EP1636651B8 - Low-viscous, radiation curable formulation, particularly for the stereolithographical production of earpieces - Google Patents
Low-viscous, radiation curable formulation, particularly for the stereolithographical production of earpieces Download PDFInfo
- Publication number
- EP1636651B8 EP1636651B8 EP04738713A EP04738713A EP1636651B8 EP 1636651 B8 EP1636651 B8 EP 1636651B8 EP 04738713 A EP04738713 A EP 04738713A EP 04738713 A EP04738713 A EP 04738713A EP 1636651 B8 EP1636651 B8 EP 1636651B8
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- viscosity
- viscous
- radiation curable
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009472 formulation Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 230000005855 radiation Effects 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000654 additive Substances 0.000 abstract 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- -1 2,2,6,6-tetramethylpiperidin-1-yloxy Chemical group 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 239000012963 UV stabilizer Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
- B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
- B29C64/135—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/118—Initiator containing with inhibitor or stabilizer
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Composite Materials (AREA)
- Structural Engineering (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
- Materials For Medical Uses (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Dental Preparations (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10328302A DE10328302A1 (en) | 2003-06-23 | 2003-06-23 | Low-viscosity, radiation-curable formulation, in particular for stereolithography, for use in medical technology, in particular for the production of ear pieces |
| PCT/DE2004/001262 WO2005001570A1 (en) | 2003-06-23 | 2004-06-17 | Low-viscous, radiation curable formulation, particularly for the stereolithographical production of earpieces |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP1636651A1 EP1636651A1 (en) | 2006-03-22 |
| EP1636651B1 EP1636651B1 (en) | 2009-10-28 |
| EP1636651B8 true EP1636651B8 (en) | 2010-02-17 |
Family
ID=33546628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04738713A Expired - Lifetime EP1636651B8 (en) | 2003-06-23 | 2004-06-17 | Low-viscous, radiation curable formulation, particularly for the stereolithographical production of earpieces |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7232646B2 (en) |
| EP (1) | EP1636651B8 (en) |
| JP (1) | JP4251368B2 (en) |
| CN (1) | CN1813220B (en) |
| AT (1) | ATE447200T1 (en) |
| AU (1) | AU2004252589B2 (en) |
| CA (1) | CA2530069C (en) |
| DE (2) | DE10328302A1 (en) |
| WO (1) | WO2005001570A1 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004050868A1 (en) * | 2004-10-18 | 2006-04-20 | Dreve Otoplastik Gmbh | Low-viscosity, radiation-curable formulation for the production of ear molds |
| DE102005050186A1 (en) * | 2005-10-18 | 2007-04-19 | Dreve Otoplastik Gmbh | Low viscosity, radiation-hardenable composition for antimicrobial medical products, especially adaptive ear pieces, is based on e.g. (meth)acrylates, glass or silver antimicrobials and photoinitiators |
| US7354870B2 (en) * | 2005-11-14 | 2008-04-08 | National Research Council Of Canada | Process for chemical etching of parts fabricated by stereolithography |
| DE102007017195A1 (en) * | 2007-04-12 | 2008-10-16 | Dreve Otoplastik Gmbh | Biocompatible, radiation-curing formulation for the generative production of medical-technical products, in particular earmolds and dental moldings, by means of image projection systems |
| DE102007041489A1 (en) | 2007-08-31 | 2009-03-05 | Deltamed Gmbh | Flexible medical-technical molded body and method for its production |
| EP2445028A1 (en) | 2010-10-25 | 2012-04-25 | Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO | Opto-electric device and method of manufacturing an opto-electric device |
