EP1691612A1 - Utilisation de fongicides pour la desinfection de semences de cereales - Google Patents
Utilisation de fongicides pour la desinfection de semences de cerealesInfo
- Publication number
- EP1691612A1 EP1691612A1 EP04764638A EP04764638A EP1691612A1 EP 1691612 A1 EP1691612 A1 EP 1691612A1 EP 04764638 A EP04764638 A EP 04764638A EP 04764638 A EP04764638 A EP 04764638A EP 1691612 A1 EP1691612 A1 EP 1691612A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- active
- combinations
- seeds
- dressing
- used according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 235000013339 cereals Nutrition 0.000 title claims description 9
- 230000000249 desinfective effect Effects 0.000 title abstract 2
- 239000000417 fungicide Substances 0.000 title description 5
- 239000004480 active ingredient Substances 0.000 claims abstract description 23
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005839 Tebuconazole Substances 0.000 claims abstract description 9
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005825 Prothioconazole Substances 0.000 claims abstract description 8
- 241000233866 Fungi Species 0.000 claims abstract description 5
- 230000003032 phytopathogenic effect Effects 0.000 claims abstract description 5
- 239000000890 drug combination Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 24
- 238000009472 formulation Methods 0.000 description 20
- 230000000855 fungicidal effect Effects 0.000 description 8
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 8
- 239000013543 active substance Substances 0.000 description 7
- 239000002270 dispersing agent Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 229930191978 Gibberellin Natural products 0.000 description 4
- 241000209140 Triticum Species 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000003448 gibberellin Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- -1 defoamers Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000005980 Gibberellic acid Substances 0.000 description 2
- 240000001931 Ludwigia octovalvis Species 0.000 description 2
- 241001459558 Monographella nivalis Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- SEEGHKWOBVVBTQ-NFMPGMCNSA-N gibberellin A7 Chemical compound C([C@@H]1C[C@]2(CC1=C)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 SEEGHKWOBVVBTQ-NFMPGMCNSA-N 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- RSQSQJNRHICNNH-UHFFFAOYSA-N Gibberellin A4 Natural products OC(=O)C1C2(CC3=C)CC3CCC2C2(OC3=O)C1C3(C)C(O)CC2 RSQSQJNRHICNNH-UHFFFAOYSA-N 0.000 description 1
- HHDWSDSMWJQURA-UHFFFAOYSA-N Gibberellin A51 Natural products C12CCC(C3)C(=C)CC23C(C(O)=O)C2C3(C)C(=O)OC21CC(O)C3 HHDWSDSMWJQURA-UHFFFAOYSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 241000722133 Tilletia Species 0.000 description 1
- 235000019714 Triticale Nutrition 0.000 description 1
- 241000221566 Ustilago Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000012868 active agrochemical ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- ALLOLPOYFRLCCX-UHFFFAOYSA-N chembl1986529 Chemical compound COC1=CC=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ALLOLPOYFRLCCX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 229960003887 dichlorophen Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- RSQSQJNRHICNNH-NFMPGMCNSA-N gibberellin A4 Chemical compound C([C@@H]1C[C@]2(CC1=C)[C@H]1C(O)=O)C[C@H]2[C@@]2(OC3=O)[C@H]1[C@@]3(C)[C@@H](O)CC2 RSQSQJNRHICNNH-NFMPGMCNSA-N 0.000 description 1
- SEEGHKWOBVVBTQ-UHFFFAOYSA-N gibberellin GA7 Natural products OC(=O)C1C2(CC3=C)CC3CCC2C2(C=CC3O)C1C3(C)C(=O)O2 SEEGHKWOBVVBTQ-UHFFFAOYSA-N 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 239000004476 plant protection product Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 241000228158 x Triticosecale Species 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Definitions
- the invention relates to the use of fungicidal compositions containing prothioconazoles and tebuconazoles for dressing seeds.
- the fungicidal action of the active compound combinations which can be used according to the invention in the treatment of seeds is considerably higher than the sum of the actions of the individual active compounds. So there is an unforeseeable, real synergistic effect and not just an addition.
- Prosthioconazoles and their use as fungicides are known (cf. WO 96-16 048).
