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EP1831459B1 - Procede de fabrication de papier, de carton-pate et de carton - Google Patents

Procede de fabrication de papier, de carton-pate et de carton Download PDF

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Publication number
EP1831459B1
EP1831459B1 EP05817729.6A EP05817729A EP1831459B1 EP 1831459 B1 EP1831459 B1 EP 1831459B1 EP 05817729 A EP05817729 A EP 05817729A EP 1831459 B1 EP1831459 B1 EP 1831459B1
Authority
EP
European Patent Office
Prior art keywords
retention aid
process according
finely divided
inorganic component
divided inorganic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP05817729.6A
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German (de)
English (en)
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EP1831459A1 (fr
Inventor
Oliver Koch
Frank Prechtl
Rainer Blum
Detlef Kannengiesser
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BASF SE
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BASF SE
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/10—Retention agents or drainage improvers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D21H17/375—Poly(meth)acrylamide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/56—Polyamines; Polyimines; Polyester-imides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
    • D21H23/06—Controlling the addition
    • D21H23/14—Controlling the addition by selecting point of addition or time of contact between components
    • D21H23/18—Addition at a location where shear forces are avoided before sheet-forming, e.g. after pulp beating or refining

Definitions

  • the invention relates to a process for the production of paper, paperboard and cardboard by adding a microparticle system of a polymeric retention agent having a molecular weight M w of at least 2 million and a finely divided inorganic component to a pulp having a maximum density of 20 g / l and dewatering the Textilstoffs, wherein the pulp before or after the addition of the cationic retention agent is subjected to at least one shear stage.
  • EP-A-0 223 223 is a method for the production of paper and cardboard by dehydration of a paper material known, wherein first added to a paper stock with a concentration of 2.5 to 5 wt .-% bentonite, then diluted the paper stock, a highly cationic polymer with a charge density of min 4 meq / g is added and finally a high molecular weight polymer based on acrylamide is added and the resulting pulp is dewatered after thorough mixing.
  • an essentially linear synthetic cationic polymer having a molecular weight of more than 500,000 in an amount of more than 0.03% by weight, based on dry paper stock, of an aqueous pulp suspension is first metered into the mixture then the action of a shear field, wherein the first formed flakes are cut into microflakes carrying a cationic charge, then dosed bentonite and dewatered the pulp thus obtained without further action of shear forces.
  • EP-A-0 335 575 describes a papermaking process in which a polymeric cationic fixing agent and then a water-soluble cationic polymer are metered into a pulp, the pulp thus obtained is then subjected to at least one shear stage and then flocculated by the addition of bentonite.
  • EP-A-0 885 328 describes a process for the production of paper, wherein initially dosed to an aqueous pulp suspension, a cationic polymer, then subjecting the mixture to the action of a shear field, then adding an activated bentonite and dewatering the pulp thus obtained.
  • EP-A-0 910 701 describes a process for the production of paper and board, wherein the paper pulp successively added a low molecular weight or medium molecular weight cationic polymer based on polyethyleneimine or polyvinylamine and then with a high molecular weight cationic polymer such as polyacrylamide, polyvinylamine or cationic starch. After this pulp has been subjected to at least one shear stage, it is flocculated by addition of bentonite and the pulp is dewatered.
  • WO-A-01/34910 there is described a process for producing paper in which a polysaccharide or a synthetic, high molecular weight polymer is metered into the pulp suspension. Subsequently, a mechanical shear of the pulp must take place.
  • the reflocculation is carried out by adding an inorganic component such as silica, bentonite or clay and a water-soluble polymer.
  • From the US-A-6,103,065 discloses a method of improving the retention and dewatering of paper stocks by adding a cationic polymer having a molecular weight of 100,000 to 2 million and a charge density of more than 4.0 meq./g to a pulp after the last shearing, simultaneously or thereafter adding a polymer having a molecular weight of at least 2 million and a charge density of less than 4.0 meq./g and then metering in bentonite. It is not necessary in this method to shear the stock after the addition of the polymers. After addition of the polymers and the bentonite, the pulp can be dewatered without further action of shearing forces.
