), in particular the Polyquaternium-6, Polyquaternium-7, Polyquater®, also known as Merquats.
  • vinyl-10 polymers Ucare Polymer IR 400, Amerchol
  • polyquaternium-4-copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups which are bonded via allyldimethylammonium chloride, cationic cellulose derivatives, such as cationic guar, such as guar hydroxypropylammonium chloride and similar quaternized guar Denvate (eg Cosmedia guar, supplier Cognis GmbH), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), for example the commercial product Glucquat ® 100, according to CTFA nomenclature a "lauryl methyl Gluceth-10 hydroxypropyl pyl Dimomum Chloride ", Copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrohdone, aminosilicone polymers and copolymers
  • Polyquaternized polymers e.g. B Luviquat Care from BASF
  • cationic African biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ® (manufacturer Cognis) polymer obtainable
  • cationic silicone sols such as the commercially available products Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimethicone), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone also referred to as amodimethicones), SM -2059 (General Electric), SLM-55067 (manufacturer Wacker) Ab ⁇ l ® quat 3270 and 3272 (manufacturer Goldschmidt Rewo, diquartare polydimethylsiloxanes Quatem ⁇ um-80), and Silicone quat Rewoquat ® SQ 1 (Tegopren® ® 6922, producers Goldschmidt Rewo)
  • R 17 may be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds s may assume values between 0 and 5
  • R 18 and R 19 are each independently H, Ci 4 alkyl or hydroxyalkyl
  • Preferred compounds are Fettsaure- amidoamme as Stearylamidopropyldimethyl- obtainable under the name Tego Am ⁇ d ® S 18 amm or erhaltliche 9124 under the name of Stepantex ® X 3 -Talgam ⁇ dopropyl-tr ⁇ methyl- ammonium methosulfate, which are distinguished not only by a good conditioning effect by farbubertra- tion-inhibiting effect and especially by their good biodegradability
  • alkylated quaternary ammonium compounds of which at least one alkyl chain is interrupted by an ester group and / or amido group, in particular N-methyl-N (2-hydroxyethyl) -N, N- (d ⁇ talgacyloxyethyl) ammonium methosulfate
  • Suitable nonionic plasticizers are, in particular, polyoxyalkylene glycol alkanoates, polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, alkyl polyglycosides, in particular sorbitan mono-, di- and tertiates, and fatty acid esters of polycarboxylic acids
  • plasticizers may be used in amounts of from 0.1 to 80% by weight, usually from 0.1 to 70% by weight, preferably from 0.2 to 60% by weight and in particular from 0.5 to 40% by weight , in each case based on the total agent, be included
  • Conditioners according to the invention may preferably contain one or more anionic surfactants, in particular those which have already been described above
  • Conditioners according to the invention may preferably comprise one or more nonionic surfactants, in particular those which have already been described above
  • gemim surfactants are generally understood as meaning compounds which have two hydrophilic groups and two hydrophobic groups per molecule. These groups are generally separated from one another by a so-called spacer disconnected This spacer is usually a carbon chain long enough for the hydrophilic groups to be spaced enough to act independently of one another.
  • Such surfactants are generally characterized by an unusually low critical micelle concentration and the ability to greatly reduce the surface tension of the water
  • Gemim surfactants is understood to mean not only dimeric, but also trimeric surfactants
  • Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis- and tertiary alcohol tert-sulfates and ether sulfates.
  • End-capped dimeric and monomeric mixed ethers are distinguished, in particular, by their bi- and multifunctional nature.
  • the end-capped surfactants mentioned have good wetting properties and are low in foam, so that they are particularly suitable for use in machine washing or cleaning processes
  • gemini polyhydroxy fatty acid amides or polyoxy hydroxy fatty acid amides as described in the relevant prior art
  • surfactants are polyhydroxy fatty acid amides of the following formula
  • the polyhydroxy fatty acid amides are known substances which are usually obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chlo ⁇ d can be
  • the group of polyhydroxy fatty acid amides also includes compounds of the following formula
  • R 24 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms
  • R 25 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxy-alkyl radical having 1 to 8 carbon atoms, wherein d.
