[go: up one dir, main page]

EP1954873B1 - Procede pour la fabrication de papier - Google Patents

Procede pour la fabrication de papier Download PDF

Info

Publication number
EP1954873B1
EP1954873B1 EP06820101A EP06820101A EP1954873B1 EP 1954873 B1 EP1954873 B1 EP 1954873B1 EP 06820101 A EP06820101 A EP 06820101A EP 06820101 A EP06820101 A EP 06820101A EP 1954873 B1 EP1954873 B1 EP 1954873B1
Authority
EP
European Patent Office
Prior art keywords
fiber
fraction
fiber fraction
fine
long
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP06820101A
Other languages
German (de)
English (en)
Other versions
EP1954873A2 (fr
Inventor
Juan Cecchini
Antti Poikolainen
Hannu LEPOMÄKI
Petteri Soini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valmet Technologies Oy
Original Assignee
Metso Paper Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metso Paper Oy filed Critical Metso Paper Oy
Publication of EP1954873A2 publication Critical patent/EP1954873A2/fr
Application granted granted Critical
Publication of EP1954873B1 publication Critical patent/EP1954873B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D5/00—Purification of the pulp suspension by mechanical means; Apparatus therefor
    • D21D5/02—Straining or screening the pulp
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00—Wet end of machines for making continuous webs of paper
    • D21F1/66—Pulp catching, de-watering, or recovering; Re-use of pulp-water
    • D21F1/68—Pulp catching, de-watering, or recovering; Re-use of pulp-water using hydrocyclones
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
    • D21H23/06—Controlling the addition
    • D21H23/08—Controlling the addition by measuring pulp properties, e.g. zeta potential, pH

