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EP1637632A1 - Dispositif pour la production de filaments en matériau thermoplastique - Google Patents

Dispositif pour la production de filaments en matériau thermoplastique Download PDF

Info

Publication number
EP1637632A1
EP1637632A1 EP04022248A EP04022248A EP1637632A1 EP 1637632 A1 EP1637632 A1 EP 1637632A1 EP 04022248 A EP04022248 A EP 04022248A EP 04022248 A EP04022248 A EP 04022248A EP 1637632 A1 EP1637632 A1 EP 1637632A1
Authority
EP
European Patent Office
Prior art keywords
blowing air
filaments
secondary blowing
sides
nozzle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04022248A
Other languages
German (de)
English (en)
Other versions
EP1637632B1 (fr
Inventor
Detlef Frey
Hans Georg Geus
Michael Latinski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reifenhaeuser GmbH and Co KG Maschinenenfabrik
Original Assignee
Reifenhaeuser GmbH and Co KG Maschinenenfabrik
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reifenhaeuser GmbH and Co KG Maschinenenfabrik filed Critical Reifenhaeuser GmbH and Co KG Maschinenenfabrik
Priority to DE502004004519T priority Critical patent/DE502004004519D1/de
Priority to EP04022248A priority patent/EP1637632B1/fr
Priority to AT04022248T priority patent/ATE368759T1/de
Priority to DK04022248T priority patent/DK1637632T3/da
Priority to ES04022248T priority patent/ES2287619T3/es
Priority to MXPA05009748A priority patent/MXPA05009748A/es
Priority to KR1020050085835A priority patent/KR100783450B1/ko
Priority to US11/226,231 priority patent/US20060061006A1/en
Priority to CN2005101040755A priority patent/CN1757800B/zh
Priority to JP2005269633A priority patent/JP2006083511A/ja
Priority to BRPI0504077-9A priority patent/BRPI0504077B1/pt
Publication of EP1637632A1 publication Critical patent/EP1637632A1/fr
Application granted granted Critical
Publication of EP1637632B1 publication Critical patent/EP1637632B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00Spinnerette packs; Cleaning thereof
    • D01D4/02Spinnerettes
    • D01D4/025Melt-blowing or solution-blowing dies
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00Spinnerette packs; Cleaning thereof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/098Melt spinning methods with simultaneous stretching