  • 4- alkyl or phenyl radicals are preferred and [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives of this radical
  • [Z] is preferably obtained by reduced amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a reduced sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be prepared, for example, by reaction with fatty acid methyl esters in the presence of an alkoxide Catalyst are converted into the desired polyhydroxy fatty acid amides
  • inventive compositions preferably also contain amphoteric surfactants
  • betaines constitute an important class
  • Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds.
  • the starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mole of salt being formed per mole of betaine
  • halocarboxylic acids or their salts in particular with sodium chloroacetate
  • suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow formula (IX),
  • R 27 R 26 -N- (CH 2 ) n COOX 1 (IX) k - in the R 26 is alkyl and / or alkenyl radicals having 6 to 22 carbon atoms
  • R 27 is hydrogen or alkyl radicals having 1 to 4 carbon atoms
  • R 28 atoms coal alkyl groups containing 1 to 4
  • n is a number from 1 to 6
  • X 1 is an alkali metal and / or alkaline earth metal or ammonium
  • Typical examples are the carboxymethylation products of Hexylmethylamm, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, Dodecylethylmethylamin , C ⁇ m-coco alkyldimethylamine, My ⁇ styldimethylamin, cetyldimethylamine, stearyldimethylamine, Ste
  • R 32 is an alkyl radical having 5 to 21 carbon atoms
  • R 33 is a hydroxyl group
  • an OCOR 32 or NHCOR 32 radical and m is 2 or 3
  • polyvalent amines such as aminoethyl-ethanolamine (AEEA) or Diethylent ⁇ amin
  • AEEA aminoethyl-ethanolamine
  • Diethylent ⁇ amin Diethylent ⁇ amin
  • the corresponding carboxyalkylation products are mixtures of different open-chain betaines
  • Typical examples are condensation products of the above fatty acids with AEEA, preferably imidazolines based on lauric acid or C, in turn, 12 / i 4 -Kokosfettsaure which are subsequently betainized with Nat ⁇ umchloracetat
  • the agents according to the invention are in liquid form, for example in the form of conditioners or liquid detergents, etc.
  • the agents according to the invention therefore optionally contain solvents
  • Solvents that can be used in the compositions according to the invention are derived, for example, from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers, provided they are miscible with water in the concentration range indicated.
  • the solvents are selected from ethanol, n- or 1-propanol, Butanols glycol, propane or butanediol, glycerol, diglycol, propyl or butyl diglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, butoxy-propoxy-propanol (BPP), dipropylene glycol monomethyl- or -ethyl ether, di-propan
  • glycol ethers are obtainable under the trade names Arcosolv ® (Arco Chemical Co.) or Cellosolve ®, carbitol ® or Propasol ® (Union Carbide Corp.), this includes for example ButylCarbitol® ®, hexyl carbitol ®, MethylCarbitol® ®, and carbitol ® itself, (2 - (2-ethoxy) ethoxy) ethanol
  • pyrrolidone solvents such as N-alkyl-pyrrol ⁇ done, for example N-methyl 2-Pyrrol ⁇ don or NC 8 -C 12 alkyl pyrrolidone, or 2-Pyrrol ⁇ don, can also be used Further preferred as the sole solvent or as part of a solvent mixture Glyce ⁇ nderivate, in particular glycene carbon
  • alcohols which may be preferably used as co-solvents in the present invention are low molecular weight liquid polyethylene glycols, for example polyethylene glycols having a molecular weight of 200, 300, 400 or 600.
  • suitable cosolvents are other alcohols, for example (a ) lower alcohols such as ethanol, propanol, isopropanol and n-butanol, (b) ketones such as acetone and methyl ethyl ketone, (c) C 2 -C 4 polyols such as a diol or a triol, for example ethylene glycol, propylene glycol, glycene or mixtures thereof, in particular preferred is from the class of diols 1 2-octanediol
  • the inventive composition contains one or more solvents from the group comprising Ci- to C4-monoalcohols, C 2 - to C 6 -glycols, C 3 - to C 12 -glycol ethers and glycene, in particular ethanol C 3 to C 12 glycol ethers contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, especially up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms
  • Ci- to C-monoalcohols are ethanol, n-propanol, / so-propanol and tert-butanol.
