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EP1808511A1 - Méthode pour rêvetir un compresseur - Google Patents

Méthode pour rêvetir un compresseur Download PDF

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Publication number
EP1808511A1
EP1808511A1 EP06000849A EP06000849A EP1808511A1 EP 1808511 A1 EP1808511 A1 EP 1808511A1 EP 06000849 A EP06000849 A EP 06000849A EP 06000849 A EP06000849 A EP 06000849A EP 1808511 A1 EP1808511 A1 EP 1808511A1
Authority
EP
European Patent Office
Prior art keywords
coating material
compressor
compressor component
component
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06000849A
Other languages
German (de)
English (en)
Inventor
Martin Biesenbach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Siemens Corp
Original Assignee
Siemens AG
Siemens Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG, Siemens Corp filed Critical Siemens AG
Priority to EP06000849A priority Critical patent/EP1808511A1/fr
Priority to PCT/EP2007/050070 priority patent/WO2007082794A1/fr
Publication of EP1808511A1 publication Critical patent/EP1808511A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125Process of deposition of the inorganic material
    • C23C18/1254Sol or sol-gel processing
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125Process of deposition of the inorganic material
    • C23C18/1262Process of deposition of the inorganic material involving particles, e.g. carbon nanotubes [CNT], flakes
    • C23C18/127Preformed particles