  • From the DE-A-102 36 252 is a method for producing paper, paperboard and cardboard by shearing a stock, adding a microparticle system of a cationic polymer and a finely divided inorganic component to the pulp after the last shear stage before the headbox, dewatering the stock to form sheets and drying the sheets one as cationic Polymers of the microparticle system cationic polyacrylamides, vinylamine units containing polymers and / or polydiallyldimethylammonium chloride having an average molecular weight M w of at least 500 000 daltons and a charge density of at most 4.0 meq./g used.
  • US 6719881 describes a microparticle system for use as a retention and drainage aid in the manufacture of alkaline and acid paper products containing a high molecular weight flocculant polymer, an acid colloid and a coagulant or flocculant having an average molecular weight.
  • the acid colloid comprises an aqueous solution of the water-soluble polymer or copolymer of melamine-aldehyde, preferably melamine-formaldehyde, and is present in an amount ranging from 0.0005% by weight to 0.5% by weight, based on the dry weight of Solids in the substance entry, available.
  • EP 1039026 discloses the production of paper by the formation of a thick stock cellulose suspension, flocculation of the thick stock by adding a polymer having a relatively high molecular weight and a relatively low cationic charge density, diluting the flocculated thick stock to form a thin stock, and then dewatering the thin stock; to form a paper sheet.
  • the coagulant is added to the slurry prior to dewatering and the best results are achieved by adding the coagulant followed by anionic colloidal material, such as bentonite.
  • the present invention has for its object to provide a further method for the production of paper, cardboard and paperboard using a microparticle system, which gives better retention and papers having an improved formation compared to the known methods.
  • the object is achieved with a method for producing paper, cardboard and cardboard by adding a microparticle system consisting of at least one cationic polymeric retention agent having a molecular weight M w of at least 2 million and a finely divided inorganic component to a pulp having a consistency of at most 20 g / l and dewatering the Textilstoffs, wherein the pulp before or after the addition of the retention agent is subjected to at least one shear stage, when dosed the retention agent at least two locations in the pulp and the finely divided inorganic component before or after the addition of the retention agent or between two dosing agents for retention aids, wherein one uses as finely divided inorganic component of the microparticle system at least one bentonite, colloidal silica, silicates, calcium carbonate or mixtures thereof.
  • all paper qualities can be produced, for example cardboard, single or multilayer carton, single or multi-layer liners, corrugating medium, papers for newspaper printing, so-called medium-fine writing and printing papers, natural gravure papers and lightweight base papers.
  • TMP thermo-mechanical pulp
  • CMP chemo-thermo-mechanical fabric
  • PGW pressure ground
  • wood pulp and sulfite and sulfate pulp emanate.
  • the pulps can be short fiber as well as long fiber.
  • fibers recovered from recovered paper alone or in admixture with other fibers for the manufacture of paper, board and cardboard Preferably, wood-free grades are produced by the process according to the invention, which yield highly white paper products.
  • the papers may optionally contain up to 40 wt .-%, usually 5 to 35 wt .-% fillers.
  • Suitable fillers are e.g. Titanium dioxide, natural and pre-painted chalk, talc, kaolin, satin white, calcium sulfate, barium sulfate, clay or alumina.
  • the production of the paper products takes place continuously. Usually, one starts from a thick material having, for example, a consistency in the range of 3 to 6 wt .-%.
  • the thick material is diluted to a substance density of at most 20 g / l and processed according to the invention to the respective desired paper product.
  • the consistency is for example 3 to 15 g / l, preferably 5 to 12 g / l and is usually in the range of 6 to 10 g / l.
  • the microparticle system according to the invention consists of at least one polymeric retention agent having a molecular weight M w of at least 2 million and a finely divided anionic component.
  • the retention aid may be cationic, anionic, amphoteric or nonionic.