Definitions

  • the invention relates to a method for manufacturing paper or board from a fiber raw material, comprising the step of fractionating the fiber raw material into a long fiber fraction, which is rich in long fibers, and a fine fiber fraction, which is rich in short fibers and fines.
  • the properties of paper or board are to a great extent determined by the type of the fiber raw material used and the manner in which the paper machine and the web forming process treat these raw materials. Only a few paper grades are produced from a single fiber type alone. In most cases, at least two types of fiber raw material are used for paper. Several paper grades, in particular those intended for printing, contain considerable amounts of mineral fillers. Moreover, dry-strength additives, sizes, retention aids and several other papermaking chemicals are often added to the paper stock in an amount of a few percent. The percentage of the latter kind of additives is, however, small as compared with the amount of fillers, whose proportion is most generally 10 to 40% of the weight of the paper.
  • the stock used for making paper is a complex, multi-phase mixture of fibers, fines, fillers and other additives.
  • the properties of all these components are continually changing, which may lead to upsets in the process.
  • a significant portion of the paper stock does not become paper in its first pass down the production line.
  • the amount of broke and white water that must be recycled varies considerably. Dewatering of the stock on the wire section may cause an amount of valuable components, above all fines and fillers, to be lost along with the white water removed from the stock through the forming wires, resulting in poor retention.
  • Pulps used as fiber raw material are in general more or less heterogenous.
  • the fibers of pulp are widely differing in their morphology, mechanical properties and chemical composition, some of them having a high papermaking potential that can be exploited as such for the production of high quality papers, while others have no potential at all unless extensively processed.
  • Appropriate classification of pulp into grades having different properties is considered an attractive possibility for utilizing its full potential.
  • Savings in energy, chemicals and raw material costs can be envisaged, and further mechanical treatment (e.g. refining) can be focused selectively on those fibers that need it, while the chemical treatment of each fraction (e.g. bleaching) can be performed with the proper agents and dosages. Thanks to fiber fractionation, pulp quality targets can be achieved with lower energy and/or chemical consumption and without damaging the fibers through excessively severe processing.
  • US 5,133,832 discloses a process for preparation of waste paper stock. After pulping and cleaning, the fiber raw material is fractionated by filtering through a continuously moving mesh belt of a predetermined mesh size which will retain substantially all of the fibers of greater than a predetermined length as a first fraction, a second fraction comprising the majority of the liquid component of the feed suspension along with small contaminant particles and the remaining fines. These two fractions are then treated separately by bleaching the first fraction and recovering the fines from the second fraction, after which the fines and the first fraction are recombined for further treatment and use.
  • US 4,731,160 discloses a method and apparatus for the bleaching of mechanical pulp.
  • Mechanical pulp directly from a secondary refiner is separated by first and second centrifugal separators into a fines fraction, which is under about 200 mesh, and into a fiber fraction.
  • the fiber fraction and the fines fraction are then bleached separately, after which they are recombined before passage to a paper products production machine. Because of the poor drainage characteristics of the fines it would be impractical to use displacement bleaching or washing techniques with the fines fraction.
  • US 4,781,793 discloses a method for improving properties of paper, in particular its retention.
  • a basic stock is divided into two separate fractions on the basis of fiber length and the fibers in each fraction are treated in accordance with specific objectives.
  • the stocks are then passed into distinct layers of a multichannel headbox.
  • WO-A-00/22233 discloses a process for making tissue paper, where fiber fractions are treated separately and fractions are combined as separate layers in the manufacturing process.
  • EP-A-838 550 discloses a method of retention aid addition for paper board production, where pulp fines from the white water system of the paper machine are mixed with one or more retention agents to form flocs, flocs are mixed with long fiber stock and mixed stock is fed to the headbox.
  • composition of certain fiber raw materials such as hardwood pulps, recycled fibers or agricultural fibers
  • variations tend to cause fluctuations in the properties of the paper and problems in the runnability of the paper machine.
  • Another problem resulting from varying fines content is the difficulty of obtaining a stable and constant level of retention.
  • the new method comprises the following steps:
  • fractionation is carried out at the stock preparation department before the different fiber raw materials are mixed to form a mixed stock.
  • more than one fiber raw material is used. It may be sufficient that only the most difficult fiber raw material, which has the largest variations in its fiber and fines content, is fractionated.
  • two or more of the fiber raw materials may be fractionated separately, after which the long fiber fractions are combined and treated together and the fine fiber fractions are combined and treated together.
  • the fiber raw materials may be fractionated as a mixture of different fiber raw materials. In that case fractionation may be carried out as late as in the approach flow system of the paper machine.
  • Fractionation may be carried out by any suitable means, using e.g. hole, slot or wire mesh screens, gap washers, hydrocyclones, etc. It is advisable that the fractionation system is modular so that it comprises two or more steps.
  • Refining only the long fiber fraction will produce savings in the form of smaller size of refiner equipment and lower consumption of energy. It may also improve the strength of the paper.
  • Additives that are mixed into the long fiber fraction, fine fiber fraction and/or mixed stock comprise conventional papermaking chemicals, such as fillers, anionic trash catchers, dry-strength additives, sizing agents, retention aids, etc. By choosing properly the place and the process stream into which each additive is mixed, the performance of additives can be improved.
  • Anionic trash comprises anionic dissolved polymeric and colloidal materials, which mostly originate from wood raw material and get released during pulping. Anionic trash interferes with the performance of cationic retention aids, cationic dry-strength agents, and wet-strength resins. Adding fixatives before the dosage of cationic starch has been found to produce considerable synergistic benefits. One of the most common benefits is better adsorption of starch onto fibers and fillers, resulting in higher overall retention. The strength of paper is also improved because the starch is to a greater degree adsorbed into the fibers and in a lesser degree into the anionic trash.