Definitions

  • the invention relates to a device for producing filaments of thermoplastic material, comprising a meltblown die having a plastic guide core with at least one row of nozzle holes for the exit of the plastic melt and further arranged on both sides of the plastic guide core feed means for primary blowing air, with which the filaments in the region of the mouths of the nozzle bores can be acted upon on both sides with the primary blowing air.
  • endless filaments are produced with the device according to the invention.
  • the filaments are deposited on a laying device to form a random fleece or meltblown fleece.
  • the meltblown webs produced in this way are used as filters or in filters.
  • the technical problem underlying the invention to provide a device of the type mentioned, with the simple and functionally reliable manner, the filament diameter can be effectively reduced, so that diameters smaller than 1 .mu.m and in particular also can be achieved significantly less than 1 micron.
  • the invention teaches an apparatus for producing filaments of thermoplastic material, - having a meltblown die, which has a plastic guide core with at least one row of nozzle holes for the exit of the plastic melt and further arranged on both sides of the plastic guide core feed means for primary blowing air, with which the filaments in the region of the mouths of the nozzle bores can be acted upon on both sides with the Primärblas Kunststoff and wherein at least one supply device for secondary blowing air is provided, with which the filaments below the meltblown blowing head can be acted on laterally or from the side with secondary blowing air.
  • the exit of the plastic melt or polymer melt from the nozzle bores of the plastic guide core takes place in the form of plastic streams which, as it were, form the filaments.
  • the Primärblas Kunststoff or Primärblas Kunststoffstrahlen are expediently guided acute angle against each other below the nozzle holes. It is within the scope of the invention that the primary blowing air is supplied through corresponding gaps on the plastic guide core in the form of Blas Kunststoff vomstrahlen.
  • the primary blowing air is supplied on both sides by gaps or channels between plastic guide core and die lips, and preferably, the gap width of the gap is adjustable.
  • the gap width of the gap is adjustable below the plastic guide core thus expediently two opposite nozzle lips arranged, which are preferably adjustable, so that the gap width of the gaps between the plastic guide core and the die lips is adjustable.
  • the distance x between the plastic guide core tip and the (imaginary) horizontal extension of the nozzle lip tip is expediently adjustable.
  • secondary blowing air below the meltblown blowing head is additionally blown from the side onto the filaments or onto the filament curtain.
  • the secondary blowing air at an angle ⁇ of 50 ° to 90 °, preferably from 65 ° to 90 ° and preferably from 75 ° to 90 ° to a running through a nozzle bore imaginary line or vertical sideways or is inflatable from the side.
  • the angle ⁇ is thus, so to speak, the angle between a Sekundärblasluftstrahl and said imaginary line or vertical.
  • the Sekundärblasluftstrahlen are thus at an angle ⁇ to the imaginary lines extending through the nozzle bores or vertical to the emerging from these nozzle bores filaments inflatable.
  • the direction of the imaginary straight line corresponds to the primary (undeflected) discharge direction of the filaments from the nozzle bores.
  • the Sekundärblas Kunststoff is orthogonal or substantially orthogonal to a running through a nozzle bore imaginary straight line or vertical inflatable.
  • Essentially orthogonal means that the angle ⁇ is 80 ° to 90 ° and preferably 85 ° to 90 °.
  • the secondary blowing air is blown at high speed to the filaments or to the filament curtain.
  • the vibrations of the filaments or of the threads are amplified both in their frequency and in their amplitude.
  • the invention is insofar the realization on the basis that additional draw points or additional points of the thread draw are generated in this way, so that a very effective and extensive stretching of the filaments is possible.
  • the at least one feed device for the secondary blowing air is set up with the proviso that secondary blowing air can be inflated with an elevated temperature compared with the room temperature (20 ° C.).
  • secondary blowing air with a temperature higher than 50 ° C, preferably with a temperature higher than 60 ° C is inflatable.
  • a secondary blowing air temperature between 65 ° C and 90 ° C, and more preferably between 70 ° C and 80 ° C.
  • the heated secondary blowing air preferably has a relative humidity of less than 70%, preferably less than 50% and very preferably less than 20%.
  • the invention is based on the finding that the thermoplastic phase of the filaments is, as it were, lengthened by blowing the warm or hot secondary blowing air so that the filaments remain stretchable on their way. In this way, a very effective stretching is thus achieved.
  • Zu Operations desken are arranged for the secondary blowing air with the proviso that the filaments or the filament curtain can be acted upon from both sides with secondary blowing air or is.
  • supply means are provided on both sides of the filament curtain, so that the bidirectional loading of the filament curtain with secondary blowing air is possible.
  • the blowing with the secondary blowing air from at least one side of the filaments or the filament curtain is constant in time.
  • Temporal constant blowing means in particular, that the blowing speed of the secondary blowing air remains constant over time.
  • the blowing with the secondary blowing air is preferably constant in time from both sides of the filaments or the filament curtain.
  • the blowing with the secondary blowing air from at least one side of the filaments or the filament curtain is pulsating (i.e., not constant in time).
  • pulsating blowing means that the blowing speed of the secondary blowing air changes over time.
  • the speed of the secondary blowing air can change, for example, in a pulsating or alternating manner between 0 and a speed value v1.
  • the device according to the invention has a depositing device on which the filaments can be deposited as random or meltblown fleece.
  • the meltblown web produced in this way is used in a very preferred embodiment of the invention as a filter or in filters and in particular in fine filters.
  • the invention also provides a process for the production of the filaments of thermoplastic material, wherein - as described - is worked both with the Primärblas Kunststoffanblasung and with the Sekundärblas Kunststoffanblasung.
  • the invention furthermore relates to the use of the filaments or of a meltblown nonwoven produced with the filaments as filter material.
  • the invention is based on the finding that with a device according to the invention or with the corresponding method according to the invention filaments can be produced, which are characterized by a surprisingly small diameter. It can easily filaments with a filament diameter smaller than 1 micron and also be produced with a filament diameter significantly smaller than 1 micron.
  • the invention is further based on the finding that the filaments are effectively excited to additional oscillations with the aid of the secondary blowing-off of the invention, and that the number of draw points or draw regions is thereby effectively increased. In combination with this, special importance is attached to the blowing of secondary higher-temperature blowing air, since this can effectively prolong the thermoplastic phase of the filaments.
  • FIGURE shows a schematic representation of a section through a device according to the invention.
  • the meltblown die 2 is equipped with a plastic guide core 3, which in the embodiment has a number of nozzle holes 4 for the exit of the plastic melt.
  • the row of nozzle bores 4 extends perpendicular to the plane of the paper.
  • supply means for secondary blowing air are provided on both sides of the filament curtain from the filaments 1, with which the filaments below the meltblown blow head 2 are laterally charged with secondary blowing air.
  • This Sekundärblas Kunststoffbeetzhausung has been indicated in the figure by the arrows B.
  • the secondary blowing air can be inflated orthogonally or essentially orthogonally to the imaginary straight lines 7 passing through the nozzle bores 4.
  • the angle ⁇ between the Sekundärblas Kunststoffanblasung or between a Sekundärblas Kunststoff and a straight line 7 is therefore 90 ° or approximately 90 °.
  • an oscillation of the filaments 1 is effectively enhanced. In this way, additional draw points or points of Fadenunterziehung to the filaments.
  • secondary blowing air having a temperature higher than 50 ° C is blown.
  • the temperature of the secondary blowing air is 65 ° C to 85 ° C, preferably 70 ° C to 80 ° C.
  • a depositing device 8 which is preferably formed and in the embodiment as a wire belt.
  • the filaments are expediently stored as not shown meltblown fleece.
  • the meltblown fleece is particularly suitable for filter applications.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Nonwoven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
EP04022248A 2004-09-17 2004-09-17 Dispositif pour la production de filaments en matériau thermoplastique Expired - Lifetime EP1637632B1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
DE502004004519T DE502004004519D1 (de) 2004-09-17 2004-09-17 Vorrichtung zur Herstellung von Filamenten aus thermoplastischem Kunststoff
EP04022248A EP1637632B1 (fr) 2004-09-17 2004-09-17 Dispositif pour la production de filaments en matériau thermoplastique
AT04022248T ATE368759T1 (de) 2004-09-17 2004-09-17 Vorrichtung zur herstellung von filamenten aus thermoplastischem kunststoff
DK04022248T DK1637632T3 (da) 2004-09-17 2004-09-17 Anordning til fremstilling af filamenter af termoplast
ES04022248T ES2287619T3 (es) 2004-09-17 2004-09-17 Dispositivo para la fabricacion de filamentos de material termoplastico.
MXPA05009748A MXPA05009748A (es) 2004-09-17 2005-09-13 Dispositivo para producir filamentos a partir de material sintetico termoplastico.
KR1020050085835A KR100783450B1 (ko) 2004-09-17 2005-09-14 열가소성 합성 섬유로 필라멘트를 제조하는 장치
US11/226,231 US20060061006A1 (en) 2004-09-17 2005-09-15 Device for producing filaments from thermoplastic synthetic
CN2005101040755A CN1757800B (zh) 2004-09-17 2005-09-15 用热塑性合成物制造长丝的设备
JP2005269633A JP2006083511A (ja) 2004-09-17 2005-09-16 熱可塑性の合成物質からフィラメントを製造するための装置
BRPI0504077-9A BRPI0504077B1 (pt) 2004-09-17 2005-09-16 Dispositivo para produzir filamentos de um termoplástico sintético