  • the average molecular weight M w of the polymeric retention aids is at least 2 million daltons, preferably at least 3 million, and is usually in the range of, for example, 3.5 million to 15 million.
  • the charge density of the polymers in question is for example at most 4.0 meq./g.
  • cationic polyacrylamides having an average molecular weight M w of at least 5 million daltons and a charge density of 0.1 to 3.5 meq./g and polyvinylamines obtainable by hydrolysis of vinylformamide units containing polymers and having an average molecular weight of at least Have 2 million daltons.
  • the polyvinylamines are preferably prepared by hydrolysis of homopolymers of N-vinylformamide, wherein the degree of hydrolysis, for example, up to 100%, usually 70 to 95%.
  • High molecular weight copolymers of N-vinylformamide with other ethylenically unsaturated monomers such as vinyl acetate, vinyl propionate, methyl acrylate, methyl methacrylate, acrylamide, acrylonitrile and / or methacrylonitrile, can be hydrolyzed to vinylamine units containing polymers and used according to the invention.
  • all polyvinylamines having a molecular weight M w of at least 2 million can be used according to the invention, which are obtainable by hydrolysis of vinylformamide units-containing polymers, the degree of hydrolysis of the vinylformamide units being 0.5 to 100 mol%.
  • the preparation of homopolymers and copolymers of N-vinylformamide is known. For example, in the US 6,132,558 , Column 2, line 36 to column 5, line 25 described in detail. The statements made there are hereby incorporated by reference into the disclosure content of the present application.
  • Cationic polyacrylamides are, for example, copolymers prepared by copolymerizing acrylamide and at least one di-C 1 -bisC 2 -alkylamino-C 2 -bisC 4 -alkyl (meth) acrylate or a basic acrylamide in the form of the free bases, the salts with organic or inorganic acids or the alkyl halides quaternized compounds are available.
  • Examples of such compounds are dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, diethylaminoethyl acrylate, dimethylaminopropyl methacrylate, dimethylaminopropyl acrylate, diethylaminopropyl methacrylate, diethylaminopropyl acrylate and / or dimethylaminoethylacrylamide, dimethylaminoethylmethacrylamide, dimethylaminopropylacrylamide, dimethylaminopropylmethacrylamide and / or diallyldimethylammonium chloride.
  • the comonomers mentioned can also be copolymerized with methacrylamide to form cationic polymethacrylamides containing, for example, 5 to 40 mol% of at least one cationic monomer, such as dimethylaminoethyl acrylate or diallyldimethylammonium chloride, in copolymerized form.
  • Cationic polymethacrylamides can also be used as the polymeric retention aid of the microparticle system.
  • polymers containing cationic polyacrylamides and vinylamine units may be the references cited in the prior art, such as EP-A-0 910 701 and US-A-6,103,065 be removed.
  • Such polymers are commercial products.
  • Branched polymers which can be prepared, for example, by copolymerization of acrylamide or methacrylamide with at least one cationic monomer in the presence of small amounts of crosslinking agents are described, for example, in the references cited in the prior art US Patent No. 5,393,381 .
  • WO-A-99/66130 and WO-A-99/63159 described.
  • polystyrene resins are poly (N-vinylformamides).
  • N-vinylformamides are prepared by polymerizing N-vinylformamide into homopolymers or by copolymerizing N-vinylformamide together with at least one other ethylenically unsaturated monomer.
  • the vinylformamide units of these polymers are not hydrolysed, in contrast to the preparation of polymers containing vinylamine units.
  • the copolymers can be cationic, anionic or amphoteric.
  • Cationic polymers are obtained, for example, by copolymerizing N-vinylformamide with at least one of the basic monomers mentioned in the copolymerization of acrylamide.
  • Anionic polymers of N-vinylformamide are obtainable by copolymerizing N-vinylformamide in the presence of at least one acid monoethylenically unsaturated monomer.
