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EP1701774A1 - Appareil de traitement d'eau autonettoyant ameliore - Google Patents

Appareil de traitement d'eau autonettoyant ameliore

Info

Publication number
EP1701774A1
EP1701774A1 EP04812500A EP04812500A EP1701774A1 EP 1701774 A1 EP1701774 A1 EP 1701774A1 EP 04812500 A EP04812500 A EP 04812500A EP 04812500 A EP04812500 A EP 04812500A EP 1701774 A1 EP1701774 A1 EP 1701774A1
Authority
EP
European Patent Office
Prior art keywords
water
steam
boiler
gases
degasser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04812500A
Other languages
German (de)
English (en)
Other versions
EP1701774A4 (fr
Inventor
Douglas M. Thom
Gary W. Lum
Joseph A. Urban
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sylvan Source Inc
Original Assignee
Sylvan Source Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sylvan Source Inc filed Critical Sylvan Source Inc
Publication of EP1701774A1 publication Critical patent/EP1701774A1/fr
Publication of EP1701774A4 publication Critical patent/EP1701774A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/0005—Degasification of liquids with one or more auxiliary substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • B01D1/30—Accessories for evaporators ; Constructional details thereof
    • B01D1/305—Demister (vapour-liquid separation)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/0042—Degasification of liquids modifying the liquid flow
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/045—Treatment of water, waste water, or sewage by heating by distillation or evaporation for obtaining ultra-pure water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/02—Odour removal or prevention of malodour

