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EP1948833B1 - Procede d'utilisation d'un four a cuve - Google Patents

Procede d'utilisation d'un four a cuve Download PDF

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Publication number
EP1948833B1
EP1948833B1 EP06840931A EP06840931A EP1948833B1 EP 1948833 B1 EP1948833 B1 EP 1948833B1 EP 06840931 A EP06840931 A EP 06840931A EP 06840931 A EP06840931 A EP 06840931A EP 1948833 B1 EP1948833 B1 EP 1948833B1
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EP
European Patent Office
Prior art keywords
shaft furnace
modulation
gas
furnace
modulated
Prior art date
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Application number
EP06840931A
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German (de)
English (en)
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EP1948833A2 (fr
Inventor
Gerd König
Wolfram KÖNIG
Hans-Heinrich Heldt
Dieter Georg Senk
Heinrich-Wilhelm Gundenau
Alexander Babich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp AT PRO Tec GmbH
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ThyssenKrupp AT PRO Tec GmbH
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Priority to PL06840931T priority Critical patent/PL1948833T3/pl
Publication of EP1948833A2 publication Critical patent/EP1948833A2/fr
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/001Injecting additional fuel or reducing agents
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B11/00Making pig-iron other than in blast furnaces
    • C21B11/02Making pig-iron other than in blast furnaces in low shaft furnaces or shaft furnaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories or equipment specially adapted for furnaces of these types
    • F27B1/16Arrangements of tuyeres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories or equipment specially adapted for furnaces of these types
    • F27B1/26Arrangements of controlling devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D19/00Arrangements of controlling devices