  • Preferred C 2 - to C 6 -glycols are ethylene glycol, 1, 2-propylene glycol, 1, 3-propylene glycol, 1, 5 Pentand ⁇ ol, neopentyl glycol and 1, 6-Hexand ⁇ ol, in particular ethylene glycol and 1, 2-propylene glycol
  • Preferred C 3 - to C 12 glycol ethers are di-, tri-, tetra- and pentaethylene glycol, di-, T ⁇ - and tetrapropylene glycol, propylene glycol monotertiarbutyl ether and propylene glycol monoethyl ether and the solvents designated according to INCI butoxydiglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, butyloctanol, ethoxydiglycol,
  • composition according to the invention may contain one or more solvents in an amount of usually up to 40% by weight, preferably 0.1 to 30% by weight, in particular 2 to 20% by weight, particularly preferably 3 to 15% by weight %, very preferably 5 to 12% by weight, for example 5.3 or 10.6% by weight, in each case based on the total agent
  • the agent according to the invention in particular the conditioning agent, may optionally contain one or more complexing agents
  • compositions that are capable of complexing and inactivating metal ions, for example to prevent their detrimental effects on the stability or appearance of the agents, such as cloudiness, are complexing agents (INCI chelating agents), also called sequestering agents Complexing the Complex of Inhomogeneous Compounds of Calcium and Magnesium The complexation of ions of heavy metals such as iron or copper retards the oxidative decomposition of the finished compounds
  • the following complexing agents designated according to INCI which are described more closely in the International Cosmetic Ingredient Dictionary and Handbook, are suitable, for example: Aminotinylmethylene Phosphonic Acid, Beta Alanines Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin Cyclohexanediamines Tetraacetic Acid, Diammomum Citrate , Diammonium EDTA Diethylenetetramine Pentamethylene Phosphonic Acid, Dipotassium EDTA Disodium Azacycloheptane Diphosphonate Disodium EDTA, Disodium Pyrophosphate, EDTA Etidronic Acid Galactacid Acid Gluconic Acid Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin Methyl Cyclodextrin Pentapotassium T ⁇ phosphates, Pentasodium Aminotimethylenes Phosphonates, Pentasodium Ethylenediamines Tetra- methylene
  • Preferred complexing agents are tertiary amines, in particular tertiary alkanolamines (amino alcohols).
  • the alkanolamines have both amino and hydroxyl and / or ether groups as functional groups.
  • Particularly preferred tertiary alkanolamines are triethanolamine and tetra-2-hydroxypropyl-ethylenediamine ( N, N, N ', N'-Tetrak ⁇ s- (2-hydroxy-propyl) ethylend ⁇ am ⁇ n)
  • Particularly preferred combinations of tertiary amines with Zink ⁇ cinoleat and one or more ethoxyherten fatty alcohols as nonionic solubilizers and optionally solvents are described in the prior art
  • a particularly preferred complexing agent is etidron acid (1-hydroxyethyl-1-1-diphosphonic acid, 1-hydroxyethyl-1, 1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts.
  • the agent according to the invention contains the same as complexing agent etidronic acid and / or one or more of its salts
  • the agent according to the invention contains a complexing agent combination of one or more tertiary amines and one or more further complexing agents, preferably one or more complexing agents or salts thereof, in particular of trimethanolamine and / or tetra-2-hydroxypropylethylend ⁇ am ⁇ n and etidronic acid and / or one or more of their salts
  • the agent according to the invention in particular conditioning agent, advantageously contains complexing agents in an amount of usually 0 to 20% by weight, preferably 0.1 to 15% by weight, in particular 0.5 to 10% by weight, more preferably 1 to 8% by weight. , most preferably 1, 5 to 6% by weight, based on the total agent
  • the agent according to the invention, in particular conditioning agent optionally contains one or more viscosity regulators, which preferably act as thickener
  • the viscosity of the compositions can be measured by conventional standard methods (for example Brookfield Viscometer RVD-VII at 20 rpm and 20 ° C., spindle 3) and is preferably in the range from 10 to 5000 mPas.