  • ATC anionic trash catchers
  • Cationic starch is primarily used for increasing dry-strength of the paper but it also affects retention and sizing. Due to their large specific surface area, fines and fillers tend to adsorb most of the cationic starch added to a papermaking stock. It has been found that the strength properties of paper may be improved by adding a major part of the starch to the long fiber fraction and only a minor part of the starch to the fine fiber fraction, instead of adding the whole dosage of the starch to the mixed stock.
  • the dose mixed into the long fiber fraction may be 50 to 99%, preferably 70 to 80% of the dry-strength additive, and the dose mixed into the fine fiber fraction or to the mixed stock may be 50 to 1%, preferably 20 to 30% of the dry-strength additive.
  • the sizing performance can be improved by dosing part of the sizing agent into the long fiber fraction and part of the sizing agent to the fine fiber fraction.
  • Measuring the average fiber length of the long fiber fraction and the fine fiber fraction gives information about the performance of the fractionation devices and the long fiber refiner. It is also possible to control the mixing ratio of the fine fiber fraction to the long fiber fraction on the basis of the average fiber length measured from the long fiber fraction and the fine fiber fraction.
  • the mixing ratio of the fine fiber fraction to the long fiber fraction may be controlled on the basis of retention measured from the wire section of the paper machine. Controlling the addition of the fine fiber fraction is a new way of managing retention on the paper machine.
  • the new system can be applied to greenfield installations, i.e. new projects, as well as to rebuilds.
  • fiber fractionation can be carried out early enough in a most suitable way for each particular type of fiber raw material. In that case the capacity and the energy requirements can be adjusted to particular type of fiber raw material.
  • a second option is to carry out fiber fractionation after the different fiber raw materials have been mixed into a paper stock. Most probably this would require a different degree of separation efficiency as well as multi-stage screening or a suitable device according to the type of raw material, e.g. GapWasherTM. Sometimes it might be advantageous to refine the different fiber raw materials together, after which the long and fine fiber fractions may still be exposed to separate chemical treatments.
  • a third option is to carry out fiber fractionation in the approach flow system after the thick stock has been diluted to the headbox consistency. In that case the possibility of separate refining of the long fiber fraction is lost.
  • This kind of arrangement is mainly focused on improving retention.
  • the strength properties of paper may also be somewhat improved by selective addition of dry-strength additives. A moderate anionic trash control can probably be obtained, too.
  • fiber fractionation can be carried out in a modular way, adapted to the particular requirements. For example, fractionation may be performed on the most demanding fiber raw material in the process. All the options discussed above in connection with a greenfield case are also valid in a rebuild case.
  • the inventive concept can as well be applied to production of multi-ply paper by using a multi-layer headbox.
  • the outer layers of the web may be produced from mixed stock having a higher percentage of fine fiber fraction in order to give the paper improved surface properties whereas the middle layers of the web are produced from stock having a higher percentage of long fiber fraction in order to improve the strength of the paper.
  • fractionation may be adjusted in accordance with the fines content of the fiber raw material, after which the two fiber fractions are refined separately and selectively in order to improve their desired properties.
  • the long fiber fraction may be refined in a conical refiner, the aim being to reduce the amount of coarse fibers and to improve the strength properties of the paper.
  • the fine fiber fraction may be refined in a double disc refiner employing low refining intensity, the aim being to improve the wet strength of the paper. Both refiners may operate at low consistency so that energy is saved in comparison with conventional HC refining.
  • Fractionation may be carried out in two steps so that the first step comprises a screening device, the separating capacity of which can be adjusted according to the fines content of the fiber raw material, and the second step comprises hydrocyclones, arranged to separate fibers according to their coarseness. From the hydrocyclones the coarser fibres are passed to a conical refiner and the finer fibers are mixed with the accept fraction of the preceding screening stage.
  • the fiber raw material comprises DIP
  • the second step enables separation and selective treatment of chemical and mechanical fibers.
  • the second step enables separation and separate treatment of mechanical fibers according to their coarseness and stiffness.
  • the two fiber fractions comprise fibers that are different in their properties and that would benefit of different kinds of treatment. It is preferable to refine the long fiber fraction that is rich in coarse and stiff fibers in a conical refiner, after which dry-strength additive should be mixed with the long fibers.
  • the aim of this treatment is to reduce the coarseness of the fibres and to improve the dry strength and smoothness of the paper. It is as well preferable to refine the fine fiber fraction that is rich in fines and short, flexible fibers in a double disc refiner employing low refining intensity.
  • selected papermaking chemicals e.g. fixatives, retention aids, fillers
  • the effects attainable by fractionation and selective treatment of fiber fractions may be further improved by measuring fiber length distributions at different points of the process and by controlling the operation of certain process devices on the basis of these measurements.
  • the operation of the fractionation device may be controlled on the basis of the fiber length distributions measured from the input flow, the reject flow (long fiber fraction) and the accept flow (fine fiber fraction). It is also possible to feed an adjustable part of the long fiber fraction back to the fine fiber fraction on the basis of the measured fiber length distributions.
  • the operation of the double disc refiner may be controlled on the basis of fiber length distributions measured from the stock before and after the refiner.
  • a fiber raw material 10 is passed to fractionation equipment F where it is divided into two fractions.
  • a first fraction 12 which is rich in long and coarse fibers, is passed to a long fiber storage 13.