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP04022248A EP1637632B1 (fr) 2004-09-17 2004-09-17 Dispositif pour la production de filaments en matériau thermoplastique

Publications (2)

Publication Number Publication Date
EP1637632A1 true EP1637632A1 (fr) 2006-03-22
EP1637632B1 EP1637632B1 (fr) 2007-08-01

Family

ID=34926598

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04022248A Expired - Lifetime EP1637632B1 (fr) 2004-09-17 2004-09-17 Dispositif pour la production de filaments en matériau thermoplastique

Country Status (11)

Country Link
US (1) US20060061006A1 (fr)
EP (1) EP1637632B1 (fr)
JP (1) JP2006083511A (fr)
KR (1) KR100783450B1 (fr)
CN (1) CN1757800B (fr)
AT (1) ATE368759T1 (fr)
BR (1) BRPI0504077B1 (fr)
DE (1) DE502004004519D1 (fr)
DK (1) DK1637632T3 (fr)
ES (1) ES2287619T3 (fr)
MX (1) MXPA05009748A (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012020053A1 (fr) * 2010-08-12 2012-02-16 Galliano Boscolo Procédé et appareil destinés à filer des fibres et, en particulier, à produire un non-tissé contenant des fibres
DE102012004227A1 (de) * 2012-03-06 2013-09-12 Carl Freudenberg Kg Verfahren und Vorrichtung zur Herstellung von superfeinen Polymerfasern durch Melt-blown-Technik
WO2013182296A1 (fr) * 2012-06-04 2013-12-12 Irema-Filter Gmbh Procédé de fabrication d'un non-tissé
US9168471B2 (en) 2010-11-22 2015-10-27 Irema-Filter Gmbh Air filter medium combining two mechanisms of action
US10273611B2 (en) 2006-03-28 2019-04-30 Irema-Filter Gmbh Pleatable nonwoven material and method and apparatus for production thereof
CN111850708A (zh) * 2020-08-26 2020-10-30 嘉兴学院 一种具有辅助吹喷功能的熔喷纺丝喷头结构
US11571645B2 (en) 2013-05-16 2023-02-07 Iremea-Filter Gmbh Fibrous nonwoven and method for the production thereof