Definitions

  • the invention relates to a method for operating a shaft furnace, in which an upper region of the shaft furnace is charged with raw materials which sink under the influence of gravity in the furnace, wherein a part of the raw materials is melted and / or reduced under the influence of the atmosphere prevailing inside the shaft furnace , And in a lower portion of the shaft furnace, a treatment gas is introduced, which at least partially affects the atmosphere prevailing within the shaft furnace atmosphere.
  • Such a method, or the shaft furnace is basically known.
  • the shaft furnace can work on the countercurrent principle.
  • Raw materials such as Möller and coke are charged at the top of the shaft furnace of the gout and sink down in the shaft furnace.
  • a treatment gas (so-called wind with 800 - 10 000 m 3 / tRE depending on the size of the furnace) is blow-blown into the furnace.
  • the wind which is usually in advance heated in Winderhitzem to about 1000 to 1300 ° C air, with the coke, where u. a, carbon monoxide is generated.
  • the carbon monoxide rises in the oven and reduces the iron ore contained in the Möller.
  • substitute reducing agents of, for example, 100-170 kg / tRE (eg, coal dust, oil or natural gas) are usually blown into the furnace, which promotes the generation of carbon monoxide.
  • 100-170 kg / tRE eg, coal dust, oil or natural gas
  • the raw materials melt due to the heat generated by the chemical processes occurring in the shaft furnace.
  • the temperature distribution over the cross section of the shaft furnace is uneven.
  • the so-called "dead man” is formed, while the relevant processes such as gasification (reaction of oxygen with coke or substitute reducing agents to carbon monoxide and carbon dioxide) takes place essentially only in the so-called vortex zone, which is an area is in front of a blow mold, that is located with respect to the cross section of the furnace only in an edge region.
  • the vortex zone has a depth to the furnace center of about 1 m and a volume of about 1.5 m 3 .
  • blow molds are arranged circumferentially in the blow molding plane in such a way that the vortex zone formed before each blow mold overlaps with the vortex zones formed on the left and right, so that the active region is essentially given by an annular region.
  • the so-called "birdsnest" is formed.
  • the hot blast can usually be enriched with oxygen in order to intensify the processes just described (gasification in the vortex zone, reduction of the iron ore), which leads to an increase in the performance of the shaft furnace.
  • the hot blast can be enriched prior to introduction with oxygen, or pure oxygen can be supplied separately, wherein for separate feeding a so-called lance can be provided, i. a tube which is e.g. within the blow mold, which is also a tubular part, extends and opens into the furnace within a mouth region of the blow mold.
  • a so-called lance can be provided, i. a tube which is e.g. within the blow mold, which is also a tubular part, extends and opens into the furnace within a mouth region of the blow mold.
  • the hot blast is correspondingly highly enriched with oxygen.
  • the addition of oxygen increases the production costs, so that the efficiency of a modern shaft furnace can not be increased simply by a correspondingly increased oxygen concentration.
  • WO 01/36891 A3 For example, a method of operating a shaft furnace is known. In this process, feedstocks, fuels, first and second oxidants are injected into the molten zone. The injection of the second oxidizing agent is carried out by repetitive time sequence of a flow phase and a rest phase. As examples, flow phases and rest periods can each last 10 s.
  • this object is achieved by a method of the type described above, in which the introduction of the treatment gas is modulated.
  • the modulation of the treatment gas takes place in such a way that the operating variables pressure p and / or volumetric flow V within a period of less than or equal to 5 s and more preferably less than 1 s is varied. It has been found that a significantly better gasification and thus an increase in performance and efficiency is achieved when the treatment gas is not introduced evenly in time in the oven, but is varied at short intervals.
  • the introduction of the treatment gas also varies in conventional methods whenever the furnace is started or shut down when different operating parameters are set for a new load of raw materials, or if only the oxygen concentration of the hot blast is changed to a higher value to increase the power.
  • these changes in time are only one-time changes that take place on a time scale of several hours.
  • the dynamic modulation of the introduction of the treatment gas according to the invention takes place on time scales of less than one minute, which is related to the fact that the mean residence time of the gas in the shaft furnace is only 5 to 10 s.
  • temporal changes in the operating parameters at a distance of more than one minute have a comparatively short time span during which the operating parameters are not static.
  • the time span between two changes in the operating parameters, in which the operating parameters are substantially constant, that is static, is greater than the time required to reach the substantially stationary state.
  • such changes are essentially static and are therefore referred to as "quasi-static modulation"
  • the time period with transient conditions in the shaft furnace is greater than the time period with substantially stationary states. Dynamic modulation disturbs dead-flow zones in the vortex zone, which increases the overall turbulence in the vortex zone; This results in an improved gasification in the vortex zone, which in turn leads to improved gasification in the shaft.
  • the modulation takes place quasi-periodically, in particular periodically, the period being 5 s or less.
  • a quasi-periodic modulation should also be understood as one in which g (t) is a continuous, but functionally dependent, function that unevenly distorts the structure of the continuous function f (t), although the underlying periodic structure is still recognizable remains.
  • g (t) is a continuous, but functionally dependent, function that unevenly distorts the structure of the continuous function f (t), although the underlying periodic structure is still recognizable remains.