  • a second fraction 16 which is rich in short fibers and fines, is passed to a fine fiber storage 17.
  • An example of possible fractionation equipment F is shown in Fig. 4 .
  • the long fibers from the long fiber storage 13 are passed to a low consistency refiner 20 in order to refine the fibers to make them more suitable for papermaking.
  • Chemical pulps are typically refined before they are passed to the paper machine. If no further refining is needed, which is the case with TMP, the refiner 20 may be omitted or bypassed. Refining only the long fiber fraction gives reduced size of equipment needed as well as savings in energy consumption.
  • fixatives such as anionic trash catchers (ATC)
  • ATC anionic trash catchers
  • Dry-strength additive 22 most often cationic starch, is added to the long fiber fraction 23 at a point that precedes its mixing with the fine fiber fraction.
  • the main part of the cationic starch about 75% of the total amount, is added to the long fiber fraction, and a minor part, about 25% of the total amount, is added either to the fine fiber fraction or to the mixed stock. This arrangement ensures that an adequate amount of starch may be adsorbed by the long fiber fraction. Splitting the starch dosage in two parts that are added to different fiber fractions increases the efficiency of starch as a dry-strength additive.
  • Fig. 1 shows a blending chest 26, which is not, however, compulsory.
  • the different stock components 23, 24 and 25 and filler 27 are mixed, either in the blending chest 26 or in a tube mixer (OptiFeed TM ), into a thick stock 31.
  • OptiFeed TM tube mixer
  • sizing agents 32 are added to the thick stock 31.
  • a control block 33 is arranged to control the mixing ratio of the fine fiber fraction 24 to the long fiber fraction 23.
  • the target is to achieve stable and constant feed of fine fibers and to compensate for any fluctuations in the composition of the original fiber raw material 10.
  • the control block 33 may be connected to an optional measuring device 34 that is arranged to indicate the average fiber lengths of the long fiber fraction 23 and the fine fiber fraction 24.
  • the thick stock 31 is first diluted with white water, which is taken from a wire pit 35.
  • OptiFeed TM indicated by line 36
  • the thick stock 31 is diluted in a tube mixer.
  • Diluted stock 37 is then fed by a first pump 38 to centrifugal cleaning equipment 39 and further to a deaerator 40.
  • the stock is fed by a second pump 41 to a machine screen 42 and finally to a headbox 43.
  • the headbox 43 distributes the diluted stock to a wire section 44, where water is drained from the stock through forming wires in order to form a paper web, which is further transported to a press section and a dryer section (not shown).
  • Filler is contained in a filler storage 45, from which it is added either to the diluted stock in the approach flow system, as indicated by reference number 46, or to the thick stock in the pulp preparation department, as indicated by reference number 27.
  • the filler dosage may be split into two parts, the first part 46 being fed to the thick stock and the second part 27 being fed to the diluted stock.
  • Retention aids 47, 48 are added to the diluted stock flow in two steps in such a way that the first retention aid component 47, e.g synthetic cationic polyacrylamide (C-PAM), is added before the machine screen 42 and the second retention aid component 48, e.g. nanoparticles, is added after the machine screen 42.
  • first retention aid component 47 e.g synthetic cationic polyacrylamide (C-PAM)
  • second retention aid component 48 e.g. nanoparticles
  • Fig. 2 illustrates another system that aims at improved fines and filler retention when the fine fiber content of the fiber raw material is fluctuating.
  • the system is suitable for chemically dirty fiber raw materials, such as thermomechanical pulp (TMP), deinked pulp (DIP), recycled fiber pulp (RCF), and chemical pulp with bleaching residues.
  • TMP thermomechanical pulp
  • DIP deinked pulp
  • RCF recycled fiber pulp
  • the fiber raw material 10 is fractionated by means of fractionation equipment F.
  • the long fiber fraction 12 is passed to a long fiber storage 13 and the fine fiber fraction 16 is passed to a fine fiber storage 17. If needed, anionic trash catchers 21 are added to the fine fiber fraction 16 at a point preceding the fine fiber storage 17. If needed, the long fiber fraction is passed to a low consistency refiner 20. Alternatively, refining may be omitted as indicated by line 50.
  • the long fiber fraction and the fine fiber fraction are not combined until at the approach flow system of the paper machine.
  • the two fiber fractions may be mixed either in connection with a wire pit 35 or in a tube mixer, in which case the wire pit 35 may be bypassed or omitted as illustrated by line 36.
  • Filler is added to the paper stock in two parts.
  • a first part 51 of the filler is mixed into the fine fiber fraction in a blender 52 while a second part 46 of the filler is mixed into the diluted paper stock in the approach flow system.
  • 20 to 50% of the filler is fed to the blending chest 52, and 50 to 80% of the filler is fed to the mixed stock in the approach flow system.
  • starch 53 or some other cationic polymer suitable for pre-coagulation is fed to the fines and filler blender 52.
  • the system comprises a retention control block 54, which receives consistency information from the headbox 43 and from the wire section 44. On the basis of the gathered information the control block 54 controls, on the one hand, mixing of the stream 55 of pre-coagulated fines and filler with the long fiber fraction 31' and, on the other hand, addition of retention aids 47 to the diluted stock 56.
  • This provides twofold retention control. Controlling the amount of the fine fiber fraction 55 represents coarse tuning of retention, whereas controlling the addition of retention aids 47 represents fine-tuning of retention.
  • Sizing agents 32, 57 are added separately to the long fiber fraction 31' (flow 32) and to the fine fiber fraction 55 (flow 57). Separate addition points allow division of the dosage in two parts as desired. This is recommended especially in the case of fine paper with high PCC addition to evaluate the sizing reactivity.
  • the ash content of the paper may be controlled by means of a control block 58 which receives information about the ash content of the dried paper and controls the addition of filler 46 to the diluted stock in the approach flow system.
  • Fig. 3 illustrates a system that is suitable for pulp blends with a constant or variable fines content.
  • Fiber raw materials suitable for this system include TMP, DIP, RCF and chemical pulp with bleaching residues.
  • the long fiber fraction 12 is passed to a low consistency refiner 20, where the long fibers are refined to make them more suitable for papermaking. If no refining is needed, refiner 20 may be omitted or bypassed as indicated by dashed line 50.
  • Dry-strength additive 22, such as starch, is added to the long fiber fraction, after which the long fibers are fed to a long fiber storage 64.