  • Such comonomers are, for example, monoethylenically unsaturated C 3 -bis C 5 carboxylic acids, acrylamido-2-methylpropanesulfonic acid, styrenesulfonic acid or sulfopropyl acrylate.
  • the acidic monomers can also be used in completely neutralized with alkali metal, alkaline earth metal and / or ammonium bases in the copolymerization with N-vinylformamide.
  • copolymers mentioned contain units of anionic or cationic monomers, for example, in amounts of 0.5 to 50, preferably 5 to 40 mol% copolymerized.
  • Copolymers of N-vinylformamide can also be amphoteric if they contain units of anionic and cationic monoethylenically unsaturated monomers in copolymerized form.
  • nonionic polyacrylamides and nonionic polymethacrylamides obtainable by polymerizing acrylamide and / or methacrylamide, as well as anionic polyacrylamides and anionic polymethacrylamides.
  • the anionic poly (meth) acrylamides are obtainable, for example, by polymerizing acrylamide or methacrylamide with at least one anionic monomer.
  • Suitable anionic monomers are, for example, monoethylenically unsaturated C 3 -C 5 -carboxylic acids, such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, vinylacetic acid or ethacrylic acid, and vinylphosphonic acid, styrenesulfonic acid, acrylamido-2-methylpropanesulfonic acid, sulfopropyl acrylate or sulfopropyl methacrylate and the alkali metal, alkaline earth metal and ammonium salts of the acid group-containing monomers into consideration.
  • monoethylenically unsaturated C 3 -C 5 -carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, vinylacetic acid or ethacrylic acid, and vinylphosphonic acid, styrenesulfonic acid, acrylamido-2-methylpropanesulfonic acid
  • the anionic copolymers contain, for example, 1 to 50 mol%, preferably 5 to 40 mol% of at least one anionic monomer in copolymerized form.
  • amphoteric copolymers of acrylamide and methacrylamide can be used as the polymeric retention aid of the microparticle system.
  • Such copolymers are obtainable by copolymerizing acrylamide or methacrylamide in the presence of at least one anionic and at least one cationic ethylenically unsaturated monomer.
  • Suitable cationic polymeric retention aids of the microparticle system are polydiallyldimethylammonium chlorides (PolyDADMAC) with an average molecular weight of at least 2 million daltons. Polymers of this type are commercial products.
  • the polymeric retention aids of the microparticle system are added to the paper stock in an amount of 0.005 to 0.5% by weight, preferably in an amount of 0.01 to 0.25% by weight, based on dry paper stock.
  • Suitable inorganic components of the microparticle system are, for example, bentonite, colloidal silicic acid, silicates and / or calcium carbonate.
  • Colloidal silicic acid is to be understood as meaning products based on silicates, for example silica microgel, silical sol, polysilicates, aluminum silicates, boron silicates, polyborosilicates, clay or zeolites.
  • Calcium carbonate can be used, for example, in the form of chalk, ground calcium carbonate or precipitated calcium carbonate can be used as the inorganic component of the microparticle system.
  • Bentonite is generally understood to be phyllosilicates which are swellable in water.
  • clay mineral montmorillonite and similar clay minerals such as nontronite, hectorite, saponite, sauconite, beidellite, allevardite, illite, halloysite, attapulgite and sepiolite.
  • These phyllosilicates are preferably activated before use, ie converted into a water-swellable form in which the phyllosilicates are treated with an aqueous base such as aqueous solutions of caustic soda, potassium hydroxide, soda, potash, ammonia or amines.
  • Bentonite in the form treated with sodium hydroxide or those bentonites which are already obtained in the sodium form, so-called Wyoming bentonites, are preferably used as the inorganic component of the microparticle system.
  • the platelet diameter of the water-dispersed bentonite in the sodium hydroxide-treated form is, for example, at most 1 to 2 ⁇ m, the thickness of the platelets is approximately 1 nm.
  • the bentonite has a specific surface area of 60 to 800 m 2 / g .
  • Typical bentonites are used in the EP-B-0235893 described.