  • the period T is 60 ms or more, preferably 100 ms or more, in particular 0.5 s or more
  • the residence time of the treatment gas in the vortex zone is extremely low, a satisfactory gasification can be achieved with period durations in these areas In that case, the generation of modulations with even shorter period duration would entail increased technical complexity.
  • T is chosen such that the treatment gases in the shaft furnace form a turbulent flow and substantially avoid laminar regions.
  • the modulation is pulsation-like.
  • the pulses themselves can be rectangular pulses, triangular pulses, gaussian pulses (spread mathematical ⁇ -pulse) or have similar pulse shapes, the exact pulse shape has less characterizing effect as the pulse width ⁇ , which is the pulse width at half pulse height (FWHM).
  • a meaningful tuning of the pulse width results when ⁇ is 5 s or less, preferably 2 s or less, in particular 1 s or less.
  • the pulse width ⁇ is 1 ms or more, preferably 10 ms or more, in particular 0.1 s or more. Very small pulse widths are more difficult to produce, on the other hand, with them an influence on processes that take place in the vortex zone with correspondingly short reaction times succeeds.
  • periodic pulsations have a ratio of pulse width to period duration ⁇ : T of 0.5 or less, preferably 0.2 or less, in particular 0.1 or less.
  • T 0.5 or less, preferably 0.2 or less, in particular 0.1 or less.
  • the pulse width ⁇ in particular 5 so> ⁇ ⁇ 1 ms, preferably 0.7 s ⁇ ⁇ ⁇ 25 ms, particularly preferably 0.1 s ⁇ ⁇ ⁇ 30 ms and more preferably 55 ms ⁇ ⁇ ⁇ 35 ms.
  • the ratio ⁇ : T is 10 -4 or greater, preferably 10 -3 or greater, in particular 10 -2 or greater.
  • the amplitude of the modulation with respect to a basic value is 5% or more, preferably 10% or more, in particular 20% or more. It has been found that even small differences in amplitude allow a satisfactory für gasung.
  • the amplitude of the modulation with respect to the base value is 100% or less, preferably 80% or less, in particular 50% or less. In particular, harmonic modulations below these limits can be easily realized in terms of the method.
  • the pulse height of a pulse exceeds the substantially unmodulated value between two pulses by a factor of 2 or more, preferably 5 or more, in particular 10 or more.
  • the shock effect of the modulation can be increased, and the disturbance of the Totströmungszonen be amplified in the vortex zone, which eventually leads to a better gasification in the furnace.
  • the factor is 200 or less, preferably 100 or less, in particular 50 or less.
  • a modulation of the introduction of the treatment gas can take place in a variety of ways.
  • the modulation is expediently via setting at least one in particular the introduction of the treatment gas controlling operating size done.
  • a modulation of the pressure of the hot blast can accelerate the gasification in the vortex zone and thus improve the gasification in the shaft.
  • pressure peaks of 300 bar may occur during pressure modulation.
  • the treatment gas to be introduced has distinguishable components. However, this includes not only the self-evident division of a gas into its components (eg nitrogen, oxygen, etc.), but also different gas phases whose distinctness is due to the fact that they are introduced separately at least at a stage of initiation become. For example, here is the separate oxygen supply by lances, valves or diaphragm to call.
  • the effects achieved in the method according to the invention are significantly enhanced if, together with the treatment gas and / or in addition to the treatment gas, replacement reducing agents are introduced into the shaft furnace.
  • the substitute reducing agent may be pulverized coal produced in particular from anthracite coal, other metallurgical dusts and small granular materials, oil, fats, tars with natural gas or other hydrocarbon carriers, which are converted to CO 2 and CO due to the oxygen, and in particular present as nano-particles. Because of the modulation according to the invention, namely, a higher degree of implementation of the injected replacement reducing agent can be achieved. This applies in particular to pulsation-like modulation, as the reaction is intensified by the pulses.
  • the aforementioned increase in total turbulence in the vortex zone prolongs the very short residence time of the replacement reductants in the vortex zone from only about 0.03 seconds to about 0.05 seconds, which can also increase the reductant conversion. Furthermore, a better implementation of the replacement reductant leads to a lower proportion of unburned particles, which promotes the gasification in the "birdsnest" area and thus allows an additional increase in the injection rate.
  • pressure and / or volume flow of at least one of the distinguishable fractions of the treatment gas and / or pressure and / or mass flow of the replacement reducing agent to be introduced are dynamically modulated. Better intuitivegasung in the shaft is thus also achieved if z. B. the treatment gas, an additional oxygen content is pulsed. Otherwise, or in combination, the pressure at which replacement reductant is injected or its mass flow can be dynamically modulated.
  • the mass flow is identical to the volumetric flow, but on the other hand, the mean density of the substitute reducing agent could be dynamically modulated even with constant volumetric flow. It can also be at least temporarily blown in whole or in part inert gas, for example, unwanted To regulate temperature peaks or to cool the supply lines or arranged in the supply lines valves.
  • the operating variable is particularly advantageously the absolute amount of one of the distinguishable fractions of the treatment gas to be introduced, and / or the relative proportion of one of the distinguishable fractions with respect to a further fraction or the entire treatment gas.
  • the absolute oxygen quantity or the relative oxygen concentration are modulated dynamically, although the main load, namely the hot wind itself does not have to be modulated.
  • This is particularly easy to implement, when pure oxygen or a gas phase with air-increased oxygen concentration is supplied separately at least during part of the introduction. If this happens pulsating, the implementation of the substitute reducing agent can be further intensified, with the further intensified effects already mentioned.
