EP1988983A1 - Cartouche filtrante permettant de récupérer des hydrocarbures halogénés - Google Patents
Cartouche filtrante permettant de récupérer des hydrocarbures halogénésInfo
- Publication number
- EP1988983A1 EP1988983A1 EP07726408A EP07726408A EP1988983A1 EP 1988983 A1 EP1988983 A1 EP 1988983A1 EP 07726408 A EP07726408 A EP 07726408A EP 07726408 A EP07726408 A EP 07726408A EP 1988983 A1 EP1988983 A1 EP 1988983A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter
- filter cartridge
- cartridge according
- halogenated hydrocarbons
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 150000008282 halocarbons Chemical class 0.000 title claims abstract description 18
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003983 inhalation anesthetic agent Substances 0.000 claims abstract description 15
- 238000003795 desorption Methods 0.000 claims abstract description 12
- 230000008929 regeneration Effects 0.000 claims abstract description 11
- 238000011069 regeneration method Methods 0.000 claims abstract description 11
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 9
- 239000002808 molecular sieve Substances 0.000 claims abstract description 8
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000010521 absorption reaction Methods 0.000 claims abstract description 6
- 238000007789 sealing Methods 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 239000010457 zeolite Substances 0.000 claims description 38
- 238000001179 sorption measurement Methods 0.000 claims description 23
- 229910021536 Zeolite Inorganic materials 0.000 claims description 18
- 239000002594 sorbent Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 14
- 238000011084 recovery Methods 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 230000015556 catabolic process Effects 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 238000012544 monitoring process Methods 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- 239000004065 semiconductor Substances 0.000 claims description 2
- 230000002262 irrigation Effects 0.000 claims 2
- 238000003973 irrigation Methods 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229960002078 sevoflurane Drugs 0.000 abstract description 9
- DFEYYRMXOJXZRJ-UHFFFAOYSA-N sevoflurane Chemical compound FCOC(C(F)(F)F)C(F)(F)F DFEYYRMXOJXZRJ-UHFFFAOYSA-N 0.000 abstract description 9
- 229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 abstract description 8
- 238000009835 boiling Methods 0.000 abstract description 6
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 abstract description 3
- 230000003444 anaesthetic effect Effects 0.000 abstract description 3
- 229940075554 sorbate Drugs 0.000 abstract description 3
- 229960003537 desflurane Drugs 0.000 abstract description 2
- DPYMFVXJLLWWEU-UHFFFAOYSA-N desflurane Chemical compound FC(F)OC(F)C(F)(F)F DPYMFVXJLLWWEU-UHFFFAOYSA-N 0.000 abstract description 2
- PIWKPBJCKXDKJR-UHFFFAOYSA-N Isoflurane Chemical compound FC(F)OC(Cl)C(F)(F)F PIWKPBJCKXDKJR-UHFFFAOYSA-N 0.000 abstract 1
- 229960002725 isoflurane Drugs 0.000 abstract 1
- 229940035674 anesthetics Drugs 0.000 description 14
- 239000003193 general anesthetic agent Substances 0.000 description 14
- 239000012071 phase Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000005755 formation reaction Methods 0.000 description 6
- 238000011068 loading method Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 4
- 238000004821 distillation Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 206010002091 Anaesthesia Diseases 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000037005 anaesthesia Effects 0.000 description 2
- 239000003994 anesthetic gas Substances 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000001944 continuous distillation Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229960000305 enflurane Drugs 0.000 description 1
- JPGQOUSTVILISH-UHFFFAOYSA-N enflurane Chemical compound FC(F)OC(F)(F)C(F)Cl JPGQOUSTVILISH-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229960003132 halothane Drugs 0.000 description 1
- BCQZXOMGPXTTIC-UHFFFAOYSA-N halothane Chemical compound FC(F)(F)C(Cl)Br BCQZXOMGPXTTIC-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. ventilators; Tracheal tubes
- A61M16/0087—Environmental safety or protection means, e.g. preventing explosion
- A61M16/009—Removing used or expired gases or anaesthetic vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. ventilators; Tracheal tubes
- A61M16/0087—Environmental safety or protection means, e.g. preventing explosion
- A61M16/009—Removing used or expired gases or anaesthetic vapours
- A61M16/0093—Removing used or expired gases or anaesthetic vapours by adsorption, absorption or filtration
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. ventilators; Tracheal tubes
- A61M16/10—Preparation of respiratory gases or vapours
- A61M16/1045—Devices for humidifying or heating the inspired gas by using recovered moisture or heat from the expired gas
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. ventilators; Tracheal tubes
- A61M16/22—Carbon dioxide-absorbing devices ; Other means for removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0415—Beds in cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2202/00—Special media to be introduced, removed or treated
- A61M2202/02—Gases
- A61M2202/0241—Anaesthetics; Analgesics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/206—Organic halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40086—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
- B01D2259/4141—Further details for adsorption processes and devices using different types of adsorbents within a single bed
- B01D2259/4145—Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
- B01D2259/4146—Contiguous multilayered adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4533—Gas separation or purification devices adapted for specific applications for medical purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0454—Controlling adsorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
- Y10S95/903—Carbon
Definitions
- the invention relates to a filter cartridge for the recovery of low-boiling halogenated hydrocarbons (HKW), in particular for collecting volatile anesthetics from the expired air of anesthetized patients, ie inhalation anesthetics.