Definitions

  • the invention relates to a process for the surface coating of a component based on sol-gel, in particular a closed compressor impeller.
  • Preferred field of application of the invention is the coating of media-contacted compressor components.
  • undercut or channel-like closed components are particularly emphasized, since the invention primarily eliminates the problems that was previously associated with the coating of these components.
  • a ceramic one Layer with organic components can be particularly effective here.
  • Such layers are for example in the DE 197 14 949 A1 and the DE 199 52 040 A1 described.
  • Important components of such a layer may be nanoscale silica particles or compounds from the group of oxides and hydroxides of the alkali and alkaline earth metals.
  • these layers also have a particular hardness which protects the surface even after a long period of operation, thereby increasing the service life of the compressor.
  • sol-gel technology Due to the mixture and reaction of various organic and inorganic materials, this results in a solution, which is also referred to as sol.
  • This solution solidifies into a gel when the charged solvent evaporates and a reaction with the moisture from the environment takes place. Subsequent heat treatment solidifies this gel into a solid with amorphous to crystalline states.
  • non-undercut surfaces particularly areas that are easily accessible
  • sol-gel technology it is difficult to provide a layer with the desired function for non-accessible surfaces, for example in compressor runner flow channels.
  • there are already sufficient difficulties on surfaces accessible from all sides to produce a uniform layer thickness it is almost impossible to access the poorly accessible areas.
  • the difficulties begin with the application of the coating material in a suitable layer thickness and continue with the evaporation of the solvent and the solidification of the gel while absorbing the ambient humidity, since not all locations are equally exposed to the environment.
  • a subsequent heat treatment at a non-optimal course of the preceding process steps leads to an unsatisfactory result, since even the different layer thicknesses lead to unacceptable errors, for example cracks in the surface.
  • the invention has the object to provide a method for coating compressor components, which enables high quality and by means of which in particular undercut or channel-like closed components can be provided with acceptable cost with a coating ,
  • the object of the invention provides that in a first step, a liquid coating material comprising nanoscale solids is applied to the compressor component, the compressor component is at least partially immersed in the coating material and rotated there about an axis, in a second step, the compressor component of the Coating material is removed and rotated about an axis, in a third step, the compressor component is exposed to a temperature of 50 ° C to 150 ° C and exposed in a fourth step, the compressor component for curing the coating under high vacuum at a temperature of up to 500 ° C. ,
  • An essential feature of the method according to the invention is the partial immersion and rotation of the compressor component to be coated in the coating material, which initially ensures that even in an undercut or channel-like component all surfaces are wetted with the coating material. In this way, the basis for a complete coating is created. Also very important is the rotation of the component outside of the coating material (1), which not only ensures even wetting, but also for a substantially constant layer thickness on the surfaces. At the same time, turning outside the coating material also ensures gas circulation, so even at less exposed surfaces on the one hand, the required evaporation of the solvent can be done and on the other hand enough moisture from the ambient air can give rise to the desired gel on the surface as a precursor to the coating. The final heat treatment can thus create a gapless and even layer.
  • the component to be coated has particularly acute-angled edges, it makes sense if these have been previously provided with the coating material, so that a sufficient layer thickness can be achieved as a result even at these locations.
  • This coating can be carried out, for example, by means of dipping, spraying, flooding, spin-coating, rolling, brushing or else by means of a combination of these methods. If necessary, it is also possible to coat specially stressed areas separately in this manner, for example, entry edges on a compressor impeller.
  • the component to be coated is immersed in the coating material with the radially outer regions prior to the first step.
  • 20 mm immersion depth for a good result are sufficient.
  • the compressor impeller rotating about the axis (4 revolutions per minute) is removed from the coating material and further rotated in the air for a certain time.
  • the coating result is further improved if, in the second step, the compressor component is subjected to a gas flow, in particular air flow, with continued rotation.
  • a gas flow in particular air flow
  • the air flow ensures a more uniform distribution of the liquid coating material and on the other hand takes place on the one hand a faster but also more uniform evaporation of the solvent of the coating material and it forms from the sol evenly and quickly the gel, absorbing the moisture of the flowing air. Even less exposed surfaces are flowing around this sufficiently.
  • a gas flow or air flow can also be applied; this procedure is advantageous in the case of very large compressor wheels in order to prevent the formation of drops and running noses.
  • the compressor component is advantageously immersed first 20 mm rotating in the coating material and after one to ten Repetitions are taken out of the coating material, rotating about the axis, and after a certain time immersed in the coating material with rotation about halfway through the diameter, with a gas flow being blown through the inside of the compressor component.
  • the compressor component is advantageously immersed first 20 mm rotating in the coating material and after one to ten Repetitions are taken out of the coating material, rotating about the axis, and after a certain time immersed in the coating material with rotation about halfway through the diameter, with a gas flow being blown through the inside of the compressor component.