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5813008B2 (ja) 2010-12-06 2015-11-17 三井化学株式会社 メルトブロー不織布、その製造方法および装置
JP5782594B1 (ja) * 2014-07-21 2015-09-24 岡 潔 ナノファイバー形成用噴射ノズルヘッドおよびナノファイバー形成用噴射ノズルヘッドを具備するナノファイバーの製造装置
CN104532368B (zh) * 2015-01-27 2018-01-09 嘉兴学院 一种装卸式可调长梭型溶液喷射纺丝喷嘴及其使用方法
JPWO2017170241A1 (ja) * 2016-03-30 2018-10-04 三井化学株式会社 不織布の製造装置、不織布の製造方法及び不織布
EP3714086A4 (fr) 2017-11-22 2021-10-06 Extrusion Group, LLC Ensemble embout de matrice et procédé de fusion-soufflage
CN109837598A (zh) * 2019-04-17 2019-06-04 中国科学院长春应用化学研究所 一种微流控纺丝装置及方法
KR102773617B1 (ko) * 2019-12-20 2025-02-25 재단법인 포항산업과학연구원 무기섬유 제조방법 및 그 제조장치
CN111910262B (zh) * 2020-08-04 2022-04-15 冯建国 熔喷式无纺布制作设备、方法、熔喷式无纺布与卫生用品
CN114075700B (zh) * 2020-08-19 2022-11-29 中国科学院宁波材料技术与工程研究所 一种链式预调制熔喷方法、链式预调制熔喷头及熔喷装置
CN112030238B (zh) * 2020-08-31 2021-06-08 山东恒鹏卫生用品有限公司 一种熔喷布生产制造熔喷模头
WO2024098139A1 (fr) * 2022-11-08 2024-05-16 Heat-Mx Worldwide Procédés pour la récupération de déchets textiles et leur recyclage sans teinture ni production de contamination microplastique dans un système d'eau

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4622259A (en) * 1985-08-08 1986-11-11 Surgikos, Inc. Nonwoven medical fabric
US4753843A (en) * 1986-05-01 1988-06-28 Kimberly-Clark Corporation Absorbent, protective nonwoven fabric
US5075068A (en) * 1990-10-11 1991-12-24 Exxon Chemical Patents Inc. Method and apparatus for treating meltblown filaments
EP0474421A2 (fr) * 1990-08-29 1992-03-11 CHICOPEE (a New Jersey corp.) Assemblage de barre d'espacement pour une filière du type fusion-soufflage
WO1992018677A1 (fr) * 1991-04-22 1992-10-29 Minnesota Mining And Manufacturing Company Fibres fondues-soufflees etirees, procedes de fabrication et textiles produits a partir desdites fibres
EP0564784A1 (fr) * 1992-04-07 1993-10-13 Kimberly-Clark Corporation Tissu non-tissé fibreux anisotropique
WO1994009200A1 (fr) * 1992-10-14 1994-04-28 Exxon Chemical Patents Inc. Tissu souffle par fusion
US5523033A (en) * 1993-12-08 1996-06-04 The Board Of Regents Of The University Of Oklahoma Polymer processing using pulsating fluidic flow
WO1997005306A1 (fr) * 1995-08-02 1997-02-13 Kimberly-Clark Worldwide, Inc. Procede et dispositif de production de fibres artificielles de bandes de non-tisses et de non-tisses sorbants
WO1999032692A1 (fr) * 1997-12-19 1999-07-01 Kimberly-Clark Worldwide, Inc. Procede et appareil de fusion-soufflage a refroidissement d'air
US6488801B1 (en) * 1999-06-16 2002-12-03 First Quality Nonwoven, Inc. Method of making media of controlled porosity and product thereof
WO2004001104A1 (fr) * 2002-06-20 2003-12-31 3M Innovative Properties Company Collecteur de fluide d'attenuation pour filiere de fusion-soufflage