  • the amplitude of the extra oxygen volume flow with respect to that of the background wind in the range 0.25 - 20%, preferably 0.5 - 10%, in particular 1 - 6%.
  • the treatment gas is introduced into the shaft furnace in at least two different ways, and a first operating variable for the control of the portion to be introduced along the first path is dynamically modulated as a second operating variable for controlling the portion of the treatment gas introduced along the second path.
  • first and second operating variables may also be the same operating variable, but their modulation may also be different modulations.
  • a further advantageous method embodiment provides that the first and the second operating variable are periodically modulated with the same period T, wherein their relative phase is shifted by one value. The phase is thus a time shift related to the period T. If the relative time shift is, for example, T / 2, the two operating variables are anticyclically modulated relative to one another.
  • oxygen pulsations may be slightly retarded in relation to corresponding pulsation-like increases in the amount of substitute reducing agent, ie, for example, to be displaced by 0 ⁇ ⁇ ⁇ ⁇ / 2.
  • the inverse period T -1 is set to an autofequency of a subsystem of the atmosphere within the shaft furnace.
  • a partial system of the atmosphere is firstly understood to mean, on the one hand, a spatial subsystem which is given here by the vortex zones; on the other hand, it can refer to a physical / chemical part of the atmosphere, for example the pressure distribution, heat distribution, density distribution, temperature distribution or composition.
  • the autofequency may be the frequency of a linear excitation in the radial direction (from the tuyeres to the furnace center), or vortex excitations in the vortex zone of a single tuyere, but also a whirlwind vortex excitation in the circumferential direction of the shaft furnace Center of this suggestion standing "dead man" for such a vortex oscillation topologically represents a hole.
  • the modulation takes place, for example, in terms of pulse duration, pulse frequency or pulse strength such that a standing wave results in the shaft furnace. Additionally or alternatively, the modulation takes place in such a way that the raw materials sink uniformly in the shaft furnace, in particular in the form of a plug flow. For this purpose, the modulation can be regulated as a function of measured process variables.
  • a further advantage of the stated method lies in influencing the vortex zone geometry, so that the area in which the main coal conversion takes place is increased. It can therefore be increased without additional energy or material expense, the performance of the shaft furnace, so an improved efficiency can be achieved.
  • Another aspect of the invention relates to a method of the type described above, wherein in a first phase of operation at least one of the operating variables is dynamically modulated setting a parameter, the effect of the modulation of the at least one operating variable is registered to at least one characteristic of the shaft furnace, then the Parameters after one predetermined system is varied and the varied parameter is set for the modulation, wherein after each variation and readjustment of their effect on the characteristic is registered, then selected from the variable parameters corresponding to the registered values of the characteristic according to predetermined selection criteria a characteristic value with the associated parameter value and, in a second phase of operation, dynamically modulating the at least one operating variable with the selected parameter value.
  • an optimal parameter value (eg, an optimal period duration) is selected based on which the dynamic (eg periodic) modulation takes place.
  • this optimization method can be carried out for further parameters, so that overall an optimum group of parameters can result, on the basis of which the dynamic modulation takes place.
  • the method according to the invention can be carried out with a shaft furnace, which is in particular designed and developed as described above with reference to the method according to the invention.
  • the means for introducing the treatment gas on a first and a second tubular part wherein in addition to a main line over which a portion of the treatment gas is introduced, via the first tubular part, an oxidizing agent and the second tubular part Spare reducing agent is inflatable.
  • an oxidizing agent such as.
  • oxygen or oxygen-enriched air as well as substitute reducing agent can be introduced separately into the shaft furnace, which allows an independent and structurally easy to implement dynamic modulation of the discharges.
  • a control device is set such that within a period of less than or equal to 40 s, the operating variables pressure p and / or volumetric flow V are varied.
  • first and second tubular part are at least partially connected to a double tube lance, wherein the tubular parts may be arranged concentrically or eccentrically to each other.
  • the functional requirements of the tubular parts can be combined with a space-saving arrangement.
  • first and the second tubular part are spatially separate lances, wherein at least one exit angle of one of the tubular parts is adjustable with respect to a horizontal and / or vertical plane of the shaft furnace, in particular the exit angle of both tubular Parts are independently adjustable.
  • the injection direction of about additional oxygen or the reducing agents with respect to the vortex zone geometry can be varied.
  • it can also be thought to also dynamically modulate the exit angle according to the above explanations when the shaft furnace is operated.
  • ceramic valves in particular disk valves or piston magnet valves, are provided in the supply lines to the shaft furnace, so that the valves are resistant to high temperatures and to high temperatures.
  • the valves therefore have a particularly low thermal expansion and can therefore be operated without difficulty even at the particularly high temperatures occurring during operation.
  • the device for introducing the treatment gas is connected to at least two storage containers, wherein the storage container are loaded in particular swelling.