  • bentonite is added to the cellulosic suspension, typically in the form of an aqueous bentonite slurry.
  • This bentonite slurry may contain up to 10% by weight of bentonite. Normally, the slurries contain about 3 to 5 wt .-% bentonite.
  • colloidal silica products from the group of silicon-based particles, silica microgels, silica sols, aluminum silicates, borosilicates, polyborosilicates or zeolites can be used. These have a specific surface area of 50 to 1500 m 2 / g and an average particle size distribution of 1-250 nm, normally in the range 5-100 nm.
  • the preparation of such components is described, for example, in US Pat EP-A-0 041 056 .
  • Clay or kaolin is a hydrous aluminum silicate with a platelet-like structure.
  • the crystals have a layer structure and an aspect ratio (diameter to thickness ratio) of up to 30: 1.
  • the particle size is e.g. at least 50% smaller than 2 ⁇ m.
  • the carbonates used are preferably natural calcium carbonate (ground calcium carbonate, GCC) or precipitated calcium carbonate (PCC).
  • GCC is produced, for example, by grinding and visual processes using grinding aids. It has a particle size of 40 - 95% less than 2 microns, the specific surface area is in the range of 6-13 m 2 / g.
  • PCC is made by passing carbon dioxide into an aqueous calcium hydroxide solution. The average particle size is in the range of 0.03-0.6 ⁇ m.
  • the specific surface area can be greatly influenced by the choice of precipitation conditions. It is in the range of 6 to 13 m 2 / g.
  • the inorganic component of the microparticle system is added to the stock in an amount of 0.01 to 2.0% by weight, preferably in an amount of 0.1 to 1.0% by weight, based on dry stock.
  • the aqueous fiber slurry is subjected to at least one shear stage. It goes through at least one cleaning, mixing and / or pumping stage.
  • the shearing of the pulp (thin material) can be done for example in a pulper, classifier or in a refiner.
  • the retention agent is metered according to the invention in at least two places in the thin and the finely divided inorganic component before or after the addition of the retention agent or between two dosing sites for retention aid.
  • the process can be carried out, for example, by adding the retention agent after the last shear stage to at least two successive points and then metering the finely divided inorganic component.
  • the retention agent after the last shear stage is added to at least two points which have the same distance from the shear stage, and then dosed the finely divided inorganic component.
  • the process can also be carried out by adding the retention agent before the last shear stage at at least two points, which are arranged in a plane perpendicular to the stock flow or behind one another, and by metering the finely divided inorganic component after the last shear stage.
  • At least one retention agent to the thin material, to subject the system to shear, then to add at least one retention agent (identical or preferably different to the first-dosed retention agent) and then to add at least one finely divided inorganic component.
  • the process according to the invention it is possible first to meter 25 to 75% by weight of the total retention agent before the last shear stage and the remaining portion of the retention agent and then to add the finely divided inorganic component or to meter it first before the last Scherimpl the finely divided inorganic component and 25 to 75 wt .-% of the retention agent and after the last shear stage the remaining portion of the retention agent.
  • the finely divided inorganic component is metered in each case before the last shearing stage, followed by the retention agent at least two in a plane perpendicular to the first Textilstoffstrom or at successively arranged locations.
  • the flow rate of the paper pulp stream is, for example, at least 2 m / sec in most paper machines and is usually in the range of 3 to 7 m / sec.
  • the dosage of the retention agent can be made for example by means of single or multi-fluid nozzles in the paper stream. This achieves a rapid distribution of the retention agent in the pulp.
  • the distance between the center of the metering points of the retention agent is, for example, at least 20 cm in successive addition of retention agent.
  • the distance between the center of a metering point for retention agent and the center of a metering point for the finely divided inorganic component for example, also at least 20 cm.
  • the retention sites for retention aids can also be arranged in a plane perpendicular to the stock flow.