- HKW low-boiling halogenated hydrocarbons
- Easily vaporizable anesthetics commonly used in medical practice, such as halothane, sevoflurane, enflurane, isofiurane, and desfiuran are chlorofluorocarbons or fluorocarbons, which are usually completely released into the environment during or after anesthesia, and can harm patients and medical personnel.
- the prior art for the removal of HKW from associated gases is characterized by adsorption filters, which act on the basis of microporous sorbents such as activated carbons and zeolites for the purpose of temporary retention and storage of the gases.
- Reactive activated carbons are already suitable for the purification of process or exhaust air (DE 37 13 346, DE 39 35 094 and DE 40 03 668).
- the prerequisites for a high sorption capacity of the sorption devices, combined with optimum regenerability, are already set forth in the documents DD 239 947, DE 36 28 858 and DE 37 31 688.
- the recovery of HKW can be done economically with a high degree of recovery by desorption only at high temperatures and low pressures. As a result of the heat treatment, however, structural damage to the sorbents as well as the formation of halogen-containing decomposition products of HKW occur.
- Zeolites have a high thermal stability and a low catalytic activity with respect to the formation of toxic products from HKW.
- the sorption of water on these so-called hydrophobic zeolites is noticeably suppressed in favor of HKW.
- a known method for separating and recovering inhalation anesthetics (DE 42 08 521) relates to the adsorption on an activated carbon or zeolite filter with the exception of the accompanying nitrous oxide, wherein the remaining further associated gases are then fed to a catalytic afterburning.
- the required temperatures up to 550 ° C are still uneconomically high.
- the device recoverable drugs are irreversibly withdrawn.
- a hydrophobic zeolitic molecular sieve with a narrow pore distribution is used which selectively separates active substances of the group of halogenated ethers of higher hydrocarbons.
- the desorption is carried out in a canister by means of a nitrogen carrier gas stream at 30 ° C to 150 ° C.
- the anesthetics are condensed and recovered. Temperatures of 30 ° C to 40 ° C, however, were not sufficient for an economically high degree of recovery. On the other hand, temperatures above about 140 ° C. led to discoloration of the sorbent particles as a result of structural aging and the formation of coke deposits.
- the spatial separation of the adsorption from the regeneration circuit does not yet meet the economic requirements of a circulation of exhalation gases.
- the filter cartridge for recovering halogenated hydrocarbons comprises a container (19) with a gas inlet (3), wherein the container (19) has a filter insert (20) and a closure (2) with a lid (4) and with a gas outlet (5) connected and by means of seals (6; 6 ') and a sieve plate (21) with the lid (4) is combined, a zeolite (8) in the filter insert (20) with openings (7), wherein the Filter insert (20) with its bottom to recesses (9) in the container (19) adapts.
- a sensor for level monitoring is located at the filter output a sensor for level monitoring.
- the filter cartridge consists essentially of a container with a jacket around a filter cartridge and with the gas inlet for the Exhalationsgase, which is connected via a closure with a lid and this with the gas outlet.