  • the storage containers have, in particular, a different volume and / or a different pressure, so that a specific storage container can be connected as needed to achieve a specific modulation. It can also be connected to a plurality of similar storage container so that when emptying the respective storage container, the pressure in the storage tank drops only slightly and sufficient time is available to replenish the storage tank to its original state while the other storage tank is connected.
  • the means for introducing the treatment gas comprises a first set of valves and a second redundant set of valves. This makes it possible to operate the individual sets alternately, so that the valves can cool down.
  • the cooling can be further improved by the not required for the supply of the treatment gas valves by means of a gas, in particular Intertgases be cooled.
  • a method for operating a shaft furnace which in particular in addition to the Anlagensrnerkmalen already described is characterized in that acting on the prevailing in the upper region of the shaft furnace atmosphere starting from the upper portion of the shaft furnace in a dynamically modulated manner ,
  • the above-described effect of dynamic modulations on an area of the atmosphere restricted to the vortex zones can be reduced to one wider range, namely by B.
  • B. is located in the upper region of the shaft furnace blast furnace gas is dynamically modulated.
  • additional gas can be introduced into the upper region of the shaft furnace and / or the top gas pressure can be modulated by suitable control of valves provided in a top gas discharge.
  • the dynamic modulations can advantageously be matched with respect to, for example, period and amplitude such that a direct further resonance excitation becomes possible, or the excitation of a subsystem of the atmosphere prevailing in the shaft furnace only comes about through a coupling effect of the external excitations.
  • the base pressure p 0 in this example is 2.4 bar.
  • the pressure amplitude 2 ⁇ p in this example is 1.2 bar, ie 50% of the basic pressure value p 0 .
  • a pulsation-like modulation of the pressure of a fraction of the treatment gas to be introduced into the shaft furnace is shown.
  • the pulse height p max is 50 bar, which means a pulsation with an amplitude factor of 20 compared to, for example, 2.5 bar ambient pressure of the introduced hot blast.
  • the pulses have a pulse width ⁇ of about 0.4 s, so that a ratio of pulse width to period duration of about 0.1 results.
  • FIG. 3 is a dynamic modulation of the oxygen concentration of the treatment gas exemplified. This is achieved as follows: A self-unmodulated hot blast of the treatment gas provides a constant base concentration n 0 , which corresponds to the natural oxygen concentration in air (the hot blast here consists of hot air). In addition to the hot blast, two more portions of the treatment gas are now introduced. A first portion, which consists either of pure oxygen or of an oxygen-containing gas phase with oxygen concentration n ' 1 , is pulsed periodically initiated with period T 1 of 2 s. The amount of pure oxygen or the concentration n ' 1 is chosen so that the oxygen concentration is increased with respect to the total treatment gas by a concentration difference n 1 .
  • the ratio n 1 / n 0 is about 60%.
  • This phase-shifted pulse-like second gas component leads to an increase in the oxygen concentration with respect to the total treatment gas from n 0 to n 0 + n 2 , as from Fig. 3 is apparent.
  • the ratio n 2 / n 0 is about 40%, so the second gas phase effectively supplies less oxygen to the treatment gas than the first. You can be good in Fig.
  • the phase shift ⁇ t about ⁇ / 2.
  • Fig. 4 shows the temporal modulation of the injection rate of substitute reducing agents, which may be coal dust here, for example, or according to their mass flow m / dt.
  • substitute reducing agents which may be coal dust here, for example, or according to their mass flow m / dt.
  • the pulse width ⁇ here is relatively large and is approximately T / 4.
  • Fig. 5 shows the simultaneous temporal modulation on the one hand of the mass flow m / dt of a substitute reducing agent and on the other hand, a volumetric flow V / dt of oxygen.
  • the temporal modulation of the oxygen volume flow V / dt which is also periodic with T, can be generated, for example, by a proportion V 0 / dt caused by the natural oxygen volume flow of the introduced hot air, and is periodically increased by additionally supplied oxygen pulses. How out Fig.
  • a blast furnace is provided as shaft furnace, which has a pressure of about 2 to 4 bar in its interior.
  • the treatment gas can be injected at a continuous pressure of about 10 bar.
  • a storage container which has a pressure of, for example, 20 bar, can be temporarily switched on via a valve.
  • a short-term pulse can be generated with a pressure increased by 1.5 to 2.5 bar, that is, the pressure of the treatment gas has a pressure of about 12 bar during the pulse.
  • a burst of energy is generated within the blast furnace by the treatment gas, which melts encrustations and slags on the surface of the reaction zone and / or perforates the layer in the encrustations and slags. Since oxygen is transported into the slag layer of the reaction zone by the energy collision, oxidation reactions take place with the slag layer. The resulting dissolved slag allows better flow through the entire blast furnace.
  • the formation of slag can at least be reduced if very small coal particles are mixed in the treatment gas, so that the reaction in the reaction zone results in less unburned constituents that might otherwise settle in the slag.
  • the effects of the modulated blown treatment gas can be enhanced by providing multiple injection sites along the circumference and / or along the height of the blast furnace.
  • a shaft furnace designed, for example, as a cupola can, in principle, be designed and operated as described above with reference to the blast furnace.
  • a cupola is operated at a lower pressure, for example 300 mbar.
  • the treatment gas can be injected continuously at a pressure of 5 bar, wherein the switchable storage container can have a pressure of 12 bar.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Details (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Manufacture Of Iron (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Blast Furnaces (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Heat Treatment Of Articles (AREA)

