EP1748088A1 - Alliage d'aluminium apte au formage à froid et à chaud du type Al-Mg-Mn - Google Patents
Alliage d'aluminium apte au formage à froid et à chaud du type Al-Mg-Mn Download PDFInfo
- Publication number
- EP1748088A1 EP1748088A1 EP05016538A EP05016538A EP1748088A1 EP 1748088 A1 EP1748088 A1 EP 1748088A1 EP 05016538 A EP05016538 A EP 05016538A EP 05016538 A EP05016538 A EP 05016538A EP 1748088 A1 EP1748088 A1 EP 1748088A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- hot
- aluminum alloy
- semifinished product
- semi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 47
- 230000001747 exhibiting effect Effects 0.000 title 1
- 239000011265 semifinished product Substances 0.000 claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 238000005266 casting Methods 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 11
- 238000000137 annealing Methods 0.000 claims abstract description 7
- 238000005097 cold rolling Methods 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract 2
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 229910052725 zinc Inorganic materials 0.000 claims abstract 2
- 229910045601 alloy Inorganic materials 0.000 claims description 18
- 239000000956 alloy Substances 0.000 claims description 18
- 238000009864 tensile test Methods 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 5
- 238000005275 alloying Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000007669 thermal treatment Methods 0.000 claims 1
- 239000011777 magnesium Substances 0.000 abstract description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 abstract description 5
- 238000005098 hot rolling Methods 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
Definitions
- the invention relates to an aluminum alloy for the production of semi-finished products or components for motor vehicles, a semifinished product or component made of an aluminum alloy and a method for producing an aluminum strip for semi-finished products or components for motor vehicles.
- components such as parts of the chassis or the body structure, made of aluminum materials are used increasingly for the production of motor vehicles.
- These are usually made of semi-finished products consisting of aluminum alloys based on an AlMgMn aluminum alloy with Mg contents of 2 to 3.5 wt .-%.
- This aluminum alloy ensures sufficiently high strength combined with good resistance to intergranular corrosion, especially in uncoated applications. Since in the manufacture of the chassis and / or structural components existing from said aluminum alloy semi-finished products are usually subjected to several forming steps, there is a desire to extend the forming limits of the semi-finished products, such as aluminum sheets, tubes or profiles.
- hot forming processes such as hot hydroforming, hydroforming with hot media, or deep drawing with heated tools, are increasingly being used in the forming operations.
- degree of deformation of the aluminum semi-finished products can be significantly increased when using hot forming processes.
- the anti-settling processes taking place in hot forming operations have the components or semi-finished products consisting of the AlMgMn aluminum alloys used today less strength than the cold-worked components used previously.
- the object of the present invention is to provide an aluminum alloy and a semifinished product or a component which, with good resistance to intergranular corrosion and recyclability, has sufficient strength even after hot working.
- the aluminum alloy according to the invention makes it possible to produce components which are not only resistant to intercrystalline corrosion but also have a higher strength after hot working compared with the aluminum alloys used hitherto. Moreover, since the aluminum alloy according to the invention contains only standard alloy components, it is very easy to recycle and can be introduced without problems into the scrap circuits of the automotive industry (Alt-Autover Aunt), as well as the semis manufacturer.
- a corresponding aluminum alloy leads to a further increase in the yield strength Rp0.2 at room temperature after hot deformation with constant resistance to intergranular corrosion, while the elongation at break values remain the same.
- the object indicated is achieved by a semifinished product or a component which consists at least partially of an aluminum alloy according to the invention.
- semifinished products or components consisting of the aluminum alloy according to the invention can be used particularly well for chassis and structural applications in motor vehicles, since they have an improved yield strength at room temperature, in particular after hot forming, with constant corrosion resistance.
- a component differs from the semifinished product in that the component has been subjected to further process steps in order to be used, for example, directly in the body of the motor vehicle.
- the semifinished product thus represents the starting product for the components.
- the possible uses of the semifinished product or component in structural applications in the motor vehicle sector can be increased by forming the semifinished product or component at room temperature or in a soft state at sheet thicknesses of at least 1 mm Yield point Rp0,2 of at least 135 MPa. Due to the high yield strength of the semifinished product or component according to the invention after forming at room temperature or in a soft state, measured according to DIN standard DIN EN 10 002, the necessary requirements for the yield strength Rp0.2 for use as a structural part by the semifinished product or component met in the vehicle.