  • the distance between the center of the dosing points of the retention agent is preferably at least 50 cm and the distance between the center of a dosing point for retention agent and the center of a dosing point for the finely divided inorganic component at least 50 cm.
  • the distance between the center of the dosing points of the retention agent is in most cases, for example in the range of 50 cm to 15 m, wherein the distance between the center of a dosing agent for retention agent and the center of a dosing point for the finely divided inorganic component, for. at least 50 cm.
  • the location of the addition points is preferably such that the distance between the center of the dosing points of the retention agent is 50 cm to 10 m and the distance between the center of a dosing point for retention agent and the center of a dosing point for the finely divided inorganic component 50 cm to 5 m.
  • the retention agents can also be metered into the paper stock stream at 3 to 5 positions arranged one behind the other. Likewise, it is possible to meter the finely divided inorganic component of the retention agent system into the stock stream at at least two successive locations.
  • the customary amounts of process chemicals customarily used in papermaking for example fixatives, dry and wet strength agents, engine sizes, biocides and / or dyes.
  • the paper stock is dewatered on a sieve with formation of sheets. The leaves thus produced are dried. Dehydrating the pulp and Drying of the sheets are part of the papermaking process and are carried out continuously in the art.
  • the process according to the invention gives papers having a surprisingly good formation and, compared to known microparticle processes, has an improved filler and fines retention.
  • the First Pass Retention was determined by determining the ratio of the solids content in the white water to the solids content in the headbox. The information is given in percent.
  • the first pass ash retention (FPAR) was determined analogously to the FPR, but only the ash content was considered.
  • the formation was measured with a TECHPAP 2D Lab Formation Sensor from Tecpap).
  • the dimensionless FX value is given in the table. The lower this value, the better the formation of the tested paper.
  • Mikroflocc® XFB As an inorganic component of the microparticle system, Mikroflocc® XFB was used.
  • Mikrofloc® XFB is a bentonite powder activated by treatment with aqueous caustic soda. It is usually converted on site in a 3-5% suspension.
  • the following examples and comparative examples were carried out on a GAP Former test paper machine. From a wood-free, bleached pulp was first prepared a pulp with a consistency of 8 g / l and 20% calcium carbonate as a filler, which in the examples and in the comparative examples in each case to a wood-free writing and printing paper having a basis weight of 80 g / m 2 was processed.
  • the paper machine contained the following arrangement of mixing and shearing units: mixing vessel, dilution, deaerator, screen and headbox. One ton of paper was produced per hour. The addition (amount and metering point) of retention aid and finely divided inorganic component was varied as indicated in the examples and comparative examples. The results obtained in each case are given in the table.
  • 650 g / t Polymin 215 (the term "650 g / t" means that 650 g Polymin® 215 were used per ton of produced paper) were added in 2 doses to 350 g / t and 300 g / t with a distance of the dosing of 300 cm in each case before screen and then 2500 g / t of Microfloc® XFB after screen fed to the paper stock described above.
  • Example 1 was repeated with the sole exception that the retention agent (650 g / t Polymin 215) was metered in at a single site 400 cm before screen.
  • Example 2 was repeated with the sole exception that the retention agent (450 g / t Polymin 215) was metered in at a single point.

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Claims (19)

  1. Procédé de fabrication de papier, de carton mince et de carton, par addition d'un système de microparticules, constitué d'au moins un agent de rétention polymère cationique ayant une masse moléculaire Mw d'au moins 2 millions et d'un composant inorganique finement divisé, pour donner une pâte à papier ayant une masse volumique de la pâte d'au plus 20 g/l, et de déshydratation de la pâte à papier, la pâte à papier étant, avant ou après addition de l'agent de rétention polymère cationique, soumis au moins à une étape de cisaillement, caractérisé en ce qu'on dose l'agent de rétention polymère cationique en au moins deux points dans la pâte à papier et le composant organique finement divisé avant ou après addition de l'agent de rétention, ce pour quoi on ajoute en tant que composant inorganique finement divisé du système de microparticules au moins une bentonite, une silice colloïdale, des silicates, du carbonate de calcium ou des mélanges de ceux-ci.