Claims (10)

  1. Procédé pour faire fonctionner un four à cuve,
    - selon lequel on alimente une zone supérieure du four à cuve avec des matières premières qui descendent dans le four à cuve sous l'action de la gravité, une partie des matières premières étant fondue et/ou au moins partiellement réduite sous l'action de l'atmosphère régnant à l'intérieur du four à cuve,
    - et selon lequel on introduit dans une zone inférieure du four à cuve un gaz de traitement qui influence au moins partiellement l'atmosphère régnant à l'intérieur du four à cuve,
    caractérisé en ce que l'on module l'introduction du gaz de traitement de manière quasi-périodique de telle sorte que, lors de la modulation, on modifie les grandeurs de fonctionnement pression p et/ou débit volumique V au moins temporairement dans les limites d'une durée de période ≤ 5 s.
  2. Procédé selon la revendication 1, la modulation s'effectuant de manière quasi-périodique, la durée de période T étant telle que 5 s ≥ T ≥ 60 ms.
  3. Procédé selon la revendication 1 ou 2, la modulation s'effectuant à la manière d'impulsions, la largeur σ d'une impulsion étant telle que 5 s ≥ σ ≥ 1 ms.
  4. Procédé selon l'une des revendications 1 à 3, la modulation s'effectuant par l'intermédiaire d'un réglage d'au moins une grandeur de fonctionnement.
  5. Procédé selon l'une des revendications 1 à 4, le gaz de traitement étant introduit par au moins deux voies différentes dans le four à cuve, une première grandeur de fonctionnement étant modulée de façon dynamique pour la commande de la part du gaz de traitement qui doit être introduite par la première voie et une deuxième grandeur de fonctionnement étant modulée de façon dynamique pour la commande de la part du gaz de traitement qui doit être introduite par la deuxième voie, la première et la deuxième grandeur de fonctionnement correspondant à la même grandeur de fonctionnement et à des modulations différentes ou la première et la deuxième grandeur de fonctionnement correspondant à des grandeurs de fonctionnement différentes et à la même modulation.
  6. Procédé selon la revendication 5, la première et la deuxième grandeur de fonctionnement étant modulées de manière périodique avec une durée de période T identique, leurs phases relatives étant décalées d'une valeur prédéterminée.
  7. Procédé selon l'une des revendications 2 à 6, l'inverse de la durée de période T-1 étant réglée sur une autofréquence d'un système partiel de l'atmosphère à l'intérieur du four à cuve.
  8. Procédé selon l'une des revendications 1 à 7, le gaz de traitement contenant au moins temporairement, partiellement ou complètement, du gaz inerte pour refroidir des vannes placées dans le débit volumique du gaz de traitement.
  9. Procédé selon l'une des revendications 1 à 8, le gaz de traitement étant modulé de telle sorte que le gaz de traitement forme une onde stationnaire dans le four à cuve.
  10. Procédé selon l'une des revendications 1 à 9, l'introduction du gaz de traitement étant régulée de telle sorte que les matières premières descendent régulièrement à l'intérieur du four à cuve.
EP06840931A 2005-11-09 2006-11-09 Procede d'utilisation d'un four a cuve Active EP1948833B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL06840931T PL1948833T3 (pl) 2005-11-09 2006-11-09 Sposób eksploatacji pieca szybowego