- the suitability of the semifinished product or component for structural applications in the motor vehicle can be further improved in that the semifinished product of hot forming with a degree of deformation of at least 15% and at most 50% to 120% at a temperature of 200 to 350 ° C.
- the semifinished product has an elongation at break A 5 of at least 50% in the hot tensile test and that the semifinished product has a yield strength at room temperature Rp0.2 of at least 150 MPa.
- the elongation at break values A 5 in the hot tensile test were measured at the respective hot forming temperatures with a corresponding proportional rod.
- the yield strength Rp0.2 of the structural parts clearly exceeds the yield strength Rp0.2 from the known AlMgMn aluminum alloy with a Mn content of 2 to 3.5% by weight of produced structural parts after hot forming, without showing any sensitivity to intergranular corrosion.
- a semifinished product or component which is further improved with regard to the yield strength at room temperature and the elongation at break can be made available by the semifinished product being subjected to hot forming with a degree of deformation of at least 15% and a maximum of 60%.
- 90% at a temperature of 250 to 350 ° C has been subjected while having an elongation at break A 5 of at least 60% in the hot tensile test and that the semi-finished product after hot working has a yield strength at room temperature of at least 165 Mpa.
- the hot tensile tests were carried out on proportional bars at the hot-forming temperatures mentioned.
- the area-related mass loss according to ASTM G 67 after a heat treatment of 17 hours at 130 ° C. is a maximum of 5 mg / cm 2 .
- the semi-finished products according to the invention therefore have a particularly good resistance to intergranular corrosion and are particularly suitable for use as or for the production of chassis or structural parts in motor vehicles.
- the above-described object is achieved by a method for producing a strip for semi-finished products or components by casting a cast bar or a cast strip from an aluminum alloy according to the invention, hot-rolling the cast bar or, optionally, the cast strip, the hot-rolled strip Cold ingot or the casting belt are cold rolled and the cold rolled strip is fed to a final annealing. Due to the properties of the aluminum alloy according to the invention, it is ensured in the described production method that sheets produced from the strip, despite used hot forming processes, have an improved yield strength at room temperature with constant elongation at break values.
- Solidification introduced into the strip by hot rolling can be reduced by subjecting the strip to annealing prior to cold rolling.
- the cold rolled strip in this case has only the solidifications introduced by cold rolling into the strip.
- the solidifications introduced into the strip by the cold rolling are reduced again by at least one intermediate annealing during cold rolling. All of the aforementioned measures serve to increase the formability in the production of aluminum strip for semi-finished products, without the structural parts produced have too low a yield point.
- the aluminum alloy C according to the invention has almost identical elongation at break values as a function of the temperature in the hot tensile test in comparison with the conventional comparative alloys A and B.
- the comparative alloy A shows as expected, due to the high magnesium content of 4.5 wt .-%, the largest values for the yield strength after hot working.
- the value of the yield strength for the comparative alloy A is about 175 MPa at a hot working temperature of 350 ° C.
- Comparative alloy B has only reached a value of 140 MPa for the yield strength Rp0.2 at room temperature at the same hot forming temperature.
- the exemplary embodiment of the aluminum alloy according to the invention achieves values of significantly more than 150 MPa. Also in the other measured values, for example at 250 ° C., the values for the measured yield strength of the exemplary embodiment of the aluminum alloy according to the invention clearly exceed those of the comparative alloy B, but below the values for the comparative alloy A.
- the comparison alloy A is more susceptible to intercrystalline corrosion due to the higher MG content, so that it is not advantageous, especially in long-term use in chassis or structural application in the motor vehicle.