- the closure is expedient a screw or bayonet connection.
- the filter cartridge has a filter cartridge with an upper ring with a screen plate for its attachment, which is inserted by means of sealing rings between the upper edge of the container and the lid and clamped there.
- the filter insert with its lateral openings in the wall and in the bottom is the zeolite in the form of a Bulk.
- an annular gap for the inhalation gases flowing into it and for the return of the regenerating water phase.
- openings for the passage of gas and liquid are provided only in a larger and lower wall portion of the container while they are missing in the wall portion of the lid or closed by the fitting in the upper sealing portion wall of the container.
- the filter cartridge has a high degree of slimming, which is that the length of the lower portion with the openings in the filter cartridge considerably exceeds the diameter of this insert and the length of the portion with the missing openings.
- the flexible filter element adapts with its lower bottom to the depressions in the container. At the same time, a bead-like lower tolerance gap is released, through which water draining from the filter insert can flow into the return flow with little hindrance.
- the depressions are introduced in the form of a reinforcing rib in the bottom of the container.
- the filter cartridge is holistically made of a suitable polymeric material with greatly reduced swelling capacity compared to inhalation anesthetics.
- the gas inlet is optionally connected via connectors, plugs and hoses with a gas supply and a steam supply.
- the steam supply simultaneously forms a return for the steam generator.
- the lid with the gas outlet leads on the one hand to an exhaust air duct and to a suction for exempt from Exhalationsgasen
- the gas inlet is also connected via connectors either to the anesthesia machine or to the steam generator.
- the filter cartridge When loading the filter cartridge is a multi-stage adsorption of exhalation gases in cross flow.
- the loading of the successive and still “fresh” stages always takes place with the same initial charge of exhalation gases.
- the loading of the gases gradually decreases to the desired residual charge, even small residence times are sufficient to achieve the required filter yield even with large throughputs of gases or vapors.
- the gases pass through bedding layers, which simultaneously serve as mist eliminators.
- the mode of operation of the filter cartridge is optimized in the interest of a high space utilization of sorptionsulphate part.
- the anesthetic gases used thus have at the top of the filter insert with the hydrophobic zeolites on "good" breakthrough curves, that is with a steep and clearly local and temporal characteristics of the transition by forming a sharp boundary between the loaded and still unladen parts of the bed of zeolite ,
- activated carbons in particular hydrophobic Molekularsiebkohlen can be used with a water absorption capacity below 2% by mass in the filter, wherein the temperature is desirably lowered for the desorption of HKW.
- Combinations of zeolites and molecular sieves in the form of a layered succession prove to be advantageous. At least one layer each of a zeolite and a molecular sieve coal should be used. The layer with lower sorption capacity should be located in the vicinity of the openings in the breakthrough region of the filter cartridge, the layer with higher sorption capacity should be located in the region of the gas inlet of the filter cartridge.
- the height of the filter insert exceeds its diameter at least four times.
- the height of the breakthrough area the height of the filter insert by at least eight times.
- the inner diameter of the container is about 1, 2 times the outer diameter of the filter cartridge.
- the optimal residence time of the anesthetic gases is determined by the gas load and the flow-through length of the filter cartridge.
- the speeds of the gases or vapors in the annular gap can be 0.2 to 0.3 m / s, the showering strengths during regeneration up to 0.4 m 3 / (m 2 h) without flooding within the filter cartridge.
- the openings to be provided in the filter cartridge are only slightly smaller than those of the commercial formations of zeolite, which are cheap as a hollow cylinder with the main dimensions of 6/3 or 7/4 mm or as a solid cylinder 2 or 4 mm supplied. As a result of this size of the openings advantageous conditions for the flow through the fluid through the wall and the bottom portion of the filter insert are set. But it is also possible to use as filter cartridges commercially available sieves or knitted fabrics of sufficient stability.
- a sorbent advantageously modified and / or dealuminated zeolites are used with a water absorption capacity below 2% by mass, the temperature is lowered to desorb the halogenated hydrocarbons.