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005053505A DE102005053505A1 (de) 2005-11-09 2005-11-09 Verfahren zum Betreiben eines Hochofens und für dieses Verfahren geeigneter Hochofen
PCT/EP2006/010752 WO2007054308A2 (fr) 2005-11-09 2006-11-09 Procede d'utilisation d'un four a cuve et four a cuve destine a ce procede

Publications (2)

Publication Number Publication Date
EP1948833A2 EP1948833A2 (fr) 2008-07-30
EP1948833B1 true EP1948833B1 (fr) 2011-09-21

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EP06840931A Active EP1948833B1 (fr) 2005-11-09 2006-11-09 Procede d'utilisation d'un four a cuve

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US (2) US8173064B2 (fr)
EP (1) EP1948833B1 (fr)
JP (1) JP5113071B2 (fr)
KR (1) KR20080067644A (fr)
CN (1) CN101305103B (fr)
AT (1) ATE525486T1 (fr)
AU (1) AU2006311226B2 (fr)
BR (1) BRPI0618470B1 (fr)
DE (1) DE102005053505A1 (fr)
EA (1) EA013386B1 (fr)
ES (1) ES2373462T3 (fr)
PL (1) PL1948833T3 (fr)
WO (1) WO2007054308A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014102913A1 (de) 2014-03-05 2015-09-10 Thyssenkrupp Ag Verfahren zum Betreiben eines Schachtofens, insbesondere eines Hochofens

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005053505A1 (de) * 2005-11-09 2007-05-10 At.Protec Technologie Team Gmbh Verfahren zum Betreiben eines Hochofens und für dieses Verfahren geeigneter Hochofen
DE102007029629A1 (de) 2007-06-26 2009-01-02 Thyssenkrupp At.Pro Tec Gmbh Schachtofen und Verfahren zum Betreiben eines Schachtofens
JP2012136762A (ja) * 2010-12-28 2012-07-19 Kubota Corp シャフト炉およびこれを用いた銑鉄溶湯の製造方法
AT510686B1 (de) * 2011-02-23 2012-06-15 Sgl Carbon Se Verfahren zum aufarbeiten von verbrauchtem kohlenstoffhaltigen kathodenmaterial
DE102012103996B4 (de) 2011-06-01 2017-04-20 Krytem - Kryotechnische + medizinische Systeme GmbH Verfahren und Vorrichtung zum Betreiben eines Schachtofens sowie Ventil zur Einleitung in einen Schachtofen
US9797023B2 (en) 2013-12-20 2017-10-24 Grede Llc Shaft furnace and method of operating same
DE102019135200A1 (de) * 2019-12-19 2021-06-24 SMB Rohrleitungsbau Wildau GmbH & Co. KG Rohr, Reaktor und Verfahren