- This active ingredient is 2- [2- (l-chlorocyclopropyl) -3- (2-chlorophenyl) -2-hydroxypropyl] -2,4-dihydro [l, 2,4] triazol-3-thione , both in the "Thiono" form of the formula
- Tebuconazole and its use as a fungicide are also known (cf. EP-A 0 040 345).
- This active ingredient is the tnazole devat of the formula
- the active compounds are present in the active compound combinations which can be used according to the invention in certain weight ratios, the synergistic effect is particularly evident.
- the weight ratios of the active ingredients in the active ingredient combinations can be varied within a relatively wide range. In general, 1 to 1 part by weight of prothioconazole accounts for 0.01 to 100 parts by weight, preferably 0.05 to 20 parts by weight, of tebuconazole.
- the active substance combinations which can be used according to the invention can also contain further active substances.
- the active substance combinations which can be used according to the invention have very good fungicidal properties and can be used to combat phytopathogenic fungi, such as plasmidiophoromycetes, Oomycetes, Chyt ⁇ diomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes etc. They are particularly suitable for combating cereal diseases such as Tilletia, Ustilago and Fusanum.
- the active compound combinations which can be used according to the invention can be converted into the customary mordant formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other coating compositions for seeds, and TLV formulations.
- customary mordant formulations such as solutions, emulsions, suspensions, powders, foams, slurries or other coating compositions for seeds, and TLV formulations.
- customary additives such as, for example, customary extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also water.
- Suitable dyes which can be contained in the mordant formulations which can be used according to the invention are all dyes customary for such purposes. Both pigments that are sparingly soluble in water and dyes that are soluble in water can be used. Examples include those under the names Rhodarr ⁇ n B, C.I. Pigment Red 112 and C.I. Solvent Red 1 known dyes.
- Suitable wetting agents which can be contained in the mordant formulations which can be used according to the invention are all substances which are customary for the formulation of agrochemical active substances and which promote wetting.
- Alkyl naphthalene sulfonates such as diisopropyl or diisobutyl naphthalene sulfonates, can preferably be used.
- Suitable dispersants and / or emulsifiers which may be present in the mordant formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active ingredients.
- Nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants can preferably be used.
- Suitable nonionic dispersants include, in particular, ethylene oxide / propylene oxide block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
- Suitable anionic dispersants are, in particular, lignin sulfonates, polyacrylic acid salts and aryl sulfonate-formaldehyde condensates.
- the mordant formulations which can be used according to the invention can contain, as defoamers, all of the foam-inhibiting substances which are customary for formulating active agrochemicals. Silicone defoamers and magnesium stearate can preferably be used.
- All substances which can be used for such purposes in agrochemical compositions can be present as preservatives in the mordant formulations which can be used according to the invention.
- Examples include dichlorophene and benzyl alcohol hemiform.
- the secondary thickeners which can be contained in the mordant formulations which can be used according to the invention are all used for such purposes in agrochemical compositions usable substances in question.
- Cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and highly disperse silica are preferred.
- Suitable adhesives which can be contained in the mordant formulations which can be used according to the invention are all binders which are customarily used in mordants.
- Polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose are preferred.
- Substances of the formula are preferably used as gibberellins which can be contained in the mordant formulations which can be used according to the invention
- R represents a hydrogen atom or a hydroxy group
- gibberellins of the formula (III) are:
- the mordant formulations which can be used according to the invention can be used either directly or after prior dilution with water to treat cereal seeds of the most varied ax.
- the concentrates or the preparations obtainable therefrom by dilution with water can be used for dressing the seeds of wheat, barley, rye, oats, millet, spelled, triticale, corn and rice.
- the seed dressing formulations which can be used according to the invention or their diluted preparations can also be used for dressing seeds of transgenic plants. In cooperation with the substances formed by expression, additional synergistic effects can also occur.
- the dressing is carried out by placing the seed in a mixer, adding the desired amount of dressing formulation either as such or after prior dilution with water and mixing until the formulation is uniformly distributed on the seed. If necessary, a drying process follows.
- the application rate of the mordant formulations which can be used according to the invention can be varied within a relatively wide range. It depends on the respective content of the active ingredients in the formulations and on the seeds.
- the application rates of active ingredient combination are generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 15 g per kilogram of seed.