  • Preferred liquid to gel-form compositions have viscosities of 20 up to 4000 mPas, with values between 40 and 2000 mPas being particularly preferred
  • Suitable thickeners are inorganic or polymeric organic compounds. Mixtures of several thickeners can also be used
  • inorganic thickeners examples include polysilicic acids, clay minerals such as montmorillonites, zeolites, silicic acid, aluminum silicates, phyllosilicates and bentonites
  • the organic thickeners are derived from the groups of natural polymers, modified natural polymers and fully synthetic polymers
  • Naturally derived polymers which are used as thickeners are, for example, xanthan gum, agar agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar gum, gellan gum, locust bean gum, starch, dextrins, gelatin and casein
  • Modified natural products are mainly from the group of modified starches and celluloses, examples being carboxymethylcellulose and other cellulose ethers, hydroxyethyl and - propylcellulose, highly etherified methylhydroxyethylcellulose and core flour ethers mentioned
  • a large group of thickeners which are widely used in a wide variety of applications, are the fully synthetic polymers such as polyacrylic and polymethacrylic compounds which may be crosslinked or uncrosslinked and optionally cationically modified, vinyl polymers, polycarboxylic acids, polyethers, activated polyamide derivatives, castor oil derivatives
  • Such Polymers are Acrylic Resins, Ethyl Acrylate-Acrylamide Copolymers Acrylic Acid Esters-Methacrylic Acid Ester Copolymers Ethyl Acrylate-Acrylic Acid-Methacrylic Acid Copolymers N-Methylolmethacrylamide, Maleic Anhydride-Methyl Vinyl Ether Copolymers, Polyether-Polyol Copolymers, Polyimines, Polyamides and Polyurethanes Copolymers as well as butadiene-styrene copolymers
  • Further suitable thickeners are derivatives of organic acids and their alkoxide adducts, for example ary
  • Thickeners from the mentioned classes of compounds are commercially available and are disclosed, for example, in US Pat Trade name Acusol®-820 (methacrylic acid (stearyl alcohol-20-EO) ester-acrylic acid copolymer, 30% in water, Rohm & Haas), Daltal® GT-282-S (alkyl polyglycol ether, Akzo), deuterol ®-Polymer-11 (Dicarboxylic acid co-polymer,
  • the agent according to the invention in particular conditioner agent, optionally contains one or more enzymes
  • Particularly suitable enzymes are those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydro- lases and mixtures of the enzymes mentioned. All of these hydrolases in the wash have the effect of removing stains such as protein -, fat or starchy staining and graying of cellulases and other glycosyl hydrolases can also contribute by removing pilling and microfibrils for color retention and to increase the softness of the textile for the bleaching or inhibition of color transfer also Oxireduktasen can be used
  • Enzymatic active substances obtained from bacterial stocks or fungi such as Bacillus subtilis, Bacillus licheniformis Streptomyceus gneusus and Humicola insolens are particularly suitable.
  • Proteases of the subtilin type and in particular proteases obtained from Bacillus lentus are preferably used.
  • enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or cellulase and lipase or lipolytic enzymes or protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest
  • lipolytic enzymes are the known cutinases Also have peroxidases or oxidases
  • the suitable amylases pay particular ⁇ -amylases, iso-amylases, pullulanases and pectinases
  • cellulases are preferably cellobiohydrolases, endoglucanases and ß-Glucos ⁇ -denen, which are also called cellobiases, or mixtures thereof Since different cellula
  • the enzymes may be adsorbed or coated on molded materials as molded articles in order to protect them against premature decomposition.
  • the proportion of the enzymes, enzyme mixtures or enzyme granules may be, for example, about 0.1 to 5% by weight, preferably 0.12 to about 2% by weight. amount, based on the total amount
  • the agents according to the invention may optionally contain bleaching agents.
  • bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and peroxygenic salts or persalts which give H 2 O 2 , such as persulfates or persulfuric acid.