  • Experience has shown that between the two dips should be about one to three minutes, during which the compressor component outside of the coating material and can be rotated by the air, which prevents dripping and runny nose on the coating.
  • This procedure according to the invention allows for the first time a high-quality coating of a closed compressor impeller.
  • this drying process can be carried out by exposing the compressor component to a temperature of 50 ° C. for 15 minutes, a temperature of 75 ° C. for 15 minutes and a temperature of 100 ° C. for 60 minutes before the cooling of the workpiece is initiated. This gentle gradual temperature curve ensures a stress-free and therefore crack-free coating.
  • the final heat treatment to cure the coating takes place between 300 and 500 ° C in a nitrogen atmosphere, in a partial vacuum or in a high vacuum (up to 10-5 mbar).
  • a heating rate of 100 ° C / h is not exceeded and to keep the selected heat treatment temperature for 1 hour.
  • a heat treatment in a high vacuum for one hour at 500 ° C the coating has a low surface energy at the same time high hardness.
  • the input of the first step S1 is a coating material (1) for coating a compressor component 3 which is designed as a compressor impeller 2 consisting of a maximum of 70% by weight of ethanol, 29% by weight of etoxysilane containing alkyl groups, 7% by weight of tetraethyl silicate and its condensates and 2.5% by weight.
  • % Sodium hydroxide diluted with an addition of 2-popanol is diluted to 28% by volume by adding 72% by volume of 2-propanol.
  • the compressor impeller 2 is coated with the coating material 1 at particularly stressed points, in particular at acute-angled edges, for example at the entry edges, by means of a brush 4 in method step S1.2.
  • the application of the coating material 1 is repeated several times, about 2 to 5 times, with between the individual jobs a three-minute air drying of the coating material 1 takes place on the compressor impeller 2.
  • a step 1.3 the compressor impeller 2 is immersed with the radially outer region about 20 mm deep in the coating material 1 and rotated at a frequency of four revolutions per minute for about 45 seconds. In this way, the coating material 1 is thinly distributed only to the 20 mm deep immersed, difficult to coat surfaces and acute-angled edges.
  • the process step S1.4 is initiated. The rotation prevents noses or dripping.
  • step S1.4 the compressor impeller 2 is first connected to a flow guide 5, which allows a flow of the compressor impeller 2 with an air flow VAIR. Subsequently, the compressor impeller 2 is immersed in the solution of the coating material 1 until it is arranged approximately to the radial half in the solution.
  • the air flow VAIR is switched on and permanently flows through the flow channels of the compressor impeller 2. With an angular speed of 4 revolutions per minute, the compressor impeller 2 is rotated through the coating material 1 for about 30 seconds. Under uniform rotational movement, the compressor impeller 2 is now lifted out of the coating material 1 at a speed v, so that after about 30 seconds - ie 2 revolutions - the compressor impeller 2 is no longer in the coating material 1
  • the compressor impeller 2 is immersed under rotation in the solution of the coating material 1 until it is arranged approximately to the radial half in the solution.
  • the air flow VAIR through the flow channels of the compressor wheel 2 takes place here permanently.
  • the compressor impeller 2 With a Angular speed of 4 revolutions per minute, the compressor impeller 2 is now lifted at a speed v from the coating material 1, so that after about 30 seconds - ie two revolutions - the compressor impeller 2 is no longer in the coating material 1.
  • step S2 the compressor impeller 2 is continued at an angular speed of 4 revolutions per minute and subjected to the air flow VAIR. dried for up to 3 minutes.
  • a stepwise heat treatment wherein the compressor impeller 2 15 minutes exposed to a temperature of 50 ° C, 15 minutes at a temperature of 75 ° C and 60 minutes at a temperature of 100 ° C in a drying oven, not shown is.
  • the compressor impeller 2 can be subjected to a final heat treatment under high vacuum and optionally subjected to further processing steps.
  • a fourth step S4 it makes sense for the compressor component 3 to be exposed to a temperature of up to 500 ° C. under high vacuum for curing the coating.
  • a precoating according to the method step denoted by S1.2 in step S1 of the method is expedient in particular in the region of the inlet 10, namely at the blade inlet edges 14 and in the region of the hub 12.
  • precoating according to the method step denoted by S1.3 in step S1 of the method in the region of the outlet is expedient.
  • Figure 2 shows the compressor impeller 2 with an axial inlet 10 and a radial outlet 11.
  • the axis for rotating the compressor impeller 2 is temporarily inserted in the region of a hub 12 according to the structural arrangement of the axis of rotation in normal operation.
  • Important is a coating in the region of the hub 12 and in the interior, ie on the surfaces of the flow channels 13, which extend from the inlet 10 to the outlet 11.
  • the outer surfaces 14 need not be coated because deposition is neither likely nor interferes with operation.
  • FIG. 3 shows a structure 20 which can be used to carry out the method according to the invention.
  • a lift 30 On a lift 30 is an upwardly open container 31 with the coating material 1 as a solution.
  • the compressor impeller 2 immersed in the solution of the coating material 1 and is rotatably mounted on an axis 33.
  • a flow guide 5, which is embodied here as a plastic hood 6, is connected to the inlet 10 of the compressor impeller 2 and guides the air flow VAIR originating from a fan 34 into the component to be coated.
  • the air flow VAIR exits from the openings of the radial outlet 11 again.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
EP06000849A 2006-01-16 2006-01-16 Méthode pour rêvetir un compresseur Withdrawn EP1808511A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP06000849A EP1808511A1 (fr) 2006-01-16 2006-01-16 Méthode pour rêvetir un compresseur
PCT/EP2007/050070 WO2007082794A1 (fr) 2006-01-16 2007-01-04 Procédé pour appliquer un revêtement de surface sur un composant de compresseur