Definitions

  • This invention pertains to the distillation of water and other liquids and, more specifically, to a distillation system and method utilizing initial degassing of the liquid, evaporation by boiling, selective separation of steam and vapor, and product condensation.
  • Water purification technology is rapidly becoming an essential aspect of modern life as conventional water resources become increasingly scarce; as municipal distribution systems for potable water deteriorate with age; as increased water usage depletes wells and reservoirs, causing saline water contamination; and as further contamination occurs in conventional resources from intensive agriculture, from gasoline additives, and even from heavy toxic metals, leading to increasing and objectionable levels of germs and bacteria, salts, MTBE, chlorates and perchlorates, arsenic, mercury, and chemicals used to disinfect potable water, such as chlorinated compounds.
  • RO reverse osmosis
  • filtration and chemical treatment rarely are able to handle the diverse range of water contaminants, and even though they are commercially available, they often require multiple treatment stages or combination of various technologies to achieve acceptable water quality.
  • UV light irradiation or ozone treatment can be effective against viruses and bacteria, but seldom remove other contaminants, such as dissolved gases, many salts, hydrocarbons, and insoluble solids.
  • distillation technologies which are generally superior at removing multiple contaminants, and unless they include selective steam separation systems, are still unable to handle all types of contaminants.
  • U.S. Patents 6,689,251 6,423,187; 6,663,770; 5,968,321 ; 6,506,284: 6,428,656; 6,406,597; 6,294,054; 6, 13,744; 5,729,987; 5,484,510; 5,587,055; 5,536,375; 5,522,970; 5,435,891; 5,232,085; and 4,938,868.
  • U.S. Patent 6,689,251 describes a distiller with a heat exchanger that allows for the periodic bleeding of boiler water as the impurity concentration in that water increases. However, there is no provision for separating the steam produced in the boiler into clean and impure fractions.
  • U.S. Patent 6,423,187 describes a distiller system that operates on the principle of thin-film evaporation by means of capillary action wicks.
  • U.S. Patent 6,663,770 describes a self-cleaning distillation system comprising a degasser, boiler, and steam separation system.
  • that invention includes a float valve to control the water level in the boiler, with the attendant abrasion and mechanical stability problems associated with such systems at boiling temperatures. It also describes a shaft that operates a mechanical wiper for cleaning the boiler, which introduces potential leak and maintenance problems.
  • Patent 5,968,321 describes a similar distillation system that relies on a heat exchanger and a compressor to recover part of the heat of condensation, and controls the level of water in the boiler by means of a side glass tube connected to a photo-sensing device.
  • U.S. Patents such as 6,436,242; 6,506,284; 6,294,054; that utilize vacuum distillation as a means of reducing the energy requirements due to evaporation. While vacuum distillation effectively allows boiling at less that 100°C, it is prone to leaks, and such leaks become increasingly likely the larger the distillation unit becomes.
  • U.S. Patents 6,365,005 Another common deficiency of vacuum distillation systems is that they usually require a vapor compression stage, and compressors suffer from high maintenance costs and, unless they are especially sealed, can introduce lubricant contamination into the water product.
  • vapor compression distillers such as U.S. Patents 6,365,005; also suffer from similar reliability and contamination problems.
  • U.S. Patent 6,428,656 describes a screen above the boiling level of the boiler as a means of capturing the salt-containing mist droplet.
  • Metallic or hydrophilic screens can capture liquid droplets, but the efficiency of capture is a function of droplet size, and unless the screen apertures are microscopic (which in turn cause a significant pressure drop across the screen), they can allow passage of small mist droplets.
  • U.S. Patent 6,406,597 describes a distiller with a degasser and a demister.
  • the demister consists of a flexible tube. Collecting impure mist droplets in a tube is generally a stochastic process that is seldom 100% efficient, and depending of the chemical composition of the polymer tube, impurities can leach into the steam that eventually becomes product water.
  • U.S. Patent 6,113,744 describes a degasser where raw water is introduced between the top and the bottom of a tubular member, with steam exit at the top of the unit and degassed water at the bottom. Such configuration achieves degassing only of the most volatile components in the water stream and is less efficient that the present invention, particularly when volatile components like MTBE and chlorine are both present in the raw water.
  • U.S. Patent 5,729,987 describes a distillation apparatus for use with salt water and is based on an array of steam separator ducts that prevent mixing of salt water with desalinized water, and using an ammonia refrigerant for heat exchange.
  • U.S. Patents 5,484,510 and 5,587,055 describe a distillation system that separates clean from impure steam by means of a pump actuated by an electric conductivity probe. However, conductivity measurements in the gas phase are effective only if the steam is homogeneous, which is not the case when mist containing micro-droplets of liquid are present.
  • U.S. Patent 5,536,375 describes a vacuum distillation system that utilizes a mechanical baffle to separate mist droplets from steam. However, in addition to the aforementioned problems of vacuum distillation, a baffle is only effective at capturing droplets above a certain size; smaller droplets have significantly lower inertia and will continue to be entrained by the flow of steam.
  • U.S. Patent 5,522,970 describes a distillation system based on a polytetrafluoroethylene tube that is permeable to water steam but impermeable to saline water.
  • U.S. Patent 5,435,891 describes a distillation system that eliminates gases fe>y heating, but there is no provision for separating clean from impure steam.
  • U.S. Patent 5,232,085 describes a distillation system that includes a degasser, a high-pressure boiling chamber, and a hydrophobic membrane to separate the steam from mist droplets.
  • a membrane separator is effective only if the mist droplets are within a certain size; smaller droplets can be carried through by the steam flow because of their low inertia.
  • U.S. Patent 4,938,868 describes a vacuum distillation system that utilizes a circular mist collector to separate mist droplets from clean steam.
  • the patent recognizes that only large mist particles can be collected.
  • the objective of the present invention is to provide a continuous, fully automated water distillation system that removes gases, solids, salts, hydrocarbons, and micro-organisms from water.
  • An improved, self-cleaning water processing apparatus comprises three sequential functions that eliminate multiple contaminants from drinking water. First, dissolved gases, such as odors and most hydrocarbons, are eliminated by means of a degasser. Next, a special design boiler produces steam that may carry micro-particles of solids or salt-containing mist. The mixture of clean arrd contaminated steam is then separated into pure and impure steam by means of a cyclone demister. The clean steam fraction is finally collected in a condenser which feeds a pure water product tank.