  • the urea peroxohydrate percarbamide which can be described by the formula H 2 N-CO-NH 2 H 2 O 2 is also suitable when using the means for cleaning hard surfaces, for example, the machine dishwashing, they may also contain bleach from the group of organic bleach, if desired, although their use is also possible in principle for detergents for detergents Typical org Anic bleaches are the diacyl peroxides, such as dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, with examples being the alkyl peroxyacids and the aryl peroxyacids.
  • Preferred representatives are peroxybenzoic acid and its ring-substituted derivatives, such as alkyl peroxybenzoic acids, but also peroxy- ⁇ -naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylic acid, peroxystearic acid, ⁇ -phthimidoperacycaproic acid (phthalimidoperoxyhexanoic acid, PAP), o-carboxybenzamidoperoxycaproic acid, N-nonenenylamicoperipiperic acid and N-nonylamino-peracid, and aliphatic and araliphatic peroxydicarboxylic acids, such as 1 , 12-Diperoxycarboxylic acid 1 9-Diperoxyazelaic acid, diperoxysebacic acid diperoxy-brassylic acid, the diperoxyphthalic acids 2-decyl-diperoxybutane-1,4
  • the bleaching agents may preferably be coated to protect against premature decomposition
  • Dyes can be used in the composition of the invention, wherein the amount of one or more dyes is to be chosen so low that after application of the agent no visible residues remain Preferably, the inventive composition is free of dyes
  • the agent according to the invention may preferably contain one or more antimicrobial active ingredients or preservatives in an amount of usually 0.0001 to 3% by weight, preferably 0.0001 to 2% by weight, in particular 0.0002 to 1% by weight, particularly preferably 0, 0002 to 0.2% by weight, most preferably 0.0003 to 0.1% by weight
  • antimicrobial agents or preservatives are distinguished between bacteriostatic agents and bactericides, fungistats and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolic acid acetate.
  • antimicrobial action and antimicrobial active substance have in the
  • the antimicrobial agents are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and - formal, benzamidines, isothiazons, phthalimide derivatives, pyrazinedimates, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinone, 1, 2-dibromo-2,4-dicycanobutane, iodine o-2-propyl-butyl-carbamate, iodine, iodophores, peroxo compounds, halogen compounds and any mixtures of the foregoing
  • the antimicrobial active ingredient may be selected from ethanol, n-propanol, ⁇ -propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycine, undecylenic acid, benzoic acid, salicylic acid dihydracetic acid, o-phenylphenol, N -Methylmorpholin-aceto-nit ⁇ l (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylene-bis (6-bromo-4-chlorophenol), 4,4'-di-chloro-2'-hydroxyd ⁇ phenylether (Dichlosan), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (T ⁇ chlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-diklorophenyl) -urea N, N '- (1, 10-decanediyld ⁇ -1-pyr ⁇ d ⁇ nyl-4
  • Bakte ⁇ ozine can be used are preferably Glycine, Glycinde ⁇ vate, formaldehyde, compounds that easily split off formaldehyde, formic acid and peroxides use
  • quaternary ammonium compounds quaternary ammonium compounds
  • Benzalkoniumchlond Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ® ex Lonza, Marquat® ® ex Mason, Va ⁇ quat * ex Witco / Sherex and Hyamine * ex Lonza and as Bardac ® ex Lonza
  • Other commercially erhaltliche antimicrobial agents are N- (3-chloroallyl) -hexam ⁇ n ⁇ umchlo ⁇ d as Dowicide and Dowicil ® ® ex Dow, Benzethoniumchlo ⁇ d as Hyamine ® 1622 ex Rohm & Haas, Methylbenzethoniumchlo ⁇ d as Hyamine ® 10X ex Rohm & Haas, cetylpyridinium chloride, such as Cepacolchlo ⁇ d ex Merrell Labs
  • the agents according to the invention in particular washing or cleaning agents, conditioners or conditioning agents, optionally Bugelangesscher to improve the water absorption, the rewettability of the treated textiles and to facilitate the Bugeins of the treated textiles contain It may be in the formulations, for example silicone de ⁇ vate used These additionally improve the unwinding behavior of the wash-active formulations by their foam-inhibiting properties.