  • Anionic trash catchers 21 are added to the fine fiber fraction 16 before it enters a fine fiber storage 17. Fine fibers from the fine fiber storage 17, filler 51 from the filler storage 45 and pre-coagulation agent 53, such as starch or cationic polymer, are blended in a fine fiber and filler blender 52 in order to pre-coagulate filler and fines and to improve their retention on the paper machine.
  • pre-coagulation agent 53 such as starch or cationic polymer
  • the long fiber fraction 31' and the fine fiber fraction 55 which also contains flocculated filler, are mixed and diluted in the approach flow system to produce diluted paper stock 37 that is fed to the paper machine.
  • sizing agents 32, 57 are separately added to both fractions 32.
  • the retention control system 54 and the ash control system 58 are similar to those described above in connection with Fig. 2 .
  • Fig. 4 shows one example of equipment that may be used for fractionation of fiber raw material.
  • the fractionation equipment F comprises two fractionation devices 11 and 15 which may be of any type that is able to divide the fiber raw material into two fractions having different average fiber lengths.
  • the first fractionation device 11 may be a coarse screen of 100 or 125 mesh while the second fractionation device 15 is a fine screen of 200 mesh.
  • the coarse fraction 12 from the first fractionation device 11 is passed to a long fiber storage while the fine fraction 14 is passed to the second fractionation device 15 for further purification.
  • From there the purified fine fiber fraction 16 is passed to a fine fiber storage while the filtrate 18 is recycled for further use.
  • a minor stream of long fibers 19 may be passed to the second fractionation device 15 to act as a sweetener that enables filtering by forming a cake that retains the fines on the screen.
  • Fig. 5 illustrates a system that aims at improving the properties of supercalendered (SC) paper and the production of it.
  • the fiber raw material 70 to be fractionated in this process comprises groundwood (GW), thermomechanical pulp (TMP), deinked pulp (DIP), or a mixture of them.
  • the fiber raw material 70 is passed to a fractionation device 71 that divides the pulp into two fractions 72 and 73.
  • the fractionation device 71 is a screen the speed of rotation of which is adjustable according to the fines content of the fiber raw material 70.
  • a first fiber fraction 72 which is rich in long and coarse fibers, is passed to hydrocyclones 74 that comprise one or more separation steps.
  • a second fraction 73 which is rich in short fibers and fines, is passed to a fine fiber storage bin 75.
  • hydrocyclones 74 are used for separating the fibers of chemical pulp from those of mechanical pulp.
  • the more resilient fibers 76 of chemical pulp are passed to the fine fiber storage bin 75 and the stiffer fibers 77 of mechanical pulp are passed to a conical refiner 78 for further refining.
  • hydrocyclones 74 are used for separating coarse and stiff fibers from flexible and resilient fibers. Also here the more resilient fibers 76 are passed to the fine fiber storage 75 and the coarser fibers 77 are passed to the conical refiner 78 for further refining.
  • the conical refiner 78 operates at low consistency, reducing shives and coarseness of the long fiber fraction.
  • dry-strength additive 80 such as starch
  • the strength and smoothness of the paper can be improved by reducing the coarseness of the long fibers and by adding starch to the fraction that benefits most from it.
  • the fine fiber fraction 73 is passed to a double disc refiner 81 that acts at low intensity and low consistency.
  • a container 82 where fixatives 83 (anionic trash catchers) are added to the stock.
  • fixatives 83 anionic trash catchers
  • fillers 85 and retention aids 86 are added to the stock.
  • Fig. 6 shows another system that aims at improving the properties of SC paper and the production of it.
  • the fiber raw material 70 to be fractionated in this process is groundwood or TMP produced in the paper mill. Additionally, hardwood bleached kraft pulp is blended with the fiber raw material in order to improve the properties of the SC paper.
  • the fiber raw material 70 is passed to a fractionation device 71 that divides the pulp into two fractions 72 and 73.
  • the first fraction is a long fiber fraction 72 that is rich in long and coarse fibers and the second fraction is a fine fibre fraction 73 that is rich in short fibers and fines.
  • a measuring device 91 is arranged to measure the fiber length distributions of the fiber raw material 70, the long fibre fraction 72 and the fine fiber fraction 73.
  • the speed of rotation of the fractionation device 71 may be adjusted on the basis of the fines content of the fiber raw material 70 in order to adjust the division of fibers into the long fiber fraction 72 and fine fiber fraction 73.
  • a major part of the long fiber fraction 72 is fed to a conical refiner 78 whereas a minor part of the same is joined with the fine fiber fraction 73.
  • the conical low consistency refiner 78 is used for reducing the proportion of coarse fibers and shives in order to improve the strength and smoothness of the paper.
  • the portion of long fibers passed to the fine fiber storage bin 75 is 10 to 20% of the total input of fiber raw material 70.
  • the amount of hardwood bleached kraft pulp added to the process is advantageously 8 to 15% of the amount of fiber raw material 70.
  • the chemical pulp is slushed in a pulper 92, deflaked in a deflaker 93 and fed to a chemical pulp storage bin 94.
  • 20 to 30% of the hardwood bleached kraft pulp is then fed to the fine fiber storage bin 75 whereas the rest of the pulp is fed directly to a final mixer 95.
  • the fine fiber fraction 73 is mixed with a portion of the long fiber fraction 72 and a portion of the hardwood bleached kraft and fixatives 96 are added to the stock.
  • the stock is passed to a double disc refiner 81 for low intensity refining carried out at a low consistency.
  • refining retention aids 97 are added to the stock by means of an mixing device 98, such as a RetaMix TM retention aid mixer, produced by Metso Paper, Inc.
  • a measuring device 99 is arranged to measure the fiber length distribution of the hardwood bleached kraft pulp and of the stock before and after the double disc refiner 81.
  • the operation of the double disc refiner 81 is controlled on the basis of the fiber lengths measured.
  • Dry-strength additive 100 such as starch
  • the mixing device 101 is preferably a RetaMix TM retention aid mixer of Metso Paper, Inc.
  • the final mixer 95 that mixes the refined long fibers 87, hardwood bleached kraft pulp 102 and mixed stock 88 is preferably a LobeMix TM stock mixer, which is produced by Metso Paper, Inc. Fillers 103 are also added to the stock at this point. Instead of a tube mixer, conventional mixing in connection with a wire pit may also be used at this point.
  • the hardwood bleached kraft pulp is preferably made out of birch or eucalyptus. This kind of pulp is cost-effective and able to improve the strength and optical properties of the paper produced.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Paper (AREA)