  • FIGURE 1 is top view of the boiler chamber 2, the degasser unit 4, and the cyclone demister 3.
  • FIGURE 2 is a side view of the distillation core, showing the degasser 4, the boiler chamber 2, and the cyclone demister 3.
  • FIGURE 3 is a detailed view of the cyclone demister 3, illustrating a preferred configuration of various elements, such as an incoming steam tube 11, a metallic steam guide 10 that directs the steam to rotate in a circular pattern, a mist collector tube 6 that directs impure steam and mist into a waste drain, and a clean steam collector tube 5 that carries the clean steam into a condenser un it.
  • various elements such as an incoming steam tube 11, a metallic steam guide 10 that directs the steam to rotate in a circular pattern, a mist collector tube 6 that directs impure steam and mist into a waste drain, and a clean steam collector tube 5 that carries the clean steam into a condenser un it.
  • FIGURE 4 is a detailed drawing of the degasser unit 4 as mounted above the boiler chamber 2 on the boiler top 1. It illustrates a preferred configuration for the incoming feed water tube 12, the positron of a coiled heat exchanger 8 inside the boiler chamber 2, the hot water tube 13 that feeds the top of the degasser unit 4, the mixing media 14 inside the degasser unit 4, the screen 15 that supports the mixing media 14, and tube 16 that carries contaminated steam and mist to a waste drain.
  • the distillation system comprises a boiler, a degassing unit, a demister for steam separation and a product condenser.
  • FIG. 1 and FIG. 2 are top and side views of the apparatus constructed in accordance with the invention.
  • the boiler top (1) is the primary structural element of the apparatus and mounted to it are the boiling chamber (2), the cyclone demister (3), and the degasser (4).
  • O-rrngs (not shown) form the seal between the borlrng chamber and boiler top; and between the cyclone demister and boiler top. All materials in the apparatus are selected to minimize corrosion of the apparatus or contamination of water being processed, such as titanium or stainless steel.
  • the boiler chamber 2 is attached to the boiler top 1 by a series of peripheral bolts and an O-ring that is placed outside the line of bolts, so as effect a compression seal, thus minimizing any contact between the steam and the Q-ring.
  • the design of the cyclone demister 3 improves prior art by combining and integrating the cyclone chamber, steam nozzle, and demister seal gland into a single component which may be fabricated by molding, casting, or stamping a variety of corrosion resistant materials.
  • the body of the cyclone demister is made from either titanium or stainless steel, although other temperature and corrosion resistant materials may also be used.
  • the cyclone demister is basically a modified cyclone. Steam from the boiler chamber enters the cyclone demister through tube 11. Upon entering the cyclone chamber, steam from the boiler encounters a metal guide 10 that forces the steam into a circular motion. The circular motion of steam in the cyclone causes mist particles, which are heavier than dry or clean steam to concentrate on the periphery of the cyclone chamber due to centrifugal forces, while clean steam, being lighter, follows a circular motion closer to the center of the cyclone chamber.
  • the cyclone demister has no moving parts, and effects a selective separation of clean steam from impure mist particles purely as a result of differential centrifugal forces.
  • the concentrated mist stream also called “blow-down”
  • This waste steam subsequently joins the gray water stream and goes to a drain.
  • Dry or clean steam exits from the center top of the cyclone demister through tube 5 and goes to a condenser uni
  • the boiling chamber 2 design makes improvement over prior art by employing high volume metal forming technology to minimize the number of seams, seals, and piece parts which significantly improves manufacturing cost and reliability of the device.
  • the heating element 10 which is permanently and intimately attached provides heat in a confined area of the boiling chamber bottom.
  • the nature of boiling water causes (sediment) or scale to form on or near surfaces where the boiling process takes place. Glass or ceramic balls 7 within the boiler are agitated by the boiling water and prevent the scale from being deposited on the surface of the boiling chamber keeping the particles suspended in the water during normal operation.
  • a sediment drain 9 opens automatically purging the boiling chamber of nearly all the water and suspended scale. This process significantly reduces the long-term build up of scale which improves the heating efficiency of the boiler and reduces the need for boiler cleaning.
  • the water level and the steam pressure in the boiling chamber are automatically regulated by means of a differential pressure switch that turns the inlet water valve off when the level of water in the boiler is full.
  • incoming feed water enters the boiler chamber through tube 12 and is preheated inside the boiling chamber within a heat exchanger 8 which is suspended from the boiler top 1.
  • the feed water reaches temperature equilibrium with the boiling chamber and exits through tube 13, which carries the hot water into the top of the degasser 4.
  • This preheating process is key to bring feed water temperatures near the boiling point before it enters the degasser.
  • volatile gases and organic compounds with a low vapor pressure lose the ability to remain in solution at temperatures close to the boiling point of water, and evolve as gases.
  • the Degasser 4 consists of a vertical tube with preheated water entering the top through tube 13 and steam from the boiler chamber 2 entering the bottom and exiting at the top through tube 16.
  • the vertical degasser tube 4 can contain a variety of materials 14 which cause a mixing of the water and steam stripping off unwanted gases in the water as it moves slowly down the degasser by gravitational force.
  • the materials that can be used for this mixing include glass balls, ceramic balls, screen discs, spiral screen, or metal chards.
  • a metal screen 15 that is resistant to corrosion is placed between the degasser tube 4 and the boiler top 1, and prevents the mixing media 14, which in a preferred embodiment consist of glass spheres, from falling into the boiling chamber.
  • An important aspect of the present invention concerns the size of the glass spheres, which must have sufficient surface area to provide for effective stripping of volatile components in the short time it takes for the incoming feed water to traverse the length of the degasser tube.
  • Horizontal configurations of degassers in the prior art normally are not effective for this reason and are, thus, unable to completely strip volatile substances from contaminated water.
  • Ultrasonic atomizatron of water may also be used to enhance the steam and water mixing.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Separating Particles In Gases By Inertia (AREA)
  • Physical Water Treatments (AREA)