- the aluminum alloy of the present invention can provide an aluminum alloy which, despite improved yield strength after hot working, has good intergranular corrosion resistance and good elongation at break properties during hot working.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metal Rolling (AREA)
- Conductive Materials (AREA)
- Polyesters Or Polycarbonates (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PT05016538T PT1748088E (pt) | 2005-07-29 | 2005-07-29 | Método para a produção de um produto semi-acabado ou uma peça de construção de aplicações em mecanismo de translação ou estruturais em veículo motorizado |
| EP05016538A EP1748088B1 (fr) | 2005-07-29 | 2005-07-29 | Procédé de fabrication de produit semi-fini ou de composant pour des applications de châssis ou de structure automobiles |
| PL05016538T PL1748088T3 (pl) | 2005-07-29 | 2005-07-29 | Sposób wytwarzania półwyrobu lub elementu konstrukcyjnego do zastosowań w podwoziu lub strukturze pojazdu mechanicznego |
| AT05016538T ATE540132T1 (de) | 2005-07-29 | 2005-07-29 | Verfahren zur herstellung eines halbzeugs oder bauteils von fahrwerk- oder strukturanwendungen im kraftfahrzeug |
| ES05016538T ES2380343T3 (es) | 2005-07-29 | 2005-07-29 | Procedimiento para la producción de un producto semiacabado o una pieza de construcción en aplicaciones de chasis o de mecanismos estructurales en vehículo motorizado |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05016538A EP1748088B1 (fr) | 2005-07-29 | 2005-07-29 | Procédé de fabrication de produit semi-fini ou de composant pour des applications de châssis ou de structure automobiles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1748088A1 true EP1748088A1 (fr) | 2007-01-31 |
| EP1748088B1 EP1748088B1 (fr) | 2012-01-04 |
Family
ID=34982200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05016538A Revoked EP1748088B1 (fr) | 2005-07-29 | 2005-07-29 | Procédé de fabrication de produit semi-fini ou de composant pour des applications de châssis ou de structure automobiles |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1748088B1 (fr) |
| AT (1) | ATE540132T1 (fr) |
| ES (1) | ES2380343T3 (fr) |
| PL (1) | PL1748088T3 (fr) |
| PT (1) | PT1748088E (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2415895A1 (fr) * | 2010-08-02 | 2012-02-08 | Benteler Automobiltechnik GmbH | Pièce de formage en tôle pour véhicule automobile |
| CN105463270A (zh) * | 2016-01-06 | 2016-04-06 | 熊超 | 一种可氧化着色的压铸铝合金 |
| CN105543741A (zh) * | 2015-12-17 | 2016-05-04 | 西南铝业(集团)有限责任公司 | 一种铝合金的中间退火工艺及汽车覆盖件用铝合金 |
| WO2016196921A1 (fr) * | 2015-06-05 | 2016-12-08 | Novelis Inc. | Alliages d'aluminium 5xxx et leurs procédés de production |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05311308A (ja) * | 1992-05-01 | 1993-11-22 | Kobe Steel Ltd | 負圧缶ステイオンタブ式エンド用Al合金板及びその製造方法 |
| JPH07316711A (ja) * | 1994-05-30 | 1995-12-05 | Sumitomo Light Metal Ind Ltd | 曲げ加工性に優れた成形加工用アルミニウム合金板材およびその製造方法 |
| JPH09287045A (ja) * | 1996-04-18 | 1997-11-04 | Toyo Kohan Co Ltd | 絞りしごき缶用樹脂被覆アルミニウム合金板 |
| JPH1053847A (ja) * | 1996-04-10 | 1998-02-24 | Toyo Kohan Co Ltd | 絞りしごき缶用樹脂被覆アルミニウム合金板の製造方法 |
| JPH1081947A (ja) * | 1996-04-10 | 1998-03-31 | Toyo Kohan Co Ltd | 絞りしごき缶用樹脂被覆アルミニウム合金板の製造方法 |
| JP2000008133A (ja) * | 1998-06-23 | 2000-01-11 | Furukawa Electric Co Ltd:The | 耐落下強度に優れる缶蓋用アルミニウム合金板およびその製造方法 |