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups contain one to five carbon atoms and are completely or partially fluorinated are then amino-functional or quaternized or Si-OH, Si-H and / or S ⁇ -Cl B'nditch have
  • the viscosities of the preferred silicones are at 25 ° C in the range between 100 and 100,000 mPas, wherein the silicones can be used in amounts of between 0.2 and 5% by weight, based on the total agent
  • the agents according to the invention can be obtained by all known techniques known to the person skilled in the art.
  • the agents can be obtained, for example, directly from their raw materials by mixing, optionally with the use of high-shear mixing apparatuses.
  • in particular conditioning agents it is recommended, for example, to melt
  • the polymerizable betaine esters of the formula (I) which can be used according to the invention or polymers which can be produced therefrom can be incorporated, for example, into the conditioning agents by simple admixing
  • the conditioning agents act as a softening agent and are usually incorporated in the afterfeed of an automatic washing machine
  • a further subject of the invention is a substrate, in particular conditioning substrate, which is impregnated and / or coated with an agent according to the invention, in particular conditioning agent, which therefore contains, in addition to other constituents, the perfume composition according to the invention
  • the Substratmatenal is preferably made of porous sheet-like towels They may consist of a fibrous or cellular flexible material which has sufficient thermal stability for use in the dryer and sufficient amounts of Impragnianss- or Can withstand coating agents to effectively condition fabrics without significant bleeding or bleeding during storage.
  • These cloths include cloths of woven and non-woven synthetic and natural fibers, felt, paper or foam, such as hydrophilic polyurethane foam
  • Nonwoven fabric wipers are generally used herein.
  • Nonwovens are generally defined as adhesively bonded fibrous products having a mat or layered fibrous structure, or those comprising fibrous mats in which the fibers are randomly or randomly distributed
  • Fibers may be natural, such as wool, silk, jute, hemp, cotton, flax, sisal, or ramie, or synthetic, such as rayon, cellulose esters, polyvinyl derivatives, polyolefins, polyamides, or polyesters.
  • any fiber diameter or titer is for the present invention Invention
  • the nonwoven fabrics employed herein tend not to rupture or disintegrate due to the random or random arrangement of fibers in the nonwoven material that impart excellent strength in all directions when used in, for example, a household washer dryer.
  • Nonwoven Fabrics which a Preferred porous and planar cleaning cloths consist of one or several fiber materials, in particular cotton, refined cotton, polyamide, polyester or mixtures thereof.
  • the cleaning substrates preferably have a cloth form a surface of 10 to 5000 cm 2 , preferably from 50 to 2000 cm 2, in particular from 100 to 1500 cm 2 and more preferably from 200 to 1000 cm 2 on the grammage of the material is usually between 20 and 1000 g / m 2 , preferably from 30 to 500 g / m 2 and in particular from 50 to 150 g / m 2
  • Konditiomersubstrate can be obtained by drowning or impregnation or by melting the inventive agents or conditioners on a substrate
  • a further subject of the invention is the use of a conditioning agent or a conditioning substrate according to the invention in a textile conditioning process, such as a post-pulp, a textile drying process and a textile dry cleaning or textile freshening process.
  • a conditioned substrate eg wood, paper, leather can
  • Preferred agents according to the invention are liquid detergents, preferably containing surfactants, and other customary ingredients of detergents or cleaners.
  • suitable liquid detergents can be used as thickening system, based in each case on the entire composition a) 0.1 to 5% by weight of a polymeric thickener , b) 0.5 to 7% by weight of a boron compound and c) 1 to 8% by weight of a complexing agent
  • aqueous, highly viscous liquid detergents are preferred whose content of surfactant (s) is above 35% by weight
  • Suitable thickening agents also called swelling agents, such as eg alginates or agar agar have been described above.
  • Preferred aqueous spray detergents contain, as thickening system, 0.2 to 4% by weight, preferably 0 to 3% by weight and in particular 0 4 to 1.5% by weight of a polysaccharide
  • a preferred polymeric thickener is xanthan gum, a microbial anionic heteropolysaccharide produced by Xanthomonas campestris and some other species under aerobic conditions and having a molecular mass of 2 to 15 million daltons.