Abstract

L'invention concerne un système de purification d'eau autonettoyant amélioré reposant sur la distillation. Ledit module comprend une chambre de chaudière (2), un dégazeur (4), et un dévésiculeur de type cyclone (3). Les améliorations portent sur la fabrication et la production à grand débit, sur le désassemblage simple en vue de l'inspection, de la réparation et du service, ainsi que sur une construction solide visant à résister aux vibrations et aux chocs mécaniques.
EP04812500A 2003-12-02 2004-12-01 Appareil de traitement d'eau autonettoyant ameliore Withdrawn EP1701774A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US52658003P 2003-12-02 2003-12-02
PCT/US2004/039993 WO2005056153A1 (fr) 2003-12-02 2004-12-01 Appareil de traitement d'eau autonettoyant ameliore

Publications (2)

Publication Number Publication Date
EP1701774A1 true EP1701774A1 (fr) 2006-09-20
EP1701774A4 EP1701774A4 (fr) 2007-07-04

Family

ID=34676632

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04812500A Withdrawn EP1701774A4 (fr) 2003-12-02 2004-12-01 Appareil de traitement d'eau autonettoyant ameliore

Country Status (4)

Country Link
EP (1) EP1701774A4 (fr)
JP (1) JP2007513752A (fr)
CA (1) CA2553651A1 (fr)
WO (1) WO2005056153A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7678235B2 (en) 2005-10-19 2010-03-16 Sylvan Source, Inc. Water purification system
WO2007103117A2 (fr) 2006-03-03 2007-09-13 Sylvan Source, Inc. Prevention contre les contaminants
JP5778031B2 (ja) 2008-09-17 2015-09-16 シルバン ソース、 インク． 大規模な浄水および脱塩
JP2012523316A (ja) * 2009-04-10 2012-10-04 シルバン ソース， インコーポレイテッド 水溶液の浄化におけるスケーリングを減らす方法およびシステム
WO2013036804A1 (fr) 2011-09-09 2013-03-14 Sylvan Source, Inc. Purification et dessalement des eaux industrielles
CN106629939A (zh) * 2016-11-04 2017-05-10 榆林学院 一种双级蒸馏苦咸水脱盐装置
CN115823568B (zh) * 2023-02-10 2023-05-12 威海市泓阳检测工程有限公司 一种锅炉外壁清理机器