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DE2618406B2 (de) * 1976-04-23 1979-07-26 Karl Fischer Apparate- & Rohrleitungsbau, 1000 Berlin Verfahren zum Herstellen vororientierter Füamentgarne aus thermoplastischen Polymeren
JP2989684B2 (ja) * 1991-04-18 1999-12-13 株式会社クラレ ポリメチルペンテン極細繊維ウエブ及びその製造方法
JP2001081660A (ja) * 1999-09-07 2001-03-27 Tonen Tapyrus Co Ltd 高強度メルトブロー不織布及びその製造方法

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4622259A (en) * 1985-08-08 1986-11-11 Surgikos, Inc. Nonwoven medical fabric
US4753843A (en) * 1986-05-01 1988-06-28 Kimberly-Clark Corporation Absorbent, protective nonwoven fabric
EP0474421A2 (fr) * 1990-08-29 1992-03-11 CHICOPEE (a New Jersey corp.) Assemblage de barre d'espacement pour une filière du type fusion-soufflage
US5075068A (en) * 1990-10-11 1991-12-24 Exxon Chemical Patents Inc. Method and apparatus for treating meltblown filaments
WO1992018677A1 (fr) * 1991-04-22 1992-10-29 Minnesota Mining And Manufacturing Company Fibres fondues-soufflees etirees, procedes de fabrication et textiles produits a partir desdites fibres
EP0564784A1 (fr) * 1992-04-07 1993-10-13 Kimberly-Clark Corporation Tissu non-tissé fibreux anisotropique
WO1994009200A1 (fr) * 1992-10-14 1994-04-28 Exxon Chemical Patents Inc. Tissu souffle par fusion
US5523033A (en) * 1993-12-08 1996-06-04 The Board Of Regents Of The University Of Oklahoma Polymer processing using pulsating fluidic flow
WO1997005306A1 (fr) * 1995-08-02 1997-02-13 Kimberly-Clark Worldwide, Inc. Procede et dispositif de production de fibres artificielles de bandes de non-tisses et de non-tisses sorbants
WO1999032692A1 (fr) * 1997-12-19 1999-07-01 Kimberly-Clark Worldwide, Inc. Procede et appareil de fusion-soufflage a refroidissement d'air
US6488801B1 (en) * 1999-06-16 2002-12-03 First Quality Nonwoven, Inc. Method of making media of controlled porosity and product thereof
WO2004001104A1 (fr) * 2002-06-20 2003-12-31 3M Innovative Properties Company Collecteur de fluide d'attenuation pour filiere de fusion-soufflage

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10273611B2 (en) 2006-03-28 2019-04-30 Irema-Filter Gmbh Pleatable nonwoven material and method and apparatus for production thereof
WO2012020053A1 (fr) * 2010-08-12 2012-02-16 Galliano Boscolo Procédé et appareil destinés à filer des fibres et, en particulier, à produire un non-tissé contenant des fibres
RU2602481C2 (ru) * 2010-08-12 2016-11-20 Бома Инжиниринг Срл Способ и устройство для формования волокон, в частности, для изготовления волокносодержащего нетканого материала
US9617658B2 (en) 2010-08-12 2017-04-11 Boma Engineering Srl Apparatus for spinning fibres and producing a fibrous-containing nonwoven
US9168471B2 (en) 2010-11-22 2015-10-27 Irema-Filter Gmbh Air filter medium combining two mechanisms of action
DE102012004227A1 (de) * 2012-03-06 2013-09-12 Carl Freudenberg Kg Verfahren und Vorrichtung zur Herstellung von superfeinen Polymerfasern durch Melt-blown-Technik
WO2013182296A1 (fr) * 2012-06-04 2013-12-12 Irema-Filter Gmbh Procédé de fabrication d'un non-tissé
US11571645B2 (en) 2013-05-16 2023-02-07 Iremea-Filter Gmbh Fibrous nonwoven and method for the production thereof
CN111850708A (zh) * 2020-08-26 2020-10-30 嘉兴学院 一种具有辅助吹喷功能的熔喷纺丝喷头结构

Also Published As

Publication number Publication date
KR20060051299A (ko) 2006-05-19
EP1637632B1 (fr) 2007-08-01
BRPI0504077B1 (pt) 2015-08-04
KR100783450B1 (ko) 2007-12-07
MXPA05009748A (es) 2006-05-31
DK1637632T3 (da) 2007-10-29
ATE368759T1 (de) 2007-08-15
JP2006083511A (ja) 2006-03-30
CN1757800B (zh) 2010-05-05
ES2287619T3 (es) 2007-12-16
BRPI0504077A (pt) 2006-05-02
US20060061006A1 (en) 2006-03-23
DE502004004519D1 (de) 2007-09-13
CN1757800A (zh) 2006-04-12

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