- the inventive method for recovering halogenated hydrocarbons using the filter cartridge described above is that the halogenated hydrocarbons are removed from associated gases and / or temporarily stored on adsorption using modified and / or dealuminated zeolites temporarily released and targeted again.
- a vapor carrier Using a vapor carrier, the cooling of the vapors leads to the formation of a phase-related vorgetrennten mixture and that the specifically lighter water layer is mainly attributed to the evaporation process of the water, resulting harmful products remain in a water cycle, thereby periodically or deliberately discharged and the specific heavier layer of halogenated hydrocarbons is fed to repeated use.
- Fig.l The filter cartridge for the recovery of inhalation anesthetics in the adsorption
- Fig. 2 Vapor pressures for water I Anesthetic mixtures as a function of the temperature
- Fig. 3 Sensor at the filter outlet for filling level monitoring
- Tab.1 Properties of inhalation anesthetics in combination with water vapor.
- the filter cartridge 1 essentially consists of a container 19 with the gas outlet 5, which is united via the closure 2 with the lid 4 and the container 19 with the gas inlet 3.
- the container 19 has a filter cartridge 20, which by means of the sealing rings 6; 6 'and a screen plate 22 is connected to the lid 4.
- the zeolite 8 is located in the filter insert 20 with the openings 7.
- the filter insert 20 adapts with its bottom to the depressions 9 in the container 19.
- the gas inlet 3 is optionally with a gas supply 10 and a steam supply 11, which simultaneously forms a return 12 and connected to a steam generator 13.
- the lid 4 with the gas outlet 5 leads on the one hand to an exhaust air duct 14 and to a suction 15, on the other hand to a Abdampe Adjust 16 via a capacitor 17 to a liquid outlet 18th
- the filter cartridge allows adsorption of the inhalation anesthetics on already desorbed sorbents by an exhalation of the gases optionally through this is passed through.
- Tab.l enters a relative boiling point reduction of the anesthetic-water mixture within the limits of 4 to 11%.
- the two components of the boiling mixture of inhalation anesthetics and water over the entire concentration range behave as if they were each alone: their partial pressure in the vapor phase corresponds to the saturation pressure at the mixture boiling temperature, and the operating pressure chosen here is the normal pressure of the saturation pressures of the two Components according to Figure 2 together.
- the almost complete insolubility of liquid inhalation anesthetics and water has an advantageous effect in terms of lowering the boiling point.
- the sensitive anesthetics are thermally protected. Their possible breakdown products pass through extraction into the water phase.
- a filter cartridge is filled with a microporous adsorbent (activated carbon, hydrophobic zeolite) and used to capture volatile anesthetics from the expiratory air of anesthetized patients.
- a sensor semiconductor sensor for the detection of CFCs
- An electronic circuit controls depending on the sensor values differently colored LEDs (green, 2x yellow, red), so that an optical breakdown control is given. From the full and attributable filters, the anesthetics are recovered by desorption (Figure 3).
- Example 4 Example 4:
- a filter cartridge according to Example 1 with an empty mass of 0.77 kg was filled with about 0.6 kg of zeolite (Tricat).
- Tricat zeolite
- an increase in mass of 0.095 kg, ie 12% was observed.
- the loaded zeolite was placed in the filter cartridge in a distillation bridge over the steam generator.
- a descending intensive condenser was attached and the condensate cooled at -0.5 0 C in a template.
- a temperature of 57 ° C. could be ascertained, which increased to 100 ° C. over a short period of about 20 minutes.
- the filter cartridge 20 is filled with zeolites of different structure, such as Z-700, Z-700 fine and TZF, which have a sorption capacity of 0.21 - 0.26 kg / kg sorbent. At relatively small times (60-90 min) for the breakthrough of sevoflurane a sharp emerges Profile of breakthrough curves. The capacity of the filter 1 is utilized, but relativized due to the shorter usage times.
- the filter cartridge 20 is a molecular sieve having a sorption capacity of 0.78 kg / kg sorbent. It turns at relatively longer times (about 270 min) for the use of the filter cartridge 1, a flat breakthrough curve. The filter is not fully utilized despite its higher capacity in its effectiveness.
- the filter cartridge 20 is filled to three-quarters proportions with a hydrophobic Molekularsiebkohle and to a quarter with a zeolite.