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2814479A (en) * 1953-01-12 1957-11-26 Otto J Leone Blast furnace control system
DE1012944B (de) * 1954-10-08 1957-08-01 Ko We Niederschachtofen Ges M Verfahren zur Regelung der Windtemperatur des Heisswindschachtofens
GB932977A (en) 1960-06-27 1963-07-31 Exxon Research Engineering Co Control of sulfur content in metals
GB986807A (en) * 1961-01-20 1965-03-24 Yawata Iron & Steel Co Blast controlling device for blast furnaces
DE1229564B (de) * 1961-10-13 1966-12-01 Siderurgie Fse Inst Rech Verfahren zum selbsttaetigen Regeln der Brennstoffzufuhr in einen Hochofen mittels Brennern, die in den Heisswindformen angeordnet sind
NL157056B (nl) * 1970-06-20 1978-06-15 Nippon Kokan Kk Werkwijze voor het reduceren van ijzererts in een hoogoven.
BE794545A (fr) 1973-01-25 1973-07-25 Centre Rech Metallurgique Procede d'injection de gaz reducteurs au haut fourneau
US4031183A (en) * 1975-03-17 1977-06-21 Terence Arthur Rourke Process for calcining limestone
US4097225A (en) * 1976-02-17 1978-06-27 Terence Arthur Rourke Process and apparatus for calcining limestone
AT378970B (de) * 1982-12-21 1985-10-25 Voest Alpine Ag Verfahren und vorrichtung zur herstellung von flùssigem roheisen oder stahlvorprodukten
JPH01162708A (ja) * 1987-12-18 1989-06-27 Nkk Corp 高炉操業法
DE19835271A1 (de) * 1998-08-04 2000-02-10 Linde Ag Verfahren zum Betreiben eines Schachtofens
DE19909742A1 (de) * 1999-03-05 2000-09-07 Linde Tech Gase Gmbh Verfahren zum Betreiben eines Schachtofens
DE19936395C2 (de) * 1999-08-03 2002-07-18 Antonia Buntz Kosmetikpflaster und Verfahren zum Anheben der weiblichen Brust mittels eines solchen Kosmetikpflasters und seine Verwendung
DE19954556A1 (de) * 1999-11-12 2001-05-23 Messer Griesheim Gmbh Verfahren zum Betreiben eines Schmelzofens
CN1144882C (zh) * 1999-11-30 2004-04-07 宝山钢铁股份有限公司 冶金竖炉鼓风方法及其设备
JP4742442B2 (ja) * 2000-08-10 2011-08-10 Jfeスチール株式会社 微粉炭の多量吹込みによる高炉操業方法
DE102005053505A1 (de) * 2005-11-09 2007-05-10 At.Protec Technologie Team Gmbh Verfahren zum Betreiben eines Hochofens und für dieses Verfahren geeigneter Hochofen

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014102913A1 (de) 2014-03-05 2015-09-10 Thyssenkrupp Ag Verfahren zum Betreiben eines Schachtofens, insbesondere eines Hochofens
WO2015132159A1 (fr) 2014-03-05 2015-09-11 Thyssenkrupp Steel Europe Ag Procédé d'exploitation d'un fourneau à cuve, en particulier d'un haut fourneau
RU2696987C1 (ru) * 2014-03-05 2019-08-08 Тиссенкрупп Стил Юроп Аг Способ эксплуатации шахтной печи, в частности доменной печи
US10386119B2 (en) 2014-03-05 2019-08-20 Thyssenkrupp Ag Method for operating a shaft furnace

Also Published As

Publication number Publication date
DE102005053505A1 (de) 2007-05-10
ES2373462T3 (es) 2012-02-03
US20080237944A1 (en) 2008-10-02
EA013386B1 (ru) 2010-04-30
WO2007054308A2 (fr) 2007-05-18
AU2006311226A1 (en) 2007-05-18
US20120217684A1 (en) 2012-08-30
JP5113071B2 (ja) 2013-01-09
PL1948833T3 (pl) 2012-04-30
US8444910B2 (en) 2013-05-21
AU2006311226B2 (en) 2010-09-09
ATE525486T1 (de) 2011-10-15
US8173064B2 (en) 2012-05-08
EA200801076A1 (ru) 2008-10-30
WO2007054308A3 (fr) 2007-09-13
EP1948833A2 (fr) 2008-07-30
JP2009515049A (ja) 2009-04-09
CN101305103A (zh) 2008-11-12
CN101305103B (zh) 2012-07-04
KR20080067644A (ko) 2008-07-21
BRPI0618470A2 (pt) 2011-08-30
BRPI0618470B1 (pt) 2016-07-05

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