- Fungicides always have a synergistic effect if the fungicidal activity of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
- X means the efficiency when using the active ingredient A in an application rate of m g / 100 kg
- Y means the efficiency when using the active ingredient B in an application rate of n g / 100 kg
- E means the efficiency when using active ingredients A and B in application rates of rn and n g / 100 kg
- the efficiency is determined in%. It means 0% an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
- the combination of the combination is superadditive, ie there is a synergistic effect.
- the actually observed efficiency may be greater than the value for the expected efficiency (E) calculated from the above formula.
- the active ingredients or the combination of active ingredients are used in such a way that commercially available liquid stains of the individual active ingredients or the combination of active ingredients are used.
- the infected seed is shaken for 3 minutes with the respective dressing agent in a sealed plastic container.
- the plants are evaluated for symptoms 3 weeks after sowing.
- the effectiveness is expressed in percent. 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Abstract
Utilisation de combinaisons de principes actifs qui contiennent du prothioconazole et du tébuconazole, pour protéger des semences contre l'attaque de champignons pathogènes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10341945A DE10341945A1 (de) | 2003-09-11 | 2003-09-11 | Verwendung von fungiziden Mitteln zur Beizung von Saatgut |
| PCT/EP2004/009672 WO2005027638A1 (fr) | 2003-09-11 | 2004-08-31 | Utilisation de fongicides pour la désinfection de semences de céréales |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1691612A1 true EP1691612A1 (fr) | 2006-08-23 |
Family
ID=34352799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04764638A Ceased EP1691612A1 (fr) | 2003-09-11 | 2004-08-31 | Utilisation de fongicides pour la desinfection de semences de cereales |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US20070054804A1 (fr) |
| EP (1) | EP1691612A1 (fr) |
| JP (1) | JP2007505061A (fr) |
| KR (1) | KR20060119939A (fr) |
| CN (1) | CN100521940C (fr) |
| AR (1) | AR045635A1 (fr) |
| AU (1) | AU2004273593A1 (fr) |
| BR (1) | BRPI0414271A (fr) |
| CA (1) | CA2538510A1 (fr) |
| DE (1) | DE10341945A1 (fr) |
| EA (1) | EA009063B1 (fr) |
| EG (1) | EG24301A (fr) |
| IL (1) | IL174096A0 (fr) |
| MA (1) | MA28040A1 (fr) |
| MX (1) | MXPA06002674A (fr) |
| NO (1) | NO20061585L (fr) |
| NZ (1) | NZ545784A (fr) |
| RS (1) | RS20060173A (fr) |
| TN (1) | TNSN06081A1 (fr) |
| UA (1) | UA83251C2 (fr) |
| WO (1) | WO2005027638A1 (fr) |
| ZA (1) | ZA200601959B (fr) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4426753A1 (de) * | 1994-07-28 | 1996-02-01 | Bayer Ag | Mittel zur Bekämpfung von Pflanzenschädlingen |
| DE19716257A1 (de) * | 1997-04-18 | 1998-10-22 | Bayer Ag | Fungizide Wirkstoffkombination |
| ATE313953T1 (de) | 1998-06-10 | 2006-01-15 | Bayer Cropscience Ag | Mittel zur bekämpfung von pflanzenschädlingen |
| DE10228102A1 (de) * | 2002-06-24 | 2004-01-15 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
| DE10228103A1 (de) * | 2002-06-24 | 2004-01-15 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
| DE10228104A1 (de) * | 2002-06-24 | 2004-01-15 | Bayer Cropscience Ag | Fungizide Wirkstoffkombination |
| DE10335183A1 (de) * | 2003-07-30 | 2005-02-24 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
| DE10347090A1 (de) | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| DE10347440A1 (de) * | 2003-10-13 | 2005-05-04 | Bayer Cropscience Ag | Synergistische insektizide Mischungen |