- the zeolite is located above the coal.
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Anesthesiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Emergency Medicine (AREA)
- Pulmonology (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Hematology (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07726408A EP1988983A1 (fr) | 2006-02-17 | 2007-02-16 | Cartouche filtrante permettant de récupérer des hydrocarbures halogénés |
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006008320A DE102006008320B4 (de) | 2006-02-17 | 2006-02-17 | Filterpatrone zur Rückgewinnung niedrigsiedender halogenierter Kohlenwasserstoffe |
| DE102006027127A DE102006027127A1 (de) | 2006-06-02 | 2006-06-02 | Verfahren und Vorrichtung zur Rückgewinnung von halogenierten Kohlenwasserstoffen und Ethern |
| EP06117003 | 2006-07-11 | ||
| DE102006053216.3A DE102006053216B4 (de) | 2006-02-17 | 2006-11-11 | Filterpatrone zur Rückgewinnung niedrigsiedender halogenierter Kohlenwasserstoffe |
| EP07726408A EP1988983A1 (fr) | 2006-02-17 | 2007-02-16 | Cartouche filtrante permettant de récupérer des hydrocarbures halogénés |
| PCT/EP2007/051520 WO2007093640A1 (fr) | 2006-02-17 | 2007-02-16 | Cartouche filtrante permettant de récupérer des hydrocarbures halogénés |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1988983A1 true EP1988983A1 (fr) | 2008-11-12 |
Family
ID=37946507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07726408A Ceased EP1988983A1 (fr) | 2006-02-17 | 2007-02-16 | Cartouche filtrante permettant de récupérer des hydrocarbures halogénés |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8038772B2 (fr) |
| EP (1) | EP1988983A1 (fr) |
| DE (1) | DE102006053216B4 (fr) |
| WO (1) | WO2007093640A1 (fr) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010056245A1 (fr) * | 2008-11-13 | 2010-05-20 | Donaldson Company, Inc. | Systèmes et procédés de gestion de cycles de fractionnateur |
| WO2012064245A1 (fr) * | 2010-11-11 | 2012-05-18 | Nordic Gas Cleaning Ab | Appareil et procédé de traitement d'un gaz anesthésique résiduel par adsorption/désorption |
| WO2014094139A1 (fr) | 2012-12-22 | 2014-06-26 | Dmf Medical Incorporated | Circuit anesthésique ayant une membrane à fibres creuses |
| KR20150131279A (ko) * | 2013-03-15 | 2015-11-24 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 층상 필터 카트리지용 사용 수명 종료 표시 시스템 |
| DE202014101587U1 (de) | 2014-04-03 | 2014-06-12 | Zeosys Gmbh | Vorrichtung zur Rückgewinnung von halogenierten Kohlenwasserstoffen |
| CN104524887B (zh) * | 2015-01-09 | 2016-03-09 | 成都冠禹科技有限公司 | 一种全麻醉废气净化装置 |
| CN104826438B (zh) * | 2015-05-14 | 2016-06-22 | 江西省太平洋节能环保科技有限公司 | 一种粉尘废气处理装置 |
| CN104826437A (zh) * | 2015-05-14 | 2015-08-12 | 周末 | 一种净化麻醉废气的装置 |
| BR102015022017A2 (pt) * | 2015-09-09 | 2017-03-14 | Copeen Treinamento e Consultoria em Anestesia EIRELI | aperfeiçoamentos introduzidos em filtro de absorção de anestésicos inalatórios halogenados para circulação extracorpórea |
| GB2548548B (en) * | 2016-02-23 | 2020-12-09 | Sagetech Medical Equipment Ltd | Improvements in the capture and elution of halocarbons by supercritical fluids |
| RU169418U1 (ru) * | 2016-08-29 | 2017-03-16 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) | Фильтр сорбционной очистки сточной воды |
| CN108358746A (zh) * | 2018-04-12 | 2018-08-03 | 南通山剑防腐科技有限公司 | 一种氯乙烷分离系统 |
| EP3693077B1 (fr) | 2019-02-05 | 2021-04-21 | ZeoSys Medical GmbH | Procédé en deux étapes de récupération des hydrocarbures halogénés |