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925176A (en) * 1973-10-10 1975-12-09 Adolph P Okert Apparatus and method for electrolytic sewage treatment
US4089662A (en) * 1977-06-22 1978-05-16 Allen Filters, Inc. Oil treatment system
GB2022428B (en) * 1978-06-02 1982-10-20 Nazareth Hospital Emms Water distilling apparatus
US4938868A (en) 1988-05-02 1990-07-03 Nelson Thomas R Method of distilling under partial vacuum
JP2665377B2 (ja) * 1989-05-26 1997-10-22 オルガノアクア株式会社 高純度蒸溜水製造装置
JP3107215B2 (ja) 1990-08-01 2000-11-06 株式会社日立製作所 蒸留装置
US5441606A (en) * 1992-03-23 1995-08-15 Fsr Patented Technologies, Ltd. Liquid purifying and vacuum distillation process
US5472622A (en) * 1993-04-20 1995-12-05 Ionics, Incorporated Salt basket for crystallizer and method of use in zero liquid discharge industrial facilities
US5435891A (en) 1993-06-01 1995-07-25 Snitchler; William H. Home water distillation apparatus
AU7870094A (en) 1993-09-10 1995-03-27 Emerson Electric Co. Water purifier having a demister
US5484510A (en) 1993-10-26 1996-01-16 Dew Enterprises, Inc. Water distilling apparatus
US5587055A (en) 1993-10-26 1996-12-24 Michael O. Hartman Water distilling apparatus and method
JPH07155561A (ja) 1993-12-07 1995-06-20 Shimizu Corp 造水チューブ
CA2167127A1 (fr) 1996-01-12 1997-07-13 James Munro Appareil de distillation de l'eau
US5968321A (en) 1996-02-13 1999-10-19 Ridgewood Waterpure Corporation Vapor compression distillation system and method
US5729987A (en) 1996-02-27 1998-03-24 Miller; Joel V. Desalinization method and apparatus
JPH09257234A (ja) * 1996-03-19 1997-09-30 Ebara Corp 廃棄物のボイラへの供給方法
US6365005B1 (en) 1997-01-27 2002-04-02 James W. Schleiffarth Apparatus and method for vapor compression distillation
JPH11244843A (ja) * 1998-03-05 1999-09-14 Hitachi Zosen Corp 蒸気圧縮式純水製造装置
US6423187B1 (en) 1998-12-11 2002-07-23 Ovation Products Corporation Heat exchanger mechanism using capillary wipers for a thin film distiller
US6406597B1 (en) 1998-12-29 2002-06-18 Chi-Hsiang Wang Water distilling device
US6294054B1 (en) 1999-02-02 2001-09-25 Douglas E. Sutter Water purification system
AU3235300A (en) 1999-02-18 2000-09-04 Psi-Ets Water-cooled distilling apparatus
JP3434238B2 (ja) 1999-06-23 2003-08-04 哲夫 宮坂 減圧蒸留装置
US6435891B1 (en) 1999-10-28 2002-08-20 Tyco Electronics Corporation Mechanically assisted blind mate electrical connector
US6436242B1 (en) 2000-02-10 2002-08-20 Pedro Joaquin Sanchez Belmar Device and method for distilling water
AU2695902A (en) 2000-11-17 2002-05-27 Stephan B Sears Water processing device
US6689251B2 (en) 2001-01-18 2004-02-10 Ovation Products Corporation Cycled-concentration distiller
ATE312151T1 (de) * 2001-05-14 2005-12-15 Smet Engineering N V De Vorrichtung und verfahren zur physikalischen raffinierung und/oder deodorisierung von essbaren ölen und fetten

Also Published As

Publication number Publication date
EP1701774A4 (fr) 2007-07-04
WO2005056153A1 (fr) 2005-06-23
JP2007513752A (ja) 2007-05-31
CA2553651A1 (fr) 2005-06-23

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