Claims (17)

  1. Procédé pour fabriquer du papier ou du carton à partir d'une matière première fibreuse, comprenant les étapes qui consistent à :
    fractionner la matière première fibreuse en une fraction de fibres longues, qui est riche en fibres longues, et une fraction de fibres fines, qui est riche en fibres courtes et fines,
    caractérisé par le fait de comprendre en plus les étapes qui consistent à :
    mélanger des additifs dans les fractions de fibres,
    combiner la fraction de fibres longues et la fraction de fibres fines pour former une pâte mélangée tout en commandant le rapport de mélange afin de maintenir la teneur en matières fines de la pâte mélangée à une valeur souhaitée,
    mélanger des additifs dans la pâte mélangée, et
    fabriquer du papier à partir de la pâte mélangée sur une machine à papier.
  2. Procédé selon la revendication 1, caractérisé par le fait d'utiliser deux matières premières fibreuses ou plus et fractionner uniquement l'une des matières premières fibreuses, ou fractionner au moins deux des matières premières fibreuses séparément, après quoi les fractions de fibres longues des matières premières fibreuses sont combinées et les fractions de fibres fines des matières premières fibreuses sont combinées, ou fractionner un mélange desdites matières premières fibreuses.
  3. Procédé selon l'une quelconque des revendications 1 ou 2, caractérisé par le fait d'ajouter des collecteurs de déchets anioniques à la fraction de fibres fines afin de commander des déchets anioniques.
  4. Procédé selon l'une quelconque des revendications 1 à 3, caractérisé par le fait de raffiner la fraction de fibres longues.
  5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé par le fait d'ajouter une partie majeure d'un additif de résistance à sec à la fraction de fibres longues et une partie mineure de l'additif de résistance à sec à la fraction de fibres fines ou à la pâte mélangée.
  6. Procédé selon la revendication 5, caractérisé par le fait de doser 50 à 99%, préférablement 70 à 80% de l'additif de résistance à sec à la fraction de fibres longues et 1 à 50%, préférablement 20 à 30% de l'additif de résistance à sec à la fraction de fibres fines ou à la pâte mélangée.
  7. Procédé selon l'une quelconque des revendications 1 à 6, caractérisé par le fait d'ajouter un agent d'encollage à la fraction de fibres longues et à la fraction de fibres fines.
  8. Procédé selon l'une quelconque des revendications 1 à 7, caractérisé par le fait d'ajouter une première partie de charge à la fraction de fibres fines et une deuxième partie de charge à la pâte mélangée.
  9. Procédé selon la revendication 8, caractérisé par le fait d'ajouter 20 à 50% de la charge à la fraction de fibres fines et 50 à 80% à la charge de la pâte mélangée.
  10. Procédé selon la revendication 8, caractérisé par le fait de mélanger des charges et des agents de pré-coagulation avec la fraction de fibres fines afin de floculer la charge et les particules fines.
  11. Procédé selon l'une quelconque des revendications 1 à 10, caractérisé par le fait de mesurer des longueurs de fibres moyennes de la fraction de fibres longues et de la fraction de fibres fines et de commander le rapport de mélange sur la base des mesures, ou par le fait de mesurer une rétention sur la section de fil de la machine à papier et de commander le rapport de mélange de la fraction de fibres fines par la fraction de fibres longues sur la base de la rétention mesurée.
  12. Procédé selon la revendication 1, caractérisé par le fait de raffiner de manière séparée et sélective et de traiter chimiquement la fraction de fibres longues et la fraction de fibres fines.
  13. Procédé selon la revendication 12, caractérisé par le fait de raffiner la fraction de fibres longues à faible consistance dans un raffineur conique (78) et de raffiner la fraction de fibres fines à faible consistance dans un raffineur à double disque (81) en utilisant une faible intensité de raffinement.
  14. Procédé selon la revendication 1, caractérisé par le fait de régler le fonctionnement du dispositif de fractionnement (71) sur la base de la teneur en matières fines de la matière première fibreuse (70).
  15. Procédé selon la revendication 14, caractérisé par un fractionnement à deux étapes où la première étape est exécutée par un tamis (71) et la deuxième étape est exécutée par des hydrocyclones (74).
  16. Procédé selon la revendication 15, caractérisé par le fait d'ajuster la vitesse de rotation du tamis (71) selon la teneur en particules fines de la matière première fibreuse (70).
  17. Procédé selon la revendication 1, caractérisé par le fait de mesurer les distributions des longueurs de fibres de la matière première fibreuse (70), de la fraction de fibres longues (72) et de la fraction de fibres fines (73) et de commander le fonctionnement du dispositif de fractionnement (71) sur la base des distributions des longueurs de fibres mesurées.
EP06820101A 2005-12-01 2006-11-28 Procede pour la fabrication de papier Not-in-force EP1954873B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20055635A FI20055635L (sv) 2005-12-01 2005-12-01 Förfarande för framställning av papper
PCT/FI2006/050522 WO2007063182A2 (fr) 2005-12-01 2006-11-28 Procede pour la fabrication de papier