  • Xanthan gum is made from a chain of ⁇ -1,4-linked glucose (Cellulose) formed with side chains The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate, whereby the number of pyruvate units determines the viscosity of xanthan gum
  • Liquid washing detergents according to the invention may preferably contain a boron compound which is used in amounts of from 0.5 to 7% by weight.
  • boron compounds which can be used in the context of the present invention are boric acid, boron oxide, alkali metal borates such as ammonium, sodium and potassium -ortho -meta and -pyroborate borax in its various stages of hydration and polyborates such as alkali metal pentaborates
  • Organic boron compounds such as esters of boric acid can also be used as well as Products of H 3 BO 3 with nonionic surfactants and / or fragrances
  • Preferred liquid detergents contain from 0.5 to 4% by weight, preferably from 0.75 to 3% by weight and in particular from 1 to 2% by weight, of boric acid and / or sodium tetraborate
  • liquid washing detergents according to the invention can contain from 1 to 8% by weight of a complexing agent.
  • Particularly preferred liquid detergents contain citric acid or sodium citrate, with liquid detergents being preferred which contain from 2.0 to 7.5% by weight, preferably from 3.0 to 6.0% by weight. and in particular from 4.0 to 5.0% by weight of sodium citrate
  • the liquid detergents according to the invention preferably contain tenside (s), whereby anionic, nonionic, cationic and / or amphoteric surfactants are used. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants, the proportion of nonionic surfactants may preferably be greater than the proportion of anionic surfactants.
  • tenside s
  • anionic, nonionic, cationic and / or amphoteric surfactants preference is given to mixtures of anionic and nonionic surfactants, the proportion of nonionic surfactants may preferably be greater than the proportion of anionic surfactants.
  • sugars and / or sugar derivatives such as Alkylpolyglucoside or Cyclodext ⁇ ne can also be done
  • a solid, unperfumed detergent was proportionally divided in the ratio 1 2
  • the component 1 was then perfumed with a perfume oil of the "citrus freshness” by spraying perfumed component 2 with a stained perfume of the Phil ⁇ chtung "balsamic, nourishing” by spraying
  • a solid, unperfumed compact detergent with spherical basic structure was separated by means of a wedge-shaped installation aid on a conveyor belt into two identical partial streams.
  • One partial stream was sprayed with a very liquid perfume oil of the type "cologne (eau de cologne)", the other partial stream, to which still colored speckles were added, with a much more viscous "flower accord” perfume oil.
  • Em liquid detergent was prepared as a base and provided with a perfume type "mandarin lemon”
  • Another, different-smelling perfume composition II was introduced into particles, which were then so suspended in the liquid detergent so that they then neither framed nor sagged
  • the particle collective which was incorporated into the liquid detergent, although based on the individual particles in each case the same Cosmeticolkomposition II, but in very different concentrations It thus resulted in a product in which two differently fragrant perfumeole were not evenly distributed in relation to each other in the product

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  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Fats And Perfumes (AREA)
  • Detergent Compositions (AREA)
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Abstract

Les produits de consommation parfumés classiques, comme par ex. les lessives, se caractérisent par une fragrance homogène sur l'ensemble du produit. A l'inverse, l'invention concerne des produits de consommation présentant une fragrance qui contient au moins deux différentes huiles parfumées aux odeurs différentes, qui ne sont pas réparties de manière homogène proportionnellement les unes aux autres dans le produit. Ce concept de produit novateur permet à l'utilisateur d'expérimenter différentes impressions olfactives avec un seul et même produit, par ex. de la lessive en poudre et de produire de multiples odeurs au moment de l'utilisation. L'invention permet de mettre définitivement un terme aux limites et à la monotonie inhérentes aux produits de consommation parfumés classiques en matière de parfum.
EP06776776A 2005-09-09 2006-08-11 Produits de consommation a odeurs multiples Withdrawn EP1928992A1 (fr)

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DE102005043189A DE102005043189A1 (de) 2005-09-09 2005-09-09 Verbrauchsprodukte mit Duftvielfalt
PCT/EP2006/007957 WO2007028479A1 (fr) 2005-09-09 2006-08-11 Produits de consommation a odeurs multiples

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WO (1) WO2007028479A1 (fr)

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