| BRPI0417315B1 (pt) * | 2003-12-04 | 2016-03-08 | Bayer Cropscience Ag | agente para controle de pragas animais, seu uso, processo para combater pragas animais, e processo para produção de agentes praguicidas. |
| BRPI0417322B1 (pt) * | 2003-12-04 | 2015-11-24 | Bayer Cropscience Ag | agente inseticida, seu processo de preparação, e processo para combate de parasitas animais |
| KR20090120014A (ko) * | 2003-12-12 | 2009-11-23 | 바이엘 크롭사이언스 아게 | 상승적 살충 혼합물 |
| DE102004020840A1 (de) * | 2004-04-27 | 2005-11-24 | Bayer Cropscience Ag | Verwendung von Alkylcarbonsäureamiden als Penetrationsförderer |
| EP1606999A1 (fr) * | 2004-06-18 | 2005-12-21 | Bayer CropScience AG | Agent pour le traitement des semences de soja |
| DE102004049041A1 (de) | 2004-10-08 | 2006-04-13 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
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| CA2958199C (fr) | 2014-08-15 | 2023-03-07 | Axonics Modulation Technologies, Inc. | Positionnement d'une derivation electromyographique et titrage de la stimulation dans un systeme de stimulation nerveuse pour le traitement de la vessie hyperactive |
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2003
- 2003-09-11 DE DE10341945A patent/DE10341945A1/de not_active Withdrawn
-
2004
- 2004-08-31 AU AU2004273593A patent/AU2004273593A1/en not_active Abandoned
- 2004-08-31 JP JP2006525695A patent/JP2007505061A/ja active Pending
- 2004-08-31 UA UAA200604027A patent/UA83251C2/ru unknown
- 2004-08-31 CA CA002538510A patent/CA2538510A1/fr not_active Abandoned
- 2004-08-31 BR BRPI0414271-3A patent/BRPI0414271A/pt not_active IP Right Cessation
- 2004-08-31 MX MXPA06002674A patent/MXPA06002674A/es unknown
- 2004-08-31 NZ NZ545784A patent/NZ545784A/en not_active IP Right Cessation
- 2004-08-31 KR KR1020067004741A patent/KR20060119939A/ko not_active Ceased
- 2004-08-31 EA EA200600537A patent/EA009063B1/ru not_active IP Right Cessation
- 2004-08-31 WO PCT/EP2004/009672 patent/WO2005027638A1/fr not_active Ceased
- 2004-08-31 RS YUP-2006/0173A patent/RS20060173A/sr unknown
- 2004-08-31 EP EP04764638A patent/EP1691612A1/fr not_active Ceased
- 2004-08-31 CN CNB2004800256597A patent/CN100521940C/zh not_active Expired - Lifetime
- 2004-08-31 US US10/570,945 patent/US20070054804A1/en not_active Abandoned
- 2004-09-10 AR ARP040103263A patent/AR045635A1/es not_active Application Discontinuation
-
2006
- 2006-03-02 IL IL174096A patent/IL174096A0/en unknown
- 2006-03-08 ZA ZA200601959A patent/ZA200601959B/en unknown
- 2006-03-08 EG EGNA2006000230 patent/EG24301A/xx active
- 2006-03-10 TN TNP2006000081A patent/TNSN06081A1/en unknown
- 2006-03-14 MA MA28874A patent/MA28040A1/fr unknown
- 2006-04-07 NO NO20061585A patent/NO20061585L/no not_active Application Discontinuation
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Also Published As
| Publication number | Publication date |
|---|---|
| RS20060173A (sr) | 2008-08-07 |
| MXPA06002674A (es) | 2006-06-06 |
| BRPI0414271A (pt) | 2006-11-07 |
| MA28040A1 (fr) | 2006-07-03 |
| AR045635A1 (es) | 2005-11-02 |
| KR20060119939A (ko) | 2006-11-24 |
| US20070054804A1 (en) | 2007-03-08 |
| EA009063B1 (ru) | 2007-10-26 |
| TNSN06081A1 (en) | 2007-10-03 |
| NZ545784A (en) | 2009-12-24 |
| NO20061585L (no) | 2006-04-07 |
| CN100521940C (zh) | 2009-08-05 |
| AU2004273593A1 (en) | 2005-03-31 |
| CN1845675A (zh) | 2006-10-11 |
| JP2007505061A (ja) | 2007-03-08 |
| CA2538510A1 (fr) | 2005-03-31 |
| DE10341945A1 (de) | 2005-04-21 |
| WO2005027638A1 (fr) | 2005-03-31 |
| EG24301A (en) | 2009-01-12 |
| EA200600537A1 (ru) | 2006-08-25 |
| IL174096A0 (en) | 2006-08-01 |
| UA83251C2 (ru) | 2008-06-25 |
| ZA200601959B (en) | 2007-05-30 |
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