  2. Procédé selon la revendication 1, caractérisé en ce qu'on ajoute l'agent de rétention, après la dernière étape de cisaillement, en au moins deux points situés l'un derrière l'autre, puis on dose le composant inorganique finement divisé.
  3. Procédé selon la revendication 1, caractérisé en ce qu'on ajoute l'agent de rétention, après la dernière étape de cisaillement, en au moins deux points, qui sont éloignés de la même distance de l'étape de cisaillement, puis on dose le composant inorganique finement divisé.
  4. Procédé selon la revendication 1, caractérisé en ce qu'on ajoute l'agent de rétention, avant la dernière étape de cisaillement, en au moins deux points, qui sont disposés dans un plan perpendiculairement au flux de pâte à papier ou l'un derrière l'autre, et on dose le composant inorganique finement divisé après la dernière étape de cisaillement.
  5. Procédé selon la revendication 1, caractérisé en ce qu'on dose 25 à 75 % en poids de la totalité de l'agent de rétention avant la dernière étape de cisaillement, et ensuite la partie restante de l'agent de rétention, puis on ajoute le composant inorganique finement divisé.
  6. Procédé selon la revendication 1, caractérisé en ce qu'on dose, avant la dernière étape de cisaillement, d'abord le composant inorganique finement divisé et 25 à 75 % en poids de l'agent de rétention, et, après la dernière étape de cisaillement, la partie restante de l'agent de rétention.
  7. Procédé selon la revendication 1, caractérisé en ce qu'on dose, avant la dernière étape de cisaillement, d'abord le composant organique finement divisé et l'agent de rétention en au moins deux points disposés dans un plan perpendiculairement au flux de pâte à papier, ou l'un derrière l'autre.
  8. Procédé selon l'une des revendications 1 à 7, caractérisé en ce que la distance entre les centres des points de dosage des agents de rétention est d'au moins 20 cm, et que la distance entre le centre d'un point de dosage des agents de rétention et le centre d'un point de dosage du composant organique finement divisé est d'au moins 20 cm.
  9. Procédé selon l'une des revendications 1 à 8, caractérisé en ce que la distance entre les centres des points de dosage des agents de rétention est d'au moins 50 cm et que la distance entre le centre d'un point de dosage des agents de rétention et le centre d'un point de dosage du composant inorganique finement divisé est d'au moins 50 cm.
  10. Procédé selon l'une des revendications 1 à 9, caractérisé en ce que la distance entre les centres des points de dosage des agents de rétention est de 50 cm à 15 m et que la distance entre le centre d'un point de dosage des agents de rétention et le centre d'un point de rétention du composant inorganique finement divisé est d'au moins 50 cm.
  11. Procédé selon l'une des revendications 1 à 10, caractérisé en ce que la distance entre les centres des points de dosage des agents de rétention est de 50 cm à 10 m et que la distance entre le centre d'un point de dosage des agents de rétention et le centre d'un point de dosage du composant organique finement divisé est de 50 cm à 5 m.
  12. Procédé selon l'une des revendications 1 à 11, caractérisé en ce qu'on utilise en tant qu'agent de rétention au moins un polymère du groupe des polyacrylamides non ioniques, des polyacrylamides cationiques, des polyacrylamides anioniques, des poly(N-vinylformamides), des polymères contenant des motifs vinylamine et des chlorures de diallyldiméthylammonium.
  13. Procédé selon l'une des revendications 1 à 12, caractérisé en ce qu'on utilise en tant qu'agent de rétention au moins un polymère cationique ayant une densité de charge d'au plus 4 méq/g.
  14. Procédé selon l'une des revendications 1 à 13, caractérisé en ce qu'on utilise en tant qu'agent de rétention au moins un polymère ayant une masse moléculaire Mw d'au moins 3 millions.