| CN110124410A (zh) * | 2019-04-17 | 2019-08-16 | 广东绿岛风空气系统股份有限公司 | 一种改进的多体全效复合空气净化过滤网 |
| LU102192B1 (de) * | 2020-11-12 | 2022-05-12 | Draegerwerk Ag & Co Kgaa | Aufnahme-Anordnung und Verfahren umfassend eine Filtereinheit zum Aufnehmen von Gas aus einem medizinischen Gerät |
| EP3922342A3 (fr) * | 2020-06-12 | 2022-03-09 | Drägerwerk AG & Co. KGaA | Agencement de réception et procédé comprenant une unité de filtre permettant de recevoir du gaz provenant d'un appareil médical |
| EP3909629A1 (fr) | 2020-09-08 | 2021-11-17 | ZeoSys Medical GmbH | Système et procédé de filtration de gaz respiratoire ainsi que réservoir tampon pour un système de filtration de gaz respiratoire |
| SE2330449A1 (en) * | 2023-10-10 | 2025-04-11 | Medclair AB | An apparatus and method for collecting anesthetic gases and a method for producing a reversible adsorbent |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3375933A (en) * | 1965-02-01 | 1968-04-02 | Fram Corp | Semi-rigid polymer encapsulated filter medium containing an unencapsulated adsorbent material |
| US3592191A (en) * | 1969-01-17 | 1971-07-13 | Richard R Jackson | Recovery of anesthetic agents |
| DE2001108A1 (de) * | 1970-01-12 | 1971-08-05 | Air Inc Van | Luftfilterpatrone |
| US3680283A (en) * | 1970-09-21 | 1972-08-01 | Gen Motors Corp | Air dryer assembly for vehicle leveling system |
| US3941573A (en) * | 1974-05-02 | 1976-03-02 | James Frederick Chapel | Apparatus for removing anesthetic gases |
| GB2109268B (en) * | 1981-11-16 | 1984-10-03 | Process Scient Innovations | Gas purifiers |
| AU601817B2 (en) * | 1987-03-04 | 1990-09-20 | Union Carbide Canada Limited | Process for the recovery of halogenated hydrocarbons in a gas stream |
| US5231980A (en) * | 1987-03-04 | 1993-08-03 | Praxair Canada, Inc. | Process for the recovery of halogenated hydrocarbons in a gas stream |
| SE459155B (sv) * | 1987-04-14 | 1989-06-12 | Siemens Elema Ab | Foerfarande och anording foer aateranvaendning av anestesimedel |
| IT1249000B (it) * | 1990-06-26 | 1995-02-11 | Getters Spa | Purificatore di gas munito di un sensore del termine della vita utile |
| US6306290B1 (en) * | 2000-06-26 | 2001-10-23 | Patrick J. Rolfes | Water filter replacement indicator |
| US6497756B1 (en) * | 2000-09-12 | 2002-12-24 | North Safety Products, Inc. | Service life indicator for respirator cartridge |
| US20050203327A1 (en) * | 2004-03-09 | 2005-09-15 | Stevan Jovanovic | Hydrocarbon separation process |
| DE102004033588A1 (de) * | 2004-07-06 | 2006-02-16 | Stach, Helmut, Prof. Dr. | Verfahren und Vorrichtung zur sorptiven Rückgewinnung halogenierter Kohlenwasserstoffe, vor allem für halogenierte Inhalationsanästhetika |
-
2006
- 2006-11-11 DE DE102006053216.3A patent/DE102006053216B4/de not_active Expired - Fee Related
-
2007
- 2007-02-16 WO PCT/EP2007/051520 patent/WO2007093640A1/fr not_active Ceased
- 2007-02-16 EP EP07726408A patent/EP1988983A1/fr not_active Ceased
-
2008
- 2008-08-18 US US12/193,265 patent/US8038772B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2007093640A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102006053216A1 (de) | 2008-05-15 |
| US20090101010A1 (en) | 2009-04-23 |
| US8038772B2 (en) | 2011-10-18 |
| WO2007093640A1 (fr) | 2007-08-23 |
| DE102006053216B4 (de) | 2015-11-26 |
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