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06000849A EP1808511A1 (fr) 2006-01-16 2006-01-16 Méthode pour rêvetir un compresseur

Publications (1)

Publication Number Publication Date
EP1808511A1 true EP1808511A1 (fr) 2007-07-18

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EP06000849A Withdrawn EP1808511A1 (fr) 2006-01-16 2006-01-16 Méthode pour rêvetir un compresseur

Country Status (2)

Country Link
EP (1) EP1808511A1 (fr)
WO (1) WO2007082794A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010089201A1 (fr) 2009-02-05 2010-08-12 Siemens Aktiengesellschaft Procédé de réalisation d'une roue à aubes de compresseur fermée
FR3046812A1 (fr) * 2016-01-20 2017-07-21 Turbomeca Roue de compresseur centrifuge ou mixte et etage de compression equipe d'une telle roue de compresseur
DE102021113999A1 (de) 2021-05-31 2022-12-01 MTU Aero Engines AG Verfahren zum beschichten eines bauteils einer strömungsmaschine

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5585136A (en) * 1995-03-22 1996-12-17 Queen's University At Kingston Method for producing thick ceramic films by a sol gel coating process
DE19714949A1 (de) * 1997-04-10 1998-10-15 Inst Neue Mat Gemein Gmbh Verfahren zum Versehen einer metallischen Oberfläche mit einer glasartigen Schicht
US6284682B1 (en) * 1999-08-26 2001-09-04 The University Of British Columbia Process for making chemically bonded sol-gel ceramics
DE10163646A1 (de) * 2001-12-21 2003-07-03 Hermsdorfer Inst Tech Keramik Oberflächenmodifizierter Werkstoffverbund und Verfahren zu seiner Herstellung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5585136A (en) * 1995-03-22 1996-12-17 Queen's University At Kingston Method for producing thick ceramic films by a sol gel coating process
DE19714949A1 (de) * 1997-04-10 1998-10-15 Inst Neue Mat Gemein Gmbh Verfahren zum Versehen einer metallischen Oberfläche mit einer glasartigen Schicht
US6284682B1 (en) * 1999-08-26 2001-09-04 The University Of British Columbia Process for making chemically bonded sol-gel ceramics
DE10163646A1 (de) * 2001-12-21 2003-07-03 Hermsdorfer Inst Tech Keramik Oberflächenmodifizierter Werkstoffverbund und Verfahren zu seiner Herstellung

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010089201A1 (fr) 2009-02-05 2010-08-12 Siemens Aktiengesellschaft Procédé de réalisation d'une roue à aubes de compresseur fermée
DE102009007648A1 (de) 2009-02-05 2010-08-19 Siemens Aktiengesellschaft Verfahren zur Herstellung eines geschlossenen Verdichterlaufrades
FR3046812A1 (fr) * 2016-01-20 2017-07-21 Turbomeca Roue de compresseur centrifuge ou mixte et etage de compression equipe d'une telle roue de compresseur
WO2017125662A1 (fr) * 2016-01-20 2017-07-27 Safran Helicopter Engines Roue de compresseur centrifuge ou mixte et étage de compression équipé d'une telle roue de compresseur
DE102021113999A1 (de) 2021-05-31 2022-12-01 MTU Aero Engines AG Verfahren zum beschichten eines bauteils einer strömungsmaschine
US20220380931A1 (en) * 2021-05-31 2022-12-01 MTU Aero Engines AG Method for coating a component of a turbomachine
EP4098766A1 (fr) * 2021-05-31 2022-12-07 MTU Aero Engines AG Procédé de revêtement d'un composant d'une turbomachine
US11939694B2 (en) * 2021-05-31 2024-03-26 MTU Aero Engines AG Method for coating a component of a turbomachine

Also Published As

Publication number Publication date
WO2007082794A1 (fr) 2007-07-26

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