Publications (2)

Publication Number Publication Date
EP1954873A2 EP1954873A2 (fr) 2008-08-13
EP1954873B1 true EP1954873B1 (fr) 2010-06-09

Family

ID=35510713

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06820101A Not-in-force EP1954873B1 (fr) 2005-12-01 2006-11-28 Procede pour la fabrication de papier

Country Status (6)

Country Link
EP (1) EP1954873B1 (fr)
CN (1) CN101321910B (fr)
AT (1) ATE470753T1 (fr)
DE (1) DE602006014861D1 (fr)
FI (1) FI20055635L (fr)
WO (1) WO2007063182A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105507057A (zh) * 2015-11-24 2016-04-20 安庆盛华纸质包装有限公司 一种高强度口杯纸的制备工艺

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080308239A1 (en) 2007-06-12 2008-12-18 Hart Peter W Fiber blend having high yield and enhanced pulp performance and method for making same
WO2008153565A1 (fr) * 2007-06-12 2008-12-18 Meadwestvaco Corporation Mélange de fibres présentant un rendement élevé et des performances de pâte améliorées, et son procédé de fabrication
FI121545B (fi) * 2007-10-18 2010-12-31 Chempolis Oy Menetelmä massan ominaisuuksien parantamiseksi
DE102007059736A1 (de) 2007-12-12 2009-06-18 Omya Development Ag Oberflächenmineralisierte organische Fasern
WO2009077001A1 (fr) * 2007-12-17 2009-06-25 Sca Hygiene Products Gmbh Procédé de préparation de pâte, et de traitement de pâte, et papier, en particulier un papier de soie
FI124464B (fi) 2009-04-29 2014-09-15 Upm Kymmene Corp Menetelmä massalietteen valmistamiseksi, massaliete ja paperi
JP5952030B2 (ja) * 2011-03-31 2016-07-13 日本製紙株式会社 紙の製造方法
CN102191728B (zh) * 2011-03-31 2013-01-16 广东理文造纸有限公司 一种高强度包装纸的制备工艺
CN102191727B (zh) * 2011-03-31 2013-01-16 广东理文造纸有限公司 一种环保挂面纸的制备工艺
CN102817282B (zh) * 2011-06-09 2015-06-03 金东纸业（江苏）股份有限公司 纸浆、纸浆制备方法、原纸及造纸方法
CN102242511A (zh) * 2011-06-21 2011-11-16 维达北方纸业(北京)有限公司 一种卫卷原纸独立配浆工艺方法
CN102296475A (zh) * 2011-09-08 2011-12-28 陕西科技大学 竹浆磨浆工艺
WO2014154297A1 (fr) * 2013-03-28 2014-10-02 Mayr-Melnhof Karton Ag Procédé de fabrication d'une âme en carton et âme en carton pour stratifiés
CN103352394B (zh) * 2013-07-19 2016-08-10 金红叶纸业集团有限公司 一种造纸工艺及该纸张
US10041209B1 (en) 2015-08-21 2018-08-07 Pulmac Systems International, Inc. System for engineering fibers to improve paper production
CN106930133A (zh) * 2017-04-12 2017-07-07 上海馨星环保科技有限公司 一种用甘蔗渣造纸的方法及其制成的水杯
DE102017110815A1 (de) * 2017-05-18 2018-11-22 Voith Patent Gmbh Verfahren zur Behandlung eines Fasersuspensionsstromes
PL3684972T3 (pl) * 2017-09-18 2023-12-18 International Paper Company Sposób i aparatura do kontroli układu frakcjonowania włókien
FI130567B (en) * 2019-06-06 2023-11-21 Valmet Technologies Oy Pulp treating apparatus and method
CN116536965B (zh) * 2023-05-30 2025-10-10 陕西科技大学 一种高耐折特种纸及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE304167B (fr) * 1960-02-29 1968-09-16 Svenska Cellulosa Ab
US4731160A (en) * 1986-03-19 1988-03-15 Kamyr, Inc. Drainage characteristics of mechanical pulp
FI75200B (fi) * 1986-07-04 1988-01-29 Valmet Oy Foerfarande vid pappersframstaellningsprocess foer foerbaettring av egenskaper hos papperet, saerskilt dess retention.
US5133832A (en) * 1991-07-08 1992-07-28 The Black Clawson Company Process and system for preparation of waste paper stock with short and long fiber fractionation
AU4188597A (en) * 1996-10-25 1998-04-30 Nalco Chemical Company Method of retention aid program addition for improved paper board production
ATE245724T1 (de) * 1998-10-15 2003-08-15 Procter & Gamble Verfahren zur herstellung von weichem seidenpapier
CN100374652C (zh) * 2000-05-16 2008-03-12 巴科曼实验室国际公司 造纸方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105507057A (zh) * 2015-11-24 2016-04-20 安庆盛华纸质包装有限公司 一种高强度口杯纸的制备工艺