  15. Procédé selon l'une des revendications 1 à 14, caractérisé en ce qu'on utilise en tant qu'agent de rétention au moins une polyvinylamine qui peut être obtenue par hydrolyse de polymères contenant des motifs vinylformamide, le degré d'hydrolyse des motifs vinylformamide étant de 5 à 100 % en moles.
  16. Procédé selon l'une des revendications 1 à 15, caractérisé en ce que l'agent de rétention est utilisé en une quantité de 0,005 à 0,5 % en poids par rapport à la pâte à papier sèche.
  17. Procédé selon l'une des revendications 1 à 16, caractérisé en ce qu'on utilise l'agent de rétention en une quantité de 0,01 à 0,25 % en poids par rapport à la pâte à papier sèche.
  18. Procédé selon l'une des revendications 1 à 17, caractérisé en ce qu'on utilise le composant inorganique finement divisé du système de microparticules en une quantité de 0,01 à 2,0, de préférence de 0,1 à 1,0 % en poids par rapport à la pâte à papier sèche, et qu'on le dose dans le flux de pâte à papier en au moins deux points disposés l'un derrière l'autre.
  19. Procédé selon l'une des revendications 1 à 18, caractérisé en ce qu'on dose les agents de rétention dans le flux de pâte à papier en 3 à 5 points disposés l'un derrière l'autre.
EP05817729.6A 2004-12-22 2005-12-17 Procede de fabrication de papier, de carton-pate et de carton Revoked EP1831459B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004063005A DE102004063005A1 (de) 2004-12-22 2004-12-22 Verfahren zur Herstellung von Papier, Pappe und Karton
PCT/EP2005/013631 WO2006069660A1 (fr) 2004-12-22 2005-12-17 Procede de fabrication de papier, de carton-pate et de carton

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EP1831459A1 EP1831459A1 (fr) 2007-09-12
EP1831459B1 true EP1831459B1 (fr) 2016-03-23

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EP05817729.6A Revoked EP1831459B1 (fr) 2004-12-22 2005-12-17 Procede de fabrication de papier, de carton-pate et de carton

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US (1) US7998314B2 (fr)
EP (1) EP1831459B1 (fr)
CN (1) CN101084346B (fr)
CA (1) CA2589653C (fr)
DE (1) DE102004063005A1 (fr)
ES (1) ES2572776T3 (fr)
PT (1) PT1831459E (fr)
WO (1) WO2006069660A1 (fr)

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CA2862095C (fr) * 2012-02-01 2017-04-11 Basf Se Procede pour la fabrication de papier et de carton
ES2663384T5 (es) * 2012-03-01 2024-10-18 Basf Se Proceso para la fabricación de papel y cartón
CN104903513B (zh) * 2013-01-11 2017-11-17 巴斯夫欧洲公司 生产纸和纸板的方法
ES2873105T3 (es) * 2013-01-11 2021-11-03 Solenis Technologies Cayman Lp Proceso para la fabricación de papel y cartón
WO2017147392A1 (fr) * 2016-02-26 2017-08-31 Ecolab Usa Inc. Gestion du drainage dans la fabrication de papier multicouches
CN106868913B (zh) * 2017-03-30 2020-11-17 山鹰国际控股股份公司 二元阳离子助留体系的助滤方法
CN117321266B (zh) * 2021-05-17 2025-09-23 斯道拉恩索公司 用于瓦楞纸板的多片层挂面纸

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Publication number Publication date
EP1831459A1 (fr) 2007-09-12
WO2006069660A1 (fr) 2006-07-06
DE102004063005A1 (de) 2006-07-13
CN101084346B (zh) 2012-05-30
US20100282424A1 (en) 2010-11-11
CA2589653C (fr) 2014-10-07
US7998314B2 (en) 2011-08-16
ES2572776T3 (es) 2016-06-02
PT1831459E (pt) 2016-06-02
CN101084346A (zh) 2007-12-05
CA2589653A1 (fr) 2006-07-06

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