| JP2000144297A (ja) * | 1998-11-06 | 2000-05-26 | Furukawa Electric Co Ltd:The | 低温での靭性に優れるアルミニウム合金溶接継手とこれを使用した構造材料 |
| FR2851579A1 (fr) * | 2003-02-26 | 2004-08-27 | Pechiney Rhenalu | PROCEDE D'EMBOUTISSAGE A TIEDE DE PIECES EN ALLIAGE A1-Mg |
| EP1508627A1 (fr) * | 2002-05-30 | 2005-02-23 | Honda Giken Kogyo Kabushiki Kaisha | Piece coulee sous pression presentant une resistance elevee |
-
2005
- 2005-07-29 PL PL05016538T patent/PL1748088T3/pl unknown
- 2005-07-29 ES ES05016538T patent/ES2380343T3/es not_active Expired - Lifetime
- 2005-07-29 PT PT05016538T patent/PT1748088E/pt unknown
- 2005-07-29 AT AT05016538T patent/ATE540132T1/de active
- 2005-07-29 EP EP05016538A patent/EP1748088B1/fr not_active Revoked
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05311308A (ja) * | 1992-05-01 | 1993-11-22 | Kobe Steel Ltd | 負圧缶ステイオンタブ式エンド用Al合金板及びその製造方法 |
| JPH07316711A (ja) * | 1994-05-30 | 1995-12-05 | Sumitomo Light Metal Ind Ltd | 曲げ加工性に優れた成形加工用アルミニウム合金板材およびその製造方法 |
| JPH1053847A (ja) * | 1996-04-10 | 1998-02-24 | Toyo Kohan Co Ltd | 絞りしごき缶用樹脂被覆アルミニウム合金板の製造方法 |
| JPH1081947A (ja) * | 1996-04-10 | 1998-03-31 | Toyo Kohan Co Ltd | 絞りしごき缶用樹脂被覆アルミニウム合金板の製造方法 |
| JPH09287045A (ja) * | 1996-04-18 | 1997-11-04 | Toyo Kohan Co Ltd | 絞りしごき缶用樹脂被覆アルミニウム合金板 |
| JP2000008133A (ja) * | 1998-06-23 | 2000-01-11 | Furukawa Electric Co Ltd:The | 耐落下強度に優れる缶蓋用アルミニウム合金板およびその製造方法 |
| JP2000144297A (ja) * | 1998-11-06 | 2000-05-26 | Furukawa Electric Co Ltd:The | 低温での靭性に優れるアルミニウム合金溶接継手とこれを使用した構造材料 |
| EP1508627A1 (fr) * | 2002-05-30 | 2005-02-23 | Honda Giken Kogyo Kabushiki Kaisha | Piece coulee sous pression presentant une resistance elevee |
| FR2851579A1 (fr) * | 2003-02-26 | 2004-08-27 | Pechiney Rhenalu | PROCEDE D'EMBOUTISSAGE A TIEDE DE PIECES EN ALLIAGE A1-Mg |
Non-Patent Citations (7)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 018, no. 128 (C - 1174) 2 March 1994 (1994-03-02) * |
| PATENT ABSTRACTS OF JAPAN vol. 1996, no. 04 30 April 1996 (1996-04-30) * |
| PATENT ABSTRACTS OF JAPAN vol. 1998, no. 03 27 February 1998 (1998-02-27) * |
| PATENT ABSTRACTS OF JAPAN vol. 1998, no. 06 30 April 1998 (1998-04-30) * |
| PATENT ABSTRACTS OF JAPAN vol. 1998, no. 08 30 June 1998 (1998-06-30) * |
| PATENT ABSTRACTS OF JAPAN vol. 2000, no. 04 31 August 2000 (2000-08-31) * |
| PATENT ABSTRACTS OF JAPAN vol. 2000, no. 08 6 October 2000 (2000-10-06) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2415895A1 (fr) * | 2010-08-02 | 2012-02-08 | Benteler Automobiltechnik GmbH | Pièce de formage en tôle pour véhicule automobile |
| US10029624B2 (en) | 2010-08-02 | 2018-07-24 | Benteler Automobiltechnik Gmbh | Sheet metal molding for motor vehicles and process for producing a sheet metal molding for motor vehicles |
| WO2016196921A1 (fr) * | 2015-06-05 | 2016-12-08 | Novelis Inc. | Alliages d'aluminium 5xxx et leurs procédés de production |
| CN105543741A (zh) * | 2015-12-17 | 2016-05-04 | 西南铝业(集团)有限责任公司 | 一种铝合金的中间退火工艺及汽车覆盖件用铝合金 |
| CN105463270A (zh) * | 2016-01-06 | 2016-04-06 | 熊超 | 一种可氧化着色的压铸铝合金 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2380343T3 (es) | 2012-05-10 |
| ATE540132T1 (de) | 2012-01-15 |
| EP1748088B1 (fr) | 2012-01-04 |
| PL1748088T3 (pl) | 2012-05-31 |
| PT1748088E (pt) | 2012-04-12 |
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