Also Published As

Publication number Publication date
ATE470753T1 (de) 2010-06-15
DE602006014861D1 (de) 2010-07-22
FI20055635A7 (fi) 2007-06-02
FI20055635A0 (fi) 2005-12-01
WO2007063182A3 (fr) 2007-08-02
FI20055635L (sv) 2007-06-02
EP1954873A2 (fr) 2008-08-13
CN101321910B (zh) 2011-03-30
CN101321910A (zh) 2008-12-10
WO2007063182A2 (fr) 2007-06-07

Similar Documents

Publication Publication Date Title
EP1954873B1 (fr) Procede pour la fabrication de papier
US4781793A (en) Method for improving paper properties in multiply paper using long and short fiber layers
US4562969A (en) Process for preparing groundwood pulp as short fiber and long fiber fractions
EP2061932B1 (fr) Procédé de fabrication d'un produit fibreux multicouche
EP0902119B1 (fr) Procédé pour la préparation d'une bande de papier
US4776926A (en) Process for producing high yield bleached cellulose pulp
EP1407073B1 (fr) Procede de production de pate thermomecanique (ptm) blanchie ou de pate chimico-thermomecanique (pctm) blanchie
JP2004525284A (ja) 印刷用紙
US20080029232A1 (en) Process and Device to Manufacture Cellulose Pulp
FI113552B (fi) Menetelmä painopaperin valmistamiseksi
US6818099B2 (en) Raw material for printing paper, method to produce it and printing paper
US5368693A (en) Apparatus for treating white water
US20070023329A1 (en) Method for selective removal of ray cells from cellulose pulp
Koskenhely et al. Effect of refining intensity on pressure screen fractionated softwood kraft
Wakelin et al. TMP long fibre fractionation with pressure screeens
FI72354C (fi) Foerfarande foer framstaellning av foerbaettrad slipmassa.
Holik et al. Stock preparation
FI78949C (fi) Foerfarande foer framstaellning av papper.
WO2004067838A1 (fr) Procede et dispositif de manipulation de rejets contenant des charges dans une machine de fabrication du papier et une machine de fabrication du carton

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20080508

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

RIN1 Information on inventor provided before grant (corrected)

Inventor name: LEPOMAEKI, HANNU

Inventor name: SOINI, PETTERI

Inventor name: POIKOLAINEN, ANTTI

Inventor name: CECCHINI, JUAN

17Q First examination report despatched

Effective date: 20090703

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 602006014861

Country of ref document: DE

Date of ref document: 20100722

Kind code of ref document: P

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

LTIE Lt: invalidation of european patent or patent extension

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100910

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101011

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101009

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101130

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

Ref country code: DE

Ref legal event code: R097

Ref document number: 602006014861

Country of ref document: DE

Effective date: 20110309

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20101128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101130

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101210

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100909

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100920

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20131120

Year of fee payment: 8

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20150731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141201

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20221121

Year of fee payment: 17

Ref country code: DE

Payment date: 20221123

Year of fee payment: 17

Ref country code: AT

Payment date: 20221121

Year of fee payment: 17

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602006014861

Country of ref document: DE

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 470753

Country of ref document: AT

Kind code of ref document: T

Effective date: 20231128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20231128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20231128

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20231128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20240601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20240601