| EP2445029A1 (en) * | 2010-10-25 | 2012-04-25 | Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO | Multilayered protective layer, organic opto-electric device and method of manufacturing the same |
| US10357435B2 (en) * | 2012-12-18 | 2019-07-23 | Dentca, Inc. | Photo-curable resin compositions and method of using the same in three-dimensional printing for manufacturing artificial teeth and denture base |
| DK2986654T3 (en) * | 2013-04-18 | 2020-05-25 | Dentca Inc | Light-curing resin compositions and methods for using them for three-dimensional printing to make artificial teeth and denture base |
| EP3234035B1 (en) * | 2014-12-18 | 2021-06-02 | BASF Coatings GmbH | Radiation curable composition comprising hydrophilic nanoparticles |
| CN112313577B (en) | 2018-04-20 | 2024-07-09 | 斯特拉塔西斯公司 | Radiation curable compositions for additive manufacturing |
| US20230365830A1 (en) * | 2020-10-08 | 2023-11-16 | Dic Corporation | Resin composition for stereolithography |
| CA3197362A1 (en) | 2020-11-30 | 2022-06-02 | Dinesh Kumar BASKER | Radiation curable resin |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0425441B1 (en) * | 1989-10-27 | 1995-12-27 | Ciba-Geigy Ag | Photosensitive mixture |
| DE4009602A1 (en) * | 1990-03-26 | 1991-10-02 | Ivoclar Ag | POLYMERIZABLE DENTAL MATERIAL |
| GB9504995D0 (en) * | 1995-03-11 | 1995-04-26 | Zeneca Ltd | Compositions |
| DE59701299D1 (en) * | 1996-07-29 | 2000-04-27 | Ciba Sc Holding Ag | Liquid, radiation-curable composition, especially for stereolithography |
| US5969000A (en) * | 1997-01-17 | 1999-10-19 | Jeneric Pentron Incorporated | Dental resin materials |
| US6569602B1 (en) * | 1998-10-05 | 2003-05-27 | E. I. Du Pont De Nemours And Company | Ionization radiation imageable photopolymer compositions |
| DE10108261B4 (en) * | 2001-02-21 | 2006-07-20 | Ivoclar Vivadent Ag | Polymerizable composition with particulate composite based filler |
| US6660208B2 (en) * | 2001-03-30 | 2003-12-09 | 3D Systems, Inc. | Detoxification of solid freeform fabrication materials |
| JP2002302523A (en) * | 2001-04-04 | 2002-10-18 | Rion Co Ltd | Stereolithography resin |
| EP1456307B1 (en) * | 2001-10-03 | 2011-12-07 | 3D Systems, Inc. | Phase change support material composition |
| GB0212062D0 (en) * | 2002-05-24 | 2002-07-03 | Vantico Ag | Jetable compositions |
| US6989225B2 (en) * | 2002-07-18 | 2006-01-24 | 3D Systems, Inc. | Stereolithographic resins with high temperature and high impact resistance |
-
2003
- 2003-06-23 DE DE10328302A patent/DE10328302A1/en not_active Withdrawn
-
2004
- 2004-06-17 EP EP04738713A patent/EP1636651B8/en not_active Expired - Lifetime
- 2004-06-17 CN CN2004800177082A patent/CN1813220B/en not_active Expired - Fee Related
- 2004-06-17 DE DE502004010300T patent/DE502004010300D1/en not_active Expired - Lifetime
- 2004-06-17 US US10/561,651 patent/US7232646B2/en not_active Expired - Lifetime
- 2004-06-17 WO PCT/DE2004/001262 patent/WO2005001570A1/en not_active Ceased
- 2004-06-17 JP JP2006520655A patent/JP4251368B2/en not_active Expired - Fee Related
- 2004-06-17 CA CA2530069A patent/CA2530069C/en not_active Expired - Lifetime
- 2004-06-17 AU AU2004252589A patent/AU2004252589B2/en not_active Ceased
- 2004-06-17 AT AT04738713T patent/ATE447200T1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE502004010300D1 (en) | 2009-12-10 |
| EP1636651A1 (en) | 2006-03-22 |
| CN1813220A (en) | 2006-08-02 |
| ATE447200T1 (en) | 2009-11-15 |
| DE10328302A1 (en) | 2005-01-27 |
| CA2530069C (en) | 2009-12-22 |
| US20060264526A1 (en) | 2006-11-23 |
| EP1636651B1 (en) | 2009-10-28 |
| AU2004252589B2 (en) | 2007-03-22 |
| US7232646B2 (en) | 2007-06-19 |
| WO2005001570A1 (en) | 2005-01-06 |
| AU2004252589A1 (en) | 2005-01-06 |
| JP2007500759A (en) | 2007-01-18 |
| JP4251368B2 (en) | 2009-04-08 |
| CN1813220B (en) | 2010-11-03 |
| CA2530069A1 (en) | 2005-01-06 |
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| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: KLARE, MARTIN Inventor name: MEISSNER, GEORGIA Inventor name: KUTSCHINSKI, MICHAEL Inventor name: VEIT, THOMAS Inventor name: ALTMANN, REINER |
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